Synthesis and evaluation of Cu/SAPO-34 catalysts for NH3-SCR 2: Solid-state ion exchange and one-pot synthesis

Gao, Feng; Walter, Eric D.; Washton, Nancy M.; Szanyi, János; Peden, Charles H. F.

doi:10.1016/j.apcatb.2014.07.029

Title: Synthesis and evaluation of Cu/SAPO-34 catalysts for NH3-SCR 2: Solid-state ion exchange and one-pot synthesis

Authors:: Gao, Feng; Walter, Eric D.; Washton, Nancy M.; Szanyi, János; Peden, Charles H. F.

Publication Date:: Thu Jan 01 00:00:00 EST 2015

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO); USDOE Office of Science (SC), Biological and Environmental Research (BER)

OSTI Identifier:: 1249840

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Applied Catalysis. B, Environmental

Additional Journal Information:: Journal Name: Applied Catalysis. B, Environmental Journal Volume: 162 Journal Issue: C; Journal ID: ISSN 0926-3373

Publisher:: Elsevier

Country of Publication:: Netherlands

Language:: English

Citation Formats


                    Gao, Feng, Walter, Eric D., Washton, Nancy M., Szanyi, János, and Peden, Charles H. F. Synthesis and evaluation of Cu/SAPO-34 catalysts for NH3-SCR 2: Solid-state ion exchange and one-pot synthesis.  Netherlands: N. p., 2015. 
Web.  doi:10.1016/j.apcatb.2014.07.029.

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                    Gao, Feng, Walter, Eric D., Washton, Nancy M., Szanyi, János, & Peden, Charles H. F. Synthesis and evaluation of Cu/SAPO-34 catalysts for NH3-SCR 2: Solid-state ion exchange and one-pot synthesis.  Netherlands.  https://doi.org/10.1016/j.apcatb.2014.07.029

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                    Gao, Feng, Walter, Eric D., Washton, Nancy M., Szanyi, János, and Peden, Charles H. F. Thu .  
"Synthesis and evaluation of Cu/SAPO-34 catalysts for NH3-SCR 2: Solid-state ion exchange and one-pot synthesis".  Netherlands.  https://doi.org/10.1016/j.apcatb.2014.07.029.

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@article{osti_1249840,

  title        = {Synthesis and evaluation of Cu/SAPO-34 catalysts for NH3-SCR 2: Solid-state ion exchange and one-pot synthesis},

  author       = {Gao, Feng and Walter, Eric D. and Washton, Nancy M. and Szanyi, János and Peden, Charles H. F.},

  abstractNote = {},

  doi          = {10.1016/j.apcatb.2014.07.029},

  journal      = {Applied Catalysis. B, Environmental},

  number       = C,

  volume       = 162,

  place        = {Netherlands},

  year         = {Thu Jan 01 00:00:00 EST 2015},

  month        = {Thu Jan 01 00:00:00 EST 2015}

}

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Synthesis and Evaluation of Cu/SAPO-34 Catalysts for NH3-SCR 2: Solid-state Ion Exchange and One-pot Synthesis

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Title: Synthesis and evaluation of Cu/SAPO-34 catalysts for NH3-SCR 2: Solid-state ion exchange and one-pot synthesis

Citation Formats

The State of the Art in Selective Catalytic Reduction of NO x by Ammonia Using Metal‐Exchanged Zeolite Catalysts journal, December 2008

Integrated operando X-ray absorption and DFT characterization of Cu–SSZ-13 exchange sites during the selective catalytic reduction of NOx with NH3 journal, April 2012

Effect of the Nature and Location of Copper Species on the Catalytic Nitric Oxide Selective Catalytic Reduction Performance of the Copper/SSZ-13 Zeolite journal, December 2013

Current Understanding of Cu-Exchanged Chabazite Molecular Sieves for Use as Commercial Diesel Engine DeNOx Catalysts journal, August 2013

Influence of the Choice of the Template on the Short- and Long-Term Stability of SAPO-34 Zeolite journal, May 1995

Catalytic DeNO activity of cobalt and copper ions in microporous MeALPO-34 and MeAPSO-34 journal, July 2002

Crystallization and Si incorporation mechanisms of SAPO-34 journal, June 2002

Nature of active species in copper-based catalysts and their chemistry of transformation of nitrogen oxides journal, November 1995

NO and CO adsorption studies on transition metal-exchanged silico-aluminophosphate of type 34 catalysts journal, February 2001

Low absorption vitreous carbon reactors for operandoXAS: a case study on Cu/Zeolites for selective catalytic reduction of NO x by NH 3 journal, January 2012

Spectroscopic and chemical characterization of active and inactive Cu species in NO decomposition catalysts based on Cu-ZSM5 journal, January 2002

Electron spin resonance and electron spin echo modulation studies of copper(II) ions in the aluminosilicate chabazite: a comparison of copper(II) cation location and adsorbate interaction with isostructural silicoaluminophosphate-34 journal, October 1992

Size-Dependent Catalytic Performance of CuO on γ-Al2O3: NO Reduction versus NH3 Oxidation journal, June 2012

Two different cationic positions in Cu-SSZ-13? journal, January 2012

In situ29Si MAS NMR studies of structural phase transitions of tridymite journal, June 1996

Changing active sites in Cu–CHA catalysts: deNOx selectivity as a function of the preparation method journal, January 2013

Copper Coordination in Cu-SSZ-13 and Cu-SSZ-16 Investigated by Variable-Temperature XRD journal, December 2009

Synthesis and Evaluation of Cu-SAPO-34 Catalysts for Ammonia Selective Catalytic Reduction. 1. Aqueous Solution Ion Exchange journal, August 2013

Rational direct synthesis methodology of very active and hydrothermally stable Cu-SAPO-34 molecular sieves for the SCR of NOx journal, October 2012

FTIR investigations of the adsorption and disproportionation of NO on Cu-exchanged silicoaluminophosphate of type 34 journal, January 1998

Use of different templates on SAPO-34 synthesis: Effect on the acidity and catalytic activity in the MTO reaction journal, January 2012

Synthesis of SAPO-34 Crystals in the Presence of Crystal Growth Inhibitors journal, December 2008

uAPSO-34 Catalysts for N2O Decomposition in the Presence of H2O. A Study of Zeolitic Structure Stability in Comparison to Cu-SAPO-34 and Cu-ZSM-5 journal, January 2003

The influence of silicon on the catalytic properties of Cu/SAPO-34 for NOx reduction by ammonia-SCR journal, October 2012

Effects of hydrothermal aging on NH3-SCR reaction over Cu/zeolites journal, March 2012

Isolated Cu 2+ ions: active sites for selective catalytic reduction of NO journal, January 2011

Location and nature of Cu species in Cu/SAPO-34 for selective catalytic reduction of NO with NH3 journal, May 2012

Structure–activity relationships in NH3-SCR over Cu-SSZ-13 as probed by reaction kinetics and EPR studies journal, April 2013

Characterization of Cu-exchanged SSZ-13: a comparative FTIR, UV-Vis, and EPR study with Cu-ZSM-5 and Cu-β with similar Si/Al and Cu/Al ratios journal, January 2013

Migration of Cu species in Cu/SAPO-34 during hydrothermal aging journal, October 2013

Influence of lattice stability on hydrothermal deactivation of Cu-ZSM-5 and Cu-IM-5 zeolites for selective catalytic reduction of NOx by NH3 journal, January 2014

Selective Catalytic Reduction of Nitric Oxide by Ammonia over Cu-FAU Catalysts in Oxygen-Rich Atmosphere journal, April 1999

Designed copper–amine complex as an efficient template for one-pot synthesis of Cu-SSZ-13 zeolite with excellent activity for selective catalytic reduction of NOx by NH3 journal, January 2011

The characteristics of SAPO-34 which influence the conversion of methanol to light olefins journal, June 1999

The effect of crystal size of SAPO-34 on the selectivity and deactivation of the MTO reaction journal, June 1999

Thermal durability of Cu-CHA NH3-SCR catalysts for diesel NOx reduction journal, April 2012

Local Environment and Nature of Cu Active Sites in Zeolite-Based Catalysts for the Selective Catalytic Reduction of NO x journal, February 2013

Confirmation of Isolated Cu 2+ Ions in SSZ-13 Zeolite as Active Sites in NH 3 -Selective Catalytic Reduction journal, February 2012

Solid-state ion exchange in H-SAPO-34: electron spin resonance and electron spin echo modulation studies of copper(II) location and adsorbate interaction journal, June 1992

Characterization of copper species over Cu/SAPO-34 in selective catalytic reduction of NO x with ammonia: Relationships between active Cu sites and de-NO x performance at low temperature journal, January 2013

The State of the Art in Selective Catalytic Reduction of NO _x by Ammonia Using Metal‐Exchanged Zeolite Catalysts
journal, December 2008

Integrated operando X-ray absorption and DFT characterization of Cu–SSZ-13 exchange sites during the selective catalytic reduction of NOx with NH3
journal, April 2012

Effect of the Nature and Location of Copper Species on the Catalytic Nitric Oxide Selective Catalytic Reduction Performance of the Copper/SSZ-13 Zeolite
journal, December 2013

Current Understanding of Cu-Exchanged Chabazite Molecular Sieves for Use as Commercial Diesel Engine DeNOx Catalysts
journal, August 2013

Influence of the Choice of the Template on the Short- and Long-Term Stability of SAPO-34 Zeolite
journal, May 1995

Catalytic DeNO activity of cobalt and copper ions in microporous MeALPO-34 and MeAPSO-34
journal, July 2002

Crystallization and Si incorporation mechanisms of SAPO-34
journal, June 2002

Nature of active species in copper-based catalysts and their chemistry of transformation of nitrogen oxides
journal, November 1995

NO and CO adsorption studies on transition metal-exchanged silico-aluminophosphate of type 34 catalysts
journal, February 2001

Low absorption vitreous carbon reactors for operandoXAS: a case study on Cu/Zeolites for selective catalytic reduction of NO _x by NH ₃
journal, January 2012

Spectroscopic and chemical characterization of active and inactive Cu species in NO decomposition catalysts based on Cu-ZSM5
journal, January 2002

Electron spin resonance and electron spin echo modulation studies of copper(II) ions in the aluminosilicate chabazite: a comparison of copper(II) cation location and adsorbate interaction with isostructural silicoaluminophosphate-34
journal, October 1992

Size-Dependent Catalytic Performance of CuO on γ-Al₂O₃: NO Reduction versus NH₃ Oxidation
journal, June 2012

Two different cationic positions in Cu-SSZ-13?
journal, January 2012

In situ²⁹Si MAS NMR studies of structural phase transitions of tridymite
journal, June 1996

Changing active sites in Cu–CHA catalysts: deNOx selectivity as a function of the preparation method
journal, January 2013

Copper Coordination in Cu-SSZ-13 and Cu-SSZ-16 Investigated by Variable-Temperature XRD
journal, December 2009

Synthesis and Evaluation of Cu-SAPO-34 Catalysts for Ammonia Selective Catalytic Reduction. 1. Aqueous Solution Ion Exchange
journal, August 2013

Rational direct synthesis methodology of very active and hydrothermally stable Cu-SAPO-34 molecular sieves for the SCR of NOx
journal, October 2012

FTIR investigations of the adsorption and disproportionation of NO on Cu-exchanged silicoaluminophosphate of type 34
journal, January 1998

Use of different templates on SAPO-34 synthesis: Effect on the acidity and catalytic activity in the MTO reaction
journal, January 2012

Synthesis of SAPO-34 Crystals in the Presence of Crystal Growth Inhibitors
journal, December 2008

uAPSO-34 Catalysts for N2O Decomposition in the Presence of H₂O. A Study of Zeolitic Structure Stability in Comparison to Cu-SAPO-34 and Cu-ZSM-5
journal, January 2003

The influence of silicon on the catalytic properties of Cu/SAPO-34 for NOx reduction by ammonia-SCR
journal, October 2012

Effects of hydrothermal aging on NH3-SCR reaction over Cu/zeolites
journal, March 2012

Isolated Cu ²⁺ ions: active sites for selective catalytic reduction of NO
journal, January 2011

Location and nature of Cu species in Cu/SAPO-34 for selective catalytic reduction of NO with NH3
journal, May 2012

Structure–activity relationships in NH3-SCR over Cu-SSZ-13 as probed by reaction kinetics and EPR studies
journal, April 2013

Characterization of Cu-exchanged SSZ-13: a comparative FTIR, UV-Vis, and EPR study with Cu-ZSM-5 and Cu-β with similar Si/Al and Cu/Al ratios
journal, January 2013

Migration of Cu species in Cu/SAPO-34 during hydrothermal aging
journal, October 2013

Influence of lattice stability on hydrothermal deactivation of Cu-ZSM-5 and Cu-IM-5 zeolites for selective catalytic reduction of NOx by NH3
journal, January 2014

Selective Catalytic Reduction of Nitric Oxide by Ammonia over Cu-FAU Catalysts in Oxygen-Rich Atmosphere
journal, April 1999

Designed copper–amine complex as an efficient template for one-pot synthesis of Cu-SSZ-13 zeolite with excellent activity for selective catalytic reduction of NOx by NH3
journal, January 2011

The characteristics of SAPO-34 which influence the conversion of methanol to light olefins
journal, June 1999

The effect of crystal size of SAPO-34 on the selectivity and deactivation of the MTO reaction
journal, June 1999

Thermal durability of Cu-CHA NH3-SCR catalysts for diesel NOx reduction
journal, April 2012

Local Environment and Nature of Cu Active Sites in Zeolite-Based Catalysts for the Selective Catalytic Reduction of NO _x
journal, February 2013

Confirmation of Isolated Cu ²⁺ Ions in SSZ-13 Zeolite as Active Sites in NH ₃ -Selective Catalytic Reduction
journal, February 2012

Solid-state ion exchange in H-SAPO-34: electron spin resonance and electron spin echo modulation studies of copper(II) location and adsorbate interaction
journal, June 1992

Characterization of copper species over Cu/SAPO-34 in selective catalytic reduction of NO x with ammonia: Relationships between active Cu sites and de-NO x performance at low temperature
journal, January 2013