DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: A new family of fluidic precursors for the self-templated synthesis of hierarchical nanoporous carbons

Abstract

Hierarchical nanoporous nitrogen-doped carbons were prepared from task specific ionic liquids having a bis-imidazolium motif linked with various organic groups. While ethyl chains linking the imidazolium ions afford microporous-mesoporous carbons, long or aromatic groups resulted in microporous samples.

Authors:
 [1];  [1];  [1];  [1];  [2];  [3]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1185352
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 49; Journal Issue: 66; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Fulvio, Pasquale F., Hillesheim, Patrick C., Oyola, Yatsandra, Mahurin, Shannon Mark, Veith, Gabriel M., and Dai, Sheng. A new family of fluidic precursors for the self-templated synthesis of hierarchical nanoporous carbons. United States: N. p., 2016. Web. doi:10.1039/c3cc44175j.
Fulvio, Pasquale F., Hillesheim, Patrick C., Oyola, Yatsandra, Mahurin, Shannon Mark, Veith, Gabriel M., & Dai, Sheng. A new family of fluidic precursors for the self-templated synthesis of hierarchical nanoporous carbons. United States. https://doi.org/10.1039/c3cc44175j
Fulvio, Pasquale F., Hillesheim, Patrick C., Oyola, Yatsandra, Mahurin, Shannon Mark, Veith, Gabriel M., and Dai, Sheng. Fri . "A new family of fluidic precursors for the self-templated synthesis of hierarchical nanoporous carbons". United States. https://doi.org/10.1039/c3cc44175j. https://www.osti.gov/servlets/purl/1185352.
@article{osti_1185352,
title = {A new family of fluidic precursors for the self-templated synthesis of hierarchical nanoporous carbons},
author = {Fulvio, Pasquale F. and Hillesheim, Patrick C. and Oyola, Yatsandra and Mahurin, Shannon Mark and Veith, Gabriel M. and Dai, Sheng},
abstractNote = {Hierarchical nanoporous nitrogen-doped carbons were prepared from task specific ionic liquids having a bis-imidazolium motif linked with various organic groups. While ethyl chains linking the imidazolium ions afford microporous-mesoporous carbons, long or aromatic groups resulted in microporous samples.},
doi = {10.1039/c3cc44175j},
journal = {ChemComm},
number = 66,
volume = 49,
place = {United States},
year = {Fri Jun 24 00:00:00 EDT 2016},
month = {Fri Jun 24 00:00:00 EDT 2016}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 29 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Carbon properties and their role in supercapacitors
journal, June 2006


Synthesis of New, Nanoporous Carbon with Hexagonally Ordered Mesostructure
journal, November 2000

  • Jun, Shinae; Joo, Sang Hoon; Ryoo, Ryong
  • Journal of the American Chemical Society, Vol. 122, Issue 43
  • DOI: 10.1021/ja002261e

Synthesis of Highly Ordered Carbon Molecular Sieves via Template-Mediated Structural Transformation
journal, September 1999

  • Ryoo, Ryong; Joo, Sang Hoon; Jun, Shinae
  • The Journal of Physical Chemistry B, Vol. 103, Issue 37
  • DOI: 10.1021/jp991673a

High-Rate Electrochemical Capacitors Based on Ordered Mesoporous Silicon Carbide-Derived Carbon
journal, February 2010

  • Korenblit, Yair; Rose, Marcus; Kockrick, Emanuel
  • ACS Nano, Vol. 4, Issue 3
  • DOI: 10.1021/nn901825y

Synthesis of Mesoporous Carbon Materials via Enhanced Hydrogen-Bonding Interaction
journal, April 2006

  • Liang, Chengdu; Dai, Sheng
  • Journal of the American Chemical Society, Vol. 128, Issue 16, p. 5316-5317
  • DOI: 10.1021/ja060242k

Synthesis of a Large-Scale Highly Ordered Porous Carbon Film by Self-Assembly of Block Copolymers
journal, November 2004

  • Liang, Chengdu; Hong, Kunlun; Guiochon, Georges A.
  • Angewandte Chemie International Edition, Vol. 43, Issue 43, p. 5785-5789
  • DOI: 10.1002/anie.200461051

Carbon materials for the electrochemical storage of energy in capacitors
journal, May 2001


Materials for electrochemical capacitors
journal, November 2008

  • Simon, Patrice; Gogotsi, Yury
  • Nature Materials, Vol. 7, Issue 11
  • DOI: 10.1038/nmat2297

Electrochemical characterizations of carbon nanomaterials by the cavity microelectrode technique
journal, November 2008


Charge storage mechanism in nanoporous carbons and its consequence for electrical double layer capacitors
journal, June 2010

  • Simon, P.; Gogotsi, Y.
  • Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 368, Issue 1923, p. 3457-3467
  • DOI: 10.1098/rsta.2010.0109

Anomalous Increase in Carbon Capacitance at Pore Sizes Less Than 1 Nanometer
journal, September 2006


Ionic liquids: solvent properties and organic reactivity
journal, January 2005

  • Chiappe, Cinzia; Pieraccini, Daniela
  • Journal of Physical Organic Chemistry, Vol. 18, Issue 4
  • DOI: 10.1002/poc.863

Ionic Liquids as Versatile Precursors for Functionalized Porous Carbon and Carbon-Oxide Composite Materials by Confined Carbonization
journal, August 2010

  • Wang, Xiqing; Dai, Sheng
  • Angewandte Chemie International Edition, Vol. 49, Issue 37
  • DOI: 10.1002/anie.201003163

A detailed view on the polycondensation of ionic liquid monomers towards nitrogen doped carbon materials
journal, January 2010

  • Paraknowitsch, Jens Peter; Thomas, Arne; Antonietti, Markus
  • Journal of Materials Chemistry, Vol. 20, Issue 32
  • DOI: 10.1039/c0jm00869a

Ionic Liquids as Precursors for Nitrogen-Doped Graphitic Carbon
journal, January 2010

  • Paraknowitsch, Jens Peter; Zhang, Jian; Su, Dangsheng
  • Advanced Materials, Vol. 22, Issue 1
  • DOI: 10.1002/adma.200900965

Fluidic Carbon Precursors for Formation of Functional Carbon under Ambient Pressure Based on Ionic Liquids
journal, December 2009


Facile Ionothermal Synthesis of Microporous and Mesoporous Carbons from Task Specific Ionic Liquids
journal, April 2009

  • Lee, Je Seung; Wang, Xiqing; Luo, Huimin
  • Journal of the American Chemical Society, Vol. 131, Issue 13
  • DOI: 10.1021/ja900686d

Boron and nitrogen-rich carbons from ionic liquid precursors with tailorable surface properties
journal, January 2011

  • Fulvio, Pasquale F.; Lee, Je Seung; Mayes, Richard T.
  • Physical Chemistry Chemical Physics, Vol. 13, Issue 30
  • DOI: 10.1039/c1cp20631a

Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis
journal, August 1999

  • Welton, Thomas
  • Chemical Reviews, Vol. 99, Issue 8, p. 2071-2084
  • DOI: 10.1021/cr980032t

Preparation of Inorganic Materials Using Ionic Liquids
journal, January 2010


Functional Carbon Materials From Ionic Liquid Precursors
journal, March 2012

  • Paraknowitsch, Jens Peter; Thomas, Arne
  • Macromolecular Chemistry and Physics, Vol. 213, Issue 10-11
  • DOI: 10.1002/macp.201100573

Gas Adsorption Characterization of Ordered Organic−Inorganic Nanocomposite Materials
journal, October 2001

  • Kruk, Michal; Jaroniec, Mietek
  • Chemistry of Materials, Vol. 13, Issue 10
  • DOI: 10.1021/cm0101069

Nitrogen-Enriched Nonporous Carbon Electrodes with Extraordinary Supercapacitance
journal, June 2009

  • Hulicova-Jurcakova, Denisa; Kodama, Masaya; Shiraishi, Soshi
  • Advanced Functional Materials, Vol. 19, Issue 11
  • DOI: 10.1002/adfm.200801100

Effect of nitrogen in carbon electrode on the supercapacitor performance
journal, March 2005


Low-Temperature Fluorination of Soft-Templated Mesoporous Carbons for a High-Power Lithium/Carbon Fluoride Battery
journal, October 2011

  • Fulvio, Pasquale F.; Brown, Suree S.; Adcock, Jamie
  • Chemistry of Materials, Vol. 23, Issue 20
  • DOI: 10.1021/cm2012395

Mechanochemical Synthesis of Carbon Fluorides
journal, January 2009

  • Read, Jeffrey A.; Behl, Wishvender K.
  • Electrochemical and Solid-State Letters, Vol. 12, Issue 1
  • DOI: 10.1149/1.3008701

On the so-called “semi-ionic” C–F bond character in fluorine–GIC
journal, January 2004


“Brick-and-Mortar” Self-Assembly Approach to Graphitic Mesoporous Carbon Nanocomposites
journal, April 2011

  • Fulvio, Pasquale F.; Mayes, Richard T.; Wang, Xiqing
  • Advanced Functional Materials, Vol. 21, Issue 12, p. 2208-2215
  • DOI: 10.1002/adfm.201002641

Synthesis of a Large-Scale Highly Ordered Porous Carbon Film by Self-Assembly of Block Copolymers
journal, November 2004

  • Liang, Chengdu; Hong, Kunlun; Guiochon, Georges A.
  • Angewandte Chemie, Vol. 116, Issue 43
  • DOI: 10.1002/ange.200461051

Ionic Liquids: Solvent Properties and Organic Reactivity
journal, August 2005


Works referencing / citing this record:

Synthesis of Functional Nanomaterials in Ionic Liquids
journal, November 2015


Silica‐assisted urea‐formaldehyde‐based carbon microspheres with enhanced supercapacitor performances as electrode
journal, August 2019

  • Yue, Jiaji; Yuan, Mengying; Zhao, Hui
  • Journal of Applied Polymer Science, Vol. 137, Issue 8
  • DOI: 10.1002/app.48388

Synthesis of Highly Active and Stable Spinel-Type Oxygen Evolution Electrocatalysts by a Rapid Inorganic Self-Templating Method
journal, August 2014

  • Ma, Tian Yi; Dai, Sheng; Jaroniec, Mietek
  • Chemistry - A European Journal, Vol. 20, Issue 39
  • DOI: 10.1002/chem.201403946

Heteroatom-Containing Porous Carbons Derived from Ionic Liquid-Doped Alkali Organic Salts for Supercapacitors
journal, February 2016


Ionic liquids and their solid-state analogues as materials for energy generation and storage
journal, January 2016

  • MacFarlane, Douglas R.; Forsyth, Maria; Howlett, Patrick C.
  • Nature Reviews Materials, Vol. 1, Issue 2
  • DOI: 10.1038/natrevmats.2015.5

N-doped ordered mesoporous carbons with improved charge storage capacity by tailoring N-dopant density with solvent-assisted synthesis
journal, January 2014

  • Almeida, Vitor C.; Silva, Rafael; Acerce, Muharrem
  • J. Mater. Chem. A, Vol. 2, Issue 36
  • DOI: 10.1039/c4ta02236j

Slat templated formation of efficient oxygen reduction electrocatalyst with a fluidic precursor
journal, May 2018