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Title: Undecametallic and hexadecametallic ferric oxo–hydroxo/ethoxo pivalate clusters

The synthesis strategies for highly condensed {Fe11} and {Fe16} pivalate clusters have been developed based on archetypal geometrically frustrated triangular {Fe33-O)} motifs that are interlinked via oxo, hydroxo, ethoxo, and carboxylate groups.
Authors:
 [1] ;  [2] ;  [2] ;  [3] ;  [4]
  1. RWTH Aachen Univ., Aachen (Germany); Institute of Applied Physics, Chinsinau (Moldova)
  2. RWTH Aachen Univ., Aachen (Germany)
  3. Ames Lab., Ames, IA (United States)
  4. RWTH Aachen Univ., Aachen (Germany); Peter Grunberg Institute, Julich (Germany)
Publication Date:
OSTI Identifier:
1221637
Grant/Contract Number:
W-7405-ENG-82
Type:
Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Volume: 44; Journal Issue: 17; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry
Research Org:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Org:
USDOE Office of Science (SC)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY