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Title: Uranium and thorium complexes of the phosphaethynolate ion

New tris-amidinate actinide (Th, U) complexes containing a rare O-bound terminal phosphaethynolate (OCP⁻) ligand were synthesized and fully characterized. The cyanate (OCN⁻) and thiocyanate (SCN⁻) analogs were prepared for comparison and feature a preferential N-coordination to the actinide metals. The Th(amid)3(OCP) complex reacts with Ni(COD)2 to yield the heterobimetallic adduct (amid)3Th(μ-η1(O):η2(C,P)-OCP)Ni(COD) featuring an unprecedented reduced (OCP⁻) bent fragment bridging the two metals.
Authors:
 [1] ;  [1] ;  [2] ;  [3] ;  [3] ;  [2] ;  [1]
  1. Lawrence Berkeley National Lab., Berkeley, CA (United States). Chemical Sciences Div.
  2. Universit´e de Toulouse, Toulouse (France). LPCNO.
  3. Univ. of Oxford, Oxford (United Kingdom). Dept. of Chemisty.
Publication Date:
OSTI Identifier:
1214437
Grant/Contract Number:
AC02-05CH11231; NIH S10-RR027172
Type:
Accepted Manuscript
Journal Name:
Chemical Science
Additional Journal Information:
Journal Volume: 6; Journal Issue: 11; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry
Research Org:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English