Ultrahigh surface area carbon from carbonated beverages. Combining self-templaing process and in situ activation
Abstract
Ultrahigh surface area carbons (USACs, e.g., >2000 m2/g) are attracting tremendous attention due to their outstanding performance in energy-related applications. The state-of-art approaches to USACs involve templating or activation methods and all these techniques show certain drawbacks. In this work, a series of USACs with specific surface areas up to 3633 m2/g were prepared in two steps: hydrothermal carbonization (200 °C) of carbonated beverages (CBs) and further thermal treatment in nitrogen (600–1000 °C). The rich inner porosity is formed by a self-templated process during which acids and polyelectrolyte sodium salts in the beverage formulas make some contribution. This strategy covers various CBs such as Coca Cola®, Pepsi Cola®, Dr. Pepper®, andFanta® and it enables an acceptable product yield (based on sugars), for example: 21 wt% for carbon (2940 m2/g) from Coca Cola®. Being potential electrode materials for supercapacitors, those carbon materials possessed a good specific capacitance (57.2–185.7 F g-1) even at a scan rate of 1000 mV s-1. Thus, a simple and efficient strategy to USACs has been presented.
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1214034
- Alternate Identifier(s):
- OSTI ID: 1246657
- Grant/Contract Number:
- AC05-00OR22725; ERKCC61
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Carbon
- Additional Journal Information:
- Journal Volume: 93; Journal ID: ISSN 0008-6223
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Zhang, Pengfei, Zhang, Zhiyong, Chen, Jihua, and Dai, Sheng. Ultrahigh surface area carbon from carbonated beverages. Combining self-templaing process and in situ activation. United States: N. p., 2015.
Web. doi:10.1016/j.carbon.2015.05.019.
Zhang, Pengfei, Zhang, Zhiyong, Chen, Jihua, & Dai, Sheng. Ultrahigh surface area carbon from carbonated beverages. Combining self-templaing process and in situ activation. United States. https://doi.org/10.1016/j.carbon.2015.05.019
Zhang, Pengfei, Zhang, Zhiyong, Chen, Jihua, and Dai, Sheng. Mon .
"Ultrahigh surface area carbon from carbonated beverages. Combining self-templaing process and in situ activation". United States. https://doi.org/10.1016/j.carbon.2015.05.019. https://www.osti.gov/servlets/purl/1214034.
@article{osti_1214034,
title = {Ultrahigh surface area carbon from carbonated beverages. Combining self-templaing process and in situ activation},
author = {Zhang, Pengfei and Zhang, Zhiyong and Chen, Jihua and Dai, Sheng},
abstractNote = {Ultrahigh surface area carbons (USACs, e.g., >2000 m2/g) are attracting tremendous attention due to their outstanding performance in energy-related applications. The state-of-art approaches to USACs involve templating or activation methods and all these techniques show certain drawbacks. In this work, a series of USACs with specific surface areas up to 3633 m2/g were prepared in two steps: hydrothermal carbonization (200 °C) of carbonated beverages (CBs) and further thermal treatment in nitrogen (600–1000 °C). The rich inner porosity is formed by a self-templated process during which acids and polyelectrolyte sodium salts in the beverage formulas make some contribution. This strategy covers various CBs such as Coca Cola®, Pepsi Cola®, Dr. Pepper®, andFanta® and it enables an acceptable product yield (based on sugars), for example: 21 wt% for carbon (2940 m2/g) from Coca Cola®. Being potential electrode materials for supercapacitors, those carbon materials possessed a good specific capacitance (57.2–185.7 F g-1) even at a scan rate of 1000 mV s-1. Thus, a simple and efficient strategy to USACs has been presented.},
doi = {10.1016/j.carbon.2015.05.019},
journal = {Carbon},
number = ,
volume = 93,
place = {United States},
year = {Mon May 11 00:00:00 EDT 2015},
month = {Mon May 11 00:00:00 EDT 2015}
}
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