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Title: Giant strain with ultra-low hysteresis and high temperature stability in grain oriented lead-free K₀̣₅Bi₀̣₅TiO₃-BaTiO₃-Na₀̣₅Bi₀̣₅TiO₃ piezoelectric materials

Abstract

We synthesized grain-oriented lead-free piezoelectric materials in (K₀̣₅Bi₀̣₅TiO₃-BaTiO₃-xNa₀̣₅Bi₀̣₅TiO₃ (KBT-BT-NBT) system with high degree of texturing along the [001]c (c-cubic) crystallographic orientation. We demonstrate giant field induced strain (~0.48%) with an ultra-low hysteresis along with enhanced piezoelectric response (d₃₃ ~ 190pC/N) and high temperature stability (~160°C). Transmission electron microscopy (TEM) and piezoresponse force microscopy (PFM) results demonstrate smaller size highly ordered domain structure in grain-oriented specimen relative to the conventional polycrystalline ceramics. The grain oriented specimens exhibited a high degree of non-180° domain switching, in comparison to the randomly axed ones. These results indicate the effective solution to the lead-free piezoelectric materials.

Authors:
 [1];  [1];  [1];  [1];  [1];  [1];  [1]
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  1. Virginia Tech, Blacksburg, VA (United States)
Publication Date:
Research Org.:
Virginia Tech, Blacksburg, VA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1188364
Grant/Contract Number:  
FG02-07ER46480
Resource Type:
Accepted Manuscript
Journal Name:
Scientific Reports
Additional Journal Information:
Journal Volume: 5; Journal Issue: 2; Journal ID: ISSN 2045-2322
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Maurya, Deepam, Zhou, Yuan, Wang, Yaojin, Yan, Yongke, Li, Jiefang, Viehland, Dwight, and Priya, Shashank. Giant strain with ultra-low hysteresis and high temperature stability in grain oriented lead-free K₀̣₅Bi₀̣₅TiO₃-BaTiO₃-Na₀̣₅Bi₀̣₅TiO₃ piezoelectric materials. United States: N. p., 2015. Web. doi:10.1038/srep08595.
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Maurya, Deepam, Zhou, Yuan, Wang, Yaojin, Yan, Yongke, Li, Jiefang, Viehland, Dwight, & Priya, Shashank. Giant strain with ultra-low hysteresis and high temperature stability in grain oriented lead-free K₀̣₅Bi₀̣₅TiO₃-BaTiO₃-Na₀̣₅Bi₀̣₅TiO₃ piezoelectric materials. United States. https://doi.org/10.1038/srep08595
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Maurya, Deepam, Zhou, Yuan, Wang, Yaojin, Yan, Yongke, Li, Jiefang, Viehland, Dwight, and Priya, Shashank. Thu . "Giant strain with ultra-low hysteresis and high temperature stability in grain oriented lead-free K₀̣₅Bi₀̣₅TiO₃-BaTiO₃-Na₀̣₅Bi₀̣₅TiO₃ piezoelectric materials". United States. https://doi.org/10.1038/srep08595. https://www.osti.gov/servlets/purl/1188364.
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@article{osti_1188364,
title = {Giant strain with ultra-low hysteresis and high temperature stability in grain oriented lead-free K₀̣₅Bi₀̣₅TiO₃-BaTiO₃-Na₀̣₅Bi₀̣₅TiO₃ piezoelectric materials},
author = {Maurya, Deepam and Zhou, Yuan and Wang, Yaojin and Yan, Yongke and Li, Jiefang and Viehland, Dwight and Priya, Shashank},
abstractNote = {We synthesized grain-oriented lead-free piezoelectric materials in (K₀̣₅Bi₀̣₅TiO₃-BaTiO₃-xNa₀̣₅Bi₀̣₅TiO₃ (KBT-BT-NBT) system with high degree of texturing along the [001]c (c-cubic) crystallographic orientation. We demonstrate giant field induced strain (~0.48%) with an ultra-low hysteresis along with enhanced piezoelectric response (d₃₃ ~ 190pC/N) and high temperature stability (~160°C). Transmission electron microscopy (TEM) and piezoresponse force microscopy (PFM) results demonstrate smaller size highly ordered domain structure in grain-oriented specimen relative to the conventional polycrystalline ceramics. The grain oriented specimens exhibited a high degree of non-180° domain switching, in comparison to the randomly axed ones. These results indicate the effective solution to the lead-free piezoelectric materials.},
doi = {10.1038/srep08595},
journal = {Scientific Reports},
number = 2,
volume = 5,
place = {United States},
year = {Thu Feb 26 00:00:00 EST 2015},
month = {Thu Feb 26 00:00:00 EST 2015}
}
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https://doi.org/10.1038/srep08595
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Works referenced in this record:

Topotactical reactions with ferrimagnetic oxides having hexagonal crystal structures—I
journal, February 1959

Temperature dependence of the piezoelectric response in lead zirconate titanate films
journal, February 2004

  • Wolf, R. A.; Trolier-McKinstry, S.
  • Journal of Applied Physics, Vol. 95, Issue 3
  • DOI: 10.1063/1.1636530

Morphotropic phase boundary and electric properties in (1− x )Bi 0.5 Na 0.5 TiO 3 - x BiCoO 3 lead-free piezoelectric ceramics
journal, June 2012

  • Guo, Fei-Fei; Yang, Bin; Zhang, Shan-Tao
  • Journal of Applied Physics, Vol. 111, Issue 12
  • DOI: 10.1063/1.4730770

Templated Grain Growth of Textured Piezoelectric Ceramics
journal, April 2004

  • Messing, G. L.; Trolier-McKinstry, S.; Sabolsky, E. M.
  • Critical Reviews in Solid State and Materials Sciences, Vol. 29, Issue 2
  • DOI: 10.1080/10408430490490905

Enhanced piezoelectric properties of barium titanate single crystals with different engineered-domain sizes
journal, July 2005

  • Wada, Satoshi; Yako, Koichi; Kakemoto, Hirofumi
  • Journal of Applied Physics, Vol. 98, Issue 1
  • DOI: 10.1063/1.1957130

Perspective on the Development of Lead-free Piezoceramics
journal, June 2009

Phase-field model of domain structures in ferroelectric thin films
journal, June 2001

  • Li, Y. L.; Hu, S. Y.; Liu, Z. K.
  • Applied Physics Letters, Vol. 78, Issue 24
  • DOI: 10.1063/1.1377855

Current Developments and Prospective of Lead-Free Piezoelectric Ceramics
journal, May 2008

  • Takenaka, Tadashi; Nagata, Hajime; Hiruma, Yuji
  • Japanese Journal of Applied Physics, Vol. 47, Issue 5
  • DOI: 10.1143/JJAP.47.3787

Tantalum doped 0.94Bi0.5Na0.5TiO3–0.06BaTiO3 piezoelectric ceramics
journal, January 2008

Local structure and piezoelectric instability in lead-free (1 − x)BaTiO 3 -xA(Cu 1/3 Nb 2/3 )O 3 (A = Sr, Ca, Ba) solid solutions
journal, January 2014

  • Maurya, Deepam; Kumar, Ashok; Petkov, Valeri
  • RSC Adv., Vol. 4, Issue 3
  • DOI: 10.1039/C3RA44886J

Large Piezoelectric Effect in Pb-Free Ceramics
journal, December 2009

In Situ X-Ray Diffraction Study of Electric-Field-Induced Domain Switching and Phase Transition in PZT-5H: In Situ X-Ray Experiments
journal, December 2004

Processing, texture quality, and piezoelectric properties of <001> C textured (1-x)Pb(Mg 1/3 Nb 2/3 )TiO 3 - xPbTiO 3 ceramics
journal, July 2011

  • Poterala, Stephen F.; Trolier-McKinstry, Susan; Meyer, Richard J.
  • Journal of Applied Physics, Vol. 110, Issue 1
  • DOI: 10.1063/1.3603045

Polarization switching mechanisms and electromechanical properties of La-modified lead zirconate titanate ceramics
journal, April 1995

  • Li, Jie-Fang; Dai, Xunhu; Chow, Albert
  • Journal of Materials Research, Vol. 10, Issue 4
  • DOI: 10.1557/JMR.1995.0926

Domain switching in polycrystalline ferroelectric ceramics
journal, September 2005

  • Li, J. Y.; Rogan, R. C.; Üstündag, E.
  • Nature Materials, Vol. 4, Issue 10
  • DOI: 10.1038/nmat1485

Electromechanical and ferroelectric properties of (Bi1∕2Na1∕2)TiO3–(Bi1∕2K1∕2)TiO3–BaTiO3 lead-free piezoelectric ceramics
journal, July 2004

  • Wang, X. X.; Tang, X. G.; Chan, H. L. W.
  • Applied Physics Letters, Vol. 85, Issue 1
  • DOI: 10.1063/1.1767592

Nanostructured lead-free ferroelectric Na0.5Bi0.5TiO3–BaTiO3 whiskers: synthesis mechanism and structure
journal, January 2012

  • Maurya, Deepam; Petkov, Valeri; Kumar, Ashok
  • Dalton Transactions, Vol. 41, Issue 18
  • DOI: 10.1039/c2dt00045h

Synthesis mechanism of grain-oriented lead-free piezoelectric Na0.5Bi0.5TiO3–BaTiO3 ceramics with giant piezoelectric response
journal, January 2013

  • Maurya, Deepam; Zhou, Yuan; Yan, Yongke
  • Journal of Materials Chemistry C, Vol. 1, Issue 11
  • DOI: 10.1039/c3tc00619k

Giant energy density in [001]-textured Pb(Mg 1/3 Nb 2/3 )O 3 -PbZrO 3 -PbTiO 3 piezoelectric ceramics
journal, January 2013

  • Yan, Yongke; Cho, Kyung-Hoon; Maurya, Deepam
  • Applied Physics Letters, Vol. 102, Issue 4
  • DOI: 10.1063/1.4789854

Field-induced Strain Memory with Non-180?ª Domain-reorientation Control
journal, October 2010

  • Kadota, Yoichi; Hosaka, Hiroshi; Morita, Takeshi
  • Journal of the Korean Physical Society, Vol. 57, Issue 4(1)
  • DOI: 10.3938/jkps.57.902

Giant strain in lead-free piezoceramics Bi0.5Na0.5TiO3–BaTiO3–K0.5Na0.5NbO3 system
journal, September 2007

  • Zhang, Shan-Tao; Kounga, Alain Brice; Aulbach, Emil
  • Applied Physics Letters, Vol. 91, Issue 11
  • DOI: 10.1063/1.2783200

Development of ferroelectric mixed states in a random field of static defects
journal, May 1998

  • Semenovskaya, S.; Khachaturyan, A. G.
  • Journal of Applied Physics, Vol. 83, Issue 10
  • DOI: 10.1063/1.367330

Piezoelectric properties of tetragonal single-domain Mn-doped NBT-6 %BT single crystals
journal, November 2013

Twinning in ferroelectric and ferroelastic ceramics: stress relief
journal, June 1990

Domain switching in polycrystalline ferroelectric ceramics
journal, September 2005

  • Li, J. Y.; Rogan, R. C.; Üstündag, E.
  • Nature Materials, Vol. 4, Issue 10
  • DOI: 10.1038/nmat1485

Nanostructured lead-free ferroelectric Na0.5Bi0.5TiO3–BaTiO3 whiskers: synthesis mechanism and structure
journal, January 2012

  • Maurya, Deepam; Petkov, Valeri; Kumar, Ashok
  • Dalton Transactions, Vol. 41, Issue 18
  • DOI: 10.1039/c2dt00045h

Temperature dependence of the piezoelectric response in lead zirconate titanate films
journal, February 2004

  • Wolf, R. A.; Trolier-McKinstry, S.
  • Journal of Applied Physics, Vol. 95, Issue 3
  • DOI: 10.1063/1.1636530

Development of ferroelectric mixed states in a random field of static defects
journal, May 1998

  • Semenovskaya, S.; Khachaturyan, A. G.
  • Journal of Applied Physics, Vol. 83, Issue 10
  • DOI: 10.1063/1.367330

Effects of B-Site Donor and Acceptor Doping in Pb-Free (Bi0.5Na0.5)TiO3 Ceramics
book, December 2010

  • Sung, Yeon Soo; Kim, Myong Ho
  • Ferroelectrics
  • DOI: 10.5772/13903
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    Works referencing / citing this record:

    Giant Strains in Non-Textured (Bi 1/2 Na 1/2 )TiO 3 -Based Lead-Free Ceramics
    journal, November 2015

    Orientation-dependent dielectric and ferroelectric properties of Pr3+-doped Na0.5Bi0.5TiO3 thin films
    journal, November 2018

    Lead-free BNT-based composite materials: enhanced depolarization temperature and electromechanical behavior
    journal, January 2017

    • Bai, Wangfeng; Zheng, Peng; Wen, Fei
    • Dalton Transactions, Vol. 46, Issue 44
    • DOI: 10.1039/c7dt02846f

    Enhanced torsional actuation and stress coupling in Mn-modified 0.93(Na 0.5 Bi 0.5 TiO 3 )-0.07BaTiO 3 lead-free piezoceramic system
    journal, January 2017

    • Berik, Pelin; Maurya, Deepam; Kumar, Prashant
    • Science and Technology of Advanced Materials, Vol. 18, Issue 1
    • DOI: 10.1080/14686996.2016.1254569

    Defect mechanisms in BaTiO 3 ‐Bi M O 3 ceramics
    journal, January 2018

    • Kumar, Nitish; Patterson, Eric A.; Frömling, Till
    • Journal of the American Ceramic Society, Vol. 101, Issue 6
    • DOI: 10.1111/jace.15403

    Microstructural, ferroelectric, and photoluminescent properties of (100)‐oriented Sm 3+ ‐doped Na 0.5 Bi 0.5 TiO 3 thin films
    journal, May 2018

    • Huang, Wenhua; Du, Xingru; Ismail, Muhammad
    • Journal of the American Ceramic Society, Vol. 101, Issue 10
    • DOI: 10.1111/jace.15737

    Optical dispersion and bandgap of pure and Mn‐doped 0.92Na 0.5 Bi 0.5 TiO 3 ‐0.08K 0.5 Bi 0.5 TiO 3 lead‐free single crystals
    journal, September 2019

    • Wu, Yang; Hu, Yuqing; Xue, Saidong
    • Journal of the American Ceramic Society, Vol. 103, Issue 2
    • DOI: 10.1111/jace.16823

    Giant electro‐strain in textured Li + ‐doped 0.852BNT–0.11BKT–0.038BT ternary lead‐free piezoelectric ceramics
    journal, October 2019

    • Si, Yuan; Li, Ying; Li, Li
    • Journal of the American Ceramic Society, Vol. 103, Issue 3
    • DOI: 10.1111/jace.16853

    Lead-free piezoelectric materials and composites for high power density energy harvesting
    journal, June 2018

    • Maurya, Deepam; Peddigari, Mahesh; Kang, Min-Gyu
    • Journal of Materials Research, Vol. 33, Issue 16
    • DOI: 10.1557/jmr.2018.172

    Lead-free piezoceramics: Status and perspectives
    journal, August 2018

    Dielectric and Piezoelectric Properties of Textured Lead-Free Na0.5Bi0.5TiO3-Based Ceramics
    journal, April 2019

    Bismuth Sodium Titanate Based Materials for Piezoelectric Actuators
    journal, December 2015

    • Reichmann, Klaus; Feteira, Antonio; Li, Ming
    • Materials, Vol. 8, Issue 12
    • DOI: 10.3390/ma8125469

    High electromechanical strain and enhanced temperature characteristics in lead-free (Na,Bi)TiO3–BaTiO3 thin films on Si substrates
    journal, May 2018

    Bismuth Sodium Titanate Based Materials for Piezoelectric Actuators
    journal, December 2015

    • Reichmann, Klaus; Feteira, Antonio; Li, Ming
    • Materials, Vol. 8, Issue 12
    • DOI: 10.3390/ma8125469
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