Interfacial charge-mediated non-volatile magnetoelectric coupling in Co0.3Fe0.7/Ba0.6Sr0.4TiO3/Nb:SrTiO3 multiferroic heterostructures

Zhou, Ziyao; Howe, Brandon M.; Liu, Ming; Nan, Tianxiang; Chen, Xing; Mahalingam, Krishnamurthy; Sun, Nian X.; Brown, Gail J.

doi:10.1038/srep07740

Title: Interfacial charge-mediated non-volatile magnetoelectric coupling in Co_0.3Fe_0.7/Ba_0.6Sr_0.4TiO₃/Nb:SrTiO₃ multiferroic heterostructures

Abstract

The central challenge in realizing non-volatile, E-field manipulation of magnetism lies in finding an energy efficient means to switch between the distinct magnetic states in a stable and reversible manner. In this work, we demonstrate using electrical polarization-induced charge screening to change the ground state of magnetic ordering in order to non-volatilely tune magnetic properties in ultra-thin Co_0.3Fe_0.7/Ba_0.6Sr_0.4TiO₃/Nb:SrTiO₃ (001) multiferroic heterostructures. A robust, voltage-induced, non-volatile manipulation of out-of-plane magnetic anisotropy up to 40 Oe is demonstrated and confirmed by ferromagnetic resonance measurements. This discovery provides a framework for realizing charge-sensitive order parameter tuning in ultra-thin multiferroic heterostructures, demonstrating great potential for delivering compact, lightweight, reconfigurable, and energy-efficient electronic devices.

Authors:

Zhou, Ziyao ^[1]; Howe, Brandon M. ^[2]; Liu, Ming ^[2]; Nan, Tianxiang ^[3]; Chen, Xing ^[4]; Mahalingam, Krishnamurthy ^[2]; Sun, Nian X. ^[3]; Brown, Gail J. ^[2]

Northeastern Univ., Boston, MA (United States); Argonne National Lab. (ANL), Argonne, IL (United States)
Air Force Research Lab. (AFRL), Wright-Patterson AFB, OH (United States)
Northeastern Univ., Boston, MA (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)

Publication Date:: Tue Jan 13 00:00:00 EST 2015

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1222944

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Scientific Reports

Additional Journal Information:: Journal Volume: 5; Journal ID: ISSN 2045-2322

Publisher:: Nature Publishing Group

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Zhou, Ziyao, Howe, Brandon M., Liu, Ming, Nan, Tianxiang, Chen, Xing, Mahalingam, Krishnamurthy, Sun, Nian X., and Brown, Gail J. Interfacial charge-mediated non-volatile magnetoelectric coupling in Co0.3Fe0.7/Ba0.6Sr0.4TiO3/Nb:SrTiO3 multiferroic heterostructures.  United States: N. p., 2015. 
Web.  doi:10.1038/srep07740.

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                    Zhou, Ziyao, Howe, Brandon M., Liu, Ming, Nan, Tianxiang, Chen, Xing, Mahalingam, Krishnamurthy, Sun, Nian X., & Brown, Gail J. Interfacial charge-mediated non-volatile magnetoelectric coupling in Co0.3Fe0.7/Ba0.6Sr0.4TiO3/Nb:SrTiO3 multiferroic heterostructures.  United States.  https://doi.org/10.1038/srep07740

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                    Zhou, Ziyao, Howe, Brandon M., Liu, Ming, Nan, Tianxiang, Chen, Xing, Mahalingam, Krishnamurthy, Sun, Nian X., and Brown, Gail J. Tue .  
"Interfacial charge-mediated non-volatile magnetoelectric coupling in Co0.3Fe0.7/Ba0.6Sr0.4TiO3/Nb:SrTiO3 multiferroic heterostructures".  United States.  https://doi.org/10.1038/srep07740.  https://www.osti.gov/servlets/purl/1222944.

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@article{osti_1222944,

  title        = {Interfacial charge-mediated non-volatile magnetoelectric coupling in Co0.3Fe0.7/Ba0.6Sr0.4TiO3/Nb:SrTiO3 multiferroic heterostructures},

  author       = {Zhou, Ziyao and Howe, Brandon M. and Liu, Ming and Nan, Tianxiang and Chen, Xing and Mahalingam, Krishnamurthy and Sun, Nian X. and Brown, Gail J.},

  abstractNote = {The central challenge in realizing non-volatile, E-field manipulation of magnetism lies in finding an energy efficient means to switch between the distinct magnetic states in a stable and reversible manner. In this work, we demonstrate using electrical polarization-induced charge screening to change the ground state of magnetic ordering in order to non-volatilely tune magnetic properties in ultra-thin Co0.3Fe0.7/Ba0.6Sr0.4TiO3/Nb:SrTiO3 (001) multiferroic heterostructures. A robust, voltage-induced, non-volatile manipulation of out-of-plane magnetic anisotropy up to 40 Oe is demonstrated and confirmed by ferromagnetic resonance measurements. This discovery provides a framework for realizing charge-sensitive order parameter tuning in ultra-thin multiferroic heterostructures, demonstrating great potential for delivering compact, lightweight, reconfigurable, and energy-efficient electronic devices.},

  doi          = {10.1038/srep07740},

  journal      = {Scientific Reports},

  number       = ,

  volume       = 5,

  place        = {United States},

  year         = {Tue Jan 13 00:00:00 EST 2015},

  month        = {Tue Jan 13 00:00:00 EST 2015}

}

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Title: Interfacial charge-mediated non-volatile magnetoelectric coupling in Co0.3Fe0.7/Ba0.6Sr0.4TiO3/Nb:SrTiO3 multiferroic heterostructures

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Citation Formats

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Surface Magnetoelectric Effect in Ferromagnetic Metal Films journal, September 2008

Voltage-Assisted Magnetization Switching in Ultrathin Fe 80 Co 20 Alloy Layers journal, May 2009

Predicted Magnetoelectric Effect in Fe / BaTiO 3 Multilayers: Ferroelectric Control of Magnetism journal, July 2006

Origin of the Magnetoelectric Coupling Effect in Pb ( Zr 0.2 Ti 0.8 ) O 3 / La 0.8 Sr 0.2 MnO 3 Multiferroic Heterostructures journal, March 2010

Multiferroic and Magnetoelectric Materials journal, October 2006

Revival of the Magnetoelectric Effect journal, August 2005

Evidence for reversible control of magnetization in a ferromagnetic material via spin-orbit magnetic field text, January 2008

Ferroelectric Control of Magnetic Anisotropy journal, September 2011

Magnetoelectric Charge Trap Memory journal, February 2012

Electric-field control of local ferromagnetism using a magnetoelectric multiferroic journal, April 2008

Quantification of strain and charge co-mediated magnetoelectric coupling on ultra-thin Permalloy/PMN-PT interface journal, January 2014

Voltage-Gated Modulation of Domain Wall Velocity in an Ultrathin Metallic Ferromagnet text, January 2012

Enhancement of magnetoelectric coupling by insertion of Co atomic layer into Fe 3 Si/BaTiO 3 (001) interfaces identified by first-principles calculations journal, December 2019

Cyclable and non-volatile electric field control of magnetism in BiFeO 3 based magnetoelectric heterostructures journal, March 2018

Non-Volatile Ferroelectric Switching of Ferromagnetic Resonance in NiFe/PLZT Multiferroic Thin Film Heterostructures journal, September 2016

Observation of an electric field-induced interface redox reaction and magnetic modification in GdO x /Co thin film by means of depth-resolved X-ray absorption spectroscopy journal, January 2018

Multiferroic magnetoelectric nanostructures for novel device applications journal, September 2015

First-principles study of interfacial magnetoelectric coupling in Fe 3 Ga/BaTiO 3 /Fe 3 Ga heterostructure journal, May 2019

Magnetoelastic coupling between NiFe thin film and LiCsSO 4 studied by Kerr microscopy journal, September 2015

Non-volatility using materials with only volatile properties: Vertically integrated magnetoelectric heterostructures and their potential for multi-level-cell devices journal, June 2019

Effect of interface coupling on magnetoelectric response of Pb(Zr0.52Ti0.48)O3/La0.67Sr0.33MnO3 thin film under different strain states journal, September 2018

Tunable properties of spin waves in magnetoelastic $\mathrm{NiFe}/{\mathrm{Gd}}_{2}{({\mathrm{MoO}}_{4})}_{3}$ heterostructure journal, May 2016

Phase separation enhanced magneto-electric coupling in La0.7Ca0.3MnO3/BaTiO3 ultra-thin films journal, December 2015

Voltage control of ferromagnetic resonance journal, June 2016

The memory effect of magnetoelectric coupling in FeGaB/NiTi/PMN-PT multiferroic heterostructure journal, February 2016

Ferromagnetic resonance manipulation by electric fields in Ni 81 Fe 19 /Bi 3.15 Nd 0.85 Ti 2.99 Mn 0.01 O 12 multiferroic heterostructures journal, October 2018

Magnetoelectric Coupling in Epitaxial Multiferroic BiFeO 3 –BaTiO 3 Composite Thin Films journal, January 2020

Phase separation enhanced magneto-electric coupling in La0.7Ca0.3MnO3/BaTiO3 ultra-thin films journal, December 2015

Title: Interfacial charge-mediated non-volatile magnetoelectric coupling in Co_0.3Fe_0.7/Ba_0.6Sr_0.4TiO₃/Nb:SrTiO₃ multiferroic heterostructures

Electrically induced enormous magnetic anisotropy in Terfenol-D/lead zinc niobate-lead titanate multiferroic heterostructures
journal, September 2012

Quantifying thickness-dependent charge mediated magnetoelectric coupling in magnetic/dielectric thin film heterostructures
journal, December 2013

Quantification of strain and charge co-mediated magnetoelectric coupling on ultra-thin Permalloy/PMN-PT interface
journal, January 2014

Thickness-dependent voltage-modulated magnetism in multiferroic heterostructures
journal, January 2012

Voltage-gated modulation of domain wall creep dynamics in an ultrathin metallic ferromagnet
journal, October 2012

Electronically Tunable Miniaturized Antennas on Magnetoelectric Substrates With Enhanced Performance
journal, November 2008

Chemical mechanical polishing of Ba0.6Sr0.4TiO3 film prepared by sol–gel method
journal, August 2004

Spin transfer torques
journal, April 2008

Tailoring magnetic anisotropy at the ferromagnetic/ferroelectric interface
journal, March 2008

Giant magnetoelectric coefficients in (Fe90Co10)78Si12B10-AlN thin film composites
journal, May 2010

Giant spin-accumulation signal and pure spin-current-induced reversible magnetization switching
journal, October 2008

Magnetoelectric Effects in Complex Oxides with Competing Ground States
journal, September 2009

Current-driven excitation of magnetic multilayers
journal, June 1996

Magnetoelectric Charge Trap Memory
journal, February 2012

Multiferroic magnetoelectric composites: Historical perspective, status, and future directions
journal, February 2008

Evidence for reversible control of magnetization in a ferromagnetic material by means of spin–orbit magnetic field
journal, August 2009

Voltage impulse induced bistable magnetization switching in multiferroic heterostructures
journal, March 2012

Towards a magnetoelectric memory
journal, June 2008

Large voltage-induced magnetic anisotropy change in a few atomic layers of iron
journal, January 2009

Voltage Tuning of Ferromagnetic Resonance with Bistable Magnetization Switching in Energy-Efficient Magnetoelectric Composites
journal, January 2013

Electric-field control of ferromagnetism
journal, December 2000

Voltage-Impulse-Induced Non-Volatile Ferroelastic Switching of Ferromagnetic Resonance for Reconfigurable Magnetoelectric Microwave Devices
journal, July 2013

Magnetization vector manipulation by electric fields
journal, September 2008

Ferroelectric Control of Magnetic Anisotropy
journal, September 2011

Thickness-dependent converse magnetoelectric coupling in bi-layered Ni/PZT thin films
journal, February 2012

Multiferroic and magnetoelectric materials
journal, August 2006

Revival of the magnetoelectric effect
journal, April 2005

Voltage Control of Magnetism in Multiferroic Heterostructures and Devices
journal, September 2012

Tunable Bandpass Filter Using Partially Magnetized Ferrites With High Power Handling Capability
journal, April 2013

Surface Magnetoelectric Effect in Ferromagnetic Metal Films
journal, September 2008

Voltage-Assisted Magnetization Switching in Ultrathin Fe ₈₀ Co ₂₀ Alloy Layers
journal, May 2009

Predicted Magnetoelectric Effect in $Fe / {BaTiO}_{3}$ Multilayers: Ferroelectric Control of Magnetism
journal, July 2006

Origin of the Magnetoelectric Coupling Effect in $Pb ({Zr}_{0.2} {Ti}_{0.8}) O_{3} / {La}_{0.8} {Sr}_{0.2} {MnO}_{3}$ Multiferroic Heterostructures
journal, March 2010

Multiferroic and Magnetoelectric Materials
journal, October 2006

Revival of the Magnetoelectric Effect
journal, August 2005

Evidence for reversible control of magnetization in a ferromagnetic material via spin-orbit magnetic field
text, January 2008

Ferroelectric Control of Magnetic Anisotropy
journal, September 2011

Magnetoelectric Charge Trap Memory
journal, February 2012

Electric-field control of local ferromagnetism using a magnetoelectric multiferroic
journal, April 2008

Quantification of strain and charge co-mediated magnetoelectric coupling on ultra-thin Permalloy/PMN-PT interface
journal, January 2014

Voltage-Gated Modulation of Domain Wall Velocity in an Ultrathin Metallic Ferromagnet
text, January 2012

Enhancement of magnetoelectric coupling by insertion of Co atomic layer into Fe ₃ Si/BaTiO ₃ (001) interfaces identified by first-principles calculations
journal, December 2019

Cyclable and non-volatile electric field control of magnetism in BiFeO ₃ based magnetoelectric heterostructures
journal, March 2018

Non-Volatile Ferroelectric Switching of Ferromagnetic Resonance in NiFe/PLZT Multiferroic Thin Film Heterostructures
journal, September 2016

Observation of an electric field-induced interface redox reaction and magnetic modification in GdO _x /Co thin film by means of depth-resolved X-ray absorption spectroscopy
journal, January 2018

Multiferroic magnetoelectric nanostructures for novel device applications
journal, September 2015

First-principles study of interfacial magnetoelectric coupling in Fe ₃ Ga/BaTiO ₃ /Fe ₃ Ga heterostructure
journal, May 2019

Magnetoelastic coupling between NiFe thin film and LiCsSO ₄ studied by Kerr microscopy
journal, September 2015

Non-volatility using materials with only volatile properties: Vertically integrated magnetoelectric heterostructures and their potential for multi-level-cell devices
journal, June 2019

Effect of interface coupling on magnetoelectric response of Pb(Zr0.52Ti0.48)O3/La0.67Sr0.33MnO3 thin film under different strain states
journal, September 2018

Tunable properties of spin waves in magnetoelastic $\mathrm{NiFe}/{\mathrm{Gd}}_{2}{({\mathrm{MoO}}_{4})}_{3}$ heterostructure
journal, May 2016

Phase separation enhanced magneto-electric coupling in La0.7Ca0.3MnO3/BaTiO3 ultra-thin films
journal, December 2015

Voltage control of ferromagnetic resonance
journal, June 2016

The memory effect of magnetoelectric coupling in FeGaB/NiTi/PMN-PT multiferroic heterostructure
journal, February 2016

Ferromagnetic resonance manipulation by electric fields in Ni ₈₁ Fe ₁₉ /Bi _3.15 Nd _0.85 Ti _2.99 Mn _0.01 O ₁₂ multiferroic heterostructures
journal, October 2018

Magnetoelectric Coupling in Epitaxial Multiferroic BiFeO ₃ –BaTiO ₃ Composite Thin Films
journal, January 2020

Phase separation enhanced magneto-electric coupling in La0.7Ca0.3MnO3/BaTiO3 ultra-thin films
journal, December 2015