A comparison of H2S, SO2, and COS poisoning on Ni/YSZ and Ni/K2O-CaAl2O4 during methane steam and dry reforming

Jablonski, Whitney S.; Villano, Stephanie M.; Dean, Anthony M.

doi:10.1016/j.apcata.2015.06.009

Title: A comparison of H2S, SO2, and COS poisoning on Ni/YSZ and Ni/K2O-CaAl2O4 during methane steam and dry reforming

Authors:: Jablonski, Whitney S.; Villano, Stephanie M.; Dean, Anthony M.

Publication Date:: Sat Aug 01 00:00:00 EDT 2015

Sponsoring Org.:: USDOE

OSTI Identifier:: 1251978

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Applied Catalysis. A, General

Additional Journal Information:: Journal Name: Applied Catalysis. A, General Journal Volume: 502 Journal Issue: C; Journal ID: ISSN 0926-860X

Publisher:: Elsevier

Country of Publication:: Netherlands

Language:: English

Citation Formats


                    Jablonski, Whitney S., Villano, Stephanie M., and Dean, Anthony M. A comparison of H2S, SO2, and COS poisoning on Ni/YSZ and Ni/K2O-CaAl2O4 during methane steam and dry reforming.  Netherlands: N. p., 2015. 
Web.  doi:10.1016/j.apcata.2015.06.009.

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                    Jablonski, Whitney S., Villano, Stephanie M., & Dean, Anthony M. A comparison of H2S, SO2, and COS poisoning on Ni/YSZ and Ni/K2O-CaAl2O4 during methane steam and dry reforming.  Netherlands.  https://doi.org/10.1016/j.apcata.2015.06.009

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                    Jablonski, Whitney S., Villano, Stephanie M., and Dean, Anthony M. Sat .  
"A comparison of H2S, SO2, and COS poisoning on Ni/YSZ and Ni/K2O-CaAl2O4 during methane steam and dry reforming".  Netherlands.  https://doi.org/10.1016/j.apcata.2015.06.009.

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@article{osti_1251978,

  title        = {A comparison of H2S, SO2, and COS poisoning on Ni/YSZ and Ni/K2O-CaAl2O4 during methane steam and dry reforming},

  author       = {Jablonski, Whitney S. and Villano, Stephanie M. and Dean, Anthony M.},

  abstractNote = {},

  doi          = {10.1016/j.apcata.2015.06.009},

  journal      = {Applied Catalysis. A, General},

  number       = C,

  volume       = 502,

  place        = {Netherlands},

  year         = {Sat Aug 01 00:00:00 EDT 2015},

  month        = {Sat Aug 01 00:00:00 EDT 2015}

}

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Title: A comparison of H2S, SO2, and COS poisoning on Ni/YSZ and Ni/K2O-CaAl2O4 during methane steam and dry reforming

Citation Formats

Performance evaluation of different configurations of biogas-fuelled SOFC micro-CHP systems for residential applications journal, April 2010

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Feasibility of direct-biogas SOFC journal, November 2008

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Hydrogen Production via Steam Reforming of the Aqueous Phase of Bio-Oil in a Fixed Bed Reactor journal, September 2006

Reforming of Methane with Carbon Dioxide to Synthesis Gas over Supported Rhodium Catalysts journal, January 1996

Internal reforming development for solid oxide fuel cells journal, May 1990

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A detailed kinetic model for biogas steam reforming on Ni and catalyst deactivation due to sulfur poisoning journal, February 2014

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Mechanisms of CO and COS Formation in the Claus Furnace
journal, January 2001

Sulfur Poisoning of SOFCs: A Model Based Explanation of Polarization Dependent Extent of Poisoning
journal, January 2014

Internal reforming SOFC running on biogas
journal, August 2010

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journal, March 2015

Performance analysis of a SOFC under direct internal reforming conditions
journal, October 2007

From Ni-YSZ to sulfur-tolerant anode materials for SOFCs: electrochemical behavior, in situ characterization, modeling, and future perspectives
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Sulfur poisoning of Boudouard and methanation reactions on nickel catalysts
journal, October 1979

The poisoning effect of sulfur-containing impurity gas on a SOFC anode: Part I. Dependence on temperature, time, and impurity concentration
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journal, April 2001

Filamentous Carbon Formation and Gasification: Thermodynamics, Driving Force, Nucleation, and Steady-State Growth
journal, July 1997

Steam Reforming and Graphite Formation on Ni Catalysts
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Modelling of tubular-designed solid oxide fuel cell with indirect internal reforming operation fed by different primary fuels
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Isotopic and kinetic assessment of the mechanism of reactions of CH4 with CO2 or H2O to form synthesis gas and carbon on nickel catalysts
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Tolerance tests of H2S-laden biogas fuel on solid oxide fuel cells
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The Effect of H2S on the Performance of SOFCs using Methane Containing Fuel
journal, September 2010

Comparison of the performance of Cu–CeO2–YSZ and Ni–YSZ composite SOFC anodes with H2, CO, and syngas
journal, March 2005

Sulfur-passivated nickel catalysts for carbon-free steam reforming of methane
journal, January 1984

The effect of current density on H2S-poisoning of nickel-based solid oxide fuel cell anodes
journal, September 2011

Kinetics of internal steam reforming of methane on Ni/YSZ-based anodes for solid oxide fuel cells
journal, December 2000

Effect of H2O on sulfur poisoning and catalytic activity of Ni–YSZ catalysts
journal, February 2011

Feasibility of direct-biogas SOFC
journal, November 2008

Study on carbon deposition associated with catalytic CH4 reforming by using density functional theory
journal, November 2013

Hydrogen Production via Steam Reforming of the Aqueous Phase of Bio-Oil in a Fixed Bed Reactor
journal, September 2006

Reforming of Methane with Carbon Dioxide to Synthesis Gas over Supported Rhodium Catalysts
journal, January 1996

Internal reforming development for solid oxide fuel cells
journal, May 1990

Influence of fractal pore structure in Claus catalyst performance
journal, April 2002

Methane reforming kinetics within a Ni–YSZ SOFC anode support
journal, October 2005

A detailed kinetic model for biogas steam reforming on Ni and catalyst deactivation due to sulfur poisoning
journal, February 2014

Fabrication and evaluation of solid-oxide fuel cell anodes employing reaction-sintered yttria-stabilized zirconia
journal, September 2009

Experimental Study of Model Biogas Catalytic Steam Reforming: 2. Impact of Sulfur on the Deactivation and Regeneration of Ni-Based Catalysts
journal, November 2008

Computational Investigation of Thermochemistry and Kinetics of Steam Methane Reforming on Ni(111) under Realistic Conditions
journal, February 2009

Intrinsic Kinetics of the Internal Steam Reforming of CH ₄ over a Ni−YSZ−Cermet Catalyst−Electrode
journal, December 2000

Electricity production from wastewater treatment via a novel biogas-SOFC aided process
journal, September 2008

Hydrodesulfurization process with pre-saturation using reformate for application in a 5kW fuel cell system
journal, November 2014

Thermodynamic Analysis of Carbon Deposition and Electrochemical Oxidation of Methane for SOFC Anodes
journal, January 2001

Internal steam reforming of methane over Ni-based electrode in solid oxide fuel cells
journal, December 1995

Small-Scale Biogas-SOFC Plant: Technical Analysis and Assessment of Different Fuel Reforming Options
journal, May 2014

Internal steam reforming in fuel cells and alkali poisoning
journal, June 1995

Process flow model of solid oxide fuel cell system supplied with sewage biogas
journal, May 2004

Mechanisms of carbon formation on nickel-containing catalysts
journal, June 1977

Sulfur poisoning of Ni-based anodes for Solid Oxide Fuel Cells in H/C-based fuels
journal, September 2014

Elementary Kinetic Numerical Simulation of Ni/YSZ SOFC Anode Performance Considering Sulfur Poisoning
journal, November 2014

A new method for obtaining ultra-low sulfur diesel fuel via ultrasound assisted oxidative desulfurization☆
journal, March 2003

Advances in catalysts for internal reforming in high temperature fuel cells
journal, March 1998

Biogas as a fuel source for SOFC co-generators
journal, March 2004

COS-Forming Reaction between CO and Sulfur: A High-Temperature Intrinsic Kinetics Study
journal, December 1998

Fuel processor integrated H2S catalytic partial oxidation technology for sulfur removal in fuel cell power plants☆
journal, December 2002