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Title: Expanding iClick to group 9 metals

In this study, the iClick (inorganic click) reactions between gold-acetylides and group 9 transition metal-azide complexes are presented. Complexes [Rh(CO)(PPh3)2][PPh3Au](μ-N3C2C6H4NO2) (3), {[Rh(CO)(PPh3)][PPh3Au](μ-N3C2C6H4NO2)}2 (4), and [(CO)(PPh3)2IrAuPPh3](μ-N3C2C6H4NO2) (6) have been synthesized via M-azide/M-acetylide cycloaddition reactions between PPh3Au(Ctriple bond; length of mdashCC6H4NO2) (2) and either Rh(CO)(PPh3)2N3 (1), or Ir(CO)(PPh3)2N3 (5). Complexes 3, 4, and 6 have been characterized by a combination of NMR spectroscopies, crystallography and combustion analysis.
Authors:
 [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [1]
  1. Univ. of Florida, Gainesville, FL (United States)
Publication Date:
OSTI Identifier:
1225602
Grant/Contract Number:
SC0010510
Type:
Accepted Manuscript
Journal Name:
Polyhedron
Additional Journal Information:
Journal Name: Polyhedron; Journal ID: ISSN 0277-5387
Publisher:
Elsevier
Research Org:
Univ. of Florida, Gainesville, FL (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY iClick; azide-alkyne cycloaddition; rhodium; iridium; heterobimetallic