Proposal for Universality in the Viscosity of Metallic Liquids

Blodgett, M. E.; Egami, Takeshi; Nussinov, Z.; Kelton, K. F.

doi:10.1038/srep13837

Title: Proposal for Universality in the Viscosity of Metallic Liquids

Abstract

The range of magnitude of the liquid viscosity, η, as a function of temperature is one of the most impressive of any physical property, changing by approximately 17 orders of magnitude from its extrapolated value at infinite temperature (η_o) to that at the glass transition temperature, T_g. We present experimental measurements of containerlessly processed metallic liquids that suggest that log(η/η_o) as a function of T_A/T is a potentially universal scaled curve. In stark contrast to previous approaches, the scaling requires only two fitting parameters, which are on average predictable. The temperature T_A corresponds to the onset of cooperative motion and is strongly correlated with T_g, suggesting that the processes underlying the glass transition first appear in the high temperature liquid.

Authors:

Blodgett, M. E. ^[1]; Egami, Takeshi ^[2]; Nussinov, Z. ^[1]; Kelton, K. F. ^[1]

Washington Univ., St. Louis, MO (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Publication Date:: Wed Sep 09 00:00:00 EDT 2015

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC)

OSTI Identifier:: 1222545

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Scientific Reports

Additional Journal Information:: Journal Volume: 5; Journal ID: ISSN 2045-2322

Publisher:: Nature Publishing Group

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Blodgett, M. E., Egami, Takeshi, Nussinov, Z., and Kelton, K. F. Proposal for Universality in the Viscosity of Metallic Liquids.  United States: N. p., 2015. 
Web.  doi:10.1038/srep13837.

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                    Blodgett, M. E., Egami, Takeshi, Nussinov, Z., & Kelton, K. F. Proposal for Universality in the Viscosity of Metallic Liquids.  United States.  https://doi.org/10.1038/srep13837

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                    Blodgett, M. E., Egami, Takeshi, Nussinov, Z., and Kelton, K. F. Wed .  
"Proposal for Universality in the Viscosity of Metallic Liquids".  United States.  https://doi.org/10.1038/srep13837.  https://www.osti.gov/servlets/purl/1222545.

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@article{osti_1222545,

  title        = {Proposal for Universality in the Viscosity of Metallic Liquids},

  author       = {Blodgett, M. E. and Egami, Takeshi and Nussinov, Z. and Kelton, K. F.},

  abstractNote = {The range of magnitude of the liquid viscosity, η, as a function of temperature is one of the most impressive of any physical property, changing by approximately 17 orders of magnitude from its extrapolated value at infinite temperature (ηo) to that at the glass transition temperature, Tg. We present experimental measurements of containerlessly processed metallic liquids that suggest that log(η/ηo) as a function of TA/T is a potentially universal scaled curve. In stark contrast to previous approaches, the scaling requires only two fitting parameters, which are on average predictable. The temperature TA corresponds to the onset of cooperative motion and is strongly correlated with Tg, suggesting that the processes underlying the glass transition first appear in the high temperature liquid.},

  doi          = {10.1038/srep13837},

  journal      = {Scientific Reports},

  number       = ,

  volume       = 5,

  place        = {United States},

  year         = {Wed Sep 09 00:00:00 EDT 2015},

  month        = {Wed Sep 09 00:00:00 EDT 2015}

}

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Works referenced in this record:

Viscosity, Plasticity, and Diffusion as Examples of Absolute Reaction Rates
journal, April 1936

Eyring, Henry
The Journal of Chemical Physics, Vol. 4, Issue 4
DOI: 10.1063/1.1749836

Why does the quark–gluon plasma at RHIC behave as a nearly ideal fluid?
journal, July 2004

Shuryak, Edward
Progress in Particle and Nuclear Physics, Vol. 53, Issue 1
DOI: 10.1016/j.ppnp.2004.02.025

Vogel–Fulcher–Tammann plot for viscosity scaled with temperature interval between actual and ideal glass transitions for metallic glasses in liquid and supercooled liquid states
journal, April 2010

Takeuchi, A.; Kato, H.; Inoue, A.
Intermetallics, Vol. 18, Issue 4
DOI: 10.1016/j.intermet.2009.08.015

Corresponding States of Structural Glass Formers
journal, April 2009

Elmatad, Yael S.; Chandler, David; Garrahan, Juan P.
The Journal of Physical Chemistry B, Vol. 113, Issue 16
DOI: 10.1021/jp810362g

Thermodynamic determination of fragility in liquids and a fragile-to-strong liquid transition in water
journal, April 1999

Ito, Kaori; Moynihan, Cornelius T.; Angell, C. Austen
Nature, Vol. 398, Issue 6727
DOI: 10.1038/19042

High-temperature contactless viscosity measurements by the gas–film levitation technique: Application to oxide and metallic glasses
journal, September 2002

Haumesser, Paul-Henri; Bancillon, Jacky; Daniel, Michel
Review of Scientific Instruments, Vol. 73, Issue 9
DOI: 10.1063/1.1499756

Viscosity of molten Pd ₈₂ Si ₁₈ and the scaling of viscosities of glass forming systems
journal, July 1992

Tsang, K. H.; Kui, H. W.
Journal of Applied Physics, Vol. 72, Issue 1
DOI: 10.1063/1.352101

Equilibrium viscosity of Zr–Cu–Ni–Al–Nb bulk metallic glasses
journal, September 2010

Evenson, Zach; Raedersdorf, Sven; Gallino, Isabella
Scripta Materialia, Vol. 63, Issue 6
DOI: 10.1016/j.scriptamat.2010.06.008

A structural signature of liquid fragility
journal, August 2014

Mauro, N. A.; Blodgett, M.; Johnson, M. L.
Nature Communications, Vol. 5, Issue 1
DOI: 10.1038/ncomms5616

Viscosity of molten Pd ₄₀ Ni ₄₀ P ₂₀
journal, November 1991

Tsang, K. H.; Lee, S. K.; Kui, H. W.
Journal of Applied Physics, Vol. 70, Issue 9
DOI: 10.1063/1.349050

Nonlinearities in the undercooled properties of Ti _39.5 Zr _39.5 Ni ₂₁
journal, January 2006

Bradshaw, R. C.; Arsenault, A. D.; Hyers, R. W.
Philosophical Magazine, Vol. 86, Issue 3-5
DOI: 10.1080/14786430500253968

Transport properties of glass-forming liquids suggest that dynamic crossover temperature is as important as the glass transition temperature
journal, December 2010

Mallamace, F.; Branca, C.; Corsaro, C.
Proceedings of the National Academy of Sciences, Vol. 107, Issue 52
DOI: 10.1073/pnas.1015340107

Thermodynamics and kinetics of the Mg65Cu25Y10 bulk metallic glass forming liquid
journal, April 1998

Busch, R.; Liu, W.; Johnson, W. L.
Journal of Applied Physics, Vol. 83, Issue 8
DOI: 10.1063/1.367167

Compilation of the fragility parameters for several glass-forming metallic alloys
journal, January 1999

Perera, D. N.
Journal of Physics: Condensed Matter, Vol. 11, Issue 19
DOI: 10.1088/0953-8984/11/19/303

Theory of Structural Glasses and Supercooled Liquids
journal, May 2007

Lubchenko, Vassiliy; Wolynes, Peter G.
Annual Review of Physical Chemistry, Vol. 58, Issue 1
DOI: 10.1146/annurev.physchem.58.032806.104653

Recent tests of the mode-coupling theory for glassy dynamics
journal, January 1999

Götze, Wolfgang
Journal of Physics: Condensed Matter, Vol. 11, Issue 10A
DOI: 10.1088/0953-8984/11/10a/002

Fitting of viscosity: Distinguishing the temperature dependences predicted by various models of supercooled liquids
journal, January 1996

Kivelson, Daniel; Tarjus, Gilles; Zhao, Xiaolin
Physical Review E, Vol. 53, Issue 1
DOI: 10.1103/physreve.53.751

Crossover to potential energy landscape dominated dynamics in a model glass-forming liquid
journal, June 2000

Schrøder, Thomas B.; Sastry, Srikanth; Dyre, Jeppe C.
The Journal of Chemical Physics, Vol. 112, Issue 22
DOI: 10.1063/1.481621

Rheology and Ultrasonic Properties of Metallic Glass-Forming Liquids: A Potential Energy Landscape Perspective
journal, August 2007

Johnson, William L.; Demetriou, Marios D.; Harmon, John S.
MRS Bulletin, Vol. 32, Issue 8
DOI: 10.1557/mrs2007.127

A thermodynamic theory of supercooled liquids
journal, September 1995

Kivelson, Daniel; Kivelson, Steven A.; Zhao, Xiaolin
Physica A: Statistical Mechanics and its Applications, Vol. 219, Issue 1-2
DOI: 10.1016/0378-4371(95)00140-3

From boiling point to glass transition temperature: Transport coefficients in molecular liquids follow three-parameter scaling
journal, October 2012

Schmidtke, B.; Petzold, N.; Kahlau, R.
Physical Review E, Vol. 86, Issue 4
DOI: 10.1103/physreve.86.041507

The influence of shear rate and temperature on the viscosity and fragility of the Zr41.2Ti13.8Cu12.5Ni10.0Be22.5 metallic-glass-forming liquid
journal, May 2007

Way, Christopher; Wadhwa, Prashant; Busch, Ralf
Acta Materialia, Vol. 55, Issue 9
DOI: 10.1016/j.actamat.2006.12.032

Breakdown of the Stokes–Einstein relation in supercooled liquids
journal, August 1995

Tarjus, Gilles; Kivelson, Daniel
The Journal of Chemical Physics, Vol. 103, Issue 8
DOI: 10.1063/1.470495

On the ergodicity of supercooled molecular glass-forming liquids at the dynamical arrest: the o-terphenyl case
journal, January 2014

Mallamace, Francesco; Corsaro, Carmelo; Leone, Nancy
Scientific Reports, Vol. 4, Issue 1
DOI: 10.1038/srep03747

Containerless Measurements of Thermophysical Properties of Zr54Ti8Cu20Al10Ni8
journal, September 2006

Bradshaw, R. C.; Warren, M. E.; Rogers, J. R.
Annals of the New York Academy of Sciences, Vol. 1077, Issue 1
DOI: 10.1196/annals.1362.058

Disentangling density and temperature effects in the viscous slowing down of glassforming liquids
journal, April 2004

Tarjus, G.; Kivelson, D.; Mossa, S.
The Journal of Chemical Physics, Vol. 120, Issue 13
DOI: 10.1063/1.1649732

The effect of cooling rates on the apparent fragility of Zr-based bulk metallic glasses
journal, June 2010

Evenson, Zach; Gallino, Isabella; Busch, Ralf
Journal of Applied Physics, Vol. 107, Issue 12
DOI: 10.1063/1.3452381

Study of the structural relaxation of Pd82Si18 metallic glass by thermal expansion and viscous flow measurements
journal, March 1991

Stojanova, Liljana; Russew, Krassimir; Illekova, Emilia
Materials Science and Engineering: A, Vol. 133
DOI: 10.1016/0921-5093(91)90126-8

A thermodynamic connection to the fragility of glass-forming liquids
journal, April 2001

Martinez, L. -M.; Angell, C. A.
Nature, Vol. 410, Issue 6829
DOI: 10.1038/35070517

Finite-temperature critical point of a glass transition
journal, July 2010

Elmatad, Y. S.; Jack, R. L.; Chandler, D.
Proceedings of the National Academy of Sciences, Vol. 107, Issue 29
DOI: 10.1073/pnas.1006306107

Viscosity of glass-forming liquids
journal, November 2009

Mauro, J. C.; Yue, Y.; Ellison, A. J.
Proceedings of the National Academy of Sciences, Vol. 106, Issue 47
DOI: 10.1073/pnas.0911705106

Under what conditions can a glass be formed?
journal, September 1969

Turnbull, David
Contemporary Physics, Vol. 10, Issue 5
DOI: 10.1080/00107516908204405

First X-Ray Scattering Studies on Electrostatically Levitated Metallic Liquids: Demonstrated Influence of Local Icosahedral Order on the Nucleation Barrier
journal, May 2003

Kelton, K. F.; Lee, G. W.; Gangopadhyay, A. K.
Physical Review Letters, Vol. 90, Issue 19
DOI: 10.1103/physrevlett.90.195504

Formation of Glasses from Liquids and Biopolymers
journal, March 1995

Angell, C. A.
Science, Vol. 267, Issue 5206
DOI: 10.1126/science.267.5206.1924

S PATIALLY H ETEROGENEOUS D YNAMICS IN S UPERCOOLED L IQUIDS
journal, October 2000

Ediger, M. D.
Annual Review of Physical Chemistry, Vol. 51, Issue 1
DOI: 10.1146/annurev.physchem.51.1.99

Anomalous structural evolution in Cu ₅₀ Zr ₅₀ glass-forming liquids
journal, July 2013

Mauro, Nicholas A.; Vogt, Adam J.; Johnson, Mark L.
Applied Physics Letters, Vol. 103, Issue 2
DOI: 10.1063/1.4813389

Correlation between kinetic strength, volumetric properties, and glass forming ability in metallic liquids
journal, September 2013

Bendert, J. C.; Kelton, K. F.
Journal of Non-Crystalline Solids, Vol. 376
DOI: 10.1016/J.Jnoncrysol.2013.05.032

The frustration-based approach of supercooled liquids and the glass transition: a review and critical assessment
journal, December 2005

Tarjus, G.; Kivelson, S. A.; Nussinov, Z.
Journal of Physics: Condensed Matter, Vol. 17, Issue 50
DOI: 10.1088/0953-8984/17/50/R01

Origin of the Vogel–Fulcher–Tammann law in glass-forming materials: the α–β bifurcation
journal, July 2000

Rault, Jacques
Journal of Non-Crystalline Solids, Vol. 271, Issue 3
DOI: 10.1016/S0022-3093(00)00099-5

Cooperative Shear Model for the Rheology of Glass-Forming Metallic Liquids
journal, August 2006

Demetriou, Marios D.; Harmon, John S.; Tao, Min
Physical Review Letters, Vol. 97, Issue 6
DOI: 10.1103/PhysRevLett.97.065502

Universal representation of viscosity in glass forming liquids
journal, January 1998

Rössler, E.; Hess, K. -U.; Novikov, V. N.
Journal of Non-Crystalline Solids, Vol. 223, Issue 3
DOI: 10.1016/S0022-3093(97)00365-7

Newtonian and non-Newtonian viscosity of supercooled liquid in metallic glasses
journal, May 2001

Kawamura, Yoshihito; Nakamura, Toshihiro; Kato, Hidemi
Materials Science and Engineering: A, Vol. 304-306
DOI: 10.1016/S0921-5093(00)01562-8

Surface Tension and Viscosity of Quasicrystal-Forming Ti–Zr–Ni Alloys
journal, July 2004

Hyers, R. W.; Bradshaw, R. C.; Rogers, J. R.
International Journal of Thermophysics, Vol. 25, Issue 4
DOI: 10.1023/B:IJOT.0000038507.99417.5b

Undercooled Liquid Viscosity and Glass Formation of a M g ₆₂ C u ₂₆ Y ₁₂ Alloy
journal, January 1996

Wu, Shyue-Sheng; Chin, Tsung-Shune; Su, Kuo-Chang
Japanese Journal of Applied Physics, Vol. 35, Issue Part 1, No. 1A
DOI: 10.1143/JJAP.35.175

Investigation of specific volume of glass-forming Pd–Cu–Ni–P alloy in the liquid, vitreous and crystalline state
journal, October 2002

Lu, I. -R; Görler, G. P.; Fecht, H. J.
Journal of Non-Crystalline Solids, Vol. 312-314
DOI: 10.1016/S0022-3093(02)01767-2

Viscosity in Strongly Interacting Quantum Field Theories from Black Hole Physics
journal, March 2005

Kovtun, P. K.; Son, D. T.; Starinets, A. O.
Physical Review Letters, Vol. 94, Issue 11
DOI: 10.1103/PhysRevLett.94.111601

Scaling concepts for the dynamics of viscous liquids near an ideal glassy state
journal, July 1989

Kirkpatrick, T. R.; Thirumalai, D.; Wolynes, P. G.
Physical Review A, Vol. 40, Issue 2
DOI: 10.1103/PhysRevA.40.1045

Measurement of the self-intermediate scattering function of suspensions of hard spherical particles near the glass transition
journal, November 1998

van Megen, W.; Mortensen, T. C.; Williams, S. R.
Physical Review E, Vol. 58, Issue 5
DOI: 10.1103/PhysRevE.58.6073

Icosahedral Short-Range Order in Deeply Undercooled Metallic Melts
journal, July 2002

Schenk, T.; Holland-Moritz, D.; Simonet, V.
Physical Review Letters, Vol. 89, Issue 7
DOI: 10.1103/PhysRevLett.89.075507

Study of the structural relaxation of Pd₈₂Si₁₈ metallic glass by thermal expansion and viscous flow measurements
book, January 1991

Stojanova, Liljana; Russew, Krassimir; Illekova, Emilia
Rapidly Quenched Materials
DOI: 10.1016/b978-0-444-89107-5.50128-3

Corresponding States of Structural Glass Formers
text, January 2008

Elmatad, Yael S.; Chandler, David; Garrahan, Juan P.
arXiv
DOI: 10.48550/arxiv.0811.2450

Finite-temperature critical point of a glass transition
text, January 2010

Elmatad, Yael S.; Jack, Robert L.; Garrahan, Juan P.
arXiv
DOI: 10.48550/arxiv.1003.3161

Connectivity of the Icosahedral Network and a Dramatically Growing Static Length Scale in Cu-Zr Binary Metallic Glasses
text, January 2013

Soklaski, Ryan; Nussinov, Zohar; Markow, Zachary
arXiv
DOI: 10.48550/arxiv.1302.1895

Disentangling density and temperature effects in the viscous slowing down of glassforming liquids
text, January 2003

Tarjus, G.; Kivelson, D.; Mossa, S.
arXiv
DOI: 10.48550/arxiv.cond-mat/0309579

The frustration-based approach of supercooled liquids and the glass transition: a review and critical assessment
text, January 2005

Tarjus, G.; Kivelson, S. A.; Nussinov, Z.
arXiv
DOI: 10.48550/arxiv.cond-mat/0509127

Crossover to Potential Energy Landscape Dominated Dynamics in a Model Glass-forming Liquid
text, January 1999

Schroeder, Thomas B.; Sastry, Srikanth; Dyre, Jeppe C.
arXiv
DOI: 10.48550/arxiv.cond-mat/9901271

Why does the Quark-Gluon Plasma at RHIC behave as a nearly ideal fluid ?
text, January 2003

Shuryak, Edward
arXiv
DOI: 10.48550/arxiv.hep-ph/0312227

A thermodynamic theory of supercooled liquids
journal, September 1995

Kivelson, Daniel; Kivelson, Steven A.; Zhao, Xiaolin
Physica A: Statistical Mechanics and its Applications, Vol. 219, Issue 1-2
DOI: 10.1016/0378-4371(95)00140-3

Study of the structural relaxation of Pd82Si18 metallic glass by thermal expansion and viscous flow measurements
journal, March 1991

Stojanova, Liljana; Russew, Krassimir; Illekova, Emilia
Materials Science and Engineering: A, Vol. 133
DOI: 10.1016/0921-5093(91)90126-8

Vogel–Fulcher–Tammann plot for viscosity scaled with temperature interval between actual and ideal glass transitions for metallic glasses in liquid and supercooled liquid states
journal, April 2010

Takeuchi, A.; Kato, H.; Inoue, A.
Intermetallics, Vol. 18, Issue 4
DOI: 10.1016/j.intermet.2009.08.015

Why does the quark–gluon plasma at RHIC behave as a nearly ideal fluid?
journal, July 2004

Shuryak, Edward
Progress in Particle and Nuclear Physics, Vol. 53, Issue 1
DOI: 10.1016/j.ppnp.2004.02.025

Thermodynamic determination of fragility in liquids and a fragile-to-strong liquid transition in water
journal, April 1999

Ito, Kaori; Moynihan, Cornelius T.; Angell, C. Austen
Nature, Vol. 398, Issue 6727
DOI: 10.1038/19042

A thermodynamic connection to the fragility of glass-forming liquids
journal, April 2001

Martinez, L. -M.; Angell, C. A.
Nature, Vol. 410, Issue 6829
DOI: 10.1038/35070517

A structural signature of liquid fragility
journal, August 2014

Mauro, N. A.; Blodgett, M.; Johnson, M. L.
Nature Communications, Vol. 5, Issue 1
DOI: 10.1038/ncomms5616

On the ergodicity of supercooled molecular glass-forming liquids at the dynamical arrest: the o-terphenyl case
journal, January 2014

Mallamace, Francesco; Corsaro, Carmelo; Leone, Nancy
Scientific Reports, Vol. 4, Issue 1
DOI: 10.1038/srep03747

Viscosity, Plasticity, and Diffusion as Examples of Absolute Reaction Rates
journal, April 1936

Eyring, Henry
The Journal of Chemical Physics, Vol. 4, Issue 4
DOI: 10.1063/1.1749836

The effect of cooling rates on the apparent fragility of Zr-based bulk metallic glasses
journal, June 2010

Evenson, Zach; Gallino, Isabella; Busch, Ralf
Journal of Applied Physics, Vol. 107, Issue 12
DOI: 10.1063/1.3452381

Viscosity of molten Pd ₄₀ Ni ₄₀ P ₂₀
journal, November 1991

Tsang, K. H.; Lee, S. K.; Kui, H. W.
Journal of Applied Physics, Vol. 70, Issue 9
DOI: 10.1063/1.349050

Viscosity of molten Pd ₈₂ Si ₁₈ and the scaling of viscosities of glass forming systems
journal, July 1992

Tsang, K. H.; Kui, H. W.
Journal of Applied Physics, Vol. 72, Issue 1
DOI: 10.1063/1.352101

Breakdown of the Stokes–Einstein relation in supercooled liquids
journal, August 1995

Tarjus, Gilles; Kivelson, Daniel
The Journal of Chemical Physics, Vol. 103, Issue 8
DOI: 10.1063/1.470495

Anomalous structural evolution in Cu ₅₀ Zr ₅₀ glass-forming liquids
journal, July 2013

Mauro, Nicholas A.; Vogt, Adam J.; Johnson, Mark L.
Applied Physics Letters, Vol. 103, Issue 2
DOI: 10.1063/1.4813389

Viscosity of glass-forming liquids
journal, November 2009

Mauro, J. C.; Yue, Y.; Ellison, A. J.
Proceedings of the National Academy of Sciences, Vol. 106, Issue 47
DOI: 10.1073/pnas.0911705106

Finite-temperature critical point of a glass transition
journal, July 2010

Elmatad, Y. S.; Jack, R. L.; Chandler, D.
Proceedings of the National Academy of Sciences, Vol. 107, Issue 29
DOI: 10.1073/pnas.1006306107

Under what conditions can a glass be formed?
journal, September 1969

Turnbull, David
Contemporary Physics, Vol. 10, Issue 5
DOI: 10.1080/00107516908204405

Nonlinearities in the undercooled properties of Ti _39.5 Zr _39.5 Ni ₂₁
journal, January 2006

Bradshaw, R. C.; Arsenault, A. D.; Hyers, R. W.
Philosophical Magazine, Vol. 86, Issue 3-5
DOI: 10.1080/14786430500253968

Compilation of the fragility parameters for several glass-forming metallic alloys
journal, January 1999

Perera, D. N.
Journal of Physics: Condensed Matter, Vol. 11, Issue 19
DOI: 10.1088/0953-8984/11/19/303

From boiling point to glass transition temperature: Transport coefficients in molecular liquids follow three-parameter scaling
journal, October 2012

Schmidtke, B.; Petzold, N.; Kahlau, R.
Physical Review E, Vol. 86, Issue 4
DOI: 10.1103/physreve.86.041507

First X-Ray Scattering Studies on Electrostatically Levitated Metallic Liquids: Demonstrated Influence of Local Icosahedral Order on the Nucleation Barrier
journal, May 2003

Kelton, K. F.; Lee, G. W.; Gangopadhyay, A. K.
Physical Review Letters, Vol. 90, Issue 19
DOI: 10.1103/physrevlett.90.195504

Theory of Structural Glasses and Supercooled Liquids
journal, May 2007

Lubchenko, Vassiliy; Wolynes, Peter G.
Annual Review of Physical Chemistry, Vol. 58, Issue 1
DOI: 10.1146/annurev.physchem.58.032806.104653

Corresponding States of Structural Glass Formers
text, January 2008

Elmatad, Yael S.; Chandler, David; Garrahan, Juan P.
arXiv
DOI: 10.48550/arxiv.0811.2450

Thermalization and possible quantum relaxation times in "classical" fluids: theory and experiment
preprint, January 2014

Nussinov, Z.; Nogueira, F.; Blodgett, M.
arXiv
DOI: 10.48550/arxiv.1409.1915

Disentangling density and temperature effects in the viscous slowing down of glassforming liquids
text, January 2003

Tarjus, G.; Kivelson, D.; Mossa, S.
arXiv
DOI: 10.48550/arxiv.cond-mat/0309579

Crossover to Potential Energy Landscape Dominated Dynamics in a Model Glass-forming Liquid
text, January 1999

Schroeder, Thomas B.; Sastry, Srikanth; Dyre, Jeppe C.
arXiv
DOI: 10.48550/arxiv.cond-mat/9901271

Works referencing / citing this record:

Local Density Correlations in Liquids
journal, February 2020

Egami, Takeshi
Frontiers in Physics, Vol. 8
DOI: 10.3389/fphy.2020.00050

Curie-Weiss behavior of liquid structure and ideal glass state
journal, December 2019

Ryu, C. W.; Dmowski, W.; Kelton, K. F.
Scientific Reports, Vol. 9, Issue 1
DOI: 10.1038/s41598-019-54758-y

Correlation of the fragility of metallic liquids with the high temperature structure, volume, and cohesive energy
journal, April 2017

Gangopadhyay, A. K.; Pueblo, C. E.; Dai, R.
The Journal of Chemical Physics, Vol. 146, Issue 15
DOI: 10.1063/1.4981011

Does the Adam-Gibbs relation hold in simulated supercooled liquids?
journal, August 2019

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The Journal of Chemical Physics, Vol. 151, Issue 8
DOI: 10.1063/1.5113477

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journal, May 2018

Dai, R.; Ashcraft, R.; Kelton, K. F.
The Journal of Chemical Physics, Vol. 148, Issue 20
DOI: 10.1063/1.5026801

Resistivity Saturation in Metallic Liquids Above a Dynamical Crossover Temperature Observed in Measurements Aboard the International Space Station
journal, November 2019

Van Hoesen, D. C.; Gangopadhyay, A. K.; Lohöfer, G.
Physical Review Letters, Vol. 123, Issue 22
DOI: 10.1103/physrevlett.123.226601

Universal localization transition accompanying glass formation: insights from efficient molecular dynamics simulations of diverse supercooled liquids
journal, January 2019

Hung, Jui-Hsiang; Patra, Tarak K.; Meenakshisundaram, Venkatesh
Soft Matter, Vol. 15, Issue 6
DOI: 10.1039/c8sm02051e

Correlation of the fragility of metallic liquids with the high temperature structure, volume, and cohesive energy
text, January 2017

Gangopadhyay, A. K.; Pueblo, C. E.; Dai, R.
arXiv
DOI: 10.48550/arxiv.1703.03467

Does the Adam-Gibbs relation hold in simulated supercooled liquids?
text, January 2019

Ozawa, Misaki; Scalliet, Camille; Ninarello, Andrea
arXiv
DOI: 10.48550/arxiv.1905.08179

Correlation between the Arrhenius crossover and the glass forming ability in metallic glasses
journal, October 2017

Wen, Tongqi; Yao, Wenjing; Wang, Nan
Scientific Reports, Vol. 7, Issue 1
DOI: 10.1038/s41598-017-13611-w

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Ryu, C. W.; Dmowski, W.; Kelton, K. F.
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A Phase Space Approach to Supercooled Liquids and a Universal Collapse of Their Viscosity
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Weingartner, Nicholas B.; Pueblo, Chris; Nogueira, Flavio S.
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Critical assessment of the equilibrium melting-based, energy distribution theory of supercooled liquids and application to jammed systems
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Weingartner, Nicholas B.; Pueblo, Chris; Kelton, K. F.
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DOI: 10.48550/arxiv.1512.04565

Polymer Glass Formation: Role of Activation Free Energy, Configurational Entropy, and Collective Motion
text, January 2021

Xu, Wen-Sheng; Douglas, Jack F.; Sun, Zhao-Yan
arXiv
DOI: 10.48550/arxiv.2102.12031

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Similar Records

Title: Proposal for Universality in the Viscosity of Metallic Liquids

Abstract

Citation Formats

Viscosity, Plasticity, and Diffusion as Examples of Absolute Reaction Rates journal, April 1936

Why does the quark–gluon plasma at RHIC behave as a nearly ideal fluid? journal, July 2004

Vogel–Fulcher–Tammann plot for viscosity scaled with temperature interval between actual and ideal glass transitions for metallic glasses in liquid and supercooled liquid states journal, April 2010

Corresponding States of Structural Glass Formers journal, April 2009

Thermodynamic determination of fragility in liquids and a fragile-to-strong liquid transition in water journal, April 1999

High-temperature contactless viscosity measurements by the gas–film levitation technique: Application to oxide and metallic glasses journal, September 2002

Viscosity of molten Pd 82 Si 18 and the scaling of viscosities of glass forming systems journal, July 1992

Equilibrium viscosity of Zr–Cu–Ni–Al–Nb bulk metallic glasses journal, September 2010

A structural signature of liquid fragility journal, August 2014

Viscosity of molten Pd 40 Ni 40 P 20 journal, November 1991

Nonlinearities in the undercooled properties of Ti 39.5 Zr 39.5 Ni 21 journal, January 2006

Transport properties of glass-forming liquids suggest that dynamic crossover temperature is as important as the glass transition temperature journal, December 2010

Thermodynamics and kinetics of the Mg65Cu25Y10 bulk metallic glass forming liquid journal, April 1998

Compilation of the fragility parameters for several glass-forming metallic alloys journal, January 1999

Theory of Structural Glasses and Supercooled Liquids journal, May 2007

Recent tests of the mode-coupling theory for glassy dynamics journal, January 1999

Fitting of viscosity: Distinguishing the temperature dependences predicted by various models of supercooled liquids journal, January 1996

Crossover to potential energy landscape dominated dynamics in a model glass-forming liquid journal, June 2000

Rheology and Ultrasonic Properties of Metallic Glass-Forming Liquids: A Potential Energy Landscape Perspective journal, August 2007

A thermodynamic theory of supercooled liquids journal, September 1995

From boiling point to glass transition temperature: Transport coefficients in molecular liquids follow three-parameter scaling journal, October 2012

The influence of shear rate and temperature on the viscosity and fragility of the Zr41.2Ti13.8Cu12.5Ni10.0Be22.5 metallic-glass-forming liquid journal, May 2007

Breakdown of the Stokes–Einstein relation in supercooled liquids journal, August 1995

On the ergodicity of supercooled molecular glass-forming liquids at the dynamical arrest: the o-terphenyl case journal, January 2014

Containerless Measurements of Thermophysical Properties of Zr54Ti8Cu20Al10Ni8 journal, September 2006

Disentangling density and temperature effects in the viscous slowing down of glassforming liquids journal, April 2004

The effect of cooling rates on the apparent fragility of Zr-based bulk metallic glasses journal, June 2010

Study of the structural relaxation of Pd82Si18 metallic glass by thermal expansion and viscous flow measurements journal, March 1991

A thermodynamic connection to the fragility of glass-forming liquids journal, April 2001

Finite-temperature critical point of a glass transition journal, July 2010

Viscosity of glass-forming liquids journal, November 2009

Under what conditions can a glass be formed? journal, September 1969

First X-Ray Scattering Studies on Electrostatically Levitated Metallic Liquids: Demonstrated Influence of Local Icosahedral Order on the Nucleation Barrier journal, May 2003

Formation of Glasses from Liquids and Biopolymers journal, March 1995

S PATIALLY H ETEROGENEOUS D YNAMICS IN S UPERCOOLED L IQUIDS journal, October 2000

Anomalous structural evolution in Cu 50 Zr 50 glass-forming liquids journal, July 2013

Correlation between kinetic strength, volumetric properties, and glass forming ability in metallic liquids journal, September 2013

The frustration-based approach of supercooled liquids and the glass transition: a review and critical assessment journal, December 2005

Origin of the Vogel–Fulcher–Tammann law in glass-forming materials: the α–β bifurcation journal, July 2000

Cooperative Shear Model for the Rheology of Glass-Forming Metallic Liquids journal, August 2006

Universal representation of viscosity in glass forming liquids journal, January 1998

Newtonian and non-Newtonian viscosity of supercooled liquid in metallic glasses journal, May 2001

Surface Tension and Viscosity of Quasicrystal-Forming Ti–Zr–Ni Alloys journal, July 2004

Undercooled Liquid Viscosity and Glass Formation of a M g 62 C u 26 Y 12 Alloy journal, January 1996

Investigation of specific volume of glass-forming Pd–Cu–Ni–P alloy in the liquid, vitreous and crystalline state journal, October 2002

Viscosity in Strongly Interacting Quantum Field Theories from Black Hole Physics journal, March 2005

Scaling concepts for the dynamics of viscous liquids near an ideal glassy state journal, July 1989

Measurement of the self-intermediate scattering function of suspensions of hard spherical particles near the glass transition journal, November 1998

Icosahedral Short-Range Order in Deeply Undercooled Metallic Melts journal, July 2002

Study of the structural relaxation of Pd82Si18 metallic glass by thermal expansion and viscous flow measurements book, January 1991

Corresponding States of Structural Glass Formers text, January 2008

Finite-temperature critical point of a glass transition text, January 2010

Connectivity of the Icosahedral Network and a Dramatically Growing Static Length Scale in Cu-Zr Binary Metallic Glasses text, January 2013

Disentangling density and temperature effects in the viscous slowing down of glassforming liquids text, January 2003

The frustration-based approach of supercooled liquids and the glass transition: a review and critical assessment text, January 2005

Crossover to Potential Energy Landscape Dominated Dynamics in a Model Glass-forming Liquid text, January 1999

Why does the Quark-Gluon Plasma at RHIC behave as a nearly ideal fluid ? text, January 2003

A thermodynamic theory of supercooled liquids journal, September 1995

Study of the structural relaxation of Pd82Si18 metallic glass by thermal expansion and viscous flow measurements journal, March 1991

Vogel–Fulcher–Tammann plot for viscosity scaled with temperature interval between actual and ideal glass transitions for metallic glasses in liquid and supercooled liquid states journal, April 2010

Why does the quark–gluon plasma at RHIC behave as a nearly ideal fluid? journal, July 2004

Thermodynamic determination of fragility in liquids and a fragile-to-strong liquid transition in water journal, April 1999

A thermodynamic connection to the fragility of glass-forming liquids journal, April 2001

A structural signature of liquid fragility journal, August 2014

On the ergodicity of supercooled molecular glass-forming liquids at the dynamical arrest: the o-terphenyl case journal, January 2014

Viscosity, Plasticity, and Diffusion as Examples of Absolute Reaction Rates journal, April 1936

The effect of cooling rates on the apparent fragility of Zr-based bulk metallic glasses journal, June 2010

Viscosity of molten Pd 40 Ni 40 P 20 journal, November 1991

Viscosity of molten Pd 82 Si 18 and the scaling of viscosities of glass forming systems journal, July 1992

Breakdown of the Stokes–Einstein relation in supercooled liquids journal, August 1995

Anomalous structural evolution in Cu 50 Zr 50 glass-forming liquids journal, July 2013

Viscosity of glass-forming liquids journal, November 2009

Finite-temperature critical point of a glass transition journal, July 2010

Under what conditions can a glass be formed? journal, September 1969

Nonlinearities in the undercooled properties of Ti 39.5 Zr 39.5 Ni 21 journal, January 2006

Compilation of the fragility parameters for several glass-forming metallic alloys journal, January 1999

From boiling point to glass transition temperature: Transport coefficients in molecular liquids follow three-parameter scaling journal, October 2012

Viscosity, Plasticity, and Diffusion as Examples of Absolute Reaction Rates
journal, April 1936

Why does the quark–gluon plasma at RHIC behave as a nearly ideal fluid?
journal, July 2004

Vogel–Fulcher–Tammann plot for viscosity scaled with temperature interval between actual and ideal glass transitions for metallic glasses in liquid and supercooled liquid states
journal, April 2010

Corresponding States of Structural Glass Formers
journal, April 2009

Thermodynamic determination of fragility in liquids and a fragile-to-strong liquid transition in water
journal, April 1999

High-temperature contactless viscosity measurements by the gas–film levitation technique: Application to oxide and metallic glasses
journal, September 2002

Viscosity of molten Pd ₈₂ Si ₁₈ and the scaling of viscosities of glass forming systems
journal, July 1992

Equilibrium viscosity of Zr–Cu–Ni–Al–Nb bulk metallic glasses
journal, September 2010

A structural signature of liquid fragility
journal, August 2014

Viscosity of molten Pd ₄₀ Ni ₄₀ P ₂₀
journal, November 1991

Nonlinearities in the undercooled properties of Ti _39.5 Zr _39.5 Ni ₂₁
journal, January 2006

Transport properties of glass-forming liquids suggest that dynamic crossover temperature is as important as the glass transition temperature
journal, December 2010

Thermodynamics and kinetics of the Mg65Cu25Y10 bulk metallic glass forming liquid
journal, April 1998

Compilation of the fragility parameters for several glass-forming metallic alloys
journal, January 1999

Theory of Structural Glasses and Supercooled Liquids
journal, May 2007

Recent tests of the mode-coupling theory for glassy dynamics
journal, January 1999

Fitting of viscosity: Distinguishing the temperature dependences predicted by various models of supercooled liquids
journal, January 1996

Crossover to potential energy landscape dominated dynamics in a model glass-forming liquid
journal, June 2000

Rheology and Ultrasonic Properties of Metallic Glass-Forming Liquids: A Potential Energy Landscape Perspective
journal, August 2007

A thermodynamic theory of supercooled liquids
journal, September 1995

From boiling point to glass transition temperature: Transport coefficients in molecular liquids follow three-parameter scaling
journal, October 2012

The influence of shear rate and temperature on the viscosity and fragility of the Zr41.2Ti13.8Cu12.5Ni10.0Be22.5 metallic-glass-forming liquid
journal, May 2007

Breakdown of the Stokes–Einstein relation in supercooled liquids
journal, August 1995

On the ergodicity of supercooled molecular glass-forming liquids at the dynamical arrest: the o-terphenyl case
journal, January 2014

Containerless Measurements of Thermophysical Properties of Zr54Ti8Cu20Al10Ni8
journal, September 2006

Disentangling density and temperature effects in the viscous slowing down of glassforming liquids
journal, April 2004

The effect of cooling rates on the apparent fragility of Zr-based bulk metallic glasses
journal, June 2010

Study of the structural relaxation of Pd82Si18 metallic glass by thermal expansion and viscous flow measurements
journal, March 1991

A thermodynamic connection to the fragility of glass-forming liquids
journal, April 2001

Finite-temperature critical point of a glass transition
journal, July 2010

Viscosity of glass-forming liquids
journal, November 2009

Under what conditions can a glass be formed?
journal, September 1969

First X-Ray Scattering Studies on Electrostatically Levitated Metallic Liquids: Demonstrated Influence of Local Icosahedral Order on the Nucleation Barrier
journal, May 2003

Formation of Glasses from Liquids and Biopolymers
journal, March 1995

S PATIALLY H ETEROGENEOUS D YNAMICS IN S UPERCOOLED L IQUIDS
journal, October 2000

Anomalous structural evolution in Cu ₅₀ Zr ₅₀ glass-forming liquids
journal, July 2013

Correlation between kinetic strength, volumetric properties, and glass forming ability in metallic liquids
journal, September 2013

The frustration-based approach of supercooled liquids and the glass transition: a review and critical assessment
journal, December 2005

Origin of the Vogel–Fulcher–Tammann law in glass-forming materials: the α–β bifurcation
journal, July 2000

Cooperative Shear Model for the Rheology of Glass-Forming Metallic Liquids
journal, August 2006

Universal representation of viscosity in glass forming liquids
journal, January 1998

Newtonian and non-Newtonian viscosity of supercooled liquid in metallic glasses
journal, May 2001

Surface Tension and Viscosity of Quasicrystal-Forming Ti–Zr–Ni Alloys
journal, July 2004

Undercooled Liquid Viscosity and Glass Formation of a M g ₆₂ C u ₂₆ Y ₁₂ Alloy
journal, January 1996

Investigation of specific volume of glass-forming Pd–Cu–Ni–P alloy in the liquid, vitreous and crystalline state
journal, October 2002

Viscosity in Strongly Interacting Quantum Field Theories from Black Hole Physics
journal, March 2005

Scaling concepts for the dynamics of viscous liquids near an ideal glassy state
journal, July 1989

Measurement of the self-intermediate scattering function of suspensions of hard spherical particles near the glass transition
journal, November 1998

Icosahedral Short-Range Order in Deeply Undercooled Metallic Melts
journal, July 2002

Study of the structural relaxation of Pd₈₂Si₁₈ metallic glass by thermal expansion and viscous flow measurements
book, January 1991

Corresponding States of Structural Glass Formers
text, January 2008

Finite-temperature critical point of a glass transition
text, January 2010

Connectivity of the Icosahedral Network and a Dramatically Growing Static Length Scale in Cu-Zr Binary Metallic Glasses
text, January 2013

Disentangling density and temperature effects in the viscous slowing down of glassforming liquids
text, January 2003

The frustration-based approach of supercooled liquids and the glass transition: a review and critical assessment
text, January 2005

Crossover to Potential Energy Landscape Dominated Dynamics in a Model Glass-forming Liquid
text, January 1999

Why does the Quark-Gluon Plasma at RHIC behave as a nearly ideal fluid ?
text, January 2003

A thermodynamic theory of supercooled liquids
journal, September 1995

Study of the structural relaxation of Pd82Si18 metallic glass by thermal expansion and viscous flow measurements
journal, March 1991

Vogel–Fulcher–Tammann plot for viscosity scaled with temperature interval between actual and ideal glass transitions for metallic glasses in liquid and supercooled liquid states
journal, April 2010

Why does the quark–gluon plasma at RHIC behave as a nearly ideal fluid?
journal, July 2004

Thermodynamic determination of fragility in liquids and a fragile-to-strong liquid transition in water
journal, April 1999

A thermodynamic connection to the fragility of glass-forming liquids
journal, April 2001

A structural signature of liquid fragility
journal, August 2014

On the ergodicity of supercooled molecular glass-forming liquids at the dynamical arrest: the o-terphenyl case
journal, January 2014

Viscosity, Plasticity, and Diffusion as Examples of Absolute Reaction Rates
journal, April 1936

The effect of cooling rates on the apparent fragility of Zr-based bulk metallic glasses
journal, June 2010

Viscosity of molten Pd ₄₀ Ni ₄₀ P ₂₀
journal, November 1991

Viscosity of molten Pd ₈₂ Si ₁₈ and the scaling of viscosities of glass forming systems
journal, July 1992

Breakdown of the Stokes–Einstein relation in supercooled liquids
journal, August 1995

Anomalous structural evolution in Cu ₅₀ Zr ₅₀ glass-forming liquids
journal, July 2013

Viscosity of glass-forming liquids
journal, November 2009

Finite-temperature critical point of a glass transition
journal, July 2010

Under what conditions can a glass be formed?
journal, September 1969

Nonlinearities in the undercooled properties of Ti _39.5 Zr _39.5 Ni ₂₁
journal, January 2006

Compilation of the fragility parameters for several glass-forming metallic alloys
journal, January 1999

From boiling point to glass transition temperature: Transport coefficients in molecular liquids follow three-parameter scaling
journal, October 2012

First X-Ray Scattering Studies on Electrostatically Levitated Metallic Liquids: Demonstrated Influence of Local Icosahedral Order on the Nucleation Barrier
journal, May 2003

Theory of Structural Glasses and Supercooled Liquids
journal, May 2007

Corresponding States of Structural Glass Formers
text, January 2008