Novel 2D RuPt core-edge nanocluster catalyst for CO electro-oxidation

Grabow, Lars C.; Yuan, Qiuyi; Doan, Hieu A.; Brankovic, Stanko R.

doi:10.1016/j.susc.2015.03.021

Title: Novel 2D RuPt core-edge nanocluster catalyst for CO electro-oxidation

Authors:: Grabow, Lars C.; Yuan, Qiuyi; Doan, Hieu A.; Brankovic, Stanko R.

Publication Date:: Thu Oct 01 00:00:00 EDT 2015

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1244766

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Surface Science

Additional Journal Information:: Journal Name: Surface Science Journal Volume: 640 Journal Issue: C; Journal ID: ISSN 0039-6028

Publisher:: Elsevier

Country of Publication:: Netherlands

Language:: English

Citation Formats


                    Grabow, Lars C., Yuan, Qiuyi, Doan, Hieu A., and Brankovic, Stanko R. Novel 2D RuPt core-edge nanocluster catalyst for CO electro-oxidation.  Netherlands: N. p., 2015. 
Web.  doi:10.1016/j.susc.2015.03.021.

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                    Grabow, Lars C., Yuan, Qiuyi, Doan, Hieu A., & Brankovic, Stanko R. Novel 2D RuPt core-edge nanocluster catalyst for CO electro-oxidation.  Netherlands.  https://doi.org/10.1016/j.susc.2015.03.021

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                    Grabow, Lars C., Yuan, Qiuyi, Doan, Hieu A., and Brankovic, Stanko R. Thu .  
"Novel 2D RuPt core-edge nanocluster catalyst for CO electro-oxidation".  Netherlands.  https://doi.org/10.1016/j.susc.2015.03.021.

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@article{osti_1244766,

  title        = {Novel 2D RuPt core-edge nanocluster catalyst for CO electro-oxidation},

  author       = {Grabow, Lars C. and Yuan, Qiuyi and Doan, Hieu A. and Brankovic, Stanko R.},

  abstractNote = {},

  doi          = {10.1016/j.susc.2015.03.021},

  journal      = {Surface Science},

  number       = C,

  volume       = 640,

  place        = {Netherlands},

  year         = {Thu Oct 01 00:00:00 EDT 2015},

  month        = {Thu Oct 01 00:00:00 EDT 2015}

}

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Title: Novel 2D RuPt core-edge nanocluster catalyst for CO electro-oxidation

Citation Formats

Lead Underpotential Deposition on Pt-submonolayer Modified Au(111) journal, October 2012

Recent advances in platinum monolayer electrocatalysts for oxygen reduction reaction: Scale-up synthesis, structure and activity of Pt shells on Pd cores journal, March 2010

Correlation between surface stress and the vibrational shift of CO chemisorbed on Cu surfaces journal, August 1994

Projector augmented-wave method journal, December 1994

The metallicity of thin films and overlayers journal, November 2000

Near-surface alloys for hydrogen fuel cell applications journal, January 2006

Mixed-Metal Pt Monolayer Electrocatalysts for Enhanced Oxygen Reduction Kinetics journal, September 2005

Elastic relaxation of coherent epitaxial deposits journal, December 1997

From ultrasoft pseudopotentials to the projector augmented-wave method journal, January 1999

Controlling the Catalytic Activity of Platinum-Monolayer Electrocatalysts for Oxygen Reduction with Different Substrates journal, March 2005

A sniftirs study of the diffuse double layer at single crystal platinum electrodes in acetonitrile journal, April 1996

Alloy catalysts designed from first principles journal, October 2004

Ternary Pt/Rh/SnO2 electrocatalysts for oxidizing ethanol to CO2 journal, January 2009

Finite-Size Effects in O and CO Adsorption for the Late Transition Metals journal, November 2012

Spontaneous deposition of Pt on the Ru(0001) surface journal, April 2001

Ru–Pt core–shell nanoparticles for preferential oxidation of carbon monoxide in hydrogen journal, March 2008

Field-Dependent Chemisorption of Carbon Monoxide on Platinum-Group (111) Surfaces: Relationships between Binding Energetics, Geometries, and Vibrational Properties as Assessed by Density Functional Theory journal, May 2001

Metal monolayer deposition by replacement of metal adlayers on electrode surfaces journal, March 2001

Investigation of Catalytic Finite-Size-Effects of Platinum Metal Clusters journal, December 2012

Tuning Reaction Rates by Lateral Strain in a Palladium Monolayer journal, March 2005

An object-oriented scripting interface to a legacy electronic structure code journal, January 2002

A density functional theory study of H2S decomposition on the (111) surfaces of model Pd-alloys journal, December 2007

Lattice strain effects on CO oxidation on Pt(111) journal, January 2006

Ligand effects in heterogeneous catalysis and electrochemistry journal, May 2007

Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set journal, July 1996

E LECTRONIC S TRUCTURE AND C ATALYSIS ON M ETAL S URFACES journal, October 2002

Atomic-Scale Evidence for an Enhanced Catalytic Reactivity of Stretched Surfaces journal, June 2003

Interaction of carbon dioxide with Cu overlayers on Pt(111) journal, February 2008

Special points for Brillouin-zone integrations journal, June 1976

Surface Strain versus Substrate Interaction in Heteroepitaxial Metal Layers: Pt on Ru(0001) journal, June 2003

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set journal, October 1996

Stabilization of Platinum Oxygen-Reduction Electrocatalysts Using Gold Clusters journal, January 2007

Pt Submonolayers on Ru Nanoparticles: A Novel Low Pt Loading, High CO Tolerance Fuel Cell Electrocatalyst journal, January 2001

CO adsorption energies on metals with correction for high coordination adsorption sites – A density functional study journal, April 2007

CO on Pt(111) puzzle: A possible solution journal, August 2002

Effect of trace amounts of Cl− in Cu underpotential deposition on Au(111) in perchlorate solutions: an in-situ scanning tunneling microscopy study journal, July 1995

Improved adsorption energetics within density-functional theory using revised Perdew-Burke-Ernzerhof functionals journal, March 1999

Size Effects in Monolayer Catalysis—Model Study: Pt Submonolayers on Au(111) journal, February 2012

A Cu/Pt Near-Surface Alloy for Water−Gas Shift Catalysis journal, May 2007

Effects of Electronic Structure Modifications on the Adsorption of Oxygen Reduction Reaction Intermediates on Model Pt(111)-Alloy Surfaces journal, November 2007

Carbon monoxide oxidation on bare and Pt-modified and Ru(0001) single crystal electrodes journal, September 2002

Role of Strain and Ligand Effects in the Modification of the Electronic and Chemical Properties of Bimetallic Surfaces journal, October 2004

Nucleation of Pt Monolayers Deposited via Surface Limited Redox Replacement Reaction journal, January 2014

Calculation of the vacancy formation energy in aluminium journal, January 1989

Stoichiometry of Pt Submonolayer Deposition via Surface-Limited Redox Replacement Reaction journal, January 2010

Platinum Monolayer Fuel Cell Electrocatalysts journal, November 2007

Bimetallic and Ternary Alloys for Improved Oxygen Reduction Catalysis journal, November 2007

Efficient C–C bond splitting on Pt monolayer and sub-monolayer catalysts during ethanol electro-oxidation: Pt layer strain and morphology effects journal, January 2014

Carbon monoxide adlayer structures on platinum (111) electrodes: A synergy between in‐situ scanning tunneling microscopy and infrared spectroscopy journal, July 1994

Adlayer structures of CO adsorbed on Ru(0001) electrode studied by in-situ STM combined with IRAS journal, September 2000

The CO/Pt(111) Puzzle † journal, May 2001

A Threshold Selection Method from Gray-Level Histograms journal, January 1979

Lead Underpotential Deposition on Pt-submonolayer Modified Au(111)
journal, October 2012

Recent advances in platinum monolayer electrocatalysts for oxygen reduction reaction: Scale-up synthesis, structure and activity of Pt shells on Pd cores
journal, March 2010

Correlation between surface stress and the vibrational shift of CO chemisorbed on Cu surfaces
journal, August 1994

Projector augmented-wave method
journal, December 1994

The metallicity of thin films and overlayers
journal, November 2000

Near-surface alloys for hydrogen fuel cell applications
journal, January 2006

Mixed-Metal Pt Monolayer Electrocatalysts for Enhanced Oxygen Reduction Kinetics
journal, September 2005

Elastic relaxation of coherent epitaxial deposits
journal, December 1997

From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999

Controlling the Catalytic Activity of Platinum-Monolayer Electrocatalysts for Oxygen Reduction with Different Substrates
journal, March 2005

A sniftirs study of the diffuse double layer at single crystal platinum electrodes in acetonitrile
journal, April 1996

Alloy catalysts designed from first principles
journal, October 2004

Ternary Pt/Rh/SnO₂ electrocatalysts for oxidizing ethanol to CO₂
journal, January 2009

Finite-Size Effects in O and CO Adsorption for the Late Transition Metals
journal, November 2012

Spontaneous deposition of Pt on the Ru(0001) surface
journal, April 2001

Ru–Pt core–shell nanoparticles for preferential oxidation of carbon monoxide in hydrogen
journal, March 2008

Field-Dependent Chemisorption of Carbon Monoxide on Platinum-Group (111) Surfaces: Relationships between Binding Energetics, Geometries, and Vibrational Properties as Assessed by Density Functional Theory
journal, May 2001

Metal monolayer deposition by replacement of metal adlayers on electrode surfaces
journal, March 2001

Investigation of Catalytic Finite-Size-Effects of Platinum Metal Clusters
journal, December 2012

Tuning Reaction Rates by Lateral Strain in a Palladium Monolayer
journal, March 2005

An object-oriented scripting interface to a legacy electronic structure code
journal, January 2002

A density functional theory study of H2S decomposition on the (111) surfaces of model Pd-alloys
journal, December 2007

Lattice strain effects on CO oxidation on Pt(111)
journal, January 2006

Ligand effects in heterogeneous catalysis and electrochemistry
journal, May 2007

Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996

E LECTRONIC S TRUCTURE AND C ATALYSIS ON M ETAL S URFACES
journal, October 2002

Atomic-Scale Evidence for an Enhanced Catalytic Reactivity of Stretched Surfaces
journal, June 2003

Interaction of carbon dioxide with Cu overlayers on Pt(111)
journal, February 2008

Special points for Brillouin-zone integrations
journal, June 1976

Surface Strain versus Substrate Interaction in Heteroepitaxial Metal Layers: Pt on Ru(0001)
journal, June 2003

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996

Stabilization of Platinum Oxygen-Reduction Electrocatalysts Using Gold Clusters
journal, January 2007

Pt Submonolayers on Ru Nanoparticles: A Novel Low Pt Loading, High CO Tolerance Fuel Cell Electrocatalyst
journal, January 2001

CO adsorption energies on metals with correction for high coordination adsorption sites – A density functional study
journal, April 2007

CO on Pt(111) puzzle: A possible solution
journal, August 2002

Effect of trace amounts of Cl− in Cu underpotential deposition on Au(111) in perchlorate solutions: an in-situ scanning tunneling microscopy study
journal, July 1995

Improved adsorption energetics within density-functional theory using revised Perdew-Burke-Ernzerhof functionals
journal, March 1999

Size Effects in Monolayer Catalysis—Model Study: Pt Submonolayers on Au(111)
journal, February 2012

A Cu/Pt Near-Surface Alloy for Water−Gas Shift Catalysis
journal, May 2007

Effects of Electronic Structure Modifications on the Adsorption of Oxygen Reduction Reaction Intermediates on Model Pt(111)-Alloy Surfaces
journal, November 2007

Carbon monoxide oxidation on bare and Pt-modified and Ru(0001) single crystal electrodes
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Role of Strain and Ligand Effects in the Modification of the Electronic and Chemical Properties of Bimetallic Surfaces
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Nucleation of Pt Monolayers Deposited via Surface Limited Redox Replacement Reaction
journal, January 2014

Calculation of the vacancy formation energy in aluminium
journal, January 1989

Stoichiometry of Pt Submonolayer Deposition via Surface-Limited Redox Replacement Reaction
journal, January 2010

Platinum Monolayer Fuel Cell Electrocatalysts
journal, November 2007

Bimetallic and Ternary Alloys for Improved Oxygen Reduction Catalysis
journal, November 2007

Efficient C–C bond splitting on Pt monolayer and sub-monolayer catalysts during ethanol electro-oxidation: Pt layer strain and morphology effects
journal, January 2014

Carbon monoxide adlayer structures on platinum (111) electrodes: A synergy between in‐situ scanning tunneling microscopy and infrared spectroscopy
journal, July 1994

Adlayer structures of CO adsorbed on Ru(0001) electrode studied by in-situ STM combined with IRAS
journal, September 2000

The CO/Pt(111) Puzzle ^†
journal, May 2001

A Threshold Selection Method from Gray-Level Histograms
journal, January 1979