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Title: Kinetics of the B1-B2 phase transition in KCl under rapid compression

Abstract

Kinetics of the B1-B2 phase transition in KCl has been investigated under various compression rates (0.03–13.5 GPa/s) in a dynamic diamond anvil cell using time-resolved x-ray diffraction and fast imaging. Our experimental data show that the volume fraction across the transition generally gives sigmoidal curves as a function of pressure during rapid compression. Based upon classical nucleation and growth theories (Johnson-Mehl-Avrami-Kolmogorov theories), we propose a model that is applicable for studying kinetics for the compression rates studied. The fit of the experimental volume fraction as a function of pressure provides information on effective activation energy and average activation volume at a given compression rate. The resulting parameters are successfully used for interpreting several experimental observables that are compression-rate dependent, such as the transition time, grain size, and over-pressurization. The effective activation energy (Qeff) is found to decrease linearly with the logarithm of compression rate. When Qeff is applied to the Arrhenius equation, this relationship can be used to interpret the experimentally observed linear relationship between the logarithm of the transition time and logarithm of the compression rates. The decrease of Qeff with increasing compression rate results in the decrease of the nucleation rate, which is qualitatively in agreement with themore » observed change of the grain size with compression rate. In conclusion, the observed over-pressurization is also well explained by the model when an exponential relationship between the average activation volume and the compression rate is assumed.« less

Authors:
 [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1]
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  1. Carnegie Inst. of Washington, Argonne, IL (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS); Carnegie Inst. of Science, Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1237736
Alternate Identifier(s):
OSTI ID: 1236399
Grant/Contract Number:  
AC02-06CH11357; NA0001974; FG02-99ER45775
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Applied Physics
Additional Journal Information:
Journal Volume: 119; Journal Issue: 4; Journal ID: ISSN 0021-8979
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
ENGLISH
Subject:
36 MATERIALS SCIENCE; 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS

Citation Formats

Lin, Chuanlong, Smith, Jesse S., Sinogeikin, Stanislav V., Park, Changyong, Kono, Yoshio, Kenney-Benson, Curtis, Rod, Eric, and Shen, Guoyin. Kinetics of the B1-B2 phase transition in KCl under rapid compression. United States: N. p., 2016. Web. doi:10.1063/1.4940771.
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Lin, Chuanlong, Smith, Jesse S., Sinogeikin, Stanislav V., Park, Changyong, Kono, Yoshio, Kenney-Benson, Curtis, Rod, Eric, & Shen, Guoyin. Kinetics of the B1-B2 phase transition in KCl under rapid compression. United States. https://doi.org/10.1063/1.4940771
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Lin, Chuanlong, Smith, Jesse S., Sinogeikin, Stanislav V., Park, Changyong, Kono, Yoshio, Kenney-Benson, Curtis, Rod, Eric, and Shen, Guoyin. Thu . "Kinetics of the B1-B2 phase transition in KCl under rapid compression". United States. https://doi.org/10.1063/1.4940771. https://www.osti.gov/servlets/purl/1237736.
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@article{osti_1237736,
title = {Kinetics of the B1-B2 phase transition in KCl under rapid compression},
author = {Lin, Chuanlong and Smith, Jesse S. and Sinogeikin, Stanislav V. and Park, Changyong and Kono, Yoshio and Kenney-Benson, Curtis and Rod, Eric and Shen, Guoyin},
abstractNote = {Kinetics of the B1-B2 phase transition in KCl has been investigated under various compression rates (0.03–13.5 GPa/s) in a dynamic diamond anvil cell using time-resolved x-ray diffraction and fast imaging. Our experimental data show that the volume fraction across the transition generally gives sigmoidal curves as a function of pressure during rapid compression. Based upon classical nucleation and growth theories (Johnson-Mehl-Avrami-Kolmogorov theories), we propose a model that is applicable for studying kinetics for the compression rates studied. The fit of the experimental volume fraction as a function of pressure provides information on effective activation energy and average activation volume at a given compression rate. The resulting parameters are successfully used for interpreting several experimental observables that are compression-rate dependent, such as the transition time, grain size, and over-pressurization. The effective activation energy (Qeff) is found to decrease linearly with the logarithm of compression rate. When Qeff is applied to the Arrhenius equation, this relationship can be used to interpret the experimentally observed linear relationship between the logarithm of the transition time and logarithm of the compression rates. The decrease of Qeff with increasing compression rate results in the decrease of the nucleation rate, which is qualitatively in agreement with the observed change of the grain size with compression rate. In conclusion, the observed over-pressurization is also well explained by the model when an exponential relationship between the average activation volume and the compression rate is assumed.},
doi = {10.1063/1.4940771},
journal = {Journal of Applied Physics},
number = 4,
volume = 119,
place = {United States},
year = {Thu Jan 28 00:00:00 EST 2016},
month = {Thu Jan 28 00:00:00 EST 2016}
}
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https://doi.org/10.1063/1.4940771
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    Works referencing / citing this record:

    Pressure-induced isosymmetric phase transition in biurea
    journal, January 2019

    • Bull, Craig L.; Funnell, Nicholas P.; Ridley, Christopher J.
    • CrystEngComm, Vol. 21, Issue 39
    • DOI: 10.1039/c9ce01028a

    New dynamic diamond anvil cells for tera-pascal per second fast compression x-ray diffraction experiments
    journal, June 2019

    • Jenei, Zs.; Liermann, H. P.; Husband, R.
    • Review of Scientific Instruments, Vol. 90, Issue 6
    • DOI: 10.1063/1.5098993

    High-pressure studies with x-rays using diamond anvil cells
    journal, November 2016

    New dynamic diamond anvil cells for tera-pascal per second fast compression x-ray diffraction experiments
    text, January 2019

    • Jenei, Zs.; Liermann, H. P.; Husband, R.
    • Deutsches Elektronen-Synchrotron, DESY, Hamburg
    • DOI: 10.3204/pubdb-2019-02611
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