Effects of cycling temperatures on the voltage fade phenomenon in 0.5Li2MnO3·0.5LiNi0.375Mn0.375Co0.25O2 cathodes

Vu, Anh; Walker, Lee K.; Bareño, Javier; Burrell, Anthony K.; Bloom, Ira

doi:10.1016/j.jpowsour.2015.01.059

Title: Effects of cycling temperatures on the voltage fade phenomenon in 0.5Li2MnO3·0.5LiNi0.375Mn0.375Co0.25O2 cathodes

Authors:: Vu, Anh; Walker, Lee K.; Bareño, Javier; Burrell, Anthony K.; Bloom, Ira

Publication Date:: Wed Apr 01 00:00:00 EDT 2015

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO)

OSTI Identifier:: 1250116

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Journal of Power Sources

Additional Journal Information:: Journal Name: Journal of Power Sources Journal Volume: 280 Journal Issue: C; Journal ID: ISSN 0378-7753

Publisher:: Elsevier

Country of Publication:: Netherlands

Language:: English

Citation Formats


                    Vu, Anh, Walker, Lee K., Bareño, Javier, Burrell, Anthony K., and Bloom, Ira. Effects of cycling temperatures on the voltage fade phenomenon in 0.5Li2MnO3·0.5LiNi0.375Mn0.375Co0.25O2 cathodes.  Netherlands: N. p., 2015. 
Web.  doi:10.1016/j.jpowsour.2015.01.059.

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                    Vu, Anh, Walker, Lee K., Bareño, Javier, Burrell, Anthony K., & Bloom, Ira. Effects of cycling temperatures on the voltage fade phenomenon in 0.5Li2MnO3·0.5LiNi0.375Mn0.375Co0.25O2 cathodes.  Netherlands.  https://doi.org/10.1016/j.jpowsour.2015.01.059

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                    Vu, Anh, Walker, Lee K., Bareño, Javier, Burrell, Anthony K., and Bloom, Ira. Wed .  
"Effects of cycling temperatures on the voltage fade phenomenon in 0.5Li2MnO3·0.5LiNi0.375Mn0.375Co0.25O2 cathodes".  Netherlands.  https://doi.org/10.1016/j.jpowsour.2015.01.059.

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@article{osti_1250116,

  title        = {Effects of cycling temperatures on the voltage fade phenomenon in 0.5Li2MnO3·0.5LiNi0.375Mn0.375Co0.25O2 cathodes},

  author       = {Vu, Anh and Walker, Lee K. and Bareño, Javier and Burrell, Anthony K. and Bloom, Ira},

  abstractNote = {},

  doi          = {10.1016/j.jpowsour.2015.01.059},

  journal      = {Journal of Power Sources},

  number       = C,

  volume       = 280,

  place        = {Netherlands},

  year         = {Wed Apr 01 00:00:00 EDT 2015},

  month        = {Wed Apr 01 00:00:00 EDT 2015}

}

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https://doi.org/10.1016/j.jpowsour.2015.01.059

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Works referenced in this record:

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Fox, Dennis S.; Opila, Elizabeth J.; Nguyen, QuynhGiao N.
Journal of the American Ceramic Society, Vol. 86, Issue 8
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Schnizlein, J. G.; Fischer, D. F.
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The Effect of Oxide Volatilization on the Oxidation Kinetics of Cr and Fe-Cr Alloys
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Wajszel, Dominik
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Countering the Voltage Decay in High Capacity xLi ₂ MnO ₃ •(1–x)LiMO ₂ Electrodes (M=Mn, Ni, Co) for Li ⁺ -Ion Batteries
journal, January 2012

Croy, Jason R.; Kim, Donghan; Balasubramanian, Mahalingam
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Paralinear Oxidation of Chromium in O2 + H2O Environment at 600–700 °C
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Pujilaksono, Bagas; Jonsson, Torbjörn; Halvarsson, Mats
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From coin cells to 400 mAh pouch cells: Enhancing performance of high-capacity lithium-ion cells via modifications in electrode constitution and fabrication
journal, August 2014

Trask, Stephen E.; Li, Yan; Kubal, Joseph J.
Journal of Power Sources, Vol. 259
DOI: 10.1016/j.jpowsour.2014.02.077

Correlating hysteresis and voltage fade in lithium- and manganese-rich layered transition-metal oxide electrodes
journal, August 2013

Gallagher, Kevin G.; Croy, Jason R.; Balasubramanian, Mahalingam
Electrochemistry Communications, Vol. 33
DOI: 10.1016/j.elecom.2013.04.022

Operando Structural Characterization of the Lithium-Substituted Layered Sodium-Ion Cathode Material P2-Na _0.85 Li _0.17 Ni _0.21 Mn _0.64 O ₂ by X-ray Absorption Spectroscopy
journal, January 2014

Karan, Naba K.; Slater, Michael D.; Dogan, Fulya
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Voltage Fade of Layered Oxides: Its Measurement and Impact on Energy Density
journal, January 2013

Bettge, Martin; Li, Yan; Gallagher, Kevin
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Effect of interface modifications on voltage fade in 0.5Li2MnO3·0.5LiNi0.375Mn0.375Co0.25O2 cathode materials
journal, March 2014

Bloom, Ira; Trahey, Lynn; Abouimrane, Ali
Journal of Power Sources, Vol. 249
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Examining Hysteresis in Composite x Li ₂ MnO ₃ ·(1– x )LiMO ₂ Cathode Structures
journal, March 2013

Croy, Jason R.; Gallagher, Kevin G.; Balasubramanian, Mahalingam
The Journal of Physical Chemistry C, Vol. 117, Issue 13
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Effects of cycling temperatures on the voltage fade phenomenon in 0.5Li 2 MnO 3 ·0.5LiNi 0.375 Mn 0.375 Co 0.25 O 2 cathodes

Journal Article Vu, Anh ; Walker, Lee K. ; Bareño, Javier ; ... - Journal of Power Sources

The rate of voltage fade in 0.5Li2MnO3•0.5LiNi0.375Mn0.375Co0.25O2 cathodes was measured in half-cells in a temperature range of 25 to 55°C. On the basis of the dependence of the values of the open-circuit potential with cycle count and temperature, the voltage fade phenomenon seems to consist of two chemical processes: one that can be described using a parabolic rate law and another that uses a linear-with-time law. As the cycling temperature increased, the relative contributions of the two processes changed. On the basis of the overall rate versus temperature data, we believe the two processes may be in competition with onemore » another.« less
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Title: Effects of cycling temperatures on the voltage fade phenomenon in 0.5Li2MnO3·0.5LiNi0.375Mn0.375Co0.25O2 cathodes

Citation Formats

Paralinear Oxidation of Silicon Nitride in a Water-Vapor/Oxygen Environment journal, August 2003

The Kinetics of Oxidation of Plutonium Metal and a Plutonium-3.4 a/o Aluminum Alloy at Temperatures from 140° to 550°C journal, January 1967

The Effect of Oxide Volatilization on the Oxidation Kinetics of Cr and Fe-Cr Alloys journal, January 1966

A Method for Calculating Paralinear Constants for the Formation of Volatile Scale journal, January 1963

Countering the Voltage Decay in High Capacity xLi 2 MnO 3 •(1–x)LiMO 2 Electrodes (M=Mn, Ni, Co) for Li + -Ion Batteries journal, January 2012

Paralinear Oxidation of Chromium in O2 + H2O Environment at 600–700 °C journal, July 2008

High-Temperature Sulfiding of Iron Alloys in Hydrogen Sulfide-Hydrogen Mixtures journal, January 1959

From coin cells to 400 mAh pouch cells: Enhancing performance of high-capacity lithium-ion cells via modifications in electrode constitution and fabrication journal, August 2014

Correlating hysteresis and voltage fade in lithium- and manganese-rich layered transition-metal oxide electrodes journal, August 2013

Operando Structural Characterization of the Lithium-Substituted Layered Sodium-Ion Cathode Material P2-Na 0.85 Li 0.17 Ni 0.21 Mn 0.64 O 2 by X-ray Absorption Spectroscopy journal, January 2014

Voltage Fade of Layered Oxides: Its Measurement and Impact on Energy Density journal, January 2013

Transitions from Parabolic to Linear Kinetics in Scaling of Metals journal, January 1959

Effect of interface modifications on voltage fade in 0.5Li2MnO3·0.5LiNi0.375Mn0.375Co0.25O2 cathode materials journal, March 2014

Examining Hysteresis in Composite x Li 2 MnO 3 ·(1– x )LiMO 2 Cathode Structures journal, March 2013

Paralinear Oxidation of Silicon Nitride in a Water-Vapor/Oxygen Environment
journal, August 2003

The Kinetics of Oxidation of Plutonium Metal and a Plutonium-3.4 a/o Aluminum Alloy at Temperatures from 140° to 550°C
journal, January 1967

The Effect of Oxide Volatilization on the Oxidation Kinetics of Cr and Fe-Cr Alloys
journal, January 1966

A Method for Calculating Paralinear Constants for the Formation of Volatile Scale
journal, January 1963

Countering the Voltage Decay in High Capacity xLi ₂ MnO ₃ •(1–x)LiMO ₂ Electrodes (M=Mn, Ni, Co) for Li ⁺ -Ion Batteries
journal, January 2012

Paralinear Oxidation of Chromium in O2 + H2O Environment at 600–700 °C
journal, July 2008

High-Temperature Sulfiding of Iron Alloys in Hydrogen Sulfide-Hydrogen Mixtures
journal, January 1959

From coin cells to 400 mAh pouch cells: Enhancing performance of high-capacity lithium-ion cells via modifications in electrode constitution and fabrication
journal, August 2014

Correlating hysteresis and voltage fade in lithium- and manganese-rich layered transition-metal oxide electrodes
journal, August 2013

Operando Structural Characterization of the Lithium-Substituted Layered Sodium-Ion Cathode Material P2-Na _0.85 Li _0.17 Ni _0.21 Mn _0.64 O ₂ by X-ray Absorption Spectroscopy
journal, January 2014

Voltage Fade of Layered Oxides: Its Measurement and Impact on Energy Density
journal, January 2013

Transitions from Parabolic to Linear Kinetics in Scaling of Metals
journal, January 1959

Effect of interface modifications on voltage fade in 0.5Li2MnO3·0.5LiNi0.375Mn0.375Co0.25O2 cathode materials
journal, March 2014

Examining Hysteresis in Composite x Li ₂ MnO ₃ ·(1– x )LiMO ₂ Cathode Structures
journal, March 2013