Enhanced cryogenic magnetocaloric effect in Eu 8 Ga 16 Ge 30 clathrate nanocrystals

Biswas, Anis; Chandra, Sayan; Stefanoski, Stevce; Blázquez, J. S.; Ipus, J. J.; Conde, A.; Phan, M. H.; Franco, V.; Nolas, G. S.; Srikanth, H.

doi:10.1063/1.4906280

Title: Enhanced cryogenic magnetocaloric effect in Eu ₈ Ga ₁₆ Ge ₃₀ clathrate nanocrystals

Authors:

Biswas, Anis ^[1]; Chandra, Sayan ^[1]; Stefanoski, Stevce ^[1]; Blázquez, J. S. ^[2]; Ipus, J. J. ^[2]; Conde, A. ^[2]; Phan, M. H. ^[1]; Franco, V. ^[2]; Nolas, G. S. ^[1]; Srikanth, H. ^[1]

Department of Physics, University of South Florida, Tampa, Florida 33620, USA
Dpto. Física de Materia Condensada, ICMSE-CSIC, Universidad de Sevilla, Sevilla 41080, Spain

Publication Date:: Wed Jan 21 00:00:00 EST 2015

Sponsoring Org.:: USDOE

OSTI Identifier:: 1228498

Grant/Contract Number:: FG02-04ER46145; FG02-07ER46438

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Journal of Applied Physics

Additional Journal Information:: Journal Name: Journal of Applied Physics Journal Volume: 117 Journal Issue: 3; Journal ID: ISSN 0021-8979

Publisher:: American Institute of Physics

Country of Publication:: United States

Language:: English

Citation Formats


                    Biswas, Anis, Chandra, Sayan, Stefanoski, Stevce, Blázquez, J. S., Ipus, J. J., Conde, A., Phan, M. H., Franco, V., Nolas, G. S., and Srikanth, H. Enhanced cryogenic magnetocaloric effect in Eu 8 Ga 16 Ge 30 clathrate nanocrystals.  United States: N. p., 2015. 
Web.  doi:10.1063/1.4906280.

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                    Biswas, Anis, Chandra, Sayan, Stefanoski, Stevce, Blázquez, J. S., Ipus, J. J., Conde, A., Phan, M. H., Franco, V., Nolas, G. S., & Srikanth, H. Enhanced cryogenic magnetocaloric effect in Eu 8 Ga 16 Ge 30 clathrate nanocrystals.  United States.  https://doi.org/10.1063/1.4906280

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                    Biswas, Anis, Chandra, Sayan, Stefanoski, Stevce, Blázquez, J. S., Ipus, J. J., Conde, A., Phan, M. H., Franco, V., Nolas, G. S., and Srikanth, H. Wed .  
"Enhanced cryogenic magnetocaloric effect in Eu 8 Ga 16 Ge 30 clathrate nanocrystals".  United States.  https://doi.org/10.1063/1.4906280.

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@article{osti_1228498,

  title        = {Enhanced cryogenic magnetocaloric effect in Eu 8 Ga 16 Ge 30 clathrate nanocrystals},

  author       = {Biswas, Anis and Chandra, Sayan and Stefanoski, Stevce and Blázquez, J. S. and Ipus, J. J. and Conde, A. and Phan, M. H. and Franco, V. and Nolas, G. S. and Srikanth, H.},

  abstractNote = {},

  doi          = {10.1063/1.4906280},

  journal      = {Journal of Applied Physics},

  number       = 3,

  volume       = 117,

  place        = {United States},

  year         = {Wed Jan 21 00:00:00 EST 2015},

  month        = {Wed Jan 21 00:00:00 EST 2015}

}

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Works referenced in this record:

Review of the magnetocaloric effect in manganite materials
journal, January 2007

Phan, Manh-Huong; Yu, Seong-Cho
Journal of Magnetism and Magnetic Materials, Vol. 308, Issue 2
DOI: 10.1016/j.jmmm.2006.07.025

Anisotropic surface-state-mediated RKKY interaction between adatoms
journal, January 2012

Patrone, Paul N.; Einstein, T. L.
Physical Review B, Vol. 85, Issue 4
DOI: 10.1103/PhysRevB.85.045429

Long-range ferromagnetism and giant magnetocaloric effect in type VIII Eu8Ga16Ge30 clathrates
journal, December 2008

Phan, M. H.; Woods, G. T.; Chaturvedi, A.
Applied Physics Letters, Vol. 93, Issue 25
DOI: 10.1063/1.3055833

Spin dynamics and criteria for onset of exchange bias in superspin glass Fe/ $γ$ -Fe $_{2}$ O $_{3}$ core-shell nanoparticles
journal, July 2012

Chandra, Sayan; Khurshid, H.; Li, Wanfeng
Physical Review B, Vol. 86, Issue 1
DOI: 10.1103/PhysRevB.86.014426

Structural, magnetic, thermal, and transport properties of $X_{8} {Ga}_{16} {Ge}_{30}$ $(X = E u, S r, Ba)$ single crystals
journal, June 2001

Sales, B. C.; Chakoumakos, B. C.; Jin, R.
Physical Review B, Vol. 63, Issue 24
DOI: 10.1103/PhysRevB.63.245113

Large reversible magnetocaloric effect in antiferromagnetic HoNiSi compound
journal, December 2014

Zhang, Hu; Wu, YuanYuan; Long, Yi
Journal of Applied Physics, Vol. 116, Issue 21
DOI: 10.1063/1.4903052

Origin of the magnetic anomaly and tunneling effect of europium on the ferromagnetic ordering in ${Eu}_{8 - x} {Sr}_{x} {Ga}_{16} {Ge}_{30} (x = 0, 4)$ type-I clathrates
journal, August 2011

Phan, Manh-Huong; Franco, Victorino; Chaturvedi, Anurag
Physical Review B, Vol. 84, Issue 5
DOI: 10.1103/PhysRevB.84.054436

Magnetotransport properties of nanocrystalline Pr0.65(Ca1−ySry)0.35MnO3 (y∼0.4,0.3): Influence of phase coexistence
journal, July 2007

Biswas, Anis; Das, I.
Applied Physics Letters, Vol. 91, Issue 1
DOI: 10.1063/1.2753709

Synthesis and thermoelectric properties of type-VIII germanium clathrates Sr8AlxGayGe46−x−y
journal, April 2009

Sasaki, Yuta; Kishimoto, Kengo; Koyanagi, Tsuyoshi
Journal of Applied Physics, Vol. 105, Issue 7
DOI: 10.1063/1.3100205

Observation of large magnetocaloric effect in HoRu ₂ Si ₂
journal, February 2014

Paramanik, Tapas; Das, Kalipada; Samanta, Tapas
Journal of Applied Physics, Vol. 115, Issue 8
DOI: 10.1063/1.4867050

Magnetic structure and magnetocalorics of ${GdPO}_{4}$
journal, December 2014

Palacios, E.; Rodríguez-Velamazán, J. A.; Evangelisti, M.
Physical Review B, Vol. 90, Issue 21
DOI: 10.1103/PhysRevB.90.214423

Structural, transport, magnetic, and thermal properties of ${Eu}_{8} {Ga}_{16} {Ge}_{30}$
journal, November 2001

Paschen, S.; Carrillo-Cabrera, W.; Bentien, A.
Physical Review B, Vol. 64, Issue 21
DOI: 10.1103/PhysRevB.64.214404

Table-like magnetocaloric effect and enhanced refrigerant capacity in Eu ₈ Ga ₁₆ Ge ₃₀ -EuO composite materials
journal, October 2011

Chaturvedi, Anurag; Stefanoski, Stevce; Phan, Manh-Huong
Applied Physics Letters, Vol. 99, Issue 16
DOI: 10.1063/1.3654157

Surface Spin Disorder in ${NiFe}_{2} O_{4}$ Nanoparticles
journal, July 1996

Kodama, R. H.; Berkowitz, A. E.; McNiff, Jr., E. J.
Physical Review Letters, Vol. 77, Issue 2
DOI: 10.1103/PhysRevLett.77.394

Magnetocaloric effect in Ho5Pd2: Evidence of large cooling power
journal, August 2007

Samanta, Tapas; Das, I.; Banerjee, S.
Applied Physics Letters, Vol. 91, Issue 8
DOI: 10.1063/1.2775050

The Magnetocaloric Effect and Magnetic Refrigeration Near Room Temperature: Materials and Models
journal, August 2012

Franco, V.; Blázquez, J. S.; Ingale, B.
Annual Review of Materials Research, Vol. 42, Issue 1
DOI: 10.1146/annurev-matsci-062910-100356

Magnetic and electronic properties of ${Eu}_{4} {Sr}_{4} {Ga}_{16} {Ge}_{30}$
journal, May 2006

Woods, G. T.; Martin, J.; Beekman, M.
Physical Review B, Vol. 73, Issue 17
DOI: 10.1103/PhysRevB.73.174403

Magnetocaloric properties of nanocrystalline LaMnO3: Enhancement of refrigerant capacity and relative cooling power
journal, December 2012

Biswas, Anis; Chandra, Sayan; Phan, Manh-Huong
Journal of Alloys and Compounds, Vol. 545
DOI: 10.1016/j.jallcom.2012.08.001

Short-range ferromagnetism and spin-glass state in $Y_{0.7} {Ca}_{0.3} {MnO}_{3}$
journal, March 2001

Mathieu, R.; Nordblad, P.; Nam, D. N. H.
Physical Review B, Vol. 63, Issue 17
DOI: 10.1103/PhysRevB.63.174405

On Variance as a Measure of Line Broadening in Diffractometry General Theory and Small Particle Size
journal, July 1962

Wilson, A. J. C.
Proceedings of the Physical Society, Vol. 80, Issue 1
DOI: 10.1088/0370-1328/80/1/333

Magnetocaloric properties of nanocrystalline Pr0.65(Ca0.6Sr0.4)0.35MnO3
journal, January 2008

Biswas, Anis; Samanta, Tapas; Banerjee, S.
Journal of Applied Physics, Vol. 103, Issue 1
DOI: 10.1063/1.2832431

Noncollinear Spin Arrangement in Ultrafine Ferrimagnetic Crystallites
journal, October 1971

Coey, J. M. D.
Physical Review Letters, Vol. 27, Issue 17
DOI: 10.1103/PhysRevLett.27.1140

Modification of the charge ordering in Pr1∕2Sr1∕2MnO3 nanoparticles
journal, December 2005

Biswas, Anis; Das, I.; Majumdar, Chandan
Journal of Applied Physics, Vol. 98, Issue 12
DOI: 10.1063/1.2146074

Direct Measurement of the “Giant” Adiabatic Temperature Change in ${Gd}_{5} {Si}_{2} {Ge}_{2}$
journal, September 1999

Giguère, A.; Foldeaki, M.; Ravi Gopal, B.
Physical Review Letters, Vol. 83, Issue 11
DOI: 10.1103/PhysRevLett.83.2262

Magnetic Transition and Large Magnetocaloric Effect Associated with Surface Spin Disorder in Co and Co _core Ag _shell Nanoparticles
journal, September 2007

Poddar, P.; Srinath, S.; Gass, J.
The Journal of Physical Chemistry C, Vol. 111, Issue 38
DOI: 10.1021/jp073274i

Semiconducting Ge clathrates: Promising candidates for thermoelectric applications
journal, July 1998

Nolas, G. S.; Cohn, J. L.; Slack, G. A.
Applied Physics Letters, Vol. 73, Issue 2
DOI: 10.1063/1.121747

Optimization of the thermoelectric properties of Ba8Ga16Ge30
journal, June 2008

Martin, J.; Wang, H.; Nolas, G. S.
Applied Physics Letters, Vol. 92, Issue 22
DOI: 10.1063/1.2939438

Interparticle interaction and crossover in critical lines on field-temperature plane in ${Pr}_{0.5} {Sr}_{0.5} {MnO}_{3}$ nanoparticles
journal, September 2010

Pramanik, A. K.; Banerjee, A.
Physical Review B, Vol. 82, Issue 9
DOI: 10.1103/PhysRevB.82.094402

Recent developments in magnetocaloric materials
journal, May 2005

Gschneidner, K. A.; Pecharsky, V. K.; Tsokol, A. O.
Reports on Progress in Physics, Vol. 68, Issue 6, p. 1479-1539
DOI: 10.1088/0034-4885/68/6/R04

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Similar Records

Title: Enhanced cryogenic magnetocaloric effect in Eu 8 Ga 16 Ge 30 clathrate nanocrystals

Citation Formats

Review of the magnetocaloric effect in manganite materials journal, January 2007

Anisotropic surface-state-mediated RKKY interaction between adatoms journal, January 2012

Long-range ferromagnetism and giant magnetocaloric effect in type VIII Eu8Ga16Ge30 clathrates journal, December 2008

Spin dynamics and criteria for onset of exchange bias in superspin glass Fe/ γ -Fe 2 O 3 core-shell nanoparticles journal, July 2012

Structural, magnetic, thermal, and transport properties of X 8 Ga 16 Ge 30 ( X = E u , S r , Ba ) single crystals journal, June 2001

Large reversible magnetocaloric effect in antiferromagnetic HoNiSi compound journal, December 2014

Origin of the magnetic anomaly and tunneling effect of europium on the ferromagnetic ordering in Eu 8 − x Sr x Ga 16 Ge 30 ( x = 0 , 4 ) type-I clathrates journal, August 2011

Magnetotransport properties of nanocrystalline Pr0.65(Ca1−ySry)0.35MnO3 (y∼0.4,0.3): Influence of phase coexistence journal, July 2007

Synthesis and thermoelectric properties of type-VIII germanium clathrates Sr8AlxGayGe46−x−y journal, April 2009

Observation of large magnetocaloric effect in HoRu 2 Si 2 journal, February 2014

Magnetic structure and magnetocalorics of GdPO 4 journal, December 2014

Structural, transport, magnetic, and thermal properties of Eu 8 Ga 16 Ge 30 journal, November 2001

Table-like magnetocaloric effect and enhanced refrigerant capacity in Eu 8 Ga 16 Ge 30 -EuO composite materials journal, October 2011

Surface Spin Disorder in NiFe 2 O 4 Nanoparticles journal, July 1996

Magnetocaloric effect in Ho5Pd2: Evidence of large cooling power journal, August 2007

The Magnetocaloric Effect and Magnetic Refrigeration Near Room Temperature: Materials and Models journal, August 2012

Magnetic and electronic properties of Eu 4 Sr 4 Ga 16 Ge 30 journal, May 2006

Magnetocaloric properties of nanocrystalline LaMnO3: Enhancement of refrigerant capacity and relative cooling power journal, December 2012

Short-range ferromagnetism and spin-glass state in Y 0.7 Ca 0.3 MnO 3 journal, March 2001

On Variance as a Measure of Line Broadening in Diffractometry General Theory and Small Particle Size journal, July 1962

Magnetocaloric properties of nanocrystalline Pr0.65(Ca0.6Sr0.4)0.35MnO3 journal, January 2008

Noncollinear Spin Arrangement in Ultrafine Ferrimagnetic Crystallites journal, October 1971

Modification of the charge ordering in Pr1∕2Sr1∕2MnO3 nanoparticles journal, December 2005

Direct Measurement of the “Giant” Adiabatic Temperature Change in Gd 5 Si 2 Ge 2 journal, September 1999

Magnetic Transition and Large Magnetocaloric Effect Associated with Surface Spin Disorder in Co and Co core Ag shell Nanoparticles journal, September 2007

Semiconducting Ge clathrates: Promising candidates for thermoelectric applications journal, July 1998

Optimization of the thermoelectric properties of Ba8Ga16Ge30 journal, June 2008

Interparticle interaction and crossover in critical lines on field-temperature plane in Pr 0.5 Sr 0.5 MnO 3 nanoparticles journal, September 2010

Recent developments in magnetocaloric materials journal, May 2005

Title: Enhanced cryogenic magnetocaloric effect in Eu ₈ Ga ₁₆ Ge ₃₀ clathrate nanocrystals

Review of the magnetocaloric effect in manganite materials
journal, January 2007

Anisotropic surface-state-mediated RKKY interaction between adatoms
journal, January 2012

Long-range ferromagnetism and giant magnetocaloric effect in type VIII Eu8Ga16Ge30 clathrates
journal, December 2008

Spin dynamics and criteria for onset of exchange bias in superspin glass Fe/ $γ$ -Fe $_{2}$ O $_{3}$ core-shell nanoparticles
journal, July 2012

Structural, magnetic, thermal, and transport properties of $X_{8} {Ga}_{16} {Ge}_{30}$ $(X = E u, S r, Ba)$ single crystals
journal, June 2001

Large reversible magnetocaloric effect in antiferromagnetic HoNiSi compound
journal, December 2014

Origin of the magnetic anomaly and tunneling effect of europium on the ferromagnetic ordering in ${Eu}_{8 - x} {Sr}_{x} {Ga}_{16} {Ge}_{30} (x = 0, 4)$ type-I clathrates
journal, August 2011

Magnetotransport properties of nanocrystalline Pr0.65(Ca1−ySry)0.35MnO3 (y∼0.4,0.3): Influence of phase coexistence
journal, July 2007

Synthesis and thermoelectric properties of type-VIII germanium clathrates Sr8AlxGayGe46−x−y
journal, April 2009

Observation of large magnetocaloric effect in HoRu ₂ Si ₂
journal, February 2014

Magnetic structure and magnetocalorics of ${GdPO}_{4}$
journal, December 2014

Structural, transport, magnetic, and thermal properties of ${Eu}_{8} {Ga}_{16} {Ge}_{30}$
journal, November 2001

Table-like magnetocaloric effect and enhanced refrigerant capacity in Eu ₈ Ga ₁₆ Ge ₃₀ -EuO composite materials
journal, October 2011

Surface Spin Disorder in ${NiFe}_{2} O_{4}$ Nanoparticles
journal, July 1996

Magnetocaloric effect in Ho5Pd2: Evidence of large cooling power
journal, August 2007

The Magnetocaloric Effect and Magnetic Refrigeration Near Room Temperature: Materials and Models
journal, August 2012

Magnetic and electronic properties of ${Eu}_{4} {Sr}_{4} {Ga}_{16} {Ge}_{30}$
journal, May 2006

Magnetocaloric properties of nanocrystalline LaMnO3: Enhancement of refrigerant capacity and relative cooling power
journal, December 2012

Short-range ferromagnetism and spin-glass state in $Y_{0.7} {Ca}_{0.3} {MnO}_{3}$
journal, March 2001

On Variance as a Measure of Line Broadening in Diffractometry General Theory and Small Particle Size
journal, July 1962

Magnetocaloric properties of nanocrystalline Pr0.65(Ca0.6Sr0.4)0.35MnO3
journal, January 2008

Noncollinear Spin Arrangement in Ultrafine Ferrimagnetic Crystallites
journal, October 1971

Modification of the charge ordering in Pr1∕2Sr1∕2MnO3 nanoparticles
journal, December 2005

Direct Measurement of the “Giant” Adiabatic Temperature Change in ${Gd}_{5} {Si}_{2} {Ge}_{2}$
journal, September 1999

Magnetic Transition and Large Magnetocaloric Effect Associated with Surface Spin Disorder in Co and Co _core Ag _shell Nanoparticles
journal, September 2007

Semiconducting Ge clathrates: Promising candidates for thermoelectric applications
journal, July 1998

Optimization of the thermoelectric properties of Ba8Ga16Ge30
journal, June 2008

Interparticle interaction and crossover in critical lines on field-temperature plane in ${Pr}_{0.5} {Sr}_{0.5} {MnO}_{3}$ nanoparticles
journal, September 2010

Recent developments in magnetocaloric materials
journal, May 2005