An in situ AFM Study of the Evolution of Surface Roughness for Zinc Electrodeposition within an Imidazolium Based Ionic Liquid Electrolyte

Keist, Jayme S.; Orme, Christine A.; Wright, Paul K.; Evans, James W.

doi:10.1016/j.electacta.2014.11.091

Title: An in situ AFM Study of the Evolution of Surface Roughness for Zinc Electrodeposition within an Imidazolium Based Ionic Liquid Electrolyte

Full Record
Other Related Research

Authors:: Keist, Jayme S.; Orme, Christine A.; Wright, Paul K.; Evans, James W.

Publication Date:: Thu Jan 01 00:00:00 EST 2015

Sponsoring Org.:: USDOE

OSTI Identifier:: 1246508

Grant/Contract Number:: 12-LW-030; AC52-07NA27344

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Electrochimica Acta

Additional Journal Information:: Journal Name: Electrochimica Acta Journal Volume: 152 Journal Issue: C; Journal ID: ISSN 0013-4686

Publisher:: Elsevier

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Keist, Jayme S., Orme, Christine A., Wright, Paul K., and Evans, James W. An in situ AFM Study of the Evolution of Surface Roughness for Zinc Electrodeposition within an Imidazolium Based Ionic Liquid Electrolyte.  United Kingdom: N. p., 2015. 
Web.  doi:10.1016/j.electacta.2014.11.091.

Copy to clipboard


                    Keist, Jayme S., Orme, Christine A., Wright, Paul K., & Evans, James W. An in situ AFM Study of the Evolution of Surface Roughness for Zinc Electrodeposition within an Imidazolium Based Ionic Liquid Electrolyte.  United Kingdom.  https://doi.org/10.1016/j.electacta.2014.11.091

Copy to clipboard


                    Keist, Jayme S., Orme, Christine A., Wright, Paul K., and Evans, James W. Thu .  
"An in situ AFM Study of the Evolution of Surface Roughness for Zinc Electrodeposition within an Imidazolium Based Ionic Liquid Electrolyte".  United Kingdom.  https://doi.org/10.1016/j.electacta.2014.11.091.

Copy to clipboard


                    
@article{osti_1246508,

  title        = {An in situ AFM Study of the Evolution of Surface Roughness for Zinc Electrodeposition within an Imidazolium Based Ionic Liquid Electrolyte},

  author       = {Keist, Jayme S. and Orme, Christine A. and Wright, Paul K. and Evans, James W.},

  abstractNote = {},

  doi          = {10.1016/j.electacta.2014.11.091},

  journal      = {Electrochimica Acta},

  number       = C,

  volume       = 152,

  place        = {United Kingdom},

  year         = {Thu Jan 01 00:00:00 EST 2015},

  month        = {Thu Jan 01 00:00:00 EST 2015}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
https://doi.org/10.1016/j.electacta.2014.11.091

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 24 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Similar Records in DOE PAGES and OSTI.GOV collections:

Coupling in situ

Journal Article Keist, Jayme S. ; Hammons, Joshua A. ; Wright, Paul K. ; ... - Electrochimica Acta

Zinc (Zn) is a low-cost material that is widely used in plating and is under consideration as a reversible deposit for a range of energy storage applications. In recent years, researchers have demonstrated that the Zn morphology can be tuned by electrodepositing from an ionic liquid often leading to morphologies that improve cyclability. However, the underlying mechanisms that control deposition and morphology are not well understood. In this work, we evaluate the evolution of zinc morphology as a function of the deposition thickness using in situ atomic force microscopy (AFM), in situ ultra-small angle X-ray scattering (USAXS) and ex situmore »« less
Cited by 6
https://doi.org/10.1016/j.electacta.2020.136073

Full Text Available
Coupling in situ atomic force microscopy (AFM) and ultra-small-angle X-ray scattering (USAXS) to study the evolution of zinc morphology during electrodeposition within an imidazolium based ionic liquid electrolyte

Journal Article Keist, Jayme S. ; Hammons, Joshua A. ; Wright, Paul K. ; ... - Electrochimica Acta
https://doi.org/10.1016/j.electacta.2020.136073
Dendrite-free Al recycling via electrodeposition using ionic liquid electrolytes: The effects of deposition temperature and cathode surface roughness

Journal Article Wang, Yifan ; Reddy, Ramana G. ; Wang, Ruigang - Journal of Cleaner Production

In this report, the electrodeposition of Al from aluminum scrap alloys (A2020) on copper cathode substrates with varied surface roughness under different deposition temperatures was studied using low-temperature AlCl₃-1-butyl-3-methyl-imidazolium chloride (BMIC) ionic liquid electrolytes. The bulk electrodeposition of Al was carried out under a voltage of 1.5 V at a stirring rate of 120 rpm using a fixed ionic liquid electrolyte concentration (molar ratio AlCl₃: BMIC = 2:1). The effects of deposition temperature (range from 80 °C to 140 °C) and surface roughness of Cu cathode substrates (polished by 320, 600, 800, 1200 grits SiC sandpapers and mirror polishing process)more »« less
https://doi.org/10.1016/j.jclepro.2020.125043

Full Text Available
Roughness evolution and dendritic growth in zinc electrodeposition from halide electrolytes. Final report

Technical Report Landau, U

Evolution of rough or dendritic surface texture during electrodeposition often restricts the capacity of rechargeable batteries by limiting the thickness of the plated layer, thereby imposing economic and operating limitations on high energy storage systems such as the zinc-halogen batteries. This technologically important phenomenon has so far been treated mostly empirically. A comprehensive model for roughness evolution in electrodeposition, taking into account the combined effects of transport by diffusion and convection, reaction kinetics and the surface energy is reported here. Critical overpotentials and induction times for roughness initiation, and propagation of roughness elements are determined. Morphological stability analysis explains whymore »« less
Electrochemical Stability Window of Imidazolium-Based Ionic Liquids as Electrolytes for Lithium Batteries

Journal Article Kazemiabnavi, Saeed ; Zhang, Zhengcheng ; Thornton, Katsuyo ; ... - Journal of Physical Chemistry. B, Condensed Matter, Materials, Surfaces, Interfaces and Biophysical Chemistry
https://doi.org/10.1021/acs.jpcb.6b03433

Similar Records