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This content will become publicly available on January 28, 2017

Title: High performance Nd-Fe-B permanent magnets without critical elements

Scanning electron microscopy, and magnetization measurements reveal that as cast (Nd1–xCex)2Fe14B alloys contain significant amounts of α-Fe that can be dramatically reduced by annealing the alloys at 1000 °C for 3 days. The room temperature intrinsic coercivity, Hci, of (Nd0.8Ce0.2)2.2Fe14B melt spun ribbons was found to be 11 kOe, which is ~32 to ~10% higher in comparison to that of Nd2Fe14B (Hci = 8.3 kOe), and (Nd0.8Ce0.2)2.0Fe14B (Hci = 10 kOe), respectively. The substitution of Co for Fe in (Nd0.8Ce0.2)2Fe14–zCozB significantly increases both TC and the maximum energy product, (BH)max. Our study shows that both Co-containing and Co-free Ce-substituted Nd2Fe14B alloys have excellent magnetic properties at room temperature and above. As a result, the experimental results also demonstrate the potential of Nd-Ce-Fe-TM-B based alloys as alternative to expensive Dy-containing high performance rare earth magnets.
Authors:
 [1] ;  [1] ;  [1] ;  [1] ;  [1]
  1. Ames Lab. and Iowa State Univ., Ames, IA (United States)
Publication Date:
OSTI Identifier:
1245625
Report Number(s):
IS-J--8915
Journal ID: ISSN 0925-8388; PII: S0925838816301955
Grant/Contract Number:
AC02-07CH11358
Type:
Accepted Manuscript
Journal Name:
Journal of Alloys and Compounds
Additional Journal Information:
Journal Volume: 668; Journal Issue: C; Journal ID: ISSN 0925-8388
Publisher:
Elsevier
Research Org:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Org:
USDOE Advanced Research Projects Agency - Energy (ARPA-E)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE permanent magnet; coercivity; maximum energy product; Nd2Fe14B; cerium