Magnetic and Mössbauer characterization of the magnetic properties of single-crystalline sub-micron sized Bi₂Fe₄O₉ cubes

Papaefthymiou, Georgia C.; Wong, Stanislaus S.; Viescas, Arthur J.; Le Breton, Jean-Marie; Chiron, Hubert; Juraszek, Jean; Park, Tae-Jin

doi:10.1016/j.cap.2014.11.008

Title: Magnetic and Mössbauer characterization of the magnetic properties of single-crystalline sub-micron sized Bi₂Fe₄O₉ cubes

Abstract

Magnetic and Mössbauer characterization of single crystalline, sub-micron sized Bi₂Fe₄O₉ cubes has been performed using SQUID magnetometry and transmission Mössbauer spectroscopy in the temperature range of 4.2 K ≤ T ≤ 300 K. A broad magnetic phase transition from the paramagnetic to the anti-ferromagnetic state is observed below 250 K, with the Mössbauer spectra exhibiting a superposition of magnetic, collapsed and quadrupolar spectra in the transition region of 200 K < T < 245 K. Room temperature Mössbauer spectra obtained in transmission geometry are identical to those recorded in back-scattering geometry via conversion electron Mössbauer spectroscopy, indicating the absence of strain at the surface. A small hysteresis loop is observed in SQUID measurements at 5 K, attributable to the presence of weak-ferromagnetism arising from the canting of Fe³⁺ ion sublattices in the antiferromagnetic matrix.

Authors:

Papaefthymiou, Georgia C. ^[1]; Wong, Stanislaus S. ^[2]; Viescas, Arthur J. ^[1]; Le Breton, Jean-Marie ^[3]; Chiron, Hubert ^[3]; Juraszek, Jean ^[3]; Park, Tae-Jin ^[4]

Villanova Univ., Villanova, PA (United States)
State Univ. of New York at Stony Brook, Stony Brook, NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)
Univ., et INSA de Rouen, Saint Etienne du Rouvray, Cedex (France)
State Univ. of New York at Stony Brook, Stony Brook, NY (United States)

Publication Date:: Tue Nov 25 00:00:00 EST 2014

Research Org.:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1182526

Alternate Identifier(s):: OSTI ID: 1251709

Report Number(s):: BNL-107583-2015-JA
Journal ID: ISSN 1567-1739; R&D Project: PM037; KC0201030

Grant/Contract Number:: SC00112704; AC02-98CH10886

Resource Type:: Accepted Manuscript

Journal Name:: Current Applied Physics

Additional Journal Information:: Journal Volume: 15; Journal Issue: 3; Journal ID: ISSN 1567-1739

Publisher:: Korean Physical Society

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; Bi₂Fe₄O₉; Mössbauer

Citation Formats


                    Papaefthymiou, Georgia C., Wong, Stanislaus S., Viescas, Arthur J., Le Breton, Jean-Marie, Chiron, Hubert, Juraszek, Jean, and Park, Tae-Jin. Magnetic and Mössbauer characterization of the magnetic properties of single-crystalline sub-micron sized Bi₂Fe₄O₉ cubes.  United States: N. p., 2014. 
Web.  doi:10.1016/j.cap.2014.11.008.

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                    Papaefthymiou, Georgia C., Wong, Stanislaus S., Viescas, Arthur J., Le Breton, Jean-Marie, Chiron, Hubert, Juraszek, Jean, & Park, Tae-Jin. Magnetic and Mössbauer characterization of the magnetic properties of single-crystalline sub-micron sized Bi₂Fe₄O₉ cubes.  United States.  https://doi.org/10.1016/j.cap.2014.11.008

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                    Papaefthymiou, Georgia C., Wong, Stanislaus S., Viescas, Arthur J., Le Breton, Jean-Marie, Chiron, Hubert, Juraszek, Jean, and Park, Tae-Jin. Tue .  
"Magnetic and Mössbauer characterization of the magnetic properties of single-crystalline sub-micron sized Bi₂Fe₄O₉ cubes".  United States.  https://doi.org/10.1016/j.cap.2014.11.008.  https://www.osti.gov/servlets/purl/1182526.

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@article{osti_1182526,

  title        = {Magnetic and Mössbauer characterization of the magnetic properties of single-crystalline sub-micron sized Bi₂Fe₄O₉ cubes},

  author       = {Papaefthymiou, Georgia C. and Wong, Stanislaus S. and Viescas, Arthur J. and Le Breton, Jean-Marie and Chiron, Hubert and Juraszek, Jean and Park, Tae-Jin},

  abstractNote = {Magnetic and Mössbauer characterization of single crystalline, sub-micron sized Bi₂Fe₄O₉ cubes has been performed using SQUID magnetometry and transmission Mössbauer spectroscopy in the temperature range of 4.2 K ≤ T ≤ 300 K. A broad magnetic phase transition from the paramagnetic to the anti-ferromagnetic state is observed below 250 K, with the Mössbauer spectra exhibiting a superposition of magnetic, collapsed and quadrupolar spectra in the transition region of 200 K < T < 245 K. Room temperature Mössbauer spectra obtained in transmission geometry are identical to those recorded in back-scattering geometry via conversion electron Mössbauer spectroscopy, indicating the absence of strain at the surface. A small hysteresis loop is observed in SQUID measurements at 5 K, attributable to the presence of weak-ferromagnetism arising from the canting of Fe³⁺ ion sublattices in the antiferromagnetic matrix.},

  doi          = {10.1016/j.cap.2014.11.008},

  journal      = {Current Applied Physics},

  number       = 3,

  volume       = 15,

  place        = {United States},

  year         = {Tue Nov 25 00:00:00 EST 2014},

  month        = {Tue Nov 25 00:00:00 EST 2014}

}

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Works referencing / citing this record:

Size, shape, and orientation dependence of the field-induced behavior in ferroelectric nanoparticles
journal, April 2019

Zhu, Daopei; Mangeri, John; Wang, Ruolin
Journal of Applied Physics, Vol. 125, Issue 13
DOI: 10.1063/1.5088864

Metastable vortex-like polarization textures in ferroelectric nanoparticles of different shapes and sizes
journal, August 2018

Pitike, Krishna Chaitanya; Mangeri, John; Whitelock, Hope
Journal of Applied Physics, Vol. 124, Issue 6
DOI: 10.1063/1.5037163

Electromechanical control of polarization vortex ordering in an interacting ferroelectric-dielectric composite dimer
journal, August 2018

Mangeri, John; Alpay, S. Pamir; Nakhmanson, Serge
Applied Physics Letters, Vol. 113, Issue 9
DOI: 10.1063/1.5046080

Electromechanical control of polarization vortex ordering in an interacting ferroelectric-dielectric composite dimer
text, January 2019

Mangeri, John; Alpay, S. Pamir; Nakhmanson, Serge
arXiv
DOI: 10.48550/arxiv.1901.11433

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Title: Magnetic and Mössbauer characterization of the magnetic properties of single-crystalline sub-micron sized Bi₂Fe₄O₉ cubes

Abstract

Citation Formats

Synthesis, structure, and magnetic properties of the layered bismuth transition metal oxide solid solution Bi2Fe4−xGaxO9 journal, July 1992

Structural and Magnetic Studies of Bi2Fe4-xAlxO9 journal, January 1995

Synthesis and characterization of submicron single-crystalline Bi2Fe4O9 cubes journal, January 2005

Hydrothermal Synthesis and Characterization of Bi 2 Fe 4 O 9 Nanoparticles journal, May 2004

Preparation of Ag2S Nanocrystals of Predictable Shape and Size journal, October 2004

Substantial magnetoelectric coupling near room temperature in Bi2Fe4O9 journal, March 2008

Catalytic Properties of the Fe2O3–Bi2O3 System in Ammonia Oxidation to Nitrogen Oxides journal, January 2002

A setup combining magneto-optical Kerr effect and conversion electron Mössbauer spectrometry for analysis of the near-surface magnetic properties of thin films journal, April 2009

Synthesis and magnetic property of submicron Bi2Fe4O9 journal, September 2006

Detection of para–antiferromagnetic transition in Bi2Fe4O9 powders by means of microwave absorption measurements journal, December 2013

Size effect on magnetic and ferroelectric properties in Bi2Fe4O9 multiferroic ceramics journal, November 2009

Size-Dependent Magnetic Properties of Single-Crystalline Multiferroic BiFeO 3 Nanoparticles journal, March 2007

The magnetic structure of Bi 2 Fe 4 O 9 – analysis of neutron diffraction measurements journal, September 1978

3.1 GeV-xenon ion latent tracks in Bi2Fe4O9: Mössbauer and electron microscopy studies journal, October 1988

Effect of antiferromagnetic order on the dielectric properties of Bi2Fe4O9 journal, March 2010

Effect of chromium substitution on structure and magnetic properties of Bi2Fe4O9 journal, October 2010

Phonon and magnon scattering of antiferromagnetic Bi 2 Fe 4 O 9 journal, January 2010

Size, shape, and orientation dependence of the field-induced behavior in ferroelectric nanoparticles journal, April 2019

Metastable vortex-like polarization textures in ferroelectric nanoparticles of different shapes and sizes journal, August 2018

Electromechanical control of polarization vortex ordering in an interacting ferroelectric-dielectric composite dimer journal, August 2018

Electromechanical control of polarization vortex ordering in an interacting ferroelectric-dielectric composite dimer text, January 2019

Synthesis, structure, and magnetic properties of the layered bismuth transition metal oxide solid solution Bi2Fe4−xGaxO9
journal, July 1992

Structural and Magnetic Studies of Bi2Fe4-xAlxO9
journal, January 1995

Synthesis and characterization of submicron single-crystalline Bi2Fe4O9 cubes
journal, January 2005

Hydrothermal Synthesis and Characterization of Bi ₂ Fe ₄ O ₉ Nanoparticles
journal, May 2004

Preparation of Ag2S Nanocrystals of Predictable Shape and Size
journal, October 2004

Substantial magnetoelectric coupling near room temperature in Bi2Fe4O9
journal, March 2008

Catalytic Properties of the Fe₂O₃–Bi₂O₃ System in Ammonia Oxidation to Nitrogen Oxides
journal, January 2002

A setup combining magneto-optical Kerr effect and conversion electron Mössbauer spectrometry for analysis of the near-surface magnetic properties of thin films
journal, April 2009

Synthesis and magnetic property of submicron Bi2Fe4O9
journal, September 2006

Detection of para–antiferromagnetic transition in Bi2Fe4O9 powders by means of microwave absorption measurements
journal, December 2013

Size effect on magnetic and ferroelectric properties in Bi2Fe4O9 multiferroic ceramics
journal, November 2009

Size-Dependent Magnetic Properties of Single-Crystalline Multiferroic BiFeO ₃ Nanoparticles
journal, March 2007

The magnetic structure of Bi ₂ Fe ₄ O ₉ – analysis of neutron diffraction measurements
journal, September 1978

3.1 GeV-xenon ion latent tracks in Bi2Fe4O9: Mössbauer and electron microscopy studies
journal, October 1988

Effect of antiferromagnetic order on the dielectric properties of Bi2Fe4O9
journal, March 2010

Effect of chromium substitution on structure and magnetic properties of Bi2Fe4O9
journal, October 2010

Phonon and magnon scattering of antiferromagnetic ${Bi}_{2} {Fe}_{4} O_{9}$
journal, January 2010

Size, shape, and orientation dependence of the field-induced behavior in ferroelectric nanoparticles
journal, April 2019

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