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Title: Multiday production of condensing organic aerosol mass in urban and forest outflow

Secondary organic aerosol (SOA) production in air masses containing either anthropogenic or biogenic (terpene-dominated) emissions is investigated using the explicit gas-phase chemical mechanism generator GECKO-A. Simulations show several-fold increases in SOA mass continuing for several days in the urban outflow, even as the initial air parcel is diluted into the regional atmosphere. The SOA mass increase in the forest outflow is more modest (∼50%) and of shorter duration (1–2 days). The production in the urban outflow stems from continuing oxidation of gas-phase precursors which persist in equilibrium with the particle phase, and can be attributed to multigenerational reaction products of both aromatics and alkanes. In particular we find large contributions from substituted maleic anhydrides and multi-substituted peroxide-bicyclic alkenes. The results show that the predicted production is a robust feature of our model even under changing atmospheric conditions, and contradict the notion that SOA undergoes little mass production beyond a short initial formation period. The results imply that anthropogenic aerosol precursors could influence the chemical and radiative characteristics of the atmosphere over an extremely wide region, and that SOA measurements near precursor sources may routinely underestimate this influence.
Authors:
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Publication Date:
OSTI Identifier:
1198289
Grant/Contract Number:
SC0006780
Type:
Published Article
Journal Name:
Atmospheric Chemistry and Physics Discussions (Online)
Additional Journal Information:
Journal Name: Atmospheric Chemistry and Physics Discussions (Online); Journal Volume: 14; Journal Issue: 12; Journal ID: ISSN 1680-7375
Publisher:
European Geosciences Union
Sponsoring Org:
USDOE Office of Science (SC), Biological and Environmental Research (BER) (SC-23)
Country of Publication:
Germany
Language:
English