Phase separation in the nonequilibrium Verwey transition in magnetite

Randi, F.; Vergara, I.; Novelli, F.; Esposito, M.; Dell'Angela, M.; Brabers, V. A. M.; Metcalf, P.; Kukreja, R.; Dürr, H. A.; Fausti, D.; Grüninger, M.; Parmigiani, F.

doi:10.1103/PhysRevB.93.054305

Title: Phase separation in the nonequilibrium Verwey transition in magnetite

Authors:: Randi, F.; Vergara, I.; Novelli, F.; Esposito, M.; Dell'Angela, M.; Brabers, V. A. M.; Metcalf, P.; Kukreja, R.; Dürr, H. A.; Fausti, D.; Grüninger, M.; Parmigiani, F.

Publication Date:: Fri Feb 26 00:00:00 EST 2016

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1239617

Grant/Contract Number:: AC02-76SF00515

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Physical Review B

Additional Journal Information:: Journal Name: Physical Review B Journal Volume: 93 Journal Issue: 5; Journal ID: ISSN 2469-9950

Publisher:: American Physical Society

Country of Publication:: United States

Language:: English

Citation Formats


                    Randi, F., Vergara, I., Novelli, F., Esposito, M., Dell'Angela, M., Brabers, V. A. M., Metcalf, P., Kukreja, R., Dürr, H. A., Fausti, D., Grüninger, M., and Parmigiani, F. Phase separation in the nonequilibrium Verwey transition in magnetite.  United States: N. p., 2016. 
Web.  doi:10.1103/PhysRevB.93.054305.

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                    Randi, F., Vergara, I., Novelli, F., Esposito, M., Dell'Angela, M., Brabers, V. A. M., Metcalf, P., Kukreja, R., Dürr, H. A., Fausti, D., Grüninger, M., & Parmigiani, F. Phase separation in the nonequilibrium Verwey transition in magnetite.  United States.  https://doi.org/10.1103/PhysRevB.93.054305

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                    Randi, F., Vergara, I., Novelli, F., Esposito, M., Dell'Angela, M., Brabers, V. A. M., Metcalf, P., Kukreja, R., Dürr, H. A., Fausti, D., Grüninger, M., and Parmigiani, F. Fri .  
"Phase separation in the nonequilibrium Verwey transition in magnetite".  United States.  https://doi.org/10.1103/PhysRevB.93.054305.

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@article{osti_1239617,

  title        = {Phase separation in the nonequilibrium Verwey transition in magnetite},

  author       = {Randi, F. and Vergara, I. and Novelli, F. and Esposito, M. and Dell'Angela, M. and Brabers, V. A. M. and Metcalf, P. and Kukreja, R. and Dürr, H. A. and Fausti, D. and Grüninger, M. and Parmigiani, F.},

  abstractNote = {},

  doi          = {10.1103/PhysRevB.93.054305},

  journal      = {Physical Review B},

  number       = 5,

  volume       = 93,

  place        = {United States},

  year         = {Fri Feb 26 00:00:00 EST 2016},

  month        = {Fri Feb 26 00:00:00 EST 2016}

}

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Works referenced in this record:

Direct Observation of Charge Ordering in Magnetite Using Resonant Multiwave X-Ray Diffraction
journal, April 2012

Weng, Shih-Chang; Lee, Yen-Ru; Chen, Cheng-Gang
Physical Review Letters, Vol. 108, Issue 14
DOI: 10.1103/PhysRevLett.108.146404

Probing orbital fluctuations in $R$ VO $_{3}$ ( $R$ $=$ Y, Gd, or Ce) by ellipsometry
journal, September 2012

Reul, J.; Nugroho, A. A.; Palstra, T. T. M.
Physical Review B, Vol. 86, Issue 12
DOI: 10.1103/PhysRevB.86.125128

Structural transformation in magnetite below the Verwey transition
journal, March 2011

Blasco, Javier; García, Joaquín; Subías, Gloria
Physical Review B, Vol. 83, Issue 10
DOI: 10.1103/PhysRevB.83.104105

Heat capacity studies on single crystal annealed ${Fe}_{3}$ $O_{4}$
journal, January 1985

Shepherd, John P.; Koenitzer, J. W.; Aragón, Ricardo
Physical Review B, Vol. 31, Issue 2
DOI: 10.1103/PhysRevB.31.1107

Charge-gap formation upon the Verwey transition in ${Fe}_{3} O_{4}$
journal, August 1998

Park, S. K.; Ishikawa, T.; Tokura, Y.
Physical Review B, Vol. 58, Issue 7
DOI: 10.1103/PhysRevB.58.3717

Direct Observation of $t_{2 g}$ Orbital Ordering in Magnetite
journal, January 2008

Schlappa, J.; Schüßler-Langeheine, C.; Chang, C. F.
Physical Review Letters, Vol. 100, Issue 2
DOI: 10.1103/PhysRevLett.100.026406

Charge-Orbital Ordering and Verwey Transition in Magnetite Measured by Resonant Soft X-Ray Scattering
journal, March 2006

Huang, D. J.; Lin, H. -J.; Okamoto, J.
Physical Review Letters, Vol. 96, Issue 9
DOI: 10.1103/PhysRevLett.96.096401

Speed limit of the insulator–metal transition in magnetite
journal, July 2013

de Jong, S.; Kukreja, R.; Trabant, C.
Nature Materials, Vol. 12, Issue 10
DOI: 10.1038/nmat3718

Electronic structure of charge-ordered ${Fe}_{3} O_{4}$ from calculated optical, magneto-optical Kerr effect, and O $K$ -edge x-ray absorption spectra
journal, October 2006

Leonov, I.; Yaresko, A. N.; Antonov, V. N.
Physical Review B, Vol. 74, Issue 16
DOI: 10.1103/PhysRevB.74.165117

Evolution of structural and optical-absorption properties in V xFe3−xO4
journal, August 2007

Kim, Kwang Joo; Choi, Seung-li; Lee, Hee Jung
Solid State Communications, Vol. 143, Issue 6-7
DOI: 10.1016/j.ssc.2007.05.044

Transition Metal Compounds
book, January 2014

Khomskii, Daniel I.
DOI: 10.1017/CBO9781139096782

Neutron scattering study of the diffuse critical scattering associated with the Verwey transition in magnetite ( ${Fe}_{3}$ $O_{4}$ )
journal, July 1976

Shapiro, S. M.; Iizumi, M.; Shirane, G.
Physical Review B, Vol. 14, Issue 1
DOI: 10.1103/PhysRevB.14.200

Ultrafast optical spectroscopy of the lowest energy excitations in the Mott insulator compound YVO $_{3}$ : Evidence for Hubbard-type excitons
journal, October 2012

Novelli, Fabio; Fausti, Daniele; Reul, Julia
Physical Review B, Vol. 86, Issue 16
DOI: 10.1103/PhysRevB.86.165135

Resonant X-Ray Diffraction Studies on the Charge Ordering in Magnetite
journal, August 2006

Nazarenko, E.; Lorenzo, J. E.; Joly, Y.
Physical Review Letters, Vol. 97, Issue 5
DOI: 10.1103/PhysRevLett.97.056403

Symmetry of Orbital Order in ${Fe}_{3} O_{4}$ Studied by Fe $L_{2, 3}$ Resonant X-Ray Diffraction
journal, May 2012

Tanaka, A.; Chang, C. F.; Buchholz, M.
Physical Review Letters, Vol. 108, Issue 22
DOI: 10.1103/PhysRevLett.108.227203

Ultrafast photoinduced structure phase transition in antimony single crystals
journal, October 2009

Fausti, Daniele; Misochko, Oleg V.; van Loosdrecht, Paul H. M.
Physical Review B, Vol. 80, Issue 16
DOI: 10.1103/PhysRevB.80.161207

Charge order and three-site distortions in the Verwey structure of magnetite
journal, December 2011

Senn, Mark S.; Wright, Jon P.; Attfield, J. Paul
Nature, Vol. 481, Issue 7380
DOI: 10.1038/nature10704

Charge ordered structure of magnetite ${Fe}_{3} O_{4}$ below the Verwey transition
journal, December 2002

Wright, Jon P.; Attfield, J. Paul; Radaelli, Paolo G.
Physical Review B, Vol. 66, Issue 21
DOI: 10.1103/PhysRevB.66.214422

Reexamination of the Temperature Dependences of Resonant Reflections in Highly Stoichiometric Magnetite
journal, May 2009

García, Joaquín; Subías, Gloria; Herrero-Martín, Javier
Physical Review Letters, Vol. 102, Issue 17
DOI: 10.1103/PhysRevLett.102.176405

Gigantic Photoresponse in 1/4-Filled-Band Organic Salt (EDO-TTF)2PF6
journal, January 2005

Chollet, M.
Science, Vol. 307, Issue 5706
DOI: 10.1126/science.1105067

Charge transfer transitions in multiferroic ${BiFeO}_{3}$ and related ferrite insulators
journal, June 2009

Pisarev, R. V.; Moskvin, A. S.; Kalashnikova, A. M.
Physical Review B, Vol. 79, Issue 23
DOI: 10.1103/PhysRevB.79.235128

Optical properties of magnetite (Fe ₃ O ₄ )
journal, March 1979

Schlegel, A.; Alvarado, S. F.; Wachter, P.
Journal of Physics C: Solid State Physics, Vol. 12, Issue 6
DOI: 10.1088/0022-3719/12/6/027

Multiferroicity due to charge ordering
journal, October 2008

van den Brink, Jeroen; Khomskii, Daniel I.
Journal of Physics: Condensed Matter, Vol. 20, Issue 43
DOI: 10.1088/0953-8984/20/43/434217

Mott-Hubbard versus charge-transfer behavior in $La Sr Mn O_{4}$ studied via optical conductivity
journal, January 2008

Gössling, A.; Haverkort, M. W.; Benomar, M.
Physical Review B, Vol. 77, Issue 3
DOI: 10.1103/PhysRevB.77.035109

Mott-Hubbard exciton in the optical conductivity of ${YTiO}_{3}$ and ${SmTiO}_{3}$
journal, August 2008

Gössling, A.; Schmitz, R.; Roth, H.
Physical Review B, Vol. 78, Issue 7
DOI: 10.1103/PhysRevB.78.075122

Infrared and Raman studies of the Verwey transition in magnetite
journal, September 2000

Gasparov, L. V.; Tanner, D. B.; Romero, D. B.
Physical Review B, Vol. 62, Issue 12
DOI: 10.1103/PhysRevB.62.7939

Temperature-dependent optical conductivity of layered LaSrFeO $_{4}$
journal, May 2013

Reul, J.; Fels, L.; Qureshi, N.
Physical Review B, Vol. 87, Issue 20
DOI: 10.1103/PhysRevB.87.205142

Witnessing the formation and relaxation of dressed quasi-particles in a strongly correlated electron system
journal, October 2014

Novelli, Fabio; De Filippis, Giulio; Cataudella, Vittorio
Nature Communications, Vol. 5, Issue 1
DOI: 10.1038/ncomms6112

Study of the 123-K phase transition of magnetite by critical neutron scattering
journal, March 1975

Fujii, Y.; Shirane, G.; Yamada, Y.
Physical Review B, Vol. 11, Issue 5
DOI: 10.1103/PhysRevB.11.2036

Electronic Conduction of Magnetite (Fe3O4) and its Transition Point at Low Temperatures
journal, August 1939

Verwey, E. J. W.
Nature, Vol. 144, Issue 3642
DOI: 10.1038/144327b0

Thermoelectric properties of magnetite at the Verwey transition
journal, August 1976

Kuipers, A. J. M.; Brabers, V. A. M.
Physical Review B, Vol. 14, Issue 4
DOI: 10.1103/PhysRevB.14.1401

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Response of the Verwey transition in magnetite to controlled point-like disorder induced by 2.5 MeV electron irradiation

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Similar Records

Title: Phase separation in the nonequilibrium Verwey transition in magnetite

Citation Formats

Direct Observation of Charge Ordering in Magnetite Using Resonant Multiwave X-Ray Diffraction journal, April 2012

Probing orbital fluctuations in R VO 3 ( R = Y, Gd, or Ce) by ellipsometry journal, September 2012

Structural transformation in magnetite below the Verwey transition journal, March 2011

Heat capacity studies on single crystal annealed Fe 3 O 4 journal, January 1985

Charge-gap formation upon the Verwey transition in Fe 3 O 4 journal, August 1998

Direct Observation of t 2 g Orbital Ordering in Magnetite journal, January 2008

Charge-Orbital Ordering and Verwey Transition in Magnetite Measured by Resonant Soft X-Ray Scattering journal, March 2006

Speed limit of the insulator–metal transition in magnetite journal, July 2013

Electronic structure of charge-ordered Fe 3 O 4 from calculated optical, magneto-optical Kerr effect, and O K -edge x-ray absorption spectra journal, October 2006

Evolution of structural and optical-absorption properties in V xFe3−xO4 journal, August 2007

Transition Metal Compounds book, January 2014

Neutron scattering study of the diffuse critical scattering associated with the Verwey transition in magnetite ( Fe 3 O 4 ) journal, July 1976

Ultrafast optical spectroscopy of the lowest energy excitations in the Mott insulator compound YVO 3 : Evidence for Hubbard-type excitons journal, October 2012

Resonant X-Ray Diffraction Studies on the Charge Ordering in Magnetite journal, August 2006

Symmetry of Orbital Order in Fe 3 O 4 Studied by Fe L 2 , 3 Resonant X-Ray Diffraction journal, May 2012

Ultrafast photoinduced structure phase transition in antimony single crystals journal, October 2009

Charge order and three-site distortions in the Verwey structure of magnetite journal, December 2011

Charge ordered structure of magnetite Fe 3 O 4 below the Verwey transition journal, December 2002

Reexamination of the Temperature Dependences of Resonant Reflections in Highly Stoichiometric Magnetite journal, May 2009

Gigantic Photoresponse in 1/4-Filled-Band Organic Salt (EDO-TTF)2PF6 journal, January 2005

Charge transfer transitions in multiferroic BiFeO 3 and related ferrite insulators journal, June 2009

Optical properties of magnetite (Fe 3 O 4 ) journal, March 1979

Multiferroicity due to charge ordering journal, October 2008

Mott-Hubbard versus charge-transfer behavior in La Sr Mn O 4 studied via optical conductivity journal, January 2008

Mott-Hubbard exciton in the optical conductivity of YTiO 3 and SmTiO 3 journal, August 2008

Infrared and Raman studies of the Verwey transition in magnetite journal, September 2000

Temperature-dependent optical conductivity of layered LaSrFeO 4 journal, May 2013

Witnessing the formation and relaxation of dressed quasi-particles in a strongly correlated electron system journal, October 2014

Study of the 123-K phase transition of magnetite by critical neutron scattering journal, March 1975

Electronic Conduction of Magnetite (Fe3O4) and its Transition Point at Low Temperatures journal, August 1939

Thermoelectric properties of magnetite at the Verwey transition journal, August 1976

Direct Observation of Charge Ordering in Magnetite Using Resonant Multiwave X-Ray Diffraction
journal, April 2012

Probing orbital fluctuations in $R$ VO $_{3}$ ( $R$ $=$ Y, Gd, or Ce) by ellipsometry
journal, September 2012

Structural transformation in magnetite below the Verwey transition
journal, March 2011

Heat capacity studies on single crystal annealed ${Fe}_{3}$ $O_{4}$
journal, January 1985

Charge-gap formation upon the Verwey transition in ${Fe}_{3} O_{4}$
journal, August 1998

Direct Observation of $t_{2 g}$ Orbital Ordering in Magnetite
journal, January 2008

Charge-Orbital Ordering and Verwey Transition in Magnetite Measured by Resonant Soft X-Ray Scattering
journal, March 2006

Speed limit of the insulator–metal transition in magnetite
journal, July 2013

Electronic structure of charge-ordered ${Fe}_{3} O_{4}$ from calculated optical, magneto-optical Kerr effect, and O $K$ -edge x-ray absorption spectra
journal, October 2006

Evolution of structural and optical-absorption properties in V xFe3−xO4
journal, August 2007

Transition Metal Compounds
book, January 2014

Neutron scattering study of the diffuse critical scattering associated with the Verwey transition in magnetite ( ${Fe}_{3}$ $O_{4}$ )
journal, July 1976

Ultrafast optical spectroscopy of the lowest energy excitations in the Mott insulator compound YVO $_{3}$ : Evidence for Hubbard-type excitons
journal, October 2012

Resonant X-Ray Diffraction Studies on the Charge Ordering in Magnetite
journal, August 2006

Symmetry of Orbital Order in ${Fe}_{3} O_{4}$ Studied by Fe $L_{2, 3}$ Resonant X-Ray Diffraction
journal, May 2012

Ultrafast photoinduced structure phase transition in antimony single crystals
journal, October 2009

Charge order and three-site distortions in the Verwey structure of magnetite
journal, December 2011

Charge ordered structure of magnetite ${Fe}_{3} O_{4}$ below the Verwey transition
journal, December 2002

Reexamination of the Temperature Dependences of Resonant Reflections in Highly Stoichiometric Magnetite
journal, May 2009

Gigantic Photoresponse in 1/4-Filled-Band Organic Salt (EDO-TTF)2PF6
journal, January 2005

Charge transfer transitions in multiferroic ${BiFeO}_{3}$ and related ferrite insulators
journal, June 2009

Optical properties of magnetite (Fe ₃ O ₄ )
journal, March 1979

Multiferroicity due to charge ordering
journal, October 2008

Mott-Hubbard versus charge-transfer behavior in $La Sr Mn O_{4}$ studied via optical conductivity
journal, January 2008

Mott-Hubbard exciton in the optical conductivity of ${YTiO}_{3}$ and ${SmTiO}_{3}$
journal, August 2008

Infrared and Raman studies of the Verwey transition in magnetite
journal, September 2000

Temperature-dependent optical conductivity of layered LaSrFeO $_{4}$
journal, May 2013

Witnessing the formation and relaxation of dressed quasi-particles in a strongly correlated electron system
journal, October 2014

Study of the 123-K phase transition of magnetite by critical neutron scattering
journal, March 1975

Electronic Conduction of Magnetite (Fe3O4) and its Transition Point at Low Temperatures
journal, August 1939

Thermoelectric properties of magnetite at the Verwey transition
journal, August 1976