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This content will become publicly available on November 13, 2016

Title: Electrocatalytic Reduction of Carbon Dioxide with a Well-Defined PN 3 -Ru Pincer Complex

We established a well-defined PN3-Ru pincer complex (5) bearing a redox-active bipyridine ligand with an aminophosphine arm as an effective and stable molecular electrocatalyst for CO2 reduction to CO and HCOOH with negligible formation of H2 in a H2O/MeCN mixture.
Authors:
 [1] ;  [2] ;  [2] ;  [3] ;  [2] ;  [2] ;  [2]
  1. King Abdullah Univ. of Science and Technology, Thuwal (Saudi Arabia); Beifang Univ. of Nationalities, Ningxia (Republic of China)
  2. King Abdullah Univ. of Science and Technology, Thuwal (Saudi Arabia)
  3. Brookhaven National Lab. (BNL), Upton, NY (United States)
Publication Date:
OSTI Identifier:
1248808
Report Number(s):
BNL--112076-2016-JA
Journal ID: ISSN 2192-6506; R&D Project: CO026; KC0304030
Grant/Contract Number:
SC00112704
Type:
Accepted Manuscript
Journal Name:
ChemPlusChem
Additional Journal Information:
Journal Volume: 81; Journal Issue: 2; Journal ID: ISSN 2192-6506
Publisher:
ChemPubSoc Europe
Research Org:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY electrocatalysts; electrochemistry; N,P ligands; redox; ruthenium