General 2.5 power law of metallic glasses
Abstract
Metallic glass (MG) is an important new category of materials, but very few rigorous laws are currently known for defining its “disordered” structure. Recently we found that under compression, the volume ( V ) of an MG changes precisely to the 2.5 power of its principal diffraction peak position (1/ q 1 ). In the present study, we find that this 2.5 power law holds even through the first-order polyamorphic transition of a Ce 68 Al 10 Cu 20 Co 2 MG. This transition is, in effect, the equivalent of a continuous “composition” change of 4 f -localized “big Ce” to 4 f -itinerant “small Ce,” indicating the 2.5 power law is general for tuning with composition. The exactness and universality imply that the 2.5 power law may be a general rule defining the structure of MGs.
- Authors:
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); National Natural Science Foundation of China (NSFC)
- OSTI Identifier:
- 1236653
- Alternate Identifier(s):
- OSTI ID: 1238286
- Grant/Contract Number:
- AC02-06CH11357; EAR 11-57758; EAR-1128799; FG02-94ER14466; FG02-99ER45775; U1530402; NSF-EAR-1055454; NA0001974
- Resource Type:
- Published Article
- Journal Name:
- Proceedings of the National Academy of Sciences of the United States of America
- Additional Journal Information:
- Journal Name: Proceedings of the National Academy of Sciences of the United States of America Journal Volume: 113 Journal Issue: 7; Journal ID: ISSN 0027-8424
- Publisher:
- National Academy of Sciences
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; general structure–property relationship; polyamorphic transition; pressure effect; composition effect; atomic packing
Citation Formats
Zeng, Qiaoshi, Lin, Yu, Liu, Yijin, Zeng, Zhidan, Shi, Crystal Y., Zhang, Bo, Lou, Hongbo, Sinogeikin, Stanislav V., Kono, Yoshio, Kenney-Benson, Curtis, Park, Changyong, Yang, Wenge, Wang, Weihua, Sheng, Hongwei, Mao, Ho-kwang, and Mao, Wendy L. General 2.5 power law of metallic glasses. United States: N. p., 2016.
Web. doi:10.1073/pnas.1525390113.
Zeng, Qiaoshi, Lin, Yu, Liu, Yijin, Zeng, Zhidan, Shi, Crystal Y., Zhang, Bo, Lou, Hongbo, Sinogeikin, Stanislav V., Kono, Yoshio, Kenney-Benson, Curtis, Park, Changyong, Yang, Wenge, Wang, Weihua, Sheng, Hongwei, Mao, Ho-kwang, & Mao, Wendy L. General 2.5 power law of metallic glasses. United States. https://doi.org/10.1073/pnas.1525390113
Zeng, Qiaoshi, Lin, Yu, Liu, Yijin, Zeng, Zhidan, Shi, Crystal Y., Zhang, Bo, Lou, Hongbo, Sinogeikin, Stanislav V., Kono, Yoshio, Kenney-Benson, Curtis, Park, Changyong, Yang, Wenge, Wang, Weihua, Sheng, Hongwei, Mao, Ho-kwang, and Mao, Wendy L. Mon .
"General 2.5 power law of metallic glasses". United States. https://doi.org/10.1073/pnas.1525390113.
@article{osti_1236653,
title = {General 2.5 power law of metallic glasses},
author = {Zeng, Qiaoshi and Lin, Yu and Liu, Yijin and Zeng, Zhidan and Shi, Crystal Y. and Zhang, Bo and Lou, Hongbo and Sinogeikin, Stanislav V. and Kono, Yoshio and Kenney-Benson, Curtis and Park, Changyong and Yang, Wenge and Wang, Weihua and Sheng, Hongwei and Mao, Ho-kwang and Mao, Wendy L.},
abstractNote = {Metallic glass (MG) is an important new category of materials, but very few rigorous laws are currently known for defining its “disordered” structure. Recently we found that under compression, the volume ( V ) of an MG changes precisely to the 2.5 power of its principal diffraction peak position (1/ q 1 ). In the present study, we find that this 2.5 power law holds even through the first-order polyamorphic transition of a Ce 68 Al 10 Cu 20 Co 2 MG. This transition is, in effect, the equivalent of a continuous “composition” change of 4 f -localized “big Ce” to 4 f -itinerant “small Ce,” indicating the 2.5 power law is general for tuning with composition. The exactness and universality imply that the 2.5 power law may be a general rule defining the structure of MGs.},
doi = {10.1073/pnas.1525390113},
journal = {Proceedings of the National Academy of Sciences of the United States of America},
number = 7,
volume = 113,
place = {United States},
year = {Mon Feb 01 00:00:00 EST 2016},
month = {Mon Feb 01 00:00:00 EST 2016}
}
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https://doi.org/10.1073/pnas.1525390113
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