Mackinawite (FeS) Reduces Mercury(II) under Sulfidic Conditions

Bone, Sharon E.; Bargar, John R.; Sposito, Garrison

doi:10.1021/es501514r

Title: Mackinawite (FeS) Reduces Mercury(II) under Sulfidic Conditions

Authors:

Bone, Sharon E. ^[1]; Bargar, John R. ^[2]; Sposito, Garrison ^[1]

Environmental Science, Policy, and Management, University of California, Berkeley, California 94720, United States, Geochemistry, Earth Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States
Stanford Synchrotron Radiation Lightsource, SLAC, 2575 Sand Hill Road, Menlo Park, California 94025, United States

Publication Date:: Tue Sep 02 00:00:00 EDT 2014

Sponsoring Org.:: USDOE Office of Science (SC), Biological and Environmental Research (BER); USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1154674

Grant/Contract Number:: AC02-05CH11231

Resource Type:: Published Article

Journal Name:: Environmental Science and Technology

Additional Journal Information:: Journal Name: Environmental Science and Technology Journal Volume: 48 Journal Issue: 18; Journal ID: ISSN 0013-936X

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

Citation Formats


                    Bone, Sharon E., Bargar, John R., and Sposito, Garrison. Mackinawite (FeS) Reduces Mercury(II) under Sulfidic Conditions.  United States: N. p., 2014. 
Web.  doi:10.1021/es501514r.

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                    Bone, Sharon E., Bargar, John R., & Sposito, Garrison. Mackinawite (FeS) Reduces Mercury(II) under Sulfidic Conditions.  United States.  https://doi.org/10.1021/es501514r

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                    Bone, Sharon E., Bargar, John R., and Sposito, Garrison. Tue .  
"Mackinawite (FeS) Reduces Mercury(II) under Sulfidic Conditions".  United States.  https://doi.org/10.1021/es501514r.

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@article{osti_1154674,

  title        = {Mackinawite (FeS) Reduces Mercury(II) under Sulfidic Conditions},

  author       = {Bone, Sharon E. and Bargar, John R. and Sposito, Garrison},

  abstractNote = {},

  doi          = {10.1021/es501514r},

  journal      = {Environmental Science and Technology},

  number       = 18,

  volume       = 48,

  place        = {United States},

  year         = {Tue Sep 02 00:00:00 EDT 2014},

  month        = {Tue Sep 02 00:00:00 EDT 2014}

}

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Title: Mackinawite (FeS) Reduces Mercury(II) under Sulfidic Conditions

Citation Formats

Natural attenuation of TCE, As, Hg linked to the heterogeneous oxidation of Fe(II): an AFM study journal, October 2002

Metallothionein-Like Multinuclear Clusters of Mercury(II) and Sulfur in Peat journal, September 2011

Sorption of Mercuric Ion by Synthetic Nanocrystalline Mackinawite (FeS) journal, November 2007

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SIXPack a Graphical User Interface for XAS Analysis Using IFEFFIT journal, January 2005

Sulfide and iron control on mercury speciation in anoxic estuarine sediment slurries journal, September 2008

Mössbauer studies of some sulphide minerals journal, March 1971

The Genetic Basis for Bacterial Mercury Methylation journal, February 2013

Reduction of Hg(II) to Hg(0) by Magnetite journal, July 2009

Binding of Hg II to High-Affinity Sites on Bacteria Inhibits Reduction to Hg 0 by Mixed Fe II/III Phases journal, November 2011

High-temperature FeS–FeS2 solid-state transitions: Reactions of solid mackinawite with gaseous H2S journal, November 2008

Near-edge x-ray-absorption fine structure of Pb: A comparison of theory and experiment journal, June 1993

The structure of mercury at low temperatures journal, January 1957

XPS and AES studies of Hg(II) sorption and desorption reactions on sulphide minerals journal, July 1990

Relationships between Hg(ii)–S bond distance and Hg(ii) coordination in thiolates journal, January 2008

Reduction of Hexavalent Chromium by Amorphous Iron Sulfide journal, July 1997

Mercury reduction and complexation by natural organic matter in anoxic environments journal, January 2011

Sulfide Species as a Sink for Mercury in Lake Sediments journal, September 2005

Competition between Disordered Iron Sulfide and Natural Organic Matter Associated Thiols for Mercury(II)—An EXAFS Study journal, February 2010

Magnetic ordering in tetragonal FeS: Evidence for strong itinerant spin fluctuations journal, February 2011

Effects of Zwitterionic Buffers on Sorption of Ferrous Iron at Goethite and Its Oxidation by CCl 4 journal, April 2011

Surface Chemistry Controls Crystallinity of ZnS Nanoparticles journal, February 2006

Sunlight-Induced Formation of Dissolved Gaseous Mercury in Lake Waters journal, December 1994

Structural evolution of aqueous mercury sulphide precipitates: energy-dispersive X-ray diffraction studies journal, February 2010

Uptake, Toxicity, and Trophic Transfer of Mercury in a Coastal Diatom journal, January 1996

Reduction of AgI, AuIII, CuII, and HgII by FeII/FeIII hydroxysulfate green rust journal, November 2003

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Oxidation of Dissolved Elemental Mercury by Thiol Compounds under Anoxic Conditions journal, November 2013

Mechanisms Regulating Mercury Bioavailability for Methylating Microorganisms in the Aquatic Environment: A Critical Review journal, February 2013

Estimation of mercury-sulfide speciation in sediment pore waters using octanol-water partitioning and implications for availability to methylating bacteria: Mercury-sulfide speciation journal, October 1999

Organic matter and sulfide inhibit methylmercury production in sediments of New York/New Jersey Harbor journal, February 2008

Oxidation State and Local Structure of Plutonium Reacted with Magnetite, Mackinawite, and Chukanovite journal, September 2011

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Natural attenuation of TCE, As, Hg linked to the heterogeneous oxidation of Fe(II): an AFM study
journal, October 2002

Metallothionein-Like Multinuclear Clusters of Mercury(II) and Sulfur in Peat
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Sorption of Mercuric Ion by Synthetic Nanocrystalline Mackinawite (FeS)
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High methylation rates of mercury bound to cysteine by Geobacter sulfurreducens
journal, January 2009

Microscopic and Spectroscopic Characterization of Hg(II) Immobilization by Mackinawite (FeS)
journal, October 2010

Kinetics of Homogeneous and Surface-Catalyzed Mercury(II) Reduction by Iron(II)
journal, June 2013

Importance of elemental mercury in lake sediments
journal, February 2009

Sulfide Controls on Mercury Speciation and Bioavailability to Methylating Bacteria in Sediment Pore Waters
journal, March 1999

The adsorption of gold(I) hydrosulphide complexes by iron sulphide surfaces
journal, February 2002

Mercury Reduction and Oxidation by Reduced Natural Organic Matter in Anoxic Environments
journal, November 2011

Rate of formation and dissolution of mercury sulfide nanoparticles: The dual role of natural organic matter
journal, August 2010

The Case for Atmospheric Mercury Contamination in Remote Areas
journal, January 1998

Oxidation and methylation of dissolved elemental mercury by anaerobic bacteria
journal, August 2013

Interaction of vapours of mercury with PbS(001): a study by X-ray photoelectron spectroscopy, RHEED and X-ray absorption spectroscopy
journal, March 2001

Uranium(VI) Reduction by Iron(II) Monosulfide Mackinawite
journal, February 2012

Chemistry of Iron Sulfides
journal, February 2007

Decrease in Net Mercury Methylation Rates Following Iron Amendment to Anoxic Wetland Sediment Slurries
journal, April 2005

SIXPack a Graphical User Interface for XAS Analysis Using IFEFFIT
journal, January 2005

Sulfide and iron control on mercury speciation in anoxic estuarine sediment slurries
journal, September 2008

Mössbauer studies of some sulphide minerals
journal, March 1971

The Genetic Basis for Bacterial Mercury Methylation
journal, February 2013

Reduction of Hg(II) to Hg(0) by Magnetite
journal, July 2009

Binding of Hg ^II to High-Affinity Sites on Bacteria Inhibits Reduction to Hg ⁰ by Mixed Fe ^II/III Phases
journal, November 2011

High-temperature FeS–FeS2 solid-state transitions: Reactions of solid mackinawite with gaseous H2S
journal, November 2008

Near-edge x-ray-absorption fine structure of Pb: A comparison of theory and experiment
journal, June 1993

The structure of mercury at low temperatures
journal, January 1957

XPS and AES studies of Hg(II) sorption and desorption reactions on sulphide minerals
journal, July 1990

Relationships between Hg(ii)–S bond distance and Hg(ii) coordination in thiolates
journal, January 2008

Reduction of Hexavalent Chromium by Amorphous Iron Sulfide
journal, July 1997

Mercury reduction and complexation by natural organic matter in anoxic environments
journal, January 2011

Sulfide Species as a Sink for Mercury in Lake Sediments
journal, September 2005

Competition between Disordered Iron Sulfide and Natural Organic Matter Associated Thiols for Mercury(II)—An EXAFS Study
journal, February 2010

Magnetic ordering in tetragonal FeS: Evidence for strong itinerant spin fluctuations
journal, February 2011

Effects of Zwitterionic Buffers on Sorption of Ferrous Iron at Goethite and Its Oxidation by CCl ₄
journal, April 2011

Surface Chemistry Controls Crystallinity of ZnS Nanoparticles
journal, February 2006

Sunlight-Induced Formation of Dissolved Gaseous Mercury in Lake Waters
journal, December 1994

Structural evolution of aqueous mercury sulphide precipitates: energy-dispersive X-ray diffraction studies
journal, February 2010

Uptake, Toxicity, and Trophic Transfer of Mercury in a Coastal Diatom
journal, January 1996

Reduction of AgI, AuIII, CuII, and HgII by FeII/FeIII hydroxysulfate green rust
journal, November 2003

Methylation of Mercury by Bacteria Exposed to Dissolved, Nanoparticulate, and Microparticulate Mercuric Sulfides
journal, January 2012

Reduction of Net Mercury Methylation by Iron in Desulfobulbus propionicus (1pr3) Cultures: Implications for Engineered Wetlands
journal, July 2003

Influence of natural dissolved organic carbon on the bioavailability of mercury to a freshwater alga
journal, July 2008

Influence of Chloride and Fe(II) Content on the Reduction of Hg(II) by Magnetite
journal, April 2013

Anaerobic oxidation of Hg(0) and methylmercury formation by Desulfovibrio desulfuricans ND132
journal, July 2013

Surface chemistry and structural properties of mackinawite prepared by reaction of sulfide ions with metallic iron
journal, March 2002

Reduction of antimony by nano-particulate magnetite and mackinawite
journal, February 2008

EXAFS analysis using FEFF and FEFFIT
journal, March 2001

New Technique for Quantification of Elemental Hg in Mine Wastes and Its Implications for Mercury Evasion Into the Atmosphere
journal, December 2010

Active transport, substrate specificity, and methylation of Hg(II) in anaerobic bacteria
journal, May 2011

Surface chemistry and morphology of poorly crystalline iron sulfides precipitated in media containing sulfate-reducing bacteria
journal, January 1998

Oxidation of Dissolved Elemental Mercury by Thiol Compounds under Anoxic Conditions
journal, November 2013

Mechanisms Regulating Mercury Bioavailability for Methylating Microorganisms in the Aquatic Environment: A Critical Review
journal, February 2013

Estimation of mercury-sulfide speciation in sediment pore waters using octanol-water partitioning and implications for availability to methylating bacteria: Mercury-sulfide speciation
journal, October 1999

Organic matter and sulfide inhibit methylmercury production in sediments of New York/New Jersey Harbor
journal, February 2008

Oxidation State and Local Structure of Plutonium Reacted with Magnetite, Mackinawite, and Chukanovite
journal, September 2011

The structural chemistry of mercury
journal, January 1965

Marine Biogeochemical Cycling of Mercury
journal, February 2007