Mixed polyanion glass cathodes: Glass-state conversion reactions

Kercher, Andrew K.; Kolopus, James A.; Carroll, Kyler; Unocic, Raymond R.; Kirklin, S.; Wolverton, C.; Stooksbury, Shelby L.; Boatner, Lynn A.; Dudney, Nancy J.

doi:10.1149/2.0381602jes

Title: Mixed polyanion glass cathodes: Glass-state conversion reactions

Abstract

Mixed polyanion (MP) glasses can undergo glass-state conversion (GSC) reactions to provide an alternate class of high-capacity cathode materials. GSC reactions have been demonstrated in phosphate/vanadate glasses with Ag, Co, Cu, Fe, and Ni cations. These MP glasses provided high capacity and good high power performance, but suffer from moderate voltages, large voltage hysteresis, and significant capacity fade with cycling. Details of the GSC reaction have been revealed by x-ray absorption spectroscopy, electron microscopy, and energy dispersive x-ray spectroscopy of ex situ cathodes at key states of charge. Using the Open Quantum Materials Database (OQMD), a computational thermodynamic model has been developed to predict the near-equilibrium voltages of glass-state conversion reactions in MP glasses.

Authors:

Kercher, Andrew K. ^[1]; Kolopus, James A. ^[1]; Carroll, Kyler ^[2]; Unocic, Raymond R. ^[1]; Kirklin, S. ^[3]; Wolverton, C. ^[4];

^[1]; Boatner, Lynn A. ^[1]; Dudney, Nancy J. ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Wildcat Discovery Technologies, San Diego, CA (United States)
Northwestern Univ., Evanston, IL (United States)
Northwestern University, Evanston

Publication Date:: Tue Nov 10 00:00:00 EST 2015

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS); Energy Frontier Research Centers (EFRC) (United States). Center for Electrical Energy Storage (CEES)

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1234999

Grant/Contract Number:: AC05-00OR22725; AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Journal of the Electrochemical Society

Additional Journal Information:: Journal Volume: 163; Journal Issue: 2; Journal ID: ISSN 0013-4651

Publisher:: IOP Publishing - The Electrochemical Society

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; cathode conversion; glass; lithium; ion battery; phosphate; vanadate

Citation Formats


                    Kercher, Andrew K., Kolopus, James A., Carroll, Kyler, Unocic, Raymond R., Kirklin, S., Wolverton, C., Stooksbury, Shelby L., Boatner, Lynn A., and Dudney, Nancy J. Mixed polyanion glass cathodes: Glass-state conversion reactions.  United States: N. p., 2015. 
Web.  doi:10.1149/2.0381602jes.

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                    Kercher, Andrew K., Kolopus, James A., Carroll, Kyler, Unocic, Raymond R., Kirklin, S., Wolverton, C., Stooksbury, Shelby L., Boatner, Lynn A., & Dudney, Nancy J. Mixed polyanion glass cathodes: Glass-state conversion reactions.  United States.  https://doi.org/10.1149/2.0381602jes

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                    Kercher, Andrew K., Kolopus, James A., Carroll, Kyler, Unocic, Raymond R., Kirklin, S., Wolverton, C., Stooksbury, Shelby L., Boatner, Lynn A., and Dudney, Nancy J. Tue .  
"Mixed polyanion glass cathodes: Glass-state conversion reactions".  United States.  https://doi.org/10.1149/2.0381602jes.  https://www.osti.gov/servlets/purl/1234999.

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@article{osti_1234999,

  title        = {Mixed polyanion glass cathodes: Glass-state conversion reactions},

  author       = {Kercher, Andrew K. and Kolopus, James A. and Carroll, Kyler and Unocic, Raymond R. and Kirklin, S. and Wolverton, C. and Stooksbury, Shelby L. and Boatner, Lynn A. and Dudney, Nancy J.},

  abstractNote = {Mixed polyanion (MP) glasses can undergo glass-state conversion (GSC) reactions to provide an alternate class of high-capacity cathode materials. GSC reactions have been demonstrated in phosphate/vanadate glasses with Ag, Co, Cu, Fe, and Ni cations. These MP glasses provided high capacity and good high power performance, but suffer from moderate voltages, large voltage hysteresis, and significant capacity fade with cycling. Details of the GSC reaction have been revealed by x-ray absorption spectroscopy, electron microscopy, and energy dispersive x-ray spectroscopy of ex situ cathodes at key states of charge. Using the Open Quantum Materials Database (OQMD), a computational thermodynamic model has been developed to predict the near-equilibrium voltages of glass-state conversion reactions in MP glasses.},

  doi          = {10.1149/2.0381602jes},

  journal      = {Journal of the Electrochemical Society},

  number       = 2,

  volume       = 163,

  place        = {United States},

  year         = {Tue Nov 10 00:00:00 EST 2015},

  month        = {Tue Nov 10 00:00:00 EST 2015}

}

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Works referencing / citing this record:

A critical review-promises and barriers of conversion electrodes for Li-ion batteries
journal, April 2017

Kraytsberg, Alexander; Ein-Eli, Yair
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Title: Mixed polyanion glass cathodes: Glass-state conversion reactions

Abstract

Citation Formats

Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries journal, September 2000

Reversible Formation and Decomposition of LiF Clusters Using Transition Metal Fluorides as Precursors and Their Application in Rechargeable Li Batteries journal, May 2003

Materials Design and Discovery with High-Throughput Density Functional Theory: The Open Quantum Materials Database (OQMD) journal, September 2013

Formation of Iron Oxyfluoride Phase on the Surface of Nano-Fe 3 O 4 Conversion Compound for Electrochemical Energy Storage journal, October 2013

Pushing the Theoretical Limit of Li-CF x Batteries: A Tale of Bifunctional Electrolyte journal, April 2014

Building better batteries journal, February 2008

Carbon Metal Fluoride Nanocomposites: High-Capacity Reversible Metal Fluoride Conversion Materials as Rechargeable Positive Electrodes for Li Batteries journal, January 2003

Performance of Lithium-Ion Battery with Tin-Phosphate Glass Anode and Its Characteristics journal, January 2013

Beyond Intercalation-Based Li-Ion Batteries: The State of the Art and Challenges of Electrode Materials Reacting Through Conversion Reactions journal, August 2010

The Reduction of Silver Vanadium Oxide in Lithium/Silver Vanadium Oxide Cells journal, January 1988

Controlled Formation of Mixed Nanoscale Domains of High Capacity Fe 2 O 3 –FeF 3 Conversion Compounds by Direct Fluorination journal, February 2015

Electrochemical reaction of α-Cu2V2O7 with lithium in organic electrolyte journal, March 1989

Electrode architectures for high capacity multivalent conversion compounds: iron (ii and iii) fluoride journal, January 2014

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Synthesis and Electrochemical Properties of Amorphous Vanadates of General Formula RVO[sub 4] (R = In, Cr, Fe, Al, Y) vs. Li journal, January 1997

A critical review-promises and barriers of conversion electrodes for Li-ion batteries journal, April 2017

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journal, May 2003

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journal, October 2013

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journal, February 2008

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journal, January 2003

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journal, January 2013

Beyond Intercalation-Based Li-Ion Batteries: The State of the Art and Challenges of Electrode Materials Reacting Through Conversion Reactions
journal, August 2010

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journal, January 1988

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journal, February 2015

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journal, January 1997

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