TEM in situ lithiation of tin nanoneedles for battery applications
Abstract
Materials such as tin (Sn) and silicon that alloy with lithium (Li) have attracted renewed interest as anode materials in Li-ion batteries. Although their superior capacity to graphite and other intercalation materials has been known for decades, their mechanical instability due to extreme volume changes during cycling has traditionally limited their commercial viability. This limitation is changing as processes emerge that produce nanostructured electrodes. The nanostructures can accommodate the repeated expansion and contraction as Li is inserted and removed without failing mechanically. Recently, one such nano-manufacturing process, which is capable of depositing coatings of Sn “nanoneedles” at low temperature with no template and at industrial scales, has been described. The present work is concerned with observations of the lithiation and delithiation behavior of these Sn nanoneedles during in situ experiments in the transmission electron microscope, along with a brief review of how in situ TEM experiments have been used to study the lithiation of Li-alloying materials. Individual needles are successfully lithiated and delithiated in solid-state half-cells against a Li-metal counter-electrode. Furthermore the microstructural evolution of the needles is discussed, including the transformation of one needle from single-crystal Sn to polycrystalline Sn–Li and back to single-crystal Sn.
- Authors:
-
- Univ. of Connecticut, Storrs, CT (United States)
- Washington State Univ., Pullman, WA (United States)
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Univ. of Connecticut, Storrs, CT (United States); Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Publication Date:
- Research Org.:
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Energy Frontier Research Centers (EFRC) (United States). Nanostructures for Electrical Energy Storage (NEES)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1236483
- Report Number(s):
- SAND-2015-7618J
Journal ID: ISSN 0022-2461; PII: 9318
- Grant/Contract Number:
- AC04-94AL85000; SC0001160
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Materials Science
- Additional Journal Information:
- Journal Volume: 51; Journal Issue: 1; Journal ID: ISSN 0022-2461
- Publisher:
- Springer
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 77 NANOSCIENCE AND NANOTECHNOLOGY; 25 ENERGY STORAGE; batteries; in-situ TEM; nanoneedles; tin; lithiation
Citation Formats
Janish, Matthew T., Mackay, David T., Liu, Yang, Jungjohann, Katherine L., Carter, C. Barry, and Norton, M. Grant. TEM in situ lithiation of tin nanoneedles for battery applications. United States: N. p., 2015.
Web. doi:10.1007/s10853-015-9318-0.
Janish, Matthew T., Mackay, David T., Liu, Yang, Jungjohann, Katherine L., Carter, C. Barry, & Norton, M. Grant. TEM in situ lithiation of tin nanoneedles for battery applications. United States. https://doi.org/10.1007/s10853-015-9318-0
Janish, Matthew T., Mackay, David T., Liu, Yang, Jungjohann, Katherine L., Carter, C. Barry, and Norton, M. Grant. Wed .
"TEM in situ lithiation of tin nanoneedles for battery applications". United States. https://doi.org/10.1007/s10853-015-9318-0. https://www.osti.gov/servlets/purl/1236483.
@article{osti_1236483,
title = {TEM in situ lithiation of tin nanoneedles for battery applications},
author = {Janish, Matthew T. and Mackay, David T. and Liu, Yang and Jungjohann, Katherine L. and Carter, C. Barry and Norton, M. Grant},
abstractNote = {Materials such as tin (Sn) and silicon that alloy with lithium (Li) have attracted renewed interest as anode materials in Li-ion batteries. Although their superior capacity to graphite and other intercalation materials has been known for decades, their mechanical instability due to extreme volume changes during cycling has traditionally limited their commercial viability. This limitation is changing as processes emerge that produce nanostructured electrodes. The nanostructures can accommodate the repeated expansion and contraction as Li is inserted and removed without failing mechanically. Recently, one such nano-manufacturing process, which is capable of depositing coatings of Sn “nanoneedles” at low temperature with no template and at industrial scales, has been described. The present work is concerned with observations of the lithiation and delithiation behavior of these Sn nanoneedles during in situ experiments in the transmission electron microscope, along with a brief review of how in situ TEM experiments have been used to study the lithiation of Li-alloying materials. Individual needles are successfully lithiated and delithiated in solid-state half-cells against a Li-metal counter-electrode. Furthermore the microstructural evolution of the needles is discussed, including the transformation of one needle from single-crystal Sn to polycrystalline Sn–Li and back to single-crystal Sn.},
doi = {10.1007/s10853-015-9318-0},
journal = {Journal of Materials Science},
number = 1,
volume = 51,
place = {United States},
year = {Wed Aug 12 00:00:00 EDT 2015},
month = {Wed Aug 12 00:00:00 EDT 2015}
}
Web of Science
Works referenced in this record:
Building better batteries
journal, February 2008
- Armand, M.; Tarascon, J.-M.
- Nature, Vol. 451, Issue 7179, p. 652-657
Challenges for Rechargeable Li Batteries
journal, February 2010
- Goodenough, John B.; Kim, Youngsik
- Chemistry of Materials, Vol. 22, Issue 3, p. 587-603
Stable cycling of double-walled silicon nanotube battery anodes through solid–electrolyte interphase control
journal, March 2012
- Wu, Hui; Chan, Gerentt; Choi, Jang Wook
- Nature Nanotechnology, Vol. 7, Issue 5
Issues and challenges facing rechargeable lithium batteries
journal, November 2001
- Tarascon, J.-M.; Armand, M.
- Nature, Vol. 414, Issue 6861, p. 359-367
Battery materials for ultrafast charging and discharging
journal, March 2009
- Kang, Byoungwoo; Ceder, Gerbrand
- Nature, Vol. 458, Issue 7235, p. 190-193
Lithium Batteries and Cathode Materials
journal, October 2004
- Whittingham, M. Stanley
- Chemical Reviews, Vol. 104, Issue 10, p. 4271-4302
Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries
journal, September 2000
- Poizot, P.; Laruelle, S.; Grugeon, S.
- Nature, Vol. 407, Issue 6803, p. 496-499
In situ microscopic studies on the structural and chemical behaviors of lithium-ion battery materials
journal, December 2014
- Shao, Minhua
- Journal of Power Sources, Vol. 270
In Situ Observation of the Electrochemical Lithiation of a Single SnO2 Nanowire Electrode
journal, December 2010
- Huang, J. Y.; Zhong, L.; Wang, C. M.
- Science, Vol. 330, Issue 6010, p. 1515-1520
Lithium alloy negative electrodes formed from convertible oxides
journal, December 1998
- Huggins, R.
- Solid State Ionics, Vol. 113-115, Issue 1-2
Lithium alloy negative electrodes
journal, September 1999
- Huggins, Robert A.
- Journal of Power Sources, Vol. 81-82, p. 13-19
Behavior of Some Binary Lithium Alloys as Negative Electrodes in Organic Solvent-Based Electrolytes
journal, January 1986
- Wang, Jiqiang
- Journal of The Electrochemical Society, Vol. 133, Issue 3
Preparation of Si/Sn-Based Nanoparticles Composited with Carbon Fibers and Improved Electrochemical Performance as Anode Materials
journal, September 2014
- Wang, Haiying; Huang, Hongqin; Chen, Lin
- ACS Sustainable Chemistry & Engineering, Vol. 2, Issue 10
In situ transmission electron microscopy and spectroscopy studies of rechargeable batteries under dynamic operating conditions: A retrospective and perspective view
journal, October 2014
- Wang, Chong-Min
- Journal of Materials Research, Vol. 30, Issue 3
Li-alloy based anode materials for Li secondary batteries
journal, January 2010
- Park, Cheol-Min; Kim, Jae-Hun; Kim, Hansu
- Chemical Society Reviews, Vol. 39, Issue 8, p. 3115-3141
Lithium-Air Batteries: Survey on the Current Status and Perspectives Towards Automotive Applications from a Battery Industry Standpoint
journal, July 2012
- Park, Myounggu; Sun, Heeyoung; Lee, Hyungbok
- Advanced Energy Materials, Vol. 2, Issue 7
Properties of containing Sn nanoparticles activated carbon fiber for a negative electrode in lithium batteries
journal, April 2002
- Egashira, Minato; Takatsuji, Hideyasu; Okada, Shigeto
- Journal of Power Sources, Vol. 107, Issue 1
Size-Dependent Fracture of Silicon Nanoparticles During Lithiation
journal, January 2012
- Liu, Xiao Hua; Zhong, Li; Huang, Shan
- ACS Nano, Vol. 6, Issue 2
Tough Germanium Nanoparticles under Electrochemical Cycling
journal, March 2013
- Liang, Wentao; Yang, Hui; Fan, Feifei
- ACS Nano, Vol. 7, Issue 4
Facile synthesis of Sn/TiO2 nanowire array composites as superior lithium-ion battery anodes
journal, February 2013
- Wei, Zhen; Mao, Han; Huang, Tao
- Journal of Power Sources, Vol. 223
Ultrafast Electrochemical Lithiation of Individual Si Nanowire Anodes
journal, June 2011
- Liu, Xiao Hua; Zhang, Li Qiang; Zhong, Li
- Nano Letters, Vol. 11, Issue 6
Lithium Ion Battery Peformance of Silicon Nanowires with Carbon Skin
journal, December 2013
- Bogart, Timothy D.; Oka, Daichi; Lu, Xiaotang
- ACS Nano, Vol. 8, Issue 1
In Situ TEM of Two-Phase Lithiation of Amorphous Silicon Nanospheres
journal, January 2013
- McDowell, Matthew T.; Lee, Seok Woo; Harris, Justin T.
- Nano Letters, Vol. 13, Issue 2
In Situ TEM Study of Lithiation Behavior of Silicon Nanoparticles Attached to and Embedded in a Carbon Matrix
journal, August 2012
- Gu, Meng; Li, Ying; Li, Xiaolin
- ACS Nano, Vol. 6, Issue 9
In Situ Encapsulation of Germanium Clusters in Carbon Nanofibers: High-Performance Anodes for Lithium-Ion Batteries
journal, August 2014
- Wang, Wei; Xiao, Ying; Wang, Xia
- ChemSusChem, Vol. 7, Issue 10
Reversible Nanopore Formation in Ge Nanowires during Lithiation–Delithiation Cycling: An In Situ Transmission Electron Microscopy Study
journal, September 2011
- Liu, Xiao Hua; Huang, Shan; Picraux, S. Tom
- Nano Letters, Vol. 11, Issue 9
Tailoring Lithiation Behavior by Interface and Bandgap Engineering at the Nanoscale
journal, September 2013
- Liu, Yang; Liu, Xiao Hua; Nguyen, Binh-Minh
- Nano Letters, Vol. 13, Issue 10
Nanostructued core–shell Sn nanowires @ CNTs with controllable thickness of CNT shells for lithium ion battery
journal, March 2015
- Zhong, Yu; Li, Xifei; Zhang, Yong
- Applied Surface Science, Vol. 332
Facile preparation of Sn hollow nanospheres anodes for lithium-ion batteries by galvanic replacement
journal, August 2014
- Hou, Hongshuai; Tang, Xiaona; Guo, Meiqing
- Materials Letters, Vol. 128
The dimensionality of Sn anodes in Li-ion batteries
journal, December 2012
- Wang, Bin; Luo, Bin; Li, Xianglong
- Materials Today, Vol. 15, Issue 12
Nanoscale Materials for Lithium-Ion Batteries
journal, August 2002
- Sides, Charles R.; Li, Naichao; Patrissi, Charles J.
- MRS Bulletin, Vol. 27, Issue 8
Preparation and electrochemical properties of profiled carbon fiber-supported Sn anodes for lithium-ion batteries
journal, April 2015
- Bai, Xuejun; Wang, Biao; Wang, Huaping
- Journal of Alloys and Compounds, Vol. 628
Tin nanoparticle-loaded porous carbon nanofiber composite anodes for high current lithium-ion batteries
journal, March 2015
- Shen, Zhen; Hu, Yi; Chen, Yanli
- Journal of Power Sources, Vol. 278
One-pot In-situ Synthesis of Sn/Carbon-fibers Nanocomposite by Chemical Vapor Deposition and Its Li-storage Properties
journal, March 2012
- Xie, J.; Zheng, Yunxiao; Liu, Shuangyu
- Journal of Materials Science & Technology, Vol. 28, Issue 3
Tin Nanoparticles Encapsulated in Porous Multichannel Carbon Microtubes: Preparation by Single-Nozzle Electrospinning and Application as Anode Material for High-Performance Li-Based Batteries
journal, November 2009
- Yu, Yan; Gu, Lin; Zhu, Changbao
- Journal of the American Chemical Society, Vol. 131, Issue 44
Superior flexibility of a wrinkled carbon shell under electrochemical cycling
journal, January 2014
- Li, Qianqian; Wang, Peng; Feng, Qiong
- Journal of Materials Chemistry A, Vol. 2, Issue 12
Facile synthesis of core/shell-structured Sn/onion-like carbon nanocapsules as high-performance anode material for lithium-ion batteries
journal, March 2015
- Cui, Caiyun; Liu, Xianguo; Wu, Niandu
- Materials Letters, Vol. 143
Tandem plasma reactions for Sn/C composites with tunable structure and high reversible lithium storage capacity
journal, November 2013
- Li, Wei; Yang, Rong; Zheng, Jie
- Nano Energy, Vol. 2, Issue 6
The effects of electrospinning parameters on coaxial Sn/C nanofibers: Morphology and lithium storage performance
journal, March 2014
- Xia, Xin; Wang, Xin; Zhou, Huiming
- Electrochimica Acta, Vol. 121
Template-free electrochemical synthesis of tin nanostructures
journal, December 2013
- Mackay, David T.; Janish, Matthew T.; Sahaym, Uttara
- Journal of Materials Science, Vol. 49, Issue 4
Electrochemical lithiation of tin and tin-based intermetallics and composites
journal, September 1999
- Winter, Martin; Besenhard, Jürgen O.
- Electrochimica Acta, Vol. 45, Issue 1-2, p. 31-50
Structural Evolution and Pulverization of Tin Nanoparticles during Lithiation-Delithiation Cycling
journal, January 2014
- Wang, Jiangwei; Fan, Feifei; Liu, Yang
- Journal of The Electrochemical Society, Vol. 161, Issue 11
Li21Si5, a Zintl phase as well as a Hume-Rothery phase
journal, September 1987
- Nesper, Reinhard; von Schnering, Hans Georg
- Journal of Solid State Chemistry, Vol. 70, Issue 1
X-ray and Neutron Diffraction Studies on “Li 4.4 Sn”
journal, June 2003
- Lupu, Corina; Mao, Jiang-Gao; Rabalais, J. Wayne
- Inorganic Chemistry, Vol. 42, Issue 12
Vapor-liquid-solid mechanism of single crystal growth
journal, March 1964
- Wagner, R. S.; Ellis, W. C.
- Applied Physics Letters, Vol. 4, Issue 5, p. 89-90
Silicon Nanowires: A Review on Aspects of their Growth and their Electrical Properties
journal, June 2009
- Schmidt, Volker; Wittemann, Joerg V.; Senz, Stephan
- Advanced Materials, Vol. 21, Issue 25-26
Nanosprings
journal, September 2001
- McIlroy, D. N.; Zhang, D.; Kranov, Y.
- Applied Physics Letters, Vol. 79, Issue 10
One-dimensional ZnO nanostructures: fabrication, optoelectronic properties, and device applications
journal, June 2013
- Panda, Debashis; Tseng, Tseung-Yuen
- Journal of Materials Science, Vol. 48, Issue 20
Self-Catalytic Growth of Tin Oxide Nanowires by Chemical Vapor Deposition Process
journal, January 2013
- Thabethe, Bongani S.; Malgas, Gerald F.; Motaung, David E.
- Journal of Nanomaterials, Vol. 2013
High-performance lithium battery anodes using silicon nanowires
journal, December 2007
- Chan, Candace K.; Peng, Hailin; Liu, Gao
- Nature Nanotechnology, Vol. 3, Issue 1, p. 31-35
VLS-growth of carbon nanotubes from the vapor
journal, January 2000
- Kukovitsky, E. F.; L'vov, S. G.; Sainov, N. A.
- Chemical Physics Letters, Vol. 317, Issue 1-2
Fabrication of single-crystal tin nanowires by hydraulic pressure injection
journal, December 2005
- Chen, Chien-Chon; Bisrat, Y.; Luo, Z. P.
- Nanotechnology, Vol. 17, Issue 2
Electrochemical fabrication of tin nanowires: A short review
journal, September 2008
- Djenizian, Thierry; Hanzu, Ilie; Eyraud, Marielle
- Comptes Rendus Chimie, Vol. 11, Issue 9
Advanced structures in electrodeposited tin base anodes for lithium ion batteries
journal, November 2007
- Zhao, Haipeng; Jiang, Changyin; He, Xiangming
- Electrochimica Acta, Vol. 52, Issue 28
On-chip lithium cells for electrical and structural characterization of single nanowire electrodes
journal, June 2014
- Subramanian, A.; Hudak, N. S.; Huang, J. Y.
- Nanotechnology, Vol. 25, Issue 26
Lithium Electrodeposition Dynamics in Aprotic Electrolyte Observed in Situ via Transmission Electron Microscopy
journal, February 2015
- Leenheer, Andrew J.; Jungjohann, Katherine L.; Zavadil, Kevin R.
- ACS Nano, Vol. 9, Issue 4
Works referencing / citing this record:
In Situ Transmission Electron Microscopy for Energy Materials and Devices
journal, June 2019
- Fan, Zheng; Zhang, Liqiang; Baumann, Daniel
- Advanced Materials, Vol. 31, Issue 33
In Situ Transmission Electron Microscopy
book, January 2019
- Ross, Frances M.; Minor, Andrew M.
- Springer Handbook of Microscopy
Preface to the 50th anniversary issue of the Journal of Materials Science
journal, October 2015
- Aindow, Mark
- Journal of Materials Science, Vol. 51, Issue 1
In Situ Transmission Electron Microscopy Studies of Electrochemical Reaction Mechanisms in Rechargeable Batteries
journal, June 2019
- Wu, Xiaoyu; Li, Songmei; Yang, Bin
- Electrochemical Energy Reviews, Vol. 2, Issue 3
Understanding materials challenges for rechargeable ion batteries with in situ transmission electron microscopy
journal, August 2017
- Yuan, Yifei; Amine, Khalil; Lu, Jun
- Nature Communications, Vol. 8, Issue 1
Review—Promises and Challenges of In Situ Transmission Electron Microscopy Electrochemical Techniques in the Studies of Lithium Ion Batteries
journal, January 2017
- Xie, Zhi-Hui; Jiang, Zimin; Zhang, Xueyuan
- Journal of The Electrochemical Society, Vol. 164, Issue 9