Observation of b2 symmetry vibrational levels of the SO2C 1B2 state: Vibrational level staggering, Coriolis interactions, and rotation-vibration constants
Abstract
The $$\tilde{C}$$ 1B2 state of SO2 has a double-minimum potential in the antisymmetric stretch coordinate, such that the minimum energy geometry has nonequivalent SO bond lengths. However, low-lying levels with odd quanta of antisymmetric stretch (b2 vibrational symmetry) have not previously been observed because transitions into these levels from the zero-point level of the $$\tilde{X}$$ state are vibronically forbidden. We use IR-UV double resonance to observe the b2 vibrational levels of the $$\tilde{C}$$ state below 1600 cm-1 of vibrational excitation. This enables a direct characterization of the vibrational level staggering that results from the double-minimum potential. In addition, it allows us to deperturb the strong c-axis Coriolis interactions between levels of a1 and b2 vibrational symmetry and to determine accurately the vibrational dependence of the rotational constants in the distorted $$\tilde{C}$$ electronic state.
- Authors:
-
- Massachusetts Institute of Technology, Cambridge, MA (United States). Dept. of Chemistry
- Publication Date:
- Research Org.:
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1248484
- Alternate Identifier(s):
- OSTI ID: 1247601; OSTI ID: 1733330; OSTI ID: 1831804
- Grant/Contract Number:
- FG02-87ER13671
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Chemical Physics
- Additional Journal Information:
- Journal Volume: 144; Journal Issue: 14; Journal ID: ISSN 0021-9606
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 74 ATOMIC AND MOLECULAR PHYSICS; SO2; sulfur dioxide; pseudo Jahn-Teller; vibronic coupling; Coriolis effects; rotation constants; wave functions; level splitting; ultraviolet light
Citation Formats
Park, G. Barratt, Jiang, Jun, Saladrigas, Catherine A., and Field, Robert W. Observation of b2 symmetry vibrational levels of the SO2C 1B2 state: Vibrational level staggering, Coriolis interactions, and rotation-vibration constants. United States: N. p., 2016.
Web. doi:10.1063/1.4944924.
Park, G. Barratt, Jiang, Jun, Saladrigas, Catherine A., & Field, Robert W. Observation of b2 symmetry vibrational levels of the SO2C 1B2 state: Vibrational level staggering, Coriolis interactions, and rotation-vibration constants. United States. https://doi.org/10.1063/1.4944924
Park, G. Barratt, Jiang, Jun, Saladrigas, Catherine A., and Field, Robert W. Thu .
"Observation of b2 symmetry vibrational levels of the SO2C 1B2 state: Vibrational level staggering, Coriolis interactions, and rotation-vibration constants". United States. https://doi.org/10.1063/1.4944924. https://www.osti.gov/servlets/purl/1248484.
@article{osti_1248484,
title = {Observation of b2 symmetry vibrational levels of the SO2C 1B2 state: Vibrational level staggering, Coriolis interactions, and rotation-vibration constants},
author = {Park, G. Barratt and Jiang, Jun and Saladrigas, Catherine A. and Field, Robert W.},
abstractNote = {The $\tilde{C}$ 1B2 state of SO2 has a double-minimum potential in the antisymmetric stretch coordinate, such that the minimum energy geometry has nonequivalent SO bond lengths. However, low-lying levels with odd quanta of antisymmetric stretch (b2 vibrational symmetry) have not previously been observed because transitions into these levels from the zero-point level of the $\tilde{X}$ state are vibronically forbidden. We use IR-UV double resonance to observe the b2 vibrational levels of the $\tilde{C}$ state below 1600 cm-1 of vibrational excitation. This enables a direct characterization of the vibrational level staggering that results from the double-minimum potential. In addition, it allows us to deperturb the strong c-axis Coriolis interactions between levels of a1 and b2 vibrational symmetry and to determine accurately the vibrational dependence of the rotational constants in the distorted $\tilde{C}$ electronic state.},
doi = {10.1063/1.4944924},
journal = {Journal of Chemical Physics},
number = 14,
volume = 144,
place = {United States},
year = {Thu Apr 14 00:00:00 EDT 2016},
month = {Thu Apr 14 00:00:00 EDT 2016}
}
Web of Science
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