An environmentally benign and low-cost approach to synthesis of thermally stable industrial catalyst Cu/SiO2 for the hydrogenation of dimethyl oxalate to ethylene glycol

Popa, Tiberiu; Zhang, Yulong; Jin, Erlei; Fan, Maohong

doi:10.1016/j.apcata.2015.07.026

Title: An environmentally benign and low-cost approach to synthesis of thermally stable industrial catalyst Cu/SiO2 for the hydrogenation of dimethyl oxalate to ethylene glycol

Authors:: Popa, Tiberiu; Zhang, Yulong; Jin, Erlei; Fan, Maohong

Publication Date:: Tue Sep 01 00:00:00 EDT 2015

Sponsoring Org.:: USDOE

OSTI Identifier:: 1250106

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Applied Catalysis. A, General

Additional Journal Information:: Journal Name: Applied Catalysis. A, General Journal Volume: 505 Journal Issue: C; Journal ID: ISSN 0926-860X

Publisher:: Elsevier

Country of Publication:: Netherlands

Language:: English

Citation Formats


                    Popa, Tiberiu, Zhang, Yulong, Jin, Erlei, and Fan, Maohong. An environmentally benign and low-cost approach to synthesis of thermally stable industrial catalyst Cu/SiO2 for the hydrogenation of dimethyl oxalate to ethylene glycol.  Netherlands: N. p., 2015. 
Web.  doi:10.1016/j.apcata.2015.07.026.

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                    Popa, Tiberiu, Zhang, Yulong, Jin, Erlei, & Fan, Maohong. An environmentally benign and low-cost approach to synthesis of thermally stable industrial catalyst Cu/SiO2 for the hydrogenation of dimethyl oxalate to ethylene glycol.  Netherlands.  https://doi.org/10.1016/j.apcata.2015.07.026

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                    Popa, Tiberiu, Zhang, Yulong, Jin, Erlei, and Fan, Maohong. Tue .  
"An environmentally benign and low-cost approach to synthesis of thermally stable industrial catalyst Cu/SiO2 for the hydrogenation of dimethyl oxalate to ethylene glycol".  Netherlands.  https://doi.org/10.1016/j.apcata.2015.07.026.

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@article{osti_1250106,

  title        = {An environmentally benign and low-cost approach to synthesis of thermally stable industrial catalyst Cu/SiO2 for the hydrogenation of dimethyl oxalate to ethylene glycol},

  author       = {Popa, Tiberiu and Zhang, Yulong and Jin, Erlei and Fan, Maohong},

  abstractNote = {},

  doi          = {10.1016/j.apcata.2015.07.026},

  journal      = {Applied Catalysis. A, General},

  number       = C,

  volume       = 505,

  place        = {Netherlands},

  year         = {Tue Sep 01 00:00:00 EDT 2015},

  month        = {Tue Sep 01 00:00:00 EDT 2015}

}

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https://doi.org/10.1016/j.apcata.2015.07.026

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Title: An environmentally benign and low-cost approach to synthesis of thermally stable industrial catalyst Cu/SiO2 for the hydrogenation of dimethyl oxalate to ethylene glycol

Citation Formats

Highly Dispersed Silica-Supported Copper Nanoparticles Prepared by Precipitation−Gel Method: A Simple but Efficient and Stable Catalyst for Glycerol Hydrogenolysis journal, August 2008

Study of extraction-oxidation desulfurization of model oil by acidic ionic liquid journal, September 2011

Unravelling the properties of supported copper oxide: can the particle size induce acidic behaviour? journal, January 2013

A new aerogel based CO 2 adsorbent developed using a simple sol–gel method along with supercritical drying journal, January 2014

Effect of feedstock solvent on the stability of Cu/SiO 2 catalyst for vapor-phase hydrogenation of dimethyl oxalate to ethylene glycol journal, January 2012

Cu/SiO2 hybrid catalysts containing HZSM-5 with enhanced activity and stability for selective hydrogenation of dimethyl oxalate to ethylene glycol journal, November 2012

Reaction processes and mechanism of supercritical transesterification in situ ATR infrared spectrum journal, November 2011

Cu/SiO2 catalysts prepared by the ammonia-evaporation method: Texture, structure, and catalytic performance in hydrogenation of dimethyl oxalate to ethylene glycol journal, July 2008

The effect of the amount of ammonia on the Cu0/Cu+ ratio of Cu/SiO2 catalyst for the hydrogenation of dimethyl oxalate to ethylene glycol journal, November 2014

A nanostructured CeO 2 promoted Pd/α-alumina diethyl oxalate catalyst with high activity and stability journal, January 2014

Temperature dependent microstructure of MTES modified hydrophobic silica aerogels journal, February 2011

A copper-phyllosilicate core-sheath nanoreactor for carbon–oxygen hydrogenolysis reactions journal, September 2013

Silver-modulated SiO2-supported copper catalysts for selective hydrogenation of dimethyl oxalate to ethylene glycol journal, November 2013

Effect of the Cu/SBA-15 catalyst preparation method on methyl acetate hydrogenation for ethanol production journal, January 2014

Solvent feedstock effect: the insights into the deactivation mechanism of Cu/SiO2 catalysts for hydrogenation of dimethyl oxalate to ethylene glycol journal, January 2013

Remarkable Improvement of Catalytic Performance for a New Cobalt-Decorated Cu/HMS Catalyst in the Hydrogenation of Dimethyloxalate journal, October 2012

Highly active and selective copper-containing HMS catalyst in the hydrogenation of dimethyl oxalate to ethylene glycol journal, October 2008

Characterization and catalytic performance of sol–gel derived Cu/SiO2 catalysts for hydrogenolysis of diethyl oxalate to ethylene glycol journal, May 2010

Cu/SiO2 Catalysts Prepared by the Sol-Gel Method for Hydrogenation of Dimethyl Oxalate to Ethylene Glycol journal, January 2011

Ag/MCM-41 as a highly efficient mesostructured catalyst for the chemoselective synthesis of methyl glycolate and ethylene glycol journal, October 2011

The influence of different precipitants on the copper-based catalysts for hydrogenation of ethyl acetate to ethanol journal, July 2014

Why Urea Eliminates Ammonia Rather than Hydrolyzes in Aqueous Solution journal, February 2007

Highly active and selective Cu/SiO2 catalysts prepared by the urea hydrolysis method in dimethyl oxalate hydrogenation journal, July 2011

Urea thermolysis studied under flow reactor conditions using DSC and FT-IR journal, August 2009

Hydrogenation of dimethyl oxalate to ethylene glycol on a Cu/SiO2/cordierite monolithic catalyst: Enhanced internal mass transfer and stability journal, November 2011

Preparation of silica-supported copper catalysts by means of deposition-precipitation journal, March 1990

Icy: an open bioimage informatics platform for extended reproducible research journal, June 2012

The Influence of Copper Particle Dispersion in Cu/SiO2 Catalysts on the Hydrogenation Synthesis of Ethylene Glycol journal, February 2010

Effect of boric oxide doping on the stability and activity of a Cu–SiO2 catalyst for vapor-phase hydrogenation of dimethyl oxalate to ethylene glycol journal, January 2011

Detection limits in XPS for more than 6000 binary systems using Al and Mg Kα X-rays: XPS detection limits journal, February 2014

Metal Particle Size in Silica-Supported Copper Catalysts. Influence of the Conditions of Preparation and of Thermal Pretreatments journal, February 2000

NIH Image to ImageJ: 25 years of image analysis journal, June 2012

Indirect coal to liquid technologies journal, April 2014

Efficient low-temperature selective hydrogenation of esters on bimetallic Au–Ag/SBA-15 catalyst journal, January 2013

Cu Nanoparticles Inlaid Mesoporous Al 2 O 3 As a High-Performance Bifunctional Catalyst for Ethanol Synthesis via Dimethyl Oxalate Hydrogenation journal, September 2014

Effect of initial precipitation temperature on the structural evolution and catalytic behavior of Cu/SiO2 catalyst in the hydrogenation of dimethyloxalate journal, February 2011

Synthesis of Ethanol via Syngas on Cu/SiO 2 Catalysts with Balanced Cu 0 –Cu + Sites journal, May 2012

Highly Dispersed Silica-Supported Copper Nanoparticles Prepared by Precipitation−Gel Method: A Simple but Efficient and Stable Catalyst for Glycerol Hydrogenolysis
journal, August 2008

Study of extraction-oxidation desulfurization of model oil by acidic ionic liquid
journal, September 2011

Unravelling the properties of supported copper oxide: can the particle size induce acidic behaviour?
journal, January 2013

A new aerogel based CO ₂ adsorbent developed using a simple sol–gel method along with supercritical drying
journal, January 2014

Effect of feedstock solvent on the stability of Cu/SiO ₂ catalyst for vapor-phase hydrogenation of dimethyl oxalate to ethylene glycol
journal, January 2012

Cu/SiO2 hybrid catalysts containing HZSM-5 with enhanced activity and stability for selective hydrogenation of dimethyl oxalate to ethylene glycol
journal, November 2012

Reaction processes and mechanism of supercritical transesterification in situ ATR infrared spectrum
journal, November 2011

Cu/SiO2 catalysts prepared by the ammonia-evaporation method: Texture, structure, and catalytic performance in hydrogenation of dimethyl oxalate to ethylene glycol
journal, July 2008

The effect of the amount of ammonia on the Cu0/Cu+ ratio of Cu/SiO2 catalyst for the hydrogenation of dimethyl oxalate to ethylene glycol
journal, November 2014

A nanostructured CeO ₂ promoted Pd/α-alumina diethyl oxalate catalyst with high activity and stability
journal, January 2014

Temperature dependent microstructure of MTES modified hydrophobic silica aerogels
journal, February 2011

A copper-phyllosilicate core-sheath nanoreactor for carbon–oxygen hydrogenolysis reactions
journal, September 2013

Silver-modulated SiO2-supported copper catalysts for selective hydrogenation of dimethyl oxalate to ethylene glycol
journal, November 2013

Effect of the Cu/SBA-15 catalyst preparation method on methyl acetate hydrogenation for ethanol production
journal, January 2014

Solvent feedstock effect: the insights into the deactivation mechanism of Cu/SiO2 catalysts for hydrogenation of dimethyl oxalate to ethylene glycol
journal, January 2013

Remarkable Improvement of Catalytic Performance for a New Cobalt-Decorated Cu/HMS Catalyst in the Hydrogenation of Dimethyloxalate
journal, October 2012

Highly active and selective copper-containing HMS catalyst in the hydrogenation of dimethyl oxalate to ethylene glycol
journal, October 2008

Characterization and catalytic performance of sol–gel derived Cu/SiO2 catalysts for hydrogenolysis of diethyl oxalate to ethylene glycol
journal, May 2010

Cu/SiO2 Catalysts Prepared by the Sol-Gel Method for Hydrogenation of Dimethyl Oxalate to Ethylene Glycol
journal, January 2011

Ag/MCM-41 as a highly efficient mesostructured catalyst for the chemoselective synthesis of methyl glycolate and ethylene glycol
journal, October 2011

The influence of different precipitants on the copper-based catalysts for hydrogenation of ethyl acetate to ethanol
journal, July 2014

Why Urea Eliminates Ammonia Rather than Hydrolyzes in Aqueous Solution
journal, February 2007

Highly active and selective Cu/SiO2 catalysts prepared by the urea hydrolysis method in dimethyl oxalate hydrogenation
journal, July 2011

Urea thermolysis studied under flow reactor conditions using DSC and FT-IR
journal, August 2009

Hydrogenation of dimethyl oxalate to ethylene glycol on a Cu/SiO2/cordierite monolithic catalyst: Enhanced internal mass transfer and stability
journal, November 2011

Preparation of silica-supported copper catalysts by means of deposition-precipitation
journal, March 1990

Icy: an open bioimage informatics platform for extended reproducible research
journal, June 2012

The Influence of Copper Particle Dispersion in Cu/SiO2 Catalysts on the Hydrogenation Synthesis of Ethylene Glycol
journal, February 2010

Effect of boric oxide doping on the stability and activity of a Cu–SiO2 catalyst for vapor-phase hydrogenation of dimethyl oxalate to ethylene glycol
journal, January 2011

Detection limits in XPS for more than 6000 binary systems using Al and Mg Kα X-rays: XPS detection limits
journal, February 2014

Metal Particle Size in Silica-Supported Copper Catalysts. Influence of the Conditions of Preparation and of Thermal Pretreatments
journal, February 2000

NIH Image to ImageJ: 25 years of image analysis
journal, June 2012

Indirect coal to liquid technologies
journal, April 2014

Efficient low-temperature selective hydrogenation of esters on bimetallic Au–Ag/SBA-15 catalyst
journal, January 2013

Cu Nanoparticles Inlaid Mesoporous Al ₂ O ₃ As a High-Performance Bifunctional Catalyst for Ethanol Synthesis via Dimethyl Oxalate Hydrogenation
journal, September 2014

Effect of initial precipitation temperature on the structural evolution and catalytic behavior of Cu/SiO2 catalyst in the hydrogenation of dimethyloxalate
journal, February 2011

Synthesis of Ethanol via Syngas on Cu/SiO ₂ Catalysts with Balanced Cu ⁰ –Cu ⁺ Sites
journal, May 2012