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Title: Experimental and numerical analysis of parallel reactant flow and transverse mixing with mineral precipitation in homogeneous and heterogeneous porous media

Formation of mineral precipitates in the mixing interface between two reactant solutions flowing in parallel in porous media is governed by reactant mixing by diffusion and dispersion and is coupled to changes in porosity/permeability due to precipitation. The spatial and temporal distribution of mixing-dependent precipitation of barium sulfate in porous media was investigated with side-by-side injection of barium chloride and sodium sulfate solutions in thin rectangular flow cells packed with quartz sand. The results for homogeneous sand beds were compared to beds with higher or lower permeability inclusions positioned in the path of the mixing zone. In the homogeneous and high permeability inclusion experiments, BaSO4 precipitate (barite) formed in a narrow deposit along the length and in the center of the solution–solution mixing zone even though dispersion was enhanced within, and downstream of, the high permeability inclusion. In the low permeability inclusion experiment, the deflected BaSO4 precipitation zone broadened around one side and downstream of the inclusion and was observed to migrate laterally toward the sulfate solution. A continuum-scale fully coupled reactive transport model that simultaneously solves the nonlinear governing equations for fluid flow, transport of reactants and geochemical reactions was used to simulate the experiments and provide insight intomore » mechanisms underlying the experimental observations. Lastly, migration of the precipitation zone in the low permeability inclusion experiment could be explained by the coupling effects among fluid flow, reactant transport and localized mineral precipitation reaction.« less
Authors:
 [1] ;  [2] ;  [1] ;  [1] ;  [3]
  1. Idaho National Lab. (INL), Idaho Falls, ID (United States)
  2. Univ. of Utah, Salt Lake City, UT (United States)
  3. Montana State Univ., Bozeman, MT (United States)
Publication Date:
OSTI Identifier:
1252729
Report Number(s):
INL/JOU--13-29594
Journal ID: ISSN 0169-3913; PII: 614
Grant/Contract Number:
AC07-05ID14517
Type:
Accepted Manuscript
Journal Name:
Transport in Porous Media
Additional Journal Information:
Journal Volume: 111; Journal Issue: 3; Journal ID: ISSN 0169-3913
Publisher:
Springer
Research Org:
Idaho National Laboratory, Idaho Falls, ID (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
54 ENVIRONMENTAL SCIENCES mixing; coupled flow-transport-reaction processes; mineral precipitation; permeability