A single crystalline porphyrinic titanium metal–organic framework
Abstract
We successfully assembled the photocatalytic titanium-oxo cluster and photosensitizing porphyrinic linker into a metal–organic framework (MOF), namely PCN-22. A preformed titanium-oxo carboxylate cluster is adopted as the starting material to judiciously control the MOF growth process to afford single crystals. This synthetic method is useful to obtain highly crystalline titanium MOFs, which has been a daunting challenge in this field. Moreover, PCN-22 demonstrated permanent porosity and photocatalytic activities toward alcohol oxidation.
- Authors:
-
- Department of Chemistry, Texas A&M University, College Station, USA
- Advanced Light Source, Lawrence Berkeley National Laboratory Berkeley, USA
- Institute of Chemical Sciences, Heriot-Watt University Riccarton, Edinburgh EH14 4AS, UK
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Advanced Research Projects Agency - Energy (ARPA-E); USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1490498
- Alternate Identifier(s):
- OSTI ID: 1214548
- Grant/Contract Number:
- AR0000249; AC02-05CH11231.; SC0001015; AC02-05CH11231; N000141310753; A-1725
- Resource Type:
- Published Article
- Journal Name:
- Chemical Science
- Additional Journal Information:
- Journal Name: Chemical Science Journal Volume: 6 Journal Issue: 7; Journal ID: ISSN 2041-6520
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Yuan, Shuai, Liu, Tian-Fu, Feng, Dawei, Tian, Jian, Wang, Kecheng, Qin, Junsheng, Zhang, Qiang, Chen, Ying-Pin, Bosch, Mathieu, Zou, Lanfang, Teat, Simon J., Dalgarno, Scott J., and Zhou, Hong-Cai. A single crystalline porphyrinic titanium metal–organic framework. United Kingdom: N. p., 2015.
Web. doi:10.1039/C5SC00916B.
Yuan, Shuai, Liu, Tian-Fu, Feng, Dawei, Tian, Jian, Wang, Kecheng, Qin, Junsheng, Zhang, Qiang, Chen, Ying-Pin, Bosch, Mathieu, Zou, Lanfang, Teat, Simon J., Dalgarno, Scott J., & Zhou, Hong-Cai. A single crystalline porphyrinic titanium metal–organic framework. United Kingdom. https://doi.org/10.1039/C5SC00916B
Yuan, Shuai, Liu, Tian-Fu, Feng, Dawei, Tian, Jian, Wang, Kecheng, Qin, Junsheng, Zhang, Qiang, Chen, Ying-Pin, Bosch, Mathieu, Zou, Lanfang, Teat, Simon J., Dalgarno, Scott J., and Zhou, Hong-Cai. Mon .
"A single crystalline porphyrinic titanium metal–organic framework". United Kingdom. https://doi.org/10.1039/C5SC00916B.
@article{osti_1490498,
title = {A single crystalline porphyrinic titanium metal–organic framework},
author = {Yuan, Shuai and Liu, Tian-Fu and Feng, Dawei and Tian, Jian and Wang, Kecheng and Qin, Junsheng and Zhang, Qiang and Chen, Ying-Pin and Bosch, Mathieu and Zou, Lanfang and Teat, Simon J. and Dalgarno, Scott J. and Zhou, Hong-Cai},
abstractNote = {We successfully assembled the photocatalytic titanium-oxo cluster and photosensitizing porphyrinic linker into a metal–organic framework (MOF), namely PCN-22. A preformed titanium-oxo carboxylate cluster is adopted as the starting material to judiciously control the MOF growth process to afford single crystals. This synthetic method is useful to obtain highly crystalline titanium MOFs, which has been a daunting challenge in this field. Moreover, PCN-22 demonstrated permanent porosity and photocatalytic activities toward alcohol oxidation.},
doi = {10.1039/C5SC00916B},
journal = {Chemical Science},
number = 7,
volume = 6,
place = {United Kingdom},
year = {Mon Jun 15 00:00:00 EDT 2015},
month = {Mon Jun 15 00:00:00 EDT 2015}
}
Free Publicly Available Full Text
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https://doi.org/10.1039/C5SC00916B
https://doi.org/10.1039/C5SC00916B
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Cited by: 196 works
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Web of Science
Figures / Tables:
Fig. 1: (a) Microscope image of PCN-22 crystals; (b) structure of the Ti7O6 cluster (only O atoms of DEFmolecules are shown for clarity); (c) representation of the tetratopic TCPP linker (left) and 12-connected Ti7O6 cluster (right); (d) views of the structure of PCN-22 along a-axis and (e) b-axis. Color scheme:more »
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