Alternating magnetic anisotropy of Li2(Li1–xTx)N (T = Mn, Fe, Co, and Ni)
Abstract
Substantial amounts of the transition metals Mn, Fe, Co, and Ni can be substituted for Li in single crystalline Li2(Li1–xTx)N. Isothermal and temperature-dependent magnetization measurements reveal local magnetic moments with magnitudes significantly exceeding the spin-only value. The additional contributions stem from unquenched orbital moments that lead to rare-earth-like behavior of the magnetic properties. Accordingly, extremely large magnetic anisotropies have been found. Most notably, the magnetic anisotropy alternates as easy plane→easy axis→easy plane→easy axis when progressing from T = Mn → Fe → Co → Ni. This behavior can be understood based on a perturbation approach in an analytical, single-ion model. As a result, the calculated magnetic anisotropies show surprisingly good agreement with the experiment and capture the basic features observed for the different transition metals.
- Authors:
-
- Iowa State Univ., Ames, IA (United States)
- Publication Date:
- Research Org.:
- Ames Laboratory (AMES), Ames, IA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1227306
- Alternate Identifier(s):
- OSTI ID: 1179303
- Report Number(s):
- IS-J-8670
Journal ID: ISSN 1098-0121; PRBMDO
- Grant/Contract Number:
- AC02-07CH11358
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review. B, Condensed Matter and Materials Physics
- Additional Journal Information:
- Journal Volume: 91; Journal Issue: 18; Journal ID: ISSN 1098-0121
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Jesche, A., Ke, L., Jacobs, J. L., Harmon, B., Houk, R. S., and Canfield, P. C. Alternating magnetic anisotropy of Li2(Li1–xTx)N (T = Mn, Fe, Co, and Ni). United States: N. p., 2015.
Web. doi:10.1103/PhysRevB.91.180403.
Jesche, A., Ke, L., Jacobs, J. L., Harmon, B., Houk, R. S., & Canfield, P. C. Alternating magnetic anisotropy of Li2(Li1–xTx)N (T = Mn, Fe, Co, and Ni). United States. https://doi.org/10.1103/PhysRevB.91.180403
Jesche, A., Ke, L., Jacobs, J. L., Harmon, B., Houk, R. S., and Canfield, P. C. Mon .
"Alternating magnetic anisotropy of Li2(Li1–xTx)N (T = Mn, Fe, Co, and Ni)". United States. https://doi.org/10.1103/PhysRevB.91.180403. https://www.osti.gov/servlets/purl/1227306.
@article{osti_1227306,
title = {Alternating magnetic anisotropy of Li2(Li1–xTx)N (T = Mn, Fe, Co, and Ni)},
author = {Jesche, A. and Ke, L. and Jacobs, J. L. and Harmon, B. and Houk, R. S. and Canfield, P. C.},
abstractNote = {Substantial amounts of the transition metals Mn, Fe, Co, and Ni can be substituted for Li in single crystalline Li2(Li1–xTx)N. Isothermal and temperature-dependent magnetization measurements reveal local magnetic moments with magnitudes significantly exceeding the spin-only value. The additional contributions stem from unquenched orbital moments that lead to rare-earth-like behavior of the magnetic properties. Accordingly, extremely large magnetic anisotropies have been found. Most notably, the magnetic anisotropy alternates as easy plane→easy axis→easy plane→easy axis when progressing from T = Mn → Fe → Co → Ni. This behavior can be understood based on a perturbation approach in an analytical, single-ion model. As a result, the calculated magnetic anisotropies show surprisingly good agreement with the experiment and capture the basic features observed for the different transition metals.},
doi = {10.1103/PhysRevB.91.180403},
journal = {Physical Review. B, Condensed Matter and Materials Physics},
number = 18,
volume = 91,
place = {United States},
year = {Mon May 11 00:00:00 EDT 2015},
month = {Mon May 11 00:00:00 EDT 2015}
}
Web of Science
Works referenced in this record:
Giant magnetic anisotropy and tunnelling of the magnetization in Li2(Li1−xFex)N
journal, February 2014
- Jesche, A.; McCallum, R. W.; Thimmaiah, S.
- Nature Communications, Vol. 5, Issue 1
Metallamide und Metallnitride, 21. Mitteilung. Über Mischkristalle der Zusammensetzung (Li, Co) 3 N, (Li, Ni) 3 N und (Li, Cu) 3 N
journal, September 1949
- Sachsze, Werner; Juza, Robert
- Zeitschrift für anorganische Chemie, Vol. 259, Issue 5-6
Ternary lithium nitridocuprates, Li3−x−yCuxN: crystal growth, bulk synthesis, structure and magnetic properties
journal, November 2001
- Gordon, Alexandra G.; Gregory, Duncan H.; Blake, Alexander J.
- International Journal of Inorganic Materials, Vol. 3, Issue 7
Layered ternary transition metal nitrides; synthesis, structure and physical properties
journal, April 2001
- Gregory, Duncan H.; O’Meara, Paul M.; Gordon, Alexandra G.
- Journal of Alloys and Compounds, Vol. 317-318
Preparation, Crystallographic, Spectroscopic and Magnetic Characterization of Low-Valency Nitridometalates Li2[(Li1-xMx)N] withM = Cu, Ni
journal, September 2003
- Niewa, R.; Huang, Z. -L.; Schnelle, W.
- Zeitschrift für anorganische und allgemeine Chemie, Vol. 629, Issue 10
Mn and Fe K-edge XAS Spectra of Manganese and Iron Nitrido Compounds
journal, April 2003
- Niewa, Rainer; Hu, Zhiwei; Kniep, Rüdiger
- European Journal of Inorganic Chemistry, Vol. 2003, Issue 8
Magnetic and electronic properties of lithium nitridometalates [()](=,,)
journal, May 2004
- Schnelle, W.; Niewa, R.; Wagner, F. R.
- Journal of Magnetism and Magnetic Materials, Vol. 272-276
Evolution of structure, transport properties and magnetism in ternary lithium nitridometalates Li 3−x−y MxN, M = Co, Ni, Cu
journal, January 2004
- Stoeva, Zlatka; Gomez, Ruben; Gregory, Duncan H.
- Dalton Trans., Issue 19
Spin-glass state in hexagonal Li2.5Co0.5N
journal, January 2009
- Liu, Da-Liang; Du, Fei; Wei, Ying-Jin
- Materials Letters, Vol. 63, Issue 1
Effect of Cobalt Substitution on Li 3–2 x Co x N Local Structure: A XAS Investigation
journal, May 2014
- Muller-Bouvet, Diane; Pereira-Ramos, Jean-Pierre; Bach, Stéphane
- Inorganic Chemistry, Vol. 53, Issue 12
Electronic structure and magnetism of 3d metal substituted Li3N
journal, May 2004
- Novák, P.; Wagner, F. R.
- Journal of Magnetism and Magnetic Materials, Vol. 272-276
Effect of transition metal (M = Co, Ni, Cu) substitution on electronic structure and vacancy formation of Li 3 N
journal, January 2011
- Wu, Shunnian; Dong, Zhili; Wu, Ping
- J. Mater. Chem., Vol. 21, Issue 1
Colossal anisotropy of the magnetic properties of doped lithium nitrodometalates
journal, September 2014
- Antropov, V. P.; Antonov, V. N.
- Physical Review B, Vol. 90, Issue 9
Single crystal growth from light, volatile and reactive materials using lithium and calcium flux
journal, April 2014
- Jesche, A.; Canfield, P. C.
- Philosophical Magazine, Vol. 94, Issue 21
High-temperature solution growth of intermetallic single crystals and quasicrystals
journal, May 2001
- Canfield, Paul C.; Fisher, Ian R.
- Journal of Crystal Growth, Vol. 225, Issue 2-4
Atomic parameters for the interpretation of ESR and diamagnetic susceptibility data
journal, March 1967
- Hurd, C. M.; Coodin, P.
- Journal of Physics and Chemistry of Solids, Vol. 28, Issue 3
β-Ca 3 N 2 , a Metastable Nitride in the System Ca-N
journal, March 2009
- Höhn, Peter; Hoffmann, Stefan; Hunger, Jens
- Chemistry - A European Journal, Vol. 15, Issue 14
Large Orbital Moments and Internal Magnetic Fields in Lithium Nitridoferrate(I)
journal, May 2002
- Klatyk, J.; Schnelle, W.; Wagner, F. R.
- Physical Review Letters, Vol. 88, Issue 20
Electronic structure of lithium nitridoferrate: Effects of correlation and spin-orbit coupling
journal, November 2002
- Novák, P.; Wagner, F. R.
- Physical Review B, Vol. 66, Issue 18
Stability of polyatomic molecules in degenerate electronic states - I—Orbital degeneracy
journal, July 1937
- Jahn, H. A.; Teller, E.
- Proceedings of the Royal Society of London. Series A - Mathematical and Physical Sciences, Vol. 161, Issue 905, p. 220-235
Reaching the magnetic anisotropy limit of a 3d metal atom
journal, May 2014
- Rau, I. G.; Baumann, S.; Rusponi, S.
- Science, Vol. 344, Issue 6187
Stable Two-Coordinate, Open-Shell (d 1 –d 9 ) Transition Metal Complexes
journal, March 2012
- Power, Philip P.
- Chemical Reviews, Vol. 112, Issue 6
Works referencing / citing this record:
Impact of fluoride for hydroxide substitution on the magnetic properties of a Co-based single-ion magnet imbedded in the barium apatite crystal lattice
journal, January 2019
- Zykin, Mikhail A.; Eliseev, Artem A.; Pogosova, Mariam A.
- CrystEngComm, Vol. 21, Issue 7
Manifestation of strong magnetic and giant Raman anisotropy in single crystals of Cu for H substituted strontium hydroxyapatite
journal, January 2019
- Kazin, Pavel E.; Zykin, Mikhail A.; Jesche, Anton
- CrystEngComm, Vol. 21, Issue 33
Multiple slow relaxation of magnetization in Dy 3+ confined in the crystal matrix of rare-earth-calcium silicates with the apatite structure
journal, January 2020
- Kazin, Pavel E.; Zykin, Mikhail A.; Trusov, Lev A.
- Dalton Transactions, Vol. 49, Issue 6
New materials physics
journal, November 2019
- Canfield, Paul C.
- Reports on Progress in Physics, Vol. 83, Issue 1