Curvature-induced and thermal strain in polyhedral gold nanocrystals

Kim, J. W.; Manna, S.; Dietze, S. H.; Ulvestad, A.; Harder, R.; Fohtung, E.; Fullerton, E. E.; Shpyrko, O. G.

doi:10.1063/1.4900866

Title: Curvature-induced and thermal strain in polyhedral gold nanocrystals

Authors:

Kim, J. W. ^[1]; Manna, S. ^[2]; Dietze, S. H. ^[1]; Ulvestad, A. ^[1]; Harder, R. ^[3]; Fohtung, E. ^[1]; Fullerton, E. E. ^[2]; Shpyrko, O. G. ^[1]

Department of Physics, University of California-San Diego, La Jolla, California 92093-0319, USA
Center for Magnetic Recording Research, University of California-San Diego, La Jolla, California 92093-0401, USA
Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439, USA

Publication Date:: Wed Oct 29 00:00:00 EDT 2014

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1224260

Grant/Contract Number:: AC02-06CH11357; SC0001805

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Applied Physics Letters

Additional Journal Information:: Journal Name: Applied Physics Letters Journal Volume: 105 Journal Issue: 17; Journal ID: ISSN 0003-6951

Publisher:: American Institute of Physics

Country of Publication:: United States

Language:: English

Citation Formats


                    Kim, J. W., Manna, S., Dietze, S. H., Ulvestad, A., Harder, R., Fohtung, E., Fullerton, E. E., and Shpyrko, O. G. Curvature-induced and thermal strain in polyhedral gold nanocrystals.  United States: N. p., 2014. 
Web.  doi:10.1063/1.4900866.

Copy to clipboard


                    Kim, J. W., Manna, S., Dietze, S. H., Ulvestad, A., Harder, R., Fohtung, E., Fullerton, E. E., & Shpyrko, O. G. Curvature-induced and thermal strain in polyhedral gold nanocrystals.  United States.  https://doi.org/10.1063/1.4900866

Copy to clipboard


                    Kim, J. W., Manna, S., Dietze, S. H., Ulvestad, A., Harder, R., Fohtung, E., Fullerton, E. E., and Shpyrko, O. G. Wed .  
"Curvature-induced and thermal strain in polyhedral gold nanocrystals".  United States.  https://doi.org/10.1063/1.4900866.

Copy to clipboard


                    
@article{osti_1224260,

  title        = {Curvature-induced and thermal strain in polyhedral gold nanocrystals},

  author       = {Kim, J. W. and Manna, S. and Dietze, S. H. and Ulvestad, A. and Harder, R. and Fohtung, E. and Fullerton, E. E. and Shpyrko, O. G.},

  abstractNote = {},

  doi          = {10.1063/1.4900866},

  journal      = {Applied Physics Letters},

  number       = 17,

  volume       = 105,

  place        = {United States},

  year         = {Wed Oct 29 00:00:00 EDT 2014},

  month        = {Wed Oct 29 00:00:00 EDT 2014}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
https://doi.org/10.1063/1.4900866

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 15 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Nanoparticles with Raman Spectroscopic Fingerprints for DNA and RNA Detection
journal, August 2002

Cao, Y. C.
Science, Vol. 297, Issue 5586
DOI: 10.1126/science.297.5586.1536

Reaction of Oxygen with Si(111) and (100): Critical Conditions for the Growth of SiO[sub 2]
journal, January 1982

Smith, F. W.
Journal of The Electrochemical Society, Vol. 129, Issue 6
DOI: 10.1149/1.2124122

Partial coherence effects on the imaging of small crystals using coherent x-ray diffraction
journal, November 2001

Vartanyants, I. A.; Robinson, I. K.
Journal of Physics: Condensed Matter, Vol. 13, Issue 47
DOI: 10.1088/0953-8984/13/47/305

Coherent X-ray diffraction imaging of strain at the nanoscale
journal, April 2009

Robinson, Ian; Harder, Ross
Nature Materials, Vol. 8, Issue 4
DOI: 10.1038/nmat2400

The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment
journal, January 2003

Kelly, K. Lance; Coronado, Eduardo; Zhao, Lin Lin
The Journal of Physical Chemistry B, Vol. 107, Issue 3
DOI: 10.1021/jp026731y

Nanoparticle Structure by Coherent X-ray Diffraction
journal, February 2013

Robinson, Ian
Journal of the Physical Society of Japan, Vol. 82, Issue 2
DOI: 10.7566/JPSJ.82.021012

Extending the methodology of X-ray crystallography to allow imaging of micrometre-sized non-crystalline specimens
journal, July 1999

Miao, Jianwei; Charalambous, Pambos; Kirz, Janos
Nature, Vol. 400, Issue 6742
DOI: 10.1038/22498

Three-Dimensional Imaging of Microstructure in Au Nanocrystals
journal, April 2003

Williams, G. J.; Pfeifer, M. A.; Vartanyants, I. A.
Physical Review Letters, Vol. 90, Issue 17
DOI: 10.1103/PhysRevLett.90.175501

A Dynamical Theory of Diffraction for a Distorted Crystal
journal, May 1969

Takagi, Satio
Journal of the Physical Society of Japan, Vol. 26, Issue 5
DOI: 10.1143/JPSJ.26.1239

Surface stress of clean and adsorbate-covered solids
journal, May 2001

Haiss, W.
Reports on Progress in Physics, Vol. 64, Issue 5
DOI: 10.1088/0034-4885/64/5/201

Selective Detection of Cysteine and Glutathione Using Gold Nanorods
journal, May 2005

Sudeep, P. K.; Joseph, S. T. Shibu; Thomas, K. George
Journal of the American Chemical Society, Vol. 127, Issue 18
DOI: 10.1021/ja051145e

Low temperature synthesis and growth mechanism of Ag nanowires
journal, May 2007

Kim, Seon Ho; Choi, Beom Suk; Kang, Kyongha
Journal of Alloys and Compounds, Vol. 433, Issue 1-2
DOI: 10.1016/j.jallcom.2006.06.053

Phase retrieval algorithms: a comparison
journal, January 1982

Fienup, J. R.
Applied Optics, Vol. 21, Issue 15
DOI: 10.1364/AO.21.002758

Coordination-dependent surface atomic contraction in nanocrystals revealed by coherent diffraction
journal, March 2008

Huang, W. J.; Sun, R.; Tao, J.
Nature Materials, Vol. 7, Issue 4
DOI: 10.1038/nmat2132

Hubble Space Telescope characterized by using phase-retrieval algorithms
journal, January 1993

Fienup, J. R.; Marron, J. C.; Schulz, T. J.
Applied Optics, Vol. 32, Issue 10
DOI: 10.1364/AO.32.001747

The role of surface stress in reconstruction, epitaxial growth and stabilization of mesoscopic structures
journal, January 1997

Ibach, Harald
Surface Science Reports, Vol. 29, Issue 5-6
DOI: 10.1016/S0167-5729(97)00010-1

Controlling synthesis of silver nanowires and dendrites in mixed surfactant solutions
journal, December 2003

Zheng, Xiuwen; Zhu, Liying; Yan, Aihui
Journal of Colloid and Interface Science, Vol. 268, Issue 2
DOI: 10.1016/j.jcis.2003.09.021

Oriented Growth of Single-Crystal Ni Nanowires onto Amorphous SiO ₂
journal, December 2010

Chan, Keith T.; Kan, Jimmy J.; Doran, Christopher
Nano Letters, Vol. 10, Issue 12
DOI: 10.1021/nl103301x

Fluorescence properties of gold nanorods and their application for DNA biosensing
journal, January 2005

Li, Chen-Zhong; Male, Keith B.; Hrapovic, Sabahudin
Chemical Communications, Issue 31
DOI: 10.1039/b504186d

Three-dimensional mapping of a deformation field inside a nanocrystal
journal, July 2006

Pfeifer, Mark A.; Williams, Garth J.; Vartanyants, Ivan A.
Nature, Vol. 442, Issue 7098
DOI: 10.1038/nature04867

Single Particle Nanomechanics in Operando Batteries via Lensless Strain Mapping
journal, August 2014

Ulvestad, Andrew; Singer, Andrej; Cho, Hyung-Man
Nano Letters, Vol. 14, Issue 9
DOI: 10.1021/nl501858u

Effect of surrounding environment on atomic structure and equilibrium shape of growing nanocrystals: gold in/on SiO2
journal, May 2007

Ruffino, F.; Bongiorno, C.; Giannazzo, F.
Nanoscale Research Letters, Vol. 2, Issue 5
DOI: 10.1007/s11671-007-9058-4

Differential stress induced by thiol adsorption on facetted nanocrystals
journal, September 2011

Watari, Moyu; McKendry, Rachel A.; Vögtli, Manuel
Nature Materials, Vol. 10, Issue 11
DOI: 10.1038/nmat3124

One-Dimensional Colloidal Gold and Silver Nanostructures
journal, September 2006

Murphy, Catherine J.; Gole, Anand M.; Hunyadi, Simona E.
Inorganic Chemistry, Vol. 45, Issue 19
DOI: 10.1021/ic0519382

Stacking Faults in Formation of Silver Nanodisks
journal, August 2003

Germain, V.; Li, Jing; Ingert, D.
The Journal of Physical Chemistry B, Vol. 107, Issue 34
DOI: 10.1021/jp0303826

Nonequilibrium Structural Dynamics of Nanoparticles in LiNi _1/2 Mn _3/2 O ₄ Cathode under Operando Conditions
journal, August 2014

Singer, Andrej; Ulvestad, Andrew; Cho, Hyung-Man
Nano Letters, Vol. 14, Issue 9
DOI: 10.1021/nl502332b

Interparticle Coupling Effect on the Surface Plasmon Resonance of Gold Nanoparticles: From Theory to Applications
journal, November 2007

Ghosh, Sujit Kumar; Pal, Tarasankar
Chemical Reviews, Vol. 107, Issue 11
DOI: 10.1021/cr0680282

Shaped gold and silver nanoparticles
journal, September 2010

Sun, Yugang; An, Changhua
Frontiers of Materials Science, Vol. 5, Issue 1
DOI: 10.1007/s11706-011-0100-1

Mechanisms Controlling Crystal Habits of Gold and Silver Colloids
journal, July 2005

Lofton, C.; Sigmund, W.
Advanced Functional Materials, Vol. 15, Issue 7
DOI: 10.1002/adfm.200400091

The influence of mechanical strain on the optical properties of spherical gold nanoparticles
journal, March 2010

Qian, Xiaohu; Park, Harold S.
Journal of the Mechanics and Physics of Solids, Vol. 58, Issue 3
DOI: 10.1016/j.jmps.2009.12.001

The oversampling phasing method
journal, October 2000

Miao, J.; Kirz, J.; Sayre, D.
Acta Crystallographica Section D Biological Crystallography, Vol. 56, Issue 10
DOI: 10.1107/S0907444900008970

Experimental studies of small particle structures
journal, June 1994

Marks, L. D.
Reports on Progress in Physics, Vol. 57, Issue 6
DOI: 10.1088/0034-4885/57/6/002

Phase-retrieval stagnation problems and solutions
journal, January 1986

Fienup, J. R.; Wackerman, C. C.
Journal of the Optical Society of America A, Vol. 3, Issue 11
DOI: 10.1364/JOSAA.3.001897

Transmission Electron Microscopy of Shape-Controlled Nanocrystals and Their Assemblies
journal, February 2000

Wang, Z. L.
The Journal of Physical Chemistry B, Vol. 104, Issue 6
DOI: 10.1021/jp993593c

Nanoparticles: Strained and Stiff
journal, July 2004

Gilbert, B.
Science, Vol. 305, Issue 5684
DOI: 10.1126/science.1098454

Nanoscale strain mapping in battery nanostructures
journal, February 2014

Ulvestad, A.; Cho, H. M.; Harder, R.
Applied Physics Letters, Vol. 104, Issue 7
DOI: 10.1063/1.4866030

Structural Characteristics and Growth of Pentagonal Silver Nanorods Prepared by a Surfactant Method
journal, April 2005

Ni, Chaoying; Hassan, Puthusserickal A.; Kaler, Eric W.
Langmuir, Vol. 21, Issue 8
DOI: 10.1021/la046807c

X-ray image reconstruction from a diffraction pattern alone
journal, October 2003

Marchesini, S.; He, H.; Chapman, H. N.
Physical Review B, Vol. 68, Issue 14
DOI: 10.1103/PhysRevB.68.140101

Cancer Cell Imaging and Photothermal Therapy in the Near-Infrared Region by Using Gold Nanorods
journal, February 2006

Huang, Xiaohua; El-Sayed, Ivan H.; Qian, Wei
Journal of the American Chemical Society, Vol. 128, Issue 6, p. 2115-2120
DOI: 10.1021/ja057254a

Similar Records in DOE PAGES and OSTI.GOV collections:

Curvature-induced and thermal strain in polyhedral gold nanocrystals

Journal Article Kim, J. W. ; Manna, S. ; Dietze, S. H. ; ... - Applied Physics Letters

We use coherent x-ray diffractive imaging to map the local distribution of strain in gold (Au) polyhedral nanocrystals grown on a silicon (Si) substrate by a single-step thermal chemical vapor deposition process. The lattice strain at the surface of the octahedral nanocrystal agrees well with the predictions of the Young-Laplace equation quantitatively, but exhibits a discrepancy near the nanocrystal-substrate interface. We attribute this discrepancy to the dissimilar interfacial energies between Au/Air and Au/Si and to the difference in thermal expansion between the nanocrystal and the substrate during the cooling process.
https://doi.org/10.1063/1.4900866
Curvature-induced and thermal strain in polyhedral gold nanocrystals

Journal Article Kim, J. W. ; Dietze, S. H. ; Ulvestad, A. ; ... - Applied Physics Letters

We use coherent x-ray diffractive imaging to map the local distribution of strain in gold (Au) polyhedral nanocrystals grown on a silicon (Si) substrate by a single-step thermal chemical vapor deposition process. The lattice strain at the surface of the octahedral nanocrystal agrees well with the predictions of the Young-Laplace equation quantitatively, but exhibits a discrepancy near the nanocrystal-substrate interface. We attribute this discrepancy to the dissimilar interfacial energies between Au/Air and Au/Si and to the difference in thermal expansion between the nanocrystal and the substrate during the cooling process.
https://doi.org/10.1063/1.4900866
Visualizing Intrinsic 3D-Strain Distribution in Gold Coated ZnO Microstructures by Bragg Coherent X-Ray Diffraction Imaging and Transmission Electron Microscopy with Respect to Piezotronic Applications

Journal Article Jordt, Philipp ; Wolff, Niklas ; Hrkac, Stjepan B. ; ... - Advanced Electronic Materials

Novel devices ranging from bio magnetic field sensors to energy harvesting nano machines utilize the piezotronic effect. For optimal function, understanding the interaction of electrical and strain phenomena within the semiconductor crystal is necessary. Here, studies of a model piezotronic system are presented, consisting of a ZnO microrod coated by a thin layer of gold, which forms a Schottky contact with the piezoelectric ZnO material. Coherent X-ray diffraction imaging (CXDI) and transmission electron microscopy (TEM) are used to visualize the structure and strain distribution, showing that the ZnO microrod exhibits strains of multiple origins in the bulk and at themore »« less
https://doi.org/10.1002/aelm.202100546

Full Text Available
Thermal stability of two-dimensional gold nanocrystal superlattices.

Journal Article Robel, I ; Lin, X -M ; Sprung, M ; ... - J. Phys.: Cond. Matter

The thermal stability of highly ordered two-dimensional superlattices consisting of dodecanethiol-ligated Au nanoparticles has been investigated using in situ grazing incidence small-angle x-ray scattering in air and in vacuum. In the lower temperature region (<70 C), annealing in air results in a minimal change of superlattice structure, whereas annealing in vacuum leads to a considerable lattice contraction and a decrease in long-range order. At higher temperatures (>100 C), ligand desorption causes nanocrystals to sinter locally, destroying quasi-long-range order. The sintering process is significantly enhanced in vacuum compared to the case in air due to the increased desorption rate of thiolmore » ligands under low pressure.« less
https://doi.org/10.1088/0953-8984/21/26/264011
In Situ 3D Imaging of Catalysis Induced Strain in Gold Nanoparticles

Journal Article Ulvestad, Andrew ; Sasikumar, Kiran ; Kim, Jong Woo ; ... - Journal of Physical Chemistry Letters

Multielectron transfer processes are crucially important in energy and biological science but require favorable catalysts to achieve fast kinetics. Nanostructuring catalysts can dramatically improve their properties, which can be difficult to understand due to strain- and size-dependent thermodynamics, the influence of defects, and substrate-dependent activities. Here, we report three-dimensional (3D) imaging of single gold nanoparticles during catalysis of ascorbic acid decomposition using Bragg coherent diffractive imaging (BCDI). Local strains were measured in single nanoparticles and modeled using reactive molecular dynamics (RMD) simulations and finite element analysis (FEA) simulations. RMD reveals the pathway for local strain generation in the gold lattice:more »« less
https://doi.org/10.1021/acs.jpclett.6b01038

Similar Records

Title: Curvature-induced and thermal strain in polyhedral gold nanocrystals

Citation Formats

Nanoparticles with Raman Spectroscopic Fingerprints for DNA and RNA Detection journal, August 2002

Reaction of Oxygen with Si(111) and (100): Critical Conditions for the Growth of SiO[sub 2] journal, January 1982

Partial coherence effects on the imaging of small crystals using coherent x-ray diffraction journal, November 2001

Coherent X-ray diffraction imaging of strain at the nanoscale journal, April 2009

The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment journal, January 2003

Nanoparticle Structure by Coherent X-ray Diffraction journal, February 2013

Extending the methodology of X-ray crystallography to allow imaging of micrometre-sized non-crystalline specimens journal, July 1999

Three-Dimensional Imaging of Microstructure in Au Nanocrystals journal, April 2003

A Dynamical Theory of Diffraction for a Distorted Crystal journal, May 1969

Surface stress of clean and adsorbate-covered solids journal, May 2001

Selective Detection of Cysteine and Glutathione Using Gold Nanorods journal, May 2005

Low temperature synthesis and growth mechanism of Ag nanowires journal, May 2007

Phase retrieval algorithms: a comparison journal, January 1982

Coordination-dependent surface atomic contraction in nanocrystals revealed by coherent diffraction journal, March 2008

Hubble Space Telescope characterized by using phase-retrieval algorithms journal, January 1993

The role of surface stress in reconstruction, epitaxial growth and stabilization of mesoscopic structures journal, January 1997

Controlling synthesis of silver nanowires and dendrites in mixed surfactant solutions journal, December 2003

Oriented Growth of Single-Crystal Ni Nanowires onto Amorphous SiO 2 journal, December 2010

Fluorescence properties of gold nanorods and their application for DNA biosensing journal, January 2005

Three-dimensional mapping of a deformation field inside a nanocrystal journal, July 2006

Single Particle Nanomechanics in Operando Batteries via Lensless Strain Mapping journal, August 2014

Effect of surrounding environment on atomic structure and equilibrium shape of growing nanocrystals: gold in/on SiO2 journal, May 2007

Differential stress induced by thiol adsorption on facetted nanocrystals journal, September 2011

One-Dimensional Colloidal Gold and Silver Nanostructures journal, September 2006

Stacking Faults in Formation of Silver Nanodisks journal, August 2003

Nonequilibrium Structural Dynamics of Nanoparticles in LiNi 1/2 Mn 3/2 O 4 Cathode under Operando Conditions journal, August 2014

Interparticle Coupling Effect on the Surface Plasmon Resonance of Gold Nanoparticles: From Theory to Applications journal, November 2007

Shaped gold and silver nanoparticles journal, September 2010

Mechanisms Controlling Crystal Habits of Gold and Silver Colloids journal, July 2005

The influence of mechanical strain on the optical properties of spherical gold nanoparticles journal, March 2010

The oversampling phasing method journal, October 2000

Experimental studies of small particle structures journal, June 1994

Phase-retrieval stagnation problems and solutions journal, January 1986

Transmission Electron Microscopy of Shape-Controlled Nanocrystals and Their Assemblies journal, February 2000

Nanoparticles: Strained and Stiff journal, July 2004

Nanoscale strain mapping in battery nanostructures journal, February 2014

Structural Characteristics and Growth of Pentagonal Silver Nanorods Prepared by a Surfactant Method journal, April 2005

X-ray image reconstruction from a diffraction pattern alone journal, October 2003

Cancer Cell Imaging and Photothermal Therapy in the Near-Infrared Region by Using Gold Nanorods journal, February 2006

Nanoparticles with Raman Spectroscopic Fingerprints for DNA and RNA Detection
journal, August 2002

Reaction of Oxygen with Si(111) and (100): Critical Conditions for the Growth of SiO[sub 2]
journal, January 1982

Partial coherence effects on the imaging of small crystals using coherent x-ray diffraction
journal, November 2001

Coherent X-ray diffraction imaging of strain at the nanoscale
journal, April 2009

The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment
journal, January 2003

Nanoparticle Structure by Coherent X-ray Diffraction
journal, February 2013

Extending the methodology of X-ray crystallography to allow imaging of micrometre-sized non-crystalline specimens
journal, July 1999

Three-Dimensional Imaging of Microstructure in Au Nanocrystals
journal, April 2003

A Dynamical Theory of Diffraction for a Distorted Crystal
journal, May 1969

Surface stress of clean and adsorbate-covered solids
journal, May 2001

Selective Detection of Cysteine and Glutathione Using Gold Nanorods
journal, May 2005

Low temperature synthesis and growth mechanism of Ag nanowires
journal, May 2007

Phase retrieval algorithms: a comparison
journal, January 1982

Coordination-dependent surface atomic contraction in nanocrystals revealed by coherent diffraction
journal, March 2008

Hubble Space Telescope characterized by using phase-retrieval algorithms
journal, January 1993

The role of surface stress in reconstruction, epitaxial growth and stabilization of mesoscopic structures
journal, January 1997

Controlling synthesis of silver nanowires and dendrites in mixed surfactant solutions
journal, December 2003

Oriented Growth of Single-Crystal Ni Nanowires onto Amorphous SiO ₂
journal, December 2010

Fluorescence properties of gold nanorods and their application for DNA biosensing
journal, January 2005

Three-dimensional mapping of a deformation field inside a nanocrystal
journal, July 2006

Single Particle Nanomechanics in Operando Batteries via Lensless Strain Mapping
journal, August 2014

Effect of surrounding environment on atomic structure and equilibrium shape of growing nanocrystals: gold in/on SiO2
journal, May 2007

Differential stress induced by thiol adsorption on facetted nanocrystals
journal, September 2011

One-Dimensional Colloidal Gold and Silver Nanostructures
journal, September 2006

Stacking Faults in Formation of Silver Nanodisks
journal, August 2003

Nonequilibrium Structural Dynamics of Nanoparticles in LiNi _1/2 Mn _3/2 O ₄ Cathode under Operando Conditions
journal, August 2014

Interparticle Coupling Effect on the Surface Plasmon Resonance of Gold Nanoparticles: From Theory to Applications
journal, November 2007

Shaped gold and silver nanoparticles
journal, September 2010

Mechanisms Controlling Crystal Habits of Gold and Silver Colloids
journal, July 2005

The influence of mechanical strain on the optical properties of spherical gold nanoparticles
journal, March 2010

The oversampling phasing method
journal, October 2000

Experimental studies of small particle structures
journal, June 1994

Phase-retrieval stagnation problems and solutions
journal, January 1986

Transmission Electron Microscopy of Shape-Controlled Nanocrystals and Their Assemblies
journal, February 2000

Nanoparticles: Strained and Stiff
journal, July 2004

Nanoscale strain mapping in battery nanostructures
journal, February 2014

Structural Characteristics and Growth of Pentagonal Silver Nanorods Prepared by a Surfactant Method
journal, April 2005

X-ray image reconstruction from a diffraction pattern alone
journal, October 2003

Cancer Cell Imaging and Photothermal Therapy in the Near-Infrared Region by Using Gold Nanorods
journal, February 2006