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Title: Radiation tolerance of neutron-irradiated model Fe-Cr-Al alloys

Abstract

The Fe Cr Al alloy system has the potential to form an important class of enhanced accident-tolerant cladding materials in the nuclear power industry owing to the alloy system's higher oxidation resistance in high-temperature steam environments compared with traditional zirconium-based alloys. However, radiation tolerance of Fe Cr Al alloys has not been fully established. In this study, a series of Fe Cr Al alloys with 10 18 wt % Cr and 2.9 4.9 wt % Al were neutron irradiated at 382 C to 1.8 dpa to investigate the irradiation-induced microstructural and mechanical property evolution as a function of alloy composition. Dislocation loops with Burgers vector of a/2 111 and a 100 were detected and quantified. Results indicate precipitation of Cr-rich is primarily dependent on the bulk chromium composition. Mechanical testing of sub-size-irradiated tensile specimens indicates the hardening response seen after irradiation is dependent on the bulk chromium composition. Furthermore, a structure property relationship was developed; it indicated that the change in yield strength after irradiation is caused by the formation of these radiation-induced defects and is dominated by the large number density of Cr-rich α' precipitates at sufficiently high chromium contents after irradiation.

Authors:
 [1];  [1];  [1];  [1];  [1]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Nuclear Energy (NE); USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1195807
Alternate Identifier(s):
OSTI ID: 1251989
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Nuclear Materials
Additional Journal Information:
Journal Volume: 465; Journal ID: ISSN 0022-3115
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 73 NUCLEAR PHYSICS AND RADIATION PHYSICS; FeCrAl; accident tolerant; phase stability; dislocation; hardening

Citation Formats

Field, Kevin G., Hu, Xunxiang, Littrell, Kenneth C., Yamamoto, Yukinori, and Snead, Lance Lewis. Radiation tolerance of neutron-irradiated model Fe-Cr-Al alloys. United States: N. p., 2015. Web. doi:10.1016/j.jnucmat.2015.06.023.
Field, Kevin G., Hu, Xunxiang, Littrell, Kenneth C., Yamamoto, Yukinori, & Snead, Lance Lewis. Radiation tolerance of neutron-irradiated model Fe-Cr-Al alloys. United States. https://doi.org/10.1016/j.jnucmat.2015.06.023
Field, Kevin G., Hu, Xunxiang, Littrell, Kenneth C., Yamamoto, Yukinori, and Snead, Lance Lewis. Tue . "Radiation tolerance of neutron-irradiated model Fe-Cr-Al alloys". United States. https://doi.org/10.1016/j.jnucmat.2015.06.023. https://www.osti.gov/servlets/purl/1195807.
@article{osti_1195807,
title = {Radiation tolerance of neutron-irradiated model Fe-Cr-Al alloys},
author = {Field, Kevin G. and Hu, Xunxiang and Littrell, Kenneth C. and Yamamoto, Yukinori and Snead, Lance Lewis},
abstractNote = {The Fe Cr Al alloy system has the potential to form an important class of enhanced accident-tolerant cladding materials in the nuclear power industry owing to the alloy system's higher oxidation resistance in high-temperature steam environments compared with traditional zirconium-based alloys. However, radiation tolerance of Fe Cr Al alloys has not been fully established. In this study, a series of Fe Cr Al alloys with 10 18 wt % Cr and 2.9 4.9 wt % Al were neutron irradiated at 382 C to 1.8 dpa to investigate the irradiation-induced microstructural and mechanical property evolution as a function of alloy composition. Dislocation loops with Burgers vector of a/2 111 and a 100 were detected and quantified. Results indicate precipitation of Cr-rich is primarily dependent on the bulk chromium composition. Mechanical testing of sub-size-irradiated tensile specimens indicates the hardening response seen after irradiation is dependent on the bulk chromium composition. Furthermore, a structure property relationship was developed; it indicated that the change in yield strength after irradiation is caused by the formation of these radiation-induced defects and is dominated by the large number density of Cr-rich α' precipitates at sufficiently high chromium contents after irradiation.},
doi = {10.1016/j.jnucmat.2015.06.023},
journal = {Journal of Nuclear Materials},
number = ,
volume = 465,
place = {United States},
year = {Tue Jul 14 00:00:00 EDT 2015},
month = {Tue Jul 14 00:00:00 EDT 2015}
}

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Works referenced in this record:

High temperature oxidation of fuel cladding candidate materials in steam–hydrogen environments
journal, September 2013


Advanced oxidation-resistant iron-based alloys for LWR fuel cladding
journal, May 2014


Accident tolerant fuels for LWRs: A perspective
journal, May 2014


Scoping assessments of ATF impact on late-stage accident progression including molten core–concrete interaction
journal, May 2014


Development and property evaluation of nuclear grade wrought FeCrAl fuel cladding for light water reactors
journal, December 2015


Effect of steam on high temperature oxidation behaviour of alumina-forming alloys
journal, January 2015


Microstructural stability of Fe–Cr–Al alloys at 450–550 °C
journal, February 2015


Deformation behavior of laser welds in high temperature oxidation resistant Fe–Cr–Al alloys for fuel cladding applications
journal, November 2014


Neutronic analysis of candidate accident-tolerant cladding concepts in pressurized water reactors
journal, January 2015


Dislocation loops and bubbles in oxide dispersion strengthened ferritic steel after helium implantation under stress
journal, January 2008


Void-swelling in irons and ferritic steels
journal, November 1979


Mapping of 475°C embrittlement in ferritic Fe–Cr–Al alloys
journal, November 2010


The effect of Al on the 475°C embrittlement of Fe–Cr alloys
journal, June 2013


Microstructural influences on the decomposition of an Al-containing ferritic stainless steel
journal, March 1996


Al partitioning in MA 956, an ODS ferritic stainless steel
journal, February 1997


Effect of nanoscale precipitation on strengthening of ferritic ODS Fe–Cr–Al alloy
journal, October 2013


Phase separation kinetics in a Fe–Cr–Al alloy
journal, July 2012


Reverse αα ´ phase separation in Fe-20Cr-6Al alloy
journal, May 2013


Influence of recrystallization on phase separation kinetics of oxide dispersion strengthened Fe–Cr–Al alloy
journal, March 2012


Phase separation in PM 2000™ Fe-base ODS alloy: Experimental study at the atomic level
journal, August 2008

  • Capdevila, C.; Miller, M. K.; Russell, K. F.
  • Materials Science and Engineering: A, Vol. 490, Issue 1-2
  • DOI: 10.1016/j.msea.2008.01.029

On the α–α′ miscibility gap of Fe–Cr alloys
journal, December 2008


The 885° f (475° c) embrittlement of ferritic stainless steels
journal, January 1973


A SANS investigation of the irradiation-enhanced α–α′ phases separation in 7–12 Cr martensitic steels
journal, February 2003


α′ precipitation in neutron-irradiated Fe–Cr alloys
journal, March 2014


Multiscale modelling of radiation damage and phase transformations: The challenge of FeCr alloys
journal, December 2008


Effect of Cr on the mechanical properties and microstructure of Fe–Cr model alloys after n-irradiation
journal, June 2008


The microstructure and tensile properties of Fe–Cr alloys after neutron irradiation at 400°C to 5.5–7.1 dpa
journal, August 1998


Mechanisms of radiation strengthening in Fe–Cr alloys as revealed by atomistic studies
journal, November 2013


Structural materials for fission & fusion energy
journal, November 2009


Optimization of Reactive-Element Additions to Improve Oxidation Performance of Alumina-Forming Alloys
journal, April 2003


Dependence on grain boundary structure of radiation induced segregation in a 9wt.% Cr model ferritic/martensitic steel
journal, April 2013


Application of STEM characterization for investigating radiation effects in BCC Fe-based alloys
journal, April 2015

  • Parish, Chad M.; Field, Kevin G.; Certain, Alicia G.
  • Journal of Materials Research, Vol. 30, Issue 9
  • DOI: 10.1557/jmr.2015.32

Observation and analysis of defect cluster production and interactions with dislocations
journal, August 2004


Electron Radiation Damage of Iron in High Voltage Electron Microscope
journal, July 1975

  • Yoshida, Naoaki; Kiritani, Michio; Eiichi Fujita, F.
  • Journal of the Physical Society of Japan, Vol. 39, Issue 1
  • DOI: 10.1143/JPSJ.39.170

Radiation hardening in neutron-irradiated polycrystalline copper: Barrier strength of defect clusters
journal, March 1991


TEM characterization of dislocation loops in irradiated bcc Fe-based steels
journal, March 2013


Fabrication of a TEM sample of ion-irradiated material using focused ion beam microprocessing and low-energy Ar ion milling
journal, May 2010

  • Jin, H. -H.; Shin, C.; Kwon, J.
  • Journal of Electron Microscopy, Vol. 59, Issue 6
  • DOI: 10.1093/jmicro/dfq020

The microstructure of neutron-irradiated Fe–Cr alloys: A small-angle neutron scattering study
journal, February 2011


SANS investigation of a neutron-irradiated Fe–9at%Cr alloy
journal, December 2010


Precipitation in iron–chromium–aluminium alloys
journal, June 1984


SANS investigation of microstructure evolution in high chromium ODS steels after thermal ageing
journal, April 2013


Heavy-ion irradiations of Fe and Fe–Cr model alloys Part 1: Damage evolution in thin-foils at lower doses
journal, July 2008


Microstructural examination of neutron-irradiated simple ferritic alloys
journal, July 1982


Swelling and dislocation evolution in simple ferritic alloys irradiated to high fluence in FFTF/MOTA
journal, August 1995


Microstructural changes in a neutron-irradiated Fe–15 at.%Cr alloy
journal, November 2014

  • Bachhav, Mukesh; Robert Odette, G.; Marquis, Emmanuelle A.
  • Journal of Nuclear Materials, Vol. 454, Issue 1-3
  • DOI: 10.1016/j.jnucmat.2014.08.026

Microstructural changes in a neutron-irradiated Fe–6 at.%Cr alloy
journal, October 2014


Oxidation studies of Fe10CrAl–RE alloys exposed to Pb at 550°C for 10,000h
journal, November 2013


Work-hardening and work-softening of face-centred cubic metal crystals
journal, March 1957


On the relationship between uniaxial yield strength and resolved shear stress in polycrystalline materials
journal, December 2000


CXXX. On the linear work hardening mate of face-centred cubic single crystals
journal, November 1955

  • Friedel, J.
  • The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science, Vol. 46, Issue 382
  • DOI: 10.1080/14786441108520630

Elastic interaction between prismatic dislocation loops and straight dislocations
journal, January 1964


Solid-solution hardening by point-like obstacles of different kinds
journal, July 2004


Irradiation damage in 304 and 316 stainless steels: experimental investigation and modeling. Part II: Irradiation induced hardening
journal, March 2004


The evolution of mechanical property change in irradiated austenitic stainless steels
journal, November 1993


Application of a three-feature dispersed-barrier hardening model to neutron-irradiated Fe–Cr model alloys
journal, May 2014


The effect of dislocation self-interaction on the orowan stress
journal, December 1973


Effect of the α γ Phase Transition on the Stability of Dislocation Loops in bcc Iron
journal, April 2008


Shape of prismatic dislocation loops in anisotropic α -Fe
journal, September 2009


Modeling of irradiation hardening of iron after low-dose and low-temperature neutron irradiation
journal, July 2014

  • Hu, Xunxiang; Xu, Donghua; Byun, Thak Sang
  • Modelling and Simulation in Materials Science and Engineering, Vol. 22, Issue 6
  • DOI: 10.1088/0965-0393/22/6/065002

Competing processes in reactions between an edge dislocation and dislocation loops in a body-centred cubic metal
journal, May 2010


Works referencing / citing this record:

Development of next generation tempered and ODS reduced activation ferritic/martensitic steels for fusion energy applications
journal, June 2017


Quantitative Phase-Field Simulation of Composition Partition and Separation Kinetics of Nanoscale Phase in Fe-Cr-Al Alloy
journal, May 2019

  • Chen, Shi; Li, Yongsheng; Shi, Shujing
  • Journal of Nanomaterials, Vol. 2019
  • DOI: 10.1155/2019/6862390

Automated defect analysis in electron microscopic images
journal, July 2018


Shear Punch Testing of Neutron-Irradiated HT-9 and 14YWT
journal, January 2020


Material Selection for Accident Tolerant Fuel Cladding
journal, September 2015

  • Pint, B. A.; Terrani, K. A.; Yamamoto, Y.
  • Metallurgical and Materials Transactions E, Vol. 2, Issue 3
  • DOI: 10.1007/s40553-015-0056-7

Microstructure Characterization and Mechanical Properties of Al Alloyed 9Cr ODS Steels with Different Al Contents
journal, April 2019

  • Xu, Shuai; Zhou, Zhangjian; Jia, Haodong
  • steel research international, Vol. 90, Issue 7
  • DOI: 10.1002/srin.201800594