Penta-Twinned Copper Nanorods: Facile Synthesis via Seed-Mediated Growth and Their Tunable Plasmonic Properties
Abstract
When seed-mediated growth is used as a versatile approach to the synthesis of penta-twinned Cu nanorods with uniform diameters and controllable aspect ratios is reported. The success of this approach relies on our recent synthesis of uniform Pd decahedra, with sizes in the range of 6–20 nm. The Pd decahedral seeds can direct the heterogeneous nucleation and growth of Cu along the fivefold axis to produce nanorods with uniform diameters defined by the lateral dimension of the original seeds. Due to a large mismatch in the lattice constants between Cu and Pd (7.1%), the deposited Cu is forced to grow along one side of the Pd decahedral seed, generating a nanorod with an asymmetric distribution of Cu, with the Pd seed situated at one of the two ends. According to extinction spectra, the as-obtained Cu nanorods can be stored in water under the ambient conditions for at least six months without noticeable degradation. The resulting stability allows us to systematically investigate the size-dependent surface plasmon resonance properties of the penta-twinned Cu nanorods. With the nanorod transverse modes positioned at 560 nm, the longitudinal modes can be readily tuned from the visible to the near-infrared region by controlling the aspect ratio.
- Authors:
-
- Georgia Inst. of Technology, Atlanta, GA (United States); Emory Univ., Atlanta, GA (United States); Wuhan Univ. (China)
- Georgia Inst. of Technology, Atlanta, GA (United States)
- Condensed Matter Physics and Materials Science Department, Brookhaven National Laboratory, Upton NY 11973 USA
- Wuhan Univ. (China)
- Georgia Inst. of Technology, Atlanta, GA (United States); Emory Univ., Atlanta, GA (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1248811
- Report Number(s):
- BNL-112086-2016-JA
Journal ID: ISSN 1616-301X; R&D Project: MA015MACA; KC0201010
- Grant/Contract Number:
- SC00112704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Functional Materials
- Additional Journal Information:
- Journal Volume: 26; Journal Issue: 8; Journal ID: ISSN 1616-301X
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
Citation Formats
Luo, Ming, Ruditskiy, Aleksey, Peng, Hsin-Chieh, Tao, Jing, Figueroa-Cosme, Legna, He, Zhike, and Xia, Younan. Penta-Twinned Copper Nanorods: Facile Synthesis via Seed-Mediated Growth and Their Tunable Plasmonic Properties. United States: N. p., 2016.
Web. doi:10.1002/adfm.201504217.
Luo, Ming, Ruditskiy, Aleksey, Peng, Hsin-Chieh, Tao, Jing, Figueroa-Cosme, Legna, He, Zhike, & Xia, Younan. Penta-Twinned Copper Nanorods: Facile Synthesis via Seed-Mediated Growth and Their Tunable Plasmonic Properties. United States. https://doi.org/10.1002/adfm.201504217
Luo, Ming, Ruditskiy, Aleksey, Peng, Hsin-Chieh, Tao, Jing, Figueroa-Cosme, Legna, He, Zhike, and Xia, Younan. Thu .
"Penta-Twinned Copper Nanorods: Facile Synthesis via Seed-Mediated Growth and Their Tunable Plasmonic Properties". United States. https://doi.org/10.1002/adfm.201504217. https://www.osti.gov/servlets/purl/1248811.
@article{osti_1248811,
title = {Penta-Twinned Copper Nanorods: Facile Synthesis via Seed-Mediated Growth and Their Tunable Plasmonic Properties},
author = {Luo, Ming and Ruditskiy, Aleksey and Peng, Hsin-Chieh and Tao, Jing and Figueroa-Cosme, Legna and He, Zhike and Xia, Younan},
abstractNote = {When seed-mediated growth is used as a versatile approach to the synthesis of penta-twinned Cu nanorods with uniform diameters and controllable aspect ratios is reported. The success of this approach relies on our recent synthesis of uniform Pd decahedra, with sizes in the range of 6–20 nm. The Pd decahedral seeds can direct the heterogeneous nucleation and growth of Cu along the fivefold axis to produce nanorods with uniform diameters defined by the lateral dimension of the original seeds. Due to a large mismatch in the lattice constants between Cu and Pd (7.1%), the deposited Cu is forced to grow along one side of the Pd decahedral seed, generating a nanorod with an asymmetric distribution of Cu, with the Pd seed situated at one of the two ends. According to extinction spectra, the as-obtained Cu nanorods can be stored in water under the ambient conditions for at least six months without noticeable degradation. The resulting stability allows us to systematically investigate the size-dependent surface plasmon resonance properties of the penta-twinned Cu nanorods. With the nanorod transverse modes positioned at 560 nm, the longitudinal modes can be readily tuned from the visible to the near-infrared region by controlling the aspect ratio.},
doi = {10.1002/adfm.201504217},
journal = {Advanced Functional Materials},
number = 8,
volume = 26,
place = {United States},
year = {Thu Jan 07 00:00:00 EST 2016},
month = {Thu Jan 07 00:00:00 EST 2016}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 88 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Copper Can Still Be Epitaxially Deposited on Palladium Nanocrystals To Generate Core–Shell Nanocubes Despite Their Large Lattice Mismatch
journal, February 2012
- Jin, Mingshang; Zhang, Hui; Wang, Jinguo
- ACS Nano, Vol. 6, Issue 3
The Growth Mechanism of Copper Nanowires and Their Properties in Flexible, Transparent Conducting Films
journal, June 2010
- Rathmell, Aaron R.; Bergin, Stephen M.; Hua, Yi-Lei
- Advanced Materials, Vol. 22, Issue 32
Aqueous Synthesis of Copper Nanocubes and Bimetallic Copper/Palladium Core−Shell Nanostructures
journal, June 2006
- Zhou, Guangjun; Lu, Mengkai; Yang, Zhongsen
- Langmuir, Vol. 22, Issue 13
Kinetically Controlled Overgrowth of Ag or Au on Pd Nanocrystal Seeds: From Hybrid Dimers to Nonconcentric and Concentric Bimetallic Nanocrystals
journal, September 2012
- Zhu, Cun; Zeng, Jie; Tao, Jing
- Journal of the American Chemical Society, Vol. 134, Issue 38
Printed electronics: the challenges involved in printing devices, interconnects, and contacts based on inorganic materials
journal, January 2010
- Perelaer, Jolke; Smith, Patrick J.; Mager, Dario
- Journal of Materials Chemistry, Vol. 20, Issue 39
Facile Synthesis of Ag Nanorods with No Plasmon Resonance Peak in the Visible Region by Using Pd Decahedra of 16 nm in Size as Seeds
journal, September 2015
- Luo, Ming; Huang, Hongwen; Choi, Sang-Il
- ACS Nano, Vol. 9, Issue 10
Polyol Synthesis of Uniform Silver Nanowires: A Plausible Growth Mechanism and the Supporting Evidence
journal, July 2003
- Sun, Yugang; Mayers, Brian; Herricks, Thurston
- Nano Letters, Vol. 3, Issue 7
Shape-Controlled Synthesis of Copper Nanocrystals in an Aqueous Solution with Glucose as a Reducing Agent and Hexadecylamine as a Capping Agent
journal, September 2011
- Jin, Mingshang; He, Guannan; Zhang, Hui
- Angewandte Chemie International Edition, Vol. 50, Issue 45, p. 10560-10564
Synthesis of Organic Monolayer-Stabilized Copper Nanocrystals in Supercritical Water
journal, August 2001
- Ziegler, Kirk J.; Doty, R. Christopher; Johnston, Keith P.
- Journal of the American Chemical Society, Vol. 123, Issue 32
Ag−Au−Ag Heterometallic Nanorods Formed through Directed Anisotropic Growth
journal, March 2008
- Seo, Daeha; Yoo, Choong Il; Jung, Jongwook
- Journal of the American Chemical Society, Vol. 130, Issue 10
Synthesis of Size-Controlled and Shaped Copper Nanoparticles
journal, May 2007
- Mott, Derrick; Galkowski, Jeffrey; Wang, Lingyan
- Langmuir, Vol. 23, Issue 10
Copper Nanowires as Fully Transparent Conductive Electrodes
journal, July 2013
- Guo, Huizhang; Lin, Na; Chen, Yuanzhi
- Scientific Reports, Vol. 3, Issue 1
Tuning Interior Nanogaps of Double-shelled Au/Ag Nanoboxes for Surface-Enhanced Raman Scattering
journal, February 2015
- Zhang, Weiqing; Rahmani, Mohsen; Niu, Wenxin
- Scientific Reports, Vol. 5, Issue 1
Synthesis of Size-Controlled Faceted Pentagonal Silver Nanorods with Tunable Plasmonic Properties and Self-Assembly of These Nanorods
journal, December 2008
- Pietrobon, Brendan; McEachran, Matthew; Kitaev, Vladimir
- ACS Nano, Vol. 3, Issue 1
Use of long chain amine as a reducing agent for the synthesis of high quality monodisperse iron(0) nanoparticles
journal, January 2011
- Meffre, Anca; Lachaize, Sébastien; Gatel, Christophe
- Journal of Materials Chemistry, Vol. 21, Issue 35
Synthesis of well-defined copper nanocubes by a one-pot solution process
journal, November 2006
- Wang, Yihai; Chen, Penglei; Liu, Minghua
- Nanotechnology, Vol. 17, Issue 24
Characterization and Growth Process of Copper Nanodisks
journal, August 2005
- Salzemann, C.; Urban, J.; Lisiecki, I.
- Advanced Functional Materials, Vol. 15, Issue 8
A Novel Method for Preparing Copper Nanorods and Nanowires
journal, February 2003
- Liu, Z.; Bando, Y.
- Advanced Materials, Vol. 15, Issue 4
Chemical Synthesis of Novel Plasmonic Nanoparticles
journal, May 2009
- Lu, Xianmao; Rycenga, Matthew; Skrabalak, Sara E.
- Annual Review of Physical Chemistry, Vol. 60, Issue 1, p. 167-192
Controlled Growth of Ag/Au Bimetallic Nanorods through Kinetics Control
journal, December 2012
- Yang, Yun; Wang, Wenfang; Li, Xingliang
- Chemistry of Materials, Vol. 25, Issue 1
Controlled Synthesis of Nanosized Palladium icosahedra and Their Catalytic Activity towards Formic-Acid Oxidation
journal, September 2013
- Lv, Tian; Wang, Yi; Choi, Sang-Il
- ChemSusChem, Vol. 6, Issue 10
Copper as a Robust and Transparent Electrocatalyst for Water Oxidation
journal, January 2015
- Du, Jialei; Chen, Zuofeng; Ye, Shengrong
- Angewandte Chemie, Vol. 127, Issue 7
Polyol synthesis of Cu2O nanoparticles: use of chloride to promote the formation of a cubic morphology
journal, January 2008
- Kim, Mun Ho; Lim, Byungkwon; Lee, Eric P.
- Journal of Materials Chemistry, Vol. 18, Issue 34
High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts
journal, February 2015
- Roberts, F. Sloan; Kuhl, Kendra P.; Nilsson, Anders
- Angewandte Chemie International Edition, Vol. 54, Issue 17
Five-Fold Twinned Pd Nanorods and Their Use as Templates for the Synthesis of Bimetallic or Hollow Nanostructures
journal, May 2015
- Huang, Hongwen; Zhang, Lei; Lv, Tian
- ChemNanoMat, Vol. 1, Issue 4
Shape-Controlled Synthesis of Colloidal Metal Nanocrystals: Thermodynamic versus Kinetic Products
journal, June 2015
- Xia, Younan; Xia, Xiaohu; Peng, Hsin-Chieh
- Journal of the American Chemical Society, Vol. 137, Issue 25
Lattice-Mismatch-Induced Twinning for Seeded Growth of Anisotropic Nanostructures
journal, February 2015
- Wang, Zhenni; Chen, Zhengzheng; Zhang, Hui
- ACS Nano, Vol. 9, Issue 3
Control of the Shape of Copper Metallic Particles by Using a Colloidal System as Template
journal, February 1997
- Tanori, J.; Pileni, M. P.
- Langmuir, Vol. 13, Issue 4
Shape-Controlled Synthesis of Metal Nanocrystals: Simple Chemistry Meets Complex Physics?
journal, December 2008
- Xia, Younan; Xiong, Yujie; Lim, Byungkwon
- Angewandte Chemie International Edition, Vol. 48, Issue 1, p. 60-103
Controlling the Nucleation and Growth of Silver on Palladium Nanocubes by Manipulating the Reaction Kinetics
journal, November 2011
- Zeng, Jie; Zhu, Cun; Tao, Jing
- Angewandte Chemie International Edition, Vol. 51, Issue 10
Polyol Syntheses of Palladium Decahedra and Icosahedra as Pure Samples by Maneuvering the Reaction Kinetics with Additives
journal, June 2014
- Huang, Hongwen; Wang, Yi; Ruditskiy, Aleksey
- ACS Nano, Vol. 8, Issue 7
On the Mechanism of Low-Temperature Water Gas Shift Reaction on Copper
journal, January 2008
- Gokhale, Amit A.; Dumesic, James A.; Mavrikakis, Manos
- Journal of the American Chemical Society, Vol. 130, Issue 4
Copper as a Robust and Transparent Electrocatalyst for Water Oxidation
journal, January 2015
- Du, Jialei; Chen, Zuofeng; Ye, Shengrong
- Angewandte Chemie International Edition, Vol. 54, Issue 7
Controlled synthesis of palladium icosahedra nanocrystals by reducing H2PdCl4 with tetraethylene glycol
journal, September 2009
- Chen, Yixian; He, Baolin; Huang, Tao
- Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 348, Issue 1-3
Tailoring Longitudinal Surface Plasmon Wavelengths, Scattering and Absorption Cross Sections of Gold Nanorods
journal, March 2008
- Ni, Weihai; Kou, Xiaoshan; Yang, Zhi
- ACS Nano, Vol. 2, Issue 4
Galvanic Replacement-Free Deposition of Au on Ag for Core–Shell Nanocubes with Enhanced Chemical Stability and SERS Activity
journal, May 2014
- Yang, Yin; Liu, Jingyue; Fu, Zheng-Wen
- Journal of the American Chemical Society, Vol. 136, Issue 23
Controlling the Synthesis and Assembly of Silver Nanostructures for Plasmonic Applications
journal, June 2011
- Rycenga, Matthew; Cobley, Claire M.; Zeng, Jie
- Chemical Reviews, Vol. 111, Issue 6
One-Pot Controllable Synthesis of Au@Ag Heterogeneous Nanorods with Highly Tunable Plasmonic Absorption
journal, June 2013
- Li, Cuncheng; Sun, Lin; Sun, Yiqiang
- Chemistry of Materials, Vol. 25, Issue 13
High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts
journal, February 2015
- Roberts, F. Sloan; Kuhl, Kendra P.; Nilsson, Anders
- Angewandte Chemie, Vol. 127, Issue 17
1-Hexadecylamine as both reducing agent and stabilizer to synthesize Au and Ag nanoparticles and their SERS application
journal, May 2010
- Hou, Xiaomiao; Zhang, Xiaoling; Fang, Yan
- Journal of Nanoparticle Research, Vol. 13, Issue 5
Copper Nanocrystal Plane Effect on Stereoselectivity of Catalytic Deoxygenation of Aromatic Epoxides
journal, March 2015
- Xiao, Bin; Niu, Zhiqiang; Wang, Yang-Gang
- Journal of the American Chemical Society, Vol. 137, Issue 11
Solution-processed copper–nickel nanowire anodes for organic solar cells
journal, January 2014
- Stewart, Ian E.; Rathmell, Aaron R.; Yan, Liang
- Nanoscale, Vol. 6, Issue 11
Quasi-Homogeneous Methanol Synthesis Over Highly Active Copper Nanoparticles
journal, December 2005
- Vukojević, Sascha; Trapp, Oliver; Grunwaldt, Jan-Dierk
- Angewandte Chemie International Edition, Vol. 44, Issue 48
Metal Nanowire Networks: The Next Generation of Transparent Conductors
journal, September 2014
- Ye, Shengrong; Rathmell, Aaron R.; Chen, Zuofeng
- Advanced Materials, Vol. 26, Issue 39
Aminoclay: a permselective matrix to stabilize copper nanoparticles
journal, January 2010
- Datta, K. K. R.; Kulkarni, C.; Eswaramoorthy, M.
- Chem. Commun., Vol. 46, Issue 4
Synthesis of Ultrathin Copper Nanowires Using Tris(trimethylsilyl)silane for High-Performance and Low-Haze Transparent Conductors
journal, October 2015
- Cui, Fan; Yu, Yi; Dou, Letian
- Nano Letters, Vol. 15, Issue 11
Cu nanorods and nanospheres and their excellent catalytic activity in chemoselective reduction of nitrobenzenes
journal, March 2010
- Patra, Astam Kumar; Dutta, Arghya; Bhaumik, Asim
- Catalysis Communications, Vol. 11, Issue 7
Mechanism for controlling the shape of Cu nanocrystals prepared by the polyol process
journal, September 2006
- Cha, Seung I.; Mo, Chan B.; Kim, Kyung T.
- Journal of Materials Research, Vol. 21, Issue 09
Solution-processed copper nanowire flexible transparent electrodes with PEDOT:PSS as binder, protector and oxide-layer scavenger for polymer solar cells
journal, October 2014
- Chen, Jianyu; Zhou, Weixin; Chen, Jun
- Nano Research, Vol. 8, Issue 3
Preparation of Cu Nanoclusters within Dendrimer Templates
journal, May 1998
- Zhao, Mingqi; Sun, Li; Crooks, Richard M.
- Journal of the American Chemical Society, Vol. 120, Issue 19
Synthesis of Ultralong Copper Nanowires for High-Performance Transparent Electrodes
journal, August 2012
- Zhang, Dieqing; Wang, Ranran; Wen, Meicheng
- Journal of the American Chemical Society, Vol. 134, Issue 35
A rapid synthesis of high aspect ratio copper nanowires for high-performance transparent conducting films
journal, January 2014
- Ye, Shengrong; Rathmell, Aaron R.; Stewart, Ian E.
- Chemical Communications, Vol. 50, Issue 20, p. 2562-2564
Structural investigations of copper nanorods by high-resolution TEM
journal, February 2000
- Lisiecki, I.; Filankembo, A.; Sack-Kongehl, H.
- Physical Review B, Vol. 61, Issue 7
Quasi-Homogeneous Methanol Synthesis Over Highly Active Copper Nanoparticles
journal, December 2005
- Vukojević, Sascha; Trapp, Oliver; Grunwaldt, Jan-Dierk
- Angewandte Chemie, Vol. 117, Issue 48
Shape-Controlled Synthesis of Copper Nanocrystals in an Aqueous Solution with Glucose as a Reducing Agent and Hexadecylamine as a Capping Agent
journal, September 2011
- Jin, Mingshang; He, Guannan; Zhang, Hui
- Angewandte Chemie, Vol. 123, Issue 45
Controlling the Nucleation and Growth of Silver on Palladium Nanocubes by Manipulating the Reaction Kinetics
journal, November 2011
- Zeng, Jie; Zhu, Cun; Tao, Jing
- Angewandte Chemie, Vol. 124, Issue 10
A Novel Method for Preparing Copper Nanorods and Nanowires.
journal, May 2003
- Liu, Zongwen; Bando, Yoshio
- ChemInform, Vol. 34, Issue 21
Works referencing / citing this record:
Space‐Confined Seeded Growth of Cu Nanorods with Strong Surface Plasmon Resonance for Photothermal Actuation
journal, May 2019
- Chen, Jinxing; Feng, Ji; Yang, Fan
- Angewandte Chemie International Edition, Vol. 58, Issue 27
Copper Template Design for the Synthesis of Bimetallic Copper-Rhodium Nanoshells through Galvanic Replacement
journal, February 2018
- Preston, Arin S.; Hughes, Robert A.; Demille, Trevor B.
- Particle & Particle Systems Characterization, Vol. 35, Issue 5
Functionalized periodic Au@MOFs nanoparticle arrays as biosensors for dual-channel detection through the complementary effect of SPR and diffraction peaks
journal, March 2017
- Hang, Lifeng; Zhou, Fei; Men, Dandan
- Nano Research, Vol. 10, Issue 7
Seed-Mediated Growth of Colloidal Metal Nanocrystals
journal, December 2016
- Xia, Younan; Gilroy, Kyle D.; Peng, Hsin-Chieh
- Angewandte Chemie International Edition, Vol. 56, Issue 1
Facile Synthesis of Cu Nanocrystals with Morphology Evolution from Transitional Truncated Octahedra to Octahedra
journal, December 2019
- Chen, Kuan-Ting; Chang, Wei-Chung; Lu, Shu-Chen
- Journal of Nanomaterials, Vol. 2019
Aqueous synthesis of protectant-free copper nanocubes by a disproportionation reaction of Cu 2 O on synthetic saponite
journal, January 2018
- Miyagawa, Masaya; Usui, Miharu; Imura, Yu
- Chemical Communications, Vol. 54, Issue 61
Facile synthesis and heteroepitaxial growth mechanism of Au@Cu core–shell bimetallic nanocubes probed by first-principles studies
journal, January 2017
- Wang, Changshun; Li, Junlong; Lou, Yeke
- CrystEngComm, Vol. 19, Issue 48
Keimvermitteltes Wachstum kolloidaler Metallnanokristalle
journal, December 2016
- Xia, Younan; Gilroy, Kyle D.; Peng, Hsin-Chieh
- Angewandte Chemie, Vol. 129, Issue 1
Recent progress of solution-processed Cu nanowires transparent electrodes and their applications
journal, January 2019
- Ding, Su; Tian, Yanhong
- RSC Advances, Vol. 9, Issue 46
Nonnoble-Metal-Based Plasmonic Nanomaterials: Recent Advances and Future Perspectives
journal, March 2018
- Kim, Sungi; Kim, Jae-Myoung; Park, Jeong-Eun
- Advanced Materials, Vol. 30, Issue 42
Seesaw-like polarized transmission behavior of silver nanowire arrays aligned by off-center spin-coating
journal, May 2018
- Kang, Lu; Chen, Hui; Yang, Zhong-Jian
- Journal of Applied Physics, Vol. 123, Issue 20
Facile Synthesis of Pd−Cu Bimetallic Twin Nanocubes and a Mechanistic Understanding of the Shape Evolution
journal, January 2020
- Shi, Yifeng; Lyu, Zhiheng; Liu, Jingyue
- ChemNanoMat, Vol. 6, Issue 3
Solvent-free synthesis of monodisperse Cu nanoparticles by thermal decomposition of an oleylamine-coordinated Cu oxalate complex
journal, January 2018
- Togashi, Takanari; Nakayama, Masato; Hashimoto, Atsuki
- Dalton Transactions, Vol. 47, Issue 15
Pentatwinned Cu Nanowires with Ultrathin Diameters below 20 nm and Their Use as Templates for the Synthesis of Au-Based Nanotubes
journal, January 2017
- Luo, Ming; Zhou, Ming; Rosa da Silva, Robson
- ChemNanoMat, Vol. 3, Issue 3
Stirring revealed new functions of ethylenediamine and hydrazine in the morphology control of copper nanowires
journal, January 2019
- Zhang, Juan; Li, Xiaona; Liu, Dongmei
- Nanoscale, Vol. 11, Issue 24
Space‐Confined Seeded Growth of Cu Nanorods with Strong Surface Plasmon Resonance for Photothermal Actuation
journal, May 2019
- Chen, Jinxing; Feng, Ji; Yang, Fan
- Angewandte Chemie, Vol. 131, Issue 27