Improved syntheses of β-octabromo-meso-triarylcorrole derivatives

Capar, Jan; Berg, Steffen; Thomas, Kolle E.; Beavers, Christine M.; Gagnon, Kevin J.; Ghosh, Abhik

doi:10.1016/j.jinorgbio.2015.07.017

Title: Improved syntheses of β-octabromo-meso-triarylcorrole derivatives

Full Record
Other Related Research

Authors:: Capar, Jan; Berg, Steffen; Thomas, Kolle E.; Beavers, Christine M.; Gagnon, Kevin J.; Ghosh, Abhik

Publication Date:: Tue Dec 01 00:00:00 EST 2015

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1246569

Grant/Contract Number:: AC02-05CH11231

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Journal of Inorganic Biochemistry

Additional Journal Information:: Journal Name: Journal of Inorganic Biochemistry Journal Volume: 153 Journal Issue: C; Journal ID: ISSN 0162-0134

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Citation Formats


                    Capar, Jan, Berg, Steffen, Thomas, Kolle E., Beavers, Christine M., Gagnon, Kevin J., and Ghosh, Abhik. Improved syntheses of β-octabromo-meso-triarylcorrole derivatives.  United States: N. p., 2015. 
Web.  doi:10.1016/j.jinorgbio.2015.07.017.

Copy to clipboard


                    Capar, Jan, Berg, Steffen, Thomas, Kolle E., Beavers, Christine M., Gagnon, Kevin J., & Ghosh, Abhik. Improved syntheses of β-octabromo-meso-triarylcorrole derivatives.  United States.  https://doi.org/10.1016/j.jinorgbio.2015.07.017

Copy to clipboard


                    Capar, Jan, Berg, Steffen, Thomas, Kolle E., Beavers, Christine M., Gagnon, Kevin J., and Ghosh, Abhik. Tue .  
"Improved syntheses of β-octabromo-meso-triarylcorrole derivatives".  United States.  https://doi.org/10.1016/j.jinorgbio.2015.07.017.

Copy to clipboard


                    
@article{osti_1246569,

  title        = {Improved syntheses of β-octabromo-meso-triarylcorrole derivatives},

  author       = {Capar, Jan and Berg, Steffen and Thomas, Kolle E. and Beavers, Christine M. and Gagnon, Kevin J. and Ghosh, Abhik},

  abstractNote = {},

  doi          = {10.1016/j.jinorgbio.2015.07.017},

  journal      = {Journal of Inorganic Biochemistry},

  number       = C,

  volume       = 153,

  place        = {United States},

  year         = {Tue Dec 01 00:00:00 EST 2015},

  month        = {Tue Dec 01 00:00:00 EST 2015}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
https://doi.org/10.1016/j.jinorgbio.2015.07.017

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 9 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Similar Records in DOE PAGES and OSTI.GOV collections:

β-Octabromo- and β-Octakis(trifluoromethyl)isocorroles: New Sterically Constrained Macrocyclic Ligands

Journal Article Thomas, Kolle E. ; Beavers, Christine M. ; Gagnon, Kevin J. ; ... - ChemistryOpen

Here, we present a study of the acid-induced demetalation of two sterically hindered copper corroles, Cu β-octabromo-meso-triphenylcorrole (Cu[Br₈TPC]) and β-octakis(trifluoromethyl)-meso-tris(p-methoxyphenyl)corrole (Cu[(CF₃)₈TpOMePC]). Unlike reductive demetalation, which affords the free-base β-octabromocorrole, demetalation of Cu[Br₈TPC] under non- reductive conditions (CHCl₃/H₂SO₄) resulted in moderate yields of free-base 5- and 10-hydroxy isocorroles. The isomeric free bases could be complexed to Co^II and Ni^II, affording stable complexes. Only reductive demetalation was found to work for Cu[(CF₃)₈TpOMePC], affording a highly saddled, hydrated corrole, H₃[5-OH,10-H-(CF₃)₈TpOMePC], where the elements of water had added across C5 and C10. Interaction of this novel free base with Co^II resulted in Co[iso-10-H-[CF₃)₈TpOMePC], amore »« less
Cited by 9
https://doi.org/10.1002/open.201700035

Full Text Available
Racemic-meso interconversion for ansa-scandocene and ansa-yttrocene derivatives. Molecular structures of rac-{l_brace}Me{sub 2}Si[{eta}{sup 5}-C{sub 5}H{sub 2}-2,4-(CHMe{sub 2}){sub 2}]{sub 2}{r_brace}ScCl {center_dot} LiCl(THF){sub 2}, [meso-{l_brace}Me{sub 2}Si[{eta}{sup 5}-C{sub 5}H{sub 2}-2,4-(CHMe{sub 2}){sub 2}]{sub 2}{r_brace} Y({mu}{sub 2}-Cl)]{sub 2}, and meso-{l_brace}Me{sub 2}Si[{eta}{sup 5}-C{sub 5}H{sub 2}-2,4-(CHMe{sub 2}){sub 2}]{sub 2}{r_brace}Zr(NMe{sub 2}){sub 2}

Journal Article Yoder, J C ; Day, M W ; Bercaw, J E - Organometallics

The dilithium bis(cyclopentadienide) species Li{sub 2}{l_brace}Me{sub 2}Si[C{sub 5}H{sub 2}-2,4-(CHMe{sub 2}){sub 2}]{sub 2}{r_brace} (Li{sub 2}Ip) reacts with ScCl{sub 3}(THF){sub 3} to afford rac-IpScCl{center_dot}LiCl(THF){sub 2} (1) and [meso-IpSc({mu}{sub 2}-Cl)]{sub 2} (2) and with YCl{sub 3}(THF){sub 3.5} to afford rac-IpYCl{center_dot}LiCl(THF){sub 2} (3) and [meso-IpY({mu}{sub 2}-Cl)]{sub 2} (4). Metalation with both scandium and yttrium chlorides yields the metallocene chlorides in approximately 3:1 racemic:meso ratios. Reaction of IpH{sub 2} with Zr(NMe{sub 2}){sub 4} yields exclusively meso-IpZr(NMe{sub 2}){sub 2} (9). Treatment of 1 or 2 with allylmagnesium bromide affords the allyl complexes rac-IpSc-({eta}{sup 3}-c{sub 3}H{sub 5}) (5) and meso-IpSc({eta}{sup 3}-C{sub 3}H{sub 5}) (6) and with crotylmagnesiummore »« less
https://doi.org/10.1021/om980349j
Meso-porous α-Fe{sub 2}O{sub 3} thin films synthesized via the sol-gel process for light-driven water oxidation

Journal Article Hamd, Wael ; Laberty-Robert, Christel ; Sanchez, Clement ; ... - Physical Chemistry Chemical Physics. PCCP (Print)

This work reports a facile and cost-effective method for synthesizing photoactive α-Fe{sub 2}O{sub 3} films as well as their performances when used as photoanodes for water oxidation. Transparent α-Fe{sub 2}O{sub 3} meso-porous films were fabricated by template-directed sol-gel chemistry coupled with the dip-coating approach, followed by annealing at various temperatures from 350 degrees C to 750 degrees C in air. α-Fe{sub 2}O{sub 3} films were characterized by X-ray diffraction, XPS, FE-SEM and electrochemical measurements. The photoelectrochemical performance of α-Fe{sub 2}O{sub 3} photoanodes was characterized and optimized through the deposition of Co-based co-catalysts via different methods (impregnation, electro-deposition and photo-electro-deposition). Interestingly,more »« less
https://doi.org/10.1039/C2CP42535A
Facilely synthesized meso-macroporous polymer as support of poly(ethyleneimine) for highly efficient and selective capture of CO 2

Journal Article Liu, Fujian ; Huang, Kuan ; Yoo, Chun-Jae ; ... - Chemical Engineering Journal
https://doi.org/10.1016/j.cej.2016.12.004
Facilely synthesized meso-macroporous polymer as support of poly(ethyleneimine) for highly efficient and selective capture of CO2

Journal Article Liu, Fujian ; Huang, Kuan ; Yoo, Chun-Jae ; ... - Chemical Engineering Journal
Cited by 72
https://doi.org/10.1016/j.cej.2016.12.004

Similar Records