DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: In Situ ATR and DRIFTS Studies of the Nature of Adsorbed CO 2 on Tetraethylenepentamine Films

Authors:
 [1];  [1];  [1]
  1. Department of Chemical and Biomolecular Engineering and §Department of Polymer Science, FirstEnergy Advance Energy Research Center, The University of Akron, Akron, Ohio 44325, United States
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1158723
Grant/Contract Number:  
FE0001780
Resource Type:
Published Article
Journal Name:
ACS Applied Materials and Interfaces
Additional Journal Information:
Journal Name: ACS Applied Materials and Interfaces Journal Volume: 6 Journal Issue: 16; Journal ID: ISSN 1944-8244
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English

Citation Formats

Wilfong, Walter Christopher, Srikanth, Chakravartula S., and Chuang, Steven S. C. In Situ ATR and DRIFTS Studies of the Nature of Adsorbed CO 2 on Tetraethylenepentamine Films. United States: N. p., 2014. Web. doi:10.1021/am5031006.
Wilfong, Walter Christopher, Srikanth, Chakravartula S., & Chuang, Steven S. C. In Situ ATR and DRIFTS Studies of the Nature of Adsorbed CO 2 on Tetraethylenepentamine Films. United States. https://doi.org/10.1021/am5031006
Wilfong, Walter Christopher, Srikanth, Chakravartula S., and Chuang, Steven S. C. Mon . "In Situ ATR and DRIFTS Studies of the Nature of Adsorbed CO 2 on Tetraethylenepentamine Films". United States. https://doi.org/10.1021/am5031006.
@article{osti_1158723,
title = {In Situ ATR and DRIFTS Studies of the Nature of Adsorbed CO 2 on Tetraethylenepentamine Films},
author = {Wilfong, Walter Christopher and Srikanth, Chakravartula S. and Chuang, Steven S. C.},
abstractNote = {},
doi = {10.1021/am5031006},
journal = {ACS Applied Materials and Interfaces},
number = 16,
volume = 6,
place = {United States},
year = {Mon Aug 04 00:00:00 EDT 2014},
month = {Mon Aug 04 00:00:00 EDT 2014}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1021/am5031006

Citation Metrics:
Cited by: 137 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Study of Carbon Dioxide Adsorption on Mesoporous Aminopropylsilane-Functionalized Silica and Titania Combining Microcalorimetry and in Situ Infrared Spectroscopy
journal, December 2009

  • Knöfel, Christina; Martin, Céline; Hornebecq, Virginie
  • The Journal of Physical Chemistry C, Vol. 113, Issue 52
  • DOI: 10.1021/jp907054h

Amino Acid-Functionalized Ionic Liquid Solid Sorbents for Post-Combustion Carbon Capture
journal, August 2013

  • Wang, Xianfeng; Akhmedov, Novruz G.; Duan, Yuhua
  • ACS Applied Materials & Interfaces, Vol. 5, Issue 17
  • DOI: 10.1021/am402306s

Adsorption of CO2 onto amine-grafted mesoporous silicas
journal, November 2009

  • Chang, Fang-Yi; Chao, Kuei-Jung; Cheng, Hsu-Hsiang
  • Separation and Purification Technology, Vol. 70, Issue 1
  • DOI: 10.1016/j.seppur.2009.08.016

Vibrational and Rotational Spectra
book, January 1975


Investigation of Porous Silica Supported Mixed-Amine Sorbents for Post-Combustion CO 2 Capture
journal, April 2012

  • Fauth, D. J.; Gray, M. L.; Pennline, H. W.
  • Energy & Fuels, Vol. 26, Issue 4
  • DOI: 10.1021/ef201578a

The Infrared Spectra of Secondary Amines and Their Salts
journal, December 1956

  • Heacock, R. A.; Marion, Léo
  • Canadian Journal of Chemistry, Vol. 34, Issue 12
  • DOI: 10.1139/v56-231

Fundamental Investigation of the Factors Controlling the CO 2 Permeability of Facilitated Transport Membranes Containing Amine-Functionalized Task-Specific Ionic Liquids
journal, January 2014

  • Kasahara, Shohei; Kamio, Eiji; Otani, Akihito
  • Industrial & Engineering Chemistry Research, Vol. 53, Issue 6
  • DOI: 10.1021/ie403116t

In Situ Infrared Study of the Effect of Amine Density on the Nature of Adsorbed CO 2 on Amine-Functionalized Solid Sorbents
journal, June 2014

  • Tumuluri, Uma; Isenberg, Mathew; Tan, Chung-Sung
  • Langmuir, Vol. 30, Issue 25
  • DOI: 10.1021/la501284y

Infrared Study of CO 2 Sorption over “Molecular Basket” Sorbent Consisting of Polyethylenimine-Modified Mesoporous Molecular Sieve
journal, April 2009

  • Wang, Xiaoxing; Schwartz, Viviane; Clark, Jason C.
  • The Journal of Physical Chemistry C, Vol. 113, Issue 17
  • DOI: 10.1021/jp809946y

Carbon dioxide and supramolecular chemistry
journal, January 2005

  • Rudkevich, Dmitry M.; Xu, Heng
  • Chemical Communications, Issue 21
  • DOI: 10.1039/b500318k

Performance and Kinetics of a Solid Amine Sorbent for Carbon Dioxide Removal
journal, October 2011

  • Monazam, Esmail R.; Shadle, Lawrence J.; Siriwardane, Ranjani
  • Industrial & Engineering Chemistry Research, Vol. 50, Issue 19
  • DOI: 10.1021/ie201214q

Aminosilane-Grafted Polymer/Silica Hollow Fiber Adsorbents for CO 2 Capture from Flue Gas
journal, March 2013

  • Rezaei, Fateme; Lively, Ryan P.; Labreche, Ying
  • ACS Applied Materials & Interfaces, Vol. 5, Issue 9
  • DOI: 10.1021/am400636c

Structural Changes of Silica Mesocellular Foam Supported Amine-Functionalized CO 2 Adsorbents Upon Exposure to Steam
journal, October 2010

  • Li, Wen; Bollini, Praveen; Didas, Stephanie A.
  • ACS Applied Materials & Interfaces, Vol. 2, Issue 11
  • DOI: 10.1021/am100786z

Carbon Dioxide Capture by an Amine Functionalized Ionic Liquid: Fundamental Differences of Surface and Bulk Behavior
journal, December 2013

  • Niedermaier, Inga; Bahlmann, Matthias; Papp, Christian
  • Journal of the American Chemical Society, Vol. 136, Issue 1
  • DOI: 10.1021/ja410745a

Polyethylenimine-Magadiite Layered Silicate Sorbent for CO 2 Capture
journal, January 2014

  • Vieira, Rômulo B.; Pastore, Heloise O.
  • Environmental Science & Technology, Vol. 48, Issue 4
  • DOI: 10.1021/es404501e

13C NMR as a method species determination in CO2 absorbent systems
journal, August 2013

  • Ciftja, Arlinda F.; Hartono, Ardi; Svendsen, Hallvard F.
  • International Journal of Greenhouse Gas Control, Vol. 16
  • DOI: 10.1016/j.ijggc.2013.04.006

Temperature-Induced Uptake of CO 2 and Formation of Carbamates in Mesocaged Silica Modified with n -Propylamines
journal, June 2010

  • Bacsik, Zoltán; Atluri, Rambabu; Garcia-Bennett, Alfonso E.
  • Langmuir, Vol. 26, Issue 12
  • DOI: 10.1021/la1001495

Mass-transfer efficiency of a spray column for CO2 capture by MEA
journal, February 2009


The Nature of Adsorbed CO 2 and Amine Sites on the Immobilized Amine Sorbents Regenerated by Industrial Boiler Steam
journal, February 2013

  • Isenberg, Mathew; Chuang, Steven S. C.
  • Industrial & Engineering Chemistry Research, Vol. 52, Issue 35
  • DOI: 10.1021/ie401892u

Probing the Adsorption/Desorption of CO 2 on Amine Sorbents by Transient Infrared Studies of Adsorbed CO 2 and C 6 H 6
journal, March 2014

  • Wilfong, Walter Christopher; Chuang, Steven S. C.
  • Industrial & Engineering Chemistry Research, Vol. 53, Issue 11
  • DOI: 10.1021/ie404403q

Transport, Zwitterions, and the Role of Water for CO 2 Adsorption in Mesoporous Silica-Supported Amine Sorbents
journal, December 2013

  • Mebane, David S.; Kress, Joel D.; Storlie, Curtis B.
  • The Journal of Physical Chemistry C, Vol. 117, Issue 50
  • DOI: 10.1021/jp4076417

CO2 capture on polyethylenimine-impregnated hydrophobic mesoporous silica: Experimental and kinetic modeling
journal, September 2011


Polyethylenimine-Impregnated Resin for High CO 2 Adsorption: An Efficient Adsorbent for CO 2 Capture from Simulated Flue Gas and Ambient Air
journal, July 2013

  • Chen, Zhenhe; Deng, Shubo; Wei, Haoran
  • ACS Applied Materials & Interfaces, Vol. 5, Issue 15
  • DOI: 10.1021/am400661b

Membranes comprising of alkanolamines incorporated into poly(vinyl alcohol) matrix for CO2/N2 separation
journal, October 2007


Fourier Transform Infrared Spectrometry
book, June 2007


CO2 Capture in Amine-Based Aqueous Solution: Role of the Gas-Solution Interface
journal, June 2011

  • Lewis, Tanza; Faubel, Manfred; Winter, Bernd
  • Angewandte Chemie International Edition, Vol. 50, Issue 43
  • DOI: 10.1002/anie.201101250

Primary, secondary, and tertiary amines for CO2 capture: Designing for mesoporous CO2 adsorbents
journal, September 2011

  • Ko, Young Gun; Shin, Seung Su; Choi, Ung Su
  • Journal of Colloid and Interface Science, Vol. 361, Issue 2
  • DOI: 10.1016/j.jcis.2011.03.045

Tetraethylenepentamine-Modified Silica Nanotubes for Low-Temperature CO 2 Capture
journal, November 2013

  • Yao, Manli; Dong, Yanyan; Hu, Xin
  • Energy & Fuels, Vol. 27, Issue 12
  • DOI: 10.1021/ef401988x

CO 2 Desorption Kinetics for Immobilized Polyethylenimine (PEI)
journal, November 2013

  • Monazam, Esmail R.; Spenik, James; Shadle, Lawrence J.
  • Energy & Fuels, Vol. 28, Issue 1
  • DOI: 10.1021/ef401879z

CO 2 Uptake and Adsorption Kinetics of Pore-Expanded SBA-15 Double-Functionalized with Amino Groups
journal, November 2013

  • Sanz, Raúl; Calleja, Guillermo; Arencibia, Amaya
  • Energy & Fuels, Vol. 27, Issue 12
  • DOI: 10.1021/ef4015229

Effect of the Pore Length on CO 2 Adsorption over Amine-Modified Mesoporous Silicas
journal, September 2011

  • Heydari-Gorji, Aliakbar; Yang, Yong; Sayari, Abdelhamid
  • Energy & Fuels, Vol. 25, Issue 9
  • DOI: 10.1021/ef200765f

Enhancement factor and kinetics of CO2 capture by MEA-methanol hybrid solvents
journal, February 2009


Amine-Tethered Adsorbents Based on Three-Dimensional Macroporous Silica for CO 2 Capture from Simulated Flue Gas and Air
journal, March 2014

  • Liu, Fa-Qian; Wang, Lei; Huang, Zhao-Ge
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 6
  • DOI: 10.1021/am500089g

Investigation of Thermal Stability and Continuous CO 2 Capture from Flue Gases with Supported Amine Sorbent
journal, January 2013

  • Zhao, Wenying; Zhang, Zhi; Li, Zhenshan
  • Industrial & Engineering Chemistry Research, Vol. 52, Issue 5
  • DOI: 10.1021/ie303254m

The reaction of CO2 with ethanolamines
journal, January 1979


Mechanisms and Kinetics for Sorption of CO 2 on Bicontinuous Mesoporous Silica Modified with n -Propylamine
journal, September 2011

  • Bacsik, Zoltán; Ahlsten, Nanna; Ziadi, Asraa
  • Langmuir, Vol. 27, Issue 17
  • DOI: 10.1021/la202033p

Modeling adsorption of CO2 on amine-functionalized mesoporous silica. 2: Kinetics and breakthrough curves
journal, July 2010

  • Serna-Guerrero, Rodrigo; Sayari, Abdelhamid
  • Chemical Engineering Journal, Vol. 161, Issue 1-2
  • DOI: 10.1016/j.cej.2010.04.042

Reaction mechanism and kinetics of aqueous solutions of 2-amino-2-methyl-1-propanol and carbon dioxide
journal, August 1990

  • Alper, Erdogan
  • Industrial & Engineering Chemistry Research, Vol. 29, Issue 8
  • DOI: 10.1021/ie00104a023

Tetraethylenepentamine-Modified Siliceous Mesocellular Foam (MCF) for CO 2 Capture
journal, February 2013

  • Feng, Xingxing; Hu, Gengshen; Hu, Xin
  • Industrial & Engineering Chemistry Research, Vol. 52, Issue 11
  • DOI: 10.1021/ie301946p

In Situ Infrared Study of the Role of PEG in Stabilizing Silica-Supported Amines for CO2 Capture
journal, August 2010


Carbon Dioxide Adsorption on Amine-Impregnated Mesoporous SBA-15 Sorbents: Experimental and Kinetics Study
journal, May 2013

  • Zhao, An; Samanta, Arunkumar; Sarkar, Partha
  • Industrial & Engineering Chemistry Research, Vol. 52, Issue 19
  • DOI: 10.1021/ie3030533

Modeling of CO2 capture by aqueous monoethanolamine
journal, July 2003


On the limits of facilitated diffusion
journal, May 1989


Periodic mesoporous organosilicas functionalized with a wide variety of amines for CO2 adsorption
journal, January 2013

  • De Canck, Els; Ascoop, Isabelle; Sayari, Abdelhamid
  • Physical Chemistry Chemical Physics, Vol. 15, Issue 24
  • DOI: 10.1039/c3cp50393c

Pilot plant experimental studies of post combustion CO2 capture by reactive absorption with MEA and new solvents
journal, February 2009


Amine-Functionalized Metal Organic Framework as a Highly Selective Adsorbent for CO 2 over CO
journal, September 2012

  • Wang, Xingrui; Li, Huiquan; Hou, Xin-Juan
  • The Journal of Physical Chemistry C, Vol. 116, Issue 37
  • DOI: 10.1021/jp3052938

Infrared Study of Strongly and Weakly Adsorbed CO 2 on Fresh and Oxidatively Degraded Amine Sorbents
journal, April 2013

  • Srikanth, Chakravartula S.; Chuang, Steven S. C.
  • The Journal of Physical Chemistry C, Vol. 117, Issue 18
  • DOI: 10.1021/jp311232f

CO2 capture from power plants
journal, April 2007

  • Abu-Zahra, Mohammad R. M.; Schneiders, Léon H. J.; Niederer, John P. M.
  • International Journal of Greenhouse Gas Control, Vol. 1, Issue 1
  • DOI: 10.1016/S1750-5836(06)00007-7

Gas-phase basicities of amines. Hydrogen bonding in proton-bound amine dimers and proton-induced cyclization of .alpha., .omega.-diamines
journal, May 1973

  • Yamdagni, R.; Kebarle, P.
  • Journal of the American Chemical Society, Vol. 95, Issue 11
  • DOI: 10.1021/ja00792a010

Polyethylenimine-impregnated siliceous mesocellular foam particles as high capacity CO2 adsorbents
journal, January 2012

  • Zhao, Junqi; Simeon, Fritz; Wang, Yujun
  • RSC Advances, Vol. 2, Issue 16
  • DOI: 10.1039/c2ra20149f

Kinetics Studies of CO 2 Adsorption/Desorption on Amine-Functionalized Multiwalled Carbon Nanotubes
journal, July 2014

  • Liu, Qing; Shi, Junjie; Zheng, Shudong
  • Industrial & Engineering Chemistry Research, Vol. 53, Issue 29
  • DOI: 10.1021/ie502009n

Influence of Silica Types on Synthesis and Performance of Amine–Silica Hybrid Materials Used for CO 2 Capture
journal, January 2014

  • Li, Kai-Min; Jiang, Jian-Guo; Tian, Si-Cong
  • The Journal of Physical Chemistry C, Vol. 118, Issue 5
  • DOI: 10.1021/jp408354r

Amine-functionalized low-cost industrial grade multi-walled carbon nanotubes for the capture of carbon dioxide
journal, January 2014


Theoretical Investigation on the Different Reaction Mechanisms of Aqueous 2-Amino-2-methyl-1-propanol and Monoethanolamine with CO 2
journal, February 2014

  • Xie, Hong-Bin; He, Ning; Song, Zhiquan
  • Industrial & Engineering Chemistry Research, Vol. 53, Issue 8
  • DOI: 10.1021/ie403280h

Amine-Functionalized Amino Acid-based Ionic Liquids as Efficient and High-Capacity Absorbents for CO 2
journal, February 2014

  • Saravanamurugan, Shunmugavel; Kunov-Kruse, Andreas J.; Fehrmann, Rasmus
  • ChemSusChem, Vol. 7, Issue 3
  • DOI: 10.1002/cssc.201300691

Efficient and Energy-Saving CO 2 Capture through the Entropic Effect Induced by the Intermolecular Hydrogen Bonding in Anion-Functionalized Ionic Liquids
journal, January 2014

  • Luo, Xiao Y.; Ding, Fang; Lin, Wen J.
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 2
  • DOI: 10.1021/jz402531n