Visualization of electrochemically driven solid-state phase transformations using operando hard X-ray spectro-imaging
Abstract
In situ techniques with high temporal, spatial and chemical resolution are key to understand ubiquitous solid-state phase transformations, which are crucial to many technological applications. Hard X-ray spectro-imaging can visualize electrochemically driven phase transformations but demands considerably large samples with strong absorption signal so far. Here we show a conceptually new data analysis method to enable operando visualization of mechanistically relevant weakly absorbing samples at the nanoscale and study electrochemical reaction dynamics of iron fluoride, a promising high-capacity conversion cathode material. In two specially designed samples with distinctive microstructure and porosity, we observe homogeneous phase transformations during both discharge and charge, faster and more complete Li-storage occurring in porous polycrystalline iron fluoride, and further, incomplete charge reaction following a pathway different from conventional belief. In conclusion, these mechanistic insights provide guidelines for designing better conversion cathode materials to realize the promise of high-capacity lithium-ion batteries.
- Authors:
-
- Univ. of Wisconsin-Madison, Madison, WI (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States). Photon Sciences Directorate
- Brookhaven National Lab. (BNL), Upton, NY (United States). Dept. of Sustainable Energy Technologies
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS); Univ. of Illinois, Chicago, IL (United States)
- Univ. of Illinois, Chicago, IL (United States)
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Northeastern Center for Chemical Energy Storage (NECCES)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1210604
- Grant/Contract Number:
- SC0001294; SC0012583; AC02- 98CH10886
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 6; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; energy storage (including batteries and capacitors); defects; charge transport; materials and chemistry by design; synthesis (novel materials)
Citation Formats
Li, Linsen, Chen-Wiegart, Yu-chen Karen, Wang, Jiajun, Gao, Peng, Ding, Qi, Yu, Young-Sang, Wang, Feng, Cabana, Jordi, Wang, Jun, and Jin, Song. Visualization of electrochemically driven solid-state phase transformations using operando hard X-ray spectro-imaging. United States: N. p., 2015.
Web. doi:10.1038/ncomms7883.
Li, Linsen, Chen-Wiegart, Yu-chen Karen, Wang, Jiajun, Gao, Peng, Ding, Qi, Yu, Young-Sang, Wang, Feng, Cabana, Jordi, Wang, Jun, & Jin, Song. Visualization of electrochemically driven solid-state phase transformations using operando hard X-ray spectro-imaging. United States. https://doi.org/10.1038/ncomms7883
Li, Linsen, Chen-Wiegart, Yu-chen Karen, Wang, Jiajun, Gao, Peng, Ding, Qi, Yu, Young-Sang, Wang, Feng, Cabana, Jordi, Wang, Jun, and Jin, Song. Mon .
"Visualization of electrochemically driven solid-state phase transformations using operando hard X-ray spectro-imaging". United States. https://doi.org/10.1038/ncomms7883. https://www.osti.gov/servlets/purl/1210604.
@article{osti_1210604,
title = {Visualization of electrochemically driven solid-state phase transformations using operando hard X-ray spectro-imaging},
author = {Li, Linsen and Chen-Wiegart, Yu-chen Karen and Wang, Jiajun and Gao, Peng and Ding, Qi and Yu, Young-Sang and Wang, Feng and Cabana, Jordi and Wang, Jun and Jin, Song},
abstractNote = {In situ techniques with high temporal, spatial and chemical resolution are key to understand ubiquitous solid-state phase transformations, which are crucial to many technological applications. Hard X-ray spectro-imaging can visualize electrochemically driven phase transformations but demands considerably large samples with strong absorption signal so far. Here we show a conceptually new data analysis method to enable operando visualization of mechanistically relevant weakly absorbing samples at the nanoscale and study electrochemical reaction dynamics of iron fluoride, a promising high-capacity conversion cathode material. In two specially designed samples with distinctive microstructure and porosity, we observe homogeneous phase transformations during both discharge and charge, faster and more complete Li-storage occurring in porous polycrystalline iron fluoride, and further, incomplete charge reaction following a pathway different from conventional belief. In conclusion, these mechanistic insights provide guidelines for designing better conversion cathode materials to realize the promise of high-capacity lithium-ion batteries.},
doi = {10.1038/ncomms7883},
journal = {Nature Communications},
number = ,
volume = 6,
place = {United States},
year = {Mon Apr 20 00:00:00 EDT 2015},
month = {Mon Apr 20 00:00:00 EDT 2015}
}
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Works referenced in this record:
Capturing metastable structures during high-rate cycling of LiFePO4 nanoparticle electrodes
journal, June 2014
- Liu, H.; Strobridge, F. C.; Borkiewicz, O. J.
- Science, Vol. 344, Issue 6191
Structural changes in a commercial lithium-ion battery during electrochemical cycling: An in situ neutron diffraction study
journal, December 2010
- Sharma, Neeraj; Peterson, Vanessa K.; Elcombe, Margaret M.
- Journal of Power Sources, Vol. 195, Issue 24
Understanding the Rate Capability of High-Energy-Density Li-Rich Layered Li 1.2 Ni 0.15 Co 0.1 Mn 0.55 O 2 Cathode Materials
journal, December 2013
- Yu, Xiqian; Lyu, Yingchun; Gu, Lin
- Advanced Energy Materials, Vol. 4, Issue 5
Origin of additional capacities in metal oxide lithium-ion battery electrodes
journal, November 2013
- Hu, Yan-Yan; Liu, Zigeng; Nam, Kyung-Wan
- Nature Materials, Vol. 12, Issue 12
In Situ Observation of the Electrochemical Lithiation of a Single SnO2 Nanowire Electrode
journal, December 2010
- Huang, J. Y.; Zhong, L.; Wang, C. M.
- Science, Vol. 330, Issue 6010, p. 1515-1520
Tracking lithium transport and electrochemical reactions in nanoparticles
journal, January 2012
- Wang, Feng; Yu, Hui-Chia; Chen, Min-Hua
- Nature Communications, Vol. 3, Issue 1
Demonstration of an Electrochemical Liquid Cell for Operando Transmission Electron Microscopy Observation of the Lithiation/Delithiation Behavior of Si Nanowire Battery Anodes
journal, November 2013
- Gu, Meng; Parent, Lucas R.; Mehdi, B. Layla
- Nano Letters, Vol. 13, Issue 12
Facet development during platinum nanocube growth
journal, August 2014
- Liao, H. -G.; Zherebetskyy, D.; Xin, H.
- Science, Vol. 345, Issue 6199
Hard X-ray Spectroscopic Nano-Imaging of Hierarchical Functional Materials at Work
journal, September 2013
- Andrews, Joy C.; Weckhuysen, Bert M.
- ChemPhysChem, Vol. 14, Issue 16
Three-dimensional imaging of chemical phase transformations at the nanoscale with full-field transmission X-ray microscopy
journal, July 2011
- Meirer, Florian; Cabana, Jordi; Liu, Yijin
- Journal of Synchrotron Radiation, Vol. 18, Issue 5
Automated markerless full field hard x-ray microscopic tomography at sub-50 nm 3-dimension spatial resolution
journal, April 2012
- Wang, Jun; Karen Chen, Yu-chen; Yuan, Qingxi
- Applied Physics Letters, Vol. 100, Issue 14
Visualization and Quantification of Electrochemical and Mechanical Degradation in Li Ion Batteries
journal, October 2013
- Ebner, M.; Marone, F.; Stampanoni, M.
- Science, Vol. 342, Issue 6159
In Operando X-ray Diffraction and Transmission X-ray Microscopy of Lithium Sulfur Batteries
journal, March 2012
- Nelson, Johanna; Misra, Sumohan; Yang, Yuan
- Journal of the American Chemical Society, Vol. 134, Issue 14
Study on Microstructural Deformation of Working Sn and SnSb Anode Particles for Li-Ion Batteries by in Situ Transmission X-ray Microscopy
journal, October 2011
- Chao, Sung-Chieh; Song, Yen-Fang; Wang, Chun-Chieh
- The Journal of Physical Chemistry C, Vol. 115, Issue 44
Insitu nanotomography and operando transmission X-ray microscopy of micron-sized Ge particles
journal, January 2014
- Weker, J. Nelson; Liu, N.; Misra, S.
- Energy Environ. Sci., Vol. 7, Issue 8
In situ chemical mapping of a lithium-ion battery using full-field hard X-ray spectroscopic imaging
journal, January 2013
- Wang, Jiajun; Chen-Wiegart, Yu-chen Karen; Wang, Jun
- Chemical Communications, Vol. 49, Issue 58
Nanoscale Morphological and Chemical Changes of High Voltage Lithium–Manganese Rich NMC Composite Cathodes with Cycling
journal, July 2014
- Yang, Feifei; Liu, Yijin; Martha, Surendra K.
- Nano Letters, Vol. 14, Issue 8
In operando tracking phase transformation evolution of lithium iron phosphate with hard X-ray microscopy
journal, August 2014
- Wang, Jiajun; Chen-Wiegart, Yu-chen Karen; Wang, Jun
- Nature Communications, Vol. 5, Issue 1
Nonequilibrium Pathways during Electrochemical Phase Transformations in Single Crystals Revealed by Dynamic Chemical Imaging at Nanoscale Resolution
journal, December 2014
- Yu, Young-Sang; Kim, Chunjoong; Liu, Yijin
- Advanced Energy Materials, Vol. 5, Issue 7
Beyond Intercalation-Based Li-Ion Batteries: The State of the Art and Challenges of Electrode Materials Reacting Through Conversion Reactions
journal, August 2010
- Cabana, Jordi; Monconduit, Laure; Larcher, Dominique
- Advanced Materials, Vol. 22, Issue 35
Li-Storage via Heterogeneous Reaction in Selected Binary Metal Fluorides and Oxides
journal, January 2004
- Li, Hong; Balaya, Palani; Maier, Joachim
- Journal of The Electrochemical Society, Vol. 151, Issue 11, p. A1878-A1885
Carbon Metal Fluoride Nanocomposites: High-Capacity Reversible Metal Fluoride Conversion Materials as Rechargeable Positive Electrodes for Li Batteries
journal, January 2003
- Badway, F.; Cosandey, F.; Pereira, N.
- Journal of The Electrochemical Society, Vol. 150, Issue 10, p. A1318-A1327
Carbon-Metal Fluoride Nanocomposites: Structure and Electrochemistry of FeF3 : C
journal, January 2003
- Badway, F.; Pereira, N.; Cosandey, F.
- Journal of The Electrochemical Society, Vol. 150, Issue 9, p. A1209-A1218
High-Capacity Lithium-Ion Battery Conversion Cathodes Based on Iron Fluoride Nanowires and Insights into the Conversion Mechanism
journal, October 2012
- Li, Linsen; Meng, Fei; Jin, Song
- Nano Letters, Vol. 12, Issue 11, p. 6030-6037
Reversible Formation and Decomposition of LiF Clusters Using Transition Metal Fluorides as Precursors and Their Application in Rechargeable Li Batteries
journal, May 2003
- Li, H.; Richter, G.; Maier, J.
- Advanced Materials, Vol. 15, Issue 9
A High-Capacity Cathode for Lithium Batteries Consisting of Porous Microspheres of Highly Amorphized Iron Fluoride Densified from Its Open Parent Phase
journal, August 2012
- Li, Chilin; Mu, Xiaoke; van Aken, Peter A.
- Advanced Energy Materials, Vol. 3, Issue 1
Fabrication of FeF3 Nanoflowers on CNT Branches and Their Application to High Power Lithium Rechargeable Batteries
journal, October 2010
- Kim, Sung-Wook; Seo, Dong-Hwa; Gwon, Hyeokjo
- Advanced Materials, Vol. 22, Issue 46
Interconnected hollow carbon nanospheres for stable lithium metal anodes
journal, July 2014
- Zheng, Guangyuan; Lee, Seok Woo; Liang, Zheng
- Nature Nanotechnology, Vol. 9, Issue 8
Building better batteries
journal, February 2008
- Armand, M.; Tarascon, J.-M.
- Nature, Vol. 451, Issue 7179, p. 652-657
Identifying the Local Structures Formed during Lithiation of the Conversion Material, Iron Fluoride, in a Li Ion Battery: A Solid-State NMR, X-ray Diffraction, and Pair Distribution Function Analysis Study
journal, August 2009
- Yamakawa, Naoko; Jiang, Meng; Key, Baris
- Journal of the American Chemical Society, Vol. 131, Issue 30
First-Principles Investigation of the Li−Fe−F Phase Diagram and Equilibrium and Nonequilibrium Conversion Reactions of Iron Fluorides with Lithium
journal, August 2008
- Doe, Robert E.; Persson, Kristin A.; Meng, Y. Shirley
- Chemistry of Materials, Vol. 20, Issue 16
Thermodynamics and Kinetics of the Li/FeF 3 Reaction by Electrochemical Analysis
journal, February 2012
- Liu, Ping; Vajo, John J.; Wang, John S.
- The Journal of Physical Chemistry C, Vol. 116, Issue 10
Conversion Reaction Mechanisms in Lithium Ion Batteries: Study of the Binary Metal Fluoride Electrodes
journal, November 2011
- Wang, Feng; Robert, Rosa; Chernova, Natasha A.
- Journal of the American Chemical Society, Vol. 133, Issue 46
In Situ Electrochemical XAFS Studies on an Iron Fluoride High-Capacity Cathode Material for Rechargeable Lithium Batteries
journal, May 2013
- Zhang, Wei; Duchesne, Paul N.; Gong, Zheng-Liang
- The Journal of Physical Chemistry C, Vol. 117, Issue 22
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005
- Ravel, B.; Newville, M.
- Journal of Synchrotron Radiation, Vol. 12, Issue 4
A method for normalization of X-ray absorption spectra
journal, June 2005
- Weng, Tsu-Chien; Waldo, Geoffrey S.; Penner-Hahn, James E.
- Journal of Synchrotron Radiation, Vol. 12, Issue 4
Mechanism and Kinetics of Spontaneous Nanotube Growth Driven by Screw Dislocations
journal, April 2010
- Morin, S. A.; Bierman, M. J.; Tong, J.
- Science, Vol. 328, Issue 5977
Screw Dislocation Driven Growth of Nanomaterials
journal, June 2013
- Meng, Fei; Morin, Stephen A.; Forticaux, Audrey
- Accounts of Chemical Research, Vol. 46, Issue 7
Facile Solution Synthesis of α-FeF 3 ·3H 2 O Nanowires and Their Conversion to α-Fe 2 O 3 Nanowires for Photoelectrochemical Application
journal, January 2012
- Li, Linsen; Yu, Yanghai; Meng, Fei
- Nano Letters, Vol. 12, Issue 2
Effect of Vertically Structured Porosity on Electrochemical Performance of FeF2 Films for Lithium Batteries
journal, April 2014
- Parkinson, Matthew F.; Ko, Jonathan K.; Halajko, Anna
- Electrochimica Acta, Vol. 125
Intercalation Pathway in Many-Particle LiFePO 4 Electrode Revealed by Nanoscale State-of-Charge Mapping
journal, February 2013
- Chueh, William C.; El Gabaly, Farid; Sugar, Joshua D.
- Nano Letters, Vol. 13, Issue 3
Current-induced transition from particle-by-particle to concurrent intercalation in phase-separating battery electrodes
journal, September 2014
- Li, Yiyang; El Gabaly, Farid; Ferguson, Todd R.
- Nature Materials, Vol. 13, Issue 12
EELS Spectroscopy of Iron Fluorides and FeFx/C Nanocomposite Electrodes Used in Li-Ion Batteries
journal, February 2007
- Cosandey, Frederic; Al-Sharab, Jafar F.; Badway, Fadwa
- Microscopy and Microanalysis, Vol. 13, Issue 02, p. 87-95
Comprehensive Study of the CuF 2 Conversion Reaction Mechanism in a Lithium Ion Battery
journal, July 2014
- Hua, Xiao; Robert, Rosa; Du, Lin-Shu
- The Journal of Physical Chemistry C, Vol. 118, Issue 28
High-purity iron pyrite (FeS 2 ) nanowires as high-capacity nanostructured cathodes for lithium-ion batteries
journal, January 2014
- Li, Linsen; Cabán-Acevedo, Miguel; Girard, Steven N.
- Nanoscale, Vol. 6, Issue 4
Chemical composition mapping with nanometre resolution by soft X-ray microscopy
journal, September 2014
- Shapiro, David A.; Yu, Young-Sang; Tyliszczak, Tolek
- Nature Photonics, Vol. 8, Issue 10
Building a better battery
journal, February 2019
- Kugler, Logan
- Communications of the ACM, Vol. 62, Issue 3
Beyond Intercalation-Based Li-Ion Batteries: The State of the Art and Challenges of Electrode Materials Reacting Through Conversion Reactions
journal, August 2010
- Cabana, Jordi; Monconduit, Laure; Larcher, Dominique
- Advanced Materials, Vol. 22, Issue 35
Fabrication of FeF3 Nanoflowers on CNT Branches and Their Application to High Power Lithium Rechargeable Batteries
journal, October 2010
- Kim, Sung-Wook; Seo, Dong-Hwa; Gwon, Hyeokjo
- Advanced Materials, Vol. 22, Issue 46
Hard X-ray Spectroscopic Nano-Imaging of Hierarchical Functional Materials at Work
journal, September 2013
- Andrews, Joy C.; Weckhuysen, Bert M.
- ChemPhysChem, Vol. 14, Issue 16
Screw Dislocation Driven Growth of Nanomaterials
journal, June 2013
- Meng, Fei; Morin, Stephen A.; Forticaux, Audrey
- Accounts of Chemical Research, Vol. 46, Issue 7
In Operando X-ray Diffraction and Transmission X-ray Microscopy of Lithium Sulfur Batteries
journal, March 2012
- Nelson, Johanna; Misra, Sumohan; Yang, Yuan
- Journal of the American Chemical Society, Vol. 134, Issue 14
Facile Solution Synthesis of α-FeF 3 ·3H 2 O Nanowires and Their Conversion to α-Fe 2 O 3 Nanowires for Photoelectrochemical Application
journal, January 2012
- Li, Linsen; Yu, Yanghai; Meng, Fei
- Nano Letters, Vol. 12, Issue 2
High-Capacity Lithium-Ion Battery Conversion Cathodes Based on Iron Fluoride Nanowires and Insights into the Conversion Mechanism
journal, October 2012
- Li, Linsen; Meng, Fei; Jin, Song
- Nano Letters, Vol. 12, Issue 11, p. 6030-6037
Demonstration of an Electrochemical Liquid Cell for Operando Transmission Electron Microscopy Observation of the Lithiation/Delithiation Behavior of Si Nanowire Battery Anodes
journal, November 2013
- Gu, Meng; Parent, Lucas R.; Mehdi, B. Layla
- Nano Letters, Vol. 13, Issue 12
Nanoscale Morphological and Chemical Changes of High Voltage Lithium–Manganese Rich NMC Composite Cathodes with Cycling
journal, July 2014
- Yang, Feifei; Liu, Yijin; Martha, Surendra K.
- Nano Letters, Vol. 14, Issue 8
Building better batteries
journal, February 2008
- Armand, M.; Tarascon, J.-M.
- Nature, Vol. 451, Issue 7179, p. 652-657
Tracking lithium transport and electrochemical reactions in nanoparticles
journal, January 2012
- Wang, Feng; Yu, Hui-Chia; Chen, Min-Hua
- Nature Communications, Vol. 3, Issue 1
In operando tracking phase transformation evolution of lithium iron phosphate with hard X-ray microscopy
journal, August 2014
- Wang, Jiajun; Chen-Wiegart, Yu-chen Karen; Wang, Jun
- Nature Communications, Vol. 5, Issue 1
Origin of additional capacities in metal oxide lithium-ion battery electrodes
journal, November 2013
- Hu, Yan-Yan; Liu, Zigeng; Nam, Kyung-Wan
- Nature Materials, Vol. 12, Issue 12
Current-induced transition from particle-by-particle to concurrent intercalation in phase-separating battery electrodes
journal, September 2014
- Li, Yiyang; El Gabaly, Farid; Ferguson, Todd R.
- Nature Materials, Vol. 13, Issue 12
Mechanism and Kinetics of Spontaneous Nanotube Growth Driven by Screw Dislocations
journal, April 2010
- Morin, S. A.; Bierman, M. J.; Tong, J.
- Science, Vol. 328, Issue 5977
Visualization and Quantification of Electrochemical and Mechanical Degradation in Li Ion Batteries
journal, October 2013
- Ebner, M.; Marone, F.; Stampanoni, M.
- Science, Vol. 342, Issue 6159
Carbon Metal Fluoride Nanocomposites: High-Capacity Reversible Metal Fluoride Conversion Materials as Rechargeable Positive Electrodes for Li Batteries
journal, January 2003
- Badway, F.; Cosandey, F.; Pereira, N.
- Journal of The Electrochemical Society, Vol. 150, Issue 10, p. A1318-A1327
Li-Storage via Heterogeneous Reaction in Selected Binary Metal Fluorides and Oxides
journal, January 2004
- Li, Hong; Balaya, Palani; Maier, Joachim
- Journal of The Electrochemical Society, Vol. 151, Issue 11, p. A1878-A1885
Works referencing / citing this record:
Persistent State-of-Charge Heterogeneity in Relaxed, Partially Charged Li 1− x Ni 1/3 Co 1/3 Mn 1/3 O 2 Secondary Particles
journal, May 2016
- Gent, William E.; Li, Yiyang; Ahn, Sungjin
- Advanced Materials, Vol. 28, Issue 31
Revealing the Atomic Origin of Heterogeneous Li‐Ion Diffusion by Probing Na
journal, May 2019
- Xiao, Biwei; Wang, Kuan; Xu, Gui‐Liang
- Advanced Materials, Vol. 31, Issue 29
Review of Recent Development of In Situ/Operando Characterization Techniques for Lithium Battery Research
journal, May 2019
- Liu, Dongqing; Shadike, Zulipiya; Lin, Ruoqian
- Advanced Materials, Vol. 31, Issue 28
Deciphering the Reaction Mechanism of Lithium–Sulfur Batteries by In Situ/Operando Synchrotron‐Based Characterization Techniques
journal, March 2019
- Yan, Yingying; Cheng, Chen; Zhang, Liang
- Advanced Energy Materials, Vol. 9, Issue 18
Kathodenmaterialien für wiederaufladbare Lithiumbatterien
journal, November 2019
- Lee, Wontae; Muhammad, Shoaib; Sergey, Chernov
- Angewandte Chemie, Vol. 132, Issue 7
Advances in the Cathode Materials for Lithium Rechargeable Batteries
journal, February 2020
- Lee, Wontae; Muhammad, Shoaib; Sergey, Chernov
- Angewandte Chemie International Edition, Vol. 59, Issue 7
In Situ Probing Multiple-Scale Structures of Energy Materials for Li-Ion Batteries
journal, May 2019
- Zhu, He; Huang, Yalan; Zhu, Hekang
- Small Methods
Visualization of anisotropic-isotropic phase transformation dynamics in battery electrode particles
journal, August 2016
- Wang, Jiajun; Karen Chen-Wiegart, Yu-chen; Eng, Christopher
- Nature Communications, Vol. 7, Issue 1
Propagation topography of redox phase transformations in heterogeneous layered oxide cathode materials
journal, July 2018
- Mu, Linqin; Yuan, Qingxi; Tian, Chixia
- Nature Communications, Vol. 9, Issue 1
Charge distribution guided by grain crystallographic orientations in polycrystalline battery materials
journal, January 2020
- Xu, Zhengrui; Jiang, Zhisen; Kuai, Chunguang
- Nature Communications, Vol. 11, Issue 1
Electrochemically driven conversion reaction in fluoride electrodes for energy storage devices
journal, April 2018
- Li, Chilin; Chen, Keyi; Zhou, Xuejun
- npj Computational Materials, Vol. 4, Issue 1
Combining operando synchrotron X-ray tomographic microscopy and scanning X-ray diffraction to study lithium ion batteries
journal, June 2016
- Pietsch, Patrick; Hess, Michael; Ludwig, Wolfgang
- Scientific Reports, Vol. 6, Issue 1
Combining operando synchrotron X-ray tomographic microscopy and scanning X-ray diffraction to study lithium ion batteries
text, January 2016
- Wood, Vanessa; Pietsch, Patrick; Hess, Michael
- ETH Zurich
X-ray microscopy
journal, July 1965
- Cosslett, V. E.
- Reports on Progress in Physics, Vol. 28, Issue 1
Visualization of anisotropic-isotropic phase transformation dynamics in battery electrode particles
journal, August 2016
- Wang, Jiajun; Karen Chen-Wiegart, Yu-chen; Eng, Christopher
- Nature Communications, Vol. 7, Issue 1
Phase transformation mechanism in lithium manganese nickel oxide revealed by single-crystal hard X-ray microscopy
journal, February 2017
- Kuppan, Saravanan; Xu, Yahong; Liu, Yijin
- Nature Communications, Vol. 8, Issue 1
Grain boundary mediated hydriding phase transformations in individual polycrystalline metal nanoparticles
journal, October 2017
- Alekseeva, Svetlana; Fanta, Alice Bastos da Silva; Iandolo, Beniamino
- Nature Communications, Vol. 8, Issue 1
Two-dimensional lithium diffusion behavior and probable hybrid phase transformation kinetics in olivine lithium iron phosphate
journal, October 2017
- Hong, Liang; Li, Linsen; Chen-Wiegart, Yuchen-Karen
- Nature Communications, Vol. 8, Issue 1
Charge distribution guided by grain crystallographic orientations in polycrystalline battery materials
journal, January 2020
- Xu, Zhengrui; Jiang, Zhisen; Kuai, Chunguang
- Nature Communications, Vol. 11, Issue 1
Combining operando synchrotron X-ray tomographic microscopy and scanning X-ray diffraction to study lithium ion batteries
text, January 2016
- Wood, Vanessa; Pietsch, Patrick; Hess, Michael
- ETH Zurich