Anisotropic small-polaron hopping in W:BiVO4 single crystals

Rettie, Alexander J. E.; Chemelewski, William D.; Lindemuth, Jeffrey; McCloy, John S.; Marshall, Luke G.; Zhou, Jianshi; Emin, David; Mullins, C. Buddie

doi:10.1063/1.4905786

Title: Anisotropic small-polaron hopping in W:BiVO4 single crystals

Authors:

Rettie, Alexander J. E. ^[1]; Chemelewski, William D. ^[2];

^[3];

^[4]; Marshall, Luke G. ^[5]; Zhou, Jianshi ^[2]; Emin, David ^[6]; Mullins, C. Buddie ^[7]

McKetta Department of Chemical Engineering, The University of Texas at Austin, Austin, Texas 78712, USA
Texas Materials Institute, The University of Texas at Austin, Austin, Texas 78712, USA
Lake Shore Cryotronics, Westerville, Ohio 43081, USA
School of Mechanical and Materials Engineering, Washington State University, Pullman, Washington 99164, USA, Materials Science and Engineering Program, Washington State University, Pullman, Washington 99164, USA
Texas Materials Institute, The University of Texas at Austin, Austin, Texas 78712, USA, Department of Chemical Engineering, Northeastern University, Boston, Massachusetts 02115, USA
Department of Physics and Astronomy, The University of New Mexico, Albuquerque, New Mexico 87131, USA
McKetta Department of Chemical Engineering, The University of Texas at Austin, Austin, Texas 78712, USA, Texas Materials Institute, The University of Texas at Austin, Austin, Texas 78712, USA, Department of Chemistry, The University of Texas at Austin, Austin, Texas 78712, USA

Publication Date:: Mon Jan 12 00:00:00 EST 2015

Sponsoring Org.:: USDOE

OSTI Identifier:: 1226686

Grant/Contract Number:: FG02-09ER16119

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Applied Physics Letters

Additional Journal Information:: Journal Name: Applied Physics Letters Journal Volume: 106 Journal Issue: 2; Journal ID: ISSN 0003-6951

Publisher:: American Institute of Physics

Country of Publication:: United States

Language:: English

Citation Formats


                    Rettie, Alexander J. E., Chemelewski, William D., Lindemuth, Jeffrey, McCloy, John S., Marshall, Luke G., Zhou, Jianshi, Emin, David, and Mullins, C. Buddie. Anisotropic small-polaron hopping in W:BiVO4 single crystals.  United States: N. p., 2015. 
Web.  doi:10.1063/1.4905786.

Copy to clipboard


                    Rettie, Alexander J. E., Chemelewski, William D., Lindemuth, Jeffrey, McCloy, John S., Marshall, Luke G., Zhou, Jianshi, Emin, David, & Mullins, C. Buddie. Anisotropic small-polaron hopping in W:BiVO4 single crystals.  United States.  https://doi.org/10.1063/1.4905786

Copy to clipboard


                    Rettie, Alexander J. E., Chemelewski, William D., Lindemuth, Jeffrey, McCloy, John S., Marshall, Luke G., Zhou, Jianshi, Emin, David, and Mullins, C. Buddie. Mon .  
"Anisotropic small-polaron hopping in W:BiVO4 single crystals".  United States.  https://doi.org/10.1063/1.4905786.

Copy to clipboard


                    
@article{osti_1226686,

  title        = {Anisotropic small-polaron hopping in W:BiVO4 single crystals},

  author       = {Rettie, Alexander J. E. and Chemelewski, William D. and Lindemuth, Jeffrey and McCloy, John S. and Marshall, Luke G. and Zhou, Jianshi and Emin, David and Mullins, C. Buddie},

  abstractNote = {},

  doi          = {10.1063/1.4905786},

  journal      = {Applied Physics Letters},

  number       = 2,

  volume       = 106,

  place        = {United States},

  year         = {Mon Jan 12 00:00:00 EST 2015},

  month        = {Mon Jan 12 00:00:00 EST 2015}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
https://doi.org/10.1063/1.4905786

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 60 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

New nonstoichiometric molybdate, tungstate, and vanadate catalysts with the scheelite-type structure
journal, March 1975

Sleight, A. W.; Aykan, K.; Rogers, D. B.
Journal of Solid State Chemistry, Vol. 13, Issue 3
DOI: 10.1016/0022-4596(75)90124-3

The Origin of Slow Carrier Transport in BiVO ₄ Thin Film Photoanodes: A Time-Resolved Microwave Conductivity Study
journal, July 2013

Abdi, Fatwa F.; Savenije, Tom J.; May, Matthias M.
The Journal of Physical Chemistry Letters, Vol. 4, Issue 16
DOI: 10.1021/jz4013257

Incorporation of Mo and W into nanostructured BiVO4 films for efficient photoelectrochemical water oxidation
journal, January 2012

Berglund, Sean P.; Rettie, Alexander J. E.; Hoang, Son
Physical Chemistry Chemical Physics, Vol. 14, Issue 19
DOI: 10.1039/c2cp40807d

Non-adiabatic small polaron hopping in the n = 3 Ruddlesden–Popper compound Ca ₄ Mn ₃ O ₁₀
journal, September 2003

Lago, J.; Battle, P. D.; Rosseinsky, M. J.
Journal of Physics: Condensed Matter, Vol. 15, Issue 40
DOI: 10.1088/0953-8984/15/40/018

The application of small polaron theory to transition metal oxide glasses
journal, October 1983

Sayer, M.; Mansingh, A.
Journal of Non-Crystalline Solids, Vol. 58, Issue 1
DOI: 10.1016/0022-3093(83)90105-9

Transport properties of amorphous antimony telluride
journal, April 2006

Baily, S. A.; Emin, David
Physical Review B, Vol. 73, Issue 16
DOI: 10.1103/PhysRevB.73.165211

The hall mobility of a small polaron in a square lattice
journal, June 1971

Emin, David
Annals of Physics, Vol. 64, Issue 2
DOI: 10.1016/0003-4916(71)90109-6

Factors in the Metal Doping of BiVO ₄ for Improved Photoelectrocatalytic Activity as Studied by Scanning Electrochemical Microscopy and First-Principles Density-Functional Calculation
journal, August 2011

Park, Hyun S.; Kweon, Kyoung Eun; Ye, Heechang
The Journal of Physical Chemistry C, Vol. 115, Issue 36
DOI: 10.1021/jp204492r

Small Polarons in Dry DNA
journal, September 2003

Alexandre, Simone S.; Artacho, Emilio; Soler, José M.
Physical Review Letters, Vol. 91, Issue 10
DOI: 10.1103/PhysRevLett.91.108105

Electrical Conduction through Poly(dA)-Poly(dT) and Poly(dG)-Poly(dC) DNA Molecules
journal, October 2001

Yoo, K. -H.; Ha, D. H.; Lee, J. -O.
Physical Review Letters, Vol. 87, Issue 19
DOI: 10.1103/PhysRevLett.87.198102

VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data
journal, October 2011

Momma, Koichi; Izumi, Fujio
Journal of Applied Crystallography, Vol. 44, Issue 6
DOI: 10.1107/S0021889811038970

Optical properties of large and small polarons and bipolarons
journal, November 1993

Emin, David
Physical Review B, Vol. 48, Issue 18
DOI: 10.1103/PhysRevB.48.13691

Efficient solar water splitting by enhanced charge separation in a bismuth vanadate-silicon tandem photoelectrode
journal, July 2013

Abdi, Fatwa F.; Han, Lihao; Smets, Arno H. M.
Nature Communications, Vol. 4, Issue 1
DOI: 10.1038/ncomms3195

Hall-Effect Sign Anomaly and Small-Polaron Conduction in $({La}_{1 - x} {Gd}_{x})_{0.67} {Ca}_{0.33} {MnO}_{3}$
journal, February 1997

Jaime, M.; Hardner, H. T.; Salamon, M. B.
Physical Review Letters, Vol. 78, Issue 5
DOI: 10.1103/PhysRevLett.78.951

Crystal growth and structure of BiVO4
journal, December 1979

Sleight, A. W.; Chen, H. -y.; Ferretti, A.
Materials Research Bulletin, Vol. 14, Issue 12
DOI: 10.1016/0025-5408(72)90227-9

Studies of small-polaron motion IV. Adiabatic theory of the Hall effect
journal, July 1969

Emin, David; Holstein, T.
Annals of Physics, Vol. 53, Issue 3
DOI: 10.1016/0003-4916(69)90034-7

Nanoporous BiVO₄ Photoanodes with Dual-Layer Oxygen Evolution Catalysts for Solar Water Splitting
journal, February 2014

Kim, Tae Woo; Choi, Kyoung-Shin
Science, Vol. 343, Issue 6174, p. 990-994
DOI: 10.1126/science.1246913

Studies of polaron motion
journal, March 1963

Friedman, L.; Holstein, T.
Annals of Physics, Vol. 21, Issue 3
DOI: 10.1016/0003-4916(63)90130-1

Approaching disorder-free transport in high-mobility conjugated polymers
journal, November 2014

Venkateshvaran, Deepak; Nikolka, Mark; Sadhanala, Aditya
Nature, Vol. 515, Issue 7527
DOI: 10.1038/nature13854

Small-polaron versus band conduction in some transition-metal oxides
journal, January 1970

Bosman, A. J.; van Daal, H. J.
Advances in Physics, Vol. 19, Issue 77, p. 1-117
DOI: 10.1080/00018737000101071

Small-Polaron Hopping Motion in Some Chalcogenide Glasses
journal, March 1972

Emin, David; Seager, C. H.; Quinn, Rod K.
Physical Review Letters, Vol. 28, Issue 13
DOI: 10.1103/PhysRevLett.28.813

Band Edge Electronic Structure of BiVO ₄ : Elucidating the Role of the Bi s and V d Orbitals
journal, February 2009

Walsh, Aron; Yan, Yanfa; Huda, Muhammad N.
Chemistry of Materials, Vol. 21, Issue 3
DOI: 10.1021/cm802894z

Combined Charge Carrier Transport and Photoelectrochemical Characterization of BiVO ₄ Single Crystals: Intrinsic Behavior of a Complex Metal Oxide
journal, July 2013

Rettie, Alexander J. E.; Lee, Heung Chan; Marshall, Luke G.
Journal of the American Chemical Society, Vol. 135, Issue 30
DOI: 10.1021/ja405550k

Electrical transport properties of Ti-doped Fe $_{2}$ $O_{3}$ (0001) epitaxial films
journal, December 2011

Zhao, B.; Kaspar, T. C.; Droubay, T. C.
Physical Review B, Vol. 84, Issue 24
DOI: 10.1103/PhysRevB.84.245325

Electron small polarons and their transport in bismuth vanadate: a first principles study
journal, January 2015

Kweon, Kyoung E.; Hwang, Gyeong S.; Kim, Jinhan
Physical Chemistry Chemical Physics, Vol. 17, Issue 1
DOI: 10.1039/C4CP03666B

Similar Records in DOE PAGES and OSTI.GOV collections:

Anisotropic small-polaron hopping in W:BiVO{sub 4} single crystals

Journal Article Rettie, Alexander J. E. ; Chemelewski, William D. ; Zhou, Jianshi ; ... - Applied Physics Letters

DC electrical conductivity, Seebeck and Hall coefficients are measured between 300 and 450 K on single crystals of monoclinic bismuth vanadate that are doped n-type with 0.3% tungsten donors (W:BiVO{sub 4}). Strongly activated small-polaron hopping is implied by the activation energies of the Arrhenius conductivities (about 300 meV) greatly exceeding the energies characterizing the falls of the Seebeck coefficients' magnitudes with increasing temperature (about 50 meV). Small-polaron hopping is further evidenced by the measured Hall mobility in the ab-plane (10{sup −1 }cm{sup 2 }V{sup −1 }s{sup −1} at 300 K) being larger and much less strongly activated than the deduced drift mobility (about 5 × 10{sup −5 }cm{sup 2 }V{sup −1 }s{supmore »« less
https://doi.org/10.1063/1.4905786
Semiclassical small-polaron hopping in a generalized molecular-crystal model

Journal Article Emin, D - Physical Review, B: Condensed Matter; (USA)

The thermally activated rates for high-temperature adiabatic and nonadiabatic small-(bi)polaron hopping are calculated for a generalization of Holstein's molecular-crystal model. In the expanded model a carrier occupying a molecule is coupled to many molecular vibrational modes rather than to just the single vibrational mode envisioned in the original model. This generalization of the molecular-crystal model does not significantly affect the semiclassical small-(bi)polaron jump rates. In particular, for the generalized model the hopping activation energy becomes a sum of contributions associated with each of the vibrational modes to which the carrier is coupled. The vibrational frequency that is the preexponential factormore »« less
https://doi.org/10.1103/PhysRevB.43.11720
Role of polaron hopping in leakage current behavior of a SrTiO{sub 3} single crystal

Journal Article Cao, Y., E-mail: yxc238@psu.edu ; Randall, C. A. ; Chen, L. Q. ; ... - Journal of Applied Physics

We studied the ionic/electronic transport and resistance degradation behavior of dielectric oxides by solving the electrochemical transport equations. Here, we took into account the non-periodical boundary conditions for the transport equations using the Chebyshev collocation algorithm. A sandwiched Ni|SrTiO{sub 3}|Ni capacitor is considered as an example under the condition of 1.0 V, 1.0 μm thickness for SrTiO{sub 3} layer, and a temperature of 150 °C. The applied voltage resulted in the migration of ionic defects (oxygen vacancies) from anode towards cathode. The simulated electric potential profile at steady state is in good agreement with the recent experimental observation. We introduced the possibility ofmore »« less
https://doi.org/10.1063/1.4842836
Effect of epitaxial strain on small-polaron hopping conduction in Pr{sub 0.7}(Ca{sub 0.6}Sr{sub 0.4}){sub 0.3}MnO{sub 3} thin films

Journal Article Wang, Jing ; Hu, Feng-xia ; Zhao, Ying-ying ; ... - Applied Physics Letters

We investigated the epitaxial strain effect on the small-polaron hopping conduction properties in Pr{sub 0.7}(Ca,Sr){sub 0.3}MnO{sub 3} (PCSMO) films. An increase in the carrier localization, as evidenced by the enhancement of the small-polaron activation energy E{sub A} in the high temperature region, was obtained by increasing the epitaxial lattice strain in either the tensile or compressive strained film. Furthermore, it was found that the magnitude of E{sub A}, and thus the carrier localization, strongly depends on the sign of the lattice strain, which explains the diverse percolative transport behaviors in PCSMO films with different types of strains. Meanwhile, similar dependenciesmore »« less
https://doi.org/10.1063/1.4914970
Appearance of small polaron hopping conduction in iron modified cobalt lithium bismuth borate glasses

Journal Article Dahiya, M. S. ; Khasa, S., E-mail: skhasa@yahoo.com ; Yadav, Arti ; ... - AIP Conference Proceedings

Lithium bismuth borate glasses containing different amounts of cobalt and iron oxides having chemical composition xFe{sub 2}O{sub 3}•(20-x)CoO•30Li{sub 2}O•10Bi{sub 2}O{sub 3}•40B{sub 2}O{sub 3} (x = 0, 5, 10, 15 and 20 mol% abbreviated as CFLBB1-5 respectively) prepared via melt quench technique have been investigated for their dc electrical conductivity. The amorphous nature of prepared glasses has been confirmed through X-ray diffraction measurements. The dc electrical conductivity has been analyzed by applying Mott’s small polaron hopping model. Activation energies corresponding to lower and higher temperature region have been evaluated. The iron ion concentration (N), mean spacing between iron ions (R) and polaronmore »« less
https://doi.org/10.1063/1.4947850

Similar Records

Title: Anisotropic small-polaron hopping in W:BiVO4 single crystals

Citation Formats

New nonstoichiometric molybdate, tungstate, and vanadate catalysts with the scheelite-type structure journal, March 1975

The Origin of Slow Carrier Transport in BiVO 4 Thin Film Photoanodes: A Time-Resolved Microwave Conductivity Study journal, July 2013

Incorporation of Mo and W into nanostructured BiVO4 films for efficient photoelectrochemical water oxidation journal, January 2012

Non-adiabatic small polaron hopping in the n = 3 Ruddlesden–Popper compound Ca 4 Mn 3 O 10 journal, September 2003

The application of small polaron theory to transition metal oxide glasses journal, October 1983

Transport properties of amorphous antimony telluride journal, April 2006

The hall mobility of a small polaron in a square lattice journal, June 1971

Factors in the Metal Doping of BiVO 4 for Improved Photoelectrocatalytic Activity as Studied by Scanning Electrochemical Microscopy and First-Principles Density-Functional Calculation journal, August 2011

Small Polarons in Dry DNA journal, September 2003

Electrical Conduction through Poly(dA)-Poly(dT) and Poly(dG)-Poly(dC) DNA Molecules journal, October 2001

VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data journal, October 2011

Optical properties of large and small polarons and bipolarons journal, November 1993

Efficient solar water splitting by enhanced charge separation in a bismuth vanadate-silicon tandem photoelectrode journal, July 2013

Hall-Effect Sign Anomaly and Small-Polaron Conduction in ( La 1 − x Gd x ) 0.67 Ca 0.33 MnO 3 journal, February 1997

Crystal growth and structure of BiVO4 journal, December 1979

Studies of small-polaron motion IV. Adiabatic theory of the Hall effect journal, July 1969

Nanoporous BiVO4 Photoanodes with Dual-Layer Oxygen Evolution Catalysts for Solar Water Splitting journal, February 2014

Studies of polaron motion journal, March 1963

Approaching disorder-free transport in high-mobility conjugated polymers journal, November 2014

Small-polaron versus band conduction in some transition-metal oxides journal, January 1970

Small-Polaron Hopping Motion in Some Chalcogenide Glasses journal, March 1972

Band Edge Electronic Structure of BiVO 4 : Elucidating the Role of the Bi s and V d Orbitals journal, February 2009

Combined Charge Carrier Transport and Photoelectrochemical Characterization of BiVO 4 Single Crystals: Intrinsic Behavior of a Complex Metal Oxide journal, July 2013

Electrical transport properties of Ti-doped Fe 2 O 3 (0001) epitaxial films journal, December 2011

Electron small polarons and their transport in bismuth vanadate: a first principles study journal, January 2015

New nonstoichiometric molybdate, tungstate, and vanadate catalysts with the scheelite-type structure
journal, March 1975

The Origin of Slow Carrier Transport in BiVO ₄ Thin Film Photoanodes: A Time-Resolved Microwave Conductivity Study
journal, July 2013

Incorporation of Mo and W into nanostructured BiVO4 films for efficient photoelectrochemical water oxidation
journal, January 2012

Non-adiabatic small polaron hopping in the n = 3 Ruddlesden–Popper compound Ca ₄ Mn ₃ O ₁₀
journal, September 2003

The application of small polaron theory to transition metal oxide glasses
journal, October 1983

Transport properties of amorphous antimony telluride
journal, April 2006

The hall mobility of a small polaron in a square lattice
journal, June 1971

Factors in the Metal Doping of BiVO ₄ for Improved Photoelectrocatalytic Activity as Studied by Scanning Electrochemical Microscopy and First-Principles Density-Functional Calculation
journal, August 2011

Small Polarons in Dry DNA
journal, September 2003

Electrical Conduction through Poly(dA)-Poly(dT) and Poly(dG)-Poly(dC) DNA Molecules
journal, October 2001

VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data
journal, October 2011

Optical properties of large and small polarons and bipolarons
journal, November 1993

Efficient solar water splitting by enhanced charge separation in a bismuth vanadate-silicon tandem photoelectrode
journal, July 2013

Hall-Effect Sign Anomaly and Small-Polaron Conduction in $({La}_{1 - x} {Gd}_{x})_{0.67} {Ca}_{0.33} {MnO}_{3}$
journal, February 1997

Crystal growth and structure of BiVO4
journal, December 1979

Studies of small-polaron motion IV. Adiabatic theory of the Hall effect
journal, July 1969

Nanoporous BiVO₄ Photoanodes with Dual-Layer Oxygen Evolution Catalysts for Solar Water Splitting
journal, February 2014

Studies of polaron motion
journal, March 1963

Approaching disorder-free transport in high-mobility conjugated polymers
journal, November 2014

Small-polaron versus band conduction in some transition-metal oxides
journal, January 1970

Small-Polaron Hopping Motion in Some Chalcogenide Glasses
journal, March 1972

Band Edge Electronic Structure of BiVO ₄ : Elucidating the Role of the Bi s and V d Orbitals
journal, February 2009

Combined Charge Carrier Transport and Photoelectrochemical Characterization of BiVO ₄ Single Crystals: Intrinsic Behavior of a Complex Metal Oxide
journal, July 2013

Electrical transport properties of Ti-doped Fe $_{2}$ $O_{3}$ (0001) epitaxial films
journal, December 2011

Electron small polarons and their transport in bismuth vanadate: a first principles study
journal, January 2015