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Title: Structure and adsorption properties of a porous cooper hexacyanoferrate polymorph

Abstract

The key questions addressed here were: the structure elucidation and the investigation of the adsorption space and framework expansion effect of a Cu(II) hexacyanoferrate (III) polymorph (labeled Cu-PBA-I). The structural analysis was performed with a broad set of characterization methods. In addition, a low and high pressure carbon dioxide adsorption investigation was performed, assuming, to comprehend the adsorption experiments, that the adsorbent plus the adsorbed phase were a solid solution. The Cu-PBA-I presented the following composition, K1/4 Cu (II) [Fe (III)(CN)6]3/4 ∙ 1/4 nH2O, exhibited an antiferromagnetic behavior and displayed a thermally stable I4 2 m space group lattice in the degassed state. Furthermore, the low pressure adsorption study allowed the calculation of the micropore volume, W¼0.09 cm3 /g and the isosteric heat of adsorption, qiso=19 kJ/mol; further, the high pressure adsorption data revealed an extremely high adsorption capacity owing to a framework expansion effect. Finally, the DRIFTS spectrum of adsorbed CO2 displayed peaks corresponding to carbon dioxide physically adsorbed and interacting with electron accepting Lewis acid sites. Hence, was produced an excellent adsorbent which combine porosity and anti-ferromagnetism, antagonist properties rarely found together.

Authors:
 [1];  [1];  [1];  [1];  [1]
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  1. University of Turabo, Gurabo (Puerto Rico); University of Puerto Rico-Mayaguez (United States)
Publication Date:
Research Org.:
University of Turabo, Gurabo (Puerto Rico)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1336313
Alternate Identifier(s):
OSTI ID: 1246689
Grant/Contract Number:  
NA0000672
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Physics and Chemistry of Solids
Additional Journal Information:
Journal Volume: 86; Journal Issue: C; Journal ID: ISSN 0022-3697
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; carbon dioxide; adsorption; Prussian blue analog; antiferromagnetism; gas storage

Citation Formats

Roque-Malherbe, R., Carballo, E., Polanco, R., Lugo, F., and Lozano, C. Structure and adsorption properties of a porous cooper hexacyanoferrate polymorph. United States: N. p., 2015. Web. doi:10.1016/j.jpcs.2015.04.009.
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Roque-Malherbe, R., Carballo, E., Polanco, R., Lugo, F., & Lozano, C. Structure and adsorption properties of a porous cooper hexacyanoferrate polymorph. United States. https://doi.org/10.1016/j.jpcs.2015.04.009
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Roque-Malherbe, R., Carballo, E., Polanco, R., Lugo, F., and Lozano, C. Thu . "Structure and adsorption properties of a porous cooper hexacyanoferrate polymorph". United States. https://doi.org/10.1016/j.jpcs.2015.04.009. https://www.osti.gov/servlets/purl/1336313.
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@article{osti_1336313,
title = {Structure and adsorption properties of a porous cooper hexacyanoferrate polymorph},
author = {Roque-Malherbe, R. and Carballo, E. and Polanco, R. and Lugo, F. and Lozano, C.},
abstractNote = {The key questions addressed here were: the structure elucidation and the investigation of the adsorption space and framework expansion effect of a Cu(II) hexacyanoferrate (III) polymorph (labeled Cu-PBA-I). The structural analysis was performed with a broad set of characterization methods. In addition, a low and high pressure carbon dioxide adsorption investigation was performed, assuming, to comprehend the adsorption experiments, that the adsorbent plus the adsorbed phase were a solid solution. The Cu-PBA-I presented the following composition, K1/4 Cu (II) [Fe (III)(CN)6]3/4 ∙ 1/4 nH2O, exhibited an antiferromagnetic behavior and displayed a thermally stable I4 2 m space group lattice in the degassed state. Furthermore, the low pressure adsorption study allowed the calculation of the micropore volume, W¼0.09 cm3 /g and the isosteric heat of adsorption, qiso=19 kJ/mol; further, the high pressure adsorption data revealed an extremely high adsorption capacity owing to a framework expansion effect. Finally, the DRIFTS spectrum of adsorbed CO2 displayed peaks corresponding to carbon dioxide physically adsorbed and interacting with electron accepting Lewis acid sites. Hence, was produced an excellent adsorbent which combine porosity and anti-ferromagnetism, antagonist properties rarely found together.},
doi = {10.1016/j.jpcs.2015.04.009},
journal = {Journal of Physics and Chemistry of Solids},
number = C,
volume = 86,
place = {United States},
year = {Thu May 14 00:00:00 EDT 2015},
month = {Thu May 14 00:00:00 EDT 2015}
}
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https://doi.org/10.1016/j.jpcs.2015.04.009
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