Local atomic structure of KxNa(1−x)NbO3 by total x-ray diffraction

Gupta, Shashaank; Petkov, Valeri; Priya, Shashank

doi:10.1063/1.4903512

Title: Local atomic structure of KxNa(1−x)NbO3 by total x-ray diffraction

Authors:

Gupta, Shashaank ^[1]; Petkov, Valeri ^[2]; Priya, Shashank ^[1]

Center for Energy Harvesting Materials and Systems (CEHMS), Virginia Tech, Blacksburg, Virginia 24061, USA
Department of Physics, Central Michigan University, Mount Pleasant, Michigan 48859, USA

Publication Date:: Mon Dec 08 00:00:00 EST 2014

Sponsoring Org.:: USDOE

OSTI Identifier:: 1226591

Grant/Contract Number:: FG02-07ER46480

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Applied Physics Letters

Additional Journal Information:: Journal Name: Applied Physics Letters Journal Volume: 105 Journal Issue: 23; Journal ID: ISSN 0003-6951

Publisher:: American Institute of Physics

Country of Publication:: United States

Language:: English

Citation Formats


                    Gupta, Shashaank, Petkov, Valeri, and Priya, Shashank. Local atomic structure of KxNa(1−x)NbO3 by total x-ray diffraction.  United States: N. p., 2014. 
Web.  doi:10.1063/1.4903512.

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                    Gupta, Shashaank, Petkov, Valeri, & Priya, Shashank. Local atomic structure of KxNa(1−x)NbO3 by total x-ray diffraction.  United States.  https://doi.org/10.1063/1.4903512

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                    Gupta, Shashaank, Petkov, Valeri, and Priya, Shashank. Mon .  
"Local atomic structure of KxNa(1−x)NbO3 by total x-ray diffraction".  United States.  https://doi.org/10.1063/1.4903512.

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@article{osti_1226591,

  title        = {Local atomic structure of KxNa(1−x)NbO3 by total x-ray diffraction},

  author       = {Gupta, Shashaank and Petkov, Valeri and Priya, Shashank},

  abstractNote = {},

  doi          = {10.1063/1.4903512},

  journal      = {Applied Physics Letters},

  number       = 23,

  volume       = 105,

  place        = {United States},

  year         = {Mon Dec 08 00:00:00 EST 2014},

  month        = {Mon Dec 08 00:00:00 EST 2014}

}

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Works referenced in this record:

Local structure of NaNbO $_{3}$ : A neutron scattering study
journal, July 2013

Jiang, Lu; Mitchell, D. C.; Dmowski, W.
Physical Review B, Vol. 88, Issue 1
DOI: 10.1103/PhysRevB.88.014105

Polarization Rotation via a Monoclinic Phase in the Piezoelectric 92% ${PbZn}_{1 / 3} {Nb}_{2 / 3} O_{3}$ -8% ${PbTiO}_{3}$
journal, April 2001

Noheda, B.; Cox, D. E.; Shirane, G.
Physical Review Letters, Vol. 86, Issue 17
DOI: 10.1103/PhysRevLett.86.3891

The high-temperature phases of sodium niobate and the nature of transitions in pseudosymmetric structures
journal, May 1966

Lefkowitz, I.; Łukaszewicz, K.; Megaw, H. D.
Acta Crystallographica, Vol. 20, Issue 5
DOI: 10.1107/S0365110X66001592

Monoclinic structure of unpoled morphotropic high piezoelectric PMN-PT and PZN-PT compounds
journal, January 2002

Kiat, Jean-Michel; Uesu, Yoshiaki; Dkhil, Brahim
Physical Review B, Vol. 65, Issue 6
DOI: 10.1103/PhysRevB.65.064106

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976

Shannon, R. D.
Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767
DOI: 10.1107/S0567739476001551

The structure of sodium niobate at room temperature, and the problem of reliability in pseudosymmetric structures
journal, May 1969

Sakowski-Cowley, A. C.; Łukaszewicz, K.; Megaw, H. D.
Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 25, Issue 5
DOI: 10.1107/S0567740869003141

Local structure of the lead-free relaxor ferroelectric ${(K_{x} {Na}_{1 - x})}_{0.5} {Bi}_{0.5} Ti O_{3}$
journal, May 2005

Shuvaeva, V. A.; Zekria, D.; Glazer, A. M.
Physical Review B, Vol. 71, Issue 17
DOI: 10.1103/PhysRevB.71.174114

A monoclinic ferroelectric phase in the Pb(Zr1−xTix)O3 solid solution
journal, April 1999

Noheda, B.; Cox, D. E.; Shirane, G.
Applied Physics Letters, Vol. 74, Issue 14
DOI: 10.1063/1.123756

Optical crystallographic study of piezoelectric KxNa1−xNbO3 (x = 0.4, 0.5 and 0.6) single crystals using linear birefringence
journal, January 2013

Gupta, Shashaank; Huband, Steven; Keeble, Dean S.
CrystEngComm, Vol. 15, Issue 34
DOI: 10.1039/c3ce40627j

Local Structures and Raman Spectra in the Ca(Zr,Ti)O ₃ Perovskite Solid Solutions
journal, February 2006

Levin, Igor; Cockayne, Eric; Lufaso, Michael W.
Chemistry of Materials, Vol. 18, Issue 3
DOI: 10.1021/cm0523438

Ferroelectric properties and dynamic scaling of ⟨100⟩ oriented (K0.5Na0.5)NbO3 single crystals
journal, June 2011

Gupta, Shashaank; Priya, Shashank
Applied Physics Letters, Vol. 98, Issue 24
DOI: 10.1063/1.3600058

Structural study of K _x Na _{1 − x} NbO ₃ (KNN) for compositions in the range x = 0.24–0.36
journal, December 2008

Baker, D. W.; Thomas, P. A.; Zhang, N.
Acta Crystallographica Section B Structural Science, Vol. 65, Issue 1
DOI: 10.1107/S0108768108037361

Crystal structure and phase transitions of sodium potassium niobate perovskites
journal, February 2009

Tellier, J.; Malic, B.; Dkhil, B.
Solid State Sciences, Vol. 11, Issue 2
DOI: 10.1016/j.solidstatesciences.2008.07.011

Influence of short-range and long-range order on the evolution of the morphotropic phase boundary in $Pb ({Zr}_{1 - x} {Ti}_{x}) O_{3}$
journal, November 2004

Glazer, A. M.; Thomas, P. A.; Baba-Kishi, K. Z.
Physical Review B, Vol. 70, Issue 18
DOI: 10.1103/PhysRevB.70.184123

Tetragonal-to-monoclinic phase transition in a ferroelectric perovskite: The structure of ${PbZr}_{0.52} {Ti}_{0.48} O_{3}$
journal, April 2000

Noheda, B.; Gonzalo, J. A.; Cross, L. E.
Physical Review B, Vol. 61, Issue 13
DOI: 10.1103/PhysRevB.61.8687

Local structure of ionic solid solutions: Extended x-ray-absorption fine-structure study
journal, May 1985

Boyce, J. B.; Mikkelsen, J. C.
Physical Review B, Vol. 31, Issue 10
DOI: 10.1103/PhysRevB.31.6903

Conformal Miniaturization of Domains with Low Domain-Wall Energy: Monoclinic Ferroelectric States near the Morphotropic Phase Boundaries
journal, November 2003

Jin, Y. M.; Wang, Y. U.; Khachaturyan, A. G.
Physical Review Letters, Vol. 91, Issue 19
DOI: 10.1103/PhysRevLett.91.197601

Competing antiferroelectric and ferroelectric interactions in $Na Nb O_{3}$ : Neutron diffraction and theoretical studies
journal, July 2007

Mishra, S. K.; Choudhury, N.; Chaplot, S. L.
Physical Review B, Vol. 76, Issue 2
DOI: 10.1103/PhysRevB.76.024110

Vegard’s law
journal, March 1991

Denton, A. R.; Ashcroft, N. W.
Physical Review A, Vol. 43, Issue 6
DOI: 10.1103/PhysRevA.43.3161

Electric-field-induced phase transitions in rhombohedral $Pb ({Zn}_{1 / 3} {Nb}_{2 / 3})_{1 - x} {Ti}_{x} O_{3}$
journal, May 2002

Noheda, B.; Zhong, Z.; Cox, D. E.
Physical Review B, Vol. 65, Issue 22
DOI: 10.1103/PhysRevB.65.224101

Stability of the monoclinic phase in the ferroelectric perovskite ${PbZr}_{1 - x} {Ti}_{x} O_{3}$
journal, December 2000

Noheda, B.; Cox, D. E.; Shirane, G.
Physical Review B, Vol. 63, Issue 1
DOI: 10.1103/PhysRevB.63.014103

Phase diagram of the ferroelectric relaxor $(1 - x) {PbMg}_{1 / 3} {Nb}_{2 / 3} O_{3} - x {PbTiO}_{3}$
journal, August 2002

Noheda, B.; Cox, D. E.; Shirane, G.
Physical Review B, Vol. 66, Issue 5
DOI: 10.1103/PhysRevB.66.054104

Dielectric Properties and Phase Transitions of NaNb $O_{3}$ and (Na,K)Nb $O_{3}$
journal, November 1954

Shirane, G.; Newnham, R.; Pepinsky, R.
Physical Review, Vol. 96, Issue 3
DOI: 10.1103/PhysRev.96.581

High Real-Space Resolution Measurement of the Local Structure of $Ga_{1 - x} In_{x} As$ Using X-Ray Diffraction
journal, November 1999

Petkov, V.; Jeong, I-K.; Chung, J. S.
Physical Review Letters, Vol. 83, Issue 20
DOI: 10.1103/PhysRevLett.83.4089

Structure and high-piezoelectricity in lead oxide solid solutions
journal, February 2002

Noheda, B.
Current Opinion in Solid State and Materials Science, Vol. 6, Issue 1
DOI: 10.1016/S1359-0286(02)00015-3

Phase diagram of the relaxor ferroelectric $(1 - x) {P b (Z n}_{1 / 3} {Nb}_{2 / 3}) O_{3} - x {PbTiO}_{3}$
journal, March 2002

La-Orauttapong, D.; Noheda, B.; Ye, Z. -G.
Physical Review B, Vol. 65, Issue 14
DOI: 10.1103/PhysRevB.65.144101

Symmetry-adaptive ferroelectric mesostates in oriented Pb(BI[sub 1/3]BII[sub 2/3])O[sub 3]–PbTiO[sub 3] crystals
journal, January 2000

Viehland, Dwight
Journal of Applied Physics, Vol. 88, Issue 8
DOI: 10.1063/1.1289789

Ferroelectricity in NaNbO ₃ : Revisited
journal, October 2010

Arioka, Takahiro; Taniguchi, Hiroki; Itoh, Mitsuru
Ferroelectrics, Vol. 401, Issue 1
DOI: 10.1080/00150191003670408

X-ray study and electrical properties of system BaxSr(1−x)MoO3
journal, August 1960

Brixner, L. H.
Journal of Inorganic and Nuclear Chemistry, Vol. 14, Issue 3-4
DOI: 10.1016/0022-1902(60)80262-X

Noncentrosymmetric phase of submicron NaNbO3 crystallites
journal, February 2007

Shiratori, Y.; Magrez, A.; Kasezawa, K.
Journal of Electroceramics, Vol. 19, Issue 4
DOI: 10.1007/s10832-007-9032-7

A comprehensive study of the phase diagram of KxNa1−xNbO3
journal, August 2009

Baker, D. W.; Thomas, P. A.; Zhang, N.
Applied Physics Letters, Vol. 95, Issue 9
DOI: 10.1063/1.3212861

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Title: Local atomic structure of KxNa(1−x)NbO3 by total x-ray diffraction

Citation Formats

Local structure of NaNbO 3 : A neutron scattering study journal, July 2013

Polarization Rotation via a Monoclinic Phase in the Piezoelectric 92% PbZn 1 / 3 Nb 2 / 3 O 3 -8% PbTiO 3 journal, April 2001

The high-temperature phases of sodium niobate and the nature of transitions in pseudosymmetric structures journal, May 1966

Monoclinic structure of unpoled morphotropic high piezoelectric PMN-PT and PZN-PT compounds journal, January 2002

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides journal, September 1976

The structure of sodium niobate at room temperature, and the problem of reliability in pseudosymmetric structures journal, May 1969

Local structure of the lead-free relaxor ferroelectric ( K x Na 1 − x ) 0.5 Bi 0.5 Ti O 3 journal, May 2005

A monoclinic ferroelectric phase in the Pb(Zr1−xTix)O3 solid solution journal, April 1999

Optical crystallographic study of piezoelectric KxNa1−xNbO3 (x = 0.4, 0.5 and 0.6) single crystals using linear birefringence journal, January 2013

Local Structures and Raman Spectra in the Ca(Zr,Ti)O 3 Perovskite Solid Solutions journal, February 2006

Ferroelectric properties and dynamic scaling of ⟨100⟩ oriented (K0.5Na0.5)NbO3 single crystals journal, June 2011

Structural study of K x Na 1 − x NbO 3 (KNN) for compositions in the range x = 0.24–0.36 journal, December 2008

Crystal structure and phase transitions of sodium potassium niobate perovskites journal, February 2009

Influence of short-range and long-range order on the evolution of the morphotropic phase boundary in Pb ( Zr 1 − x Ti x ) O 3 journal, November 2004

Tetragonal-to-monoclinic phase transition in a ferroelectric perovskite: The structure of PbZr 0.52 Ti 0.48 O 3 journal, April 2000

Local structure of ionic solid solutions: Extended x-ray-absorption fine-structure study journal, May 1985

Conformal Miniaturization of Domains with Low Domain-Wall Energy: Monoclinic Ferroelectric States near the Morphotropic Phase Boundaries journal, November 2003

Competing antiferroelectric and ferroelectric interactions in Na Nb O 3 : Neutron diffraction and theoretical studies journal, July 2007

Vegard’s law journal, March 1991

Electric-field-induced phase transitions in rhombohedral Pb ( Zn 1 / 3 Nb 2 / 3 ) 1 − x Ti x O 3 journal, May 2002

Stability of the monoclinic phase in the ferroelectric perovskite PbZr 1 − x Ti x O 3 journal, December 2000

Phase diagram of the ferroelectric relaxor ( 1 − x ) PbMg 1 / 3 Nb 2 / 3 O 3 − x PbTiO 3 journal, August 2002

Dielectric Properties and Phase Transitions of NaNb O 3 and (Na,K)Nb O 3 journal, November 1954

High Real-Space Resolution Measurement of the Local Structure of Ga 1 − x In x As Using X-Ray Diffraction journal, November 1999

Structure and high-piezoelectricity in lead oxide solid solutions journal, February 2002

Phase diagram of the relaxor ferroelectric ( 1 − x ) P b ( Z n 1 / 3 Nb 2 / 3 ) O 3 − x PbTiO 3 journal, March 2002

Symmetry-adaptive ferroelectric mesostates in oriented Pb(BI[sub 1/3]BII[sub 2/3])O[sub 3]–PbTiO[sub 3] crystals journal, January 2000

Ferroelectricity in NaNbO 3 : Revisited journal, October 2010

X-ray study and electrical properties of system BaxSr(1−x)MoO3 journal, August 1960

Noncentrosymmetric phase of submicron NaNbO3 crystallites journal, February 2007

A comprehensive study of the phase diagram of KxNa1−xNbO3 journal, August 2009

Local structure of NaNbO $_{3}$ : A neutron scattering study
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Polarization Rotation via a Monoclinic Phase in the Piezoelectric 92% ${PbZn}_{1 / 3} {Nb}_{2 / 3} O_{3}$ -8% ${PbTiO}_{3}$
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The high-temperature phases of sodium niobate and the nature of transitions in pseudosymmetric structures
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journal, January 2002

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976

The structure of sodium niobate at room temperature, and the problem of reliability in pseudosymmetric structures
journal, May 1969

Local structure of the lead-free relaxor ferroelectric ${(K_{x} {Na}_{1 - x})}_{0.5} {Bi}_{0.5} Ti O_{3}$
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A monoclinic ferroelectric phase in the Pb(Zr1−xTix)O3 solid solution
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Local structure of ionic solid solutions: Extended x-ray-absorption fine-structure study
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Conformal Miniaturization of Domains with Low Domain-Wall Energy: Monoclinic Ferroelectric States near the Morphotropic Phase Boundaries
journal, November 2003

Competing antiferroelectric and ferroelectric interactions in $Na Nb O_{3}$ : Neutron diffraction and theoretical studies
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Vegard’s law
journal, March 1991

Electric-field-induced phase transitions in rhombohedral $Pb ({Zn}_{1 / 3} {Nb}_{2 / 3})_{1 - x} {Ti}_{x} O_{3}$
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Stability of the monoclinic phase in the ferroelectric perovskite ${PbZr}_{1 - x} {Ti}_{x} O_{3}$
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Phase diagram of the ferroelectric relaxor $(1 - x) {PbMg}_{1 / 3} {Nb}_{2 / 3} O_{3} - x {PbTiO}_{3}$
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High Real-Space Resolution Measurement of the Local Structure of $Ga_{1 - x} In_{x} As$ Using X-Ray Diffraction
journal, November 1999

Structure and high-piezoelectricity in lead oxide solid solutions
journal, February 2002

Phase diagram of the relaxor ferroelectric $(1 - x) {P b (Z n}_{1 / 3} {Nb}_{2 / 3}) O_{3} - x {PbTiO}_{3}$
journal, March 2002

Symmetry-adaptive ferroelectric mesostates in oriented Pb(BI[sub 1/3]BII[sub 2/3])O[sub 3]–PbTiO[sub 3] crystals
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Ferroelectricity in NaNbO ₃ : Revisited
journal, October 2010

X-ray study and electrical properties of system BaxSr(1−x)MoO3
journal, August 1960

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