Using “Tender” x-ray ambient pressure x-Ray photoelectron spectroscopy as a direct probe of solid-liquid interface
Abstract
We report a new method to probe the solid-liquid interface through the use of a thin liquid layer on a solid surface. An ambient pressure XPS (AP-XPS) endstation that is capable of detecting high kinetic energy photoelectrons (7 keV) at a pressure up to 110 Torr has been constructed and commissioned. Additionally, we have deployed a “dip & pull” method to create a stable nanometers-thick aqueous electrolyte on platinum working electrode surface. Combining the newly constructed AP-XPS system, “dip & pull” approach, with a “tender” X-ray synchrotron source (2 keV–7 keV), we are able to access the interface between liquid and solid dense phases with photoelectrons and directly probe important phenomena occurring at the narrow solid-liquid interface region in an electrochemical system. Using this approach, we have performed electrochemical oxidation of the Pt electrode at an oxygen evolution reaction (OER) potential. Under this potential, we observe the formation of both Pt²⁺ and Pt⁴⁺ interfacial species on the Pt working electrode in situ. We believe this thin-film approach and the use of “tender” AP-XPS highlighted in this study is an innovative new approach to probe this key solid-liquid interface region of electrochemistry.
- Authors:
-
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Chinese Academy of Sciences, Shanghai (Republic of China)
- VG Scienta,Uppsala (Sweden)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Chinese Academy of Sciences, Shanghai (Republic of China); Shanghai Tech Univ., Shanghai (China)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1187106
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Scientific Reports
- Additional Journal Information:
- Journal Volume: 5; Journal Issue: 5; Journal ID: ISSN 2045-2322
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; batteries; surface spectroscopy; electrocatalysis
Citation Formats
Axnanda, Stephanus, Crumlin, Ethan J., Mao, Baohua, Rani, Sana, Chang, Rui, Karlsson, Patrik G., Edwards, Mårten O. M., Lundqvist, Måns, Moberg, Robert, Ross, Phil, Hussain, Zahid, and Liu, Zhi. Using “Tender” x-ray ambient pressure x-Ray photoelectron spectroscopy as a direct probe of solid-liquid interface. United States: N. p., 2015.
Web. doi:10.1038/srep09788.
Axnanda, Stephanus, Crumlin, Ethan J., Mao, Baohua, Rani, Sana, Chang, Rui, Karlsson, Patrik G., Edwards, Mårten O. M., Lundqvist, Måns, Moberg, Robert, Ross, Phil, Hussain, Zahid, & Liu, Zhi. Using “Tender” x-ray ambient pressure x-Ray photoelectron spectroscopy as a direct probe of solid-liquid interface. United States. https://doi.org/10.1038/srep09788
Axnanda, Stephanus, Crumlin, Ethan J., Mao, Baohua, Rani, Sana, Chang, Rui, Karlsson, Patrik G., Edwards, Mårten O. M., Lundqvist, Måns, Moberg, Robert, Ross, Phil, Hussain, Zahid, and Liu, Zhi. Thu .
"Using “Tender” x-ray ambient pressure x-Ray photoelectron spectroscopy as a direct probe of solid-liquid interface". United States. https://doi.org/10.1038/srep09788. https://www.osti.gov/servlets/purl/1187106.
@article{osti_1187106,
title = {Using “Tender” x-ray ambient pressure x-Ray photoelectron spectroscopy as a direct probe of solid-liquid interface},
author = {Axnanda, Stephanus and Crumlin, Ethan J. and Mao, Baohua and Rani, Sana and Chang, Rui and Karlsson, Patrik G. and Edwards, Mårten O. M. and Lundqvist, Måns and Moberg, Robert and Ross, Phil and Hussain, Zahid and Liu, Zhi},
abstractNote = {We report a new method to probe the solid-liquid interface through the use of a thin liquid layer on a solid surface. An ambient pressure XPS (AP-XPS) endstation that is capable of detecting high kinetic energy photoelectrons (7 keV) at a pressure up to 110 Torr has been constructed and commissioned. Additionally, we have deployed a “dip & pull” method to create a stable nanometers-thick aqueous electrolyte on platinum working electrode surface. Combining the newly constructed AP-XPS system, “dip & pull” approach, with a “tender” X-ray synchrotron source (2 keV–7 keV), we are able to access the interface between liquid and solid dense phases with photoelectrons and directly probe important phenomena occurring at the narrow solid-liquid interface region in an electrochemical system. Using this approach, we have performed electrochemical oxidation of the Pt electrode at an oxygen evolution reaction (OER) potential. Under this potential, we observe the formation of both Pt²⁺ and Pt⁴⁺ interfacial species on the Pt working electrode in situ. We believe this thin-film approach and the use of “tender” AP-XPS highlighted in this study is an innovative new approach to probe this key solid-liquid interface region of electrochemistry.},
doi = {10.1038/srep09788},
journal = {Scientific Reports},
number = 5,
volume = 5,
place = {United States},
year = {Thu May 07 00:00:00 EDT 2015},
month = {Thu May 07 00:00:00 EDT 2015}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 227 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Photoelectron spectroscopy under ambient pressure and temperature conditions
journal, March 2009
- Frank Ogletree, D.; Bluhm, Hendrik; Hebenstreit, Eleonore D.
- Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 601, Issue 1-2
In situ investigation of electrochemical devices using ambient pressure photoelectron spectroscopy
journal, October 2013
- Crumlin, Ethan J.; Bluhm, Hendrik; Liu, Zhi
- Journal of Electron Spectroscopy and Related Phenomena, Vol. 190
Accurate Electron Inelastic Cross Sections and Stopping Powers for Liquid Water over the 0.1-10 keV Range Based on an Improved Dielectric Description of the Bethe Surface
journal, January 2007
- Emfietzoglou, D.; Nikjoo, H.
- Radiation Research, Vol. 167, Issue 1
Electronic Effects in the Electric Double Layer
journal, January 1996
- Schmickler, Wolfgang
- Chemical Reviews, Vol. 96, Issue 8
Ultra-high vacuum techniques in the study of single-crystal electrode surfaces
journal, April 1992
- Soriaga, Manuel P.
- Progress in Surface Science, Vol. 39, Issue 4
Atomic subshell photoionization cross sections and asymmetry parameters: 1 ⩽ Z ⩽ 103
journal, January 1985
- Yeh, J. J.; Lindau, I.
- Atomic Data and Nuclear Data Tables, Vol. 32, Issue 1
Influence of Hydrocarbon and CO 2 on the Reversibility of Li–O 2 Chemistry Using In Situ Ambient Pressure X-ray Photoelectron Spectroscopy
journal, December 2013
- Lu, Yi-Chun; Crumlin, Ethan J.; Carney, Thomas J.
- The Journal of Physical Chemistry C, Vol. 117, Issue 49
A differentially pumped electrostatic lens system for photoemission studies in the millibar range
journal, November 2002
- Ogletree, D. Frank; Bluhm, Hendrik; Lebedev, Gennadi
- Review of Scientific Instruments, Vol. 73, Issue 11
Formation of Nanometer-Sized Surface Platinum Oxide Clusters on a Stepped Pt(557) Single Crystal Surface Induced by Oxygen: A High-Pressure STM and Ambient-Pressure XPS Study
journal, February 2012
- Zhu, Zhongwei; Tao, Franklin (Feng); Zheng, Fan
- Nano Letters, Vol. 12, Issue 3
Multielement Activity Mapping and Potential Mapping in Solid Oxide Electrochemical Cells through the use of operando XPS
journal, September 2012
- Zhang, Chunjuan; Grass, Michael E.; Yu, Yi
- ACS Catalysis, Vol. 2, Issue 11
In Situ Characterization of Ceria Oxidation States in High-Temperature Electrochemical Cells with Ambient Pressure XPS
journal, November 2010
- DeCaluwe, Steven C.; Grass, Michael E.; Zhang, Chunjuan
- The Journal of Physical Chemistry C, Vol. 114, Issue 46
Reaction-Driven Restructuring of Rh-Pd and Pt-Pd Core-Shell Nanoparticles
journal, November 2008
- Tao, F.; Grass, M. E.; Zhang, Y.
- Science, Vol. 322, Issue 5903
Mechanistic Studies of Water Electrolysis and Hydrogen Electro-Oxidation on High Temperature Ceria-Based Solid Oxide Electrochemical Cells
journal, July 2013
- Zhang, Chunjuan; Yu, Yi; Grass, Michael E.
- Journal of the American Chemical Society, Vol. 135, Issue 31
Methanol Oxidation on a Copper Catalyst Investigated Using in Situ X-ray Photoelectron Spectroscopy †
journal, September 2004
- Bluhm, Hendrik; Hävecker, Michael; Knop-Gericke, Axel
- The Journal of Physical Chemistry B, Vol. 108, Issue 38
Electron transport in solids for quantitative surface analysis
journal, January 2001
- Werner, Wolfgang S. M.
- Surface and Interface Analysis, Vol. 31, Issue 3
Break-Up of Stepped Platinum Catalyst Surfaces by High CO Coverage
journal, February 2010
- Tao, F.; Dag, S.; Wang, L. -W.
- Science, Vol. 327, Issue 5967
Ambient pressure photoelectron spectroscopy: A new tool for surface science and nanotechnology
journal, April 2008
- Salmeron, M.; Schlogl, R.
- Surface Science Reports, Vol. 63, Issue 4
Electron spectroscopy of platinum-oxygen surfaces and application to electrochemical studies
journal, November 1971
- Kim, K. S.; Winograd, N.; Davis, R. E.
- Journal of the American Chemical Society, Vol. 93, Issue 23
In situ x-ray photoelectron spectroscopy studies of water on metals and oxides at ambient conditions
journal, April 2008
- Yamamoto, S.; Bluhm, H.; Andersson, K.
- Journal of Physics: Condensed Matter, Vol. 20, Issue 18
In situ x-ray photoelectron spectroscopy for electrochemical reactions in ordinary solvents
journal, September 2013
- Masuda, Takuya; Yoshikawa, Hideki; Noguchi, Hidenori
- Applied Physics Letters, Vol. 103, Issue 11
Observation of systematic electrochemically induced binding energy shift in the XPS spectra of emersed Cs+ double layer species
journal, January 1986
- D'Agostino, Alfred T.; Hansen, Wilford N.
- Surface Science, Vol. 165, Issue 1
In situ study of an oxidation reaction on a Pt/C electrode by ambient pressure hard X-ray photoelectron spectroscopy
journal, September 2014
- Takagi, Yasumasa; Wang, Heng; Uemura, Yohei
- Applied Physics Letters, Vol. 105, Issue 13
UHV Techniques in the Study of Electrode Surfaces
journal, January 1987
- Kolb, D. M.
- Zeitschrift für Physikalische Chemie, Vol. 154, Issue Part_1_2
Electron spectroscopy for chemical analysis of liquids and solutions
journal, March 1985
- Siegbahn, Hans
- The Journal of Physical Chemistry, Vol. 89, Issue 6
ESCA study of sputtered platinum films
journal, March 1975
- Bancroft, G. Michael.; Adams, Ian.; Coatsworth, Leighton L.
- Analytical Chemistry, Vol. 47, Issue 3
Measuring individual overpotentials in an operating solid-oxide electrochemical cell
journal, January 2010
- El Gabaly, Farid; Grass, Michael; McDaniel, Anthony H.
- Physical Chemistry Chemical Physics, Vol. 12, Issue 38
A few selected applications of surface nonlinear optical spectroscopy.
journal, October 1996
- Shen, Y. R.
- Proceedings of the National Academy of Sciences, Vol. 93, Issue 22
Effect of pretreatment on a platinized tin oxide catalyst used for low-temperature Co oxidation
journal, July 1990
- Drawdy, Jean E.; Hoflund, Gar B.; Gardner, Steven D.
- Surface and Interface Analysis, Vol. 16, Issue 1-12
Quantitative electron spectroscopy of surfaces: A standard data base for electron inelastic mean free paths in solids
journal, February 1979
- Seah, M. P.; Dench, W. A.
- Surface and Interface Analysis, Vol. 1, Issue 1
X-ray photoelectron spectroscopy and electron microscopy of Pt$z.sbnd;Rh gauzes used for catalytic oxidation of ammonia
journal, June 1977
- Contour, J.
- Journal of Catalysis, Vol. 48, Issue 1-3
In Situ Study of the Gas-Phase Electrolysis of Water on Platinum by NAP-XPS
journal, September 2013
- Arrigo, Rosa; Hävecker, Michael; Schuster, Manfred E.
- Angewandte Chemie International Edition, Vol. 52, Issue 44
Investigation of solid/vapor interfaces using ambient pressure X-ray photoelectron spectroscopy
journal, January 2013
- Starr, D. E.; Liu, Z.; Hävecker, M.
- Chemical Society Reviews, Vol. 42, Issue 13
Measure of Surface Potential at the Aqueous–Oxide Nanoparticle Interface by XPS from a Liquid Microjet
journal, October 2013
- Brown, Matthew A.; Beloqui Redondo, Amaia; Sterrer, Martin
- Nano Letters, Vol. 13, Issue 11
Kinetics of CO oxidation on high-concentration phases of atomic oxygen on Pt(111)
journal, December 2005
- Gerrard, Alex L.; Weaver, Jason F.
- The Journal of Chemical Physics, Vol. 123, Issue 22
A Reactive Oxide Overlayer on Rhodium Nanoparticles during CO Oxidation and Its Size Dependence Studied by In Situ Ambient-Pressure X-ray Photoelectron Spectroscopy
journal, November 2008
- Grass, Michael E.; Zhang, Yawen; Butcher, Derek R.
- Angewandte Chemie International Edition, Vol. 47, Issue 46
Surface science studies of model fuel cell electrocatalysts
journal, April 2002
- Markovic, N.
- Surface Science Reports, Vol. 45, Issue 4-6
Surface Chemistry of Late Transition Metal Oxides
journal, December 2012
- Weaver, Jason F.
- Chemical Reviews, Vol. 113, Issue 6
Different Reactivity of the Various Platinum Oxides and Chemisorbed Oxygen in CO Oxidation on Pt(111)
journal, April 2014
- Miller, Daniel; Sanchez Casalongue, Hernan; Bluhm, Hendrik
- Journal of the American Chemical Society, Vol. 136, Issue 17
In Situ Oxidation Study of Pt(110) and Its Interaction with CO
journal, December 2011
- Butcher, Derek R.; Grass, Michael E.; Zeng, Zhenhua
- Journal of the American Chemical Society, Vol. 133, Issue 50
Oxidation of Pt(111) under Near-Ambient Conditions
journal, November 2011
- Miller, D. J.; Öberg, H.; Kaya, S.
- Physical Review Letters, Vol. 107, Issue 19
Measuring fundamental properties in operating solid oxide electrochemical cells by using in situ X-ray photoelectron spectroscopy
journal, September 2010
- Zhang, Chunjuan; Grass, Michael E.; McDaniel, Anthony H.
- Nature Materials, Vol. 9, Issue 11
In Situ Characterizations of Nanostructured SnO x /Pt(111) Surfaces Using Ambient-Pressure XPS (APXPS) and High-Pressure Scanning Tunneling Microscopy (HPSTM)
journal, January 2014
- Axnanda, Stephanus; Zhu, Zhongwei; Zhou, Weiping
- The Journal of Physical Chemistry C, Vol. 118, Issue 4
Ellipsometric Study of Oxygen‐Containing Films on Platinum Anodes
journal, January 1968
- Reddy, A. K. N.; Genshaw, M. A.; Bockris, J. O'M.
- The Journal of Chemical Physics, Vol. 48, Issue 2
Importance of the Metal-Oxide Interface in Catalysis: In Situ Studies of the Water-Gas Shift Reaction by Ambient-Pressure X-ray Photoelectron Spectroscopy
journal, April 2013
- Mudiyanselage, Kumudu; Senanayake, Sanjaya D.; Feria, Leticia
- Angewandte Chemie International Edition, Vol. 52, Issue 19
Ambient-pressure photoelectron spectroscopy for heterogeneous catalysis and electrochemistry
journal, April 2013
- Kaya, Sarp; Ogasawara, Hirohito; Näslund, Lars-Åke
- Catalysis Today, Vol. 205
An analytical SEM and XPS study of platinum-rhodium gauzes used in high pressure ammonia burners
journal, October 1988
- Fierro, J. L. G.; Palacios, J. M.; Tomas, F.
- Surface and Interface Analysis, Vol. 13, Issue 1
New ambient pressure photoemission endstation at Advanced Light Source beamline 9.3.2
journal, May 2010
- Grass, Michael E.; Karlsson, Patrik G.; Aksoy, Funda
- Review of Scientific Instruments, Vol. 81, Issue 5
An ESCA Study on the Electrochemical Double Layer of Emersed Electrodes
journal, December 1983
- Kolb, P. M.; Rath, D. L.; Wille, R.
- Berichte der Bunsengesellschaft für physikalische Chemie, Vol. 87, Issue 12
Simulation of electron spectra for surface analysis (SESSA): a novel software tool for quantitative Auger-electron spectroscopy and X-ray photoelectron spectroscopy
journal, January 2005
- Smekal, Werner; Werner, Wolfgang S. M.; Powell, Cedric J.
- Surface and Interface Analysis, Vol. 37, Issue 11
In Situ Ambient Pressure X-ray Photoelectron Spectroscopy Studies of Lithium-Oxygen Redox Reactions
journal, October 2012
- Lu, Yi-Chun; Crumlin, Ethan J.; Veith, Gabriel M.
- Scientific Reports, Vol. 2, Issue 1
Electrochemical Equilibria
book, January 1973
- Pourbaix, Marcel; Staehle, Roger W.; Pourbaix, Marcel
- Lectures on Electrochemical Corrosion, p 83-183
Observation of systematic electrochemically induced binding energy shift in the XPS spectra of emersed Cs+ double layer species
journal, January 1986
- D'Agostino, Alfred T.; Hansen, Wilford N.
- Surface Science Letters, Vol. 165, Issue 1
A Reactive Oxide Overlayer on Rhodium Nanoparticles during CO Oxidation and Its Size Dependence Studied by In Situ Ambient-Pressure X-ray Photoelectron Spectroscopy
journal, November 2008
- Grass, Michael E.; Zhang, Yawen; Butcher, Derek R.
- Angewandte Chemie, Vol. 120, Issue 46
Importance of the Metal-Oxide Interface in Catalysis: In Situ Studies of the Water-Gas Shift Reaction by Ambient-Pressure X-ray Photoelectron Spectroscopy
journal, April 2013
- Mudiyanselage, Kumudu; Senanayake, Sanjaya D.; Feria, Leticia
- Angewandte Chemie, Vol. 125, Issue 19
A Reactive Oxide Overlayer on Rhodium Nanoparticles during CO Oxidation and Its Size Dependence Studied by In Situ Ambient-Pressure X-ray Photoelectron Spectroscopy
journal, November 2008
- Grass, Michael E.; Zhang, Yawen; Butcher, Derek R.
- Angewandte Chemie International Edition, Vol. 47, Issue 46
Importance of the Metal-Oxide Interface in Catalysis: In Situ Studies of the Water-Gas Shift Reaction by Ambient-Pressure X-ray Photoelectron Spectroscopy
journal, April 2013
- Mudiyanselage, Kumudu; Senanayake, Sanjaya D.; Feria, Leticia
- Angewandte Chemie International Edition, Vol. 52, Issue 19
In Situ Study of the Gas-Phase Electrolysis of Water on Platinum by NAP-XPS
journal, September 2013
- Arrigo, Rosa; Hävecker, Michael; Schuster, Manfred E.
- Angewandte Chemie International Edition, Vol. 52, Issue 44
An ESCA Study on the Electrochemical Double Layer of Emersed Electrodes
journal, December 1983
- Kolb, P. M.; Rath, D. L.; Wille, R.
- Berichte der Bunsengesellschaft für physikalische Chemie, Vol. 87, Issue 12
Quantitative electron spectroscopy of surfaces: A standard data base for electron inelastic mean free paths in solids
journal, February 1979
- Seah, M. P.; Dench, W. A.
- Surface and Interface Analysis, Vol. 1, Issue 1
Electron transport in solids for quantitative surface analysis
journal, January 2001
- Werner, Wolfgang S. M.
- Surface and Interface Analysis, Vol. 31, Issue 3
X-ray photoelectron spectroscopy and electron microscopy of Pt$z.sbnd;Rh gauzes used for catalytic oxidation of ammonia
journal, June 1977
- Contour, J.
- Journal of Catalysis, Vol. 48, Issue 1-3
Ambient-pressure photoelectron spectroscopy for heterogeneous catalysis and electrochemistry
journal, April 2013
- Kaya, Sarp; Ogasawara, Hirohito; Näslund, Lars-Åke
- Catalysis Today, Vol. 205
Photoelectron spectroscopy under ambient pressure and temperature conditions
journal, March 2009
- Frank Ogletree, D.; Bluhm, Hendrik; Hebenstreit, Eleonore D.
- Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 601, Issue 1-2
ESCA study of sputtered platinum films
journal, March 1975
- Bancroft, G. Michael.; Adams, Ian.; Coatsworth, Leighton L.
- Analytical Chemistry, Vol. 47, Issue 3
Surface Chemistry of Late Transition Metal Oxides
journal, December 2012
- Weaver, Jason F.
- Chemical Reviews, Vol. 113, Issue 6
Electronic Effects in the Electric Double Layer
journal, January 1996
- Schmickler, Wolfgang
- Chemical Reviews, Vol. 96, Issue 8
Electron spectroscopy of platinum-oxygen surfaces and application to electrochemical studies
journal, November 1971
- Kim, K. S.; Winograd, N.; Davis, R. E.
- Journal of the American Chemical Society, Vol. 93, Issue 23
In Situ Oxidation Study of Pt(110) and Its Interaction with CO
journal, December 2011
- Butcher, Derek R.; Grass, Michael E.; Zeng, Zhenhua
- Journal of the American Chemical Society, Vol. 133, Issue 50
Mechanistic Studies of Water Electrolysis and Hydrogen Electro-Oxidation on High Temperature Ceria-Based Solid Oxide Electrochemical Cells
journal, July 2013
- Zhang, Chunjuan; Yu, Yi; Grass, Michael E.
- Journal of the American Chemical Society, Vol. 135, Issue 31
Different Reactivity of the Various Platinum Oxides and Chemisorbed Oxygen in CO Oxidation on Pt(111)
journal, April 2014
- Miller, Daniel; Sanchez Casalongue, Hernan; Bluhm, Hendrik
- Journal of the American Chemical Society, Vol. 136, Issue 17
Methanol Oxidation on a Copper Catalyst Investigated Using in Situ X-ray Photoelectron Spectroscopy †
journal, September 2004
- Bluhm, Hendrik; Hävecker, Michael; Knop-Gericke, Axel
- The Journal of Physical Chemistry B, Vol. 108, Issue 38
In Situ Characterization of Ceria Oxidation States in High-Temperature Electrochemical Cells with Ambient Pressure XPS
journal, November 2010
- DeCaluwe, Steven C.; Grass, Michael E.; Zhang, Chunjuan
- The Journal of Physical Chemistry C, Vol. 114, Issue 46
In Situ Characterizations of Nanostructured SnO x /Pt(111) Surfaces Using Ambient-Pressure XPS (APXPS) and High-Pressure Scanning Tunneling Microscopy (HPSTM)
journal, January 2014
- Axnanda, Stephanus; Zhu, Zhongwei; Zhou, Weiping
- The Journal of Physical Chemistry C, Vol. 118, Issue 4
Influence of Hydrocarbon and CO 2 on the Reversibility of Li–O 2 Chemistry Using In Situ Ambient Pressure X-ray Photoelectron Spectroscopy
journal, December 2013
- Lu, Yi-Chun; Crumlin, Ethan J.; Carney, Thomas J.
- The Journal of Physical Chemistry C, Vol. 117, Issue 49
Formation of Nanometer-Sized Surface Platinum Oxide Clusters on a Stepped Pt(557) Single Crystal Surface Induced by Oxygen: A High-Pressure STM and Ambient-Pressure XPS Study
journal, February 2012
- Zhu, Zhongwei; Tao, Franklin (Feng); Zheng, Fan
- Nano Letters, Vol. 12, Issue 3
Measure of Surface Potential at the Aqueous–Oxide Nanoparticle Interface by XPS from a Liquid Microjet
journal, October 2013
- Brown, Matthew A.; Beloqui Redondo, Amaia; Sterrer, Martin
- Nano Letters, Vol. 13, Issue 11
Measuring fundamental properties in operating solid oxide electrochemical cells by using in situ X-ray photoelectron spectroscopy
journal, September 2010
- Zhang, Chunjuan; Grass, Michael E.; McDaniel, Anthony H.
- Nature Materials, Vol. 9, Issue 11
Investigation of solid/vapor interfaces using ambient pressure X-ray photoelectron spectroscopy
journal, January 2013
- Starr, D. E.; Liu, Z.; Hävecker, M.
- Chemical Society Reviews, Vol. 42, Issue 13
Ellipsometric Study of Oxygen‐Containing Films on Platinum Anodes
journal, January 1968
- Reddy, A. K. N.; Genshaw, M. A.; Bockris, J. O'M.
- The Journal of Chemical Physics, Vol. 48, Issue 2
Kinetics of CO oxidation on high-concentration phases of atomic oxygen on Pt(111)
journal, December 2005
- Gerrard, Alex L.; Weaver, Jason F.
- The Journal of Chemical Physics, Vol. 123, Issue 22
New ambient pressure photoemission endstation at Advanced Light Source beamline 9.3.2
journal, May 2010
- Grass, Michael E.; Karlsson, Patrik G.; Aksoy, Funda
- Review of Scientific Instruments, Vol. 81, Issue 5
In situ x-ray photoelectron spectroscopy for electrochemical reactions in ordinary solvents
journal, September 2013
- Masuda, Takuya; Yoshikawa, Hideki; Noguchi, Hidenori
- Applied Physics Letters, Vol. 103, Issue 11
In situ study of an oxidation reaction on a Pt/C electrode by ambient pressure hard X-ray photoelectron spectroscopy
journal, September 2014
- Takagi, Yasumasa; Wang, Heng; Uemura, Yohei
- Applied Physics Letters, Vol. 105, Issue 13
Influence of the Local Surface Structure on the Photoemission of Adsorbed Xenon
journal, September 1979
- Küppers, J.; Wandelt, K.; Ertl, G.
- Physical Review Letters, Vol. 43, Issue 13
Reaction-Driven Restructuring of Rh-Pd and Pt-Pd Core-Shell Nanoparticles
journal, November 2008
- Tao, F.; Grass, M. E.; Zhang, Y.
- Science, Vol. 322, Issue 5903
Break-Up of Stepped Platinum Catalyst Surfaces by High CO Coverage
journal, February 2010
- Tao, F.; Dag, S.; Wang, L. -W.
- Science, Vol. 327, Issue 5967
Works referencing / citing this record:
Electronic Structure Characterization of Soft Semiconductors
journal, June 2019
- Liu, Xianjie; Fahlman, Mats
- Advanced Materials Interfaces
NiFe-Based (Oxy)hydroxide Catalysts for Oxygen Evolution Reaction in Non-Acidic Electrolytes
journal, July 2016
- Dionigi, Fabio; Strasser, Peter
- Advanced Energy Materials, Vol. 6, Issue 23
Electrode Architecture in Galvanic and Electrolytic Energy Cells
journal, March 2016
- Jeong, Beomgyun; Ocon, Joey D.; Lee, Jaeyoung
- Angewandte Chemie International Edition, Vol. 55, Issue 16
Ambient Pressure Photoelectron Spectroscopy: Opportunities in Catalysis from Solids to Liquids and Introducing Time Resolution
journal, January 2018
- Roy, Kanak; Artiglia, Luca; van Bokhoven, Jeroen A.
- ChemCatChem, Vol. 10, Issue 4
In‐Situ/Operando X‐ray Characterization of Metal Hydrides
journal, March 2019
- Liu, Yi‐Sheng; Jeong, Sohee; White, James L.
- ChemPhysChem, Vol. 20, Issue 10
External RBS analysis setup at University of Göttingen: RBS analysis for liquid samples
journal, February 2018
- Saito, M.; Holm, K.; Bregolin, F. L.
- Surface and Interface Analysis, Vol. 50, Issue 11
Single-Atom Electrocatalysts for Water Splitting
book, January 2020
- Guimaraes, Robson R.; Gonçalves, Josue M.; Björneholm, Olle
- Methods for Electrocatalysis: Advanced Materials and Allied Applications, p. 67-111
In Situ Electrochemical Cells to Study the Oxygen Evolution Reaction by Near Ambient Pressure X-ray Photoelectron Spectroscopy
journal, October 2018
- Streibel, Verena; Hävecker, Michael; Yi, Youngmi
- Topics in Catalysis, Vol. 61, Issue 20
Stabilizing the Meniscus for Operando Characterization of Platinum During the Electrolyte-Consuming Alkaline Oxygen Evolution Reaction
journal, October 2018
- Stoerzinger, Kelsey A.; Favaro, Marco; Ross, Philip N.
- Topics in Catalysis, Vol. 61, Issue 20
Various spectroelectrochemical cells for in situ observation of electrochemical processes at solid–liquid interfaces
journal, October 2018
- Masuda, Takuya
- Topics in Catalysis, Vol. 61, Issue 20
Speciation and Electronic Structure of La1−xSrxCoO3−δ During Oxygen Electrolysis
journal, October 2018
- Stoerzinger, Kelsey A.; Renshaw Wang, Xiao; Hwang, Jonathan
- Topics in Catalysis, Vol. 61, Issue 20
An APXPS endstation for gas–solid and liquid–solid interface studies at SSRF
journal, April 2019
- Cai, Jun; Dong, Qiao; Han, Yong
- Nuclear Science and Techniques, Vol. 30, Issue 5
Unravelling the electrochemical double layer by direct probing of the solid/liquid interface
journal, August 2016
- Favaro, Marco; Jeong, Beomgyun; Ross, Philip N.
- Nature Communications, Vol. 7, Issue 1
Probing a battery electrolyte drop with ambient pressure photoelectron spectroscopy
journal, July 2019
- Maibach, Julia; Källquist, Ida; Andersson, Margit
- Nature Communications, Vol. 10, Issue 1
Multiphase carbon mineralization for the reactive separation of CO2 and directed synthesis of H2
journal, January 2020
- Gadikota, Greeshma
- Nature Reviews Chemistry, Vol. 4, Issue 2
Frontiers of water oxidation: the quest for true catalysts
journal, January 2017
- Li, J.; Güttinger, R.; Moré, R.
- Chemical Society Reviews, Vol. 46, Issue 20
Molecular species forming at the α-Fe 2 O 3 nanoparticle–aqueous solution interface
journal, January 2018
- Ali, Hebatallah; Seidel, Robert; Pohl, Marvin N.
- Chemical Science, Vol. 9, Issue 19
Electronic structure of aqueous-phase anatase titanium dioxide nanoparticles probed by liquid jet photoelectron spectroscopy
journal, January 2019
- Ali, Hebatallah; Seidel, Robert; Bergmann, Arno
- Journal of Materials Chemistry A, Vol. 7, Issue 12
2D oxides on metal materials: concepts, status, and perspectives
journal, January 2019
- Barcaro, Giovanni; Fortunelli, Alessandro
- Physical Chemistry Chemical Physics, Vol. 21, Issue 22
The effect of grain size on the hydration of BaZr 0.9 Y 0.1 O 3−δ proton conductor studied by ambient pressure X-ray photoelectron spectroscopy
journal, January 2020
- Jarry, Angelique; Jackson, Gregory S.; Crumlin, Ethan J.
- Physical Chemistry Chemical Physics, Vol. 22, Issue 1
Atmospheric pressure X-ray photoelectron spectroscopy apparatus: Bridging the pressure gap
journal, May 2016
- Velasco-Vélez, J. J.; Pfeifer, V.; Hävecker, M.
- Review of Scientific Instruments, Vol. 87, Issue 5
Advances in liquid phase soft-x-ray photoemission spectroscopy: A new experimental setup at BESSY II
journal, July 2017
- Seidel, Robert; Pohl, Marvin N.; Ali, Hebatallah
- Review of Scientific Instruments, Vol. 88, Issue 7
Revealing the formation dynamics of the electric double layer by means of in - situ Rutherford backscattering spectrometry
journal, August 2019
- Khojasteh, Nasrin B.; Apelt, Sabine; Bergmann, Ute
- Review of Scientific Instruments, Vol. 90, Issue 8
Restructuring of silica supported vanadia during propane oxidative dehydrogenation studied by combined synchrotron radiation based in situ soft X-ray absorption and photoemission
journal, March 2017
- Hävecker, Michael; Düngen, Pascal; Buller, Saskia
- Catalysis, Structure & Reactivity, Vol. 3, Issue 1-2
Ambient pressure photoelectron spectroscopy: Practical considerations and experimental frontiers
journal, December 2016
- Trotochaud, Lena; Head, Ashley R.; Karslıoğlu, Osman
- Journal of Physics: Condensed Matter, Vol. 29, Issue 5
The offset droplet: a new methodology for studying the solid/water interface using x-ray photoelectron spectroscopy
journal, October 2017
- Booth, S. G.; Tripathi, A. M.; Strashnov, I.
- Journal of Physics: Condensed Matter, Vol. 29, Issue 45
Beyond Koopmans’ theorem: electron binding energies in disordered materials
journal, December 2018
- Muchová, Eva; Slavíček, Petr
- Journal of Physics: Condensed Matter, Vol. 31, Issue 4
In-depth study of the chemical/electronic structures of two-dimensional molybdenum disulfide materials with sub-micrometer-resolution scanning photoelectron microscopy
journal, January 2020
- Yun, Dong-Jin; Lee, Hyangsook; Baik, Jaeyoon
- 2D Materials, Vol. 7, Issue 2
Water-mediated photo-induced reduction of platinum films
journal, June 2019
- Fraxedas, Jordi; Zhang, Kuan; Sepúlveda, Borja
- Journal of Synchrotron Radiation, Vol. 26, Issue 4
Perovskites in catalysis and electrocatalysis
journal, November 2017
- Hwang, Jonathan; Rao, Reshma R.; Giordano, Livia
- Science, Vol. 358, Issue 6364
A high-pressure x-ray photoelectron spectroscopy instrument for studies of industrially relevant catalytic reactions at pressures of several bars
text, January 2019
- Amann, Peter; Degerman, David; Lee, Ming-Tao
- Deutsches Elektronen-Synchrotron, DESY, Hamburg
Interface Science Using Ambient Pressure Hard X-ray Photoelectron Spectroscopy
journal, January 2019
- Favaro, Marco; Abdi, Fatwa; Crumlin, Ethan
- Surfaces, Vol. 2, Issue 1
A high-pressure x-ray photoelectron spectroscopy instrument for studies of industrially relevant catalytic reactions at pressures of several bars
journal, October 2019
- Amann, Peter; Degerman, David; Lee, Ming-Tao
- Review of Scientific Instruments, Vol. 90, Issue 10
Water-mediated photo-induced reduction of platinum films
text, January 2019
- Fraxedas, Jordi; Zhang, Kuan; Sepúlveda, Borja
- International Union of Crystallography (IUCr)
Probing a battery electrolyte drop with ambient pressure photoelectron spectroscopy
text, January 2019
- Maibach, Julia; Källquist, Ida; Andersson, Margit
- Karlsruhe
Restructuring of silica supported vanadia during propane oxidative dehydrogenation studied by combined synchrotron radiation based in situ soft X-ray absorption and photoemission
text, January 2017
- Hävecker, Michael; Düngen, Pascal; Buller, Saskia
- Taylor & Francis
A high-pressure x-ray photoelectron spectroscopy instrument for studies of industrially relevant catalytic reactions at pressures of several bars
text, January 2019
- Amann, Peter; Degerman, David; Lee, Ming-Tao
- Deutsches Elektronen-Synchrotron, DESY, Hamburg
Restructuring of silica supported vanadia during propane oxidative dehydrogenation studied by combined synchrotron radiation based in situ soft X-ray absorption and photoemission
text, January 2017
- Hävecker, Michael; Düngen, Pascal; Buller, Saskia
- Taylor & Francis
Nanocarbon-Edge-Anchored High-Density Pt Atoms for 3-nitrostyrene Hydrogenation: Strong Metal-Carbon Interaction
journal, March 2019
- Lou, Yang; Wu, Honglu; Liu, Jingyue
- iScience, Vol. 13
The Oxidation of Platinum under Wet Conditions Observed by Electrochemical X-ray Photoelectron Spectroscopy
journal, March 2019
- Mom, Rik; Frevel, Lorenz; Velasco-Vélez, Juan-Jesús
- Journal of the American Chemical Society, Vol. 141, Issue 16
Unravelling the electrochemical double layer by direct probing of the solid/liquid interface
journal, August 2016
- Favaro, Marco; Jeong, Beomgyun; Ross, Philip N.
- Nature Communications, Vol. 7, Issue 1
Probing a battery electrolyte drop with ambient pressure photoelectron spectroscopy
text, January 2019
- Maibach, Julia; Källquist, Ida; Andersson, Margit
- Karlsruhe