Extraction of Lanthanide and Actinide Ions from Aqueous Mixtures Using a Carboxylic Acid-Functionalized Porous Aromatic Framework
Abstract
Porous aromatic frameworks (PAFs) incorporating a high concentration of acid functional groups possess characteristics that are promising for use in separating lanthanide and actinide metal ions, as required in the treatment of radioactive waste. These materials have been shown to be indefinitely stable to concentrated acids and bases, potentially allowing for multiple adsorption/stripping cycles. Additionally, the PAFs combine exceptional features from MOFs and inorganic/ activated carbons giving rise to tunable pore surfaces and maximum chemical stability. Herein, we present a study of the adsorption of selected metal ions, Sr2+, Fe3+, Nd3+, and Am3+, from aqueous solutions employing a carbon-based porous aromatic framework, BPP-7 (Berkeley Porous Polymer-7). This material displays high metal loading capacities together with excellent adsorption selectivity for neodymium over strontium based on Langmuir adsorption isotherms and ideal adsorbed solution theory (IAST) calculations. Based in part upon X-ray absorption spectroscopy studies, the stronger adsorption of neodymium is attributed to multiple metal ion and binding site interactions resulting from the densely functionalized and highly interpenetrated structure of BPP-7. Finally, recyclability and combustibility experiments demonstrate that multiple adsorption/stripping cycles can be completed with minimal degradation of the polymer adsorption capacity.
- Authors:
-
- Chemistry Department, Lomonosov Moscow State University, Leninskie Gory, Moscow 11991, Russia
- Radiochemistry Department, China Institute of Atomic Energy, Beijing 102413, China
- Actinide Chemistry Group, Energy and Environment Science Division, Quantum Beam Science Center, Japan Atomic Energy Agency, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5148, Japan
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1247030
- Alternate Identifier(s):
- OSTI ID: 1435066
- Grant/Contract Number:
- AC02-05CH11231; SC0001015
- Resource Type:
- Published Article
- Journal Name:
- ACS Central Science
- Additional Journal Information:
- Journal Name: ACS Central Science Journal Volume: 2 Journal Issue: 4; Journal ID: ISSN 2374-7943
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE
Citation Formats
Demir, Selvan, Brune, Nicholas K., Van Humbeck, Jeffrey F., Mason, Jarad A., Plakhova, Tatiana V., Wang, Shuao, Tian, Guoxin, Minasian, Stefan G., Tyliszczak, Tolek, Yaita, Tsuyoshi, Kobayashi, Tohru, Kalmykov, Stepan N., Shiwaku, Hideaki, Shuh, David K., and Long, Jeffrey R. Extraction of Lanthanide and Actinide Ions from Aqueous Mixtures Using a Carboxylic Acid-Functionalized Porous Aromatic Framework. United States: N. p., 2016.
Web. doi:10.1021/acscentsci.6b00066.
Demir, Selvan, Brune, Nicholas K., Van Humbeck, Jeffrey F., Mason, Jarad A., Plakhova, Tatiana V., Wang, Shuao, Tian, Guoxin, Minasian, Stefan G., Tyliszczak, Tolek, Yaita, Tsuyoshi, Kobayashi, Tohru, Kalmykov, Stepan N., Shiwaku, Hideaki, Shuh, David K., & Long, Jeffrey R. Extraction of Lanthanide and Actinide Ions from Aqueous Mixtures Using a Carboxylic Acid-Functionalized Porous Aromatic Framework. United States. https://doi.org/10.1021/acscentsci.6b00066
Demir, Selvan, Brune, Nicholas K., Van Humbeck, Jeffrey F., Mason, Jarad A., Plakhova, Tatiana V., Wang, Shuao, Tian, Guoxin, Minasian, Stefan G., Tyliszczak, Tolek, Yaita, Tsuyoshi, Kobayashi, Tohru, Kalmykov, Stepan N., Shiwaku, Hideaki, Shuh, David K., and Long, Jeffrey R. Tue .
"Extraction of Lanthanide and Actinide Ions from Aqueous Mixtures Using a Carboxylic Acid-Functionalized Porous Aromatic Framework". United States. https://doi.org/10.1021/acscentsci.6b00066.
@article{osti_1247030,
title = {Extraction of Lanthanide and Actinide Ions from Aqueous Mixtures Using a Carboxylic Acid-Functionalized Porous Aromatic Framework},
author = {Demir, Selvan and Brune, Nicholas K. and Van Humbeck, Jeffrey F. and Mason, Jarad A. and Plakhova, Tatiana V. and Wang, Shuao and Tian, Guoxin and Minasian, Stefan G. and Tyliszczak, Tolek and Yaita, Tsuyoshi and Kobayashi, Tohru and Kalmykov, Stepan N. and Shiwaku, Hideaki and Shuh, David K. and Long, Jeffrey R.},
abstractNote = {Porous aromatic frameworks (PAFs) incorporating a high concentration of acid functional groups possess characteristics that are promising for use in separating lanthanide and actinide metal ions, as required in the treatment of radioactive waste. These materials have been shown to be indefinitely stable to concentrated acids and bases, potentially allowing for multiple adsorption/stripping cycles. Additionally, the PAFs combine exceptional features from MOFs and inorganic/ activated carbons giving rise to tunable pore surfaces and maximum chemical stability. Herein, we present a study of the adsorption of selected metal ions, Sr2+, Fe3+, Nd3+, and Am3+, from aqueous solutions employing a carbon-based porous aromatic framework, BPP-7 (Berkeley Porous Polymer-7). This material displays high metal loading capacities together with excellent adsorption selectivity for neodymium over strontium based on Langmuir adsorption isotherms and ideal adsorbed solution theory (IAST) calculations. Based in part upon X-ray absorption spectroscopy studies, the stronger adsorption of neodymium is attributed to multiple metal ion and binding site interactions resulting from the densely functionalized and highly interpenetrated structure of BPP-7. Finally, recyclability and combustibility experiments demonstrate that multiple adsorption/stripping cycles can be completed with minimal degradation of the polymer adsorption capacity.},
doi = {10.1021/acscentsci.6b00066},
journal = {ACS Central Science},
number = 4,
volume = 2,
place = {United States},
year = {Tue Apr 12 00:00:00 EDT 2016},
month = {Tue Apr 12 00:00:00 EDT 2016}
}
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https://doi.org/10.1021/acscentsci.6b00066
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Works referenced in this record:
Comet 81P/Wild 2 Under a Microscope
journal, December 2006
- Brownlee, D.; Tsou, P.; Aleon, J.
- Science, Vol. 314, Issue 5806
Hydrogen Storage in Metal–Organic Frameworks
journal, September 2011
- Suh, Myunghyun Paik; Park, Hye Jeong; Prasad, Thazhe Kootteri
- Chemical Reviews, Vol. 112, Issue 2, p. 782-835
Crystal Structure of a Novel Neodymium Hydroxide Perchlorate Hydrate, Nd2(OH)3(ClO4)3.5H2O.
journal, January 1989
- Csöregh, Ingeborg; Huskowska, Ewa; Ertan, Anne
- Acta Chemica Scandinavica, Vol. 43
Doping Metal–Organic Frameworks for Water Oxidation, Carbon Dioxide Reduction, and Organic Photocatalysis
journal, August 2011
- Wang, Cheng; Xie, Zhigang; deKrafft, Kathryn E.
- Journal of the American Chemical Society, Vol. 133, Issue 34, p. 13445-13454
Thermodynamics of mixed-gas adsorption
journal, January 1965
- Myers, A. L.; Prausnitz, J. M.
- AIChE Journal, Vol. 11, Issue 1, p. 121-127
Impact of Natural Organic Matter on Uranium Transport through Saturated Geologic Materials: From Molecular to Column Scale
journal, May 2012
- Yang, Yu; Saiers, James E.; Xu, Na
- Environmental Science & Technology, Vol. 46, Issue 11
A Comparison of 4 f vs 5 f Metal−Metal Bonds in (CpSiMe 3 ) 3 M−ECp* (M = Nd, U; E = Al, Ga; Cp* = C 5 Me 5 ): Synthesis, Thermodynamics, Magnetism, and Electronic Structure
journal, September 2009
- Minasian, Stefan G.; Krinsky, Jamin L.; Rinehart, Jeffrey D.
- Journal of the American Chemical Society, Vol. 131, Issue 38
Pentavalent and Tetravalent Uranium Selenides, Tl 3 Cu 4 USe 6 and Tl 2 Ag 2 USe 4 : Syntheses, Characterization, and Structural Comparison to Other Layered Actinide Chalcogenide Compounds
journal, July 2011
- Bugaris, Daniel E.; Choi, Eun Sang; Copping, Roy
- Inorganic Chemistry, Vol. 50, Issue 14
Radioactive waste partitioning and transmutation within advanced fuel cycles: Achievements and challenges
journal, January 2011
- Salvatores, M.; Palmiotti, G.
- Progress in Particle and Nuclear Physics, Vol. 66, Issue 1
Solid-phase extraction technology for actinide and lanthanide separations in nuclear fuel reprocessing
book, January 2011
- Tranter, T. J.
- Advanced Separation Techniques for Nuclear Fuel Reprocessing and Radioactive Waste Treatment
Diniobium Inverted Sandwich Complexes with μ-η 6 :η 6 -Arene Ligands: Synthesis, Kinetics of Formation, and Electronic Structure
journal, February 2013
- Gianetti, Thomas L.; Nocton, Grégory; Minasian, Stefan G.
- Journal of the American Chemical Society, Vol. 135, Issue 8
Impact limits of partitioning and transmutation scenarios on the radiotoxicity of actinides in radioactive waste
journal, October 2003
- Magill, J.; Berthou, V.; Haas, D.
- Nuclear Energy, Vol. 42, Issue 5
Highly polydentate ligands. Part 4. Crystal structures of neodymium( III ) and erbium( III ) complexes of 3,12-bis(carboxymethyl)-6,9-dioxa-3,12-diazatetradecanedioate(4–)
journal, January 1989
- Schauer, Cynthia K.; Anderson, Oren P.
- J. Chem. Soc., Dalton Trans., Issue 1
Hydrothermal synthesis and crystal structure study of two novel 3-D mellitates {Nd2[C6(COO)6] (H2O)6} and {Ho2[C6(COO)6](H2O)6}
journal, December 2008
- Tang, Xiaoyong; Yue, Shantang; Li, Ping
- Journal of Rare Earths, Vol. 26, Issue 6
Complexation and Extraction of Trivalent Actinides and Lanthanides by Triazinylpyridine N -Donor Ligands
journal, October 2012
- Panak, Petra J.; Geist, Andreas
- Chemical Reviews, Vol. 113, Issue 2
Quantitative Mapping of Structured Polymeric Systems Using Singular Value Decomposition Analysis of Soft X-ray Images
journal, May 2002
- Koprinarov, I. N.; Hitchcock, A. P.; McCrory, C. T.
- The Journal of Physical Chemistry B, Vol. 106, Issue 21
The Truex Process and the Management of Liquid Tru Uwaste
journal, October 1988
- Schulz, W. W.; Horwitz, E. P.
- Separation Science and Technology, Vol. 23, Issue 12-13
Speciation and Quantitative Mapping of Metal Species in Microbial Biofilms Using Scanning Transmission X-ray Microscopy
journal, March 2006
- Dynes, James J.; Tyliszczak, Tolek; Araki, Tohru
- Environmental Science & Technology, Vol. 40, Issue 5
Using molecular simulations for screening of zeolites for separation of CO2/CH4 mixtures
journal, September 2007
- Krishna, R.; van Baten, J. M.
- Chemical Engineering Journal, Vol. 133, Issue 1-3
Covalency in Metal–Oxygen Multiple Bonds Evaluated Using Oxygen K-edge Spectroscopy and Electronic Structure Theory
journal, January 2013
- Minasian, Stefan G.; Keith, Jason M.; Batista, Enrique R.
- Journal of the American Chemical Society, Vol. 135, Issue 5
Comparison of Extraction Behavior of Neptunium from Nitric Acid Medium Employing Tri- n -Butyl Phosphate and N,N -dihexyl Octanamide as Extractants
journal, June 2012
- Kumari, Neelam; Pathak, P. N.; Prabhu, D. R.
- Separation Science and Technology, Vol. 47, Issue 10
Characterization of Ca-phosphate biological materials by scanning transmission X-ray microscopy (STXM) at the Ca L2,3-, P L2,3- and C K-edges
journal, January 2015
- Cosmidis, Julie; Benzerara, Karim; Nassif, Nadine
- Acta Biomaterialia, Vol. 12
NEXAFS spectromicroscopy of polymers: overview and quantitative analysis of polyurethane polymers
journal, October 1999
- Urquhart, Stephen G.; Hitchcock, Adam P.; Smith, Archie P.
- Journal of Electron Spectroscopy and Related Phenomena, Vol. 100, Issue 1-3
Highly porous and stable metal–organic frameworks for uranium extraction
journal, January 2013
- Carboni, Michaël; Abney, Carter W.; Liu, Shubin
- Chemical Science, Vol. 4, Issue 6, p. 2396-2402
Scanning Transmission X-Ray, Laser Scanning, and Transmission Electron Microscopy Mapping of the Exopolymeric Matrix of Microbial Biofilms
journal, September 2003
- Lawrence, J. R.; Swerhone, G. D. W.; Leppard, G. G.
- Applied and Environmental Microbiology, Vol. 69, Issue 9
La 2 U 2 Se 9 : An Ordered Lanthanide/Actinide Chalcogenide with a Novel Structure Type
journal, March 2010
- Bugaris, Daniel E.; Copping, Roy; Tyliszczak, Tolek
- Inorganic Chemistry, Vol. 49, Issue 5
Transmission and emission x-ray microscopy: operation modes, contrast mechanisms and applications
journal, February 2011
- Kaulich, Burkhard; Thibault, Pierre; Gianoncelli, Alessandra
- Journal of Physics: Condensed Matter, Vol. 23, Issue 8
The thermal decomposition of neodymium nitrate
journal, August 1986
- Van Vuuren, C. P. J.; Strydom, C. A.
- Thermochimica Acta, Vol. 104
Quantitative organic and light-element analysis of comet 81P/Wild 2 particles using C-, N-, and O-μ-XANES
journal, February 2008
- Cody, George D.; Ade, Harald; Alexander, M. O'D.
- Meteoritics & Planetary Science, Vol. 43, Issue 1-2
Chemical composition mapping with nanometre resolution by soft X-ray microscopy
journal, September 2014
- Shapiro, David A.; Yu, Young-Sang; Tyliszczak, Tolek
- Nature Photonics, Vol. 8, Issue 10
Ammonia Capture in Porous Organic Polymers Densely Functionalized with Brønsted Acid Groups
journal, January 2014
- Van Humbeck, Jeffrey F.; McDonald, Thomas M.; Jing, Xiaofei
- Journal of the American Chemical Society, Vol. 136, Issue 6, p. 2432-2440
Nuclear Energy: A Perspective on Recent Results on the Removal of Strontium from Waste
journal, April 2011
- Centi, Gabriele; Joester, Derk
- ChemSusChem, Vol. 4, Issue 4
THE NOVEL EXTRACTANTS, DIGLYCOLAMIDES, FOR THE EXTRACTION OF LANTHANIDES AND ACTINIDES IN HNO 3 – n -DODECANE SYSTEM
journal, January 2001
- Sasaki, Yuji; Sugo, Yumi; Suzuki, Shinichi
- Solvent Extraction and Ion Exchange, Vol. 19, Issue 1
Deconstructing the Crystal Structures of Metal–Organic Frameworks and Related Materials into Their Underlying Nets
journal, September 2011
- O’Keeffe, Michael; Yaghi, Omar M.
- Chemical Reviews, Vol. 112, Issue 2, p. 675-702
Mesoporous materials in the field of nuclear industry: applications and perspectives
journal, January 2012
- Makowski, Philippe; Deschanels, Xavier; Grandjean, Agnès
- New J. Chem., Vol. 36, Issue 3
Enrichment and Encapsulation of Uranium with Iron Nanoparticle
journal, February 2015
- Ling, Lan; Zhang, Wei-xian
- Journal of the American Chemical Society, Vol. 137, Issue 8
Do the lanthanides form inner sphere complexes with ClO4− ions in competition with H2O molecules?
journal, March 1992
- Huskowska, E.; Legendziewicz, J.; Schleid, Th.
- Materials Chemistry and Physics, Vol. 31, Issue 1-2
Review and Analysis of Molecular Simulations of Methane, Hydrogen, and Acetylene Storage in Metal–Organic Frameworks
journal, September 2011
- Getman, Rachel B.; Bae, Youn-Sang; Wilmer, Christopher E.
- Chemical Reviews, Vol. 112, Issue 2, p. 703-723
Structural study of lanthanides(III) in aqueous nitrate and chloride solutions by EXAFS
journal, February 1999
- Yaita, T.; Narita, H.; Suzuki, Sh.
- Journal of Radioanalytical and Nuclear Chemistry, Vol. 239, Issue 2
Commensurate Adsorption of Hydrocarbons and Alcohols in Microporous Metal Organic Frameworks
journal, September 2011
- Wu, Haohan; Gong, Qihan; Olson, David H.
- Chemical Reviews, Vol. 112, Issue 2
Cryogenically Cooled Monochromator with Multi-crystal Switching System on BL11XU at SPring-8
conference, January 2004
- Shiwaku, Hideaki
- SYNCHROTRON RADIATION INSTRUMENTATION: Eighth International Conference on Synchrotron Radiation Instrumentation, AIP Conference Proceedings
Targeted Synthesis of a Porous Aromatic Framework with High Stability and Exceptionally High Surface Area
journal, November 2009
- Ben, Teng; Ren, Hao; Ma, Shengqian
- Angewandte Chemie International Edition, Vol. 48, Issue 50, p. 9457-9460
Americium(III) Capture Using Phosphonic Acid-Functionalized Silicas with Different Mesoporous Morphologies: Adsorption Behavior Study and Mechanism Investigation by EXAFS/XPS
journal, May 2014
- Zhang, Wen; He, Xihong; Ye, Gang
- Environmental Science & Technology, Vol. 48, Issue 12
Extraction of Actinides(Iii), (Iv), (v), (Vi), and Lanthanides(Iii) by Structurally Tailored Diamides
journal, February 2002
- Sasaki, Yuji; Tachimori, Shoichi
- Solvent Extraction and Ion Exchange, Vol. 20, Issue 1
Detailed Tabulation of Atomic Form Factors, Photoelectric Absorption and Scattering Cross Section, and Mass Attenuation Coefficients in the Vicinity of Absorption Edges in the Soft X-Ray (Z=30–36, Z=60–89, E=0.1 keV–10 keV), Addressing Convergence Issues of Earlier Work
journal, July 2000
- Chantler, C. T.
- Journal of Physical and Chemical Reference Data, Vol. 29, Issue 4
Carbon Dioxide Capture in Metal–Organic Frameworks
journal, September 2011
- Sumida, Kenji; Rogow, David L.; Mason, Jarad A.
- Chemical Reviews, Vol. 112, Issue 2, p. 724-781
Theory of solid-state contributions to the x-ray elastic scattering amplitude
journal, July 2000
- Ankudinov, A. L.; Rehr, J. J.
- Physical Review B, Vol. 62, Issue 4
Modeling the Radiolytic Corrosion of Fractured Nuclear Fuel under Permanent Disposal Conditions
journal, January 2014
- Wu, Linda; Liu, Nazhen; Qin, Zack
- Journal of The Electrochemical Society, Vol. 161, Issue 8
Resistant behavior of a novel silica-based octyl(phenyl)-N,N-diisobutyl carbamoylmethylphoshine oxide neutral extraction resin against nitric acid, temperature and γ-radiation
journal, March 2005
- Zhang, Anyun; Wei, Yuezhou; Kumagai, Mikio
- Radiation Physics and Chemistry, Vol. 72, Issue 4
Evaluating metal–organic frameworks for post-combustion carbon dioxide capture via temperature swing adsorption
journal, January 2011
- Mason, Jarad A.; Sumida, Kenji; Herm, Zoey R.
- Energy & Environmental Science, Vol. 4, Issue 8, p. 3030-3040
Crystal Structure and Absorption Spectroscopy of a Neodymium(III) Complex with Triethylenetetraaminehexaacetic Acid, Na 3 [Nd(TTHA)]·2.5NaClO 4 ·7.617H 2 O
journal, March 1997
- Mondry, Anna; Starynowicz, Przemysław
- Inorganic Chemistry, Vol. 36, Issue 6
Carbon K-Edge X-ray Absorption Spectroscopy and Time-Dependent Density Functional Theory Examination of Metal–Carbon Bonding in Metallocene Dichlorides
journal, September 2013
- Minasian, Stefan G.; Keith, Jason M.; Batista, Enrique R.
- Journal of the American Chemical Society, Vol. 135, Issue 39
Entropy effects during sorption of alkanes in zeolites
journal, April 2002
- Krishna, Rajamani; Smit, Berend; Calero, Sofia
- Chemical Society Reviews, Vol. 31, Issue 3
Prediction of binary adsorption isotherms of Cu2+, Cd2+ and Pb2+ on calcium alginate beads from single adsorption data
journal, March 2009
- Papageorgiou, S. K.; Katsaros, F. K.; Kouvelos, E. P.
- Journal of Hazardous Materials, Vol. 162, Issue 2-3
Synthesis and characterization of thorium, uranium and cerium oxide nanoparticles
journal, March 2013
- Batuk, Olga N.; Szabó, D. Vinga; Denecke, Melissa A.
- Radiochimica Acta, Vol. 101, Issue 4
Metal–Organic Frameworks for Separations
journal, September 2011
- Li, Jian-Rong; Sculley, Julian; Zhou, Hong-Cai
- Chemical Reviews, Vol. 112, Issue 2, p. 869-932
Computer simulations for the adsorption and separation of CO2/CH4/H2/N2 gases by UMCM-1 and UMCM-2 metal organic frameworks
journal, January 2011
- Peng, Xuan; Cheng, Xuan; Cao, Dapeng
- Journal of Materials Chemistry, Vol. 21, Issue 30
Gas detection by structural variations of fluorescent guest molecules in a flexible porous coordination polymer
journal, September 2011
- Yanai, Nobuhiro; Kitayama, Koji; Hijikata, Yuh
- Nature Materials, Vol. 10, Issue 10, p. 787-793
Resistance properties of a macroporous silica-based N,N,N′,N′-tetraoctyl-3-oxapentane-1,5-diamide-impregnated polymeric adsorption material against nitric acid, temperature and γ-irradiation
journal, April 2005
- Zhang, Anyun; Wei, Yuezhou; Hoshi, Harutaka
- Radiation Physics and Chemistry, Vol. 72, Issue 6
Sulfonate-Grafted Porous Polymer Networks for Preferential CO2 Adsorption at Low Pressure
journal, November 2011
- Lu, Weigang; Yuan, Daqiang; Sculley, Julian
- Journal of the American Chemical Society, Vol. 133, Issue 45, p. 18126-18129
Soft X-ray microscopy and spectroscopy at the molecular environmental science beamline at the Advanced Light Source
journal, February 2006
- Bluhm, H.; Andersson, K.; Araki, T.
- Journal of Electron Spectroscopy and Related Phenomena, Vol. 150, Issue 2-3
Multielemental Elution Behavior of Metal Ions Adsorbed on Iminodiacetic Acid Chelating Resin by Using Hydrogen Peroxide as an Eluent
journal, January 2012
- Yabutani, Tomoki; Sumi, Hidehiko; Nakamura, Takamasa
- Analytical Sciences, Vol. 28, Issue 5
THE TRUEX PROCESS - A PROCESS FOR THE EXTRACTION OF THE TKANSURANIC ELEMENTS EROM NITRIC AC In WASTES UTILIZING MODIFIED PUREX SOLVENT*
journal, February 1985
- Philip Horwitz, E.; Kalina, Dale C.; Diamond, Herbert
- Solvent Extraction and Ion Exchange, Vol. 3, Issue 1-2
Ab initio calculation of the crystal structure of the lanthanide Ln2O3 sesquioxides
journal, March 2003
- Hirosaki, Naoto; Ogata, Shigenobu; Kocer, Cenk
- Journal of Alloys and Compounds, Vol. 351, Issue 1-2
Polyamine-Tethered Porous Polymer Networks for Carbon Dioxide Capture from Flue Gas
journal, June 2012
- Lu, Weigang; Sculley, Julian P.; Yuan, Daqiang
- Angewandte Chemie International Edition, Vol. 51, Issue 30, p. 7480-7484
WinXAS a Program for X-ray Absorption Spectroscopy Data Analysis under MS-Windows
journal, March 1998
- Ressler, T.
- Journal of Synchrotron Radiation, Vol. 5, Issue 2, p. 118-122