CO2 hydrogenation catalyzed by iridium complexes with a proton-responsive ligand
Abstract
In this study, the catalytic cycle for the production of formic acid by CO₂ hydrogenation and the reverse reaction has received renewed attention because they are viewed as offering a viable scheme for hydrogen storage and release. In this Forum Article, CO₂ hydrogenation catalyzed by iridium complexes bearing N^N-bidentate ligands is reported. We describe how a ligand containing hydroxyl groups as proton-responsive substituents enhances catalytic performance by an electronic effect of the oxyanions and a pendent-base effect through secondary coordination sphere interaction. In particular, [(Cp*IrCl)₂(TH2BPM)]Cl₂ (Cp* = pentamethyl cyclopentadienyl, TH2BPM = 4,4',6,6'-tetrahydroxy-2,2'-bipyrimidine) promotes enormously the catalytic hydrogenation of CO₂ by these synergistic effects under atmospheric pressure and at room temperature. Additionally, newly designed complexes with azole-type ligands are applied to CO₂ hydrogenation. The catalytic efficiencies of the azole-type complexes are much higher than that of the unsubstituted bipyridine complex [Cp*Ir(bpy)(OH₂)]SO₄. Furthermore, the introduction of one or more hydroxyl groups into ligands such as 2-pyrazolyl-6-hydroxypyridine, 2-pyrazolyl-4,6-dihydroxyl pyrimidine, and 4-pyrazolyl-2,6-dihydroxyl pyrimidine enhanced catalytic activity. It is clear that the incorporation of electron-donating hydroxyl groups into proton-responsive ligands is effective for promoting the hydrogenation of CO₂.
- Authors:
-
- National Institute of Advanced Industrial Science and Technology, Ibaraki (Japan); Japan Science and Technology Agency, Saitama (Japan)
- National Institute of Advanced Industrial Science and Technology, Ibaraki (Japan)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1182536
- Report Number(s):
- BNL-107637-2015-JA
Journal ID: ISSN 0020-1669; R&D Project: CO026; KC0304030
- Grant/Contract Number:
- SC00112704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Inorganic Chemistry
- Additional Journal Information:
- Journal Volume: 54; Journal Issue: 11; Journal ID: ISSN 0020-1669
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; proton-responsive ligand; iridium complexes; CO₂ hydrogenation
Citation Formats
Onishi, Naoya, Xu, Shaoan, Manaka, Yuichi, Suna, Yuki, Wang, Wan -Hui, Muckerman, James T., Fujita, Etsuko, and Himeda, Yuichiro. CO2 hydrogenation catalyzed by iridium complexes with a proton-responsive ligand. United States: N. p., 2015.
Web. doi:10.1021/ic502904q.
Onishi, Naoya, Xu, Shaoan, Manaka, Yuichi, Suna, Yuki, Wang, Wan -Hui, Muckerman, James T., Fujita, Etsuko, & Himeda, Yuichiro. CO2 hydrogenation catalyzed by iridium complexes with a proton-responsive ligand. United States. https://doi.org/10.1021/ic502904q
Onishi, Naoya, Xu, Shaoan, Manaka, Yuichi, Suna, Yuki, Wang, Wan -Hui, Muckerman, James T., Fujita, Etsuko, and Himeda, Yuichiro. Wed .
"CO2 hydrogenation catalyzed by iridium complexes with a proton-responsive ligand". United States. https://doi.org/10.1021/ic502904q. https://www.osti.gov/servlets/purl/1182536.
@article{osti_1182536,
title = {CO2 hydrogenation catalyzed by iridium complexes with a proton-responsive ligand},
author = {Onishi, Naoya and Xu, Shaoan and Manaka, Yuichi and Suna, Yuki and Wang, Wan -Hui and Muckerman, James T. and Fujita, Etsuko and Himeda, Yuichiro},
abstractNote = {In this study, the catalytic cycle for the production of formic acid by CO₂ hydrogenation and the reverse reaction has received renewed attention because they are viewed as offering a viable scheme for hydrogen storage and release. In this Forum Article, CO₂ hydrogenation catalyzed by iridium complexes bearing N^N-bidentate ligands is reported. We describe how a ligand containing hydroxyl groups as proton-responsive substituents enhances catalytic performance by an electronic effect of the oxyanions and a pendent-base effect through secondary coordination sphere interaction. In particular, [(Cp*IrCl)₂(TH2BPM)]Cl₂ (Cp* = pentamethyl cyclopentadienyl, TH2BPM = 4,4',6,6'-tetrahydroxy-2,2'-bipyrimidine) promotes enormously the catalytic hydrogenation of CO₂ by these synergistic effects under atmospheric pressure and at room temperature. Additionally, newly designed complexes with azole-type ligands are applied to CO₂ hydrogenation. The catalytic efficiencies of the azole-type complexes are much higher than that of the unsubstituted bipyridine complex [Cp*Ir(bpy)(OH₂)]SO₄. Furthermore, the introduction of one or more hydroxyl groups into ligands such as 2-pyrazolyl-6-hydroxypyridine, 2-pyrazolyl-4,6-dihydroxyl pyrimidine, and 4-pyrazolyl-2,6-dihydroxyl pyrimidine enhanced catalytic activity. It is clear that the incorporation of electron-donating hydroxyl groups into proton-responsive ligands is effective for promoting the hydrogenation of CO₂.},
doi = {10.1021/ic502904q},
journal = {Inorganic Chemistry},
number = 11,
volume = 54,
place = {United States},
year = {Wed Feb 18 00:00:00 EST 2015},
month = {Wed Feb 18 00:00:00 EST 2015}
}
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Works referenced in this record:
Catalysis for the Valorization of Exhaust Carbon: from CO 2 to Chemicals, Materials, and Fuels. Technological Use of CO 2
journal, November 2013
- Aresta, Michele; Dibenedetto, Angela; Angelini, Antonella
- Chemical Reviews, Vol. 114, Issue 3
Recent advances in catalytic hydrogenation of carbon dioxide
journal, January 2011
- Wang, Wei; Wang, Shengping; Ma, Xinbin
- Chemical Society Reviews, Vol. 40, Issue 7
Catalysis Research of Relevance to Carbon Management: Progress, Challenges, and Opportunities
journal, April 2001
- Arakawa, Hironori; Aresta, Michele; Armor, John N.
- Chemical Reviews, Vol. 101, Issue 4
Transformation of Carbon Dioxide
journal, June 2007
- Sakakura, Toshiyasu; Choi, Jun-Chul; Yasuda, Hiroyuki
- Chemical Reviews, Vol. 107, Issue 6
The Hydrogen Issue
journal, December 2010
- Armaroli, Nicola; Balzani, Vincenzo
- ChemSusChem, Vol. 4, Issue 1
Liquid-phase chemical hydrogen storage materials
journal, January 2012
- Yadav, Mahendra; Xu, Qiang
- Energy & Environmental Science, Vol. 5, Issue 12
Hydrogen generation from formic acid and alcohols using homogeneous catalysts
journal, January 2010
- Johnson, Tarn C.; Morris, David J.; Wills, Martin
- Chem. Soc. Rev., Vol. 39, Issue 1
B–N compounds for chemical hydrogenstorage
journal, January 2009
- Hamilton, Charles W.; Baker, R. Tom; Staubitz, Anne
- Chem. Soc. Rev., Vol. 38, Issue 1, p. 279-293
Development of dehydrogenation catalyst for hydrogen generation in organic chemical hydride method
journal, August 2006
- Okada, Y.; Sasaki, E.; Watanabe, E.
- International Journal of Hydrogen Energy, Vol. 31, Issue 10
CO2-“Neutral” Hydrogen Storage Based on Bicarbonates and Formates
journal, May 2011
- Boddien, Albert; Gärtner, Felix; Federsel, Christopher
- Angewandte Chemie International Edition, Vol. 50, Issue 28
Towards the development of a hydrogen battery
journal, January 2012
- Boddien, Albert; Federsel, Christopher; Sponholz, Peter
- Energy & Environmental Science, Vol. 5, Issue 10
A Rechargeable Hydrogen Battery Based on Ru Catalysis
journal, May 2014
- Hsu, Shih-Fan; Rommel, Susanne; Eversfield, Philipp
- Angewandte Chemie International Edition, Vol. 53, Issue 27
Catalytic Fixation of Carbon Dioxide to Formic acid by Transition-Metal Complexes Under mild Conditions
journal, August 1976
- Inoue, Yoshio; Izumida, Hitoshi; Sasaki, Yoshiyuki
- Chemistry Letters, Vol. 5, Issue 8
Recent advances in the homogeneous hydrogenation of carbon dioxide
journal, December 2004
- Jessop, Philip G.; Joó, Ferenc; Tai, Chih-Cheng
- Coordination Chemistry Reviews, Vol. 248, Issue 21-24, p. 2425-2442
Interconversion of CO2 and formic acid by bio-inspired Ir complexes with pendent bases
journal, August 2013
- Fujita, Etsuko; Muckerman, James T.; Himeda, Yuichiro
- Biochimica et Biophysica Acta (BBA) - Bioenergetics, Vol. 1827, Issue 8-9
High-Pressure Combinatorial Screening of Homogeneous Catalysts: Hydrogenation of Carbon Dioxide
journal, November 2003
- Tai, Chih-Cheng; Chang, Tangel; Roller, Brentin
- Inorganic Chemistry, Vol. 42, Issue 23
Liquid Poly(ethylene glycol) and Supercritical Carbon Dioxide: A Benign Biphasic Solvent System for Use and Recycling of Homogeneous Catalysts
journal, May 2003
- Heldebrant, David J.; Jessop, Philip G.
- Journal of the American Chemical Society, Vol. 125, Issue 19
In Situ Formation of Ruthenium Catalysts for the Homogeneous Hydrogenation of Carbon Dioxide
journal, March 2002
- Tai, Chih-Cheng; Pitts, Justine; Linehan, John C.
- Inorganic Chemistry, Vol. 41, Issue 6
Homogeneous catalytic hydrogenation of supercritical carbon dioxide
journal, March 1994
- Jessop, Philip G.; Ikariya, Takao; Noyori, Ryoji
- Nature, Vol. 368, Issue 6468
Activation of carbon dioxide
journal, July 1994
- Leitner, Walter; Dinjus, Eckhard; Gaßner, Franz
- Journal of Organometallic Chemistry, Vol. 475, Issue 1-2
Homogeneous hydrogenation of aqueous hydrogen carbonate to formate under exceedingly mild conditions—a novel possibility of carbon dioxide activation†
journal, January 1999
- Joó, Ferenc; Joó, Ferenc; Nádasdi, Levente
- Chemical Communications, Issue 11
Formation and Characterization of Water-Soluble Hydrido-Ruthenium(II) Complexes of 1,3,5-Triaza-7-phosphaadamantane and Their Catalytic Activity in Hydrogenation of CO 2 and HCO 3 - in Aqueous Solution
journal, October 2000
- Laurenczy, Gábor; Joó, Ferenc; Nádasdi, Levente
- Inorganic Chemistry, Vol. 39, Issue 22
Structure-Reactivity Relationships in the Hydrogenation of Carbon Dioxide with Ruthenium Complexes Bearing Pyridinylazolato Ligands
journal, April 2013
- Muller, Keven; Sun, Yu; Heimermann, Andreas
- Chemistry - A European Journal, Vol. 19, Issue 24
Direct synthesis of formic acid from carbon dioxide by hydrogenation in acidic media
journal, June 2014
- Moret, Séverine; Dyson, Paul J.; Laurenczy, Gábor
- Nature Communications, Vol. 5, Issue 1
(Pentamethylcyclopentadienyl)iridium-PTA (PTA = 1,3,5-Triaza-7-phosphaadamantane) Complexes and Their Application in Catalytic Water Phase Carbon Dioxide Hydrogenation
journal, February 2008
- Erlandsson, Mikael; Landaeta, Vanessa R.; Gonsalvi, Luca
- European Journal of Inorganic Chemistry, Vol. 2008, Issue 4
Half-Sandwich Complexes with 4,7-Dihydroxy-1,10-phenanthroline: Water-Soluble, Highly Efficient Catalysts for Hydrogenation of Bicarbonate Attributable to the Generation of an Oxyanion on the Catalyst Ligand
journal, March 2004
- Himeda, Yuichiro; Onozawa-Komatsuzaki, Nobuko; Sugihara, Hideki
- Organometallics, Vol. 23, Issue 7
CO 2 Activation and Catalysis Driven by Iridium Complexes
journal, September 2013
- Fernández-Alvarez, Francisco J.; Iglesias, Manuel; Oro, Luis A.
- ChemCatChem, Vol. 5, Issue 12
Catalytic interconversion between hydrogen and formic acid at ambient temperature and pressure
journal, January 2012
- Maenaka, Yuta; Suenobu, Tomoyoshi; Fukuzumi, Shunichi
- Energy & Environmental Science, Vol. 5, Issue 6
Secondary Coordination Sphere Interactions Facilitate the Insertion Step in an Iridium(III) CO 2 Reduction Catalyst
journal, June 2011
- Schmeier, Timothy J.; Dobereiner, Graham E.; Crabtree, Robert H.
- Journal of the American Chemical Society, Vol. 133, Issue 24
Highly Efficient Reversible Hydrogenation of Carbon Dioxide to Formates Using a Ruthenium PNP-Pincer Catalyst
journal, April 2014
- Filonenko, Georgy A.; van Putten, Robbert; Schulpen, Erik N.
- ChemCatChem, Vol. 6, Issue 6
A Well-Defined Iron Catalyst for the Reduction of Bicarbonates and Carbon Dioxide to Formates, Alkyl Formates, and Formamides
journal, November 2010
- Federsel, Christopher; Boddien, Albert; Jackstell, Ralf
- Angewandte Chemie International Edition, Vol. 49, Issue 50
Well-Defined Iron Catalyst for Improved Hydrogenation of Carbon Dioxide and Bicarbonate
journal, December 2012
- Ziebart, Carolin; Federsel, Christopher; Anbarasan, Pazhamalai
- Journal of the American Chemical Society, Vol. 134, Issue 51
Catalytic Hydrogenation of Carbon Dioxide and Bicarbonates with a Well-Defined Cobalt Dihydrogen Complex
journal, December 2011
- Federsel, Christopher; Ziebart, Carolin; Jackstell, Ralf
- Chemistry - A European Journal, Vol. 18, Issue 1
A Cobalt-Based Catalyst for the Hydrogenation of CO 2 under Ambient Conditions
journal, July 2013
- Jeletic, Matthew S.; Mock, Michael T.; Appel, Aaron M.
- Journal of the American Chemical Society, Vol. 135, Issue 31
Cp*Co(III) Catalysts with Proton-Responsive Ligands for Carbon Dioxide Hydrogenation in Aqueous Media
journal, October 2013
- Badiei, Yosra M.; Wang, Wan-Hui; Hull, Jonathan F.
- Inorganic Chemistry, Vol. 52, Issue 21
Low-Pressure Hydrogenation of Carbon Dioxide Catalyzed by an Iron Pincer Complex Exhibiting Noble Metal Activity
journal, September 2011
- Langer, Robert; Diskin-Posner, Yael; Leitus, Gregory
- Angewandte Chemie International Edition, Vol. 50, Issue 42
A New Approach to the Reduction of Carbon Dioxide: CO 2 Reduction to Formate by Transfer Hydrogenation in i PrOH
journal, October 2009
- Sanz, Sergio; Benítez, Miriam; Peris, Eduardo
- Organometallics, Vol. 29, Issue 1
Water-Soluble IrIII N-Heterocyclic Carbene Based Catalysts for the Reduction of CO2 to Formate by Transfer Hydrogenation and the Deuteration of Aryl Amines in Water
journal, March 2011
- Azua, Arturo; Sanz, Sergio; Peris, Eduardo
- Chemistry - A European Journal, Vol. 17, Issue 14
‘(η6-arene)Ru(bis-NHC)’ complexes for the reduction of CO2 to formate with hydrogen and by transfer hydrogenation with iPrOH
journal, January 2010
- Sanz, Sergio; Azua, Arturo; Peris, Eduardo
- Dalton Transactions, Vol. 39, Issue 27
Towards a Sustainable Synthesis of Formate Salts: Combined Catalytic Methanol Dehydrogenation and Bicarbonate Hydrogenation
journal, May 2014
- Liu, Qiang; Wu, Lipeng; Gülak, Samet
- Angewandte Chemie International Edition, Vol. 53, Issue 27
Formic acid as a hydrogen source – recent developments and future trends
journal, January 2012
- Grasemann, Martin; Laurenczy, Gábor
- Energy & Environmental Science, Vol. 5, Issue 8
Carbon dioxide and formic acid—the couple for environmental-friendly hydrogen storage?
journal, January 2010
- Enthaler, Stephan; von Langermann, Jan; Schmidt, Thomas
- Energy & Environmental Science, Vol. 3, Issue 9
Hydrogen storage: beyond conventional methods
journal, January 2013
- Dalebrook, Andrew F.; Gan, Weijia; Grasemann, Martin
- Chemical Communications, Vol. 49, Issue 78
Controlled Generation of Hydrogen from Formic Acid Amine Adducts at Room Temperature and Application in H 2 /O 2 Fuel Cells
journal, May 2008
- Loges, Björn; Boddien, Albert; Junge, Henrik
- Angewandte Chemie International Edition, Vol. 47, Issue 21
A Viable Hydrogen-Storage System Based On Selective Formic Acid Decomposition with a Ruthenium Catalyst
journal, May 2008
- Fellay, Céline; Dyson, Paul J.; Laurenczy, Gábor
- Angewandte Chemie International Edition, Vol. 47, Issue 21, p. 3966-3968
Insights into Hydrogen Generation from Formic Acid Using Ruthenium Complexes
journal, July 2009
- Morris, David J.; Clarkson, Guy J.; Wills, Martin
- Organometallics, Vol. 28, Issue 14
Mechanistic Studies on the Reversible Hydrogenation of Carbon Dioxide Catalyzed by an Ir-PNP Complex
journal, December 2011
- Tanaka, Ryo; Yamashita, Makoto; Chung, Lung Wa
- Organometallics, Vol. 30, Issue 24
Efficient Dehydrogenation of Formic Acid Using an Iron Catalyst
journal, September 2011
- Boddien, A.; Mellmann, D.; Gartner, F.
- Science, Vol. 333, Issue 6050
Hydrogen Generation from Formic Acid Decomposition by Ruthenium Carbonyl Complexes. Tetraruthenium Dodecacarbonyl Tetrahydride as an Active Intermediate
journal, March 2011
- Czaun, Miklos; Goeppert, Alain; May, Robert
- ChemSusChem, Vol. 4, Issue 9
Formic Acid As a Hydrogen Storage Medium: Ruthenium-Catalyzed Generation of Hydrogen from Formic Acid in Emulsions
journal, December 2013
- Czaun, Miklos; Goeppert, Alain; Kothandaraman, Jotheeswari
- ACS Catalysis, Vol. 4, Issue 1
Long-range metal–ligand bifunctional catalysis: cyclometallated iridium catalysts for the mild and rapid dehydrogenation of formic acid
journal, January 2013
- Barnard, Jonathan H.; Wang, Chao; Berry, Neil G.
- Chemical Science, Vol. 4, Issue 3
Base‐Free Non‐Noble‐Metal‐Catalyzed Hydrogen Generation from Formic Acid: Scope and Mechanistic Insights
journal, September 2014
- Mellmann, Dörthe; Barsch, Enrico; Bauer, Matthias
- Chemistry – A European Journal, Vol. 20, Issue 42
Towards a Practical Setup for Hydrogen Production from Formic Acid
journal, June 2013
- Sponholz, Peter; Mellmann, Dörthe; Junge, Henrik
- ChemSusChem, Vol. 6, Issue 7
Lewis Acid-Assisted Formic Acid Dehydrogenation Using a Pincer-Supported Iron Catalyst
journal, July 2014
- Bielinski, Elizabeth A.; Lagaditis, Paraskevi O.; Zhang, Yuanyuan
- Journal of the American Chemical Society, Vol. 136, Issue 29
Exploring the Reactivity of Nickel Pincer Complexes in the Decomposition of Formic Acid to CO 2 /H 2 and the Hydrogenation of NaHCO 3 to HCOONa
journal, October 2014
- Enthaler, Stephan; Brück, Andreas; Kammer, Anja
- ChemCatChem, Vol. 7, Issue 1
Heterogeneous Silica-Supported Ruthenium Phosphine Catalysts for Selective Formic Acid Decomposition
journal, June 2013
- Gan, Weijia; Dyson, Paul J.; Laurenczy, Gábor
- ChemCatChem, Vol. 5, Issue 10
Hydrogen Production by Selective Dehydrogenation of HCOOH Catalyzed by Ru-Biaryl Sulfonated Phosphines in Aqueous Solution
journal, August 2014
- Guerriero, Antonella; Bricout, Hervé; Sordakis, Katerina
- ACS Catalysis, Vol. 4, Issue 9
Ruthenium(II)-Catalyzed Hydrogen Generation from Formic Acid using Cationic, Ammoniomethyl-Substituted Triarylphosphine Ligands
journal, March 2013
- Gan, Weijia; Snelders, Dennis J. M.; Dyson, Paul J.
- ChemCatChem, Vol. 5, Issue 5
Unusually Large Tunneling Effect on Highly Efficient Generation of Hydrogen and Hydrogen Isotopes in pH-Selective Decomposition of Formic Acid Catalyzed by a Heterodinuclear Iridium−Ruthenium Complex in Water
journal, February 2010
- Fukuzumi, Shunichi; Kobayashi, Takeshi; Suenobu, Tomoyoshi
- Journal of the American Chemical Society, Vol. 132, Issue 5
Highly efficient hydrogen evolution by decomposition of formic acid using an iridium catalyst with 4,4′-dihydroxy-2,2′-bipyridine
journal, January 2009
- Himeda, Yuichiro
- Green Chemistry, Vol. 11, Issue 12
Reversible hydrogen storage using CO2 and a proton-switchable iridium catalyst in aqueous media under mild temperatures and pressures
journal, March 2012
- Hull, Jonathan F.; Himeda, Yuichiro; Wang, Wan-Hui
- Nature Chemistry, Vol. 4, Issue 5, p. 383-388
Efficient H 2 generation from formic acid using azole complexes in water
journal, January 2014
- Manaka, Yuichi; Wang, Wan-Hui; Suna, Yuki
- Catal. Sci. Technol., Vol. 4, Issue 1
The interconversion of formic acid and hydrogen/carbon dioxide using a binuclear ruthenium complex catalyst
journal, January 2000
- Gao, Yuan; Kuncheria, Joshi K.; Jenkins, Hilary A.
- Journal of the Chemical Society, Dalton Transactions, Issue 18
A Charge/Discharge Device for Chemical Hydrogen Storage and Generation
journal, September 2011
- Papp, Gábor; Csorba, Jenő; Laurenczy, Gábor
- Angewandte Chemie International Edition, Vol. 50, Issue 44
Excited state proton transfer of ruthenium(II) complexes of 4,7-dihydroxy-1,10-phenanthroline. Increased acidity in the excited state
journal, October 1978
- Giordano, Paul J.; Bock, C. Randolph; Wrighton, Mark S.
- Journal of the American Chemical Society, Vol. 100, Issue 22
Polymer-Supported pH Sensors Based on Hydrophobically Bound Luminescent Ruthenium(II) Complexes
journal, January 1998
- Price, Jason M.; Xu, Wenying; Demas, J. N.
- Analytical Chemistry, Vol. 70, Issue 2
Structural, Electronic, and Acid/Base Properties of [Ru(bpy) 2 (bpy(OH) 2 )] 2+ (bpy = 2,2′-Bipyridine, bpy(OH) 2 = 4,4′-Dihydroxy-2,2′-bipyridine)
journal, April 2011
- Klein, Samantha; Dougherty, William G.; Kassel, W. Scott
- Inorganic Chemistry, Vol. 50, Issue 7
Structural, electronic and acid/base properties of [Ru(bpy(OH)2)3]2+ (bpy(OH)2 = 4,4′-dihydroxy-2,2′-bipyridine)
journal, January 2012
- Fuentes, Michelle J.; Bognanno, Richard J.; Dougherty, William G.
- Dalton Transactions, Vol. 41, Issue 40
Structural, electronic and acid/base properties of [Ru(tpy)(tpyOH)]2+ and [Ru(tpyOH)2]2+ (tpy=2,2′:6′,2″-terpyridine, tpyOH=4′-hydroxy-2,2′:6′,2″-terpyridine)
journal, January 2014
- Maghacut, Kent A.; Wood, Alessa B.; Boyko, Walter J.
- Polyhedron, Vol. 67
Ruthenium dihydroxybipyridine complexes are tumor activated prodrugs due to low pH and blue light induced ligand release
journal, January 2014
- Hufziger, Kyle T.; Thowfeik, Fathima Shazna; Charboneau, David J.
- Journal of Inorganic Biochemistry, Vol. 130
Stabilization and Destabilization of the Ru?CO Bond During the 2,2?-Bipyridin-6-onato (bpyO)-Localized Redox Reaction of [Ru(terpy)(bpyO)(CO)](PF6)
journal, January 2005
- Tomon, Takashi; Koizumi, Take-aki; Tanaka, Koji
- European Journal of Inorganic Chemistry, Vol. 2005, Issue 2
Water soluble phosphines VII. Palladium-catalyzed PC cross coupling reactions between primary or secondary phosphines and functional aryliodides — a novel synthetic route to water soluble phosphines
journal, September 1996
- Herd, Olive; Heßler, Antonella; Hingst, Martin
- Journal of Organometallic Chemistry, Vol. 522, Issue 1
Rhodium catalysed hydroformlyation of higher alkenes using amphiphilic ligands: part 2
journal, February 1997
- Buhling, Armin; Kamer, Paul C. J.; van Leeuwen, Piet W. N. M.
- Journal of Molecular Catalysis A: Chemical, Vol. 116, Issue 1-2
Hydroxy-substituted pyridine-like N-heterocycles: versatile ligands in organometallic catalysis
journal, January 2013
- Wang, Wan-Hui; Muckerman, James T.; Fujita, Etsuko
- New Journal of Chemistry, Vol. 37, Issue 7
Transfer hydrogenation of a variety of ketones catalyzed by rhodium complexes in aqueous solution and their application to asymmetric reduction using chiral Schiff base ligands
journal, March 2003
- Himeda, Yuichiro; Onozawa-Komatsuzaki, Nobuko; Sugihara, Hideki
- Journal of Molecular Catalysis A: Chemical, Vol. 195, Issue 1-2
Ruthenium(II)-Catalyzed Hydrogenation of Carbon Dioxide to Formic Acid. Theoretical Study of Real Catalyst, Ligand Effects, and Solvation Effects
journal, March 2005
- Ohnishi, Yu-ya; Matsunaga, Tadashi; Nakao, Yoshihide
- Journal of the American Chemical Society, Vol. 127, Issue 11
Simultaneous Tuning of Activity and Water Solubility of Complex Catalysts by Acid−Base Equilibrium of Ligands for Conversion of Carbon Dioxide
journal, January 2007
- Himeda, Yuichiro; Onozawa-Komatsuzaki, Nobuko; Sugihara, Hideki
- Organometallics, Vol. 26, Issue 3
Interconversion between Formic Acid and H2/CO2 using Rhodium and Ruthenium Catalysts for CO2 Fixation and H2 Storage
journal, January 2011
- Himeda, Yuichiro; Miyazawa, Satoru; Hirose, Takuji
- ChemSusChem, Vol. 4, Issue 4
pH-Dependent Catalytic Activity and Chemoselectivity in Transfer Hydrogenation Catalyzed by Iridium Complex with 4,4′-Dihydroxy-2,2′-bipyridine
journal, December 2008
- Himeda, Yuichiro; Onozawa-Komatsuzaki, Nobuko; Miyazawa, Satoru
- Chemistry - A European Journal, Vol. 14, Issue 35
Recyclable Catalyst for Conversion of Carbon Dioxide into Formate Attributable to an Oxyanion on the Catalyst Ligand
journal, September 2005
- Himeda, Yuichiro; Onozawa-Komatsuzaki, Nobuko; Sugihara, Hideki
- Journal of the American Chemical Society, Vol. 127, Issue 38
Positional Effects of Hydroxy Groups on Catalytic Activity of Proton-Responsive Half-Sandwich Cp*Iridium(III) Complexes
journal, November 2014
- Suna, Yuki; Ertem, Mehmed Z.; Wang, Wan-Hui
- Organometallics, Vol. 33, Issue 22
Second-coordination-sphere and electronic effects enhance iridium(iii)-catalyzed homogeneous hydrogenation of carbon dioxide in water near ambient temperature and pressure
journal, January 2012
- Wang, Wan-Hui; Hull, Jonathan F.; Muckerman, James T.
- Energy & Environmental Science, Vol. 5, Issue 7
Mechanistic Insight through Factors Controlling Effective Hydrogenation of CO 2 Catalyzed by Bioinspired Proton-Responsive Iridium(III) Complexes
journal, April 2013
- Wang, Wan-Hui; Muckerman, James T.; Fujita, Etsuko
- ACS Catalysis, Vol. 3, Issue 5
Hydrogenation of Carbon Dioxide Using Half-Sandwich Cobalt, Rhodium, and Iridium Complexes: DFT Study on the Mechanism and Metal Effect
journal, August 2014
- Hou, Cheng; Jiang, Jingxing; Zhang, Shidong
- ACS Catalysis, Vol. 4, Issue 9
Formic Acid Dehydrogenation with Bioinspired Iridium Complexes: A Kinetic Isotope Effect Study and Mechanistic Insight
journal, May 2014
- Wang, Wan-Hui; Xu, Shaoan; Manaka, Yuichi
- ChemSusChem, Vol. 7, Issue 7
Works referencing / citing this record:
Bio-mimetic self-assembled computationally designed catalysts of Mo and W for hydrogenation of CO 2 /dehydrogenation of HCOOH inspired by the active site of formate dehydrogenase
journal, January 2019
- Shiekh, Bilal Ahmad; Kaur, Damanjit; Kumar, Sourav
- Physical Chemistry Chemical Physics, Vol. 21, Issue 38
A computational study on ligand assisted vs. ligand participation mechanisms for CO 2 hydrogenation: importance of bifunctional ligand based catalysts
journal, January 2019
- Mandal, Shyama Charan; Rawat, Kuber Singh; Pathak, Biswarup
- Physical Chemistry Chemical Physics, Vol. 21, Issue 7
Efficient Hydrogen Storage and Production Using a Catalyst with an Imidazoline‐Based, Proton‐Responsive Ligand
journal, December 2016
- Wang, Lin; Onishi, Naoya; Murata, Kazuhisa
- ChemSusChem, Vol. 10, Issue 6
Utilization of a Fluorescent Dye Molecule as a Proton and Electron Reservoir
journal, February 2018
- Kieffer, Ian A.; Allen, Robert J.; Fernandez, Jordan L.
- Angewandte Chemie International Edition, Vol. 57, Issue 13
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journal, April 2019
- Fink, Cornel; Laurenczy, Gábor
- European Journal of Inorganic Chemistry, Vol. 2019, Issue 18
Enhanced Hydrogen Generation from Formic Acid by Half-Sandwich Iridium(III) Complexes with Metal/NH Bifunctionality: A Pronounced Switch from Transfer Hydrogenation
journal, August 2015
- Matsunami, Asuka; Kayaki, Yoshihito; Ikariya, Takao
- Chemistry - A European Journal, Vol. 21, Issue 39
Half‐sandwich ruthenium complexes with S chiff base ligands bearing a hydroxyl group: Preparation, characterization and catalytic activities
journal, November 2019
- Jia, Wei‐Guo; Wang, Zhi‐Bao; Zhi, Xue‐Ting
- Applied Organometallic Chemistry, Vol. 34, Issue 1
Cooperative iridium complex-catalyzed synthesis of quinoxalines, benzimidazoles and quinazolines in water
journal, January 2019
- Chakrabarti, Kaushik; Maji, Milan; Kundu, Sabuj
- Green Chemistry, Vol. 21, Issue 8
Synthesis of Carboxylic Acids and Esters from CO2
journal, December 2016
- Wu, Xiao-Feng; Zheng, Feng
- Topics in Current Chemistry, Vol. 375, Issue 1
Evaluating the impacts of amino acids in the second and outer coordination spheres of Rh-bis(diphosphine) complexes for CO 2 hydrogenation
journal, January 2019
- Walsh, Aaron P.; Laureanti, Joseph A.; Katipamula, Sriram
- Faraday Discussions, Vol. 215
Changing the Mechanism for CO 2 Hydrogenation Using Solvent-Dependent Thermodynamics
journal, October 2017
- Burgess, Samantha A.; Appel, Aaron M.; Linehan, John C.
- Angewandte Chemie International Edition, Vol. 56, Issue 47
Development of Effective Catalysts for Hydrogen Storage Technology Using Formic Acid
journal, September 2018
- Onishi, Naoya; Iguchi, Masayuki; Yang, Xinchun
- Advanced Energy Materials, Vol. 9, Issue 23
Biomimetic heterobimetallic architecture of Ni( ii ) and Fe( ii ) for CO 2 hydrogenation in aqueous media. A DFT study
journal, January 2019
- Shiekh, Bilal Ahmad
- RSC Advances, Vol. 9, Issue 57
CO 2 reduction: the quest for electrocatalytic materials
journal, January 2017
- Khezri, Bahareh; Fisher, Adrian C.; Pumera, Martin
- Journal of Materials Chemistry A, Vol. 5, Issue 18
Carbon Nitride as a Ligand: Selective Hydrogenation of Terminal Alkenes Using [(η 5 ‐C 5 Me 5 )IrCl(g‐C 3 N 4 ‐κ 2 N,N’ )]Cl
journal, April 2020
- Coulson, Ben; Lari, Leonardo; Isaacs, Mark
- Chemistry – A European Journal
Ruthenium complexes bearing an unsymmetrical pincer ligand with a 2-hydroxypyridylmethylene fragment: active catalysts for transfer hydrogenation of ketones
journal, January 2016
- Shi, Jing; Hu, Bowen; Gong, Dawei
- Dalton Transactions, Vol. 45, Issue 11
Protic NNN and NCN Pincer-Type Ruthenium Complexes Featuring (Trifluoromethyl)pyrazole Arms: Synthesis and Application to Catalytic Hydrogen Evolution from Formic Acid
journal, December 2017
- Nakahara, Yoshiko; Toda, Tatsuro; Matsunami, Asuka
- Chemistry - An Asian Journal, Vol. 13, Issue 1
Carbon Dioxide Hydrogenation and Formic Acid Dehydrogenation Catalyzed by Iridium Complexes Bearing Pyridyl-pyrazole Ligands: Effect of an Electron-donating Substituent on the Pyrazole Ring on the Catalytic Activity and Durability
journal, November 2018
- Onishi, Naoya; Kanega, Ryoichi; Fujita, Etsuko
- Advanced Synthesis & Catalysis, Vol. 361, Issue 2
Transfer hydrogenation of carbon dioxide and bicarbonate from glycerol under aqueous conditions
journal, January 2018
- Heltzel, Jacob M.; Finn, Matthew; Ainembabazi, Diana
- Chemical Communications, Vol. 54, Issue 48
Catalytic reactivity of an iridium complex with a proton responsive N-donor ligand in CO 2 hydrogenation to formate
journal, January 2018
- Gunasekar, Gunniya Hariyanandam; Yoon, Yeahsel; Baek, Il-hyun
- RSC Advances, Vol. 8, Issue 3
Iridium–NHC-based catalyst for ambient pressure storage and low temperature release of H 2 via the CO 2 /HCO 2 H couple
journal, January 2018
- Semwal, Shrivats; Kumar, Abhishek; Choudhury, Joyanta
- Catalysis Science & Technology, Vol. 8, Issue 23
Mixed-valence copper( i,ii ) complexes with 4-(1H-pyrazol-1-yl)-6-R-pyrimidines: from ionic structures to coordination polymers
journal, January 2016
- Vinogradova, Katerina A.; Krivopalov, Viktor P.; Nikolaenkova, Elena B.
- Dalton Transactions, Vol. 45, Issue 2
Base-free hydrogenation of CO 2 to formic acid in water with an iridium complex bearing a N,N′-diimine ligand
journal, January 2016
- Lu, Sheng-Mei; Wang, Zhijun; Li, Jun
- Green Chemistry, Vol. 18, Issue 16
Ruthenium NNN complexes with a 2-hydroxypyridylmethylene fragment for transfer hydrogenation of ketones: Ruthenium complexes for transfer hydrogenation of ketones
journal, October 2017
- Shi, Jing; Shang, Shu; Hu, Bowen
- Applied Organometallic Chemistry, Vol. 32, Issue 2
Iridium Complexes with Proton-Responsive Azole-Type Ligands as Effective Catalysts for CO 2 Hydrogenation
journal, November 2017
- Suna, Yuki; Himeda, Yuichiro; Fujita, Etsuko
- ChemSusChem, Vol. 10, Issue 22
Making a Splash in Homogeneous CO 2 Hydrogenation: Elucidating the Impact of Solvent on Catalytic Mechanisms
journal, July 2018
- Wiedner, Eric S.; Linehan, John C.
- Chemistry – A European Journal, Vol. 24, Issue 64
Utilization of a Fluorescent Dye Molecule as a Proton and Electron Reservoir
journal, February 2018
- Kieffer, Ian A.; Allen, Robert J.; Fernandez, Jordan L.
- Angewandte Chemie, Vol. 130, Issue 13
Synthesis of Carboxylic Acids and Esters from CO2
book, January 2016
- Wu, Xiao-Feng; Zheng, Feng
- Topics in Current Chemistry Collections
A DFT Study of CO2Hydrogenation on Faujasite-Supported Ir4Clusters: on the Role of Water for Selectivity Control
journal, June 2016
- Szyja, Bartłomiej M.; Smykowski, Daniel; Szczygieł, Jerzy
- ChemCatChem, Vol. 8, Issue 15
Synthesis, Reactivity, and Catalytic Transfer Hydrogenation Activity of Ruthenium Complexes Bearing NNN Tridentate Ligands: Influence of the Secondary Coordination Sphere
journal, July 2017
- Shi, Jing; Hu, Bowen; Chen, Xiangyang
- ACS Omega, Vol. 2, Issue 7