Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: High thermal stability of La2O3 and CeO2-stabilized tetragonal ZrO2

Abstract

Catalyst support materials of tetragonal ZrO2, stabilized by either La2O3 (La2O3-ZrO2) or CeO2 (CeO2-ZrO2), were synthesized under hydrothermal conditions at 200 °C with NH4OH or tetramethylammonium hydroxide as the mineralizer. From In Situ synchrotron powder X-ray diffraction and small-angle X-ray scattering measurements, the calcined La2O3-ZrO2 and CeO2-ZrO2 supports were nonporous nanocrystallites that exhibited rectangular shapes with thermal stability up to 1000 °C in air. These supports had an average size of ~10 nm and a surface area of 59-97 m2/g. The catalysts Pt/La2O3-ZrO2 and Pt/CeO2-ZrO2 were prepared by using atomic layer deposition with varying Pt loadings from 6.3-12.4 wt %. Mono-dispersed Pt nanoparticles of ~3 nm were obtained for these catalysts. As a result, the incorporation of La2O3 and CeO2 into the t-ZrO2 structure did not affect the nature of the active sites for the Pt/ZrO2 catalysts for the water-gas-shift (WGS) reaction.

Authors:
 [1];  [1];  [1];  [1];  [2];  [2];  [3];  [3];  [2];  [2];  [2];  [2]
+ Show Author Affiliations
  1. Northwestern Univ., Evanston, IL (United States)
  2. Argonne National Lab. (ANL), Argonne, IL (United States)
  3. Purdue Univ., West Lafayette, IN (United States)
Publication Date:
Research Org.:
Argonne National Laboratory (ANL), Argonne, IL (United States); Energy Frontier Research Centers (EFRC) (United States). Institute for Atom-efficient Chemical Transformations (IACT)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1241300
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Inorganic Chemistry
Additional Journal Information:
Journal Volume: 55; Journal Issue: 5; Journal ID: ISSN 0020-1669
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; ALD; La2O3; CeO2; hydrothermal; stabilized; tetragonal ZrO2; water-gas-shift

Citation Formats

Wang, Shichao, Xie, Hong, Lin, Yuyuan, Poeppelmeier, Kenneth R., Li, Tao, Winans, Randall E., Cui, Yanran, Ribeiro, Fabio H., Canlas, Christian P., Elam, Jeffrey W., Zhang, Hongbo, and Marshall, Christopher L. High thermal stability of La2O3 and CeO2-stabilized tetragonal ZrO2. United States: N. p., 2016. Web. doi:10.1021/acs.inorgchem.5b02810.
Copy to clipboard
Wang, Shichao, Xie, Hong, Lin, Yuyuan, Poeppelmeier, Kenneth R., Li, Tao, Winans, Randall E., Cui, Yanran, Ribeiro, Fabio H., Canlas, Christian P., Elam, Jeffrey W., Zhang, Hongbo, & Marshall, Christopher L. High thermal stability of La2O3 and CeO2-stabilized tetragonal ZrO2. United States. https://doi.org/10.1021/acs.inorgchem.5b02810
Copy to clipboard
Wang, Shichao, Xie, Hong, Lin, Yuyuan, Poeppelmeier, Kenneth R., Li, Tao, Winans, Randall E., Cui, Yanran, Ribeiro, Fabio H., Canlas, Christian P., Elam, Jeffrey W., Zhang, Hongbo, and Marshall, Christopher L. Mon . "High thermal stability of La2O3 and CeO2-stabilized tetragonal ZrO2". United States. https://doi.org/10.1021/acs.inorgchem.5b02810. https://www.osti.gov/servlets/purl/1241300.
Copy to clipboard
@article{osti_1241300,
title = {High thermal stability of La2O3 and CeO2-stabilized tetragonal ZrO2},
author = {Wang, Shichao and Xie, Hong and Lin, Yuyuan and Poeppelmeier, Kenneth R. and Li, Tao and Winans, Randall E. and Cui, Yanran and Ribeiro, Fabio H. and Canlas, Christian P. and Elam, Jeffrey W. and Zhang, Hongbo and Marshall, Christopher L.},
abstractNote = {Catalyst support materials of tetragonal ZrO2, stabilized by either La2O3 (La2O3-ZrO2) or CeO2 (CeO2-ZrO2), were synthesized under hydrothermal conditions at 200 °C with NH4OH or tetramethylammonium hydroxide as the mineralizer. From In Situ synchrotron powder X-ray diffraction and small-angle X-ray scattering measurements, the calcined La2O3-ZrO2 and CeO2-ZrO2 supports were nonporous nanocrystallites that exhibited rectangular shapes with thermal stability up to 1000 °C in air. These supports had an average size of ~10 nm and a surface area of 59-97 m2/g. The catalysts Pt/La2O3-ZrO2 and Pt/CeO2-ZrO2 were prepared by using atomic layer deposition with varying Pt loadings from 6.3-12.4 wt %. Mono-dispersed Pt nanoparticles of ~3 nm were obtained for these catalysts. As a result, the incorporation of La2O3 and CeO2 into the t-ZrO2 structure did not affect the nature of the active sites for the Pt/ZrO2 catalysts for the water-gas-shift (WGS) reaction.},
doi = {10.1021/acs.inorgchem.5b02810},
journal = {Inorganic Chemistry},
number = 5,
volume = 55,
place = {United States},
year = {Mon Feb 15 00:00:00 EST 2016},
month = {Mon Feb 15 00:00:00 EST 2016}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1021/acs.inorgchem.5b02810
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Citation Metrics:
Cited by: 17 works
Citation information provided by
Web of Science
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

Application of ZrO2 as a catalyst and a catalyst support
journal, June 1994

Metal oxide analogue of metal alloy catalysts
journal, November 1984

HIGH SELECTIVITIES OF ZIRCONIUM OXIDE CATALYST FOR ISOMERIZATION OF 1-BUTENE AND DEHYDRATION OF sec -BUTANOL
journal, September 1973

  • Yamaguchi, Tsutomu; Sasaki, Hiroshi; Tanabe, Kozo
  • Chemistry Letters, Vol. 2, Issue 9
  • DOI: 10.1246/cl.1973.1017

AN INFRARED SPECTROSCOPIC STUDY ON THE MECHANISM OF METHANOL FORMATION FROM CO AND H 2 OVER ZIRCONIA
journal, November 1984

  • Abe, Hiroshi; Maruya, Ken-ichi; Domen, Kazunari
  • Chemistry Letters, Vol. 13, Issue 11
  • DOI: 10.1246/cl.1984.1875

Infrared studies of the adsorption of synthesis gas on zirconium dioxide
journal, June 1984

Catalytic performance of copper supported on zirconia polymorphs for CO hydrogenation
journal, April 2005

Hydrogenation of conjugated dienes over ZrO2 by H2 and cyclohexadiene
journal, April 1983

Monoclinic and Tetragonal High Surface Area Sulfated Zirconias in Butane Isomerization: CO Adsorption and Catalytic Results
journal, March 2001

New solid superacid catalysts for n-butane isomerization: γ-Al2O3 or SiO2 supported sulfated zirconia
journal, February 2000

Highly active and stable Ni/Ce–ZrO2 catalyst for H2 production from methane
journal, March 2002

Direct epoxidation of propylene with molecular oxygen over Ag–MoO3/ZrO2 catalyst
journal, September 2004

Role of Praseodymium on Zirconia Phases Stabilization
journal, December 2001

  • Corradi, Anna Bonamartini; Bondioli, Federica; Ferrari, Anna Maria
  • Chemistry of Materials, Vol. 13, Issue 12
  • DOI: 10.1021/cm010212a

Effects of zirconia phase on the synthesis of higher alcohols over zirconia and modified zirconia
journal, February 2004

The effect of zirconia polymorphs on the structure and catalytic properties of V2O5/ZrO2 catalysts
journal, March 2009

Catalytic behavior and nature of active sites in copper-on-zirconia catalysts for the decomposition of N2O
journal, January 1996

Water-Assisted Tetragonal-to-Monoclinic Phase Transformation of ZrO 2 at Low Temperatures
journal, August 2000

  • Xie, Shuibo; Iglesia, Enrique; Bell, Alexis T.
  • Chemistry of Materials, Vol. 12, Issue 8
  • DOI: 10.1021/cm000212v

Role of Water Vapor in Crystallite Growth and Tetragonal-Monoclinic Phase Transformation of ZrO2
journal, March 1983

Influence of the synthesis conditions on the properties of hydrous zirconia and the stability of low-temperature t-ZrO2
journal, July 2000

Effect of Nanocrystallite Morphology on the Metastable Tetragonal Phase Stabilization in Zirconia
journal, September 2002

  • Shukla, Satyajit; Seal, Sudipta; Vij, Rashmi
  • Nano Letters, Vol. 2, Issue 9
  • DOI: 10.1021/nl025660b

Formation and stabilization of tetragonal phase in sol–gel derived ZrO2 treated with base-hot-water
journal, October 2010

  • Prastomo, Niki; Muto, Hiroyuki; Sakai, Mototsugu
  • Materials Science and Engineering: B, Vol. 173, Issue 1-3
  • DOI: 10.1016/j.mseb.2009.12.011

Hydrated surface structure and its impacts on the stabilization of t-ZrO2
journal, October 2007

Hydrothermal synthesis of zirconia nanomaterials
journal, January 2001

Nanocrystallization and Phase Transformation in Monodispersed Ultrafine Zirconia Particles from Various Homogeneous Precipitation Methods
journal, September 1999

The preparation of high surface area zirconia — Influence of precipitating agent and digestion
journal, December 1997

Effect of Supported Na+Ions on the Texture Properties of ZrO2
journal, June 1998

  • Liu, Zheng; Ji, Weijie; Dong, Lin
  • Journal of Solid State Chemistry, Vol. 138, Issue 1
  • DOI: 10.1006/jssc.1998.7752

The Occurrence of Metastable Tetragonal Zirconia as a Crystallite Size Effect
journal, April 1965

  • Garvie, Ronald C.
  • The Journal of Physical Chemistry, Vol. 69, Issue 4
  • DOI: 10.1021/j100888a024

Synthesis of Na-Stabilized Nonporous t-ZrO 2 Supports and Pt/t-ZrO 2 Catalysts and Application to Water-Gas-Shift Reaction
journal, December 2012

  • Xie, Hong; Lu, Junling; Shekhar, Mayank
  • ACS Catalysis, Vol. 3, Issue 1
  • DOI: 10.1021/cs300596q

Synthesis and characterization of doped nano-sized ceria–zirconia solid solutions
journal, August 2009

Role of cerium–zirconium mixed oxides as catalysts for car pollution: A short review
journal, July 1998

On the structural chemistry of zirconium oxide
journal, June 1982

Structural, magnetic and luminescent characteristics of Pr 3+ -doped ZrO 2 powders synthesized by a sol–gel method
journal, March 2009

  • Isasi-Marín, J.; Pérez-Estébanez, M.; Díaz-Guerra, C.
  • Journal of Physics D: Applied Physics, Vol. 42, Issue 7
  • DOI: 10.1088/0022-3727/42/7/075418

Hydrothermal synthesis and characterization of zirconia based catalysts
journal, July 2013

Synthesis of nanocrystalline La2O3–Y2O3–ZrO2 solid solutions by hydrothermal method: A crystal growth and structural study
journal, November 2011

Structure and State of Copper Oxide Species Supported on Yttria-Stabilized Zirconia
journal, November 2009

  • Pakharukova, Vera P.; Moroz, Ella M.; Kriventsov, Vladimir V.
  • The Journal of Physical Chemistry C, Vol. 113, Issue 51
  • DOI: 10.1021/jp907652n

Structure and Reactivity of Molybdenum Oxide Catalysts Supported on La 2 O 3 -Stabilized Tetragonal ZrO 2
journal, December 2003

  • Reddy, Kondakindi Rajender; Bhaskar, Thallada; Chary, Komandur V. R.
  • Langmuir, Vol. 19, Issue 26
  • DOI: 10.1021/la020843z

Low temperature hydrothermal synthesis of ZrO2-CaO solid solutions
journal, January 2000

  • Dell'Agli, G.; Mascolo, G.
  • Journal of Materials Science, Vol. 35, Issue 3, p. 661-665
  • DOI: 10.1023/A:1004740830928

Enhanced Kinetic Stability of Pure and Y-Doped Tetragonal ZrO 2
journal, November 2014

  • Kogler, Michaela; Köck, Eva-Maria; Vanicek, Stefan
  • Inorganic Chemistry, Vol. 53, Issue 24
  • DOI: 10.1021/ic502623t

Effect of Dopants on Zirconia Stabilization-An X-ray Absorption Study: II, Tetravalent Dopants
journal, May 1994

Effect of Dopants on Zirconia Stabilization-An X-ray Absorption Study: III, Charge-Compensating Dopants
journal, May 1994

Effect of Dopants on Zirconia Stabilization-An X-ray Absorption Study: I, Trivalent Dopants
journal, January 1994

Variation of the oxygen content in tetragonal, calcium oxide-doped zirconia
journal, November 1994

Oxygen vacancies in transition metal and rare earth oxides: Current state of understanding and remaining challenges
journal, June 2007

  • Ganduglia-Pirovano, M. Verónica; Hofmann, Alexander; Sauer, Joachim
  • Surface Science Reports, Vol. 62, Issue 6
  • DOI: 10.1016/j.surfrep.2007.03.002

Production of syngas from steam reforming and CO removal with water gas shift reaction over nanosized Zr0.95Ru0.05O2−δ solid solution
journal, October 2013

Atomic Layer Deposition of Platinum Thin Films
journal, May 2003

  • Aaltonen, Titta; Ritala, Mikko; Sajavaara, Timo
  • Chemistry of Materials, Vol. 15, Issue 9, p. 1924-1928
  • DOI: 10.1021/cm021333t

Controlled Growth of Platinum Nanoparticles on Strontium Titanate Nanocubes by Atomic Layer Deposition
journal, March 2009

  • Christensen, Steven T.; Elam, Jeffrey W.; Rabuffetti, Federico A.
  • Small, Vol. 5, Issue 6
  • DOI: 10.1002/smll.200801920

Viscous flow reactor with quartz crystal microbalance for thin film growth by atomic layer deposition
journal, August 2002

  • Elam, J. W.; Groner, M. D.; George, S. M.
  • Review of Scientific Instruments, Vol. 73, Issue 8, p. 2981-2987
  • DOI: 10.1063/1.1490410

Irena : tool suite for modeling and analysis of small-angle scattering
journal, February 2009

Effect of Zn addition on the water–gas shift reaction over supported palladium catalysts
journal, July 2008

Kinetics of the water–gas shift reaction on Pt catalysts supported on alumina and ceria
journal, May 2007

Periodic DFT Study of the Tetragonal ZrO 2 Nanocrystals: Equilibrium Morphology Modeling and Atomistic Surface Hydration Thermodynamics
journal, August 2012

  • Piskorz, Witold; Gryboś, Joanna; Zasada, Filip
  • The Journal of Physical Chemistry C, Vol. 116, Issue 36
  • DOI: 10.1021/jp3050059

Metallic Pt as active sites for the water–gas shift reaction on alkali-promoted supported catalysts
journal, February 2012

Identification of active sites in CO oxidation and water-gas shift over supported Pt catalysts
journal, September 2015

    Sort by:
    [ × clear filter / sort ]

    Works referencing / citing this record:

    Enhanced catalytic activity of Ni–Mo2C/La2O3–ZrO2 bifunctional catalyst for dry reforming of methane
    journal, June 2018

    • Tao, Qingqing; Wang, Zhida; Jayasundera, Bandara
    • Journal of Materials Science, Vol. 53, Issue 20
    • DOI: 10.1007/s10853-018-2642-4

    Catalytic depolymerization of alkali lignin in ionic liquids on Pt-supported La 2 O 3 –SO 4 2− /ZrO 2 catalysts
    journal, January 2020

    • Wang, Xiuhui; Luo, Yi; Qian, Moriko
    • Sustainable Energy & Fuels, Vol. 4, Issue 3
    • DOI: 10.1039/c9se00682f
      Sort by:
      [ × clear filter / sort ]

      Similar Records in DOE PAGES and OSTI.GOV collections: