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Title: Correlating size and composition-dependent effects with magnetic, Mössbauer, and pair distribution function measurements in a family of catalytically active ferrite nanoparticles

Abstract

The magnetic spinel ferrites, MFe₂O₄ (wherein 'M' = a divalent metal ion such as but not limited to Mn, Co, Zn, and Ni), represent a unique class of magnetic materials in which the rational introduction of different 'M's can yield correspondingly unique and interesting magnetic behaviors. Herein we present a generalized hydrothermal method for the synthesis of single-crystalline ferrite nanoparticles with 'M' = Mg, Fe, Co, Ni, Cu, and Zn, respectively, which can be systematically and efficaciously produced simply by changing the metal precursor. Our protocol can moreover lead to reproducible size control by judicious selection of various surfactants. As such, we have probed the effects of both (i) size and (ii) chemical composition upon the magnetic properties of these nanomaterials using complementary magnetometry and Mössbauer spectroscopy techniques. The structure of the samples was confirmed by atomic PDF analysis of X-ray and electron powder diffraction data as a function of particle size. These materials retain the bulk spinel structure to the smallest size (i.e., 3 nm). In addition, we have explored the catalytic potential of our ferrites as both (a) magnetically recoverable photocatalysts and (b) biological catalysts, and noted that many of our as-prepared ferrite systems evinced intrinsically higher activitiesmore » as compared with their iron oxide analogues.« less

Authors:
 [1];  [2];  [3];  [4];  [4];  [4];  [5];  [4];  [6];  [4];  [3];  [3];  [7];  [7];  [7];  [8];  [8];  [3]
+ Show Author Affiliations
  1. State Univ. of New York at Stony Brook, Stony Brook, NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)
  2. Villanova Univ., Villanova, PA (United States); Centro Brasileiro de Pesquisas Fisicas, Rio de Janeiro (Brazil)
  3. State Univ. of New York at Stony Brook, Stony Brook, NY (United States)
  4. Brookhaven National Lab. (BNL), Upton, NY (United States)
  5. Columbia Univ., New York, NY (United States)
  6. Brookhaven National Lab. (BNL), Upton, NY (United States); Columbia Univ., New York, NY (United States)
  7. Centro Brasileiro de Pesquisas Fisicas, Rio de Janeiro (Brazil)
  8. Villanova Univ., Villanova, PA (United States)
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Re-Defining Photovoltaic Efficiency Through Molecule Scale Control (RPEMSC); Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1201345
Report Number(s):
BNL-107932-2015-JA
Journal ID: ISSN 0897-4756; R&D Project: PM037; PM032; KC0201030; KC0202010
Grant/Contract Number:  
SC00112704
Resource Type:
Accepted Manuscript
Journal Name:
Chemistry of Materials
Additional Journal Information:
Journal Volume: 27; Journal Issue: 10; Journal ID: ISSN 0897-4756
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; ferrites; nanoparticles; photocatalysis; peroxidase; magnetic properties

Citation Formats

Wong, Stanislaus, Papaefthymiou, Georgia C., Lewis, Crystal S., Han, Jinkyu, Zhang, Cheng, Li, Qiang, Shi, Chenyang, Abeykoon, A. M.Milinda, Billinge, Simon J.L., Stach, Eric, Thomas, Justin, Guerrero, Kevin, Munayco, Pablo, Munayco, Jimmy, Scorzelli, Rosa B., Burnham, Philip, Viescas, Arthur J, and Tiano, Amanda L. Correlating size and composition-dependent effects with magnetic, Mössbauer, and pair distribution function measurements in a family of catalytically active ferrite nanoparticles. United States: N. p., 2015. Web. doi:10.1021/acs.chemmater.5b00767.
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Wong, Stanislaus, Papaefthymiou, Georgia C., Lewis, Crystal S., Han, Jinkyu, Zhang, Cheng, Li, Qiang, Shi, Chenyang, Abeykoon, A. M.Milinda, Billinge, Simon J.L., Stach, Eric, Thomas, Justin, Guerrero, Kevin, Munayco, Pablo, Munayco, Jimmy, Scorzelli, Rosa B., Burnham, Philip, Viescas, Arthur J, & Tiano, Amanda L. Correlating size and composition-dependent effects with magnetic, Mössbauer, and pair distribution function measurements in a family of catalytically active ferrite nanoparticles. United States. https://doi.org/10.1021/acs.chemmater.5b00767
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Wong, Stanislaus, Papaefthymiou, Georgia C., Lewis, Crystal S., Han, Jinkyu, Zhang, Cheng, Li, Qiang, Shi, Chenyang, Abeykoon, A. M.Milinda, Billinge, Simon J.L., Stach, Eric, Thomas, Justin, Guerrero, Kevin, Munayco, Pablo, Munayco, Jimmy, Scorzelli, Rosa B., Burnham, Philip, Viescas, Arthur J, and Tiano, Amanda L. Wed . "Correlating size and composition-dependent effects with magnetic, Mössbauer, and pair distribution function measurements in a family of catalytically active ferrite nanoparticles". United States. https://doi.org/10.1021/acs.chemmater.5b00767. https://www.osti.gov/servlets/purl/1201345.
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@article{osti_1201345,
title = {Correlating size and composition-dependent effects with magnetic, Mössbauer, and pair distribution function measurements in a family of catalytically active ferrite nanoparticles},
author = {Wong, Stanislaus and Papaefthymiou, Georgia C. and Lewis, Crystal S. and Han, Jinkyu and Zhang, Cheng and Li, Qiang and Shi, Chenyang and Abeykoon, A. M.Milinda and Billinge, Simon J.L. and Stach, Eric and Thomas, Justin and Guerrero, Kevin and Munayco, Pablo and Munayco, Jimmy and Scorzelli, Rosa B. and Burnham, Philip and Viescas, Arthur J and Tiano, Amanda L.},
abstractNote = {The magnetic spinel ferrites, MFe₂O₄ (wherein 'M' = a divalent metal ion such as but not limited to Mn, Co, Zn, and Ni), represent a unique class of magnetic materials in which the rational introduction of different 'M's can yield correspondingly unique and interesting magnetic behaviors. Herein we present a generalized hydrothermal method for the synthesis of single-crystalline ferrite nanoparticles with 'M' = Mg, Fe, Co, Ni, Cu, and Zn, respectively, which can be systematically and efficaciously produced simply by changing the metal precursor. Our protocol can moreover lead to reproducible size control by judicious selection of various surfactants. As such, we have probed the effects of both (i) size and (ii) chemical composition upon the magnetic properties of these nanomaterials using complementary magnetometry and Mössbauer spectroscopy techniques. The structure of the samples was confirmed by atomic PDF analysis of X-ray and electron powder diffraction data as a function of particle size. These materials retain the bulk spinel structure to the smallest size (i.e., 3 nm). In addition, we have explored the catalytic potential of our ferrites as both (a) magnetically recoverable photocatalysts and (b) biological catalysts, and noted that many of our as-prepared ferrite systems evinced intrinsically higher activities as compared with their iron oxide analogues.},
doi = {10.1021/acs.chemmater.5b00767},
journal = {Chemistry of Materials},
number = 10,
volume = 27,
place = {United States},
year = {Wed May 06 00:00:00 EDT 2015},
month = {Wed May 06 00:00:00 EDT 2015}
}
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https://doi.org/10.1021/acs.chemmater.5b00767
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    Evidence of a cubic iron sub-lattice in t-CuFe2O4 demonstrated by X-ray Absorption Fine Structure
    journal, January 2018

    Dopant driven tunability of dielectric relaxation in M x Co (1-x) Fe 2 O 4 (M: Zn 2+ , Mn 2+ , Ni 2+ ) nano-ferrites
    journal, July 2017

    • Datt, Gopal; Abhyankar, A. C.
    • Journal of Applied Physics, Vol. 122, Issue 3
    • DOI: 10.1063/1.4990275

    The properties of Mn–CuFe2O4 spinel ferrite nanoparticles under various synthesis conditions
    journal, September 2017

    In situ microcalorimetric investigation on effects of surfactants on cluster-shaped Ni-doped Fe3O4 formation
    journal, January 2018

    Synthesis, characterization, and evaluation of PEGylated first-row transition metal ferrite nanoparticles as T 2 contrast agents for high-field MRI
    journal, January 2017

    • Banerjee, Abhinandan; Blasiak, Barbara; Pasquier, Eva
    • RSC Advances, Vol. 7, Issue 61
    • DOI: 10.1039/c7ra05495e

    Characterization techniques for nanoparticles: comparison and complementarity upon studying nanoparticle properties
    journal, January 2018

    • Mourdikoudis, Stefanos; Pallares, Roger M.; Thanh, Nguyen T. K.
    • Nanoscale, Vol. 10, Issue 27
    • DOI: 10.1039/c8nr02278j

    Photoelectrochemical and theoretical investigations of spinel type ferrites (M x Fe 3− x O 4 ) for water splitting: a mini-review
    journal, October 2016

    • Taffa, Dereje H.; Dillert, Ralf; Ulpe, Anna C.
    • Journal of Photonics for Energy, Vol. 7, Issue 1
    • DOI: 10.1117/1.jpe.7.012009

    Nanomaterials with enzyme-like characteristics (nanozymes): next-generation artificial enzymes (II)
    journal, January 2019

    • Wu, Jiangjiexing; Wang, Xiaoyu; Wang, Quan
    • Chemical Society Reviews, Vol. 48, Issue 4
    • DOI: 10.1039/c8cs00457a

    Wet chemical synthesis of metal oxide nanoparticles: a review
    journal, January 2018

    • Nikam, A. V.; Prasad, B. L. V.; Kulkarni, A. A.
    • CrystEngComm, Vol. 20, Issue 35
    • DOI: 10.1039/c8ce00487k
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