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This content will become publicly available on October 2, 2016

Title: Cerium migration during PEM fuel cell assembly and operation

Cerium migration between PEM fuel cell components is influenced by potential-driven mobility, ionic diffusion, and gradients in water content. These factors were investigated in ex situ experiments and in operating fuel cells. Potential-induced migration was measured ex situ in hydrated window cells. Cerium-containing MEAs were also fabricated and tested under ASTs. MEA disassembly and subsequent XRF analysis were used to observe rapid cerium migration during cell assembly and operation. During MEA hot pressing, humidification, and low RH operation at OCV, ionic diffusion causes uniform migration from the membrane into the catalyst layers. During high RH operation at OCV, in-plane cerium gradients arise due to variations in water content. These gradients may diminish the scavenging efficacy of cerium by reducing its proximity to generated radicals.
Authors:
 [1] ;  [2] ;  [2] ;  [2] ;  [2] ;  [2] ;  [3] ;  [3]
  1. Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Univ. of Delaware, Newark, DE (United States)
  2. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
  3. Univ. of Delaware, Newark, DE (United States)
Publication Date:
OSTI Identifier:
1234248
Report Number(s):
LA-UR-15-25324
Journal ID: ISSN 1938-6737
Grant/Contract Number:
AC52-06NA25396
Type:
Accepted Manuscript
Journal Name:
ECS Transactions (Online)
Additional Journal Information:
Journal Name: ECS Transactions (Online); Journal Volume: 69; Journal Issue: 17; Journal ID: ISSN 1938-6737
Research Org:
Los Alamos National Laboratory (LANL)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
08 HYDROGEN Energy Sciences; Fuel Cell