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Title: Further investigation of g factors for the lead monofluoride ground state

We report the results of our theoretical study and analysis of earlier experimental data for the g-factor tensor components of the ground 2II1/2 state of the free PbF radical. These values obtained both within the relativistic coupled-cluster method combined with the generalized relativistic effective core potential approach and with our fit of the experimental data from [R. J. Mawhorter, B. S. Murphy, A. L. Baum, T. J. Sears, T. Yang, P. M. Rupasinghe, C. P. McRaven, N. E. Shafer-Ray, L. D. Alphei, and J.-U. Grabow, Phys. Rev. A 84, 022508 (2011); A. L. Baum, B.A. thesis, Pomona College, 2011]. The obtained results agree very well with each other but contradict the previous fit performed in the cited works. Our final prediction for g factors is G=0.081(5),G=–0.27(1).
Authors:
 [1] ;  [1] ;  [1] ;  [2] ;  [3] ;  [4] ;  [5]
  1. B.P. Konstantinov Petersburg Nuclear Physics Institute, Gatchina (Russia); St. Petersburg State Univ., St. Petersburg (Russia)
  2. Pomona College, Claremont, CA (United States); Institut fur Physikalische Chemie and Elektrochemie, Hannover (Germany)
  3. Pomona College, Claremont, CA (United States)
  4. Brookhaven National Lab. (BNL), Upton, NY (United States)
  5. Institut fur Physikalische Chemie and Elektrochemie, Hannover (Germany)
Publication Date:
OSTI Identifier:
1222617
Report Number(s):
BNL--108432-2015-JA
Journal ID: ISSN 1050-2947; PLRAAN; R&D Project: CO006; KC0301020
Grant/Contract Number:
13-02-01406; SC0012704
Type:
Accepted Manuscript
Journal Name:
Physical Review. A
Additional Journal Information:
Journal Volume: 92; Journal Issue: 3; Journal ID: ISSN 1050-2947
Publisher:
American Physical Society (APS)
Research Org:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY