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Title: Elevated temperature tribology of cobalt and tantalum-based alloys

This paper describes the friction and wear behavior of a Co–Cr alloy sliding on a Ta–W alloy. Measurements were performed in a pin-on-flat configuration with a hemispherically tipped Co-base alloy pin sliding on a Ta–W alloy flat from ambient to 430°C. Focused ion beam-scanning electron microscopy (FIB-SEM) and cross-sectional transmission electron microscopy (TEM) were used to identify the friction-induced changes to the chemistry and crystal structure in the subsurface regions of wear tracks. During sliding contact, transfer of material varied as a function of the test temperature, either from pin-to-flat, flat-to-pin, or both, resulting in either wear loss and/or volume gain. Friction coefficients (μ) and wear rates also varied as a function of test temperature. The lowest friction coefficient (μ=0.25) and wear rate (1×10–4 mm3/N•m) were observed at 430°C in argon atmosphere. This was attributed to the formation of a Co-base metal oxide layer (glaze), predominantly (Co, Cr)O with Rocksalt crystal structure, on the pin surface. Part of this oxide film transferred to the wear track on Ta–W, providing a self-mated oxide-on-oxide contact. Once the oxide glaze is formed, it is able to provide friction reduction for the entire temperature range of this study, ambient to 430°C. Furthermore, the resultsmore » of this study indicate that glazing the surfaces of Haynes alloys with continuous layers of cobalt chrome oxide prior to wear could protect the cladded surfaces from damage.« less
Authors:
 [1] ;  [2] ;  [2] ;  [2] ;  [2]
  1. Univ. of North Texas, Denton, TX (United States)
  2. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Publication Date:
OSTI Identifier:
1235348
Report Number(s):
SAND--2014-17398J
Journal ID: ISSN 0043-1648; PII: S0043164815000046
Grant/Contract Number:
AC04-94AL85000
Type:
Accepted Manuscript
Journal Name:
Wear
Additional Journal Information:
Journal Volume: 330-331; Journal Issue: C; Journal ID: ISSN 0043-1648
Research Org:
Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org:
USDOE National Nuclear Security Administration (NNSA)
Country of Publication:
United States
Language:
English
Subject:
sliding wear; high temperature wear; cobalt alloys; tantalum alloys; glaze layer