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Note: This page contains sample records for the topic "zinc tin selenium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Speciation of Selenium, Arsenic, and Zinc in Class C Fly Ash  

Science Conference Proceedings (OSTI)

A major environmental concern associated with coal fly ash is the mobilization of trace elements that may contaminate water. To better evaluate proper use of fly ash, determine appropriate disposal methods, and monitor postdisposal conditions, it is important to understand the speciation of trace elements in fly ash and their possible environmental impact. The speciation of selenium, arsenic, and zinc was determined in five representative Class C fly ash samples from combustion of sub-bituminous Powder River Basin coal using synchrotron-based X-ray absorption spectroscopy to provide an improved understanding of the mechanisms of trace element association with the fly ash. Selenium in all fly ash samples occurs predominantly as Se(IV), with the exception of one sample, in which there was a minor amount of Se(0). Se(0) is likely associated with the high content of unburned coal in the sample. Arsenic exists in the fly ash as a single phase most consistent with calcium pyroarsenate. In contrast, zinc occurs as two distinct species in the silicate glass matrix of the fly ash. This work demonstrates that residual carbon in fly ash may reduce potential Se mobility in the environment by retaining it as less soluble elemental Se instead of Se(IV). Further, this work suggests that As and Zn in Class C fly ash will display substantially different release and mobilization behaviors in aquatic environments. While As release will primarily depend upon the dissolution and hydrolysis of calcium pyroarsenate, Zn release will be controlled by the dissolution of alkaline aluminosilicate glass in the ash.

Luo, Yun; Giammar, Daniel E.; Huhmann, Brittany L.; Catalano, Jeffrey G. (WU)

2011-11-17T23:59:59.000Z

2

The electronic structure of co-sputtered zinc indium tin oxide thin films  

SciTech Connect

Zinc indium tin oxide (ZITO) transparent conductive oxide layers were deposited via radio frequency (RF) magnetron co-sputtering at room temperature. A series of samples with gradually varying zinc content was investigated. The samples were characterized with x-ray and ultraviolet photoemission spectroscopy (XPS, UPS) to determine the electronic structure of the surface. Valence and conduction bands maxima (VBM, CBM), and work function were determined. The experiments indicate that increasing Zn content results in films with a higher defect rate at the surface leading to the formation of a degenerately doped surface layer if the Zn content surpasses {approx}50%. Furthermore, the experiments demonstrate that ZITO is susceptible to ultraviolet light induced work function reduction, similar to what was earlier observed on ITO and TiO{sub 2} films.

Carreras, Paz; Antony, Aldrin; Bertomeu, Joan [Departament de Fisica Aplicada i Optica, Universitat de Barcelona, 08028 Barcelona (Spain); Gutmann, Sebastian [Department of Chemistry, University of South Florida, Tampa, Florida 33620 (United States); Schlaf, Rudy [Department of Electrical Engineering, University of South Florida, Tampa, Florida 33620 (United States)

2011-10-01T23:59:59.000Z

3

Synthesizing photovoltaic thin films of high quality copper-zinc-tin alloy with at least one chalcogen species  

DOE Patents (OSTI)

A method for synthesizing a thin film of copper, zinc, tin, and a chalcogen species ("CZTCh" or "CZTSS") with well-controlled properties. The method includes depositing a thin film of precursor materials, e.g., approximately stoichiometric amounts of copper (Cu), zinc (Zn), tin (Sn), and a chalcogen species (Ch). The method then involves re-crystallizing and grain growth at higher temperatures, e.g., between about 725 and 925 degrees K, and annealing the precursor film at relatively lower temperatures, e.g., between 600 and 650 degrees K. The processing of the precursor film takes place in the presence of a quasi-equilibrium vapor, e.g., Sn and chalcogen species. The quasi-equilibrium vapor is used to maintain the precursor film in a quasi-equilibrium condition to reduce and even prevent decomposition of the CZTCh and is provided at a rate to balance desorption fluxes of Sn and chalcogens.

Teeter, Glenn; Du, Hui; Young, Matthew

2013-08-06T23:59:59.000Z

4

EFFECT OF THERMAL PROCESSES ON COPPER-TIN ALLOYS FOR ZINC GETTERING  

SciTech Connect

A contamination mitigation plan was initiated to address the discovery of radioactive zinc‐65 in a glovebox. A near term solution was developed, installation of heated filters in the glovebox piping. This solution is effective at retaining the zinc in the currently contaminated area, but the gamma emitting contaminant is still present in a system designed for tritium beta. A project was initiated to develop a solution to contain the {sup 65}Zn in the furnace module. Copper and bronze (a Cu/Sn alloy) were found to be candidate materials to combine with zinc‐65 vapor, using thermodynamic calculations. A series of binary Cu/Sn alloys were developed (after determining that commercial alloys were unacceptable), that were found to be effective traps of zinc vapor. The task described in this report was undertaken to determine if the bronze substrates would retain their zinc gettering capability after being exposed to simulated extraction conditions with oxidizing and reducing gases. Pure copper and three bronze alloys were prepared, exposed to varying oxidation conditions from 250 to 450{degree}C, then exposed to varying reduction conditions in He-H{sub 2} from 250-450{degree}C, and finally exposed to zinc vapor at 350{degree}C for four hours. The samples were characterized using scanning electron microscopy, X-ray diffraction, differential thermal analysis, mass change, and visual observation. It was observed that the as fabricated samples and the reduced samples all retained their zinc gettering capacity while samples in the "as-oxidized" condition exhibited losses in zinc gettering capacity. Over the range of conditions tested, i.e., composition, oxidation temperature, and reduction temperature, no particular sample composition appeared better. Samples reduced at 350{degree}C exhibited the greatest zinc capacity, although there were some testing anomalies associated with these samples. This work clearly demonstrated that the zinc gettering was not adversely affected by exposure to simulated process conditions and a full scale lithium and zinc trap should be fabricated for testing in the Tritium Extraction Facility.

Korinko, P.; Golyski, M.

2013-11-01T23:59:59.000Z

5

Lead Zinc and Tin  

Science Conference Proceedings (OSTI)

"High Temperature Lead-free Solder for Microelectronics" (Overview), Frank R. Gayle, Gary Becka, Jerry Badgett, Gordon Whitten, Tsung-Yu Pan, Angela Grusd,

6

Lead Zinc and Tin  

Science Conference Proceedings (OSTI)

Title, Author, Publisher, Product Type, In Stock, Date Published. Add to Cart, Image, Click on Title to view details, Member (Student) Price, Non-member Price.

7

Multivitamin/Multielement Dietary Supplement SRM  

Science Conference Proceedings (OSTI)

... chromium, copper, iodine, iron, magnesium, manganese, molybdenum, nickel, phosphorous, potassium, selenium, silicon, tin, vanadium, and zinc. ...

2012-10-22T23:59:59.000Z

8

Tin (Sn)  

Science Conference Proceedings (OSTI)

...Tin phase Interatomic distance, nm Number of neighbors α tin 0.279 4 0.456 8 β tin 0.302 4 0.318 2 0.376 4 Liquid tin (250 °C) 0.338 10 Source: Ref 433...

9

Pure Tin  

Science Conference Proceedings (OSTI)

Table 1   Corrosion of tin exposed in different environments for 10 and 20 years...? ? Marine (Florida) 0.0023 0.09 ? ? Marine (California) ? ? 0.0029 0.11 Semiarid ? ? 0.00044 0.017 Rural 0.00049 0.019 ? ? (a) Converted from weight

10

Properties of double-layered Ga-doped Al-zinc-oxide/titanium-doped indium-tin-oxide thin films prepared by dc magnetron sputtering applied for Si-based thin film solar cells  

Science Conference Proceedings (OSTI)

In this article, Ga-doped Al-zinc-oxide (GAZO)/titanium-doped indium-tin-oxide (ITIO) bi-layer films were deposited onto glass substrates by direct current (dc) magnetron sputtering. The bottom ITIO film, with a thickness of 200 nm, was sputtered onto the glass substrate. The ITIO film was post-annealed at 350 deg. C for 10-120 min as a seed layer. The effect of post-annealing conditions on the morphologies, electrical, and optical properties of ITIO films was investigated. A GAZO layer with a thickness of 1200 nm was continuously sputtered onto the ITIO bottom layer. The results show that the properties of the GAZO/ITIO films were strongly dependent on the post-annealed conditions. The spectral haze (T{sub diffuse}/T{sub total}) of the GAZO/ITIO bi-layer films increases upon increasing the post-annealing time. The haze and resistivity of the GAZO/ITIO bi-layer films were improved with the post-annealed process. After optimizing the deposition and annealing parameters, the GAZO/ITIO bi-layer film has an average transmittance of 83.20% at the 400-800 nm wavelengths, a maximum haze of 16%, and the lowest resistivity of 1.04 x 10{sup -3}{Omega} cm. Finally, the GAZO/ITIO bi-layer films, as a front electrode for silicon-based thin film solar cells, obtained a maximum efficiency of 7.10%. These encouraging experimental results have potential applications in GAZO/ITIO bi-layer film deposition by in-line sputtering without the wet-etching process and enable the production of highly efficient, low-cost thin film solar cells.

Wang, Chao-Chun; Wuu, Dong-Sing; Lin, Yang-Shih; Lien, Shui-Yang; Huang, Yung-Chuan; Liu, Chueh-Yang; Chen, Chia-Fu; Nautiyal, Asheesh; Lee, Shuo-Jen [Department of Materials Science and Engineering, National Chung Hsing University, Taichung 40227, Taiwan (China); Department of Materials Science and Engineering, MingDao University, Changhua 52345, Taiwan (China); Department of Mechanical Engineering, Yuan Ze University, Taoyuan 320, Taiwan (China)

2011-11-15T23:59:59.000Z

11

Review of Selenium Thermodynamic Data  

Science Conference Proceedings (OSTI)

Utilities need accurate equilibrium and nonequilibrium models to predict concentrations of toxic metals, such as selenium, in the environment. A comprehensive review of available information revealed the insufficiency and inaccuracy of selenium thermodynamic data available for equilibrium modeling.

1988-02-12T23:59:59.000Z

12

Chemical Attenuation Reactions of Selenium  

Science Conference Proceedings (OSTI)

Selenium, which is often found in trace concentrations in coal combustion wastes, presents significant challenges to utility efforts to quantify its transport in the subsurface. This report focuses on the complex environmental chemistry and geochemistry of selenium to help utility engineers predict the movement of selenium from waste disposal operations.

1994-03-01T23:59:59.000Z

13

It's Elemental - The Element Tin  

NLE Websites -- All DOE Office Websites (Extended Search)

carbon. Tin makes up only about 0.001% of the earth's crust and is chiefly mined in Malaysia. Two allotropes of tin occur near room temperature. The first form of tin is called...

14

Kinds of Scrap Tin Materials  

Science Conference Proceedings (OSTI)

...tin that is usually fairly high in tin content. Prices for this type are quoted in American Metal Market. The specific scrap grades within this type??block tin, and high-tin babbitt and pewter??are consistent enough to identify and define....

15

NIDC: Online Catalog of Isotope Products | Request a Quote  

NLE Websites -- All DOE Office Websites (Extended Search)

Selenium Silicon Silver Sodium Strontium Sulfur Tantalum Technetium Tellurium Thallium Thorium Tin Titanium Tungsten Uranium Vanadium Xenon Ytterbium Yttrium Zinc Zirconium Find...

16

Refining Primary Lead by GranulationLeachingElectrowinning  

Science Conference Proceedings (OSTI)

For example, smelters of complex concentrates may have iron, copper, nickel, cobalt, zinc, arsenic, antimony, tin, bismuth, selenium, tellurium, silver, and gold, ...

17

P-64: A Comparative Study of Metal Oxide Coated Indium-tin Oxide Anodes  

E-Print Network (OSTI)

Indium-tin oxide anodes capped with certain oxides of metals enhance while other oxides degrade the hole-injection and quantum efficiencies of organic light-emitting diodes (OLEDs). The oxides of tin, zinc, praseodymium, yttrium, gallium, terbium and titanium have been investigated. The power efficiency of an OLED with a 1nm thick praseodymium oxide cap is improved by 2.5 times over that of a conventional OLED without an oxide capped anode.

For Organic Light-Emitting; Chengfeng Qiu; Haiying Chen; Zhilang Xie; Man Wong; Hoi Sing Kwok

2002-01-01T23:59:59.000Z

18

Zinc Products  

Science Conference Proceedings (OSTI)

Table 7   Typical applications of wrought zinc and zinc alloys...deep-drawn hardware; address plates; solar collectors Zn-Pb-Cd-Fe Building construction materials, dry-cell battery

19

Wrought Zinc and Zinc Alloys  

Science Conference Proceedings (OSTI)

Table 12   Typical applications of wrought zinc and zinc alloys...deep-drawn hardware; address plates; solar collectors Zn-Pb-Cd-Fe Building construction materials, dry-cell battery

20

Production of selenium-72 and arsenic-72  

SciTech Connect

Methods for producing selenium-72, separating it from its daughter isotope arsenic-72, and generating multiple portions of a solution containing arsenic-72 from a reusable parent substance comprised of selenium-72.

Phillips, Dennis R. (Los Alamos, NM)

1993-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "zinc tin selenium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Wrought Zinc and Zinc Alloys  

Science Conference Proceedings (OSTI)

Table 12 Typical applications of wrought zinc and zinc alloys...materials; deep-drawn hardware; address plates; solar collectors Zn-Pb-Cd-Fe Building construction materials, dry-cell battery cans, deep-drawn hardware, address plates, electrical components Zn-Al (superplastic zinc) Shaped components such as typewriter casings, computer panels, and covers...

22

Selenium metabolite levels in human urine after dosing selenium in different chemical forms  

Science Conference Proceedings (OSTI)

It has been well known that selenium in marine fish such as tuna and swordfish protects the toxicity of methylmercury in vivo. The protective potency might depend on the chemical forms of selenium in the meat of marine fish sebastes and sperm whale. Little has been revealed, however, on the chemical forms of selenium in the meat of these animals or the selenium metabolites in urine, because the amount of the element is very scarce. Urine is the major excretory route for selenium. The chemical forms of urinary selenium may reflect the metabolism of the element. We have developed methodology for analysis of selenium-containing components in human urine. Using this method, we have observed the time courses of excretory levels of urinary selenium components after a single dose of selenium as selenious acid, selenomethionine, trimethylselenonium ion or tuna meat. 14 refs., 6 figs., 1 tab.

Hasunuma, Ryoichi; Tsuda, Morizo; Ogawa, Tadao; Kawanishi, Yasuhiro [Kitasato Univ., Kanagawa (Japan)

1993-11-01T23:59:59.000Z

23

What is a TIN/EIN?  

Science Conference Proceedings (OSTI)

TIN/EIN Information. As ... number. Please see the following Frequently Asked Questions (FAQ) for information. What is a TIN/EIN? ...

2012-11-19T23:59:59.000Z

24

Vacuum Distillation Refining of Crude Tin - Thermodynamics ...  

Science Conference Proceedings (OSTI)

Presentation Title, Vacuum Distillation Refining of Crude Tin - Thermodynamics Analysis and Experiments on the Removal of Arsenic from the Crude Tin.

25

Aluminum doped zinc oxide for organic photovoltaics  

Science Conference Proceedings (OSTI)

Aluminum doped zinc oxide (AZO) was grown via magnetron sputtering as a low-cost alternative to indium tin oxide (ITO) for organic photovoltaics (OPVs). Postdeposition ozone treatment resulted in devices with lower series resistance, increased open-circuit voltage, and power conversion efficiency double that of devices fabricated on untreated AZO. Furthermore, cells fabricated using ozone treated AZO and standard ITO displayed comparable performance.

Murdoch, G. B.; Hinds, S.; Sargent, E. H.; Tsang, S. W.; Mordoukhovski, L.; Lu, Z. H. [Department of Materials Science and Engineering, University of Toronto, 184 College St., Toronto, Ontario M5S 3E4 (Canada)

2009-05-25T23:59:59.000Z

26

V1, Alkanethiol Island Formation on Single Crystal Zinc Oxide ...  

Science Conference Proceedings (OSTI)

... through the Renewable Energy Materials Research Science and Engineering Center is ... A2, Observation and Elimination of Indium Surface Segregation ... B5, The Universal Optimal Seebeck Coefficient for Maximum Power Factor ..... X9, Solution-Processed Zirconium Oxide and Integration with Zinc-Tin Oxide Thin-

27

Health and Ecological Effects of Selenium  

Science Conference Proceedings (OSTI)

Selenium is a naturally occurring element that can be found at background levels in food, soil, and water. It is also present in coal combustion products (CCPs) and CCP leachate. While selenium is essential to human and animal life, it has the potential to cause toxicity to humans and other organisms above a certain threshold level. This report summarizes the adverse human and ecological effects that can potentially occur from overexposure to selenium and the levels at which the effects can occur, with p...

2010-11-30T23:59:59.000Z

28

Zinc electrode with cement additive  

DOE Patents (OSTI)

A zinc electrode having a cement additive, preferably, Portland Cement, distributed in the zinc active material.

Charkey, Allen (Brookfield, CT)

1982-06-01T23:59:59.000Z

29

Production of selenium-72 and arsenic-72  

DOE Patents (OSTI)

Methods and apparatus for producing selenium-72, separating it from its daughter isotope arsenic-72, and generating multiple portions of a solution containing arsenic-72 from a reusable parent substance comprised of selenium-72. The invention provides apparatus which can be located at a site where arsenic-72 is used, for purposes such as PET imaging, to produce arsenic-72 as needed, since the half-life of arsenic-72 is very short.

Phillips, Dennis R. (Los Alamos, NM)

1994-01-01T23:59:59.000Z

30

Production of selenium-72 and arsenic-72  

DOE Patents (OSTI)

Methods and apparatus for producing selenium-72, separating it from its daughter isotope arsenic-72, and generating multiple portions of a solution containing arsenic-72 from a reusable parent substance comprised of selenium-72. The invention provides apparatus which can be located at a site where arsenic-72 is used, for purposes such as PET imaging, to produce arsenic-72 as needed, since the half-life of arsenic-72 is very short.

Phillips, Dennis R. (Los Alamos, NM)

1995-01-01T23:59:59.000Z

31

\\Chemical Constituents in Coal Combustion Product Leachate: Selenium  

Science Conference Proceedings (OSTI)

Selenium is a common constituent in coal and coal combustion products (CCPs) and can be found in CCP leachate. The chemical profile provided here assembles and summarizes existing information on seleniums environmental characteristics, which are focused on conditions associated with CCP management. Extensive references provide a means for obtaining more detailed information on specific subject areas. The following topics are covered: 1) occurrence and sources of selenium; 2) environmental ...

2013-12-26T23:59:59.000Z

32

Production of zinc pellets  

DOE Patents (OSTI)

Uniform zinc pellets are formed for use in batteries having a stationary or moving slurry zinc particle electrode. The process involves the cathodic deposition of zinc in a finely divided morphology from battery reaction product onto a non-adhering electrode substrate. The mossy zinc is removed from the electrode substrate by the action of gravity, entrainment in a flowing electrolyte, or by mechanical action. The finely divided zinc particles are collected and pressed into pellets by a mechanical device such as an extruder, a roller and chopper, or a punch and die. The pure zinc pellets are returned to the zinc battery in a pumped slurry and have uniform size, density and reactivity. Applications include zinc-air fuel batteries, zinc-ferricyanide storage batteries, and zinc-nickel-oxide secondary batteries. 6 figs.

Cooper, J.F.

1996-11-26T23:59:59.000Z

33

Production of zinc pellets  

DOE Patents (OSTI)

Uniform zinc pellets are formed for use in batteries having a stationary or moving slurry zinc particle electrode. The process involves the cathodic deposition of zinc in a finely divided morphology from battery reaction product onto a non-adhering electrode substrate. The mossy zinc is removed from the electrode substrate by the action of gravity, entrainment in a flowing electrolyte, or by mechanical action. The finely divided zinc particles are collected and pressed into pellets by a mechanical device such as an extruder, a roller and chopper, or a punch and die. The pure zinc pellets are returned to the zinc battery in a pumped slurry and have uniform size, density and reactivity. Applications include zinc-air fuel batteries, zinc-ferricyanide storage batteries, and zinc-nickel-oxide secondary batteries.

Cooper, John F. (Oakland, CA)

1996-01-01T23:59:59.000Z

34

Enhancing the efficiency of SnS solar cells via band-offset engineering with a zinc oxysulfide buffer layer  

E-Print Network (OSTI)

S absorber layers without breaking vacuum. Indium tin oxide (ITO) (200 nm) was deposited at room temperature at the National Renewable Energy Laboratory (NREL), exhibiting an improved cell performance of Jsc ¼ 19.4mA/cm2 by vapor deposition of p-type tin(II) sulfide, SnS, and n-type zinc oxysulfide, Zn(O,S), using a device

Gordon, Roy

35

Selenium in Oklahoma ground water and soil  

SciTech Connect

Selenium with a consumption of 2 liters per day (5). The objectives of this study are: (1) to determine the concentrations of Se in Oklahoma ground water and soil samples. (2) to map the geographical distribution of Se species in Oklahoma. (3) to relate groundwater depth, pH and geology with concentration of Se.

Atalay, A.; Vir Maggon, D.

1991-03-30T23:59:59.000Z

36

Nickel/zinc batteries  

SciTech Connect

A review of the design, components, electrochemistry, operation and performance of nickel-zinc batteries is presented. 173 references. (WHK)

McBreen, J.

1982-07-01T23:59:59.000Z

37

Infrared Images of Shock-Heated Tin  

Science Conference Proceedings (OSTI)

High-resolution, gated infrared images were taken of tin samples shock heated to just below the 505 K melting point. Sample surfaces were either polished or diamond-turned, with grain sizes ranging from about 0.05 to 10 mm. A high explosive in contact with a 2-mm-thick tin sample induced a peak sample stress of 18 GPa. Interferometer data from similarly-driven tin shots indicate that immediately after shock breakout the samples spall near the free (imaged) surface with a scab thickness of about 0.1 mm.

Craig W. McCluskey; Mark D. Wilke; William D. Turley; Gerald D. Stevens; Lynn R. Veeser; Michael Grover

2004-09-01T23:59:59.000Z

38

Evaluation of Selenium Species in Flue Gas Desulfurization Waters  

Science Conference Proceedings (OSTI)

Flue gas desulfurization (FGD) is a process used in the electrical power industry to remove sulfur dioxide from flue gas produced by coal-fired power plants. The trace element selenium is found in coal and can become concentrated in the wastewater from the FGD process. Some chemical forms, or species, of selenium are more resistant to removal by water treatment processes than others; thus, understanding the speciation of selenium is important to designing effective wastewater treatment systems. In additi...

2009-03-23T23:59:59.000Z

39

120122013 General Bulletin US TIN S TATE  

E-Print Network (OSTI)

12012­2013 General Bulletin S TEPHENF.A US TIN S TATE UNIVERSITY 1 9 2 3 General Bulletin FOr 2012­2013 ..............................................................................................................................8 University Calendar for 2012-2013................................................................................................................. 10 May-mester, 2013

Long, Nicholas

40

Improved zinc electrode and rechargeable zinc-air battery  

DOE Patents (OSTI)

The invention comprises an improved rechargeable zinc-air cell/battery having recirculating alkaline electrolyte and a zinc electrode comprising a porous foam support material which carries the active zinc electrode material. 5 figs.

Ross, P.N. Jr.

1988-06-21T23:59:59.000Z

Note: This page contains sample records for the topic "zinc tin selenium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Fate and Effects of Selenium in Lentic and Lotic Systems  

Science Conference Proceedings (OSTI)

This document summarizes existing knowledge on the biological fate and effects of selenium in aquatic systems, with an emphasis on differences between flowing (lotic) versus standing (lentic) systems. The report is divided into three main areas: selenium chemistry and biogeochemistry, fate and disposition, and effects.

2006-03-27T23:59:59.000Z

42

Applications of Zinc  

Science Conference Proceedings (OSTI)

Table 1   Typical applications of zinc-coated steel products...galvanized Various alloys Structural steel for power generating plants, petrochemical

43

Zinc-Nickel Battery  

The short lifetime of the conventional zinc-nickel oxide battery has been the primary factor limiting its commercial use, ... Higher voltage, lower co ...

44

99M-Technetium labeled tin colloid radiopharmaceuticals  

DOE Patents (OSTI)

An improved 99m-technetium labeled tin(II) colloid, size-stabilized for reticuloendothelial organ imaging without the use of macromolecular stabilizers and a packaged tin base reagent and an improved method for making it are disclosed.

Winchell, Harry S. (Lafayette, CA); Barak, Morton (Walnut Creek, CA); Van Fleet, III, Parmer (Walnut Creek, CA)

1976-07-06T23:59:59.000Z

45

Design and fabrication of a tin-sulfide annealing furnace  

E-Print Network (OSTI)

A furnace was designed and its heat transfer properties were analyzed for use in annealing thin-film tins-ulfide solar cells. Tin sulfide has been explored as an earth abundant solar cell material, and the furnace was ...

Lewis, Raymond, S.M. (Raymond A.) Massachusetts Institute of Technology

2011-01-01T23:59:59.000Z

46

How Spineless Prickly Pear Cactus Utilize Selenium  

NLE Websites -- All DOE Office Websites (Extended Search)

How Spineless Prickly Pear Cactus How Spineless Prickly Pear Cactus Utilize Selenium How Spineless Prickly Pear Cactus Utilize Selenium Print Monday, 12 March 2012 13:50 Due to drought and limited freshwater supplies, the increased accumulation of naturally occurring salts, boron (B), and selenium (Se) has worsened in some agricultural areas, such as in the west side of the San Joaquin Valley, California. Growing Se-biofortified crops is an emerging method for utilizing these "semiretired lands" because the nutraceutical benefits of enhancing organic Se, an essential micronutrient in crops, is concomitant with the phytoremediation of inorganic Se pollutants. Researchers from the U.S. Department of Agriculture used ALS Beamline 10.3.2 to study the chemical forms and distribution of Se in the attractive alternative crop Opuntia ficus-indica, an edible spineless prickly pear cactus that tolerates both drought and adverse saline- and B-impacted soil conditions while accumulating and volatilizing organic Se. Micro x-ray fluorescence (mXRF) mapping showed Se concentrated in the tips of the plant's cladodes (edible pads), cladode vasculature, and seed embryos. Se K-edge x-ray absorption near edge structure (XANES) spectroscopy demonstrated that >90% of total Se in cladodes, fruit juice, fruit pulp, and seeds is in organic form (C-Se-C). Cladode tips contain both inorganic selenate (SeO42-) and C-Se-C. Enzymatic digestion confirmed that Se was mainly present in a "free," non-proteinaceous form inside cladode and fruit, whereas in the seed, Se was incorporated into proteins associated with lipids.

47

Electron Microscopy Study of Tin Whisker Growth  

Science Conference Proceedings (OSTI)

The growth of tin whiskers formed on sputtered tin layers deposited on brass was studied using electron microscopy. The occurrence of whiskers appeared to be largely independent of the macroscopic stress state in the film; rather it was microscopic compressive stresses arising from the formation of an intermetallic phase that appeared to be the necessary precursor. Whisker morphology was a result of whether nucleation had occurred on single grains or on multiple grains. In the latter case, the whiskers had a fluted or striated surface. The formation of whiskers on electron transparent samples was demonstrated. These samples showed the whiskers were monocrystalline and defect free, and that the growth direction could be determined.

Norton, Murray G. (Washington State University); Lebret, Joel (8392)

2003-03-30T23:59:59.000Z

48

Microwave plasma CVD of NANO structured tin/carbon composites  

DOE Patents (OSTI)

A method for forming a graphitic tin-carbon composite at low temperatures is described. The method involves using microwave radiation to produce a neutral gas plasma in a reactor cell. At least one organo tin precursor material in the reactor cell forms a tin-carbon film on a supporting substrate disposed in the cell under influence of the plasma. The three dimensional carbon matrix material with embedded tin nanoparticles can be used as an electrode in lithium-ion batteries.

Marcinek, Marek (Warszawa, PL); Kostecki, Robert (Lafayette, CA)

2012-07-17T23:59:59.000Z

49

Lead-Free Surface Finishes for Electronic Components: Tin ...  

Science Conference Proceedings (OSTI)

... tin with the substrate. Our focused ion beam (FIB) milling has revealed this internal microstructure. We have also developed ...

2012-10-02T23:59:59.000Z

50

Identification of Unknown Selenium Species in Flue Gas Desulfurization Water  

Science Conference Proceedings (OSTI)

Flue gas desulfurization (FGD) is a process used in the electrical power industry to remove sulfur dioxide (SO2) from flue gas produced by coal-fired power plants. In a wet FGD system, circulating water must be periodically blown down and treated to remove solids and dissolved chemicals. Along with SO2, other substances in flue gas may dissolve in water, including selenium (Se). In addition to the common selenium species selenite and selenate, past research has identified selenium-containing species that...

2008-03-25T23:59:59.000Z

51

Sealed nickel-zinc battery  

SciTech Connect

A sealed, rechargeable nickel-zinc cell includes a zinc electrode active mass essentially free of zinc metal when at full discharge, a carboxylated styrene-butadiene binder retaining the zinc electrode mixture in a coherent structure, a predetermined amount of cadmium being included in the zinc electrode mixture, a separator preferably comprising at least two layers of material free of any adhesive binding the layers together and a wicking layer positioned between the nickel positive electrode and the separator.

Gibbard, H. F.; Menard, C. J.; Murray Jr., R. C.; Putt, R. A.; Valentine, T. W.

1985-11-12T23:59:59.000Z

52

Zinc phosphate conversion coatings  

DOE Patents (OSTI)

Zinc phosphate conversion coatings for producing metals which exhibit enhanced corrosion prevention characteristics are prepared by the addition of a transition-metal-compound promoter comprising a manganese, iron, cobalt, nickel, or copper compound and an electrolyte such as polyacrylic acid, polymethacrylic acid, polyitaconic acid and poly-L-glutamic acid to a phosphating solution. These coatings are further improved by the incorporation of Fe ions. Thermal treatment of zinc phosphate coatings to generate .alpha.-phase anhydrous zinc phosphate improves the corrosion prevention qualities of the resulting coated metal.

Sugama, Toshifumi (Wading River, NY)

1997-01-01T23:59:59.000Z

53

Zinc electrode and rechargeable zinc-air battery  

DOE Patents (OSTI)

An improved zinc electrode is disclosed for a rechargeable zinc-air battery comprising an outer frame and a porous foam electrode support within the frame which is treated prior to the deposition of zinc thereon to inhibit the formation of zinc dendrites on the external surface thereof. The outer frame is provided with passageways for circulating an alkaline electrolyte through the treated zinc-coated porous foam. A novel rechargeable zinc-air battery system is also disclosed which utilizes the improved zinc electrode and further includes an alkaline electrolyte within said battery circulating through the passageways in the zinc electrode and an external electrolyte circulation means which has an electrolyte reservoir external to the battery case including filter means to filter solids out of the electrolyte as it circulates to the external reservoir and pump means for recirculating electrolyte from the external reservoir to the zinc electrode.

Ross, Jr., Philip N. (Kensington, CA)

1989-01-01T23:59:59.000Z

54

Arsenic and Selenium Treatment Technology Summary for Power Plant Wastewaters  

Science Conference Proceedings (OSTI)

This report summarizes the most suitable technologies available for the removal of arsenic and selenium from power plant wastewaters. The information stems from literature searches and the authors' experience in wastewater treatment systems from generally non-power plant sources since there are limited operating experiences for power plant applications. The report lists existing and potential technologies that meet the treatment goals of reducing arsenic and selenium to the levels set for U.S. En...

2004-11-03T23:59:59.000Z

55

THE NATURE AND IMPORTANCE OF SELENIUM METABOLITES IN THE ANIMAL  

SciTech Connect

Although the toxicity of selenium has been known for several decades and its essentiality has been established for over one decade, very little is known concerning the organic forms of selenium occurring within animals and their functions. Dimethyl selenide has been shown to be an exhalation product from rats injected with selenate or selenite. Recently trimethylselenonium ion has been shown to be excreted in the urine of rats receiving selenite. The work reported here concerns the biological activity and metabolism of trimethylselenonium ion.

Halverson, A W; Palmer, I S; Whitehead, E I

1969-01-01T23:59:59.000Z

56

Detailed sequential extraction study of selenium in coal and coal-associated strata from a coal mine in West Virginia.  

E-Print Network (OSTI)

??This study of the mode of occurrence and distribution of selenium in a rock core from southcentral West Virginia reveals that total selenium concentration varies (more)

Roy, Mimi.

2005-01-01T23:59:59.000Z

57

Bioavailable nanoparticles obtained in laser ablation of a selenium target in water  

Science Conference Proceedings (OSTI)

The process of producing colloidal solutions of selenium nanoparticles in water using the laser ablation method is described. The prospects of using nanoparticles of elementary selenium as a nutrition source of this microelement are discussed. (nanoparticles)

Kuzmin, P G; Shafeev, Georgii A; Voronov, Valerii V; Raspopov, R V; Arianova, E A; Trushina, E N; Gmoshinskii, I V; Khotimchenko, S A

2012-11-30T23:59:59.000Z

58

Nanocomposite Carbon/Tin Anodes for Lithium Ion Batteries ...  

An approach developed by Robert Kostecki and Marek Marcinek of Berkeley Lab has given rise to a new generation of nanostructured carbon-tin films that ...

59

Reliability of Copper Wire Bonding on Copper Substrate with Tin ...  

Science Conference Proceedings (OSTI)

Suitable bonding conditions, Tin thickness, stage temperature, wire bonding power and bonding time are chosen through wire bonding tests. Peel strength of a...

60

Silicon/Graphite Tin Nano-structured Composites Synthesized by ...  

Science Conference Proceedings (OSTI)

Presentation Title, Silicon/Graphite Tin Nano-structured Composites Synthesized by High Energy Mechanical Milling for Lithium-ion Rechargeable Batteries...

Note: This page contains sample records for the topic "zinc tin selenium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Zinc electrode in alkaline electrolyte  

DOE Green Energy (OSTI)

The zinc electrode in alkaline electrolyte is unusual in that supersaturated zincate solutions can form during discharge and spongy or mossy zinc deposits can form on charge at low overvoltages. The effect of additives on regular pasted ZnO electrodes and calcium zincate electrodes is discussed. The paper also reports on in situ x-ray absorption (XAS) results on mossy zinc deposits.

McBreen, J.

1995-12-31T23:59:59.000Z

62

Photovoltaic cells employing zinc phosphide  

DOE Patents (OSTI)

A photovoltaic cell having a zinc phosphide absorber. The zinc phosphide can be a single or multiple crystal slice or a thin polycrystalline film. The cell can be a Schottky barrier, heterojunction or homojunction device. Methods for synthesizing and crystallizing zinc phosphide are disclosed as well as a method for forming thin films.

Barnett, Allen M. (Newark, DE); Catalano, Anthony W. (Wilmington, DE); Dalal, Vikram L. (Newark, DE); Masi, James V. (Wilbraham, MA); Meakin, John D. (Newark, DE); Hall, Robert B. (Newark, DE)

1984-01-01T23:59:59.000Z

63

Mercury-selenium interactions in the environment  

Science Conference Proceedings (OSTI)

The Clean Air Act Amendments of 1990 require the U.S. Environmental Protection Agency (EPA) to consider the need to control emissions of trace elements and compounds emitted from coal combustion, including coal-fired power plants. Concern has been expressed about emissions of mercury and arsenic, for example, since health effects may be associated with exposure to some of these compounds. By and large, effects of trace element emissions have been considered individually, without regard for possible interactions. To the extent that the relevant environmental pathways and health endpoints differ, this mode of analysis is appropriate. For example, arsenic is considered a carcinogen and mercury affects the brain. However, there may be compelling reasons to consider emissions of mercury (Hg) and selenium (Se) together: (1) Both Se and Hg are emitted from power plants primarily as vapors. (2) Hg and Se are both found in fish, which is the primary pathway for Hg health effects. (3) Se has been shown to suppress Hg methylation in aqueous systems, which is a necessary step for Hg health effects at current environmental concentrations. (4) Se is a trace element that is essential for health but that can also be toxic at high concentrations; it can thus have both beneficial and adverse health effects, depending on the dosage. This paper reviews some of the salient characteristics and interactions of the Hg-Se system, to consider the hypothesis that the effects of emissions of these compounds should be considered jointly.

Saroff, L. [Department of Energy, Washington, DC (United States); Lipfert, W.; Moskowitz, P.D. [Brookhaven National Lab., Upton, NY (United States). Dept. of Applied Science

1996-02-01T23:59:59.000Z

64

Corrosion Resistance of Zinc  

Science Conference Proceedings (OSTI)

Table 15 Compatibility of untreated zinc with various media...free Excellent Gas (a) Towns, natural, propane, butane Excellent Glycerine . . . Excellent Inks Printing Excellent Aqueous writing Not recommended Insecticides Dry Excellent In solution Not recommended Lubricants Mineral, acid free Excellent Organic Not recommended Paraffin . . . Excellent...

65

Zinc sulfide liquefaction catalyst  

DOE Patents (OSTI)

A process for the liquefaction of carbonaceous material, such as coal, is set forth wherein coal is liquefied in a catalytic solvent refining reaction wherein an activated zinc sulfide catalyst is utilized which is activated by hydrogenation in a coal derived process solvent in the absence of coal.

Garg, Diwakar (Macungie, PA)

1984-01-01T23:59:59.000Z

66

Doped zinc oxide microspheres  

DOE Patents (OSTI)

A new composition and method of making same for a doped zinc oxide microsphere and articles made therefrom for use in an electrical surge arrestor which has increased solid content, uniform grain size and is in the form of a gel. 4 figures.

Arnold, W.D. Jr.; Bond, W.D.; Lauf, R.J.

1993-12-14T23:59:59.000Z

67

Sources of Zinc Scrap  

Science Conference Proceedings (OSTI)

...and up to 1% Cu. Zinc die castings are generally small, from less than one ounce up to several pounds in weight. They are frequently found as components in complex assemblies such as in automobiles, appliances, and electronics. Separation of castings from these larger assemblies is difficult, as is the...

68

Zinc alkaline secondary battery  

SciTech Connect

A zinc alkaline secondary battery with improved service life in which a multi-layer separator is interposed between the negative and positive electrodes and the quantity of the alkaline electrolyte in the layer of the separator adjacent to the negative electrode is less than that of the electrolyte in the layer of the separator adjacent to the positive electrode.

Furukawa, N.; Nishizawa, N.

1983-03-29T23:59:59.000Z

69

Corrosion Resistance of Zinc  

Science Conference Proceedings (OSTI)

Table 15   Compatibility of untreated zinc with various media...Sulfur free Excellent Gas (a) Towns, natural, propane, butane Excellent Glycerine ? Excellent Inks Printing Excellent Aqueous writing Not recommended Insecticides Dry Excellent In solution Not recommended Lubricants Mineral, acid free Excellent Organic Not recommended Paraffin ? Excellent...

70

JV Task - 116 Selenium's Role in the Seafood Safety Issue  

SciTech Connect

Continuing studies under these three funded projects - (JV Task 77 The Health Implications of the Mercury-Selenium Interaction, JV Task 96 Investigating the Importance of the Mercury-Selenium Interaction, and JV Task 116 Selenium's Role in the Seafood Safety Issue) - were performed to determine the effects of different levels of dietary mercury and selenium on the growth and development of test animals, and related tissue analyses, to understand the protective benefits of dietary selenium in reference to low-level exposure to mercury. Maternal exposure to methylmercury from seafood has been found to cause neurodevelopmental harm in children. However, significant nutritional benefits will be lost if fish consumption is needlessly avoided. The results of these studies support the hypothesis that intracellular Se itself is the physiologically important biomolecule and that the harm of mercury toxicity arises when Hg abundance becomes great enough to bind a significant portion of intracellular Se in vulnerable tissues such as the brain. Formation of HgSe limits bioavailability of Se for synthesis of Se-dependent enzymes, particularly in brain tissues. When production of these enzymes is impaired, the loss of their numerous essential functions results in the signs and symptoms of Hg toxicity. The finding that one mole of Se protects against many moles of Hg indicates that its beneficial effect is not due to sequestration of mercury as HgSe but rather due to the biological activity of the Se. Therefore, the selenium content of seafoods must be considered along with their methylmercury contents in evaluating the effect of dietary exposure to mercury.

Nicholas Ralston; Laura Raymond

2009-03-30T23:59:59.000Z

71

Arsenic and Selenium Speciation in Fly Ash and Wastewater  

Science Conference Proceedings (OSTI)

The objective of the work is to predict As and Se behavior in pond wastewater based on coal and power plant characteristics so that utilities will have tools for selection of coals (and blends) that will allow them to meet applicable water quality regulations in the ash pond discharge. Arsenic and selenium were chosen as the focus of this work because the behavior of arsenic and selenium is not well correlated with pH in ash pond water, but with speciation of these oxyanions in the fly ash. Furthermore, ...

2005-03-28T23:59:59.000Z

72

Molten tin reprocessing of spent nuclear fuel elements  

DOE Patents (OSTI)

A method and apparatus for reprocessing spent nuclear fuel is described. Within a containment vessel, a solid plug of tin and nitride precipitates supports a circulating bath of liquid tin therein. Spent nuclear fuel is immersed in the liquid tin under an atmosphere of nitrogen, resulting in the formation of nitride precipitates. The layer of liquid tin and nitride precipitates which interfaces the plug is solidified and integrated with the plug. Part of the plug is melted, removing nitride precipitates from the containment vessel, while a portion of the plug remains solidified to support the liquid tin and nitride precipitates remaining in the containment vessel. The process is practiced numerous times until substantially all of the precipitated nitrides are removed from the containment vessel.

Heckman, Richard A. (Castro Valley, CA)

1983-01-01T23:59:59.000Z

73

J7, Copper Zinc Tin Sulfide Solar Cell Development by RF ...  

Science Conference Proceedings (OSTI)

L6, PECVD-SiN, Si or Si/Al2O3-Capped ED-Mode AlN/GaN Inverters Hide details for [

74

Active Zinc Oxide Production From Waste Zinc Powder  

Science Conference Proceedings (OSTI)

In this study, various quality of active zinc oxides containing up to 98 wt. ... Comparison of Microstructural Evolution of Nickel During Conventional and Spark...

75

Solderability perservative coatings: Electroless tin vs. organic azoles  

SciTech Connect

This paper compares the solderability performance and corrosions ion protection effectiveness of electroless tin coatings versus organic azole films after exposure to a series of humidity and thermal (lead-free solders) cycling conditions. The solderability of immersion tin is directly related to the tin oxide growth on the surface and is not affected by the formation of Sn-Cu intermetallic phases as long as the intermetallic phase is protected by a Sn layer. For a nominal tin thickness of 60{mu}inches, the typical thermal excursions associated with assembly are not sufficient to cause the intermetallic phase to consume the entire tin layer. Exposure to humidity at moderate to elevated temperatures promotes heavy tin oxide formation which leads to solderability loss. In contrast, thin azole films are more robust to humidity exposure; however upon heating in the presence of oxygen, they decompose and lead to severe solderability degradation. Evaluations of lead-free solder pastes for surface mount assembly applications indicate that immersion tin significantly improves the spreading of Sn:Ag and Sn:Bi alloys as compared to azole surface finishes.

Artaki, I.; Ray, U.; Jackson, A.M.; Gordon, H.M. [AT and T Bell Labs., Princeton, NJ (United States); Vianco, P.T. [Sandia National Labs., Albuquerque, NM (United States)

1993-07-01T23:59:59.000Z

76

Boiling Water Reactor Zinc Addition Sourcebook  

Science Conference Proceedings (OSTI)

Boiling water reactors (BWRs) have been injecting zinc into the primary coolant via the feedwater system for over 25 years to control primary system radiation fields. The zinc injection process has evolved since the initial application at the Hope Creek Nuclear Station in 1986. This evolution included transition from natural zinc oxide to depleted zinc oxide and from active zinc injection skids (pumped systems) to passive injection systems (zinc pellet beds). Also occurring were various ...

2013-11-15T23:59:59.000Z

77

Iron Control in Zinc Pressure Leach Processes  

Science Conference Proceedings (OSTI)

Consequently, the disposal of iron residues is an integral part of the design and operation of zinc refineries. Zinc has been recovered from sulfide concentrates...

78

Zinc Matrix Power Inc | Open Energy Information  

Open Energy Info (EERE)

Zinc Matrix Power Inc Jump to: navigation, search Name Zinc Matrix Power Inc Place Santa Barbara, California Zip 93101 Product Develops high-performance rechargeable alkaline...

79

Properties of dc magnetron reactively sputtered TiN  

Science Conference Proceedings (OSTI)

Titanium nitride is of interest for IC fabrication because of its excellent performance as a metallic diffusion barrier. TiN films have been deposited in a batch sputtering system equipped with dc magnetron cathodes

Jim Stimmell

1986-01-01T23:59:59.000Z

80

Aqueous speciation of selenium during its uptake by green algae Chlamydomonas reinhardtii.  

E-Print Network (OSTI)

??Selenium (Se) is a micronutrient, yet elevated Se can be toxic to aquatic organisms. The range of Se concentrations within which Se uptake goes from (more)

Zhang, Xu

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "zinc tin selenium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Precipitation in a lead calcium tin anode  

SciTech Connect

Samples from a hot rolled sheet of a tin and calcium bearing lead alloy were solution heat treated at 300 Degree-Sign C and cooled down to room temperature at different rates; these samples were left at room temperature to study natural precipitation of CaSn{sub 3} particles. The samples were aged for 45 days before analysing their microstructure, which was carried out in a scanning electron microscope using secondary and backscattered electron detectors. Selected X-ray spectra analyses were conducted to verify the nature of the precipitates. Images were taken at different magnifications in both modes of observation to locate the precipitates and record their position within the images and calculate the distance between them. Differential scanning calorimeter analyses were conducted on selected samples. It was found that the mechanical properties of the material correlate with the minimum average distance between precipitates, which is related to the average cooling rate from solution heat treatment. - Highlights: Black-Right-Pointing-Pointer The distance between precipitates in a lead alloy is recorded. Black-Right-Pointing-Pointer The relationship between the distance and the cooling rate is established. Black-Right-Pointing-Pointer It is found that the strengthening of the alloy depends on the distance between precipitates.

Perez-Gonzalez, Francisco A., E-mail: fco.aurelio@inbox.com [Facultad de Ingenieria Mecanica y Electrica, Universidad Autonoma de Nuevo Leon (Mexico); Centro de Innovacion, Investigacion y Desarrollo en Ingenieria y Tecnologia, Universidad Autonoma de Nuevo Leon (Mexico); Camurri, Carlos G., E-mail: ccamurri@udec.cl [Departamento de Ingenieria de Materiales, Universidad de Concepcion (Chile); Carrasco, Claudia A., E-mail: ccarrascoc@udec.cl [Departamento de Ingenieria de Materiales, Universidad de Concepcion (Chile); Colas, Rafael, E-mail: rafael.colas@uanl.edu.mx [Facultad de Ingenieria Mecanica y Electrica, Universidad Autonoma de Nuevo Leon (Mexico); Centro de Innovacion, Investigacion y Desarrollo en Ingenieria y Tecnologia, Universidad Autonoma de Nuevo Leon (Mexico)

2012-02-15T23:59:59.000Z

82

It's Elemental - The Element Zinc  

NLE Websites -- All DOE Office Websites (Extended Search)

Copper Copper Previous Element (Copper) The Periodic Table of Elements Next Element (Gallium) Gallium The Element Zinc [Click for Isotope Data] 30 Zn Zinc 65.38 Atomic Number: 30 Atomic Weight: 65.38 Melting Point: 692.68 K (419.53°C or 787.15°F) Boiling Point: 1180 K (907°C or 1665°F) Density: 7.134 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 4 Group Number: 12 Group Name: none What's in a name? From the German word zink. Say what? Zinc is pronounced as ZINK. History and Uses: Although zinc compounds have been used for at least 2,500 years in the production of brass, zinc wasn't recognized as a distinct element until much later. Metallic zinc was first produced in India sometime in the 1400s by heating the mineral calamine (ZnCO3) with wool. Zinc was rediscovered by

83

Experience with Zinc Injection in European PWRs  

Science Conference Proceedings (OSTI)

Zinc injection is an effective technique for lowering shutdown dose rates in pressurized water reactors (PWRs). This report compiles information about zinc injection experience at Siemens PWRs and compares the results with the use of zinc injection at U.S. PWRs. The plant data confirm that even low concentrations of zinc in the reactor water can indeed lower shutdown dose rates, but plants should make a concerted effort to inject zinc on a continuous basis to achieve the best results.

2002-11-01T23:59:59.000Z

84

Stabilized nickel-zinc battery  

SciTech Connect

An alkaline nickel-zinc cell which has (1) a nickel-nickel hydroxide cathode; (2) a zinc-zinc oxide anode containing (A) a corrosion inhibitor such as PBO, SNO2, Tl2O3, in(OH)3 or mixtures thereof; (B) a slight corrosion accelerator such as cdo, bi2o3, ga2o3, or mixtures thereof; and (C) a zinc active material; (3) a mass-transport separator; (4) an alkaline electrolyte; and (5) means for charging the cell with an interrupted current having a frequency of from more than zero to 16 hertz with a rest period of not less than 60 milliseconds. Another desirable feature is the use of a pressure-cutoff switch to terminate charging when the internal pressure of the cell reaches a selected value in the range of from 5 to 8 psig.

Himy, A.; Wagner, O.C.

1982-04-27T23:59:59.000Z

85

Specifications for Recycled Lead  

Science Conference Proceedings (OSTI)

...in lead are antimony, arsenic, bismuth, copper, nickel, silver, tin, and zinc. Recently, selenium and tellurium have been added as important impurities in the United States. Primary-lead companies generally produce the 99.99% Pb grade, whereas recyclers produce the 99.97% Pb grade. The major difference...

86

Zinc and Health: Current Status and Future Directions Zinc Transport in the Brain: Routes of Zinc Influx and Efflux in Neurons1,2  

E-Print Network (OSTI)

Zinc and Health: Current Status and Future Directions Zinc Transport in the Brain: Routes of Zinc and that mediate extracellular zinc toxicity and (3) a plasma membrane transporter potentially present in all of mechanism, is the transporter pathway. The kinetics of zinc uptake in cultured neurons under resting

87

The Antioxidant Vitamins C & EChapter 15 Vitamin E and Selenium Effects on Differential Gene  

Science Conference Proceedings (OSTI)

The Antioxidant Vitamins C & E Chapter 15 Vitamin E and Selenium Effects on Differential Gene Health Nutrition Biochemistry eChapters Health - Nutrition - Biochemistry Press Downloadable pdf of Chapter 15 Vitam

88

Lag and ghosting in a clinical flat-panel selenium digital mammography system  

Science Conference Proceedings (OSTI)

We present measurements of lag and ghosting in a FDA-approved digital mammography system that uses a dielectric/selenium based detector structure. Lag is the carryover of signal from a previous image, whereas ghosting is the reduction of sensitivity caused by previous exposure history of the detector. Data from six selenium units were acquired. For the type of selenium detector tested, and under typical clinical usage conditions, the lag was as high as 0.15% of source signal and the ghosting could be as high as 15%. The amount of lag and ghosting varied from unit to unit. Results were compared with data acquired on a phosphor-based full-field digital mammography system. Modifications in the technology of the selenium detectors appear to have resulted in a marked decrease in both lag and ghosting effects in more recent systems.

Bloomquist, Aili K.; Yaffe, Martin J.; Mawdsley, Gordon E.; Hunter, David M.; Beideck, Daniel J. [Sunnybrook and Women's College Health Sciences Centre, Toronto, Ontario M4N 3M5 (Canada); Fletcher Allan Health Care, University of Vermont, Burlington, Vermont 05401 (United States)

2006-08-15T23:59:59.000Z

89

Selenium hyperaccumulation offers protection from cell disruptor herbivores  

SciTech Connect

Hyperaccumulation, the rare capacity of certain plant species to accumulate toxic trace elements to levels several orders of magnitude higher than other species growing on the same site, is thought to be an elemental defense mechanism against herbivores and pathogens. Previous research has shown that selenium (Se) hyperaccumulation protects plants from a variety of herbivores and pathogens. Selenium hyperaccumulating plants sequester Se in discrete locations in the leaf periphery, making them potentially more susceptible to some herbivore feeding modes than others. In this study we investigate the protective function of Se in the Se hyperaccumulators Stanleya pinnata and Astragalus bisulcatus against two cell disrupting herbivores, the western flower thrips (Frankliniella occidentalis) and the two-spotted spider mite (Tetranychus urticae). Astragalus bisulcatus and S. pinnata with high Se concentrations (greater than 650 mg Se kg{sup -1}) were less subject to thrips herbivory than plants with low Se levels (less than 150 mg Se kg{sup -1}). Furthermore, in plants containing elevated Se levels, leaves with higher concentrations of Se suffered less herbivory than leaves with less Se. Spider mites also preferred to feed on low-Se A. bisulcatus and S. pinnata plants rather than high-Se plants. Spider mite populations on A. bisulcatus decreased after plants were given a higher concentration of Se. Interestingly, spider mites could colonize A. bisulcatus plants containing up to 200 mg Se kg{sup -1} dry weight, concentrations which are toxic to many other herbivores. Selenium distribution and speciation studies using microfocused X-ray fluorescence ({mu}XRF) mapping and Se K-edge X-ray absorption spectroscopy revealed that the spider mites accumulated primarily methylselenocysteine, the relatively non-toxic form of Se that is also the predominant form of Se in hyperaccumulators. This is the first reported study investigating the protective effect of hyperaccumulated Se against cell-disrupting herbivores. The finding that Se protected the two hyperaccumulator species from both cell disruptors lends further support to the elemental defense hypothesis and increases the number of herbivores and feeding modes against which Se has shown a protective effect. Because western flower thrips and two-spotted spider mites are widespread and economically important herbivores, the results from this study also have potential applications in agriculture or horticulture, and implications for the management of Se-rich crops.

Quinn, Colin F; Freeman, John L; Reynolds, Ray JB; Cappa, Jennifer J; Fakra, Sirine C; Marcus, Matthew A; Lindblom, Stormy D; Quinn, Erin K; Bennett, Lindsay E; Pilon-Smits, Elizabeth AH

2011-07-06T23:59:59.000Z

90

Modeling the behavior of selenium in Pulverized-Coal Combustion systems  

Science Conference Proceedings (OSTI)

The behavior of Se during coal combustion is different from other trace metals because of the high degree of vaporization and high vapor pressures of the oxide (SeO{sub 2}) in coal flue gas. In a coal-fired boiler, these gaseous oxides are absorbed on the fly ash surface in the convective section by a chemical reaction. The composition of the fly ash (and of the parent coal) as well as the time-temperature history in the boiler therefore influences the formation of selenium compounds on the surface of the fly ash. A model was created for interactions between selenium and fly ash post-combustion. The reaction mechanism assumed that iron reacts with selenium at temperatures above 1200 C and that calcium reacts with selenium at temperatures less than 800 C. The model also included competing reactions of SO{sub 2} with calcium and iron in the ash. Predicted selenium distributions in fly ash (concentration versus particle size) were compared against measurements from pilot-scale experiments for combustion of six coals, four bituminous and two low-rank coals. The model predicted the selenium distribution in the fly ash from the pilot-scale experiments reasonably well for six coals of different compositions. (author)

Senior, Constance; Otten, Brydger Van; Wendt, Jost O.L.; Sarofim, Adel [Reaction Engineering International, 77 W. 200 South, Salt Lake City, UT 84101 (United States)

2010-11-15T23:59:59.000Z

91

Conductive Polymer Binder-Enabled Cycling of Pure Tin Nanoparticle  

NLE Websites -- All DOE Office Websites (Extended Search)

Conductive Polymer Binder-Enabled Cycling of Pure Tin Nanoparticle Conductive Polymer Binder-Enabled Cycling of Pure Tin Nanoparticle Composite Anode Electrodes for a Lithium-Ion Battery Title Conductive Polymer Binder-Enabled Cycling of Pure Tin Nanoparticle Composite Anode Electrodes for a Lithium-Ion Battery Publication Type Journal Article Year of Publication 2013 Authors Xun, Shidi, Xiangyun Song, Vincent S. Battaglia, and Gao Liu Journal Journal of the Electrochemical Society Volume 160 Start Page A849 Issue 6 Pagination A849 - A855 Date Published 01/2013 ISSN 0013-4651 Abstract Pure tin (Sn) nanoparticles can be cycled in stable and high gravimetric capacity (>500 mAh/g) with a polyfluorene-type conductive polymer binder in composite electrodes. Crystalline Sn nanoparticles (<150 nanometers, nm) were used as anode materials in this study. The average diameter of Sn secondary particles is 270 nm, calculated based on BET surface area. The composite electrodes contain a conductive polymer binder that constitutes 2% to 10% of the material, without any conductive additives (e.g., acetylene black). The electrode containing the 5% conductive binder showed the best cycling performance, with a reversible capacity of 510 mAh/g. Crystallinity of Sn particles gradually degrades during cycling, and pulverization of particles was observed after long-term cycling, leading to the capacity fade. The conductive polymer binder shows advantages over other conventional binders, such as Poly(vinylidene difluoride) (PVDF) and carboxymethylcellulose (CMC) binders, because it can provide electrical conductivity and strong adhesion during Sn volume change.

92

Magnetism and spin transport studies on indium tin oxide  

E-Print Network (OSTI)

MAGNETISM AND SPIN TRANSPORT STUDIES ON INDIUM TIN OXIDE Ali Moraad Hakimi Darwin College University of Cambridge A dissertation submitted for the degree of Doctor of Philosophy at the University of Cambridge February 2011 In loving memory of my... Grandfathers, Cyrus and Peter Abstract This dissertation reports on a detailed systematic study of the investigation into using Indium Oxide based materials in next generation spin-transport electronic ap- plications. Initial studies focused on the optimisation...

Hakimi, Ali Moraad Heydar

2011-07-12T23:59:59.000Z

93

Method for the regeneration of spent molten zinc chloride  

DOE Patents (OSTI)

In a process for regenerating spent molten zinc chloride which has been used in the hydrocracking of coal or ash-containing polynuclear aromatic hydrocarbonaceous materials derived therefrom and which contains zinc chloride, zinc oxide, zinc oxide complexes and ash-containing carbonaceous residue, by incinerating the spent molten zinc chloride to vaporize the zinc chloride for subsequent condensation to produce a purified molten zinc chloride: an improvement comprising the use of clay in the incineration zone to suppress the vaporization of metals other than zinc. Optionally water is used in conjunction with the clay to further suppress the vaporization of metals other than zinc.

Zielke, Clyde W. (McMurray, PA); Rosenhoover, William A. (Pittsburgh, PA)

1981-01-01T23:59:59.000Z

94

Available Technologies: Aluminum-doped Zinc Oxide Nanoink  

Renewable Energy; Environmental Technologies. Monitoring and Imaging; Remediation; ... indium tin oxide while offering comparable optical and electronic properties.

95

Liquid Tin Anode Direct Coal Fuel Cell - CellTech Power  

NLE Websites -- All DOE Office Websites (Extended Search)

Liquid Tin Anode Direct Coal Liquid Tin Anode Direct Coal Fuel Cell-CellTech Power Background Direct carbon solid oxide fuel cells (SOFCs) offer a theoretical efficiency advantage over traditional SOFCs operating on gasified carbon (syngas). CellTech Power LLC (CellTech) has been developing a liquid tin anode (LTA) SOFC that can directly convert carbonaceous fuels including coal into electricity without gasification. One of the most significant impediments

96

Direct spark plasma erosion synthesis of tin and silicon alloy nano ...  

Science Conference Proceedings (OSTI)

However, silicon and tin must be reduced to the nano-level to mitigate pulverization from drastic volume changes during lithium insertion/extraction. Current...

97

MTF-1-Mediated Repression of the Zinc Transporter Zip10 Is Alleviated by Zinc Restriction  

E-Print Network (OSTI)

The regulation of cellular zinc uptake is a key process in the overall mechanism governing mammalian zinc homeostasis and how zinc participates in cellular functions. We analyzed the zinc transporters of the Zip family in both the brain and liver of zinc-deficient animals and found a large, significant increase in Zip10 expression. Additionally, Zip10 expression decreased in response to zinc repletion. Moreover, isolated mouse hepatocytes, AML12 hepatocytes, and Neuro 2A cells also respond differentially to zinc availability in vitro. Measurement of Zip10 hnRNA and actinomycin D inhibition studies indicate that Zip10 was transcriptionally regulated by zinc deficiency. Through luciferase promoter constructs and ChIP analysis, binding of MTF-1 to a metal response element located 17 bp downstream of the transcription start site was shown to be necessary for zinc-induced repression of Zip10. Furthermore, zinc-activated MTF-1 causes down-regulation of Zip10 transcription by physically blocking Pol II movement through the gene. Lastly, ZIP10 is localized to the plasma membrane of hepatocytes and neuro 2A cells. Collectively, these results reveal a novel repressive role for MTF-1 in the regulation of the Zip10 zinc transporter expression by pausing Pol II transcription. ZIP10 may have roles in control of zinc homeostasis in specific sites particularly those of the brain and liver. Within that context ZIP10 may act as an important survival mechanism during

Louis A. Lichten; Moon-suhn Ryu; Liang Guo; Jennifer Embury; Robert J. Cousins

2011-01-01T23:59:59.000Z

98

Direct Leaching Alternatives for Zinc Concentrates  

Science Conference Proceedings (OSTI)

Biosorption Characteristics of Pb(II) from Aqueous Solution onto Poplar Cotton Characterization of Aluminum Cathode Sheets Used for Zinc Electrowinning.

99

Zinc air battery development for electric vehicles  

DOE Green Energy (OSTI)

This report summarizes the results of research conducted during the sixteen month continuation of a program to develop rechargeable zinc-air batteries for electric vehicles. The zinc-air technology under development incorporates a metal foam substrate for the zinc electrode, with flow of electrolyte through the foam during battery operation. In this soluble'' zinc electrode the zincate discharge product dissolves completely in the electrolyte stream. Cycle testing at Lawrence Berkeley Laboratory, where the electrode was invented, and at MATSI showed that this approach avoids the zinc electrode shape change phenomenon. Further, electrolyte flow has been shown to be necessary to achieve significant cycle life (> 25 cycles) in this open system. Without it, water loss through the oxygen electrode results in high-resistance failure of the cell. The Phase I program, which focused entirely on the zinc electrode, elucidated the conditions necessary to increase electrode capacity from 75 to as much as 300 mAh/cm{sup 2}. By the end of the Phase I program over 500 cycles had accrued on one of the zinc-zinc half cells undergoing continuous cycle testing. The Phase II program continued the half cell cycle testing and separator development, further refined the foam preplate process, and launched into performance and cycle life testing of zinc-air cells.

Putt, R.A.; Merry, G.W. (MATSI, Inc., Atlanta, GA (United States))

1991-07-01T23:59:59.000Z

100

The marine biogeochemistry of zinc isotopes  

E-Print Network (OSTI)

Zinc (Zn) stable isotopes can record information about important oceanographic processes. This thesis presents data on Zn isotopes in anthropogenic materials, hydrothermal fluids and minerals, cultured marine phytoplankton, ...

John, Seth G

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "zinc tin selenium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Laboratory-scale evaluation of secondary alkaline zinc batteries...  

NLE Websites -- All DOE Office Websites (Extended Search)

Laboratory-scale evaluation of secondary alkaline zinc batteries for electric vehicles Title Laboratory-scale evaluation of secondary alkaline zinc batteries for electric vehicles...

102

The zinc electrode: Reactions and mechanisms  

DOE Green Energy (OSTI)

The zinc electrode in alkaline electrolyte is unusual in that supersaturated zincate solutions can form during discharge and spongy or mossy zinc deposits can form on charge at low overvoltages. This paper reports on in situ x-ray absorption (XAS) results on supersaturated zincate and on mossy deposits.

McBreen, J. [Brookhaven National Lab., Upton, NY (United States)

1993-12-31T23:59:59.000Z

103

Silicon-tin oxynitride glassy composition and use as anode for lithium-ion battery  

DOE Patents (OSTI)

Disclosed are silicon-tin oxynitride glassy compositions which are especially useful in the construction of anode material for thin-film electrochemical devices including rechargeable lithium-ion batteries, electrochromic mirrors, electrochromic windows, and actuators. Additional applications of silicon-tin oxynitride glassy compositions include optical fibers and optical waveguides.

Neudecker, Bernd J. (Knoxville, TN); Bates, John B. (Oak Ridge, TN)

2001-01-01T23:59:59.000Z

104

Investigation of post-annealing indium tin oxide for future electro-optical device application  

Science Conference Proceedings (OSTI)

The nanostructure transformation associated with electro-optical properties via post-annealing of indium tin oxide film (ITO) is investigated by increasing post-annealing temperature in ambient oxygen. Although oxygen vacancy and activation Sn ions contribute ... Keywords: Burstein-Moss effect, indium tin oxide film (ITO), oxygen vacancy, photoluminescence, post-annealing

Ching-Yuan Ho; Tse-Yi Tu; Chun-Chieh Wang; Yuan Kang

2011-05-01T23:59:59.000Z

105

Impact of TiN post-treatment on metal insulator metal capacitor performances  

Science Conference Proceedings (OSTI)

When deposited by chemical vapor deposition (CVD), TiN layers must be post-treated with N"2/H"2 plasma. Metal-insulator-metal (MIM) capacitors using CVD-TiN as electrodes and Al"2O"3 as insulator are studied from both electrical and physico-chemical ... Keywords: EELS analysis, Electrical characteristics, MIM capacitors, TiN post-treatment

A. Bajolet; J-P. Manceau; S. Bruyre; R. Clerc; M. Proust; N. Gaillard; J-C. Giraudin; P. Delpech; L. Monts; G. Ghibaudo

2006-11-01T23:59:59.000Z

106

Molten tin reprocessing of spent nuclear fuel elements. [Patent application; continuous process  

DOE Patents (OSTI)

A method and apparatus for reprocessing spent nuclear fuel is described. Within a containment vessel, a solid plug of tin and nitride precipitates supports a circulating bath of liquid tin therein. Spent nuclear fuel is immersed in the liquid tin under an atmosphere of nitrogen, resulting in the formation of nitride precipitates. The layer of liquid tin and nitride precipitates which interfaces the plug is solidified and integrated with the plug. Part of the plug is melted, removing nitride precipitates from the containment vessel, while a portion of the plug remains solidified to support te liquid tin and nitride precipitates remaining in the containment vessel. The process is practiced numerous times until substantially all of the precipitated nitrides are removed from the containment vessel.

Heckman, R.A.

1980-12-19T23:59:59.000Z

107

Determination of the toxicity, water-quality interactions, and biomagnification of selenium in aquatic food chains. Technical report for 15 August 1987-14 August 1989 (Final)  

Science Conference Proceedings (OSTI)

Ecological degradation of aquatic ecosystems associated with the presence of elevated concentrations of the trace element selenium has been of considerable scientific, governmental, and public concern. The increased flux of selenium into several aquatic ecosystems, due to anthropogenic activities, has resulted in death, teratogenesis, reproductive impairment and decreased populations in fish and waterfowl communities in the systems. Research is continuing on several investigations into the toxicity, bioaccumulation, transfer, and biotransformation of selenium in aquatic organisms and laboratory food chains. Initial studies were primarily concerned with the comparative acute and chronic toxicity, water-quality interactions, and toxicological interactions of several chemical species of selenium to a variety of aquatic organisms. Further research was directed towards the biotransformation, transfer, and subsequent bioaccumulation of selenium in simplified laboratory aquatic food chains. Studies on the transfer, bioaccumulation, and toxicity of selenium from dietary sources to consumers were conducted. The development of methodology for determining and quantifying the biochemical speciation of selenium in aquatic organisms was initiated.

Maier, K.J.; Ogle, R.S.; Maier, K.A.R.; Williams, M.J.; Malchow, D.

1989-08-14T23:59:59.000Z

108

Pulsed-magnetron-sputtered low-temperature indium tin oxide films for flat-panel display applications  

Science Conference Proceedings (OSTI)

In this paper, indium tin oxide (ITO) thin films were prepared by unipolar and bipolar direct current (DC)-pulsed magnetron sputtering in a mixture of argon and oxygen onto unheated glass substrates. The target of ITO with 10 wt.% tin is used. The influences ... Keywords: DC-pulsed magnetron sputtering, Indium tin oxide, electrical and optical properties

William J. Lee; Yean-Kuen Fang; Jyh-Jier Ho; Chin-Ying Chen; Rung-Ywan Tsai; Daoyang Huang; Fang C. Ho; H. W. Chou; C. C. Chen

2002-02-01T23:59:59.000Z

109

ZINC MITIGATION INTERIM REPORT - THERMODYNAMIC STUDY  

Science Conference Proceedings (OSTI)

An experimental program was initiated in order to develop and validate conditions that will effectively trap Zn vapors that are released during extraction. The proposed work is broken down into three tasks. The first task is to determine the effectiveness of various pore sizes of filter elements. The second task is to determine the effect of filter temperature on zinc vapor deposition. The final task is to determine whether the zinc vapors can be chemically bound. The approach for chemically binding the zinc vapors has two subtasks, the first is a review of literature and thermodynamic calculations and the second is an experimental approach using the best candidates. This report details the results of the thermodynamic calculations to determine feasibility of chemically binding the zinc vapors within the furnace module, specifically the lithium trap (1). A review of phase diagrams, literature, and thermodynamic calculations was conducted to determine if there are suitable materials to capture zinc vapor within the lithium trap of the extraction basket. While numerous elements exist that form compounds with zinc, many of these also form compounds with hydrogen or the water that is present in the TPBARs. This relatively comprehensive review of available data indicates that elemental cobalt and copper and molybdenum trioxide (MoO3) may have the requisite properties to capture zinc and yet not be adversely affected by the extraction gases and should be considered for testing.

Korinko, P.

2010-12-17T23:59:59.000Z

110

GIS INTERNET MAP SERVICE FOR DISPLAYING SELENIUM CONTAMINATION DATA IN THE SOUTHEASTERN IDAHO PHOSPHATE MINING RESOURCE AREA  

SciTech Connect

Selenium is present in waste rock/overburden that is removed during phosphate mining in southeastern Idaho. Waste rock piles or rock used during reclamation can be a source of selenium (and other metals) to streams and vegetation. Some instances (in 1996) of selenium toxicity in grazing sheep and horses caused public health and environmental concerns, leading to Idaho Department of Environmental Quality (DEQ) involvement. The Selenium Information System Project is a collaboration among the DEQ, the United States Forest Service (USFS), the Bureau of Land Management (BLM), the Idaho Mining Association (IMA), Idaho State University (ISU), and the Idaho National Laboratory (INL)2. The Selenium Information System is a centralized data repository for southeastern Idaho selenium data. The data repository combines information that was previously in numerous agency, mining company, and consultants databases and web sites. These data include selenium concentrations in soil, water, sediment, vegetation and other environmental media, as well as comprehensive mine information. The Idaho DEQ spearheaded a selenium area-wide investigation through voluntary agreements with the mining companies and interagency participants. The Selenium Information System contains the results of that area-wide investigation, and many other background documents. As studies are conducted and remedial action decisions are made the resulting data and documentation will be stored within the information system. Potential users of the information system are agency officials, students, lawmakers, mining company personnel, teachers, researchers, and the general public. The system, available from a central website, consists of a database that contains the area-wide sampling information and an ESRI ArcIMS map server. The user can easily acquire information pertaining to the area-wide study as well as the final area-wide report. Future work on this project includes creating custom tools to increase the simplicity of the website and increasing the amount of information available from site-specific studies at 15 mines.

Roger Mayes; Sera White; Randy Lee

2005-04-01T23:59:59.000Z

111

Rechargeable zinc cell with alkaline electrolyte which inhibits shape change in zinc electrode  

DOE Patents (OSTI)

An improved rechargeable zinc cell is described comprising a zinc electrode and another electrode such as, for example, a nickel-containing electrode, and having an electrolyte containing KOH and a combination of KF and K[sub 2]CO[sub 3] salts which inhibits shape change in the zinc electrode, i.e., the zinc electrode exhibits low shape change, resulting in an improved capacity retention of the cell over an number of charge-discharge cycles, while still maintaining high discharge rate characteristics. 8 figures.

Adler, T.C.; McLarnon, F.R.; Cairns, E.J.

1994-04-12T23:59:59.000Z

112

Rechargeable zinc cell with alkaline electrolyte which inhibits shape change in zinc electrode  

DOE Patents (OSTI)

An improved rechargeable zinc cell is described comprising a zinc electrode and another electrode such as, for example, a nickel-containing electrode, and having an electrolyte containing KOH and a combination of KF and K.sub.2 CO.sub.3 salts which inhibits shape change in the zinc electrode, i.e., the zinc electrode exhibits low shape change, resulting in an improved capacity retention of the cell over an number of charge-discharge cycles, while still maintaining high discharge rate characteristics.

Adler, Thomas C. (Berkeley, CA); McLarnon, Frank R. (Orinda, CA); Cairns, Elton J. (Walnut Creek, CA)

1994-01-01T23:59:59.000Z

113

Content and chemical form of mercury and selenium in Lake Ontario salmon and trout  

SciTech Connect

The content and chemical form of mercury and selenium were determined in the edible tissue of salmon (coho, chinook) and trout (lake, brown) taken offshore from Lake Ontario near Rochester, New York. For all species, total mercury content ranged from 0.3 to 0.8 micro g/g (fresh-weight), which is similar to concentrations commonly found in canned tuna. Most of the total mercury (63 to 79%) was present as methylmercury, the remainder being divalent inorganic mercury. For all species, 6 to 45% of the total selenium content was present as selenate (SeVI), the remainder being selenite (SeIV) and selenide (SEII). On a molar basis, total selenium content usually exceeded that of total mercury. Samples of smoked and unsmoked brown trout fillets were also examined. Based on the results of this study there is no immediate human health hazard from mercury and selenium. However, there is a need to report specific forms of these metals in Lake Ontario salmonid fish so that elevated concentrations can be better evaluated. 42 references, 1 figure, 4 tables.

Cappon, C.J.

1984-01-01T23:59:59.000Z

114

Selenium in Oklahoma ground water and soil. Quarterly report No. 6  

SciTech Connect

Selenium with a consumption of 2 liters per day (5). The objectives of this study are: (1) to determine the concentrations of Se in Oklahoma ground water and soil samples. (2) to map the geographical distribution of Se species in Oklahoma. (3) to relate groundwater depth, pH and geology with concentration of Se.

Atalay, A.; Vir Maggon, D.

1991-03-30T23:59:59.000Z

115

Speciation and Attenuation of Arsenic and Selenium at Coal Combustion By-Product Management Facilities  

Science Conference Proceedings (OSTI)

The overall objective of this project was to evaluate the impact of key constituents captured from power plant air streams (principally arsenic and selenium) on the disposal and utilization of coal combustion products (CCPs). Specific objectives of the project were: (1) to develop a comprehensive database of field leachate concentrations at a wide range of CCP management sites, including speciation of arsenic and selenium, and low-detection limit analyses for mercury; (2) to perform detailed evaluations of the release and attenuation of arsenic species at three CCP sites; and (3) to perform detailed evaluations of the release and attenuation of selenium species at three CCP sites. Each of these objectives was accomplished using a combination of field sampling and laboratory analysis and experimentation. All of the methods used and results obtained are contained in this report. For ease of use, the report is subdivided into three parts. Volume 1 contains methods and results for the field leachate characterization. Volume 2 contains methods and results for arsenic adsorption. Volume 3 contains methods and results for selenium adsorption.

K. Ladwig

2005-12-31T23:59:59.000Z

116

Spontaneous discharge in nickel-zinc accumulations  

SciTech Connect

The authors have examined discharge in nickel-zinc accumulators and monitored the gas. The measurements were made at room temperature with types having two layers of hydrated cellulose separators on the zinc electrodes and capron separators on the nickel oxide ones. There was a ratio of 2.5 between the active masses of the negative and positive electrodes. After three controlled cycles the accumulators were tested for spontaneous discharge. Then they determined the spontaneous discharge after use. The hydrogen, oxygen, and nitrogen in the gas were determined by a gasometric method in combination with gas chromatography. The zinc and the nickel oxide electrodes contribute to the self-discharge, which considerably exceeds the capacity loss determined from the hydrogen production. The zinc electrode corrosion indicated by the hydrogen production increases when the accumulator is operated. When a charged battery is stored, nitrogen is produced as well as hydrogen and oxygen. The nitrate accelerates the spontaneous discharge.

Dmitrenko, V.E.; Zubov, M.S.; Kuznetsova, L.N.; Okhlobystin, N.I.; Toguzov, B.M.; Tikhomirov, Yu.V.

1988-06-20T23:59:59.000Z

117

Exploring the structural basis for selenium/mercury antagonism in Allium fistulosum  

Science Conference Proceedings (OSTI)

While continuing efforts are devoted to studying the mutually protective effect of mercury and selenium in mammals, few studies have investigated the mercury-selenium antagonism in plants. In this study, we report the metabolic fate of mercury and selenium in Allium fistulosum (green onion) after supplementation with sodium selenite and mercuric chloride. Analysis of homogenized root extracts via capillary reversed phase chromatography coupled with inductively coupled plasma mass spectrometry (capRPLC-ICP-MS) suggests the formation of a mercury-selenium containing compound. Micro-focused synchrotron X-ray fluorescence mapping of freshly excised roots show Hg sequestered on the root surface and outlining individual root cells, while Se is more evenly distributed throughout the root. There are also discrete Hg-only, Se-only regions and an overall strong correlation between Hg and Se throughout the root. Analysis of the X-ray absorption near edge structure (XANES) spectra show a 'background' of methylselenocysteine within the root with discrete spots of SeO{sub 3}{sup 2-}, Se{sup 0} and solid HgSe on the root surface. Mercury outlining individual root cells is possibly binding to sulfhydryl groups or plasma membrane or cell wall proteins, and in some places reacting with reduced selenium in the rhizosphere to form a mercury(II) selenide species. Together with the formation of the root-bound mercury(II) selenide species, we also report on the formation of cinnabar (HgS) and Hg{sup 0} in the rhizosphere. The results presented herein shed light on the intricate chemical and biological processes occurring within the rhizosphere that influence Hg and Se bioavailability and will be instrumental in predicting the fate and assisting in the remediation of these metals in the environment and informing whether or not fruit and vegetable food selection from aerial plant compartments or roots from plants grown in Hg contaminated soils, are safe for consumption.

McNear, Jr., David H.; Afton, Scott E.; Caruso, Joseph A. (UCIN); (Kentucky)

2012-12-10T23:59:59.000Z

118

Extracellular Proteins Promote Zinc Sulfide Aggregation  

NLE Websites -- All DOE Office Websites (Extended Search)

Extracellular Proteins Promote Zinc Sulfide Aggregation Print Extracellular Proteins Promote Zinc Sulfide Aggregation Print Researchers from the ALS, Berkeley Lab's National Center for Electron Microscopy (NCEM), and Lawrence Livermore National Laboratory analyzed biofilm samples rich in zinc sulfide and dominated by sulfate-reducing bacteria, which were collected from lead-zinc mine waters. The researchers were curious about the relationship of the organic material and metals, particularly how organics affect mobility, and its potential for bioremediation. It is known that some organics promote aggregation. Amine-bearing molecules, for example, can organize sulfide nanoparticles into semiconductor nanowires. The research team used a series of imaging techniques and detectors to analyze aggregates of biogenic zinc sulfide nanocrystals in the biofilms. Their examination yielded excellent results and some surprises. They were able to prove that natural organic matter promotes dense aggregation of the zinc sulfide nanocrystals into much larger spheroids and that the organic matter is preserved in nanometer-scale pores in the spheroids. What was not expected was the presence of proteins in the spheroids, making them a key component in aggregation and an example of extracellular biomineralization.

119

Extracellular Proteins Promote Zinc Sulfide Aggregation  

NLE Websites -- All DOE Office Websites (Extended Search)

Extracellular Proteins Promote Extracellular Proteins Promote Zinc Sulfide Aggregation Extracellular Proteins Promote Zinc Sulfide Aggregation Print Wednesday, 26 September 2007 00:00 Researchers from the ALS, Berkeley Lab's National Center for Electron Microscopy (NCEM), and Lawrence Livermore National Laboratory analyzed biofilm samples rich in zinc sulfide and dominated by sulfate-reducing bacteria, which were collected from lead-zinc mine waters. The researchers were curious about the relationship of the organic material and metals, particularly how organics affect mobility, and its potential for bioremediation. It is known that some organics promote aggregation. Amine-bearing molecules, for example, can organize sulfide nanoparticles into semiconductor nanowires. The research team used a series of imaging techniques and detectors to analyze aggregates of biogenic zinc sulfide nanocrystals in the biofilms. Their examination yielded excellent results and some surprises. They were able to prove that natural organic matter promotes dense aggregation of the zinc sulfide nanocrystals into much larger spheroids and that the organic matter is preserved in nanometer-scale pores in the spheroids. What was not expected was the presence of proteins in the spheroids, making them a key component in aggregation and an example of extracellular biomineralization.

120

Extracellular Proteins Promote Zinc Sulfide Aggregation  

NLE Websites -- All DOE Office Websites (Extended Search)

Extracellular Proteins Promote Zinc Sulfide Aggregation Print Extracellular Proteins Promote Zinc Sulfide Aggregation Print Researchers from the ALS, Berkeley Lab's National Center for Electron Microscopy (NCEM), and Lawrence Livermore National Laboratory analyzed biofilm samples rich in zinc sulfide and dominated by sulfate-reducing bacteria, which were collected from lead-zinc mine waters. The researchers were curious about the relationship of the organic material and metals, particularly how organics affect mobility, and its potential for bioremediation. It is known that some organics promote aggregation. Amine-bearing molecules, for example, can organize sulfide nanoparticles into semiconductor nanowires. The research team used a series of imaging techniques and detectors to analyze aggregates of biogenic zinc sulfide nanocrystals in the biofilms. Their examination yielded excellent results and some surprises. They were able to prove that natural organic matter promotes dense aggregation of the zinc sulfide nanocrystals into much larger spheroids and that the organic matter is preserved in nanometer-scale pores in the spheroids. What was not expected was the presence of proteins in the spheroids, making them a key component in aggregation and an example of extracellular biomineralization.

Note: This page contains sample records for the topic "zinc tin selenium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Formation of zinc oxide films using submicron zinc particle dispersions  

SciTech Connect

The thermal oxidation of submicron metallic Zn particles was studied as a method to form nanostructured ZnO films. The particles used for this work were characterized by electron microscopy, x-ray diffraction and thermal analysis to evaluate the Zn-ZnO core shell structure, surface morphology, and oxidation characteristics. Significant nanostructural changes were observed for films annealed to 400 C or higher, where nanoflakes, nanoribbons, nanoneedles and nanorods were formed as a result of stress induced fractures arising in the ZnO outer shell due to differential thermal expansion between the metallic Zn core and the ZnO shell. Mass transport occurs through these defects due to the high vapor pressure for metallic Zn at temperatures above 230 C, whereupon the Zn vapor rapidly oxidizes in air to form the ZnO nanostructures. The Zn particles were also incorporated into zinc indium oxide precursor solutions to form thin film transistor test structures to evaluate the potential of forming nanostructured field effect sensors using simple solution processing.

Rajachidambaram, Meena Suhanya; Varga, Tamas; Kovarik, Libor; Sanghavi, Rahul P.; Shutthanandan, V.; Thevuthasan, Suntharampillai; Han, Seungyeol; Chang, Chih-hung; Herman, Gregory S.

2012-07-27T23:59:59.000Z

122

STUDIES OF MICROMORPHOLOGY AND CURRENT EFFICIENCY OF ZINC ELECTRODEPOSITED FROM FLOWING CHLORIDE ELECTROLYTES  

E-Print Network (OSTI)

the rechargeable zinc/chlorine and zinc/bromine batteriesthis section. The zinc/chlorine and zinc/bromine batteriesare high: 2.32 V for the chlorine (12) and tions are 1.85 V

Mc Vay, L.

2011-01-01T23:59:59.000Z

123

Zinc halogen battery electrolyte composition with lead additive  

SciTech Connect

This disclosure relates to a zinc halogen battery electrolyte composition containing an additive providing improved zinc-on-zinc recyclability. The improved electrolyte composition involves the use of a lead additive to inhibit undesirable irregular plating and reduce nodular or dendritic growth on the electrode surface. The lead-containing electrolyte composition of the present invention appears to influence not only the morphology of the base plate zinc, but also the morphology of the zinc-on-zinc replate. In addition, such lead-containing electrolyte compositions appear to reduce hydrogen formation.

Henriksen, Gary L. (Troy, MI)

1981-01-01T23:59:59.000Z

124

Fabrication of heterojunction solar cells by improved tin oxide deposition on insulating layer  

DOE Patents (OSTI)

Highly efficient tin oxide-silicon heterojunction solar cells are prepared by heating a silicon substrate, having an insulating layer thereon, to provide a substrate temperature in the range of about 300.degree. C. to about 400.degree. C. and thereafter spraying the so-heated substrate with a solution of tin tetrachloride in a organic ester boiling below about 250.degree. C. Preferably the insulating layer is naturally grown silicon oxide layer.

Feng, Tom (Morris Plains, NJ); Ghosh, Amal K. (New Providence, NJ)

1980-01-01T23:59:59.000Z

125

Zinc air refuelable battery: alternative zinc fuel morphologies and cell behavior  

DOE Green Energy (OSTI)

Multicell zinc/air batteries have been tested previously in the laboratory and as part of the propulsion system of an electric bus; cut zinc wire was used as the anode material. This battery is refueled by a hydraulic transport of 0.5-1 mm zinc particles into hoppers above each cell. We report an investigation concerning alternative zinc fuel morphologies, and energy losses associated with refueling and with overnight or prolonged standby. Three types of fuel pellets were fabricated, tested and compared with results for cut wire: spheres produced in a fluidized bed electrolysis cell; elongated particles produced by gas-atomization; and pellets produced by chopping 1 mm porous plates made of compacted zinc fines. Relative sizes of the particles and cell gap dimensions are critical. All three types transported within the cell 1553 and showed acceptable discharge characteristics, but a fluidized bed approach appears especially attractive for owner/user recovery operations.

Cooper, J.F.; Krueger, R.

1997-01-01T23:59:59.000Z

126

Tin City Long Range Radar Station Wind Farm | Open Energy Information  

Open Energy Info (EERE)

Tin City Long Range Radar Station Wind Farm Tin City Long Range Radar Station Wind Farm Jump to: navigation, search Name Tin City Long Range Radar Station Wind Farm Facility Tin City Long Range Radar Station Sector Wind energy Facility Type Community Wind Facility Status In Service Owner Tin City Long Range Radar Station Developer Tanadgusix Corp. Energy Purchaser Tin City Long Range Radar Station Location Nome AK Coordinates 65.559372°, -167.949686° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":65.559372,"lon":-167.949686,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

127

The influence of temperature and humidity on the wettability of immersion tin coated printed wiring boards  

SciTech Connect

This paper investigates the merits and drawbacks of immersion tin coatings as potential printed wiring board (PWB) surface finishes. Immersion tin films applied in various thicknesses (0.2 to 2 {mu}m) to different copper substrates were characterized relative to thermal stability and shelflife. Thermal excursions included those typical in mixed technology assembly processes. Exposure to temperature/humidity was varied from near ambient (35{degree}C/85%RH) to harsh (steam aging). A minimum thickness of {approximately}60{mu}in (1.5{mu}m) was determined to be critical for assembly operations involving multiple thermal excursions. Even though formation of Cu-Sn intermetallic compounds (IMC) is facile, at the copper-tin interface, these compounds do not adversely affect the soldering performance, as long as the IMC phase is protected by a tin surface layer. Immersion tin finishes are relatively stable to thermal exposure, but are readily oxidized in the presence of humidity. This oxide growth is directly responsible for solderability degradation. The underlying copper substrate was also found to have a significant impact on the thermal stability of tin films. An electroless copper substrate caused significantly more intermetallic formation, that resulted in poor solderability even under moderate temperature, humidity conditions.

Ray, U.; Artaki, I. [AT and T Bell Labs., Princeton, NJ (United States); Vianco, P.T. [Sandia National Labs., Albuquerque, NM (United States)

1993-12-31T23:59:59.000Z

128

Aspects of nitrogen surface chemistry relevant to TiN chemical vapor deposition  

Science Conference Proceedings (OSTI)

NH{sub 3} is an important component of many chemical vapor deposition (CVD) processes for TiN films, which are used for diffusion barriers and other applications in microelectronic circuits. In this study, the interaction of NH{sub 3} with TiN surfaces is examined with temperature programmed desorption (TPD) and Auger electron spectroscopy. NH{sub 3} has two adsorption states on TiN: a chemisorbed state and a multilayer state. A new method for analyzing TPD spectra in systems with slow pumping speeds yields activation energies for desorption for the two states of 24 kcal/mol and 7.3 kcal/mol, respectively. The sticking probability into the chemisorption state is {approximately}0.06. These results are discussed in the context of TiN CVD. In addition, the high temperature stability of TiN is investigated. TiN decomposes to its elements only after heating to 1300 K, showing that decomposition is unlikely to occur under CVD conditions.

Schulberg, M.T.; Allendorf, M.D.; Outka, D.A.

1996-08-01T23:59:59.000Z

129

Gated Conductance of Thin Indium Tin Oxide - The Simplest Transistor  

E-Print Network (OSTI)

Transistors are the fundamental building block of modern electronic devices. So far, all transistors are based on various types of semiconductor junctions. The most common bipolar-junction transistors and metal-oxide-semiconductor field-effect transistors contain p-n junctions to control the current, depending on applied biases across the junctions. Thin-film transistors need metal-semiconductor junctions for injecting and extracting electrons from their channels. Here, by coating a heavily-doped thin indium-tin-oxide (ITO) film through a shadow mask onto a biopolymer chitosan/ITO/glass substrate, we can have a high-performance junctionless transparent organic-inorganic hybrid thin film transistor. This could be the simplest transistor in the world, to our knowledge, not only in its structure, but also its fabrication process. In addition, the device performance is found to be greatly enhanced using a reinforced chitosan/SiO2 hybrid bilayer dielectric stack. Our results clearly show that this architecture can...

Jiang, Jie; Sun, Jia; Dou, Wei; Zhang, Qing

2012-01-01T23:59:59.000Z

130

Amino acid, lipid and red blood cell studies on selenium toxicity with the laboratory rat.  

SciTech Connect

The amino acid and lipid analysis on blood and liver and the amino acid analysis on urine gave irregular values for each determination. Therefore, the average values which were presented in the 1966 Technical Progress report (C00-1449-2) were not considered valid and were not submitted for publication. However, experiments on the in vivo conversion of 75 Se-labeled selenite-Se to urinary metabolites led to the observance of an unknown metabolite. This metabolite, which was different from the ordinary selenium analogues of sulfur, was designated as "U-1" (C00-1449-3). The use of the 59 Fe was involved in the study of the anemia of chronic selenium toxicity. The findings because of the labeled iron led to the conclusion that the anemia was from massive hemolysis (C00-1449-3).

Halverson, A W; Tsay, D -T; Triebwasser, K C; Whitehead, E I

1966-01-01T23:59:59.000Z

131

Electrically and Hydraulically Rechargeable Zinc-air Battery  

A secondary zinc air battery, which can be either eletrically or hydraulically recharged, is provided with an inventive metal ...

132

Chemists Measure Copper Levels in Zinc Oxide Nanowires  

Science Conference Proceedings (OSTI)

... Nikoobakht. Analysis of copper incorporation into zinc oxide nanowires. ACS Nano Articles ASAP, published online Jan. 12, 2008.

2012-10-17T23:59:59.000Z

133

Processing of Lead, Zinc, Copper and Nickel Concentrates  

Science Conference Proceedings (OSTI)

Abstract Scope, Processing of copper, zinc, lead and nickel concentrates is becoming more challenging due increasingly complex mineralogy. Smelters are ...

134

Cadmium zinc telluride substrate growth, characterization, and evaluation  

Science Conference Proceedings (OSTI)

Keywords: cadmium zinc telluride (CZT), chemical analysis, infrared focal plane arrays (INFRAs), single crystal growth, subsstrate defects, substrates

M. Kestigian; A. B. Bollong; J. J. Derby; H. L. Glass; K. Harris; H. L. Hettich; P. K. Liao; P. Mitra; P. W. Norton; H. Wadley

1999-06-01T23:59:59.000Z

135

Acid treatment removes zinc sulfide scale restriction  

Science Conference Proceedings (OSTI)

This paper reports that removal of zinc sulfide (ZnS) scale with acid restored an offshore Louisiana well's production to original rates. The zinc sulfide scale was determined to be in the near well bore area. The selected acid had been proven to control iron sulfide (FeS) scales in sour wells without causing harm to surface production equipment, tubing, and other downhole hardware. The successful removal of the blockage re-established previous production rates with a 105% increase in flowing tubing pressure. On production for a number of months, a high rate, high-pressure offshore well was experiencing unusually rapid pressure and rate declines. A small sample of the restrictive material was obtained during the wire line operations. The well was subsequently shut in while a laboratory analysis determined that zinc sulfide was the major component of the obstruction.

Biggs, K. (Kerr McGee Corp., Lafayette, LA (US)); Allison, D. (Otis Engineering Corp., Lafayette, LA (US)); Ford, W.G.F. (Halliburton Co., Duncan, OK (United States))

1992-08-31T23:59:59.000Z

136

Improvement of Plants for Selenium and Heavy Metal Phytoremediation Through Genetic Engineering  

Science Conference Proceedings (OSTI)

Phytoremediation -- the use of plants to remove, stabilize, or detoxify pollutants -- has proved very promising for the cleanup of trace elements from contaminated soil and water. Under the EPRI-Genetics Research Program, investigators successfully used genetic engineering to create seven genetically altered lines of plants with superior capacities for the phytoremediation of selenium (Se) and heavy metals, such as Molybdenum (Mo), Tungsten (W), and Cadmium (Cd). These transgenic plants are more tolerant...

1999-12-13T23:59:59.000Z

137

Effect of Ag thickness on electrical transport and optical properties of indium tin oxide-Ag-indium tin oxide multilayers  

SciTech Connect

We report the dependence of electronic and optical properties on the Ag thickness in transparent conductive indium tin oxide (ITO)-Ag-ITO (IMI) multilayer films deposited on polyethylene naphthalate flexible substrate by sputtering at room temperature. The electrical properties (such as carrier concentration, mobility, and resistivity) changed significantly with incorporation of Ag between the ITO layers. Comparison of sheet resistance of the IMI multilayers and the calculated sheet resistance of the Ag midlayer indicates that most of the conduction is through the Ag film. The critical thickness of Ag to form a continuous conducting layer is found to be 8 nm using electrical and optical analysis. A conduction mechanism is proposed to elucidate the mobility variation with increased Ag thickness. Carrier transport is limited by either interface scattering or grain-boundary scattering depending on the thickness of the Ag midlayer. Interface scattering is dominant for thinner (5.5-7 nm) Ag and grain-boundary scattering is dominant for thicker (8-10.5 nm) Ag midlayers. In addition, the effect of varying Ag midlayer thickness on transmittance behavior is also discussed. A figure of merit is used to compare performance of the IMI multilayer systems as a function of Ag thickness.

Indluru, A.; Alford, T. L. [School of Materials and Flexible Display Center, Arizona State University, Tempe, Arizona 85287 (United States)

2009-06-15T23:59:59.000Z

138

Regenerative zinc/air and zinc/ferricyanide batteries for stationary power applications  

DOE Green Energy (OSTI)

The authors report a novel configuration for a zinc-particle, packed-bed anode in which an open structure of high hydraulic permeability is maintained indefinitely in a cell with closely spaced walls by the formation of particle bridges and associated gaps. The configuration minimizes electrolyte pumping costs, allows rapid refueling and partial recharge, and provides for 100% zinc consumption. This approach benefits zinc/air fuel batteries by allowing nearly continuous operation and fuel recycle without commercial infrastructure; it benefits Zn/[Fe(CN){sub 6}]{sup {minus}3} batteries by eliminating shape-change and polarization problems found with planar anodes.

Cooper, J.F.; Keene, L.E.; Noring, J.; Maimoni, A.; Peterman, K.

1994-05-01T23:59:59.000Z

139

On-line coating of glass with tin oxide by atmospheric pressure chemical vapor deposition.  

SciTech Connect

Atmospheric pressure chemical vapor deposition (APCVD) of tin oxide is a very important manufacturing technique used in the production of low-emissivity glass. It is also the primary method used to provide wear-resistant coatings on glass containers. The complexity of these systems, which involve chemical reactions in both the gas phase and on the deposition surface, as well as complex fluid dynamics, makes process optimization and design of new coating reactors a very difficult task. In 2001 the U.S. Dept. of Energy Industrial Technologies Program Glass Industry of the Future Team funded a project to address the need for more accurate data concerning the tin oxide APCVD process. This report presents a case study of on-line APCVD using organometallic precursors, which are the primary reactants used in industrial coating processes. Research staff at Sandia National Laboratories in Livermore, CA, and the PPG Industries Glass Technology Center in Pittsburgh, PA collaborated to produce this work. In this report, we describe a detailed investigation of the factors controlling the growth of tin oxide films. The report begins with a discussion of the basic elements of the deposition chemistry, including gas-phase thermochemistry of tin species and mechanisms of chemical reactions involved in the decomposition of tin precursors. These results provide the basis for experimental investigations in which tin oxide growth rates were measured as a function of all major process variables. The experiments focused on growth from monobutyltintrichloride (MBTC) since this is one of the two primary precursors used industrially. There are almost no reliable growth-rate data available for this precursor. Robust models describing the growth rate as a function of these variables are derived from modeling of these data. Finally, the results are used to conduct computational fluid dynamic simulations of both pilot- and full-scale coating reactors. As a result, general conclusions are reached concerning the factors affecting the growth rate in on-line APCVD reactors. In addition, a substantial body of data was generated that can be used to model many different industrial tin oxide coating processes. These data include the most extensive compilation of thermochemistry for gas-phase tin-containing species as well as kinetic expressions describing tin oxide growth rates over a wide range of temperatures, pressures, and reactant concentrations.

Allendorf, Mark D.; Sopko, J.F. (PPF Industries, Pittsburgh, PA); Houf, William G.; Chae, Yong Kee; McDaniel, Anthony H.; Li, M. (PPF Industries, Pittsburgh, PA); McCamy, J.W. (PPF Industries, Pittsburgh, PA)

2006-11-01T23:59:59.000Z

140

Paraoccupational exposures to lead and tin carried by electric-cable splicers  

SciTech Connect

To test the hypothesis that electric-cable splicers contaminate their homes with lead and tin, nine splicers were matched with nine of their neighbors. House dust samples were collected in two areas within each home: a laundry room/dirty clothes area, and a composite sample from other areas in the house. Samples were analyzed by energy dispersive X-ray fluorescence for lead and tin (tin is a tracer to the occupational source of lead). The difference in the geometric mean lead concentrations in the laundry areas between the splicers' and neighbors' homes (1021 ppm and 390 ppm) was statistically significant (p < 0.025). The difference in concentrations from the other areas of the house (585 ppm and 329 ppm) was also significant (p < 0.05). Tin concentrations in house dust were very different between the two groups (p < 0.0005), suggesting that electric-cable splicers were contaminating their homes with lead and tin from work. Recommendations are included to prevent paraoccupational lead exposures by eliminating the pathways into the home. Another recommendation suggests that blood-lead levels be screened in children under the age of seven who live with electric-cable splicers.

Rinehart, R.D.; Yanagisawa, Y. (Harvard School of Public Health, Boston, MA (United States))

1993-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "zinc tin selenium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Rechargeable zinc cell with alkaline electrolyte which inhibits shape change in zinc electrode  

DOE Patents (OSTI)

An improved rechargeable zinc cell is described comprising a zinc electrode and another electrode such as, for example, a nickel-containing electrode, and having an electrolyte containing one or more hydroxides having the formula M(OH), one or more fluorides having the formula MF, and one or more carbonates having the formula M.sub.2 CO.sub.3, where M is a metal selected from the group consisting of alkali metals. The electrolyte inhibits shape change in the zinc electrode, i.e., the zinc electrode exhibits low shape change, resulting in an improved capacity retention of the cell over an number of charge-discharge cycles, while still maintaining high discharge rate characteristics.

Adler, Thomas C. (Berkeley, CA); McLarnon, Frank R. (Orinda, CA); Cairns, Elton J. (Walnut Creek, CA)

1995-01-01T23:59:59.000Z

142

It's Elemental - The Periodic Table of Elements  

NLE Websites -- All DOE Office Websites (Extended Search)

Selenium Bromine Krypton Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine...

143

Optical properties of TiN thin films close to the superconductor-insulator transition.  

Science Conference Proceedings (OSTI)

We present the intrinsic optical properties over a broad spectral range of TiN thin films deposited on an Si/SiO{sub 2} substrate. We analyze the measured reflectivity spectra of the film-substrate multilayer structure within a well-establish procedure based on the Fresnel equation and extract the real part of the optical conductivity of TiN. We identify the metallic contribution as well as the finite energy excitations and disentangle the spectral weight distribution among them. The absorption spectrum of TiN bears some similarities with the electrodynamic response observed in the normal state of the high-temperature superconductors. Particularly, a mid-infrared feature in the optical conductivity is quite reminiscent of a pseudogap-like excitation.

Pfuner, F.; Degiorgi, L.; Baturina, T. I.; Vinokur, V. M.; Baklanov, M. R.; Materials Science Division; ETH Zurich; Inst. Semiconductor Physics; IMEC Kapeldreef

2009-11-10T23:59:59.000Z

144

HYDROGEN OUTGASSING AND SURFACE PROPERTIES OF TIN COATED STAINLESS STEEL CHAMBERS.  

DOE Green Energy (OSTI)

The stainless steel vacuum chambers of the 248m accumulator ring of Spallation Neutron Source (SNS) are coated with {approx} 100 nm of titanium nitride (TiN) to reduce the secondary electron yield. The coating is produced by DC magnetron sputtering using a long cathode imbedded with permanent magnets. The outgassing rates of several SNS half-cell chambers were measured with and without TiN coating, and before and after in-situ bake. One potential benefit of a TiN coating is to serve as hydrogen permeation barrier that reduces the ultimate outgassing rate. By varying the coating parameters, films of different surface roughness were produced and analyzed by Auger electron spectroscopy, scanning electron microscopy and atomic force microscopy to illustrate the dependence of the outgassing on the film structure.

HE,P.; HSEUH,H.C.; MAPES,M.; TODD,R.; WEISS,D.; WILSON,D.

2002-11-11T23:59:59.000Z

145

State of the Art Power-in Tube Niobium-Tin Superconductors  

Science Conference Proceedings (OSTI)

Powder-in-Tube (PIT) processed Niobium-Tin wires are commercially manufactured for nearly three decades and have demonstrated a combination of very high current density (presently up to 2500 A mm{sup -2} non-Cu at 12 T and 4.2 K) with fine (35 {micro}m), well separated filaments. We review the developments that have led to the present state of the art PIT Niobium-Tin wires, discuss the wire manufacturing and A15 formation processes, and describe typical superconducting performance in relation to magnetic field and strain. We further highlight successful applications of PIT wires and conclude with an outlook on possibilities for further improvements in the performance of PIT Niobium-Tin wires.

Godeke, A.; Ouden, A. Den; Nijhuis, A.; ten Kate, H.H.J.

2008-06-01T23:59:59.000Z

146

Surface Composition, Work Function, and Electrochemical Characteristics of Gallium-Doped Zinc Oxide  

Science Conference Proceedings (OSTI)

Gallium-doped zinc oxide (GZO) possesses the electric conductivity, thermal stability, and earth abundance to be a promising transparent conductive oxide replacement for indium tin oxide electrodes in a number of molecular electronic devices, including organic solar cells and organic light emitting diodes. The surface chemistry of GZO is complex and dominated by the hydrolysis chemistry of ZnO, which influences the work function via charge transfer and band bending caused by adsorbates. A comprehensive characterization of the surface chemical composition and electrochemical properties of GZO electrodes is presented, using both solution and surface adsorbed redox probe molecules. The GZO surface is characterized using monochromatic X-ray photoelectron spectroscopy and ultraviolet photoelectron spectroscopy after the following pretreatments: (i) hydriodic acid etch, (ii) potassium hydroxide etch, (iii) RF oxygen plasma etching, and (iv) high-vacuum argon-ion sputtering. The O 1s spectra for the GZO electrodes have contributions from the stoichiometric oxide lattice, defects within the lattice, hydroxylated species, and carbonaceous impurities, with relative near-surface compositions varying with pretreatment. Solution etching procedures result in an increase of the work function and ionization potential of the GZO electrode, but yield different near surface Zn:Ga atomic ratios, which significantly influence charge transfer rates for a chemisorbed probe molecule. The near surface chemical composition is shown to be the dominant factor in controlling surface work function and significantly influences the rate of electron transfer to both solution and tethered probe molecules.

Ratcliff, E. L.; Sigdel, A. K.; Macech, M. R.; Nebesny, K.; Lee, P. A.; Ginley, D. S.; Armstrong, N. R.; Berry, J. J.

2012-06-30T23:59:59.000Z

147

Detection and classification of volatile organic compounds using Indium Tin Oxide sensor array and artificial neural network  

Science Conference Proceedings (OSTI)

This article reveals the novel approach of fabricating Indium Tin Oxide thin films grown on glass substrate at 648 K temperatures using direct evaporation method for detection of small concentration volatile organic compounds (VOCs) and their ... Keywords: ANNs, ITO thin films, VOC mixtures, VOCs, artificial neural networks, direct evaporation, indium tin oxide, sensor arrays, thin film sensors, volatile organic compounds

H. J. Pandya

2009-05-01T23:59:59.000Z

148

Copper-tin anodes for rechargeable lithium batteries : an example of the matrix effect in an intermetallic system.  

DOE Green Energy (OSTI)

Lithium batteries are typically constructed from a lithium cobalt oxide cathode and a carbon anode. We have investigated intermetallic anode materials based on tin, which can provide a high capacity at a slightly higher voltage (400 mV) than metallic lithium and thus reduce the safety concerns associated with the carbon anode. In particular, we have investigated the copper-tin system at around the composition Cu{sub 6}Sn{sub 5} and have determined the effect on cycling and capacity of electrodes with various ratios of copper to tin. Anode compositions that are slightly copper rich (Cu{sub 6}Sn{sub 4}) were found to exhibit greater utilization of the tin than those with the stoichiometric bronze ratio (Cu{sub 6}Sn{sub 5}) or those having a slight excess of tin (Cu{sub 6}Sn{sub 6}). The differences in electrochemical behavior are explained in terms of an inert matrix model.

Kepler, K. D.

1998-09-02T23:59:59.000Z

149

Thermal treatment for recovery of manganese and zinc from zinc-carbon and alkaline spent batteries  

SciTech Connect

Highlights: Black-Right-Pointing-Pointer We separated Zn from Mn in zinc-carbon and alkaline batteries after removal of Hg. Black-Right-Pointing-Pointer Almost total removal of Hg is achieved at low temperature in air. Black-Right-Pointing-Pointer Nitrogen atmosphere is needed to reduce zinc and to permit its volatilization. Black-Right-Pointing-Pointer A high grade Zn concentrate was obtained with a high recovery at 1000-1200 Degree-Sign C. Black-Right-Pointing-Pointer The grade of Mn in the residue was enhanced with complete recovery. - Abstract: The aim of this paper is the recovery of manganese and zinc from a mixture of zinc-carbon and alkaline spent batteries, containing 40.9% of Mn and 30.1% of Zn, after preliminary physical treatment followed by removal of mercury. Separation of the metals has been carried out on the basis of their different boiling points, being 357 Degree-Sign C and 906 Degree-Sign C the boiling point of mercury and zinc and 1564 Degree-Sign C the melting point of Mn{sub 2}O{sub 3}. Characterization by chemical analysis, TGA/DTA and X-ray powder diffraction of the mixture has been carried out after comminution sieving and shaking table treatment to remove the anodic collectors and most of chlorides contained in the mixture. The mixture has been roasted at various temperatures and resident times in a flow of air to set the best conditions to remove mercury that were 400 Degree-Sign C and 10 min. After that, the flow of air has been turned into a nitrogen one (inert atmosphere) and the temperatures raised, thus permitting the zinc oxide to be reduced to metallic zinc by the carbon present in the original mixture and recovered after volatilization as a high grade concentrate, while manganese was left in the residue. The recovery and the grade of the two metals, at 1000 Degree-Sign C and 30 min residence time, were 84% and 100% for zinc and 85% and 63% for manganese, respectively. The recovery of zinc increased to 99% with a grade of 97% at 1200 Degree-Sign C and 30 min residence time, while the recovery and grade of manganese were 86% and 87%, respectively, at that temperature. Moreover, the chlorinated compounds that could form by the combustion of the plastics contained in the spent batteries, are destroyed at the temperature required by the process.

Belardi, G. [Institute for Environmental Engineering and Geosciences (CNR) Area della Ricerca CNR, via Salaria km 29,300, Monterotondo, 00016 Rome (Italy); Lavecchia, R.; Medici, F. [Department of Chemical Engineering, Materials and Environment, Sapienza University of Rome, via Eudossiana 84, 00184 Rome (Italy); Piga, L., E-mail: luigi.piga@uniroma1.it [Department of Chemical Engineering, Materials and Environment, Sapienza University of Rome, via Eudossiana 84, 00184 Rome (Italy)

2012-10-15T23:59:59.000Z

150

Microstructure development in Nb3Sn(Ti) internal tin superconducting wire  

E-Print Network (OSTI)

in the inner and outer rings of the 26-bundle wire (left) and in the 85-bundle wire (right). The voids observed to identify the phases present and X-ray microtomography (XMT) to investigate the void volume and distribution tin [1], powder-in-tube (PIT) [2] and bronze processes [3]. In this study, two commercially produced

Elliott, James

151

Correlation between the Indium Tin Oxide morphology and the performances of polymer light-emitting diodes  

E-Print Network (OSTI)

: This paper reports on performance enhancement of polymer light-emitting diodes (PLEDs) based on poly(2,5-bis. Keywords : Polymer light emitting diode; Indium tin oxide; Atomic force microscopy; Rutherford backscattering spectroscopy 1. Introduction Polymer light-emitting diodes (PLEDs) have received worldwide

Paris-Sud XI, Université de

152

Reduction of the Casimir Force from Indium Tin Oxide Film by UV Treatment  

Science Conference Proceedings (OSTI)

A significant decrease in the magnitude of the Casimir force (from 21% to 35%) was observed after an indium tin oxide sample interacting with an Au sphere was subjected to the UV treatment. Measurements were performed by using an atomic force microscope in high vacuum. The experimental results are compared with theory and a hypothetical explanation for the observed phenomenon is proposed.

Chang, C.-C.; Banishev, A. A.; Mohideen, U. [Department of Physics and Astronomy, University of California, Riverside, California 92521 (United States); Klimchitskaya, G. L. [North-West Technical University, Millionnaya Street 5, St. Petersburg, 191065 (Russian Federation); Mostepanenko, V. M. [Noncommercial Partnership ''Scientific Instruments,'' Tverskaya Street 11, Moscow, 103905 (Russian Federation)

2011-08-26T23:59:59.000Z

153

Reduction of the Casimir force from indium tin oxide film by UV treatment  

E-Print Network (OSTI)

A significant decrease in the magnitude of the Casimir force (from 21% to 35%) was observed after an indium tin oxide (ITO) sample interacting with an Au sphere was subjected to the UV treatment. Measurements were performed by using an atomic force microscope (AFM) in high vacuum. The experimental results are compared with theory, and a hypothetical explanation for the observed phenomenon is proposed.

Chang, C C; Klimchitskaya, G L; Mostepanenko, V M; Mohideen, U

2011-01-01T23:59:59.000Z

154

Reduction of the Casimir force from indium tin oxide film by UV treatment  

E-Print Network (OSTI)

A significant decrease in the magnitude of the Casimir force (from 21% to 35%) was observed after an indium tin oxide (ITO) sample interacting with an Au sphere was subjected to the UV treatment. Measurements were performed by using an atomic force microscope (AFM) in high vacuum. The experimental results are compared with theory, and a hypothetical explanation for the observed phenomenon is proposed.

C. C. Chang; A. A. Banishev; G. L. Klimchitskaya; V. M. Mostepanenko; U. Mohideen

2011-08-03T23:59:59.000Z

155

Fluorescent chemosensors for exploring zinc metalloneurochemistry and detecting mercury in aqueous solution  

E-Print Network (OSTI)

Chapter 1. An Introduction to Zinc Metalloneurochemistry and Zinc Detection in Biology. This chapter presents an overview of zinc neurophysiology and pathology, which provides motivation for the design of new tools and ...

Nolan, Elizabeth M. (Elizabeth Marie), 1978-

2006-01-01T23:59:59.000Z

156

Infrared Emissivity of Tin upon Release of a 25 GPa Shock into a LiF Window  

SciTech Connect

We measured the emissivity of a tin sample at its interface with a lithium-fluoride window upon release of a 25 GPa shock wave from the tin into the window. Measurements were made over four wavelength bands between 1.2 and 5.4 ?m. Thermal emission backgrounds from the tin, glue, and lithium fluoride were successfully removed from the reflectance signals. Emissivity changes for the sample, which was initially nearly specular, were small except for the longest wavelength band, where uncertainties were high because of poor signal-to-noise ratio at that wavelength. A thin glue layer, which bonds the sample to the window, was found to heat from reverberations of the shock wave between the tin and the lithium fluoride. At approximately 3.4 ?m the thermal emission from the glue was large compared to the tin, allowing a good estimate of the glue temperature from the thermal radiance. The glue appears to remain slightly colder than the tin, thereby minimizing heat conduction into or out of the tin immediately after the shock passage.

Turley, W. D., Holtkamp, D. B., Marshall, B. R., Stevens, G. D., Veeser, L. R.

2011-11-01T23:59:59.000Z

157

Mechanical Pretreatment of Lead Based Alloy Anode for Zinc ...  

Science Conference Proceedings (OSTI)

Biosorption Characteristics of Pb(II) from Aqueous Solution onto Poplar Cotton Characterization of Aluminum Cathode Sheets Used for Zinc Electrowinning.

158

Zinc-catalyzed copolymerization of carbon dioxide and propylene oxide  

E-Print Network (OSTI)

The zinc-catalyzed copolymerization of carbon dioxide and propylene oxide, which is one of the promising reactions for the utilization of carbon dioxide, has been investigated from various aspects. Above all, considering that supercritical carbon dioxide has recently been paid attention in the field of extraction, separation, and reaction medium, its aptitude for both a reaction solvent and a reactant was examined in zinc glutarate-catalyzed reactions. As a result, it was proved that supercritical carbon dioxide was a suitable substitute for organic solvents in the copolymerization reactions. Great diffusivity of supercritical carbon dioxide into polymer segments was thought to promote carbon dioxide supply to the active sites of the zinc species and to afford alternating polycarbonate production. Low reaction temperature appeared to be advantageous to polycarbonate and cyclic carbonate formation. Apart from zinc glutarate catalyst whose detailed mechanistic studies were hard to perform due to its insolubility, some other zinc compounds were studied. A homogeneous catalyst, bis(ethyl fumarato)zinc, showed similar polycarbonate yield to zinc glutarate, and the method of the catalyst preparation affected its catalytic activity. Only a small amount of the catalyst was considered to be active in the copolymerization process even in the homogeneous systems. In the zinc dicarboxylate complexes, the carbon number between two carboxyl groups and the steric nature in the vicinity of the zinc atom might be important factors for the copolymerization catalysis.

Katsurao, Takumi

1994-01-01T23:59:59.000Z

159

Reduction Process Of Zinc From Concentrates With CO2 Reduced ...  

Science Conference Proceedings (OSTI)

Recoveries of >90% of Zinc, and reduced CO2 gas emission product are expected after evaluation. Proceedings Inclusion? Planned: A print-only volume...

160

Aluminum-doped Zinc Oxide Nanoink - Energy Innovation Portal  

Scientists at Berkeley Lab have developed a method for fabricating conductive aluminum-doped zinc oxide (AZO) nanocrystals that provide a lower cost, less toxic ...

Note: This page contains sample records for the topic "zinc tin selenium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Zinc air battery development for electric vehicles. Final report  

DOE Green Energy (OSTI)

This report summarizes the results of research conducted during the sixteen month continuation of a program to develop rechargeable zinc-air batteries for electric vehicles. The zinc-air technology under development incorporates a metal foam substrate for the zinc electrode, with flow of electrolyte through the foam during battery operation. In this ``soluble`` zinc electrode the zincate discharge product dissolves completely in the electrolyte stream. Cycle testing at Lawrence Berkeley Laboratory, where the electrode was invented, and at MATSI showed that this approach avoids the zinc electrode shape change phenomenon. Further, electrolyte flow has been shown to be necessary to achieve significant cycle life (> 25 cycles) in this open system. Without it, water loss through the oxygen electrode results in high-resistance failure of the cell. The Phase I program, which focused entirely on the zinc electrode, elucidated the conditions necessary to increase electrode capacity from 75 to as much as 300 mAh/cm{sup 2}. By the end of the Phase I program over 500 cycles had accrued on one of the zinc-zinc half cells undergoing continuous cycle testing. The Phase II program continued the half cell cycle testing and separator development, further refined the foam preplate process, and launched into performance and cycle life testing of zinc-air cells.

Putt, R.A.; Merry, G.W. [MATSI, Inc., Atlanta, GA (United States)

1991-07-01T23:59:59.000Z

162

Zinc Electrowinning Using Novel Rolled Pb-Ag-Ca Anodes  

Science Conference Proceedings (OSTI)

Aug 1, 2003 ... Since May 2001, industrial-scale tests have been carried out at two zinc refineries in North America in industrial electrowinning cells.

163

Dechlorination Thermodynamics of CuCl Residue from Zinc ...  

Science Conference Proceedings (OSTI)

Commissioning of a Second Cobalt Recovery Furnace at Nchanga Smelter .... Study of Dielectric Properties and Drying Characteristics on Zinc Alloy Power from...

164

Synthesis and Characterization of Nanocrystalline Nickel Zinc Oxide ...  

Science Conference Proceedings (OSTI)

Stochiometric amount of nickel nitrate and zinc nitrate were used to prepare the corresponding solution. Particles were synthesized by hydrogen reduction of the ...

165

On the Effects of Zinc and AlB  

Science Conference Proceedings (OSTI)

Presentation Title, On the Effects of Zinc and AlB2 Particles on Absorbed Impact ... on Mechanical Properties of Spark Plasma Sintered Nickel-CNT Composites.

166

Chromium-free Conversion Coating for Electroplated Zinc-nickel  

Science Conference Proceedings (OSTI)

Presentation Title, Chromium-free Conversion Coating for Electroplated Zinc- nickel. Author(s), Melissa L. Klingenberg, Clayton Drees, Elizabeth Berman,...

167

Novel electrolyte additives to enhance zinc electrode cycle life  

DOE Green Energy (OSTI)

Electrochemical power sources that utilize zinc electrodes possess many advantages. Zinc is abundantly available, benign, inexpensive, stable over a wide operating temperature range, and has a high oxidation potential. In spite of these advantageous characteristics, rechargeable electrochemical systems based on zinc chemistry have not found widespread use. The major disadvantages of zinc electrodes are that they have limited cycle life due to zinc slumping and zinc electrode shape changes in alkaline solutions resulting from the solubility of zincate (Zn(OH){sub 4}{sup 2-}) in these solutions. As a result, premature cell failure often results due to cell shorting caused by dendritic growth as well as zinc slumping. In this paper we describe the chemical and physical characteristics of electrolyte solutions employing additives, particularly for zinc based electrochemical systems. These electrolytes are prepared using the alkali metal salts of 1,3,5-phenyltrisulfonic acid in combination with potassium hydroxide. The alkali metal salts of the acid possess good thermal stability, good ionic conductivity, and have a wide electrochemical voltage window in aqueous systems. With these electrolyte solutions improved cycle life was achieved in Zn/NiOOH and Zn/AgO. Improved cycle life with this additive is attributed to decreased zincate solubility, resulting in reduced zinc slumping and electrode shape changes. In addition, increased shelf-life and reduced self-discharge were also observed in many alkaline power sources.

Doddapaneni, N.; Ingersoll, D.

1995-11-01T23:59:59.000Z

168

The Role of Ate Complexes in the Lithium-Sulfur, Lithium-Selenium and Lithium-Tellurium Exchange Reactions  

E-Print Network (OSTI)

The Role of Ate Complexes in the Lithium-Sulfur, Lithium-Selenium and Lithium-Tellurium Exchange/Se exchange was substantially faster than exchange of the lithium reagents with the ate complex. Therefore, these ate complexes are not on the actual Li/Se exchange pathway. Introduction. ± The lithium

Reich, Hans J.

169

Selenium Bioaccumulation in Stocked Fish as an Indicator of Fishery Potential in Pit Lakes on Reclaimed Coal Mines  

E-Print Network (OSTI)

on Reclaimed Coal Mines in Alberta, Canada L. L. Miller · J. B. Rasmussen · V. P. Palace · G. Sterling · A to selenium (Se) and other metals and metalloids in pit lakes formed by open pit coal mining in Tertiary (thermal coal) and in Cretaceous (metallurgical coal) bedrock. Juvenile hatchery rainbow trout

Hontela, Alice

170

Development of new sorbents to remove mercury and selenium from flue gas. Final report, September 1, 1993--August 31, 1994  

Science Conference Proceedings (OSTI)

Mercury (Hg) and selenium (Se) are two of the volatile trace metals in coal, which are often not captured by conventional gas clean up devices of coal-fired boilers. An alternative is to use sorbents to capture the volatile components of trace metals after coal combustion. In this project sorbent screening tests were performed in which ten sorbents were selected to remove metallic mercury in N{sub 2}. These sorbents included activated carbon, char prepared from Ohio No. 5 coal, molecular sieves, silica gel, aluminum oxide, hydrated lime, Wyoming bentonite, kaolin, and Amberite IR-120 (an ion-exchanger). The sorbents were selected based on published information and B&W`s experience on mercury removal. The promising sorbent was then selected and modified for detailed studies of removal of mercury and selenium compounds. The sorbents were tested in a bench-scale adsorption facility. A known amount of each sorbent was loaded in the column as a packed bed. A carrier gas was bubbled through the mercury and selenium compounds. The vaporized species were carried by the gas and went through the sorbent beds. The amount of mercury and selenium compounds captured by the sorbents was determined by atomic absorption. Results are discussed.

Shiao, S.Y. [Babcock and Wilcox Co., Alliance, OH (United States)

1995-02-01T23:59:59.000Z

171

Quantification, Localization, and Speciation of Selenium in Seeds of Canola and Two Mustard Species Compared to Seed-Meals Produced  

E-Print Network (OSTI)

Quantification, Localization, and Speciation of Selenium in Seeds of Canola and Two Mustard Species with Se. We report a chemical analysis of Se in Brassica seeds (canola, Indian mustard, and white mustard shoots of several Brassica species, canola (Brassica napus), Indian mustard (Brassica juncea), and white

172

Zinc ion and neutral emission from single crystal zinc oxide during 193-nm excimer laser exposure  

SciTech Connect

Mass resolved time-of-flight measurements on neutral zinc atoms and zinc ions show energetic ions and neutrals during 193-nm irradiation of single crystals of semiconducting zinc oxide. Typical Zn+ kinetic energies are 3-5 eV. At fluences (energy per unit area per pulse) below 200 mJ/cm2, the ion intensities (per laser pulse) decrease monotonically to low values with laser pulse number. The depletion kinetics change from exponential to second order near 50 mJ/cm2. We attribute this change to the annihilation of defects yielding Zn+ emission when Zn+ or other surface defects become mobile. At fluences between 200 and 300 mJ/cm2, Zn+ emission becomes more sustained due to defects created by the laser. In this same fluence range, we observe the onset of detectable neutral atomic zinc emission. These neutral atoms display Maxwell-Boltzmann kinetic energy distributions w th effective surface temperatures that approach 5000 K as the fluence is raised to 350 mJ/cm2. These high surface temperatures are remarkable given the low etch rates observed at these fluences, suggesting that heated layer is extremely thin. We propose emission mechanisms and experiments to resolve outstanding questions.

Kahn, E. H. [Washington State University; Langford, S. C. [Washington State University; Boatner, Lynn A [ORNL; Dickinson, J. T. [Washington State University

2011-01-01T23:59:59.000Z

173

Sulfidation and reduction of zinc titanate and zinc oxide sorbents for injection in gasifier exit ducts  

DOE Green Energy (OSTI)

The sulfidation reaction kinetics of fine particles of zinc titanate and zinc oxide with H{sub 2}S were studied in order to test the potential of the sorbent injection hot-gas desulfurization process. Fine sorbent particles with diameter between 0.3 and 60 {mu}m were sulfided with H{sub 2}S and/or reduced with H{sub 2} in a laminar flow reactor over the temperature range of 500-900{degrees}C. Sulfidation/reduction conversion was compared for different particle sizes and sorbents with various porosities and atomic ratios of Zn and Ti. In reduction of ZnO with H{sub 2} and without H{sub 2}S, significant amount of Zn was formed and vaporized, while the presence of H{sub 2}S suppressed elemental Zn formation. This suggests that H{sub 2}S may suppress the surface reduction of ZnO and/or gaseous Zn may react with H{sub 2}S homogeneously and form fine particles of ZnS. Formation and vaporization of elemental Zn from zinc titanate sorbents was slower than from zinc oxide with and without H{sub 2}S.

Ishikawa, K. [Tufts Univ., Medford, MA (United States). Dept. of Chemical Engineering]|[Kawasaki Heavy Industries Ltd., Akashi, Hyogo (Japan). Technical Inst.; Krueger, C.; Flytzani-Stephanopoulos, M. [Tufts Univ., Medford, MA (United States). Dept. of Chemical Engineering; Jl, W.; Higgins, R.J.; Bishop, B.A.; Goldsmith, R.L. [CeraMem Corp., Waltham, MA (United States)

1995-12-31T23:59:59.000Z

174

Energy level alignment at the interfaces between typical electrodes and nucleobases: Al/adenine/indium-tin-oxide and Al/thymine/indium-tin-oxide  

Science Conference Proceedings (OSTI)

We investigated the interfacial electronic structures of Al/adenine/indium-tin-oxide (ITO) and Al/thymine/ITO using in situ ultraviolet and x-ray photoemission spectroscopy and density functional theory calculations. Adenine shows both an interface dipole and level bending, whereas thymine shows only an interface dipole in contact with ITO. In addition, thymine possesses a larger ionization energy than adenine. These are understood with delocalized {pi} states confirmed with theoretical calculations. For the interface between nucleobases and Al, both nucleobases show a prominent reduction of the electron injection barrier from Al to each base in accordance with a downward level shift.

Lee, Younjoo; Lee, Hyunbok; Park, Soohyung; Yi, Yeonjin [Institute of Physics and Applied Physics, Yonsei University, 50 Yonsei-ro, Seodaemoon-gu, Seoul 120-749 (Korea, Republic of)

2012-12-03T23:59:59.000Z

175

Research on separators for alkaline zinc batteries. Final report  

Science Conference Proceedings (OSTI)

This project is concerned with the research and development of a hybrid separator as an improved battery separator in alkaline zinc secondary batteries. Particular emphasis has been directed toward increasing the cycle life of zinc electrodes by controlling the permselectivity of the separator.

Yeo, R.S.

1985-12-01T23:59:59.000Z

176

Attacking the Kad Network Peng Wang, James Tyra, Eric Chan-Tin, Tyson Malchow, Denis Foo Kune,  

E-Print Network (OSTI)

Attacking the Kad Network Peng Wang, James Tyra, Eric Chan-Tin, Tyson Malchow, Denis Foo Kune 55455 {pwang,tyra,dchantin,malchow,foo,hopper,kyd}@cs.umn.edu ABSTRACT The Kad network

Kim, Dae-Shik

177

Methods for chemical recovery of non-carrier-added radioactive tin from irradiated intermetallic Ti-Sb targets  

DOE Patents (OSTI)

The invention provides a method of chemical recovery of no-carrier-added radioactive tin (NCA radiotin) from intermetallide TiSb irradiated with accelerated charged particles. An irradiated sample of TiSb can be dissolved in acidic solutions. Antimony can be removed from the solution by extraction with dibutyl ether. Titanium in the form of peroxide can be separated from tin using chromatography on strong anion-exchange resin. In another embodiment NCA radiotin can be separated from iodide solution containing titanium by extraction with benzene, toluene or chloroform. NCA radiotin can be finally purified from the remaining antimony and other impurities using chromatography on silica gel. NCA tin-117m can be obtained from this process. NCA tin-117m can be used for labeling organic compounds and biological objects to be applied in medicine for imaging and therapy of various diseases.

Lapshina, Elena V. (Troitsk, RU); Zhuikov, Boris L. (Troitsk, RU); Srivastava, Suresh C. (Setauket, NY); Ermolaev, Stanislav V. (Obninsk, RU); Togaeva, Natalia R. (Obninsk, RU)

2012-01-17T23:59:59.000Z

178

Selenium fractionation and cycling in the intertidal zone of the Carquinez Strait. Annual Report. October 1, 1995 through December 31, 1996.  

E-Print Network (OSTI)

from areas more distant from refinery outfall are shown in Acollected adjacent to the refinery outfalls are shown in B.selenium (Se) by local oil refineries, San Joaquin Valley

Zawislanski, P.T.

2010-01-01T23:59:59.000Z

179

Zinc electrode shape change. 1; In situ monitoring  

SciTech Connect

This paper reports on zinc electrode shape change, the redistribution of zinc material over the electrode during repeated cycling, identified as one of the main life-limiting factors for alkaline nickel oxide/zinc secondary batteries. To investigate this phenomenon in situ, a radiotracer, {sup 65}Zn, is incorporated in the battery and its movement monitored during repeated cycling of the battery. The changes in the distribution of {sup 65}Zn over the electrode during battery operation are attributed to the displacement of radioactive zincate ions via the battery electrolyte. It is shown that the spatial distribution of {sup 65}Zn offers a reliable indication for the zinc material distribution over the electrode, provided an electrode with uniformly specific radioactivity is used in the measurements. Radiotracer experiments using zinc electrodes containing 2 weight percent HgO as an additive and uniformly labeled with {sup 203}Hg, have revealed that during battery cycling no substantial net transport of mercury species occurs.

Visschev, W.; Barendrecht, E.; Einerhand, R.E.F.; deGoeij, J.J.M. (Eindhoven University of Technology, 5600 MB Eindhoven (NL))

1991-01-01T23:59:59.000Z

180

EFFECTIVENESS OF COPPER AND BRONZE FOR ZINC CAPTURE  

SciTech Connect

A series of experiments was conducted to determine the efficacy of using copper and bronze sheet and screen under high vacuum conditions to capture zinc vapor. The experiments were conducted in a parametric manner using a fixed zinc vaporization temperature (350C) but varying the filter temperature from ambient to 550C. Consistent with previous work, metallic zinc was deposited at low temperatures, but the deposit was non?adherent. At an intermediate temperature range (350?450C), the deposit formed an alloy with both copper and bronze materials. At higher temperatures (> 500C) the zinc did not deposit on the surfaces likely due to its high vapor pressure. Additional testing to optimize the zinc 'getter' chemistry and surface condition is warranted.

Korinko, P. S.

2012-11-02T23:59:59.000Z

Note: This page contains sample records for the topic "zinc tin selenium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Defect structure of indium tin oxide and its relationship to conductivity  

DOE Green Energy (OSTI)

Doping In{sub 2}O{sub 3} with tin results in an improved transparent conducting oxide (TCO). Although indium tin oxide (ITO) is the most frequently used commercial TCO, its defect structure is still uncertain. Previously, its defect chemistry has been inferred based on the conductivity of the material. To directly study the defect structure of ITO, the authors prepared powders under different processing environments and performed neutron powder diffraction. Structural information was obtained by performing Rietveld analysis. The results include positions of the atoms, their thermal displacements, the fractional occupancy of the defect oxygen site, and the fractional occupancies of Sn on each of the two nonequivalent cation sites, showing a strong preference for the b site. These structural results are correlated with the measured electrical properties of the same samples.

Gonzalez, G. B.; Cohen, J. B.; Hwang, J.-H.; Mason, T. O.; Hodges, J. P.; Jorgensen, J. D.

2000-05-09T23:59:59.000Z

182

Nanopattern-stimulated superconductor-insulator transition in thin TiN films.  

SciTech Connect

We present the results of the comparative study of transport properties of continuous and nanoperforated TiN films, enabling us to separate the disorder and the geometry effects. Nanopatterning transforms a thin TiN film into an array of superconducting weak links and eo ipso stimulates the disorder- and magnetic-field-driven superconductor-to-insulator transitions, shifting both transitions to a lower degree of microscopic disorder. We observe magnetoresistance oscillations reflecting collective phase-frustration behaviour of the multiconnected superconducting weak link network in a wide range of temperatures. We find that nanopatterning enhances the role of the two-dimensional Coulomb interaction and changes the characteristic energies of the film on length scales significantly larger than the mean free path or the superconducting coherence length.

Baturina, T. I.; Vinokur, V. M.; Mironov, A. Yu.; Chtchelkatchev, N. M.; Nasimov, D. A.; Latyshev, A. V. (Materials Science Division); (A. V. Rzhanov Inst. Semoconductor Physics); (Russian Academy of Sciences)

2011-02-01T23:59:59.000Z

183

DC sputtered indium-tin oxide transparent cathode for organic light-emitting diodes  

E-Print Network (OSTI)

AbstractThe performance of top-emitting organic light-emitting diodes depends not just on the choice of the transparent cathodes but also on their techniques of formation. Compared to the damage induced by radio frequency sputtering of indium-tin oxide cathode, that induced by dc sputtering was verified to be less severe and relatively independent of the sputtering power. Consequently, a high dc sputtering power of 120 W could be employed to achieve a high deposition rate of 0.1 nm/s. Adequate emission efficiency was maintained, even with a relatively thin 7-nm copper (II) phthalocyanine buffer layer. Index TermsIndium-tin oxide, organic light-emitting diodes, sputtering, top-emission, transparent cathode. I.

Haiying Chen; Chengfeng Qiu; Man Wong; Hoi Sing Kwok

2003-01-01T23:59:59.000Z

184

Formation and evolution of self-organized Au nanorings on indium-tin-oxide surface  

Science Conference Proceedings (OSTI)

This work reports on the formation of Au nanoclusters and on their evolution in nanoring structures on indium-tin-oxide surface by sputtering deposition and annealing processes. The quantification of the characteristics of the nanorings (surface density, depth, height, and width) is performed by atomic force microscopy. The possibility to control these characteristics by tuning annealing temperature and time is demonstrated establishing relations which allow to set the process parameters to obtain nanostructures of desired morphological properties for various technological applications.

Ruffino, F.; Simone, F.; Grimaldi, M. G. [Dipartimento di Fisica e Astronomia, Universita di Catania, via S. Sofia 64, 95123 Catania (Italy); MATIS CNR-IMM, via S. Sofia 64, 95123 Catania (Italy); Crupi, I. [MATIS CNR-IMM, via S. Sofia 64, 95123 Catania (Italy)

2011-01-10T23:59:59.000Z

185

Disordered surface structure of an ultra-thin tin oxide film on Rh(100)  

SciTech Connect

The composition and structure of an ultra-thin tin oxide film on Rh(100), prepared by the deposition of a submonolayer of tin followed by annealing in an O{sub 2} atmosphere, were examined by a combination of low-energy electron diffraction (LEED), Auger electron spectroscopy, X-ray photoemission spectroscopy (XPS), scanning tunneling microscopy (STM), and ab initio calculations based on density functional theory (DFT). Although the LEED pattern exhibited c(2 x 8) spots clearly, a uniform periodicity of the c(2 x 8) unit cell was not observed in the STM images. The bright dots that were observed periodically in the STM image were similar to those of the ultra-thin Sn{sub 2}O{sub 3} film on Rh(111) and formed a zigzag arrangement with the numerous point and line defects. The XPS study revealed that the Sn 3d{sub 5/2} peak of the tin oxide film on Rh(100) showed a metallic state as well as an oxide state that was between the SnO{sub 2} and SnO states. The structural models, which were based on the Sn{sub 2}O{sub 3} structure on Rh(111), were determined using DFT total energy calculations. The simulated STM images of the two slightly different honeycomb-chain models well reproduced the zigzag arrangement in the STM image. The STM image and XPS spectrum were interpreted using a combination of the two models.

Zenkyu, R.; Tajima, D.; Yuhara, J. [Department of Materials, Physics and Energy Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, 464-8603 (Japan)

2012-03-15T23:59:59.000Z

186

Selenium Speciation in Biofilms from Granular Sludge Bed Reactors Used for Wastewater Treatment  

DOE Green Energy (OSTI)

Se K-edge XAFS spectra were collected for various model compounds of Se as well as for 3 biofilm samples from bioreactors used for Se-contaminated wastewater treatment. In the biofilm samples, Se is dominantly as Se(0) despite Se K-edge XANES spectroscopy cannot easily distinguish between elemental Se and Se(-I)-bearing selenides. EXAFS spectra indicate that Se is located within aperiodic domains, markedly different to these known in monoclinic red selenium. However, Se can well occur within nanodivided domains related to monoclinic red Se, as this form was optically observed at the rim of some sludges. Aqueous selenate is then efficiently bioreduced, under sulfate reducing and methanogenic conditions.

van Hullenbusch, Eric; /Marne la Vallee U.; Farges, Francois; /Stanford U., Geo. Environ. Sci. /Museum Natl. Hist. Natur., Paris; Lenz, Markus; Lens, Piet; /Wageningen U.; Brown, Gordon E., Jr.; /Stanford U., Geo. Environ. Sci. /SLAC, SSRL

2006-12-13T23:59:59.000Z

187

Transient and steady-state dark current mechanisms in amorphous selenium avalanche radiation detectors  

SciTech Connect

A theoretical model for describing bias-dependent transient and steady-state behaviors of dark current in amorphous selenium (a-Se) avalanche detector structures has been developed. The analytical model considers bulk thermal generation current from mid-gap sates, transient carrier depletion, and carrier injection from the electrodes incorporating avalanche multiplication. The proposed physics-based dark current model is compared with the published experimental results on three potential a-Se avalanche detector structures. The steady-state dark current is the minimum for the structures that have effective blocking layers for both holes and electrons. The transient decay time to reach a plateau decreases considerably with increasing electric field.

Kabir, M. Z.; Imam, Safayat-Al [Department of Electrical and Computer Engineering, Concordia University, 1455 Blvd. de Maisonneuve West, Montreal, Quebec H3G 1M8 (Canada)] [Department of Electrical and Computer Engineering, Concordia University, 1455 Blvd. de Maisonneuve West, Montreal, Quebec H3G 1M8 (Canada)

2013-04-15T23:59:59.000Z

188

Fabrication and characterization of flower-like zinc oxide for dye-sensitized solar cell photoanode  

Science Conference Proceedings (OSTI)

Zinc oxide porous film consists of nanoparticles which assemble forming flake-like particle is synthesised through pyrolitic of chemical bath deposition product. Zinc oxide film consists of nanoparticle around 20 nm with surface area of 58.6 m2/gram ... Keywords: chemical bath depostition, dye sensitized soalr cell, nanoparticle, porous film, zinc carbonate hydroxide, zinc oxide

H. Abdullah; N. P. Ariyanto; B. Yuliarto; S. Junaidi; Yap Chi Chin; Muhamad Yahaya; S. Shaari

2010-02-01T23:59:59.000Z

189

The Implications of selenium deficiency for wild herbivore conservation: a review  

Science Conference Proceedings (OSTI)

Selenium (Se) has been identified as an essential micronutrient in all animals. It is required at the most fundamental physiological level as a component of the selenoproteins containing the 21st amino acid, selenocysteine. Adequate levels of Se are vital to proper reproductive performance, bone metabolism, immune function and iodine metabolism. Yet, Se is a relatively rare element, and is often present at low concentrations in soil and vegetation. Selenium deficiencies are widespread in domestic stock and are unavoidable in some wildlife populations. This may be especially true for populations confined to high elevation ranges, or on areas with granitic bedrock with low Se content, or that have lost access to Se-containing parts of their ranges such as mineral licks or low-elevation winter range. The condition may be exacerbated by increased levels of oxidative stress. Because our understanding of Se as a micronutrient is relatively new, many wildlife managers are unaware of the elements importance in physiology and population dynamics. Severe deficiency results in obvious symptoms such as white muscle disease. However, more frequently, deficiency may be chronic and subclinical. Individuals then display no obvious signs of malady, yet performance suffers until their populations decline without apparent cause. While mysterious population declines are not always due to Se deficiency, the wildlife manager should be aware of the possibility. Therefore, this review presents not only a summary of the wildlife literature regarding Se nutrition, but also a comprehensive look at the role of Se in mammalian physiology, and the behavior of this important element in the environment. Finally, the role of the biogeochemical Se cycle is discussed, and evidence is provided that the levels of available Se in the environment are decreasing while physiological demands often are increasing.

Werner T. Flueck; J.M. Smith Flueck; J. Mionczynski; B.J. Mincher

2012-07-01T23:59:59.000Z

190

Copper and Zinc Metallation Status of Copper Zinc Superoxide Dismutase form Amyotrophic Lateral Sclerosis Transgenic Mice  

Science Conference Proceedings (OSTI)

Mutations in the metalloenzyme copper-zinc superoxide dismutase (SOD1) cause one form of familial amyotrophic lateral sclerosis (ALS), and metals are suspected to play a pivotal role in ALS pathology. To learn more about metals in ALS, we determined the metallation states of human wild-type or mutant (G37R, G93A, and H46R/H48Q) SOD1 proteins from SOD1-ALS transgenic mice spinal cords. SOD1 was gently extracted from spinal cord and separated into insoluble (aggregated) and soluble (supernatant) fractions, and then metallation states were determined by HPLC inductively coupled plasma MS. Insoluble SOD1-rich fractions were not enriched in copper and zinc. However, the soluble mutant and WT SOD1s were highly metallated except for the metal-binding-region mutant H46R/H48Q, which did not bind any copper. Due to the stability conferred by high metallation of G37R and G93A, it is unlikely that these soluble SOD1s are prone to aggregation in vivo, supporting the hypothesis that immature nascent SOD1 is the substrate for aggregation. We also investigated the effect of SOD1 overexpression and disease on metal homeostasis in spinal cord cross-sections of SOD1-ALS mice using synchrotron-based x-ray fluorescence microscopy. In each mouse genotype, except for the H46R/H48Q mouse, we found a redistribution of copper between gray and white matters correlated to areas of high SOD1. Interestingly, a disease-specific increase of zinc was observed in the white matter for all mutant SOD1 mice. Together these data provide a picture of copper and zinc in the cell as well as highlight the importance of these metals in understanding SOD1-ALS pathology.

Lelie, H.L.; Miller, L.; Liba, A.; Bourassa, M.W.; Chattopadhyay, M.; Chan, P.K.; Gralla, E.B.; Borchelt, D.R.; et al

2010-09-24T23:59:59.000Z

191

Regeneration of zinc halide catalyst used in the hydrocracking of polynuclear hydrocarbons  

DOE Patents (OSTI)

Improved recovery of spent molten zinc halide hydro-cracking catalyst is achieved in the oxidative vapor phase regeneration thereof by selective treatment of the zinc oxide carried over by the effluent vapors from the regeneration zone with hydrogen halide gas under conditions favoring the reaction of the zinc oxide with the hydrogen halide, whereby regenerated zinc halide is recovered in a solids-free state with little loss of zinc values.

Gorin, Everett (San Rafael, CA)

1978-01-01T23:59:59.000Z

192

Pressurized Water Reactor Zinc Application: Data Analysis and Evaluation of Primary Chemistry Responses  

Science Conference Proceedings (OSTI)

The Electric Power Research Institute (EPRI) Pressurized Water Reactor Zinc Application Users Group (PWR ZUG) facilitates and improves the use of zinc injection in PWR primary coolant systems by assisting in the evaluation of zinc injection performance; documentation of lessons learned; communication of information on zinc injection qualification, monitoring, and operating experience; and review of zinc application effectiveness regarding primary water stress corrosion cracking (PWSCC) and radiation fiel...

2010-08-15T23:59:59.000Z

193

Testing of a refuelable zinc/air bus battery  

DOE Green Energy (OSTI)

We report tests of a refuelable zinc/air battery of modular, bipolar-cell design, intended for fleet electric busses and vans. The stack consists of twelve 250-cm{sup 2} cells built of two units: (1) a copper-clad glass-reinforced epoxy board supporting anode and cathode current collectors, and (2) polymer frame providing for air- and electrolyte distribution and zinc fuel storage. The stack was refueled in 4 min. by a hydraulic transfer of zinc particles entrained in solution flow.

Cooper, J.F.; Fleming, D.; Koopman, R.; Hargrove, D.; Maimoni, A.; Peterman, K.

1995-02-22T23:59:59.000Z

194

Cadmium zinc sulfide by solution growth  

SciTech Connect

A process for depositing thin layers of a II-VI compound cadmium zinc sulfide (CdZnS) by an aqueous solution growth technique with quality suitable for high efficiency photovoltaic or other devices which can benefit from the band edge shift resulting from the inclusion of Zn in the sulfide. A first solution comprising CdCl.sub.2 2.5H.sub.2 O, NH.sub.4 Cl, NH.sub.4 OH and ZnCl.sub.2, and a second solution comprising thiourea ((NH.sub.2).sub.2 CS) are combined and placed in a deposition cell, along with a substrate to form a thin i.e. 10 nm film of CdZnS on the substrate. This process can be sequentially repeated with to achieve deposition of independent multiple layers having different Zn concentrations.

Chen, Wen S. (Seattle, WA)

1992-05-12T23:59:59.000Z

195

Selenium Accumulation, Distribution, and Speciation in Spineless Prickly Pear Cactus: A Drought- and Salt-Tolerant, Selenium-Enriched Nutraceutical Fruit Crop for Biofortified Foods  

SciTech Connect

The organ-specific accumulation, spatial distribution, and chemical speciation of selenium (Se) were previously unknown for any species of cactus. We investigated Se in Opuntia ficus-indica using inductively coupled plasma mass spectrometry, microfocused x-ray fluorescence elemental and chemical mapping ({micro}XRF), Se K-edge x-ray absorption near-edge structure (XANES) spectroscopy, and liquid chromatography-mass spectrometry (LC-MS). {micro}XRF showed Se concentrated inside small conic, vestigial leaves (cladode tips), the cladode vasculature, and the seed embryos. Se K-edge XANES demonstrated that approximately 96% of total Se in cladode, fruit juice, fruit pulp, and seed is carbon-Se-carbon (C-Se-C). Micro and bulk XANES analysis showed that cladode tips contained both selenate and C-Se-C forms. Inductively coupled plasma mass spectrometry quantification of Se in high-performance liquid chromatography fractions followed by LC-MS structural identification showed selenocystathionine-to-selenomethionine (SeMet) ratios of 75:25, 71:29, and 32:68, respectively in cladode, fruit, and seed. Enzymatic digestions and subsequent analysis confirmed that Se was mainly present in a 'free' nonproteinaceous form inside cladode and fruit, while in the seed, Se was incorporated into proteins associated with lipids. {micro}XRF chemical mapping illuminated the specific location of Se reduction and assimilation from selenate accumulated in the cladode tips into the two LC-MS-identified C-Se-C forms before they were transported into the cladode mesophyll. We conclude that Opuntia is a secondary Se-accumulating plant whose fruit and cladode contain mostly free selenocystathionine and SeMet, while seeds contain mainly SeMet in protein. When eaten, the organic Se forms in Opuntia fruit, cladode, and seed may improve health, increase Se mineral nutrition, and help prevent multiple human cancers.

Banuelos, Gary S.; Fakra, Sirine C.; Walse, Spencer S.; Marcus, Matthew A.; Yang, Soo In; Pickering, Ingrid J.; Pilon-Smits, Elizabeth A.H.; Freeman, John L.

2011-07-01T23:59:59.000Z

196

JV Task 124 - Understanding Multi-Interactions of SO3, Mercury, Selenium, and Arsenic in Illinois Coal Flue Gas  

Science Conference Proceedings (OSTI)

This project consisted of pilot-scale combustion testing with a representative Illinois basin coal to explore the multi-interactions of SO{sub 3}, mercury, selenium and arsenic. The parameters investigated for SO{sub 3} and mercury interactions included different flue gas conditions, i.e., temperature, moisture content, and particulate alkali content, both with and without activated carbon injection for mercury control. Measurements were also made to track the transformation of selenium and arsenic partitioning as a function of flue gas temperature through the system. The results from the mercury-SO{sub 3} testing support the concept that SO{sub 3} vapor is the predominant factor that impedes efficient mercury removal with activated carbon in an Illinois coal flue gas, while H{sub 2}SO{sub 4} aerosol has less impact on activated carbon injection performance. Injection of a suitably mobile and reactive additives such as sodium- or calcium-based sorbents was the most effective strategy tested to mitigate the effect of SO{sub 3}. Transformation measurements indicate a significant fraction of selenium was associated with the vapor phase at the electrostatic precipitator inlet temperature. Arsenic was primarily particulate-bound and should be captured effectively with existing particulate control technology.

Ye Zhuang; Christopher Martin; John Pavlish

2009-03-31T23:59:59.000Z

197

Biological Properties of Zinc Oxide-Coated Anodized Aluminum Oxide  

Science Conference Proceedings (OSTI)

We used agar diffusion assays to evaluate the activity of zinc oxide-coated ... Zirconia Stabilisation Nano-Confined by Using Electroless Nickel Cladding .... Metal Oxide Nanofibers Produced by a ForceSpinning Method for Battery Electrodes.

198

AN INVENTORY OF PHOTOGRAPHS OF ZINC ELECTRODEPOSITED FROM ACID ELECTROLYTES  

E-Print Network (OSTI)

for publication AN INVENTORY OF PHOTOGRAPHS OF ZINCemployer. LBL-16601 AN INVENTORY OF PHOTOGRAPHS OF ZINCNo. DE-AC03-76SF00098 AN INVENTORY OF PHOTOGRAPHS OF ZINC

Faltemier, J.L.

2011-01-01T23:59:59.000Z

199

Spouted Bed Electrowinning of Zinc from Chloride Electrolytes  

Science Conference Proceedings (OSTI)

Aug 1, 2000 ... Current efficiencies, for the cell with the SBE, have been as high as 90% and DC energy consumption as Iow as 2.8 kWh/kg zinc deposited.

200

Determination of the solubility of tin indium oxide using in situ and ex x-ray diffraction  

SciTech Connect

A novel approach to determine the thermodynamic solubility of tin in indium oxide via the exsolution from tin overdoped nano-ITO powders is presented. High-energy, in situ and ex situ synchrotron X-ray diffraction was utilized to study the solubility limit at temperatures ranging from 900 C to 1375 C. The tin exsolution from overdoped nanopowders and the formation of In{sub 4}Sn{sub 3}O{sub 12} were observed in situ during the first 4-48 h of high-temperature treatment. Samples annealed between 900 C and 1175 C were also studied ex situ with heat treatments for up to 2060 h. Structural results obtained from Rietveld analysis include compositional phase analysis, atomic positions, and lattice parameters. The tin solubility in In{sub 2}O{sub 3} was determined using the phase analysis compositions from X-ray diffraction and the elemental compositions obtained from X-ray fluorescence. Experimental complications that can lead to incorrect tin solubility values in the literature are discussed.

Gonzalez, G. B.; Mason, T. O.; Okasinski, J. S.; Buslaps, T.; Honkimaki, V. (X-Ray Science Division); (DePaul Univ.); (Northwestern Univ.); (European Synchrotron Radiation Facility, Grenoble, France)

2012-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "zinc tin selenium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Overcoming Solubility Limitations to Zinc Addition in Pressurized Water Reactors  

Science Conference Proceedings (OSTI)

Zinc addition to the reactor coolant system (RCS) of a pressurized water reactor (PWR) is being used for dose rate reduction and primary water stress corrosion cracking (PWSCC) mitigation. This report summarizes results of aqueous zinc oxide solubility experiments from 150 to 350 degrees Celsius (302 to 662 degrees Fahrenheit). These experiments were performed to develop quantitative models of solubility and aqueous-phase solute speciation behavior as functions of temperature, pH, and solution compositio...

2001-11-29T23:59:59.000Z

202

Pressurized Water Reactor Primary Zinc Application Sourcebook, Revision 1  

Science Conference Proceedings (OSTI)

Utilities continually strive to optimize core design, address primary system material issues, and minimize dose impact on plant personnel. To meet these challenges, the Electric Power Research Institute (EPRI), Westinghouse, and Southern Nuclear-Plant Farley began zinc injection in 1994 for mitigation of primary water stress corrosion cracking (PWSCC) and radiation field reductions. Additional information from industry research continues to show the beneficial impact of zinc injection on radiation fields...

2012-07-13T23:59:59.000Z

203

The effects of alcohol use on zinc status  

E-Print Network (OSTI)

Alcohol consumption has been shown to have adverse affects on bone growth and maintenance, although the mechanism has not been elucidated. The objective of this research was to look at the relationship between zinc and alcohol as a possible mechanism for the negative effects of ethanol consumption on bone health. Five studies were performed in order to analyze the effects of different types of alcohol consumption on female Sprague-Dawley rats of various ages. The animals were fed one of three diets (alcohol, pair-fed or chow). The rats were sacrificed at varying time intervals according to the specific study. Zinc analysis of the serum, femur and tibia was performed using atomic absorption spectrophotometry. The alcohol eventually affected the serum zinc status of the rats in the adolescent project. The zinc status of the animals in the moderate alcohol, 2-day binge, 5-day binge and short-term adult alcohol projects was not significantly altered due to the alcohol. A longer duration and/or a higher amount of ethanol was needed to consistently detect changes in the serum and bone zinc concentrations of all the animals. Although zinc status is altered by ethanol consumption, this relationship is not likely to be the sole mechanism behind the effects of alcohol on bone health.

Chapman, Lisa Louise

1998-01-01T23:59:59.000Z

204

Real-time X-ray Diffraction Measurements of Shocked Polycrystalline Tin and Aluminum  

SciTech Connect

A new, fast, single-pulse x-ray diffraction (XRD) diagnostic for determining phase transitions in shocked polycrystalline materials has been developed. The diagnostic consists of a 37-stage Marx bank high-voltage pulse generator coupled to a needle-and-washer electron beam diode via coaxial cable, producing line and bremsstrahlung x-ray emission in a 35-ns pulse. The characteristic K? lines from the selected anodes of silver and molybdenum are used to produce the diffraction patterns, with thin foil filters employed to remove the characteristic K? line emission. The x-ray beam passes through a pinhole collimator and is incident on the sample with an approximately 3-mm by 6-mm spot and 1 full-width-half-maximum (FWHM) angular divergence in a Bragg-reflecting geometry. For the experiments described in this report, the angle between the incident beam and the sample surface was 8.5. A Debye-Scherrer diffraction image was produced on a phosphor located 76 mm from the polycrystalline sample surface. The phosphor image was coupled to a charge-coupled device (CCD) camera through a coherent fiberoptic bundle. Dynamic single-pulse XRD experiments were conducted with thin foil samples of tin, shock loaded with a 1-mm vitreous carbon back window. Detasheet high explosive with a 2-mm-thick aluminum buffer was used to shock the sample. Analysis of the dynamic shock-loaded tin XRD images revealed a phase transformation of the tin beta phase into an amorphous or liquid state. Identical experiments with shock-loaded aluminum indicated compression of the face-centered-cubic (fcc) aluminum lattice with no phase transformation.

Dane V. Morgan, Don Macy, Gerald Stevens

2008-11-22T23:59:59.000Z

205

Microstructure evolution in TiN films reactively sputter deposited on multiphase substrates  

SciTech Connect

Cross-sectional transmission electron microscopy (X-TEM) has been used to investigate the microstructure of TiN films deposited by reactive magnetron sputtering onto ASP 30 high speed steel (HSS) substrates. ASP 30 is a multiphase material consisting of a martensitic matrix with MC and M/sub 6/C transition--metal particles embedded in it. The TiN films were approx.4 ..mu..m thick and were grown at substrate temperatures T/sub s/ between 200 and 550/sup 0/C. The X-TEM results showed that the film microstructure was very nonhomogeneous. A dense columnar morphology was observed above both the martensitic and M/sub 6/C substrate phases. The average column diameter ranged from 15 nm (T/sub s/ = 200/sup 0/C) to 50 nm (T/sub s/ = 550/sup 0/C) near the film/substrate interface over the martensitic phase and was in a factor of 2 less in the film regions adjacent to the M/sub 6/C phase. increased in both regions to 100 nm (T/sub s/ = 200/sup 0/C) to 150 nm (T/sub s/ = 550/sup 0/C) near the surface of the films. TiN grew epitaxially on MC particles but contained a high dislocation density which (except at 550/sup 0/C where some of the epitaxial grains extended throughout the entire film thickness) eventually coalesced to form low-angle grain boundaries and, finally, high-angle boundaries.

Helmersson, U.; Sundgren, J.; Greene, J.E.

1986-05-01T23:59:59.000Z

206

Spin-polarized relativistic linear-muffin-tin-orbital method: Volume-dependent electronic structure and magnetic moment of plutonium  

Science Conference Proceedings (OSTI)

The linear-muffin-tin-orbital method is generalized to the case of relativistic and spin-polarized self-consistent band calculations. Our formalism is analogous to the standard orthogonal--linear-muffin-tin-orbital formalism, except that the potential functions and the potential parameters are now matrices. The method is used to perform density-functional calculations for fcc plutonium with different atomic volumes. The formation of spin and orbital magnetic moments, as well as the changes in the energy bands for volume changes corresponding to the {alpha}-{delta} transition, are investigated. The calculated magnetic moments agree quite well with the experimental ones.

Solovyev, I.V. (Institute of Chemistry, Ural Branch of U.S.S.R. Academy of Science, Sverdlovsk GSP-145, U.S.S.R. (SU)); Liechtenstein, A.I. (Max-Planck-Institut fuer Festkoerperforschung, Heisenbergstrasse 1, D-7000 Stuttgart 80, Federal Republic of Germany (DE)); Gubanov, V.A. (Institute of Chemistry, Ural Branch of U.S.S.R. Academy of Science, Sverdlovsk GSP-145, U.S.S.R. (SU)); Antropov, V.P. (Institute of Metal Physics, Ural Branch of U.S.S.R. Academy of Science, Sverdlosk GSP-145, U.S.S.R. (SU)); Andersen, O.K. (Max-Planck-Institut fuer Festkoerperforschung, Heisenbergstrasse 1, D-7000 Stuttgart 80, Federal Republic of Germany (DE))

1991-06-15T23:59:59.000Z

207

REDUCTION AND STABILIZATION (IMMOBILIZATION) OF PERTECHNETATE TO AN IMMOBILE REDUCED TECHNETIUM SPECIES USING TIN(II) APATITE  

SciTech Connect

Synthetic tin(II)apatite reduces pertechnetate from the mobile +7 to a non-mobile oxidation state and sequesters the technetium, preventing re-oxidization to mobile +7 state under acidic or oxygenated conditions. Previous work indicated technetium reacted Sn(II)apatite can achieve an ANSI leachability index of 12.8 in Cast Stone. An effect by pH is observed on the distribution coefficient, the highest distribution coefficient being l70,900 observed at pH levels of 2.5 to 10.2. The tin apatite was resistant to releasing technetium under test conditions.

Duncan JB

2012-11-02T23:59:59.000Z

208

Phase Structure and Cyclic Deformation in Eutectic Tin-Lead Alloy: A Numerical Analysis  

Science Conference Proceedings (OSTI)

This study is devoted to providing a mechanistic rationale of coarsening induced failure in solder alloys during thermomechanical fatigue. Micromechanical modeling of cyclic deformation of eutectic tin-lead alloy was undertaken using the finite element method. The models consist of regularly arranged tin-rich and lead-rich phases, simulating the lamellar array and colony structure in a typical eutectic system. A fine structure and a coarse structure, bearing the same phase fraction but different in the aspect ratio of each lead-rich layer and in the number of lead-rich layers in each colony, are utilized for representing the microstructure before and after coarsening, respectively. Both phases are treated as elastic-plastic solids with their respective properties. For simplicity the creep effect is ignored without compromising the main objective of this study. Cyclic loading under pure shear and uniaxial conditions is modeled. It is found that both the fine and coarse structures exhibit essentially the same macroscopic stress-strain response. The coarse structure, however, shows a greater maximum effective plastic strain on a local scale throughout the deformation. The numerical result implies that, in a solder joint, a locally coarsened region may not be mechanically weaker than its surrounding, but it is subject to early damage initiation due to accumulated plasticity. Other implications regarding solder alloy failure and micromechanical modeling of two-phase materials are discussed.

FANG,HUEI ELIOT; Li,W; SHEN,Y.-L

1999-09-09T23:59:59.000Z

209

and electrical properties of zinc oxide films  

E-Print Network (OSTI)

Undoped and indium-doped ZnO films have been deposited onto glass substrates by the spray pyrolysis method. The effect of indium incorporation on structural and electrical properties of ZnO films has been investigated. Zinc acetate dihydrate, indium chloride were used as a starting material and a dopant source, respectively. X-ray diffraction pattern of the films showed hexagonal wurtzite type polycrystalline structure. The results show that indium incorporation leads to substantial changes in the structural characteristics of ZnO films. The grain size was found to be in the range 15-50 nm, depending on indium content. In addition, the surface morphology features of the films, as a function of the indium content, are shown. For all the films, a linear dependence typical of ohmic behavior was observed. The electrical conductivity of ZnO films was improved by indium incorporation. The most important changes were observed for 1 at. % In-doped ZnO film which exhibit a resistivity of 3.2x10-1 ?cm. At certain constant voltage, from Arrhenius plots of In-doped ZnO films, activation energy values have been calculated from 17 meV to 89 meV.

unknown authors

2006-01-01T23:59:59.000Z

210

Studies of selenium and xenon in inductively coupled plasma mass spectrometry  

SciTech Connect

Since its development, inductively coupled plasma mass spectrometry (ICP-MS) has been a widely used analytical technique. ICP-MS offers low detection limits, easy determination of isotope ratios, and simple mass spectra from analyte elements. ICP-MS has been successfully employed for many applications including geological, environmental, biological, metallurgical, food, medical, and industrial. One specific application important to many areas of study involves elemental speciation by using ICP-MS as an element specific detector interfaced to liquid chromatography. Elemental speciation information is important and cannot be obtained by atomic spectrometric methods alone which measure only the total concentration of the element present. Part 1 of this study describes the speciation of selenium in human serum by size exclusion chromatography (SEC) and detection by ICP-MS. Although ICP-MS has been widely sued, room for improvement still exists. Difficulties in ICP-MS include noise in the background, matrix effects, clogging of the sampling orifice with deposited solids, and spectral interference caused by polyatomic ions. Previous work has shown that the addition of xenon into the central channel of the ICP decreases polyatomic ion levels. In Part 2 of this work, a fundamental study involving the measurement of the excitation temperature is carried out to further understand xenon`s role in the reduction of polyatomic ions. 155 refs.

Bricker, T.

1994-07-27T23:59:59.000Z

211

Recycling of cadmium and selenium from photovoltaic modules and manufacturing wastes  

DOE Green Energy (OSTI)

Since the development of the first silicon based photovoltaic cell in the 1950's, large advances have been made in photovoltaic material and processing options. At present there is growing interest in the commercial potential of cadmium telluride (CdTe) and copper indium diselenide (CIS) photovoltaic modules. As the commercial potential of these technologies becomes more apparent, interest in the environmental, health and safety issues associated with their production, use and disposal has also increased because of the continuing regulatory focus on cadmium and selenium. In future, recycling of spent or broken CdTe and CIS modules and manufacturing wastes may be needed for environmental, economic or political reasons. To assist industry to identify recycling options early in the commercialization process, a Workshop was convened. At this Workshop, representatives from the photovoltaic, electric utility, and nonferrous metals industries met to explore technical and institutional options for the recycling of spent CdTe and CIS modules and manufacturing wastes. This report summarizes the results of the Workshop. This report includes: (1) A discussion of the Resource Conservation and Recovery Act regulations and their potential implications to the photovoltaic industry; (2) an assessment of the needs of the photovoltaic industry from the perspective of module manufacturers and consumers; (3) an overview of recycling technologies now employed by other industries for similar types of materials; and, (4) a list of recommendation.

Moskowitz, P.D.; Zweibel, K. (eds.)

1992-01-01T23:59:59.000Z

212

Recycling of cadmium and selenium from photovoltaic modules and manufacturing wastes. A workshop report  

DOE Green Energy (OSTI)

Since the development of the first silicon based photovoltaic cell in the 1950`s, large advances have been made in photovoltaic material and processing options. At present there is growing interest in the commercial potential of cadmium telluride (CdTe) and copper indium diselenide (CIS) photovoltaic modules. As the commercial potential of these technologies becomes more apparent, interest in the environmental, health and safety issues associated with their production, use and disposal has also increased because of the continuing regulatory focus on cadmium and selenium. In future, recycling of spent or broken CdTe and CIS modules and manufacturing wastes may be needed for environmental, economic or political reasons. To assist industry to identify recycling options early in the commercialization process, a Workshop was convened. At this Workshop, representatives from the photovoltaic, electric utility, and nonferrous metals industries met to explore technical and institutional options for the recycling of spent CdTe and CIS modules and manufacturing wastes. This report summarizes the results of the Workshop. This report includes: (1) A discussion of the Resource Conservation and Recovery Act regulations and their potential implications to the photovoltaic industry; (2) an assessment of the needs of the photovoltaic industry from the perspective of module manufacturers and consumers; (3) an overview of recycling technologies now employed by other industries for similar types of materials; and, (4) a list of recommendation.

Moskowitz, P.D.; Zweibel, K. [eds.

1992-10-01T23:59:59.000Z

213

C:\Documents and Settings\burris\My Documents\My Files\Eco-SSLs\Contaminant Specific Documents\Selenium\June 2007\Eco-SSL for S  

NLE Websites -- All DOE Office Websites (Extended Search)

Selenium Selenium Interim Final OSWER Directive 9285.7-72 U.S. Environmental Protection Agency Office of Solid Waste and Emergency Response 1200 Pennsylvania Avenue, N.W. Washington, DC 20460 July 2007 This page intentionally left blank i TABLE OF CONTENTS 1.0 INTRODUCTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 2.0 SUMMARY OF ECO-SSLs FOR SELENIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 3.0 ECO-SSL FOR TERRESTRIAL PLANTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 4.0 ECO-SSL FOR SOIL INVERTEBRATES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 5.0 ECO-SSL FOR AVIAN WILDLIFE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8 5.1 Avian TRV . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8 5.2 Estimation of Dose and Calculation of the Eco-SSL . . . . . . . . . . . . . . . . . . . . . . . 14 6.0 ECO-SSL FOR MAMMALIAN WILDLIFE .

214

Tin Production  

Science Conference Proceedings (OSTI)

...descending order, Brazil, Indonesia, Malaysia, Thailand, Bolivia, and Australia. These countries supply more than 85% of total world production....

215

Preparation, characterization, and stability of calcium zinc hydrophosphate  

Science Conference Proceedings (OSTI)

Calcium zinc hydrophosphate phases with different Zn/(Zn + Ca) molar ratios (x{sub Zn}, from 0 to 1) were synthesized using co-precipitation method at pH 10, 25 deg. C. X-ray diffraction, FT-IR spectroscopy and field emission scanning electron microscopy (FE-SEM) were used to characterize the synthesized products. Thermal behavior of the products was examined by thermal analytical instruments (TG-DSC-MS), while the chemical stability of the products was tested by toxicity characteristic leaching procedure (TCLP). The results showed that the phase constituents of formed calcium zinc hydrophosphate phases were related to the molar contents of Zn{sup 2+}. With the increase of x{sub Zn}, it formed calcium-deficient hydorxyapatite (CaHap), calcium zinc hydorxyapatite (CaZnHap), CaZn{sub 2}(PO{sub 4}){sub 2}.2H{sub 2}O, and Zn{sub 3}(PO{sub 4}){sub 2}.4H{sub 2}O, respectively. All the calcium zinc hydrophosphates were thermally stable up to 600 deg. C, and less Zn{sup 2+} leached in a wide pH range of 2-11, which indicated that calcium zinc hydrophosphate could effectively hold Zn{sup 2+} in their crystal phases with stabilization ratios of over 99.99%.

Qian Guangren [School of Environmental Engineering, Shanghai University, Shanghai 200072 (China)], E-mail: grqian@shu.edu.cn; Xu Xia; Sun Weimin; Xu Yunfeng; Liu Qiang [School of Environmental Engineering, Shanghai University, Shanghai 200072 (China)

2008-12-01T23:59:59.000Z

216

A NEW CONCEPT IN AN ELECTRICALLY RECHARGEABLE ZINC-AIR ALKALINE BATTERY  

E-Print Network (OSTI)

Study of a New Zinc-Air Battery Concept Using Flowingdiagram of the zinc-air battery single cell prototype usedDivision . Presented at the Battery and Electrochemical

Ross, P.N.

2010-01-01T23:59:59.000Z

217

A new concept in an electrically rechargeable zinc-air alkaline battery. [Porous electrodes  

SciTech Connect

This paper describes a new idea for zinc-air battery design. The novel idea is a porous zinc electrode surrounded with a supersaturated zincate solution. 3 figs. (JDH)

Ross, P.N.

1987-10-01T23:59:59.000Z

218

Evaluation of Zinc Addition During Cycle 9 at Diablo Canyon Unit 1  

Science Conference Proceedings (OSTI)

Laboratory studies have shown that zinc addition to primary coolant can mitigate primary water stress corrosion cracking (PWSCC) of Alloy 600 and reduce radiation fields in PWRs. This report documents experience with zinc addition during Cycle 9 at Diablo Canyon Power Plant Unit 1 (DCPP-1), operated by Pacific Gas & Electric. This project evaluated the effect of zinc addition on PWSCC initiation and propagation. It also examined the impact of zinc addition on radiation fields and fuel cladding deposition...

1999-10-27T23:59:59.000Z

219

Tuna fish diet influences cat behavior. [Elevated levels of selenium and mercury in commercial tuna fish cat food  

SciTech Connect

When observed in their home cages, cats fed commercial tuna fish cat food were less active, vocalized less, and spent more time on the floor and more time eating than cats fed commercial beef cat food. There were no differences in response to human handling between the two groups. There were no differences in learning ability on a two-choice point maze or in reversal learning in the same maze between beef- and tuna-fed cats. The behavior of the groups differed in a 15-min open field test only in the number of toys contacted. Cats fed the tuna had elevated tissue levels of mercury and selenium.

Houpt, K.A.; Essick, L.A.; Shaw, E.B.; Alo, D.K.; Gilmartin, J.E.; Gutenmann, W.H.; Littman, C.B.; Lisk, D.J.

1988-01-01T23:59:59.000Z

220

PRELIMINARY STUDY OF METHODS TO CHEMICALLY BIND ZINC  

DOE Green Energy (OSTI)

To address the {sup 65}Zn contamination issue in the TEF, a multi-task experimental program was initiated. The first two experimental tasks were completed. The results of the third experimental task are reported here. This task was conducted to determine if the zinc vapors could be chemically bound on two non hydrogen active substrates. Based on a thermodynamic study copper and cobalt were the most favorable for capturing zinc without forming hydrides. Within the experimental parameters tested, which include temperatures of 350, 400, and 450 C at pressures of nominally 20-40 millitorr, the zinc deposited on the both copper screen and cobalt rods but did not react to form a compound. The conditions that were tested are not prototypic and additional testing under higher vacuum conditions, i.e., .01 millitorr, may enhance the reactivity of the surfaces and is recommended.

Korinko, P.

2011-06-10T23:59:59.000Z

Note: This page contains sample records for the topic "zinc tin selenium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Separation and Purification Technology 40 (2004) 251257 Copper and zinc sorption by treated oil shale ash  

E-Print Network (OSTI)

Jordanian oil shale ash was used as an adsorbent for the removal of copper and zinc from aqueous solution.V. All rights reserved. Keywords: Oil shale; Ash; Adsorption; Copper and zinc removal 1. IntroductionSeparation and Purification Technology 40 (2004) 251­257 Copper and zinc sorption by treated oil

Shawabkeh, Reyad A.

222

Sorption of Arsenic, Mercury, Selenium onto Nanostructured Adsorbent Media and Stabilization via Surface Reactions  

E-Print Network (OSTI)

The overall goal of this study is to evaluate the ability of novel nanostructured adsorbent media (NTAs, iron sulfides (FeS2 and FeS)) to remove arsenic, selenium and mercury from ash and scrubber pond effluents. The NTAs aim to enhance arsenic removal from solution compared to conventional adsorbents. The iron sulfides are expected to produce stable residuals for ultimate disposal after removing As, Se and Hg from solution, so that removal of these compounds from wastewaters will not result in contamination of soils and groundwaters. Methods for reliably and economically producing these materials were developed. The synthesized NTAs and iron sulfides were characterized by surface analysis techniques such as XRD, FT-IR, SEM-EDS, TEM, XPS, AFM and N2-adsorption. These analyses indicated that Ti(25)-SBA-15 has highly ordered hexagonal mesopores, MT has interparticle mesopores, pyrite (FeS2) forms crystalline, nonporous rectangular nanoparticles (<500 nm), and mackinawite (FeS) forms amorphous, nonporous nanoparticles (<100 nm). Kinetic and equilibrium tests for As(III, V) removal were conducted with NTAs over a range of pH (4, 7, 9.5). The rates of arsenic uptake were very fast and followed a bi-phasic sorption pattern, where sorption was fast for the first 10 minutes, and then slowed and was almost completed within 200 minutes. Distinct sorption maxima for As(III) removal were observed between pH 7 and pH 9.5 for MT and between pH 4 and pH 7 for Ti(25)-SBA-15. The amount of As(V) adsorbed generally decreased as pH increased. In addition, a surface complexation model (SCM) based on the diffuse layer model (DLM) was used to predict arsenic adsorption envelopes by NTAs under various environmental conditions. The SCM for As(III, V) adsorption by NTAs demonstrated the role of mono- and bidentate surface complexes in arsenic adsorption. A batch reactor system was employed in an anaerobic chamber to conduct experiments to characterize both the removal of As, Se, Hg from solution and their subsequent reactions with iron sulfides. Experiment variables for removal experiments included: contaminant valence state (As(V), As(III), Se(VI), Se(IV), Hg(II)); adsorbent/reactant type (FeS, FeS2); adsorbent/reactant concentration; pH (7, 8, 9, 10); and competing ion (SO42-) concentration (0, 1, 10 mM). Experimental variables for reaction experiments were reaction time (up to 30 days) at pH 8 and oxidation states of contaminants. In addition, the stability of iron sulfides (FeS2, FeS) combined with target compounds was investigated by measuring the ability of the target compounds to resist release to the aqueous phase after removal. These experiments showed that iron sulfides were good adsorbent/reactants for target contaminants in spite of the presence of sulfate. This was particularly true at intermediate concentrations of target compounds. The experiments also demonstrated that iron sulfides interacted with target contaminants in such a way to improve their resistance to being released back to solution as pH was changed. Therefore, this study demonstrates the ability of novel nanostructured adsorbent media to remove arsenic, selenium and mercury from ash and scrubber pond effluents and the ability of iron sulfides to produce residuals that are stable when disposed in landfills.

Han, Dong Suk

2009-12-01T23:59:59.000Z

223

Enhanced durability and reactivity for zinc ferrite desulfurization sorbent  

Science Conference Proceedings (OSTI)

AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

Jha, M.C.; Berggren, M.H.

1989-05-02T23:59:59.000Z

224

Secondary battery containing zinc electrode with modified separator and method  

DOE Patents (OSTI)

A battery containing a zinc electrode with a porous separator between the anode and cathode. The separator is a microporous substrate carrying therewith an organic solvent of benzene, toluene or xylene with a tertiary organic amine therein, wherein the tertiary amine has three carbon chains each containing from six to eight carbon atoms. The separator reduces the rate of zinc dentrite growth in the separator during battery operation prolonging battery life by preventing short circuits. A method of making the separator is also disclosed.

Poa, D.S.

1984-02-16T23:59:59.000Z

225

Secondary battery containing zinc electrode with modified separator and method  

DOE Patents (OSTI)

A battery containing a zinc electrode with a porous separator between the anode and cathode. The separator is a microporous substrate carrying therewith an organic solvent of benzene, toluene or xylene with a tertiary organic amine therein, wherein the tertiary amine has three carbon chains each containing from six to eight carbon atoms. The separator reduces the rate of zinc dentrite growth in the separator during battery operation prolonging battery life by preventing short circuits. A method of making the separator is also disclosed.

Poa, David S. (Naperville, IL); Yao, Neng-Ping (Clarendon Hills, IL)

1985-01-01T23:59:59.000Z

226

Boiling Water Reactor (BWR) Zinc Injection Strategy Evaluation  

Science Conference Proceedings (OSTI)

All U.S. boiling water reactors (BWRs) inject depleted zinc oxide (DZO) into the reactor feedwater for the purpose of suppressing drywell shutdown radiation dose rates. Current guidance in BWRVIP-190: BWR Vessel and Internals Project, BWR Water Chemistry Guidelines2008 Revision (EPRI report 1016579) is to inject sufficient zinc to achieve a Co-60(s)/Zn(s) ratio of Utility-specific goals may encourage even lower Co-60(s)/Zn(s) levels. This may be in part because BWR e...

2010-11-24T23:59:59.000Z

227

Pressure-temperature phase diagram for a tin modified lead zirconate titanate ceramic.  

Science Conference Proceedings (OSTI)

Structural phase transformations between ferroelectric (FE), antiferroelectric (AFE), and paraelectric (FE) phases are frequently observed in the zirconia-rich phase region on the lead zirconate-titanate (PZT) phase diagram. Since the free energy difference among these phases is small, phase transformation can be easily induced by temperature, pressure and electric field. These induced transformation characteristics have been used for many practical applications. This study focuses on a hydrostatic pressure induced FE-to-AFE phase transformation in a tin modified PZT ceramic (PSZT). The relative phase stability between FE and AFE phases is determined by the dielectric permittivity measurement as a function of temperature from -60 C to 125 C. A pressure-temperature phase diagram for the PSZT system will be presented.

Grubbs, Robert K.; DiAntonio, Christopher Brian; Yang, Pin; Roesler, Alexander William; Montgomery, Stephen Tedford; Moore, Roger Howard

2010-06-01T23:59:59.000Z

228

Modifying the Casimir force between indium tin oxide film and Au sphere  

E-Print Network (OSTI)

We present complete results of the experiment on measuring the Casimir force between an Au-coated sphere and an untreated or, alternatively, UV-treated indium tin oxide film deposited on a quartz substrate. Measurements were performed using an atomic force microscope in a high vacuum chamber. The measurement system was calibrated electrostatically. Special analysis of the systematic deviations is performed, and respective corrections in the calibration parameters are introduced. The corrected parameters are free from anomalies discussed in the literature. The experimental data for the Casimir force from two measurement sets for both untreated and UV-treated samples are presented. The experimental errors are determined at a 95% confidence level. It is demonstrated that the UV treatment of an I TO plate results in a significant decrease in the magnitude of the Casimir force (from 21% to 35% depending on separation). However, ellipsometry measurements of the imaginary parts of dielectric permittivities of the un...

Banishev, A A; Castillo-Garza, R; Klimchitskaya, G L; Mostepanenko, V M; Mohideen, U; 10.1103/PhysRevB.85.045436

2012-01-01T23:59:59.000Z

229

Thin film cadmium telluride, zinc telluride, and mercury zinc telluride solar cells  

DOE Green Energy (OSTI)

This report describes research to demonstrate (1) thin film cadmium telluride solar cells with a quantum efficiency of 75% or higher at 0. 44 {mu}m and a photovoltaic efficiency of 11.5% or greater, and (2) thin film zinc telluride and mercury zinc telluride solar cells with a transparency to sub-band-gap radiation of 65% and a photovoltaic conversion efficiency of 5% and 8%, respectively. Work was directed at (1) depositing transparent conducting semiconductor films by solution growth and metal-organic chemical vapor deposition (MOCVD) technique, (2) depositing CdTe films by close-spaced sublimation (CSS) and MOCVD techniques, (3) preparing and evaluating thin film CdTe solar cells, and (4) preparing and characterizing thin film ZnTe, CD{sub 1-x}Zn{sub 1-x}Te, and Hg{sub 1-x}Zn{sub x}Te solar cells. The deposition of CdS films from aqueous solutions was investigated in detail, and their crystallographic, optical, and electrical properties were characterized. CdTe films were deposited from DMCd and DIPTe at 400{degrees}C using TEGa and AsH{sub 3} as dopants. CdTe films deposited by CSS had significantly better microstructures than those deposited by MOCVD. Deep energy states in CdTe films deposited by CSS and MOCVD were investigated. Thin films of ZnTe, Cd{sub 1- x}Zn{sub x}Te, and Hg{sub 1-x}Zn{sub x}Te were deposited by MOCVD, and their crystallographic, optical, and electrical properties were characterized. 67 refs.

Chu, T.L. (University of South Florida, Tampa, FL (United States))

1992-04-01T23:59:59.000Z

230

Methods of making copper selenium precursor compositions with a targeted copper selenide content and precursor compositions and thin films resulting therefrom  

DOE Patents (OSTI)

Precursor compositions containing copper and selenium suitable for deposition on a substrate to form thin films suitable for semi-conductor applications. Methods of forming the precursor compositions using primary amine solvents and methods of forming the thin films wherein the selection of temperature and duration of heating controls the formation of a targeted species of copper selenide.

Curtis, Calvin J. (Lakewood, CO); Miedaner, Alexander (Boulder, CO); van Hest, Marinus Franciscus Antonius Maria (Lakewood, CO); Ginley, David S. (Evergreen, CO); Leisch, Jennifer (Denver, CO); Taylor, Matthew (West Simsbury, CT); Stanbery, Billy J. (Austin, TX)

2011-09-20T23:59:59.000Z

231

Process for fabricating doped zinc oxide microsphere gel  

DOE Patents (OSTI)

Disclosed are a new composition and method of making same for a doped zinc oxide microsphere and articles made therefrom for use in an electrical surge arrestor which has increased solid content, uniform grain size and is in the form of a gel. 4 figures.

Arnold, W.D. Jr.; Bond, W.D.; Lauf, R.J.

1991-11-05T23:59:59.000Z

232

Interfacial electron transfer dynamics of photosensitized zinc oxide nanoclusters  

DOE Green Energy (OSTI)

The authors have prepared and characterized photosensitized zinc oxide (ZnO) nanoclusters, dispersed in methanol, using carboxylated coumarin dyes for surface adsorption. Femtosecond time-resolved emission spectroscopy allows the authors to measure the photo-induced charge carrier injection rate constant from the adsorbed photosensitizer to the n-type semiconductor nanocluster. These results are compared with other photosensitized semiconductors.

Murakoshi, Kei; Yanagida, Shozo [Osaka Univ. (Japan). Graduate School of Engineering; Capel, M. [Brookhaven National Lab., Upton, NY (United States)] [and others

1997-06-01T23:59:59.000Z

233

Amorphous hafnium-indium-zinc oxide semiconductor thin film transistors  

Science Conference Proceedings (OSTI)

We reported on the performance and electrical properties of co-sputtering-processed amorphous hafnium-indium-zinc oxide (?-HfIZO) thin film transistors (TFTs). Co-sputtering-processed ?-HfIZO thin films have shown an amorphous phase in nature. ...

Sheng-Po Chang; San-Syong Shih

2012-01-01T23:59:59.000Z

234

A New Portable Instrument for In Situ Measurement of Atmospheric Methane Mole Fraction by Applying an Improved Tin DioxideBased Gas Sensor  

Science Conference Proceedings (OSTI)

A new portable instrument based on a tin dioxide natural gas leak detector was developed to monitor the atmospheric methane mixing ratio in areas lacking sufficient infrastructure to sustain a conventional measurement system, such as a large ...

Hiroshi Suto; Gen Inoue

2010-07-01T23:59:59.000Z

235

NIDC: Online Catalog of Isotope Products | Add a Product to Quote...  

NLE Websites -- All DOE Office Websites (Extended Search)

Rubidium Ruthenium Samarium Selenium Silicon Silver Sodium Strontium Sulfur Tantalum Technetium Tellurium Thallium Thorium Tin Titanium Tungsten Uranium Vanadium Xenon Ytterbium...

236

The Risk Assessment Information System  

NLE Websites -- All DOE Office Websites (Extended Search)

Niobium Scandium Selenium Silicon Silver Strontium, Stable Thallium (Soluble Salts) Thorium Tin Titanium Uranium, Insoluble Compounds Vanadium and Compounds Ytterbium Yttrium...

237

Effects of zinc on Salmonella in the layer house environments and laying hens, and the ability of zinc to induce molt in laying hens  

E-Print Network (OSTI)

There is increasing interest in developing methods to detect and identify Salmonella, to eliminate or reduce the risk of contamination of shell eggs, and to retain the economic advantages of induced molting without increasing the risk of Salmonella enteritidis infection. S. enteritidis and S. typhimurium are the most common serotypes among 2449 known serotypes of the Salmonella, and are the causes of most egg- related foodborne salmonellosis in humans in the U. S. These two species are also responsible for environmental contamination and the incidence of infections. Therefore, this study was conducted in three phases consisting of ten in vivo and in vitro experiments. This study investigated the effects of zinc on Salmonella growth and survivability in poultry environments, and its ability to induce a molt in single comb white leghorn hens. In part, the antibacterial properties of zinc may reduce environmental contamination in a poultry house by interrupting airborne routes. The first phase involved detecting airborne bacteria by aerosol sampling methods, and then screening any Salmonella mutant (s) that survived desiccation by transposon footprinting. The second phase examined, in vitro, the addition of zinc on the growth kinetics of Salmonella under aerobic or anaerobic conditions, the effects of combinating zinc and acidic conditions on the growth kinetics of Salmonella in vitro under aerobic or anaerobic conditions, and the effects of zinc amended feed on the survival of a dry inoculum of Salmonella. The third phase investigated the ability of zinc propionate, as an alternative salt form of zinc, to induce molt in laying hens, the influence of zinc acetate and zinc propionate on gastrointestinal tract fermentation, and susceptibility of laying hens to S. enteritidis during an induced molt, and the comparison of digestive microbial crop and cecal communities among molted hens fed by either zinc acetate or zinc propionate amended molting diets with hens undergoing feed withdrawal or full fed nonmolted hens using molecular-based denaturing gradient gel electrophoresis.

Park, Shinyoung

2003-12-01T23:59:59.000Z

238

NREL: Hydrogen and Fuel Cells Research - Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

high conductivity) for this application include tin oxide, indium tin oxide, and zinc oxide. Contact: Bryan Pivovar 303-275-3809 Printable Version Hydrogen & Fuel Cells Research...

239

Synthesis, Characterization and Applications of InSb Semiconductor Nanowires  

E-Print Network (OSTI)

ITO), indium oxide (In 2 O 3 ), and zinc oxide (ZnO) havenanotube (CNT), tin oxide (SnO 2 ), indium tin oxide (

Paul, Rajat Kanti

2011-01-01T23:59:59.000Z

240

Roll Printed Electronics: Development and Scaling of Gravure Printing Techniques  

E-Print Network (OSTI)

gravure printing of indium tin oxide nanoparticle patternsfor the deposition of indium tin oxide nanoparticles forwith and without Indium Zinc Oxide (IZO) conductive layers

de la Fuente Vornbrock, Alejandro

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "zinc tin selenium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Kinetics of the wetting of tin on air-passivated copper in the absence of a fluxing agent  

SciTech Connect

A specially designed ultrahigh vacuum in situ surface analysis and wetting system has been constructed to study the spreading of liquid metal solders on carefully prepared and well-characterized solid substrates. Initial studies have been completed for the spreading of pure tin solder on copper substrates in the absence of any fluxing agent. Surface chemical analysis by x-ray photoelectron spectroscopy showed the air-exposed surface to consisted of about 3 nm of Cu{sub 2}O, while the as-received surface consisted of about 8 nm of Cu{sub 2}O. The sputter-cleaned surface contained less than one monolayer (0.3 nm) of Cu{sub 2}O. Sample surfaces were prepared and spreading experiments performed without intermediate exposure of the surfaces to contaminating atmospheres. Solder spreading was performed under 50 torr of highly purified helium gas to allow for adequate thermal coupling between the solder and the substrate. Spreading experiments utilizing a linear temperature ramp show that pure tin solder spreads readily on oxidized copper surfaces at elevated temperatures. The initiation temperature for rapid tin spreading on the as-received copper surface was 325{degrees}C, similar to the temperature where isothermal spreading changes activation energy or rate. Decreasing the thickness of the oxide on the surface lowered the observed temperature for the initiation of spreading and increased the rate of spreading. On the sputter-cleaned copper surface, rapid solder spreading was observed immediately upon melting of the solder.

Peebles, D.E.; Peebles, H.C.; Ohlhausen, J.A.; Yost, F.G.

1994-10-01T23:59:59.000Z

242

Indium-Tin-Oxide-Based Transparent Conducting Layers for Highly Efficient Photovoltaic Devices  

Science Conference Proceedings (OSTI)

Additional hydrogen (H{sub 2}) annealing and subsequent electrochemical treatment are found to make tin-doped indium oxide (ITO)-based photoelectrodes suitable for highly efficient dye sensitized solar cells. The additional H{sub 2} annealing process recovered the electrical conductivity of the ITO film the same as its initial high conductivity, which enhanced the charge collecting property. Moreover, the employment of electrochemical oxidation of TiO{sub 2}/ITO photoelectrode improved the energy conversion efficiency of the ITO-based dye-sensitized solar cells (DSSC), higher than that of a conventional FTO-based DSSC. Electrochemical impedance analysis showed that the H2 annealing process reduced the internal resistance of the cell, i.e., the resistance of the ITO and the Schottky barrier at the TiO{sub 2}/ITO interface were reduced, and that the electrochemical treatment recovered the diodelike characteristics of the DSSC by retarding back electron transfer from the photoelectrode to the electrolyte. The present work demonstrates that thermally and electrochemically modified ITO-based photoelectrode is another alternative to the conventionally used FTO-based photoelectrode.

Lee, S.; Noh, J. H.; Bae, S. T.; Cho, I. S.; Kim, J. Y.; Shin, H.; Lee, J. K.; Jung, H. S.; Hong, K. S.

2009-01-01T23:59:59.000Z

243

Interfacial reactions between indium tin oxide and triphenylamine tetramer layers induced by photoirradiation  

Science Conference Proceedings (OSTI)

The effects of photoirradiation on the interfacial chemical reactions between indium tin oxide (ITO) films and layers of triphenylamine tetramer (TPTE) were investigated by using in situ x-ray photoelectron spectroscopy (XPS). Thin TPTE layers deposited onto sputter-deposited ITO films were irradiated with violet light-emitting diodes (peak wavelength: 380 nm). Shifts in the peak positions of spectral components that originated in the organic layer toward the higher binding-energy side were observed in the XPS profiles during the early stages of irradiation. No further peak shifts were observed after additional irradiation. An increase in the ratio of the organic component in the O 1s spectra was also observed during the photoirradiation. The ratio of the organic component increased in proportion to the cube root of the irradiation time. These results suggest that photoirradiation induces an increase in the height of the carrier injection barrier at the interface between TPTE and ITO in the early stages of the irradiation, possibly due to the rapid diffusion controlled formation and growth of an oxidized TPTE layer, which is considered to act as a high resistance layer.

Satoh, Toshikazu; Fujikawa, Hisayoshi [Toyota Central R and D Laboratories, Inc., 41-1 Yokomichi, Nagakute, Aichi 480-1192 (Japan); Yamamoto, Ichiro; Murasaki, Takanori; Kato, Yoshifumi [Toyota Industries Corporation, 8 Chaya, Kyowa, Obu, Aichi 474-8601 (Japan)

2008-05-01T23:59:59.000Z

244

Performance enhancement of organic light-emitting diodes by chlorine plasma treatment of indium tin oxide  

SciTech Connect

The characteristics of green phosphorescent organic light-emitting diodes (OLEDs) fabricated on ITO/glass substrates pretreated with low-energy O{sub 2} and Cl{sub 2} plasma were compared. At 20 mA/cm{sup 2}, the OLEDs with O{sub 2} and Cl{sub 2} plasma-treated indium tin oxide (ITO) had voltages of 9.6 and 7.6 eV, and brightness of 9580 and 12380 cd/m{sup 2}, respectively. At {approx}10{sup 4} cd/m{sup 2}, the latter had a 30% higher external quantum efficiency and a 74% higher power efficiency. Photoelectron spectroscopies revealed that Cl{sub 2} plasma treatment created stable In-Cl bonds and raised the work function of ITO by up to 0.9 eV. These results suggest that the better energy level alignment at the chlorinated ITO/organic interface enhances hole injection, leading to more efficient and more reliable operation of the OLEDs. The developed plasma chlorination process is very effective for surface modification of ITO and compatible with the fabrication of various organic electronics.

Cao, X. A.; Zhang, Y. Q. [Department of Computer Science and Electrical Engineering, West Virginia University, Morgantown, West Virginia 26506 (United States)

2012-04-30T23:59:59.000Z

245

The crystallinity and mechanical properties of indium tin oxide coatings on polymer substrates  

SciTech Connect

We present the relationship between the microstructure and mechanical strength of indium tin oxide (ITO) on flexible substrates. With varying thickness (h{sub f}), ITO is deposited on polyethylene terephthalate (PET) by dc magnetron sputtering. The microstructure of ITO is controlled by substrate surface conditions and sputtering parameters. The maximum substrate temperature during deposition is limited to 80 deg. C due to the low glass transition temperature (T{sub g}) of PET. The crystallinity and surface roughness (R{sub rms}) are analyzed by high resolution x-ray diffraction, high resolution transmission electron microscopy, and AFM. The crack resistance of ITO is evaluated by uniaxial tension test. The experimental results reveal that, at a fixed h{sub f}, the degree and quality of crystallinity of ITO are highly improved by increasing sputtering power and the substrate temperature. As the crystallinity is improved, the ratio of preferred growth orientations of (222) to (400) is increased and the degree of peak shifts to lower 2{theta} is decreased. They indicate that the crystallinity is improved as the lattice damage is reduced and film density is increased. The tension test results confirm that, up to a certain h{sub f}, the strength of ITO can be significantly enhanced by improving the microstructures.

Kim, Eun-Hye; Yang, Chan-Woo; Park, Jin-Woo [Department of Materials Science and Engineering, Yonsei University, Seoul 120-749 (Korea, Republic of)

2011-02-15T23:59:59.000Z

246

Mitigation of Sulfur Poisoning of Ni/Zirconia SOFC Anodes by Antimony and Tin  

Science Conference Proceedings (OSTI)

Surface Ni/Sb and Ni/Sb alloys were found to efficiently minimize the negative effects of sulfur on the performance of Ni/zirconia anode-supported solid oxide fuel cells (SOFC). Prior to operating on fuel gas containing low concentrations of H2S, the nickel/zirconia anodes were briefly exposed to antimony or tin vapor, which only slightly affected the SOFC performance. During the subsequent exposures to 1 and 5 ppm H2S, increases in anodic polarization losses were minimal compared to those observed for the standard nickel/zirconia anodes. Post-test XPS analyses showed that Sb and Sn tended to segregate to the surface of Ni particles, and further confirmed a significant reduction of adsorbed sulfur on the Ni surface in Ni/Sn and Ni/Sb samples compared to the Ni. The effect may be the result of weaker sulfur adsorption on bimetallic surfaces, adsorption site competition between sulfur and Sb or Sn on Ni, or other factors. The use of dilute binary alloys of Ni-Sb or Ni-Sn in the place of Ni, or brief exposure to Sb or Sn vapor, may be effective means to counteract the effects of sulfur poisoning in SOFC anodes and Ni catalysts. Other advantages, including suppression of coking or tailoring the anode composition for the internal reforming, are also expected.

Marina, Olga A.; Coyle, Christopher A.; Engelhard, Mark H.; Pederson, Larry R.

2011-02-28T23:59:59.000Z

247

Amine templated zinc phosphates phases for membrane separations  

Science Conference Proceedings (OSTI)

This research is focused on developing inorganic molecular sieve membranes for light gas separations such as hydrogen recovery and natural gas purification, and organic molecular separations, such as chiral enantiomers. The authors focus on zinc phosphates because of the ease in crystallization of new phases and the wide range of pore sizes and shapes obtained. With hybrid systems of zinc phosphate crystalline phases templated by amine molecules, the authors are interested in better understanding the association of the template molecules to the inorganic phase, and how the organic transfers its size, shape, and (in some cases) chirality to the bulk. Furthermore, the new porous phases can also be synthesized as thin films on metal oxide substrates. These films allow one to make membranes from organic/inorganic hybrid systems, suitable for diffusion experiments. Characterization techniques for both the bulk phases and the thin films include powder X-ray diffraction, TGA, Scanning Electron Micrograph (SEM) and Electron Dispersive Spectrometry (EDS).

Nenoff, T.M.; Chavez, A.V.; Thoma, S.G.; Provencio, P. [Sandia National Labs., Albuquerque, NM (United States); Harrison, W.T.A. [Univ. of Western Australia, Nedlands (Australia); Phillips, M.L.F. [Gemfire Corp., Palo Alto, CA (United States)

1998-08-01T23:59:59.000Z

248

Fluxes in ;Free; and Total Zinc Are Essential for Progression of Intraerythrocytic Stages of Plasmodium falciparum  

Science Conference Proceedings (OSTI)

Dynamic fluxes in the concentration of ions and small molecules are fundamental features of cell signaling, differentiation, and development. Similar roles for fluxes in transition metal concentrations are less well established. Here, we show that massive zinc fluxes are essential in the infection cycle of an intracellular eukaryotic parasite. Using single-cell quantitative imaging, we show that growth of the blood-stage Plasmodium falciparum parasite requires acquisition of 30 million zinc atoms per erythrocyte before host cell rupture, corresponding to a 400% increase in total zinc concentration. Zinc accumulates in a freely available form in parasitophorous compartments outside the food vacuole, including mitochondria. Restriction of zinc availability via small molecule treatment causes a drop in mitochondrial membrane potential and severely inhibits parasite growth. Thus, extraordinary zinc acquisition and trafficking are essential for parasite development.

Marvin, Rebecca G.; Wolford, Janet L.; Kidd, Matthew J.; Murphy, Sean; Ward, Jesse; Que, Emily L.; Mayer, Meghan L.; Penner-Hahn, James E.; Haldar, Kasturi; O; Halloran, Thomas V. (Michigan); (UWASH); (NWU); (Notre)

2012-10-23T23:59:59.000Z

249

Development of the Zinc-Chloride Battery for Utility Applications  

Science Conference Proceedings (OSTI)

This report reviews progress in Phase 2 (April 1978-March 1980) of a program to develop the zinc-chloride battery for utility load-leveling applications. Tasks in this phase included refurbishment of a 45-kWh module to increase capacity and efficiency, cycle testing of a 1.7-kWh battery, and development of a 50-kWh module to serve as the building block for the 4-MWh battery for the Battery Energy Test Facility.

1980-05-01T23:59:59.000Z

250

PROMOTED ZINC CHROMITE CATALYSTS FOR HIGHER ALCOHOL SYNTHESIS  

SciTech Connect

During this reporting period, a ''zinc chromite'' catalyst promoted with 6 wt.% cesium (Cs) was evaluated at the following operating conditions: Temperature - 375 C and 400 C; Total Pressure--13.6 MPa (2000 psig); Gas Hourly Space Velocity (GHSV) - 5000 standard liters/kg(cat)-hr; and H{sub 2}/CO feed ratio--0.5, 1.0 and 2.0 mole/mole. Decahydronaphthalene (DHN) was used as the slurry liquid. The experiment lasted for twelve days of continuous operation. Unpromoted zinc chromite catalyst then was re-examined under the same operating conditions. Reproducible data was achieved with a continuous liquid make-up. Compared with unpromoted zinc chromite catalyst, 6 wt.% Cs-promoted catalyst shifted the product distribution from methanol to higher alcohols, even though methanol was still the major product. The effect of operating conditions was less important than the addition of promoter. However, it was observed that higher temperature favors higher alcohol synthesis, and that a higher H{sub 2}/CO ratio leads to lower oxygenates selectivity and higher hydrocarbons selectivity. These trends showed clearly with the Cs-promoted catalyst, but were not as prominent with the unpromoted catalyst. The slurry liquid did not decompose or alkylate to a measurable extent during either continuous, 12 - day experiment, even with the higher reactor temperature (400 C). There was a relatively significant loss of catalyst surface area during the experiment with the promoted catalyst, but not with the unpromoted catalyst.

Ms. Xiaolei Sun; Professor George W. Roberts

2000-12-20T23:59:59.000Z

251

Zinc Addition Fuel Study for Byron Unit 1 and Braidwood Unit 1  

Science Conference Proceedings (OSTI)

This study reports on an ongoing program to qualify zinc for use in higher duty cores. Braidwood Unit 1 and Byron Unit 1 represent two of the highest duty plants in the U.S. Therefore, prior to injecting zinc at these units, a thorough risk assessment was required to identify the optimum conditions to add zinc while maintaining margin for fuel cladding integrity and other fuel performance issues.

2008-10-09T23:59:59.000Z

252

Modeling and Analysis of Pressurized Water Reactor (PWR) Primary Coolant Zinc Transients  

Science Conference Proceedings (OSTI)

Analysis of plant responses to transients in power production and zinc injection rates has the potential to reveal additional information about how, where, and at what rate zinc is deposited and incorporated into the films on primary system surfaces. Although the process of zinc transport and incorporation is complicated by the numerous mechanisms and surfaces available for incorporation, a control theory type analysis (linear systems analysis) could be useful for the analysis of transients, including in...

2009-09-24T23:59:59.000Z

253

Isolation and characterization of a new zinc-binding protein from albacore tuna plasma  

SciTech Connect

The protein responsible for sequestering high levels of zinc in the plasma of the albacore tuna (Thunnus alalunga) has been isolated by sequential chromatography. The glycoprotein has a molecular weight of 66,000. Approximately 8.2% of its amino acid residues are histidines. Equilibrium dialysis experiments show it to bind 3 mol of zinc/mol of protein. The stoichiometric constant for the association of zinc with a binding site containing three histidines was determined to be 10/sup 9.4/. This protein is different from albumin and represents a previously uncharacterized zinc transport protein.

Dyke, B.; Hegenauer, J.; Saltman, P.; Laurs, R.M.

1987-06-02T23:59:59.000Z

254

Investigation of the zinc electrode reaction. Annual report, October 1, 1979-September 30, 1980  

SciTech Connect

The excellent performance characteristics of the nickel-zinc battery make it an attractive option for both all-battery and hydride electric vehicles. Commercialization of the battery has been delayed because of limited cycle life particularly under conditions of deep discharge. In nickel-zinc batteries, with pasted zinc electrodes, zinc electrode shape change or redistribution of the active material from the edge of the electrodes toward the center has been the major life-limiting factor. In batteries with soluble free electrolyte zinc electrodes, morphology changes, particularly under random cycling conditions, is a major operational problem. The present work was focussed on finding insights and possible solutions to these two problems. The areas covered in the work were (1) additive and substrate effects on zinc electrode morphology; (2) investigations of zinc electrodes of the second kind; (3) separator effects on zinc electrode shape change; and (4) investigation of the effect of modified charging methods on the morphology and behavior of both pasted and soluble free electrolyte zinc electrodes.

McBreen, J.

1980-12-01T23:59:59.000Z

255

Selective electrodiffusion of zinc ions in a Zrt-, Irt-like protein, ZIPB  

Science Conference Proceedings (OSTI)

All living cells need zinc ions to support cell growth. Zrt-, Irt-like proteins (ZIPs) represent a major route for entry of zinc ions into cells, but how ZIPs promote zinc uptake has been unclear. Here we report the molecular characterization of ZIPB from Bordetella bronchiseptica, the first ZIP homolog to be purified and functionally reconstituted into proteoliposomes. Zinc flux through ZIPB was found to be nonsaturable and electrogenic, yielding membrane potentials as predicted by the Nernst equation. Conversely, membrane potentials drove zinc fluxes with a linear voltage-flux relationship. Direct measurements of metal uptake by inductively coupled plasma mass spectroscopy demonstrated that ZIPB is selective for two group 12 transition metal ions, Zn{sup 2+} and Cd{sup 2+}, whereas rejecting transition metal ions in groups 7 through 11. Our results provide the molecular basis for cellular zinc acquisition by a zinc-selective channel that exploits in vivo zinc concentration gradients to move zinc ions into the cytoplasm.

Lin, W.; Fu, D.; Chai, J.; Love, J.

2010-12-10T23:59:59.000Z

256

Selenium Removal by Iron Cementation from a Coal-Fired Power Plant Flue Gas Desulfurization Wastewater in a Continuous Flow System-- a Pilot Study  

Science Conference Proceedings (OSTI)

This technical update describes work funded by the Electric Power Research Institute (EPRI) and performed by MSE Technology Applications, Inc. (MSE) at a coal-fired power plant burning Powder River Basin (PRB) coal (identified in this report as Plant E). This work was based on encouraging results obtained during previous EPRI-funded work on flue gas desulfurization (FGD) wastewater treatability testing by MSE, which focused on selenium removal from a variety of FGD wastewater sources. The results from th...

2009-07-29T23:59:59.000Z

257

Pilot-Scale and Full-Scale Evaluation of Treatment Technologies for the Removal of Mercury and Selenium in Flue Gas Desulphurization Water  

Science Conference Proceedings (OSTI)

This report presents an overall evaluation of the various advanced treatment technologies that the Electric Power Research Institute (EPRI) has tested for removal of mercury and selenium from flue gas desulfurization (FGD) water. EPRI conducted a literature survey followed by a preliminary laboratory-scale evaluation to screen promising technologies. For the technologies that were selected based on the success of laboratory-scale testing, EPRI worked with treatment vendors to further evaluate these techn...

2010-05-11T23:59:59.000Z

258

Physicochemical characterization of point defects in fluorine doped tin oxide films  

SciTech Connect

The physical and chemical properties of spray deposited FTO films are studied using FESEM, x-ray diffraction (XRD), x-ray photoelectron spectroscopy (XPS), electrical and optical measurements. The results of XRD measurements showed that the films are polycrystalline (grain size 20-50 nm) with Rutile structure and mixed preferred orientation along the (200) and (110) planes. An angular shift of the XRD peaks after F-doping is observed and interpreted as being due to the formation of substitutional fluorine defects (F{sub O}) in presence of high concentration of oxygen vacancies (V{sub O}) that are electrically neutral. The electrical neutrality of oxygen vacancies is supported by the observation that the electron concentration n is two orders of magnitude lower than the V{sub O} concentration calculated from chemical analyses using XPS measurements. It is shown that an agreement between XPS, XRD, and Hall effect results is possible provided that the degree of deviation from stoichiometry is calculated with the assumption that the major part of the bulk carbon content is involved in O-C bonds. High temperature thermal annealing is found to cause an increase in the F{sub O} concentration and a decrease in both n and V{sub O} concentrations with the increase of the annealing temperature. These results could be interpreted in terms of a high temperature chemical exchange reaction between the SnO{sub 2} matrix and a precipitated fluoride phase. In this reaction, fluorine is released to the matrix and Sn is trapped by the fluoride phase, thus creating substitutional fluorine F{sub O} and tin vacancy V{sub Sn} defects. The enthalpy of this reaction is determined to be approximately 2.4 eV while the energy of formation of a V{sub Sn} through the migration of Sn{sub Sn} host atom to the fluoride phase is approximately 0.45 eV.

El Akkad, Fikry; Joseph, Sudeep [Physics Department, Kuwait University, P.O. Box 5969, Safat 13060 (Kuwait)

2012-07-15T23:59:59.000Z

259

Tin, Antimony, Bismuth, and Tellurium Lewis Acids in sigma-Accepting Ligands for Transition Metals  

E-Print Network (OSTI)

The interactions between ligands and transition metals have been an essential subject in inorganic chemistry. Other than the commonly known L-type (two-electron donors) and X-type ligands (one-electron donors), Z-type ligands (two-electron acceptors) have begun to surface in the past decade. Capable of drawing a pair of d-electrons away from a metal, Z-ligands affect the electronic structures of transition metals leading to fascinating properties as well as reactivity. In particular, recent advance in Z-ligand chemistry have resulted in the discovery of transition metal borane complexes featuring metal ? boron interactions. Owing to the presence of a metal ? boron interaction which stabilizes the low valent state, these complexes have been shown to activate small molecules such as H2, CO2, and CHCl3. Further, the concept of Z-ligand has been extended to s- and d-block Lewis acids. In spite of these achievements, Z-ligands that contain Group 14-16 elements as Lewis acids remain scarce and relatively unexplored. For this reason, we have launched a series of investigations targeting complexes with transition metal ? Group 14-16 interactions. These investigations have allowed us to synthesize a series of novel complexes with palladium, platinum, or gold as metallobasic late transition metals and tin, antimony, bismuth, and tellurium as Lewis acids. The transition metal ? Lewis acid interactions of these complexes, which are supported by o-phosphinophenylene, 1,8-naphthalenediyl or 8-quinolinyl buttresses, have been established experimentally and theoretically. Further, the reactivity of these complexes toward anions and oxidants has also been explored. These experiments have led to the discovery of tellurium-platinum complexes that sustain reversible two-electron redox processes including the photo-reductive elimination of chlorine. Other noteworthy outcomes of this research include the isolation of the first telluroxanyl-metal complex as well as the discovery of complexes with HgII ? SbV interactions.

Lin, Tzu-Pin

2012-08-01T23:59:59.000Z

260

Modifying the Casimir force between indium tin oxide film and Au sphere  

E-Print Network (OSTI)

We present complete results of the experiment on measuring the Casimir force between an Au-coated sphere and an untreated or, alternatively, UV-treated indium tin oxide film deposited on a quartz substrate. Measurements were performed using an atomic force microscope in a high vacuum chamber. The measurement system was calibrated electrostatically. Special analysis of the systematic deviations is performed, and respective corrections in the calibration parameters are introduced. The corrected parameters are free from anomalies discussed in the literature. The experimental data for the Casimir force from two measurement sets for both untreated and UV-treated samples are presented. The experimental errors are determined at a 95% confidence level. It is demonstrated that the UV treatment of an I TO plate results in a significant decrease in the magnitude of the Casimir force (from 21% to 35% depending on separation). However, ellipsometry measurements of the imaginary parts of dielectric permittivities of the untreated and UV-treated samples did not reveal any significant differences. The experimental data are compared with computations in the framework of the Lifshitz theory. It is found that the data for the untreated sample are in a very good agreement with theoretical results taking into account the free charge carriers in an ITO film. For the UV-treated sample the data exclude the theoretical results obtained with account of free charge carriers. These data are in a very good agreement with computations disregarding the contribution of free carriers. According to the explanation provided, this is caused by the phase transition of the ITO film from metallic to dielectric state caused by the UV treatment. Possible applications of the discovered phenomenon in nanotechnology are discussed.

A. A. Banishev; C. -C. Chang; R. Castillo-Garza; G. L. Klimchitskaya; V. M. Mostepanenko; U. Mohideen

2012-01-26T23:59:59.000Z

Note: This page contains sample records for the topic "zinc tin selenium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Electronic states at the interface between indium tin oxide and silicon  

Science Conference Proceedings (OSTI)

Electronic properties and thermal stability of interfacial states between indium tin oxide (ITO) and monocrystalline silicon (Si) have been investigated. ITO films with thicknesses of about 300 nm were deposited by dc magnetron sputtering on n- and p-type (100) Si at room temperature. The samples were then annealed for 30 min at different temperatures in the range 100-600 deg. C, and the ITO-Si junction was found to exhibit rectifying behavior. Current-voltage (IV), capacitance-voltage (CV), and deep-level transient spectroscopy (DLTS) measurements have been used to electrically characterize the ITO-Si interface. DLTS measurements on p-type Si samples reveal a dominant hole trap at around 0.37 eV above the valence band edge. In the n-type samples, a broad band of electron traps occur in the range 0.1-0.2 eV below the conduction band edge. These electron traps display wide DLTS peaks, indicating a band of electronic energy levels rather than well-defined states originating from isolated point defects. All the traps in both the p- and n-type samples are found to be located near the ITO-Si interface. Investigations of the thermal stability of the observed electronic states show that the dominant hole trap anneal out after 30 min at 250 deg. C, while the dominant electron traps can be stable up to 500 deg. C. IV and DLTS measurements demonstrate a clear correlation between the annealing of the dominant electronic states and increase in the junction rectification.

Malmbekk, H.; Vines, L.; Monakhov, E. V.; Svensson, B. G. [University of Oslo, Physics Department/Center for Materials Science and Nanotechnology, P.O. Box 1048, Blindern, Oslo N-0316 (Norway)

2011-10-01T23:59:59.000Z

262

Interim Results from a Study of the Impacts of Tin (II) Based Mercury Treatment in a Small Stream Ecosystem: Tims Branch, Savannah River Site  

SciTech Connect

A research team is assessing the impacts of an innovative mercury treatment system in Tims Branch, a small southeastern stream. The treatment system, installed in 2007, reduces and removes inorganic mercury from water using tin(II) (stannous) chloride addition followed by air stripping. The system results in discharge of inorganic tin to the ecosystem. This screening study is based on historical information combined with measurements of contaminant concentrations in water, fish, sediment, biofilms and invertebrates. Initial mercury data indicate that first few years of mercury treatment resulted in a significant decrease in mercury concentration in an upper trophic level fish, redfin pickerel, at all sampling locations in the impacted reach. For example, the whole body mercury concentration in redfin pickerel collected from the most impacted pond decreased approximately 72% between 2006 (pre-treatment) and 2010 (post-treatment). Over this same period, mercury concentrations in the fillet of redfin pickerel in this pond were estimated to have decreased from approximately 1.45 {micro}g/g (wet weight basis) to 0.45 {micro}g/g - a decrease from 4.8x to 1.5x the current EPA guideline concentration for mercury in fillet (0.3 {micro}g/g). Thermodynamic modeling, scanning electron microscopy, and other sampling data for tin suggest that particulate tin (IV) oxides are a significant geochemical species entering the ecosystem with elevated levels of tin measured in surficial sediments and biofilms. Detectable increases in tin in sediments and biofilms extended approximately 3km from the discharge location. Tin oxides are recalcitrant solids that are relatively non-toxic and resistant to dissolution. Work continues to develop and validate methods to analyze total tin in the collected biota samples. In general, the interim results of this screening study suggest that the treatment process has performed as predicted and that the concentration of mercury in upper trophic level fish, as a surrogate for all of the underlying transport and transformation processes in a complex ecosystem, has declined as a direct result of the elimination of inorganic mercury inputs. Inorganic tin released to the ecosystem has been found in compartments where particles accumulate with notable levels measured in biofilms.

Looney, Brian [Savannah River National Laboratory (SRNL); BryanJr., Larry [Savannah River Ecology Laboratory; Mathews, Teresa J [ORNL; Peterson, Mark J [ORNL; Roy, W Kelly [ORNL; Jett, Robert T [ORNL; Smith, John G [ORNL

2012-03-01T23:59:59.000Z

263

ITP Mining: Energy and Environmental Profile of the U.S. Mining Industry: Chapter 6: Lead and Zinc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

6 6 Lead and Zinc Lead and zinc ores are usually found together with gold and silver. A lead-zinc ore may also contain lead sulfide, zinc sulfide, iron sulfide, iron carbonate, and quartz. When zinc and lead sulfides are present in profitable amounts they are regarded as ore minerals. The remaining rock and minerals are called gangue. Forms of Lead and Zinc Ore The two principal minerals containing lead and zinc are galena and sphalerite. These two minerals are frequently found together along with other sulfide minerals, but one or the other may be predominant. Galena may contain small amounts of impurities including the precious metal silver, usually in the form of a sulfide. When silver is present in sufficient quantities, galena is regarded as a silver ore and called argentiferous galena. Sphalerite is zinc sulfide, but

264

Low Temperature, Self-nucleated Growth of Indium Tin Oxide Nanostructures by Pulsed Laser Deposition in Argon  

SciTech Connect

Indium tin oxide (ITO) nanostructures were successfully deposited on glass substrate by pulsed laser ablation in argon gas at 250 deg. C. Microstructural changes were observed in the argon gas pressure between 30 to 50 mTorr. The as-grown, nanostructured ITO exhibit In{sub 2}O{sub 3} bixbyite structure orientated at <111> direction. At the initial stage of growth, there was a large number of nucleation sites detected which eventually evolved into needle-like branches. The presence of spheres at the tip of these branches indicates that these nanostructured ITO were likely governed by vapor-liquid-solid (VLS) growth mechanism.

Tan, S. S.; Lee, W. K.; Kee, Y. Y.; Wong, H. Y.; Tou, T. Y. [Faculty of Engineering, Multimedia University, 63100 Cyberjaya (Malaysia)

2011-03-30T23:59:59.000Z

265

Evaluation of Zinc Addition to Primary Coolant of Farley-2 PWR  

Science Conference Proceedings (OSTI)

A demonstration project at Southern Nuclear Operating Company's Farley Unit 2 showed that the addition of 35-45 ppb zinc to the primary coolant resulted in lower radiation dose rates and an apparent decrease in primary water stress corrosion cracking (PWSCC) of Alloy 600 steam generator tubing. The zinc had no significant effect on fuel cladding corrosion.

1996-10-31T23:59:59.000Z

266

The Sugar Creek zinc deposit, Jackson Co. TN -- Exploration history, geology and mineralization  

SciTech Connect

During the 60's and 70's zinc exploration of central TN and KY was active. The Sugar Creek Project was one of several investigated by Exxon. The discovery hole, Cu 15, was drilled in early 1973. The Sugar Creek Zinc Deposit was acquired by Independence Mining Co. in 1986 and I.M.C. has subsequently completed additional drilling, both stepout and confirmation holes. A total of 137 holes for 300,833 ft have been drilled. The Sugar Creek deposit is a typical Tennessee zinc deposit (Mississippi Valley Type) which occurs in solution collapse breccias in the Lower Ordovician, Knox Dolomite. The Knox consists of fine grained dolomite with interlayered limestones and crystalline dolomite. Only scattered residual limestone is found in the Sugar Creek area. Collapse breccias have formed which control zinc deposition and are similar to other TN Zn. deposits. At Sugar Creek the types of breccias include: a vertically exaggerated glory hole breakthrough breccia which extends to within 137 ft. of the Knox unconformity, has 500 ft. of zinc mineralization with 8 significant zinc intervals; holes with stacked zinc intervals interpreted to be sides of breakthrough breccia; and single zinc intervals in laterally positioned bedded mineral zones. A total of 99 holes were drilled in the more intense mineralized areas. The ratio of ore to non ore holes is nearly 1 to 1. The mineralization is typical M.V.T. with predominantly sphalerite and only minor occurrences of galena, fluorite, pyrite, etc.

Reinbold, G.; Moran, A.V.; Stevens, D.L. (Independence Mining Co. Inc., Reno, NV (United States))

1993-03-01T23:59:59.000Z

267

Research, development and demonstration of nickel-zinc batteries for electric vehicle propulsion. Annual report, 1978  

DOE Green Energy (OSTI)

The work carried out under the Yardney Contract with ANL for R, D and D on nickel zinc batteries over the past year was directed in three major areas: (1) elucidating the failure modes of the nickel-zinc battery system; (2) improving performance of the system; and (3) effecting a cost reduction program. Progress on the three areas is reported. (TFD)

Not Available

1979-10-01T23:59:59.000Z

268

Enhanced durability and reactivity for zinc ferrite desulfurization sorbent  

Science Conference Proceedings (OSTI)

AMAX Research Development Center (AMAX R D) investigated methods for enhancing the reactivity and durability of zinc ferrite desulfurization sorbents. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For this program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such as size, strength, and specific surface area during 10 cycles of sulfidation and oxidation. Two base case sorbents, a spherical pellet and a cylindrical extrude used in related METC-sponsored projects, were used to provide a basis for the aimed enhancement in durability and reactivity. Sorbent performance was judged on the basis of physical properties, single particle kinetic studies based on thermogravimetric (TGA) techniques, and multicycle bench-scale testing of sorbents. A sorbent grading system was utilized to quantify the characteristics of the new sorbents prepared during the program. Significant enhancements in both reactivity and durability were achieved for the spherical pellet shape over the base case formulation. Overall improvements to reactivity and durability were also made to the cylindrical extrude shape. The primary variables which were investigated during the program included iron oxide type, zinc oxide:iron oxide ratio, inorganic binder concentration, organic binder concentration, and induration conditions. The effects of some variables were small or inconclusive. Based on TGA studies and bench-scale tests, induration conditions were found to be very significant.

Berggren, M.H.; Jha, M.C.

1989-10-01T23:59:59.000Z

269

Durable zinc oxide-containing sorbents for coal gas desulfurization  

DOE Patents (OSTI)

Durable zinc-oxide containing sorbent pellets for removing hydrogen sulfide from a gas stream at an elevated temperature are made up to contain titania as a diluent, high-surface-area silica gel as a matrix material, and a binder. These materials are mixed, moistened, and formed into pellets, which are then dried and calcined. The resulting pellets undergo repeated cycles of sulfidation and regeneration without loss of reactivity and without mechanical degradation. Regeneration of the pellets is carried out by contacting the bed with an oxidizing gas mixture.

Siriwardane, R.V.

1994-12-31T23:59:59.000Z

270

PROMOTED ZINC CHROMITE CATALYSTS FOR HIGHER ALCOHOL SYNTHESIS  

DOE Green Energy (OSTI)

Work during the report period was concentrated on developing analytical techniques. Thin-layer chromatography (TLC) was used in an attempt to define the best mobile phase to separate the components of ''spent'' tetrahydroquinoline by liquid chromatography in a silica gel column. Conditions have been defined for separating the light gases produced by the reaction of carbon monoxide (CO) and hydrogen (H{sub 2}) over promoted ''zinc chromite'' catalysts. This will be done with a temperature-programmed Carboxen-1000 column, using a thermal conductivity detector for analysis. A Petrocol DM 150 capillary column will be purchased to separate the heavier products, which will be analyzed using a flame ionization detector.

Ms. Xiaolei Sun; Professor George W. Roberts

2000-06-21T23:59:59.000Z

271

ZINC/AIR BATTERY R & D RESEARCH AND DEVELOPMENT OF BIFUNCTIONAL OXYGEN ELECTRODE TASKS I AND II  

E-Print Network (OSTI)

ENCE DIVISION ZINC/AIR BATTERY R&D C-.J(~ur.1":! rfS SECTIONLBL-22661 ZINC/AIR BATTERY R&D RESEARCH AND DEVELOPMENT OFTask III - Zinc Air for EV Battery - an engineerin~~~~~! 3!

Klein, M.

2009-01-01T23:59:59.000Z

272

Lithium/selenium secondary battery for implantation. Annual report, 23 June 1970--30 July 1971. [Li/Se and Li--Al/S--Se--Tl, 400 C, 30 W  

DOE Green Energy (OSTI)

A lithium/selenium battery is being developed as an implantable power source for an artificial heart or heart-assist device. During this period, the principal effort was directed toward extending the lifetimes of two types of lithium/selenium cells operating at about 400C. One type consists of a liquid lithium anode, a liquid selenium cathode, and a rigid past electrolyte composed of a molten-salt eutectic and lithium aluminate filler. The other type employs a molten-salt-eutectic liquid electrolyte, a solid lithium--aluminum alloy anode, and an immobilized sulfur--selenium--thallium alloy cathode. Cell cycle life had been severely limited by the transport of selenium to the anode; long-term, steady-state operation of single cells using Se--Tl cathodes demonstrated that this problem has been solved. An improved cell design (employing a liquid electrolyte and solid lithium--aluminum anode) which appears capable of meeting or exceeding the capacity density, power density, and weight objectives for an implantable 30-W battery is presented.

Chilenskas, A.A.; Walsh, W.J.; Trevorrow, L.E.; Webster, D.S.; Cairns, E.J.

1971-10-01T23:59:59.000Z

273

A preliminary report on zinc-induced resistance to nitrogen mustard toxicity in mice  

SciTech Connect

Previous studies with cultured human normal fibroblasts indicated that treatment of cells with zinc before exposure to alkylating agents enhanced cell survival by seven- to nine-fold. To establish whether a similar zinc-induced protective response could be elicited in vivo, a set of preliminary experiments was carried out in which Balb/cJ mice were treated with zinc chloride (2 mg/kg body weight) or saline by intraperitoneal (ip) injection at 48, 36, 24, and 12 h before ip administration of 4 mg/kg of the alkylating agent nitrogen mustard. Of the animals that received saline before nitrogen mustard, 57% were killed compared with only 20% in the group treated with zinc before administration of the alkylating agent. These results (which almost certainly were achieved with less than optimal induction conditions) provide evidence for the existence, in vivo, of a zinc-inducible process that reduces alkylating agent lethality. 12 refs., 4 figs.

Shackelford, M.E.; Tobey, R.A.

1988-12-01T23:59:59.000Z

274

The development of a micropatterned electrode for studies of zinc electrodeposition  

DOE Green Energy (OSTI)

A micropatterned electrode was prepared for the study of electrocrystallization. Using microphotolithography, in conjunction with evaporation and pulse electrodeposition of thin films, a set of artificially roughened electrodes with hemispherical surface features five microns in diameter was developed. Voltammetric studies were conducted to determine the best electrode material. Gold, platinum, and various carbon surfaces were evaluated for zinc nucleation density and hydrogen overpotential. Surface homogeneity was examined by both light and scanning electron microscopy. Gold was determined to possess the best combination of material properties: chemical inertness, low melting point, and a high work function allowing underpotential deposition of zinc which reduces the rate of hydrogen evolution. Stripping coulometry was employed to determine zinc limiting currents, and evaluate effective diffusion coefficients in concentrated zinc chloride solutions. Although the method worked well for dilute zinc chloride and copper sulfate solutions, it failed at higher current densities; the emergence of surface roughness obscured actual limiting current plateaus.

Sutija, D.P.; Muller, R.H.; Tobias, C.W.

1986-12-01T23:59:59.000Z

275

Thermal Degradation of Single Crystal Zinc Oxide and the Growth of Nanostructures  

SciTech Connect

Heat treatment of (0001) single crystal zinc oxide (ZnO) seems to degrade the surface morphology at high temperature. The degradation, however, does not suppress the growth of ZnO nanostructures on selective regions of the single crystal ZnO that have been sputtered with metallic zinc (Zn) and annealed at 800 degree sign C. On the uncoated regions, no growth occurs but the presence of pits suggests material loss from the surface. The formation of ZnO nanostructures on the selective regions could be aided by the preferential loss of oxygen as well as zinc suboxides from the uncoated regions. Indirect evidence of the role of oxygen and zinc suboxides can be inferred from the formation of nickel zinc oxide Ni{sub 0.9}Zn{sub 0.1}O and nickel oxide NiO{sub 2} when Zn is replaced by Ni and annealed under similar conditions.

Saw, K. G.; Tan, G. L. [Physics Section, School of Distance Education, Universiti Sains Malaysia, 11800 Penang (Malaysia); Hassan, Z.; Yam, F. K.; Ng, S. S. [Schools of Physics, Universiti Sains Malaysia, 11800 Penang (Malaysia)

2010-07-07T23:59:59.000Z

276

Zinc Uptake and Radial Transport in Roots of Arabidopsis thaliana: A Modelling Approach to Understand Accumulation  

E-Print Network (OSTI)

Zinc uptake in roots is believed to be mediated by ZIP (ZRT-, IRT- like Proteins) transporters. Once inside the symplast, zinc is transported to the pericycle, where it exits by means of HMA (Heavy Metal ATPase) transporters. The combination of symplastic transport and spatial separation of influx and efflux produces a pattern in which zinc accumulates in the pericycle. Here, mathematical modelling was employed to study the importance of ZIP regulation, HMA level and symplastic transport in creation of the radial pattern of zinc in primary roots of Arabidopsis thaliana. A comprehensive one-dimensional dynamical model of radial zinc transport in roots was developed and used to conduct simulations. The model accounts for the structure of the root consisting of symplast and apoplast and includes effects of water flow, diffusion, and cross-membrane transport via transporters. It also incorporates the radial geometry and varying porosity of root tissues, as well as regulation of ZIP transporters. Steady state patt...

Claus, Juliane; Chavarra-Krauser, Andrs

2012-01-01T23:59:59.000Z

277

Research on separators for alkaline zinc batteries. Final report  

Science Conference Proceedings (OSTI)

This project is concerned with the research and development of a hybrid separator as an improved battery separator in alkaline zinc secondary batteries. Particular emphasis has been directed toward mitigating the failure of zinc electrodes by controlling the permselectivity of the separator. Hybrid separators were synthesized and fabricated. These separators consist of a microporous film, radiation-grafted with a monomer containing ion-exchange groups. The new separator incorporates the favorable aspects of both ion-exchange membranes and microporous separators. Such a hybrid separator should ideally be highly specific for fast transport of electrolyte while inhibiting zincate diffusion. Hybrid separators with a wide range of percent graft (0 to 60%) were made by varying the monomer concentration and radiation time. The grafting of these ionic groups imparts the ion selectivity of the separators. The electrolyte uptake of hybrid separators is ca. 60 wt %. The higher the percent graft of the separator, the higher the water uptake and the lower the KOH uptake that are observed. The permeabilities of zincate ions were measured for a series of hybrid separators.

Yeo, R.S.

1984-10-01T23:59:59.000Z

278

Induced Positron Annihiliation Investigation of Cadmium Zinc Telluride Crystal Microstructures  

Science Conference Proceedings (OSTI)

Cadmium-Zinc-Telluride (CZT) crystals are used in semiconductor radiation detectors for the detection of x-ray and gamma radiation. However, production of detector grade crystals is difficult as small variations in compositional uniformity and primarily the zinc content can significantly affect the ability of the CZT crystal to function as a radiation detector. Currently there are no known nondestructive methods that can be used to identify detector grade crystals. The current test method is to fabricate and test the detector to determine if the crystal is sufficiently uniform and of the correct composition to be considered a detector grade crystal. Consequently, nondestructive detection methods are needed to identify detector grade crystals prior to the fabrication process. The purpose of this feasibility study was to perform a preliminary assessment of the ability of several new, nondestructive technologies based on Induced Positron Annihilation (IPA) to determine if detector grade CZT crystals can be identified. Results of measurements performed on specimens from Fisk University and EV Products, Inc. indicate that both the near surface Distributed Source Positron Annihilation (up to 3 mm penetration) and the volumetric Photon Induced Positron Annihilation methods may be suitable for determining CZT crystal quality. Further work on CZT crystals with a broader range of compositions and detector characteristics is needed to provide a well defined, calibrated, method for assessing CZT crystal quality.

D. W. Akers

2005-06-01T23:59:59.000Z

279

PDF Application  

Science Conference Proceedings (OSTI)

?Computer Applications and Process Control. ?Copper Nickel and Cobalt ... ? Iron and Steel. ?Joining. ?Lead Zinc and Tin. ?Lightweight Materials.

280

PDF Application  

Science Conference Proceedings (OSTI)

Copper Nickel and Cobalt education electrometallurgy electronic materials energy ... Lead Zinc and tin. Lightweight materials magnesium manufacturing and...

Note: This page contains sample records for the topic "zinc tin selenium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Absorption of zinc and iron by rats fed meals containing sorghum food products  

Science Conference Proceedings (OSTI)

Zinc and iron absorption from freeze-dried traditionally-prepared sorghum food products was studied in rats. After a period of marginal zinc or iron depletion, rats were fed test meals containing 1 of 4 sorghum foods cooked maize gruel or an inorganic mineral each of which was extrinsically labeled with either /sup 65/Zn or /sup 59/Fe before being added to the diets. Absorption was determined by whole body percent retention of the initial radioisotope dose over a period of 19 days. Iron was highly available from all products tested (75-83%) with no significant differences in absorption among groups (p>0.05). Zinc from fermented Aceta (97%) was more available than that from the other sorghum products (69-78%) or maize gruel (76%). Zinc from acid To (78%) and Aceta (97%) was as available as that from zinc oxide in the control diet (93%) (p>0.05). There were no significant differences in zinc absorption among groups fed Acid To (78%), neutral To (76), alkali To (69%) or maize gruel (76%) (psorghum foods. Iron and zinc were highly available from all sorghum foods. Reduction phytate by fermentation increased Zn availability.

Stuart, S.M.A.; Johnson, P.E.; Hamaker, B.; Kirleis, A.

1986-03-05T23:59:59.000Z

282

Transparent and Conductive Carbon Nanotube Multilayer Thin Films Suitable as an Indium Tin Oxide Replacement  

E-Print Network (OSTI)

Transparent electrodes made from metal oxides suffer from poor flexibility and durability. Highly transparent and electrically conductive thin films based on carbon nanotubes (CNTs) were assembled as a potential indium tin oxide (ITO) replacement using layer-by-layer (LbL) assembly. The ultimate objective of this dissertation work is to produce CNT-based assemblies with sheet resistance below 100 Omega/sq and visible light transmission greater than 85 percent. The alternate deposition of positively charged poly(diallyldimethylammonium chloride) [PDDA] and CNTs stabilized with negatively charged deoxycholate (DOC) exhibit linear film growth and thin film properties can be precisely tuned. Ellipsometry, quartz crystal microbalance, and UV-vis were used to measure the growth of these films as a function of PDDA-CNT bilayers deposited, while TEM, SEM, and AFM were used to visualize the nanostructure of these films. Following a literature review describing potential ITO substitutes and LbL technology, the influence of CNT type on optoelectronic performance of LbL assemblies is described. Three different types of nanotubes were investigated: (1) multiwalled carbon nanotubes (MWNTs), (2) few-walled carbon nanotubes (FWNT), and (3) purified single-walled carbon nanotubes (SWNTs). SWNTs produced the most transparent (>85 percent visible light transmittance) and electrically conductive (148 S/cm, 1.62 kOmega/sq) 20-bilayer films with a 41.6 nm thickness, while MWNT-based films are much thicker and more opaque. A 20-bilayer PDDA/(MWNT DOC) film is approximately 103 nm thick, with a conductivity of 36 S/cm and a transmittance of 30 percent. In an effort to improve both transparency and electrical conductivity, heat and acid treatments were studied. Heating films to 300 degree C reduced sheet resistance to 701 Omega/sq (618 S/cm conductivity, 38.4 nm thickness), with no change in transparency, owing to the removal of insulating component in the film. Despite improving conductivity, heating is not compatible with most plastic substrates, so acid doping was investigated as an alternate means to enhance properties. Exposing SWNT-based assemblies to HNO3 vapor reduced sheet resistance of a 10 BL film to 227 Omega/sq. Replacing SWNTs with double walled carbon nanotubes (DWNTs) provided further reduction in sheet resistance due to the greater metallic of DWNT. A 5 BL DWNT film exhibited the lowest 104 Omega/sq sheet resistance (4200 S/cm conductivity, 22.9 nm thickness) with 84 percent transmittance after nitric acid treatment. DWNT-based assemblies maintained their low sheet resistance after repeated bending and also showed electrochemical stability relative to ITO. This work demonstrates the excellent optoelectronic performance, mechanical flexibility, and electrochemical stability of CNT-based assemblies, which are potentially useful as flexible transparent electrodes for a variety of flexible electronics.

Park, Yong Tae

2011-05-01T23:59:59.000Z

283

The analysis of cross-sections of proton and deuteron induced reactions on tin isotopes at the beam energy of 3.65 GeV/nucleon  

E-Print Network (OSTI)

In the given paper the total inelastic cross-sections of the reactions of protons and deuterons on nuclear targets of enriched tin isotopes were compared. The factorization of cross-sections of reactions was discussed. Furthermore, the comparison of theoretical estimations on total inelastic cross-sections with corresponding experimental ones was made.

A. R. Balabekyan; N. A. Demekhina; V. M. Zhamkochyan; G. S. Karapetyan

2013-02-07T23:59:59.000Z

284

Light output enhancement of InGaN/GaN light-emitting diodes with contrasting indium tin-oxide nanopatterned structures  

Science Conference Proceedings (OSTI)

Various nanopatterns on the transparent conducting indium tin oxide (ITO) layer are investigated to enhance the light extraction efficiency of the InGaN/GaN light-emitting diodes (LEDs). Triangular, square, and circular nanohole patterns with the square ...

Sang Hyun Jung, Keun Man Song, Young Su Choi, Hyeong-Ho Park, Hyun-Beom Shin, Ho Kwan Kang, Jaejin Lee

2013-01-01T23:59:59.000Z

285

Growth and Properties of (001)-oriented Pb(Zr?.??Ti?.??)O?/LaNiO? Films on Si(001) Substrates with TiN Buffer Layers  

E-Print Network (OSTI)

Pulsed laser deposition has been used to grow Pb(Zr?.??Ti?.??)O? (PZT)/LaNiO? (LNO) heterostructures with restricted crystallographic orientations on bare Si(001) and SiO?-coated Si(001) substrates, using TiN buffer layers. ...

Zhu, Tie-Jun

286

A new high energy stabilized nickel-zinc rechargeable battery system for SLI and EV applications  

SciTech Connect

The nickel oxide-zinc rechargeable battery system is a serious candidate for a high power economical EV battery. The introduction of a new chemistry has resulted in stabilization of the performance of the zinc anode without adversely affecting the nickel electrode. The result has been a major enhancement of the cycle life capability with retention of the remarkably high practical energy density (both gravimetric and volumetric) of the nickel-zinc system. Near term practical applications for both passenger car truck SLI batteries as well as long term deep cycle applications for electric vehicles are discussed.

Reisner, D.; Eisenberg, M.

1989-01-01T23:59:59.000Z

287

Partitioning of mercury, arsenic, selenium, boron, and chloride in a full-scale coal combustion process equipped with selective catalytic reduction, electrostatic precipitation, and flue gas desulfurization systems  

SciTech Connect

A full-scale field study was carried out at a 795 MWe coal-fired power plant equipped with selective catalytic reduction (SCR), an electrostatic precipitator (ESP), and wet flue gas desulfurization (FGD) systems to investigate the distribution of selected trace elements (i.e., mercury, arsenic, selenium, boron, and chloride) from coal, FGD reagent slurry, makeup water to flue gas, solid byproduct, and wastewater streams. Flue gases were collected from the SCR outlet, ESP inlet, FGD inlet, and stack. Concurrent with flue gas sampling, coal, bottom ash, economizer ash, and samples from the FGD process were also collected for elemental analysis. By combining plant operation parameters, the overall material balances of selected elements were established. The removal efficiencies of As, Se, Hg, and B by the ESP unit were 88, 56, 17, and 8%, respectively. Only about 2.5% of Cl was condensed and removed from flue gas by fly ash. The FGD process removed over 90% of Cl, 77% of B, 76% of Hg, 30% of Se, and 5% of As. About 90% and 99% of the FGD-removed Hg and Se were associated with gypsum. For B and Cl, over 99% were discharged from the coal combustion process with the wastewater. Mineral trona (trisodium hydrogendicarbonate dehydrate, Na{sub 3}H(CO{sub 3}){sub 2}.2H{sub 2}O) was injected before the ESP unit to control the emission of sulfur trioxide (SO{sub 3}). By comparing the trace elements compositions in the fly ash samples collected from the locations before and after the trona injection, the injection of trona did not show an observable effect on the partitioning behaviors of selenium and arsenic, but it significantly increased the adsorption of mercury onto fly ash. The stack emissions of mercury, boron, selenium, and chloride were for the most part in the gas phase. 47 refs., 3 figs., 11 tabs.

Chin-Min Cheng; Pauline Hack; Paul Chu; Yung-Nan Chang; Ting-Yu Lin; Chih-Sheng Ko; Po-Han Chiang; Cheng-Chun He; Yuan-Min Lai; Wei-Ping Pan [Western Kentucky University, Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology

2009-09-15T23:59:59.000Z

288

Development of Thin Section Zinc Die Casting Technology  

SciTech Connect

A new high fluidity zinc high pressure die casting alloy, termed the HF alloy, was developed during laboratory trials and proven in industrial production. The HF alloy permits castings to be achieved with section thicknesses of 0.3 mm or less. Technology transfer activities were conducted to develop usage of the HF high fluidity alloy. These included production of a brochure and a one-hour webinar on the HF alloy. The brochure was then sent to 1,184 product designers in the Interzinc database. There was excellent reception to this mailing, and from this initial contact 5 technology transfer seminars were conducted for 81 participants from 30 companies across a wide range of business sectors. Many of the successful applications to date involve high quality surface finishes. Design and manufacturing assistance was given for development of selected applications.

Goodwin, Frank [International Lead Zinc Research Org., Inc.] [International Lead Zinc Research Org., Inc.

2013-10-31T23:59:59.000Z

289

Study on thermal annealing of cadmium zinc telluride (CZT) crystals  

Science Conference Proceedings (OSTI)

Cadmium Zinc Telluride (CZT) has attracted increasing interest with its promising potential as a room-temperature nuclear-radiation-detector material. However, different defects in CZT crystals, especially Te inclusions and dislocations, can degrade the performance of CZT detectors. Post-growth annealing is a good approach potentially to eliminate the deleterious influence of these defects. At Brookhaven National Laboratory (BNL), we built up different facilities for investigating post-growth annealing of CZT. Here, we report our latest experimental results. Cd-vapor annealing reduces the density of Te inclusions, while large temperature gradient promotes the migration of small-size Te inclusions. Simultaneously, the annealing lowers the density of dislocations. However, only-Cd-vapor annealing decreases the resistivity, possibly reflecting the introduction of extra Cd in the lattice. Subsequent Te-vapor annealing is needed to ensure the recovery of the resistivity after removing the Te inclusions.

Yang, G.; Bolotnikov, A.E.; Fochuk, P.M.; Camarda, G.S.; Cui, Y.; Hossain, A.; Kim, K.; Horace, J.; McCall, B.; Gul, R.; Xu, L.; Kopach, O.V.; and James, R.B.

2010-08-01T23:59:59.000Z

290

Electric Field Distribution of Cadmium Zinc Telluride (CZT)  

Science Conference Proceedings (OSTI)

Cadmium Zinc Telluride (CZT) is attracting increasing interest with its promise as a room-temperature nuclear-radiation-detector material. The distribution of the electric field in CZT detectors substantially affects their detection performance. At Brookhaven National Laboratory (BNL), we employed a synchrotron X-Ray mapping technique and a Pockels-effect measurement system to investigate this distribution in different detectors. Here, we report our latest experimental results with three detectors of different width/height ratios. A decrease in this ratio aggravates the non-uniform distribution of electric field, and focuses it on the central volume. Raising the bias voltage effectively can minimize such non-uniformity of the electric field distribution. The position of the maximum electric field is independent of the bias voltage; the difference between its maximum- and minimum-intensity of electric field increases with the applied bias voltage.

Yang,G.; Bolotnikov, A.; Camarda, G.S.; Cui, Y.; Hossain, A.; Kim, K.; James, R.B.

2009-08-02T23:59:59.000Z

291

Ion Beam Layer Separation of Cadmium Zinc Telluride  

Science Conference Proceedings (OSTI)

We have investigated the approach of ion induced layer separation process for layer splitting from Cadmium Zinc Telluride (CZT) bulk single crystal and transferring and bonding the separated layers with Silicon (Si) wafers. Layer separation experiments have been carried out at UES using 1 MeV H{sup +} ions from the high energy accelerator (1.7 MV Tandetron). Ion dose and annealing temperature for complete separation of 1 cmx1 cm size layers have been optimized. Bonding of CZT with Si was accomplished using various IR transmitting chalcogenide glasses. Cracking of separated CZT films was occurring for chalcogenide glass bonded films. Optimization of thermal treatment has led to the minimization of such cracks. Detailed characterizations of the separated films will be presented.

Bhattacharya, Rabi S.; He, P.; Xu, Y. [UES, Inc. 4401 Dayton-Xenia Road, Dayton, OH 45432 (United States); Goorsky, M. [University of California at Los Angeles, 10920 Wilshire Blvd, Suite 107, Los Angeles CA 90024 (United States)

2008-11-03T23:59:59.000Z

292

(001) textured L1{sub 0}-FePt pseudo spin valve with TiN spacer  

Science Conference Proceedings (OSTI)

TiN was investigated as a potential spacer material in L1{sub 0}-FePt based pseudo spin valves (PSV). PSVs with the structure MgO/L1{sub 0}-Fe{sub 50}Pt{sub 50} (20 nm)/TiN (5 nm)/L1{sub 0}-Fe{sub 50}Pt{sub 50} (x nm) were fabricated, where x was varied from 5 to 20 nm. The highest giant magnetoresistance (GMR) ratio of 0.61% was obtained for the PSV with a top L1{sub 0}-FePt thickness of 20 nm. Contributions to the GMR arose from both the spin dependent scattering at the FePt/TiN interfaces and domain wall resistivity. Magnon magnetoresistance was also observed in the fabricated PSVs.

Ho, P. [Department of Materials Science and Engineering, National University of Singapore, 117576 Singapore (Singapore) and Data Storage Institute, Agency of Science, Technology and Research (A-STAR), 117608 Singapore (Singapore); Han, G. C. [Data Storage Institute, Agency of Science, Technology and Research (A-STAR), 117608 Singapore (Singapore); He, K. H.; Chow, G. M.; Chen, J. S. [Department of Materials Science and Engineering, National University of Singapore, 117576 Singapore (Singapore)

2011-12-19T23:59:59.000Z

293

Reversible wettability of electron-beam deposited indium-tin-oxide driven by ns-UV irradiation  

Science Conference Proceedings (OSTI)

Indium tin oxide (ITO) is one of the most widely used semiconductor oxides in the field of organic optoelectronics, especially for the realization of anode contacts. Here the authors report on the control of the wettability properties of ITO films deposited by reactive electron beam deposition and irradiated by means of nanosecond-pulsed UV irradiation. The enhancement of the surface water wettability, with a reduction of the water contact angle larger than 50 deg., is achieved by few tens of seconds of irradiation. The analyzed photo-induced wettability change is fully reversible in agreement with a surface-defect model, and it can be exploited to realize optically transparent, conductive surfaces with controllable wetting properties for sensors and microfluidic circuits.

Persano, Luana [NNL, National Nanotechnology Laboratory of CNR-Istituto Nanoscienze, Universita del Salento, via Arnesano, I-73100 Lecce (Italy); Center for Biomolecular Nanotechnologies UNILE, Istituto Italiano di Tecnologia, Via Barsanti, I-73010 Arnesano-LE (Italy); Del Carro, Pompilio [NNL, National Nanotechnology Laboratory of CNR-Istituto Nanoscienze, Universita del Salento, via Arnesano, I-73100 Lecce (Italy); Pisignano, Dario [NNL, National Nanotechnology Laboratory of CNR-Istituto Nanoscienze, Universita del Salento, via Arnesano, I-73100 Lecce (Italy); Center for Biomolecular Nanotechnologies UNILE, Istituto Italiano di Tecnologia, Via Barsanti, I-73010 Arnesano-LE (Italy); Dipartimento di Matematica e Fisica ''Ennio De Giorgi'', Universita del Salento, via Arnesano, I-73100 Lecce (Italy)

2012-04-09T23:59:59.000Z

294

Alkaline earth lead and tin compounds Ae2Pb, Ae2Sn, Ae=Ca,Sr,Ba, as thermoelectric materials  

SciTech Connect

We present a detailed theoretical study of three alkaline earth compounds Ca2Pb, Sr2Pb and Ba2Pb, which have undergone little previous study, calculating electronic band structures and Boltzmann transport and bulk moduli using density functional theory. We also study the corresponding tin compounds Ca2 Sn, Sr2 Sn and Ba2 Sn. We find that these are all narrow band gap semiconductors with an electronic structure favorable for thermoelectric performance, with substantial thermopowers for the lead compounds at temperature ranges from 300 to 800 K. For the lead compounds, we further find very low calculated bulk moduli - roughly half of the values for the lead chalcogenides, suggestive of soft phonons and hence low lattice thermal conductivity. All these facts indicate that these materials merit experimental investigation as potential high performance thermoelectrics. We find good potential for thermoelectric performance in the environmentally friendly stannide materials, particularly at high temperature.

Parker, David S [ORNL; Singh, David J [ORNL

2013-01-01T23:59:59.000Z

295

COAL LIQUEFACTION USING ZINC CHLORIDE CATALYST IN AN EXTRACTING SOLVENT MEDIUM  

E-Print Network (OSTI)

Rate Data o a o u a a Catalyst Loading . Reaction Time . and Pressure Effect of CO-catalysts and Additives .Co-catalysts a. Zinc Metal b. Nickel and Nickel

Gandhi, Shamim Ahmed

2013-01-01T23:59:59.000Z

296

Relating the biogeochemistries of zinc, cobalt, and phosphorus to phytoplankton activities in the sea  

E-Print Network (OSTI)

This thesis explores the potential of zinc, cobalt, and phosphorus to influence primary production in the subarctic North Pacific, the Bering Sea, and the North Atlantic Ocean. In the North Pacific and Bering Sea, total ...

Wisniewski, Rachel J. (Rachel Jane), 1978-

2006-01-01T23:59:59.000Z

297

ESS 2012 Peer Review - Flow-Assisted Zinc Anode Batteries for...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

6&91&>09-+&@C:40(:&O7B0& %.PQRR340(+;"""GS8P(+:S:75& FLOW-ASSISTED ZINC ANODE BATTERIES FOR GRID-SCALE ELECTRICITY STORAGE Prof. Sanjoy Banerjee, banerjee@che.ccny.cuny.e...

298

Biochemistry of mobile zinc and nitric oxide revealed by fluorescent sensors  

E-Print Network (OSTI)

Biological mobile zinc and nitric oxide (NO) are two prominent examples of inorganic compounds involved in numerous signaling pathways in living systems. In the past decade, a synergy of regulation, signaling, and translocation ...

Pluth, Michael D.

299

Fabrication and corrosion resistance of superhydrophobic hydroxide zinc carbonate film on aluminum substrates  

Science Conference Proceedings (OSTI)

Superhydrophobic hydroxide zinc carbonate (HZC) films were fabricated on aluminum substrate through a convenient in situ deposition process. Firstly, HZC films with different morphologies were deposited on aluminum substrates through immersing the aluminum ...

Jin Liang, Yunchu Hu, Yiqiang Wu, Hong Chen

2013-01-01T23:59:59.000Z

300

C:\Documents and Settings\burris\My Documents\My Files\Eco-SSLs\Contaminant Specific Documents\Zinc\June 2007\Eco-SSL for Zinc  

NLE Websites -- All DOE Office Websites (Extended Search)

Zinc Zinc Interim Final OSWER Directive 9285.7-73 U.S. Environmental Protection Agency Office of Solid Waste and Emergency Response 1200 Pennsylvania Avenue, N.W. Washington, DC 20460 June 2007 This page intentionally left blank i TABLE OF CONTENTS 1.0 INTRODUCTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 2.0 SUMMARY OF ECO-SSLs FOR ZINC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 3.0 ECO-SSL FOR TERRESTRIAL PLANTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 4.0 ECO-SSL FOR SOIL INVERTEBRATES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 5.0 ECO-SSL FOR AVIAN WILDLIFE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 5.1 Avian TRV . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 5.2 Estimation of Dose and Calculation of the Eco-SSL . . . . . . . . . . . . . . . . . . . . . . . 14 6.0 ECO-SSL FOR MAMMALIAN WILDLIFE .

Note: This page contains sample records for the topic "zinc tin selenium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

EPNews2009Winter  

NLE Websites -- All DOE Office Websites (Extended Search)

are arsenic, iron, magnesium, chromium, zinc, boron, barium, selenium, and manganese. Oil shale produced waters are typically derived from retorting, mine drainage, and leachate...

302

Research, development and demonstration of nickel-zinc batteries for electric vehicle propulsion. Annual report for 1978  

DOE Green Energy (OSTI)

This is the first annual report describing progress in the 33-month cooperative program between Argonne National Laboratory and Gould Inc.'s Nickel-Zinc/Electric Vehicle Project. The purpose of the program is to demonstrate the technical and economic feasibility of the nickel-zinc battery for electric vehicle propulsion. The successful completion of the program will qualify the nickel-zinc battery for use in the Department of Energy's demonstration program under the auspices of Public Law 94-413.

Not Available

1979-10-01T23:59:59.000Z

303

Ordered Nucleation Sites for the Growth of Zinc Oxide Nanofibers  

Science Conference Proceedings (OSTI)

Organic photovoltaics (OPVs) offer a promising route to low cost photovoltaic (PV) technology that can be inexpensively manufactured on a large scale for use in power generation and commercial products. Solar power conversion efficiencies of laboratory scale OPV devices have recently reached ~5%; however, projected efficiencies of at least 10% will be required for commercialization. An analogous approach that has arisen recently that can potentially increase efficiencies employs metal oxide semiconductors as the electron acceptor, creating a hybrid organic-inorganic device. This approach offers the advantage that the conduction band of the oxide can be tuned in a systematic way through doping, thus potentially achieving higher photovoltages in the device. Additionally, nanostructures of these materials can be easily grown from precursor solutions, providing a technique to precisely control the nanoscale geometry. This work focuses on using ZnO, which is known to have high electron mobility (>100 cm2/Vs), as the electron acceptor. Nanofibers of ZnO can be grown from precursors such as zinc acetate or zinc nitrate to form arrays of nanofibers into which a conjugated polymer can be intercalated to form a composite PV device. The morphology of the nanofiber array is critical to the performance of the device, but current methods of nanofiber growth from a flat, polycrystalline nucleation layer allow for little morphological control. To overcome this limitation, we have created ordered arrays of ZnO nucleation sites with controllable size and spacing. Toluene solutions of diblock copolymer micelles with ZnCl2 incorporated into the micellar cores were spin-coated onto glass substrates and etched with an O2 plasma to yield hexagonally ordered arrays of ZnO nanoparticles that functioned as nucleation sites. Changing the concentration of ZnCl2 and the molecular weight and ratio of the diblock copolymer resulted in systematic variation in the size and spacing of the nucleation sites. Thermal anneal treatment provided further modification of the nucleation layer, from which ZnO nanofibers were successfully grown from solution, although at present it is not known if the geometry of the as-grown ZnO nanofibers precisely reflects that of the underlying nucleation layer. This work provides a simple and useful method for potentially controlling the nucleation of ZnO nanofibers to be used in hybrid ZnO/organic nanocomposite PV devices.

Wang, J.; Ginley, D.S.; Shaheen, S.

2006-01-01T23:59:59.000Z

304

ZINC/AIR BATTERY R & D RESEARCH AND DEVELOPMENT OF BIFUNCTIONAL OXYGEN ELECTRODE TASKS I AND II  

E-Print Network (OSTI)

requirements, weight of battery and cost comparisons arecost, convenience and com- plexity of each of the schemes. The following zinc-air battery

Klein, M.

2009-01-01T23:59:59.000Z

305

Understanding the defect structure of solution grown zinc oxide  

Science Conference Proceedings (OSTI)

Zinc oxide (ZnO) is a wide bandgap semiconducting oxide with many potential applications in various optoelectronic devices such as light emitting diodes (LEDs) and field effect transistors (FETs). Much effort has been made to understand the ZnO structure and its defects. However, one major issue in determining whether it is Zn or O deficiency that provides ZnO its unique properties remains. X-ray absorption spectroscopy (XAS) is an ideal, atom specific characterization technique that is able to probe defect structure in many materials, including ZnO. In this paper, comparative studies of bulk and aqueous solution grown ({lighting and other optoelectronic device applications. - Graphical abstract: Highlights: Black-Right-Pointing-Pointer ZnO powders have been synthesized through an aqueous solution method. Black-Right-Pointing-Pointer Defect structure studied using XAS and XPDF. Black-Right-Pointing-Pointer Zn-Zn correlations are less in the ZnO powders synthesized in solution than bulk. Black-Right-Pointing-Pointer Zn vacancies are present in the powders synthesized. Black-Right-Pointing-Pointer EXAFS and XPDF, when used complementary, are useful characterization techniques.

Liew, Laura-Lynn [Institute of Materials Research and Engineering, Agency for Science, Technology and Research (A-STAR), 3 Research Link, Singapore 117602 (Singapore); School of Materials Science and Engineering, Nanyang Technological University, Block N4.1 Nanyang Avenue, Singapore 639798 (Singapore); Sankar, Gopinathan, E-mail: g.sankar@ucl.ac.uk [Department of Chemistry, University College London, 20 Gordon Street, London WC1H 0AJ (United Kingdom); Handoko, Albertus D. [Institute of Materials Research and Engineering, Agency for Science, Technology and Research (A-STAR), 3 Research Link, Singapore 117602 (Singapore); Goh, Gregory K.L., E-mail: g-goh@imre.a-star.edu.sg [Institute of Materials Research and Engineering, Agency for Science, Technology and Research (A-STAR), 3 Research Link, Singapore 117602 (Singapore); School of Materials Science and Engineering, Nanyang Technological University, Block N4.1 Nanyang Avenue, Singapore 639798 (Singapore); Kohara, Shinji [Japan Synchrotron Radiation Research Institute (JASRI), Mikazuki, Sayo, Hyogo 679-5198 (Japan)

2012-05-15T23:59:59.000Z

306

Zinc-chlorine battery plant system and method  

DOE Patents (OSTI)

A zinc-chlorine battery plant system and method of redirecting the electrical current around a failed battery module. The battery plant includes a power conditioning unit, a plurality of battery modules connected electrically in series to form battery strings, a plurality of battery strings electrically connected in parallel to the power conditioning unit, and a bypass switch for each battery module in the battery plant. The bypass switch includes a normally open main contact across the power terminals of the battery module, and a set of normally closed auxiliary contacts for controlling the supply of reactants electrochemically transformed in the cells of the battery module. Upon the determination of a failure condition, the bypass switch for the failed battery module is energized to close the main contact and open the auxiliary contacts. Within a short time, the electrical current through the battery module will substantially decrease due to the cutoff of the supply of reactants, and the electrical current flow through the battery string will be redirected through the main contact of the bypass switch.

Whittlesey, Curtis C. (Birmingham, MI); Mashikian, Matthew S. (Huntington Woods, MI)

1981-01-01T23:59:59.000Z

307

Proof-of-concept zinc/bromine electric vehicle battery  

SciTech Connect

At the inception of the contract, Johnson Controls acquired and tested the zinc/bromine battery design developed by Exxon Research and Engineering Corporation (the Z-design) and, with Exxon, determined the key problems in this design: expansion and warping of electrodes, leaking of electrolyte from the battery stack, and excessive self-discharge brought about by transfer of bromine across the separator. The problems of electrode expansion and high self-discharge were mitigated by developing improved electrode and separator materials. Starting in the second year of the contract, JCI developed a new V-design battery stack which used different hardware and tooling to address the problem of stack leakage. The V-design uses thermal welding to achieve a hermetically sealed construction. The flow distribution is improved, and the massive endblocks of the original system have been replaced by thinner, lighter endblocks which are stiffened by means of rigid aluminum honeycomb inserts. Highlights of performance characteristics of batteries built and tested under the contract given. The battery was developed for the ETX-II, a Ford Aerostar minivan. 44 figs., 21 tabs.

Bolsted, J.; Eidler, P.; Miles, R.; Petersen, R.; Yaccarino, K. (Johnson Controls, Inc., Milwaukee, WI (USA). Advanced Battery Engineering); Lott, S. (Sandia National Labs., Albuquerque, NM (USA))

1991-04-01T23:59:59.000Z

308

Root Uptake of Lipophilic Zinc?Rhamnolipid Complexes  

Science Conference Proceedings (OSTI)

This study investigated the formation and plant uptake of lipophilic metal-rhamnolipid complexes. Monorhamnosyl and dirhamnosyl rhamnolipids formed lipophilic complexes with copper (Cu), manganese (Mn), and zinc (Zn). Rhamnolipids significantly increased Zn absorption by Brassica napus var. Pinnacle roots in {sup 65}Zn-spiked ice-cold solutions, compared with ZnSO{sub 4} alone. Therefore, rhamnolipid appeared to facilitate Zn absorption via a nonmetabolically mediated pathway. Synchrotron XRF and XAS showed that Zn was present in roots as Zn-phytate-like compounds when roots were treated with Zn-free solutions, ZnSO{sub 4}, or Zn-EDTA. With rhamnolipid application, Zn was predominantly found in roots as the Zn-rhamnolipid complex. When applied to a calcareous soil, rhamnolipids increased dry matter production and Zn concentrations in durum (Triticum durum L. cv. Balcali-2000) and bread wheat (Triticum aestivum L. cv. BDME-10) shoots. Rhamnolipids either increased total plant uptake of Zn from the soil or increased Zn translocation by reducing the prevalence of insoluble Zn-phytate-like compounds in roots.

Stacey, Samuel P.; McLaughlin, Michael J.; Cakmak, Ismail; Hettiarachchi, Ganga M.; Scheckel, Kirk G.; Karkkainen, Michael (Sabanci); (EPA); (CSIRO/LW); (Adelaide)

2009-06-16T23:59:59.000Z

309

PROMOTED ZINC CHROMITE CATALYSTS FOR HIGHER ALCOHOL SYNTHESIS  

DOE Green Energy (OSTI)

This report describes the analytical protocols that were developed during the last two years to analyze ''spent'' THQ (tetrahydroquinoline) slurry liquid. Identification of the components of the ''spent'' THQ should help to understand the influence of the slurry medium on the methanol synthesis reaction, and on other reactions with THQ as the slurry liquid. Silica gel liquid chromatography and high performance liquid chromatography (HPLC) were used to isolate and purify the major compounds in the ''spent'' slurry liquid. Gas chromatography/mass spectroscopy (GC/MS), Fourier transform infrared (FTIR) and nuclear magnetic resonance (NMR) were applied to identify the major compounds. Methyl-, dimethyl-, and trimethyl-THQ were found to comprise more than 80% of the ''spent'' liquid. The balance was various methylated indoles. A methyl group always is attached to the N atom in the ring structure. Speculative mechanisms are presented that may help to understand the interaction between the catalyst and the alkylated THQ slurry liquid, and the effect of liquid composition on the methanol synthesis reaction. A poster entitled ''Promoted Zinc Chromite Catalyst for Higher Alcohol Synthesis in a Slurry Reactor-2. Spent Liquid Analysis'' was presented at the AIChE National Meeting, Los Angeles, CA, Nov 12-17, 2000.

Ms. Xiaolei Sun; Professor George W. Roberts

2001-06-15T23:59:59.000Z

310

PROMOTED ZINC CHROMITE CATALYSTS FOR HIGHER ALCOHOL SYNTHESIS  

SciTech Connect

During this reporting period, a ''zinc chromite'' catalyst promoted with 6 wt.% cesium (Cs) was evaluated at the following conditions: Temperature--375 C; Total Pressure--6.8 MPa (1000 psig); Gas Hourly Space Velocity (GHSV) - 5000 standard liters/kg(cat)-hr, and; H{sub 2}/CO feed ratio--1.0 mole/mole. Decahydronaphthalene (DHN) was used as the slurry liquid. The experiment lasted for eight days of continuous operation. Although the experimental data once again did not exhibit the desired degree of consistency, the data did show that methanol was the primary reaction product. The slurry liquid did not decompose or alkylate to a measurable extent during the continuous 8-day experiment. There was a relatively significant loss of catalyst surface area during the experiment. Gas chromatography/mass spectrometry (GC/MS) analysis of various fractions of ''spent'' THQ was carried out. The fractions were prepared by silica gel liquid chromatography (LC). Chemical formuli and probable structures for each major compound were obtained. However, a higher degree of purification will be necessary to allow nuclear magnetic resonance (NMR) analysis to be used for definitive compound identification. A new Maxpro gas booster (DLE 15-75) was purchased because the existing Haskel gas booster once again developed a severe leak of carbon monoxide and hydrogen, and was judged to be unworthy of repair.

Ms. Xiaolei Sun; Professor George W. Roberts

2000-08-29T23:59:59.000Z

311

Ambient temperature cadmium zinc telluride radiation detector and amplifier circuit  

DOE Patents (OSTI)

A low noise, low power consumption, compact, ambient temperature signal amplifier for a Cadmium Zinc Telluride (CZT) radiation detector. The amplifier can be used within a larger system (e.g., including a multi-channel analyzer) to allow isotopic analysis of radionuclides in the field. In one embodiment, the circuit stages of the low power, low noise amplifier are constructed using integrated circuit (IC) amplifiers , rather than discrete components, and include a very low noise, high gain, high bandwidth dual part preamplification stage, an amplification stage, and an filter stage. The low noise, low power consumption, compact, ambient temperature amplifier enables the CZT detector to achieve both the efficiency required to determine the presence of radio nuclides and the resolution necessary to perform isotopic analysis to perform nuclear material identification. The present low noise, low power, compact, ambient temperature amplifier enables a CZT detector to achieve resolution of less than 3% full width at half maximum at 122 keV for a Cobalt-57 isotope source. By using IC circuits and using only a single 12 volt supply and ground, the novel amplifier provides significant power savings and is well suited for prolonged portable in-field use and does not require heavy, bulky power supply components.

McQuaid, James H. (Livermore, CA); Lavietes, Anthony D. (Hayward, CA)

1998-05-29T23:59:59.000Z

312

Ambient temperature cadmium zinc telluride radiation detector and amplifier circuit  

DOE Patents (OSTI)

A low noise, low power consumption, compact, ambient temperature signal amplifier for a Cadmium Zinc Telluride (CZT) radiation detector is disclosed. The amplifier can be used within a larger system (e.g., including a multi-channel analyzer) to allow isotopic analysis of radionuclides in the field. In one embodiment, the circuit stages of the low power, low noise amplifier are constructed using integrated circuit (IC) amplifiers , rather than discrete components, and include a very low noise, high gain, high bandwidth dual part preamplification stage, an amplification stage, and an filter stage. The low noise, low power consumption, compact, ambient temperature amplifier enables the CZT detector to achieve both the efficiency required to determine the presence of radionuclides and the resolution necessary to perform isotopic analysis to perform nuclear material identification. The present low noise, low power, compact, ambient temperature amplifier enables a CZT detector to achieve resolution of less than 3% full width at half maximum at 122 keV for a Cobalt-57 isotope source. By using IC circuits and using only a single 12 volt supply and ground, the novel amplifier provides significant power savings and is well suited for prolonged portable in-field use and does not require heavy, bulky power supply components. 9 figs.

McQuaid, J.H.; Lavietes, A.D.

1998-05-26T23:59:59.000Z

313

INTERIM RESULTS FROM A STUDY OF THE IMPACTS OF TIN(II) BASED MERCURY TREATMENT IN A SMALL STREAM ECOSYSTEM: TIMS BRANCH, SAVANNAH RIVER SITE  

Science Conference Proceedings (OSTI)

Mercury (Hg) has been identified as a 'persistent, bioaccumulative and toxic' pollutant with widespread impacts throughout North America and the world (EPA. 1997a, 1997b, 1998a, 1998b, 2000). Although most of the mercury in the environment is inorganic Hg, a small proportion of total Hg is transformed through the actions of aquatic microbes into methylmercury (MeHg). In contrast to virtually all other metals, MeHg biomagnifies or becomes increasingly concentrated as it is transferred through aquatic food chains so that the consumption of mercury contaminated fish is the primary route of this toxin to humans. For this reason, the ambient water quality criterion (AWQC) for mercury is based on a fish tissue endpoint rather than an aqueous Hg concentration, as the tissue concentration (e.g., fish are more closely linked to aqueous MeHg than to inorganic Hg concentrations (Sveinsdottir and Mason 2005), but MeHg production is not easily predicted or controlled. At point-source contaminated sites, mercury methylation is not only affected by the absolute mercury load, but also by the form of mercury loaded. In addition, once MeHg is formed, the hydrology, trophic structure, and water chemistry of a given system affect how it is transformed and transferred through the food chain to fish. Decreasing inorganic Hg concentrations and loading may often therefore be a more achievable remediation goal, but has led to mixed results in terms of responses in fish bioaccumulation. A number of source control measures have resulted in rapid responses in lake or reservoir fisheries (Joslin 1994, Turner and Southworth 1999; Orihel et al., 2007), but examples of similar responses in Hg-contaminated stream ecosystems are less common. Recent work suggests that stream systems may actually be more susceptible to mercury bioaccumulation than lakes, highlighting the need to better understand the ecological drivers of mercury bioaccumulation in stream-dwelling fish (Chasar et al. 2009, Ward et al. 2010). In the present study we examine the response of fish to remedial actions in Tims Branch, a point-source contaminated stream on the Department of Energy's (DOE) Savannah River Site in Aiken, South Carolina. This second order stream received inorganic mercury inputs at its headwaters from the 1950s-2000s which contaminated the water, sediments, and biota downstream. In 2007, an innovative mercury removal system using tin (II) chloride (stannous chloride, SnCl{sub 2}) was implemented at a pre-existing air stripper. Tin(II) reduces dissolved Hg (II) to Hg (0), which is removed by the air stripper. During this process, tin(II) is oxidized to tin (IV) which is expected to precipitate as colloidal tin(IV) oxides and hydroxides, particulate materials with relatively low toxicity (Hallas and Cooney, 1981, EPA 2002, ATSDR, 2005). The objectives of the present research are to provide an initial assessment of the net impacts of the tin(II) based mercury treatment on key biota and to document the distribution and fate of inorganic tin in this small stream ecosystem after the first several years of operating a full scale system. To support these objectives, we collected fish, sediment, water, invertebrates, and biofilm samples from Tims Branch to quantify the general behavior and accumulation patterns for mercury and tin in the ecosystem and to determine if the treatment process has resulted in: (1) a measurable beneficial impact on (i.e., decrease of) mercury concentration in upper trophic level fish and other biota; this is a key environmental endpoint since reducing mercury concen

Looney, B.; Bryan, L.; Mathews, T.

2012-03-30T23:59:59.000Z

314

Highly conductive indium zinc oxide prepared by reactive magnetron cosputtering technique using indium and zinc metallic targets  

SciTech Connect

Zn-doped In{sub 2}O{sub 3} film is frequently deposited from an oxide target; but the use of metallic target is increasingly expected as preparing the film with comparable properties. This work aimed to prepare a highly conductive and transparent Zn-doped In{sub 2}O{sub 3} thin film on Corning Eagle{sup 2000} glass substrate by magnetron cosputtering method using indium and zinc targets. Structural characterization was performed using x-ray diffraction and x-ray photoelectron spectroscopy. The film had an amorphous structure when the film was prepared on an unheated substrate, but had an In{sub 2}O{sub 3} polycrystalline structure when the film was deposited on 150 and 300 deg. C substrates. The electrical properties of the film were greatly affected by annealing; the Zn-doped In{sub 2}O{sub 3} film had a low resistivity of 6.1x10{sup -4} {Omega} cm and an average transmittance of 81.7% when the film was deposited without substrate heating and followed a 600 deg. C annealing.

Tsai, T. K.; Chen, H. C.; Lee, J. H.; Huang, Y. Y.; Fang, J. S. [Department of Materials Science and Engineering, National Formosa University, Huwei, Yunlin 632, Taiwan (China); LinCo Technology, Taichung 407, Taiwan (China); Department of Materials Science and Engineering, National Formosa University, Huwei, Yunlin 632, Taiwan (China)

2010-05-15T23:59:59.000Z

315

EXAMINATION OF THE OXIDATION PROTECTION OF ZINC COATINGS FORMED ON COPPER ALLOYS AND STEEL SUBSTRATES  

SciTech Connect

The exposure of metallic components at aggressive high temperature environments, usually limit their usage at similar application because they suffer from severe oxidation attack. Copper alloys are used in a wide range of high-quality indoor and outdoor applications, statue parts, art hardware, high strength and high thermal conductivity applications. On the other hand, steel is commonly used as mechanical part of industrial set outs or in the construction sector due to its high mechanical properties. The aim of the present work is the examination of the oxidation resistance of pack cementation zinc coatings deposited on copper, leaded brass and steel substrates at elevated temperature conditions. Furthermore, an effort made to make a long-term evaluation of the coated samples durability. The oxidation results showed that bare substrates appear to have undergone severe damage comparing with the coated ones. Furthermore, the mass gain of the uncoated samples was higher than this of the zinc covered ones. Particularly zinc coated brass was found to be more resistant to oxidation conditions in which it was exposed as it has the lower mass gain as compared to the bare substrates and zinc coated copper. Zinc coated steel was also proved to be more resistive than the uncoated steel.

Papazoglou, M.; Chaliampalias, D.; Vourlias, G.; Pavlidou, E.; Stergioudis, G. [Department of Physics, Aristotle University of Thessaloniki, 541 24 Thessaloniki (Greece); Skolianos, S. [Physical Metallurgy Laboratory, Department of Mechanical Engineering, Aristotle University of Thessaloniki, 541 24, Thessaloniki (Greece)

2010-01-21T23:59:59.000Z

316

Threshold concentrations in zinc-doped lithium niobate crystals and their structural conditionality  

SciTech Connect

On the basis of precise X-ray diffraction study of lithium niobate single crystals of congruent composition and four zinc-doped (at 2.8, 5.2, 7.6, and 8.2 mol %) crystals, structural conditionality of the threshold concentrations of the dopant has been established. At these concentrations, the mechanism of zinc incorporation into crystal changes. As the zinc concentration increases, this element first substitutes excess niobium, localized in lithium positions, with a simultaneous decrease in the number of vacancies in these positions. Then zinc substitutes lithium with formation of new lithium vacancies. When a certain limit on the number of vacancies is reached, zinc begins to substitute niobium in its main positions. This process is naturally accompanied by a decrease in the number of vacancies to their complete disappearance and formation of a self-compensating crystal. The character of the dependence of the crystal physical properties on the dopant concentration changes specifically when the impurity concentration passes through the threshold values.

Chernaya, T. S.; Volk, T. R.; Verin, I. A.; Simonov, V. I., E-mail: simonov@ns.crys.ras.ru [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation)

2008-07-15T23:59:59.000Z

317

Electrochemical studies of the automotive lubricant additive zinc n-dibutyldithiophosphate  

Science Conference Proceedings (OSTI)

Zinc dialkyldithiophosphates (ZDTPs) are widely incorporated in lubricant formulations as antioxidant and antiwear additives. Using the model compound zinc n-dibutyldithiophosphate (Bu-ZDTP) in dimethylformamide (DMF) solution, cyclic voltammetry is applied to a detailed study of Bu-ZDTP electro-oxidation. Bu-ZDTP is shown to be oxidized in a chemically irreversible electron transfer process under diffusion-limited conditions. A similar study of Bu-ZDTP reduction revealed nucleation of zinc at the electrode surface. A chronoamperometric investigation of zinc deposition classified the nucleation according to a progressive mechanism with the diffusion coefficient for Bu-ZDTP in DMF solution as 6.5 {times} 10{sup {minus}6} cm{sup 2}/s. By comparison with diffusion coefficients obtained via Levich analysis of Bu-ZDTP oxidation, the oxidation process is assigned as a two-electron transfer. The use of atomic force microscopy as a means of directly visualizing zinc nuclei formed as a result of Bu-ZDTP reduction is described.

Jacob, S.R.; Compton, R.G. [Oxford Univ. (United Kingdom). Physical and Theoretical Chemistry Lab.

1999-07-01T23:59:59.000Z

318

Zinc Thiolate Reactivity toward Nitrogen Oxides: Insights into the Interaction of Zn[superscript 2+] with S-Nitrosothiols and Implications for Nitric Oxide Synthase  

E-Print Network (OSTI)

Zinc thiolate complexes containing N[subscript 2]S tridentate ligands were prepared to investigate their reactivity toward reactive nitrogen species, chemistry proposed to occur at the zinc tetracysteine thiolate site of ...

Kozhukh, Julia

319

Influence of defects and processing parameters on the properties of indium tin oxide films on polyethylene napthalate substrate  

Science Conference Proceedings (OSTI)

Indium tin oxide (ITO) thin films were deposited on polyethylene napthalate (PEN) by rf sputtering using different rf powers (60 and 120 W) and at different substrate temperatures (room temperature and 100 deg. C). Selected PEN substrates were pretreated using an Ar plasma before ITO sputter deposition. Rutherford backscattering spectrometry was used to determine the oxygen content in the films. Hall effect measurements were used to evaluate the electrical properties. In this paper the influence of defect structure, sputtering conditions, and the effect of annealing on the electrical and optical properties of ITO on PEN have been investigated. Electrical properties such as carrier concentration, mobility, and resistivity of the ITO films varied with rf power and substrate temperature. The electrical and optical properties of the films changed after annealing in air. This study also describes how the as-deposited amorphous ITO changes from amorphous to crystalline as a result of heat treatment, and investigates the effects of Sn defect clustering on electrical and optical properties of the ITO films.

Han, H.; Zoo, Yeongseok; Bhagat, S. K.; Lewis, J. S.; Alford, T. L. [School of Materials, Arizona State University, Tempe, Arizona 85287-8706 (United States); Center for Materials and Electronic Technologies, RTI International, P.O. Box 12194, Research Triangle Park, North Carolina 27709-2194 (United States); School of Materials and Flexible Display Center, Arizona State University, Tempe, Arizona 85287-8706 (United States)

2007-09-15T23:59:59.000Z

320

Hydrogen Sensor Based on Yttria-Stabilized Zirconia Electrolyte and Tin-Doped Indium Oxide Sensing Electrode  

DOE Green Energy (OSTI)

A solid state electrochemical sensor has been developed for hydrogen leak detection in ambient air. The sensor uses an yttria-stabilized electrolyte with a tin-doped indium oxide sensing electrode and a Pt reference electrode. Excellent sensitivity, and response time of one second or less, are reported for hydrogen gas over the concentration range of 0.03 to 5.5% in air. Cross-sensitivity to relative humidity and to CO{sub 2} are shown to be low. The response to methane, a potentially significant source of interference for such a sensor, is significantly less than that for hydrogen. The sensor shows good reproducibility and was unaffected by thermal cycling over the course of this investigation. The effects of sensing electrode thickness and thermal aging are also reported, and the sensing mechanism is discussed. The sensor is intended for use in vehicles powered by hydrogen fuel cells and hydrogen internal combustion engines. Those vehicles will use and/or store significant quantities of hydrogen, and will require safety sensor for monitoring potential hydrogen leakage in order to ensure passenger safety.

Martin, L P; Glass, R S

2004-03-26T23:59:59.000Z

Note: This page contains sample records for the topic "zinc tin selenium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Thickness effect on laser-induced-damage threshold of indium-tin oxide films at 1064 nm  

Science Conference Proceedings (OSTI)

Laser-induced-damage characteristics of commercial indium-tin oxide (ITO) films deposited by DC magnetron sputtering deposition on K9 glass substrates as a function of the film thickness have been studied at 1064 nm with a 10 ns laser pulse in the 1-on-1 mode, and the various mechanisms for thickness effect on laser-induced-damage threshold (LIDT) of the film have been discussed in detail. It is observed that laser-damage-resistance of ITO film shows dramatic thickness effect with the LIDT of the 50-nm ITO film 7.6 times as large as the value of 300 nm film, and the effect of depressed carrier density by decreasing the film thickness is demonstrated to be the primary reason. Our experiment findings indicate that searching transparent conductive oxide (TCO) film with low carrier density and high carrier mobility is an efficient technique to improve the laser-damage-resistance of TCO films based on maintaining their well electric conductivity.

Wang Haifeng; Huang Zhimeng; Zhang Dayong; Luo Fei; Huang Lixian; Li Yanglong; Luo Yongquan; Wang Weiping; Zhao Xiangjie [Institute of Fluid Physics, China Academy of Engineering Physics, Mianyang 621900 (China)

2011-12-01T23:59:59.000Z

322

Indium-tin-oxide-free tris(8-hydroxyquinoline) Al organic light-emitting diodes with 80% enhanced power efficiency  

Science Conference Proceedings (OSTI)

Efficient indium tin oxide (ITO)-free small molecule organic light-emitting diodes (SMOLEDs) with multilayered highly conductive poly(3,4-ethylenedioxy thiophene):poly(styrenesulfonate) (PEDOT:PSS) as the anode are demonstrated. PEDOT:PSS/MoO{sub 3}/N,N'-diphenyl- N,N'-bis(1-naphthylphenyl)-1,1'-biphenyl-4,4'-diamine (NPD)/tris(8-hydroxyquinoline) Al (Alq{sub 3})/4,7-diphenyl-1,10-phenanthroline (BPhen)/LiF/Al SMOLEDs exhibited a peak power efficiency of 3.82 lm/W, 81% higher than that of similar ITO-based SMOLEDs (2.11 lm/W). The improved performance is believed to be due to the higher work function, lower refractive index, and decreased surface roughness of PEDOT:PSS vs ITO, and to Ohmic hole injection from PEDOT:PSS to the NPD layer via the MoO{sub 3} interlayer. The results demonstrate that PEDOT:PSS can substitute ITO in SMOLEDs with strongly improved device performance.

Cai, Min; Xiao, Teng; Liu, Rui; Chen, Ying; Shinar, Ruth; Shinar, Joseph

2011-10-11T23:59:59.000Z

323

Triboluminescent properties of zinc sulfide phosphors due to hypervelocity impact  

SciTech Connect

The emission of light due to crystal fracture, or triboluminescence (TL), is a phenomenon that has been known for centuries. One of the most common examples of TL is the flash created from chewing Wint-O-Green Lifesavers . From 2004 to 2006, research was completed using the two-stage light gas gun located at the NASA Marshall Space Flight Center (MSFC) in Huntsville, Alabama to measure the TL properties for zinc sulfide doped with both manganese (ZnS:Mn) and copper (ZnS:Cu). Results clearly show that hypervelocity impact-induced TL has been observed for both ZnS:Mn and ZnS:Cu. For ZnS:Mn, TL produced during 4.7 and 5.7km/s impacts was statistically more luminous than was observed from similar data collected at 3.3km/s. The TL decay time for ZnS:Mn was found to be 292 58 s, which is totally consistent with earlier measurements that did not use impact as an excitation source. Further, the emission of TL from ZnS:Mn undergoing hypervelocity impact has been demonstrated to have a significant component at the known peak emission wavelength of ZnS:Mn of 585nm. Small TL emission generated as a result of hypervelocity impact was also observed from ZnS:Cu. The most intriguing conclusion from this research is that it may be possible to discriminate impact velocity by measuring the time-integrated luminosity of TL phosphors. An ability to measure the velocity of a hypervelocity impact is a significant indicator of the potential usefulness for this concept for use as an impact sensor in future spacecraft.

Bergeron, Mr. Noah P. [Louisiana Tech University; HollermanPh.D., Dr. William A. [University of Louisiana, Lafayette; Goedeke, Shawn [ORNL; Moore, R. J. [University of Louisiana, Lafayette

2008-01-01T23:59:59.000Z

324

A zinc-air battery and flywheel zero emission vehicle  

DOE Green Energy (OSTI)

In response to the 1990 Clean Air Act, the California Air Resources Board (CARB) developed a compliance plan known as the Low Emission Vehicle Program. An integral part of that program was a sales mandate to the top seven automobile manufacturers requiring the percentage of Zero Emission Vehicles (ZEVs) sold in California to be 2% in 1998, 5% in 2001 and 10% by 2003. Currently available ZEV technology will probably not meet customer demand for range and moderate cost. A potential option to meet the CARB mandate is to use two Lawrence Livermore National Laboratory (LLNL) technologies, namely, zinc-air refuelable batteries (ZARBs) and electromechanical batteries (EMBs, i. e., flywheels) to develop a ZEV with a 384 kilometer (240 mile) urban range. This vehicle uses a 40 kW, 70 kWh ZARB for energy storage combined with a 102 kW, 0.5 kWh EMB for power peaking. These technologies are sufficiently near-term and cost-effective to plausibly be in production by the 1999-2001 time frame for stationary and initial vehicular applications. Unlike many other ZEVs currently being developed by industry, our proposed ZEV has range, acceleration, and size consistent with larger conventional passenger vehicles available today. Our life-cycle cost projections for this technology are lower than for Pb-acid battery ZEVs. We have used our Hybrid Vehicle Evaluation Code (HVEC) to simulate the performance of the vehicle and to size the various components. The use of conservative subsystem performance parameters and the resulting vehicle performance are discussed in detail.

Tokarz, F.; Smith, J.R.; Cooper, J.; Bender, D.; Aceves, S.

1995-10-03T23:59:59.000Z

325

Zinc and Zinc Alloys  

Science Conference Proceedings (OSTI)

...deep-drawn hardware; address plates; solar collectors Zn-Pb-Cd-Fe Building construction materials, dry-cell battery

326

Zinc Deficiency Linked to Increased Risk of Less-Common Form of Esophageal  

NLE Websites -- All DOE Office Websites (Extended Search)

National Cancer Institute National Cancer Institute Journal of the NCI X-ray Microscopy Group Zinc Deficiency Linked to Increased Risk of Less-Common Form of Esophageal Cancer Researchers at the National Cancer Institute (NCI), part of the National Institutes of Health, using x-ray fluorescence spectroscopy at X-ray Operations and Research beamline 2-BM at the U.S. Department of Energy's Advanced Photon Source have found that zinc deficiency in humans is associated with an increased risk of developing esophageal squamous cell carcinoma, an often-fatal form of esophageal cancer that has about 7,000 cases a year. NCI researchers used a novel approach to measure the concentration of zinc and other elements directly in the esophageal tissue. Their results, appearing in the February 15, 2005, Journal of the National

327

Impacts of humidity and temperature on the performance of transparent conducting zinc oxide.  

Science Conference Proceedings (OSTI)

The impact of humidity and temperature on a zinc oxide based transparent conducting oxide (TCO) was assessed under accelerated aging conditions. An in situ electroanalytical method was used to monitor the electrical properties for a conducting zinc oxide under controlled atmospheric (humidity, temperature and irradiation) conditions. A review of thin film photovoltaic (PV) literature has shown one major failure mode of cells/modules is associated with the ingress of water into modules in the field. Water contamination has been shown to degrade the performance of the TCO in addition to corroding interconnects and other conductive metals/materials associated with the module. Water ingress is particularly problematic in flexible thin film PV modules since traditional encapsulates such as poly(ethyl vinyl acetate) (EVA) have high water vapor transmission rates. The accelerated aging studies of the zinc oxide based TCOs will allow acceleration factors and kinetic parameters to be determined for reliability purposes.

Granata, Jennifer E.; Yaklin, Melissa A.; Schneider, Duane Allen; Staiger, Chad Lynn; Norman, Kirsten

2010-06-01T23:59:59.000Z

328

Nickel-zinc batteries for RPV applications. Interim technical report 15 Nov 78-15 Dec 79  

SciTech Connect

Interim results are presented for a program dealing with the placement of nickel-zinc batteries in specific military applications, namely the BQM-34A and the PQM-102 Remotely Piloted Vehicles. The nickel-zinc system was chosen for these applications because RPV's demand a high quality secondary battery that offers a compromise between long life (calendar and cycle) and low weight and volume. Program tasks include continued development of the nickel zinc system, calendar and cycle life testing of the two candidate batteries, qualification testing, and flight testing in operational RPV's. Test results of developmental cells and batteries include cycle life testing of various separator materials, high rate/low temperature discharges with various types of nickel electrodes, zinc electrode substrate, and charging methods. Calendar and cycle life testing is underway which will demonstrate the ability of the nickel-zinc system to be routinely cycled over an extended period of time.

Dappert, D.

1980-05-01T23:59:59.000Z

329

State of zincate in supersaturated solutions obtained during the discharging of a nickel-zinc electrochemical system  

SciTech Connect

This article examines the ultraviolet (UV) spectra of supersaturated zincate solutions obtained as a result of the discharging of the nickel-zinc system during their aging. A disadvantage of the nickel-zinc storage battery is its relatively short service life due to the instability of the zinc electrode. This instability is caused by the tendency of the zincate solution to become supersaturated. The UV spectra of the supersaturated zincate solutions obtained in the silver-zinc and nickel-zinc systems show significant absorption at 240 nm and strong absorption at 280 nm. The strong absorption at 280 nm in the supersaturated zincate solutions corresponds to the weak absorption in the solution obtained by ordinary dissolution. It is suggested that the stability of supersaturated zincate solutions may be increased by the formation of additional bridging bonds, which link the individual molecules of their aggregates to form a three-dimensional structure.

Smitrenko, V.E.; Baulov, V.I.; Kotov, A.V.; Zubov, M.S.

1984-05-01T23:59:59.000Z

330

Reliability, Availability, and Maintainability Assessment of a Zinc Chloride Battery System  

Science Conference Proceedings (OSTI)

UNIRAM analyses guided the design of an advanced energy storage system for load leveling and management. The study showed that, in comparison with competing technologies that are available approximately 90% of the time, a 2-MW system of zinc chloride batteries would have an availability greater than 98%.

1986-12-10T23:59:59.000Z

331

Speciation and Release Kinetics of Zinc in Contaminated Paddy Soils Saengdao Khaokaew,*,  

E-Print Network (OSTI)

Speciation and Release Kinetics of Zinc in Contaminated Paddy Soils Saengdao Khaokaew,*, Gautier of Plant and Soil Sciences, 152 Townsend Hall, Newark, Delaware 19716, United States U.S. Department of Zn is controlled by many factors, especially soil pH and Eh, which can vary in lowland rice culture

Sparks, Donald L.

332

Feasibility study of a new zinc-air battery concept using flowing alkaline electrolyte  

SciTech Connect

Proof-of-principle experiments are reported for a new concept in electrically rechargeable zinc-air battery. The zinc electrode is a porous flow-thru type using a copper foam metal substrate with zinc deposition onto the foam metal from concentrated zincate electrolyte (as used in zinc-slurry type batteries). The bifunctional air electrode employs low-cost materials, being fabricated entirely from carbon-based precursors and small amounts of nickel and/or cobalt oxide. Corrosion measurements on the graphite materials in the air electrode indicate sufficient corrosion resistance for 8000 h life on charge. A prototype single cell was constructed having 1.5 Ah capacity producing 1.2 V discharge -2.0 charge at the three hour rate and has produced stable voltages for more than 150 cycles. Based on the 1.5 Ah prototype characteristics, design calculations for a 32 kWh battery project an energy density of about 110 Wh/kg, peak power density of 140 W/kg, electrical efficiency of 60% and an attractive materials cost of less than or equal to$20 per kWh.

Ross, P.N. Jr.

1986-04-01T23:59:59.000Z

333

Biomimetic synthesis of zinc oxide 3D architectures with gelatin as matrix  

Science Conference Proceedings (OSTI)

Peanut-like and flower-like zinc oxide 3D architectures were synthesized via a facile biomimetic process using gelatin as matrix. Techniques of XRD, SEM, HRTEM, FT-IR, and UV-vis absorption spectra were used to characterize the structure and property ...

Yong Gan; Fubo Gu; Dongmei Han; Zhihua Wang; Guangsheng Guo

2010-01-01T23:59:59.000Z

334

A refuelable zinc/air battery for fleet electric vehicle propulsion  

SciTech Connect

We report the development and on-vehicle testing of an engineering prototype zinc/air battery. The battery is refueled by periodic exchange of spent electrolyte for zinc particles entrained in fresh electrolyte. The technology is intended to provide a capability for nearly continuous vehicle operation, using the fleet s home base for 10 minute refuelings and zinc recycling instead of commercial infrastructure. In the battery, the zinc fuel particles are stored in hoppers, from which they are gravity fed into individual cells and completely consumed during discharge. A six-celled (7V) engineering prototype battery was combined with a 6 V lead/acid battery to form a parallel hybrid unit, which was tested in series with the 216 V battery of an electric shuttle bus over a 75 mile circuit. The battery has an energy density of 140 Wh/kg and a mass density of 1.5 kg/L. Cost, energy efficiency, and alternative hybrid configurations are discussed.

Cooper, J.F.; Fleming, D.; Hargrove, D.; Koopman, R.; Peterman, K.

1995-04-20T23:59:59.000Z

335

Method and apparatus for maintaining the pH in zinc-bromine battery systems  

DOE Patents (OSTI)

A method and apparatus for maintaining the pH level in a zinc-bromine battery features reacting decomposition hydrogen with bromine in the presence of a catalyst. The catalyst encourages the formation of hydrogen and bromine ions. The decomposition hydrogen is therefore consumed, alloying the pH of the system to remain substantially at a given value.

Grimes, Patrick G. (Westfield, NJ)

1985-09-10T23:59:59.000Z

336

Hydrometallurgical process for recovering iron sulfate and zinc sulfate from baghouse dust  

DOE Patents (OSTI)

A process for recovering zinc-rich and iron-rich fractions from the baghouse dust that is generated in various metallurgical operations, especially in steel-making and other iron-making plants, comprises the steps of leaching the dust by hot concentrated sulfuric acid so as to generate dissolved zinc sulfate and a precipitate of iron sulfate, separating the precipitate from the acid by filtration and washing with a volatile liquid, such as methanol or acetone, and collecting the filtered acid and the washings into a filtrate fraction. The volatile liquid may be recovered by distillation, and the zinc may be removed from the filtrate by alternative methods, one of which involves addition of a sufficient amount of water to precipitate hydrated zinc sulfate at 10 C, separation of the precipitate from sulfuric acid by filtration, and evaporation of water to regenerate concentrated sulfuric acid. The recovery of iron may also be effected in alternative ways, one of which involves roasting the ferric sulfate to yield ferric oxide and sulfur trioxide, which can be reconverted to concentrated sulfuric acid by hydration. The overall process should not generate any significant waste stream. 1 figure.

Zaromb, S.; Lawson, D.B.

1994-02-15T23:59:59.000Z

337

Catalytic reforming and hydrocracking of organic compounds employing promoted zinc titanate as the catalytic agent  

Science Conference Proceedings (OSTI)

The catalytic reforming of a feedstock which contains at least one reformable organic compound or the hydrocracking of a feedstock which contains at least one hydrocrackable organic compound is carried out in the presence of a catalyst composition comprising zinc, titanium and rhenium.

Drehman, L.E.; Farha, F.E.

1981-04-21T23:59:59.000Z

338

Catalytic reforming and hydrocracking of organic compounds employing zinc titanate as the catalytic agent  

Science Conference Proceedings (OSTI)

The catalytic reforming of a feedstock which contains at least one reformable organic compound or the hydrocracking of a feedstock which contains at least one hydrocrackable organic compound is carried out in the presence of a catalyst composition comprising zinc and titanium.

Drehman, L.E.; Farha, F.E.; Walker, D.W.

1981-04-21T23:59:59.000Z

339

Tribology and Tool Wear of Hot Dip Galvanized Zinc Magnesium Alloys on Cold Rolled Steel Sheets  

SciTech Connect

Recently zinc based coatings on cold rolled steel with improved functionality in terms of forming and/or corrosion behaviour have been intensively investigated in the steel industry. One of the most promising products are zinc magnesium alloys produced in hot dip galvanizing process. These coatings were already introduced in construction industry a few years ago. With some modifications the improved properties of the coating are also interesting for automotive industry. In the present work the tribological potential of hot dip galvanized zinc magnesium coatings (HDG/ZM) produced at an industrial line under regular production, was studied in terms of sliding properties, adhesive and abrasive tool wear.First a short introduction into surface morphology of HDG/ZM will be given. For the tribological characterization of the material, which is the main topic of the contribution, different tests were performed on hot dip galvanised zinc magnesium material and results were compared with classic hot dip galvanized zinc coating (HDG/Z). The investigations are mainly based on the strip draw test which allows the determination of the friction coefficient directly by using a constant contact pressure. Deep drawing property was tested by forming model cups. The abrasive tool wear was tested using a standard test for material used in automotive industry. The adhesive tool wear was investigated by characterizing the coating material transferred to the tool in the strip draw test.All performed tests show an improved drawability of HDG/ZM compared to classical HDG/Z reference material. However the most promising difference between HDG/ZM and HDG/Z is that galling was found to be less for HDG/ZM than for HDG/Z. Therefore HDG/ZM is an interesting system not only with respect to corrosion protection but also in terms of tribology and provides clear advantages in formability.

Raab, A. E.; Berger, E.; Freudenthaler, J.; Leomann, F.; Walch, C. [Research and Development, Forming Technology voestalpine Stahl GmbH, Voest-Alpine Strasse 3, 4031 Linz (Austria)

2011-05-04T23:59:59.000Z

340

Trace metals in fucoid algae and purple sea urchins near a high arctic lead/zinc ore deposit  

SciTech Connect

Trace metal concentrations in fucoid algae and in purple sea urchins from the vicinity of a metal mining district on North Baffin Island were determined. Higher concentrations of iron and zinc were present in algae and urchins collected nearer the mining area than in those collected further away. Concentrations of copper, iron, and zinc in algae increased with tissue age; arsenic and cadmium were lowest in intermediate-age algae tissues. Tissue distributions of iron and zinc in urchins and algae illustrate the food chain relationship between these species. 7 references, 2 tables.

Bohn, A.

1979-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "zinc tin selenium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

41 - 5750 of 28,560 results. 41 - 5750 of 28,560 results. Download EIS-0287: Final Environmental Impact Statement Idaho High-Level Waste and Facilities Disposition http://energy.gov/nepa/downloads/eis-0287-final-environmental-impact-statement Download EA-1591: Mitigation Action Plan Palisades-Goshen Transmission Line Reconstruction Project http://energy.gov/nepa/downloads/ea-1591-mitigation-action-plan Download Evaluation Report: IG-0843 The Department's Unclassified Cyber Security Program - 2010 http://energy.gov/ig/downloads/evaluation-report-ig-0843 Download CX-005780: Categorical Exclusion Determination Sintered Copper Zinc Tin Selenium Nanoparticle Solar Cells on Metal Foil CX(s) Applied: A9, A11, B3.6 Date: 05/11/2011 Location(s): San Jose, California Office(s): Energy Efficiency and Renewable Energy, Golden Field Office

342

NIDC: Online Catalog of Isotope Products | Product List  

NLE Websites -- All DOE Office Websites (Extended Search)

List List Please select an available isotope product from the lists below. If you would like an isotope product that is not listed, you can make a request by clicking here. Stable Isotope Products Radio-Isotope Products Antimony Argon (Alt) Barium Bromine Bromine (Alt) Cadmium Calcium Carbon (Alt) Cerium Chlorine Chlorine (Alt) Chromium Copper Dysprosium Erbium Europium Gadolinium Gallium Germanium Hafnium Helium (Alt) Indium Iridium Iron Krypton (Alt) Lanthanum Lead Lithium Lutetium Magnesium Mercury Molybdenum Neodymium Neon (Alt) Nickel Nitrogen (Alt) Osmium Oxygen (Alt) Palladium Platinum Potassium Rhenium Rubidium Ruthenium Samarium Selenium Silicon Silver Strontium Sulfur Sulfur (Alt) Tantalum Tellurium Thallium Tin Titanium Tungsten Vanadium Xenon (Alt) Ytterbium Zinc Zirconium Actinium-225 Aluminum-26 Americium-241

343

NIDC: Online Catalog of Isotope Products | Product Search  

NLE Websites -- All DOE Office Websites (Extended Search)

Product Search Product Search Step 1 - Enter your search criteria below. Element Name Actinium Aluminum Americium Antimony Argon Arsenic Astatine Barium Berkelium Beryllium Bismuth Bohrium Boron Bromine Cadmium Caesium Calcium Californium Carbon Cerium Chlorine Chromium Cobalt Copernicium Copper Curium Darmstadtium Dubnium Dysprosium Einsteinium Erbium Europium Fermium Fluorine Francium Gadolinium Gallium Germanium Gold Hafnium Hassium Helium Holmium Hydrogen Indium Iodine Iridium Iron Krypton Lanthanum Lawrencium Lead Lithium Lutetium Magnesium Manganese Meitnerium Mendelevium Mercury Molybdenum Neodymium Neon Neptunium Nickel Niobium Nitrogen Nobelium Osmium Oxygen Palladium Phosphorus Platinum Plutonium Polonium Potassium Praseodymium Promethium Protactinium Radium Radon Rhenium Rhodium Roentgenium Rubidium Ruthenium Rutherfordium Samarium Scandium Seaborgium Selenium Silicon Silver Sodium Strontium Sulfur Tantalum Technetium Tellurium Terbium Thallium Thorium Thulium Tin Titanium Tungsten Ununhexium Ununoctium Ununpentium Ununquadium Ununseptium Ununtrium Uranium Vanadium Xenon Ytterbium Yttrium Zinc Zirconium

344

CX-005780: Categorical Exclusion Determination | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

80: Categorical Exclusion Determination 80: Categorical Exclusion Determination CX-005780: Categorical Exclusion Determination Sintered Copper Zinc Tin Selenium Nanoparticle Solar Cells on Metal Foil CX(s) Applied: A9, A11, B3.6 Date: 05/11/2011 Location(s): San Jose, California Office(s): Energy Efficiency and Renewable Energy, Golden Field Office The Photovoltaic (PV) Technology Incubator project represents a significant component of the United States (U.S.) Department of Energy (DOE) business strategy of partnering with U.S. industry to accelerate the commercialization of photovoltaic system research and development (R&D) to meet aggressive cost and installed capacity goals. DOCUMENT(S) AVAILABLE FOR DOWNLOAD CX-005780.pdf More Documents & Publications Bertrand Fillon, Commissariat à l'Energie Atomique et aux Energies

345

NIDC: Online Catalog of Isotope Products | Request a New Product  

NLE Websites -- All DOE Office Websites (Extended Search)

Request a New Product Request a New Product Step 1 - Enter the new product's criteria below. Element Name Actinium Aluminum Americium Antimony Argon Arsenic Astatine Barium Berkelium Beryllium Bismuth Bohrium Boron Bromine Cadmium Caesium Calcium Californium Carbon Cerium Chlorine Chromium Cobalt Copernicium Copper Curium Darmstadtium Dubnium Dysprosium Einsteinium Erbium Europium Fermium Fluorine Francium Gadolinium Gallium Germanium Gold Hafnium Hassium Helium Holmium Hydrogen Indium Iodine Iridium Iron Krypton Lanthanum Lawrencium Lead Lithium Lutetium Magnesium Manganese Meitnerium Mendelevium Mercury Molybdenum Neodymium Neon Neptunium Nickel Niobium Nitrogen Nobelium Osmium Oxygen Palladium Phosphorus Platinum Plutonium Polonium Potassium Praseodymium Promethium Protactinium Radium Radon Rhenium Rhodium Roentgenium Rubidium Ruthenium Rutherfordium Samarium Scandium Seaborgium Selenium Silicon Silver Sodium Strontium Sulfur Tantalum Technetium Tellurium Terbium Thallium Thorium Thulium Tin Titanium Tungsten Ununhexium Ununoctium Ununpentium Ununquadium Ununseptium Ununtrium Uranium Vanadium Xenon Ytterbium Yttrium Zinc Zirconium

346

INTERIM RESULTS FROM A STUDY OF THE IMPACTS OF TIN(II) BASED MERCURY TREATMENT IN A SMALL STREAM ECOSYSTEM: TIMS BRANCH, SAVANNAH RIVER SITE  

SciTech Connect

Mercury (Hg) has been identified as a 'persistent, bioaccumulative and toxic' pollutant with widespread impacts throughout North America and the world (EPA. 1997a, 1997b, 1998a, 1998b, 2000). Although most of the mercury in the environment is inorganic Hg, a small proportion of total Hg is transformed through the actions of aquatic microbes into methylmercury (MeHg). In contrast to virtually all other metals, MeHg biomagnifies or becomes increasingly concentrated as it is transferred through aquatic food chains so that the consumption of mercury contaminated fish is the primary route of this toxin to humans. For this reason, the ambient water quality criterion (AWQC) for mercury is based on a fish tissue endpoint rather than an aqueous Hg concentration, as the tissue concentration (e.g., < 0.3 {mu}g/g fillet) is considered to be a more consistent indicator of exposure and risk (EPA, 2001). Effective mercury remediation at point-source contaminated sites requires an understanding of the nature and magnitude of mercury inputs, and also knowledge of how these inputs must be controlled in order to achieve the desired reduction of mercury contamination in biota necessary for compliance with AWQC targets. One of the challenges to remediation is that mercury body burdens in fish are more closely linked to aqueous MeHg than to inorganic Hg concentrations (Sveinsdottir and Mason 2005), but MeHg production is not easily predicted or controlled. At point-source contaminated sites, mercury methylation is not only affected by the absolute mercury load, but also by the form of mercury loaded. In addition, once MeHg is formed, the hydrology, trophic structure, and water chemistry of a given system affect how it is transformed and transferred through the food chain to fish. Decreasing inorganic Hg concentrations and loading may often therefore be a more achievable remediation goal, but has led to mixed results in terms of responses in fish bioaccumulation. A number of source control measures have resulted in rapid responses in lake or reservoir fisheries (Joslin 1994, Turner and Southworth 1999; Orihel et al., 2007), but examples of similar responses in Hg-contaminated stream ecosystems are less common. Recent work suggests that stream systems may actually be more susceptible to mercury bioaccumulation than lakes, highlighting the need to better understand the ecological drivers of mercury bioaccumulation in stream-dwelling fish (Chasar et al. 2009, Ward et al. 2010). In the present study we examine the response of fish to remedial actions in Tims Branch, a point-source contaminated stream on the Department of Energy's (DOE) Savannah River Site in Aiken, South Carolina. This second order stream received inorganic mercury inputs at its headwaters from the 1950s-2000s which contaminated the water, sediments, and biota downstream. In 2007, an innovative mercury removal system using tin (II) chloride (stannous chloride, SnCl{sub 2}) was implemented at a pre-existing air stripper. Tin(II) reduces dissolved Hg (II) to Hg (0), which is removed by the air stripper. During this process, tin(II) is oxidized to tin (IV) which is expected to precipitate as colloidal tin(IV) oxides and hydroxides, particulate materials with relatively low toxicity (Hallas and Cooney, 1981, EPA 2002, ATSDR, 2005). The objectives of the present research are to provide an initial assessment of the net impacts of the tin(II) based mercury treatment on key biota and to document the distribution and fate of inorganic tin in this small stream ecosystem after the first several years of operating a full scale system. To support these objectives, we collected fish, sediment, water, invertebrates, and biofilm samples from Tims Branch to quantify the general behavior and accumulation patterns for mercury and tin in the ecosystem and to determine if the treatment process has resulted in: (1) a measurable beneficial impact on (i.e., decrease of) mercury concentration in upper trophic level fish and other biota; this is a key environmental endpoint since reducing mercury concen

Looney, B.; Bryan, L.; Mathews, T.

2012-03-30T23:59:59.000Z

347

Summary and assessment of METC zinc ferrite hot coal gas desulfurization test program, final report: Volume 2, Appendices  

Science Conference Proceedings (OSTI)

The Morgantown Energy Technology Center (METC) has conducted a test program to develop a zinc ferrite-based high temperature desulfurization process which could be applied to fuel gas entering downstream components such as molten carbonate fuel cells or gas turbines. As a result of prior METC work with iron oxide and zinc oxide sorbents, zinc ferrite evolved as a candidate with the potential for high capacity, low equilibrium levels of H/sub 2/S, and structural stability after multiple regenerations. The program consisted of laboratory-scale testing with a two-inch diameter reactor and simulated fixed-bed gasifier gas; bench-scale testing with a six-inch diameter reactor and actual gas from the METC 42-inch fixed bed gasifier; as well as laboratory-scale testing of zinc ferrite with simulated fluidized bed gasifier gas. Data from sidestream testing are presented. 18 refs.

Underkoffler, V.S.

1986-12-01T23:59:59.000Z

348

Design and synthesis of novel functionalized sensors for the biological imaging of zinc(II) and nitric oxide  

E-Print Network (OSTI)

CHAPTER 1: Fluorescent Sensors for the Biological sensing of Zinc(II) A variety of fluorescent techniques have been developed for the in vivo sensing of Zn2+. This chapter presents a brief overview of techniques used to ...

Won, Annie C., 1983-

2005-01-01T23:59:59.000Z

349

T ti E St S tTetiaroa Energy Storage System Estimated ZBB Zinc Bromide Battery Performance and Costs  

E-Print Network (OSTI)

T ti E St S tTetiaroa Energy Storage System Estimated ZBB Zinc Bromide Battery Performance and Costs Prull / KammenPrull / Kammen Renewable and Appropriate Energy Lab, UC Berkeley 7/26/2010 http

Kammen, Daniel M.

350

Nickel-zinc batteries for RPV applications. Final technical report 15 Nov 79-15 Aug 81  

SciTech Connect

Final technical results are presented for a program dealing with the placement of nickel-zinc batteries in specific military applications, namely the BQM-34A and the PQM-102 Remotely Piloted Vehicles (RPV's). The nickel-zinc system was selected for these applications because RPV's demand a high quality secondary battery that offers a compromise between long life (calendar and cycle) and low weight and volume.

Dappert, D.

1982-02-01T23:59:59.000Z

351

Cadmium ban spurs interest in zinc-nickel coating for corrosive aerospace environments  

SciTech Connect

OSHA recently reduced the permissible exposure level for cadmium. The new standard virtually outlaws cadmium production and use, except in the most cost-insensitive applications. Aerospace manufacturers, which use cadmium extensively in coatings applications because of the material's corrosion resistance, are searching for substitutes. The most promising alternative found to date is a zinc-nickel alloy. Tests show that the alloy outperforms cadmium without generating associated toxicity issues. As a result, several major manufacturing and standards organizations have adopted the zinc-nickel compound as a standard cadmium replacement. The basis for revising the cadmium PEL -- which applies to occupational exposure in industrial, agricultural and maritime occupations -- is an official OSHA determination that employees exposed to cadmium under the existing PEL face significant health risks from lung cancer and kidney damage. In one of its principal uses, cadmium is electroplated to steel, where it acts as an anticorrosive agent.

Bates, J. (Pure Coatings Inc., West Palm Beach, FL (United States))

1994-02-01T23:59:59.000Z

352

Evaluation of a new type stable nickel-zinc battery for electric vehicle application. Final report  

SciTech Connect

This report describes discharge-recharge cycle testing of 14 nickel-zinc storage battery cells of a proprietary design. This testing was to obtain performance data on new types of stabilized nickel-zinc battery cells for possible electric vehicle applications. The test sample cells were manufactured by Electrochimica Corporation (ELCA) in two sizes (15 ampere-hours and 225 ampere-hours) with a total of seven different internal combinations. The cells completed up to 470 cycles when testing was halted due to funding limitations. Near the end of testing, the cells were providing 40% of nominal capacity when discharged to 1.2 volts and 58 to 73% when discharged in two steps to 1.0 volt.

Not Available

1985-07-26T23:59:59.000Z

353

CdS/CdTe Thin-Film Solar Cell with a Zinc Stannate Buffer Layer  

DOE Green Energy (OSTI)

This paper describes an improved CdS/CdTe polycrystalline thin-film solar-cell device structure that integrates a zinc stannate (Zn2SnO4 or ZTO) buffer layer between the transparent conductive oxide (TCO) layer and the CdS window layer. Zinc stannate films have a high bandgap, high transmittance, low absorptance, and low surface roughness. In addition, these films are chemically stable and exhibit higher resistivities that are roughly matched to that of the CdS window layer in the device structure. Preliminary device results have demonstrated that by integrating a ZTO buffer layer in both SnO2-based and Cd2SnO4 (CTO)-based CdS/CdTe devices, performance and reproducibility can be significantly enhanced

Wu, X.; Sheldon, P.; Mahathongdy, Y.; Ribelin, R.; Mason, A.; Moutinho, H. R.; Coutts, T. J.

1998-10-28T23:59:59.000Z

354

Reaction Diffusion in the Silver-Zinc and Silver-Aluminum Systems  

SciTech Connect

Multiphase diffusion was investigated in the silver-zinc and silver-aluminum binary systems using metallographic and electron microprobe techniques. Diffusion couples in the silver-zinc system were prepared by electroplating silver onto coupons of a AgZn alloy (62.2% Ag), and diffusion behavior was studied at 600 and 650 degrees C. Couples in the silver-aluminum system were prepared by electroplating silver onto coupons of a AgAl alloy (87.7% Ag) and diffusion measurements were made between 400-600 degrees C. Significant deviations from equilibrium compositions were observed at the moving interphase boundary in each couple. The nucleation of a non-equilibrium silver-rich phase was observed at the location of the initial interface in many of the couples.

Braun, Japnell D.; Powell, Gordon W.

1971-10-01T23:59:59.000Z

355

Influences of Mgo on Roasting Properties of Iron Ore Oxidized Pellets  

Science Conference Proceedings (OSTI)

Arc Plasma Smelting of Niobium Pentoxide towards Production of Nb Metal ... Phase Transformation of Andalusite-Mullite and Its Fiber Reinforcement to Refractory ... Preparation of Metallized Pellets and Recovery of Tin and Zinc from Tin,...

356

Influence of Additives on Dephosphorization of Oolitic Hematite by ...  

Science Conference Proceedings (OSTI)

Arc Plasma Smelting of Niobium Pentoxide towards Production of Nb Metal ... Passes Laser Phase Transformation Hardening by Using High-Power Direct Diode Laser ... Preparation of Metallized Pellets and Recovery of Tin and Zinc from Tin,...

357

1st International Symposium on High-Temperature Metallurgical ...  

Science Conference Proceedings (OSTI)

Arc Plasma Smelting of Niobium Pentoxide towards Production of Nb Metal ... Passes Laser Phase Transformation Hardening by Using High-Power Direct Diode Laser ... Preparation of Metallized Pellets and Recovery of Tin and Zinc from Tin,...

358

A Study on Beneficiation of Low Grade High-Phosphorus Iron Ore  

Science Conference Proceedings (OSTI)

Arc Plasma Smelting of Niobium Pentoxide towards Production of Nb Metal ... Passes Laser Phase Transformation Hardening by Using High-Power Direct Diode Laser ... Preparation of Metallized Pellets and Recovery of Tin and Zinc from Tin,...

359

Develop nickel--zinc battery suitable for electric vehicle propulsion. Task A: design and cost study  

DOE Green Energy (OSTI)

A three-month design and cost study for the use of nickel--zinc batteries in electric vehicles is presented. Battery configuration is analyzed, and expected performance is set forth. Current development problems concern component materials and capacity decline on cycling, electrolyte maintenance, and thermal characteristics. The manufacturing process is outlined, and estimates are made for cost, materials requirements, capital needs, etc. 61 figures, 24 tables. (RWR)

None

1977-02-15T23:59:59.000Z

360

Photovoltaic devices comprising zinc stannate buffer layer and method for making  

DOE Patents (OSTI)

A photovoltaic device has a buffer layer zinc stannate Zn.sub.2 SnO.sub.4 disposed between the semiconductor junction structure and the transparent conducting oxide (TCO) layer to prevent formation of localized junctions with the TCO through a thin window semiconductor layer, to prevent shunting through etched grain boundaries of semiconductors, and to relieve stresses and improve adhesion between these layers.

Wu, Xuanzhi (Golden, CO); Sheldon, Peter (Lakewood, CO); Coutts, Timothy J. (Lakewood, CO)

2001-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "zinc tin selenium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Review of membrane separators and zinc-nickel oxide battery development  

SciTech Connect

After a discussion of membranes and their role in zinc-nickel oxide batteries, possible solutions are reviewed for problems related to membrane separators in these batteries. Experiments to characterize a membrane are also summarized. A bibliography is included to show what is being done in the field of battery research to develop practical membranes for use in Ni/Zn or Ag/Zn batteries. (LEW)

Bennion, D.N.

1980-10-01T23:59:59.000Z

362

LABORATORY REPORT ON THE REDUCTION AND STABILIZATION (IMMOBILIZATION) OF PERTECHNETATE TO TECHNETIUM DIOXIDE USING TIN(II)APATITE  

SciTech Connect

This effort is part of the technetium management initiative and provides data for the handling and disposition of technetium. To that end, the objective of this effort was to challenge tin(II)apatite (Sn(II)apatite) against double-shell tank 241-AN-105 simulant spiked with pertechnetate (TcO{sub 4}{sup -}). The Sn(II)apatite used in this effort was synthesized on site using a recipe developed at and provided by Sandia National Laboratories; the synthesis provides a high quality product while requiring minimal laboratory effort. The Sn(II)apatite reduces pertechnetate from the mobile +7 oxidation state to the non-mobile +4 oxidation state. It also sequesters the technetium and does not allow for re-oxidization to the mo bile +7 state under acidic or oxygenated conditions within the tested period oftime (6 weeks). Previous work (RPP-RPT-39195, Assessment of Technetium Leachability in Cement-Stabilized Basin 43 Groundwater Brine) indicated that the Sn(II)apatite can achieve an ANSI leachability index in Cast Stone of 12.8. The technetium distribution coefficient for Sn(II)apatite exhibits a direct correlation with the pH of the contaminated media. Table A shows Sn(II)apatite distribution coefficients as a function of pH. The asterisked numbers indicate that the lower detection limit of the analytical instrument was used to calculate the distribution coefficient as the concentration of technetium left in solution was less than the detection limit. The loaded sample (200 mg of Sn(II)apatite loaded with O.311 mg of Tc-99) was subjected to different molarities of nitric acid to determine if the Sn(II)apatite would release the sequestered technetium. The acid was allowed to contact for 1 minute with gentle shaking ('1st wash'); the aqueous solution was then filtered, and the filtrate was analyzed for Tc-99. Table B shows the results ofthe nitric acid exposure. Another portion of acid was added, shaken for a minute, and filtered ('2nd wash'). The technetium-loaded Sn(II)apatite was also subjected to water leach tests. The loaded sample (0.2 g of Sn(II)apatite was loaded with 0.342 mg of Tc-99) was placed in a 200-mL distilled water column and sparged with air. Samples were taken weekly over a 6-week period, and the dissolved oxygen ranged from 8.4 to 8.7 mg/L (average 8.5 mg/L); all samples recorded less than the detection limit of 0.01 mg/L Tc-99. The mechanism by which TcO{sub 2} is sequestered and hence protected from re-oxidation appears to be an exchange with phosphate in the apatite lattice, as the phosphorus that appeared in solution after reaction with technetium was essentially the same moles of technetium that were taken up by the Sn(II)apatite (Table 6). Overall, the reduction of the mobile pertechnetate (+7) to the less mobile technetium dioxide (+4) by Sn(II)apatite and subsequent sequestration of the technetium in the material indicates that Sn(II)apatite is an excellent candidate for long-term immobilization of technetium. The indications are that the Sn(II)apatite will lend itself to sequestering and inhibiting the reoxidation to the mobile pertechnetate species, thus keeping the radionuclide out of the environment.

DUNCAN JB; HAGERTY K; MOORE WP; RHODES RN; JOHNSON JM; MOORE RC

2012-06-01T23:59:59.000Z

363

Acid buffering a high pH soil for zinc diffusion  

SciTech Connect

The effective use of an aqueous buffer solution of acetic acid and sodium acetate (1.0 M HOAc/1.4 M NaOAc, pH = 4.8) to lower the pH of a sand-attapulgite clay mixture from 9.4 to 4.8 is demonstrated. Soil buffering is necessary to prevent precipitation of Zn{sup 2+} as Zn(OH){sub 2(s)} during zinc diffusion tests. The choice of the acetic acid/sodium acetate buffer solution is based on results of batch-type tests and permeation tests performed to evaluate the soil-mixture pH lowering and buffering capacity of dilute solutions of HNO{sub 3} (a strong acid), 0.057 M HOAc (a weak acid), potassium hydrogen phthalate (a pH {approximately} 4 buffer), and the 1.0 M HOAc/1.4 MNaOAc buffer solution. Measured values of effective diffusion coefficients D* for zinc on unconfined, compacted test specimens of the buffered soil mixture ranged from 0.54 {times} 10{sup {minus}6} cm{sup 2}/s to 6.5 {times} 10{sup {minus}6} cm{sup 2}/s. This range of D*-values is within the range of D*-values reported for most reactive inorganic solutes in saturated clay soils and at the lower end of the range of D*-values for zinc in saturated clay soils.

Shackelford, C.D.; Cotten, T.E.; Rohal, K.M.; Strauss, S.H. [Colorado State Univ., Fort Collins, CO (United States)

1997-03-01T23:59:59.000Z

364

Low-energy Coulomb excitation of neutron-rich zinc isotopes  

E-Print Network (OSTI)

At the radioactive ion beam facility REX-ISOLDE, neutron-rich zinc isotopes were investigated using low-energy Coulomb excitation. These experiments have resulted in B(E2,20) values in 74-80Zn, B(E2,42) values in 74,76Zn and the determination of the energy of the first excited 2 states in 78,80Zn. The zinc isotopes were produced by high-energy proton- (A=74,76,80) and neutron- (A=78) induced fission of 238U, combined with selective laser ionization and mass separation. The isobaric beam was postaccelerated by the REX linear accelerator and Coulomb excitation was induced on a thin secondary target, which was surrounded by the MINIBALL germanium detector array. In this work, it is shown how the selective laser ionization can be used to deal with the considerable isobaric beam contamination and how a reliable normalization of the experiment can be achieved. The results for zinc isotopes and the N=50 isotones are compared to collective model predictions and state-of-the-art large-scale shell-model calculations, i...

Van de Walle, J; Behrens, T; Bildstein, V; Blazhev, A; Cederkll, J; Clment, E; Cocolios, T E; Davinson, T; Delahaye, P; Eberth, J; Ekstrm, A; Fedorov, D V; Fedosseev, V; Fraile, L M; Franchoo, S; Gernhuser, R; Georgiev, G; Habs, D; Heyde, K; Huber, G; Huyse, M; Ibrahim, F; Ivanov, O; Iwanicki, J; Jolie, J; Kester, O; Kster, U; Krll, T; Krcken, R; Lauer, M; Lisetskiy, A F; Lutter, R; Marsh, B A; Mayet, P; Niedermaier, O; Pantea, M; Raabe, R; Reiter, P; Sawicka, M; Scheit, H; Schrieder, G; Schwalm, D; Seliverstov, M D; Sieber, T; Sletten, G; Smirnova, N; Stanoiu, M; Stefanescu, I; Thomas, J C; Valiente-Dobn, J J; Van Duppen, P; Verney, D; Voulot, D; Warr, N; Weisshaar, D; Wenander, F; Wolf, B H; Zielinska, M

2009-01-01T23:59:59.000Z

365

Analysis of indium zinc oxide thin films by laser-induced breakdown spectroscopy  

Science Conference Proceedings (OSTI)

We have performed spectroscopic analysis of the plasma generated by Nd:YAG ({lambda} = 266 nm) laser irradiation of thin indium zinc oxide films with variable In content deposited by combinatorial pulsed laser deposition on glass substrates. The samples were irradiated in 5 x 10{sup 4} Pa argon using laser pulses of 5 ns duration and 10 mJ energy. The plasma emission spectra were recorded with an Echelle spectrometer coupled to a gated detector with different delays with respect to the laser pulse. The relative concentrations of indium and zinc were evaluated by comparing the measured spectra to the spectral radiance computed for a plasma in local thermal equilibrium. Plasma temperature and electron density were deduced from the relative intensities and Stark broadening of spectral lines of atomic zinc. Analyses at different locations on the deposited thin films revealed that the In/(In + Zn) concentration ratio significantly varies over the sample surface, from 0.4 at the borders to about 0.5 in the center of the film. The results demonstrate that laser-induced breakdown spectroscopy allows for precise and fast characterization of thin films with variable composition.

Popescu, A. C. [LP3, CNRS - Universite Aix-Marseille, 163 Ave. de Luminy, Marseille 13288 (France); National Institute for Lasers, Plasma and Radiation Physics, Magurele, Ilfov 077125 (Romania); Beldjilali, S. [LP3, CNRS - Universite Aix-Marseille, 163 Ave. de Luminy, Marseille 13288 (France); LPPMCA, Universite des Sciences et de la Technologie d'Oran, BP 1505 El Mnaouer, Oran (Algeria); Socol, G.; Mihailescu, I. N. [National Institute for Lasers, Plasma and Radiation Physics, Magurele, Ilfov 077125 (Romania); Craciun, V. [National Institute for Lasers, Plasma and Radiation Physics, Magurele, Ilfov 077125 (Romania); MAIC, University of Florida, Gainesville, FL 32611 (United States); Hermann, J. [LP3, CNRS - Universite Aix-Marseille, 163 Ave. de Luminy, Marseille 13288 (France)

2011-10-15T23:59:59.000Z

366

Bioavailability of Iron, Zinc, Phytate and Phytase Activity during Soaking and Germination of White Sorghum Varieties  

E-Print Network (OSTI)

The changes in phytate, phytase activity and in vitro bioavailability of iron and zinc during soaking and germination of three white sorghum varieties (Sorghum bicolor L. Moench), named Dorado, Shandweel-6, and Giza-15 were investigated. Sorghum varieties were soaked for 20 h and germinated for 72 h after soaking for 20 h to reduce phytate content and increase iron and zinc in vitro bioavailability. The results revealed that iron and zinc content was significantly reduced from 28.16 to 32.16 % and 13.78 to 26.69 % for soaking treatment and 38.43 to 39.18 % and 21.80 to 31.27 % for germination treatments, respectively. Phytate content was significantly reduced from 23.59 to 32.40 % for soaking treatment and 24.92 to 35.27 % for germination treatments, respectively. Phytase enzymes will be activated during drying in equal form in all varieties. The results proved that the main distinct point is the change of phytase activity as well as specific activity during different treatment which showed no significant differences between the varieties used. The in vitro bioavailability of iron

Abd El-moneim M. R. Afify; Hossam S. El-beltagi; Samiha M. Abd El-salam; Azza A. Omran

2010-01-01T23:59:59.000Z

367

The relationship between structural evolution and electrical percolation of the initial stages of tungsten chemical vapor deposition on polycrystalline TiN  

SciTech Connect

This paper presents experimental results and a geometric model of the evolution of sheet resistance and surface morphology during the transition from nucleation to percolation of tungsten chemical vapor deposition over ultrathin polycrystalline titanium nitride (TiN). We observed two mechanisms of reduction in sheet resistance. At deposition temperatures higher than 310 deg. C, percolation effect is formed at {approx}35% of surface coverage, {theta}, and characterized with a sharp drop in resistance. At temperature below 310 deg. C, a reduction in resistance occurs in two steps. The first step occurs when {theta} = 35% and the second step at {theta} = 85%. We suggest a geometric model in which the electrical percolation pass is modulated by the thickness threshold of the islands at the instant of collision.

Rozenblat, A. [Micron Semiconductors Israel Ltd., Qiryat-Gat 82109 (Israel); Department of Physical Electronics, Electrical Engineering, Tel Aviv University, Tel Aviv 69978 (Israel); Haimson, S. [Material Science Program, Tel Aviv University, Tel Aviv 69978 (Israel); Shacham-Diamand, Y. [Department of Physical Electronics, Electrical Engineering, Tel Aviv University, Tel Aviv 69978 (Israel); Horvitz, D. [Micron Semiconductors Israel Ltd., Qiryat-Gat 82109 (Israel)

2012-01-16T23:59:59.000Z

368

Ternary Phase Diagram of the Zn-Sn-P System for Fabrication of ...  

Science Conference Proceedings (OSTI)

First, we establish the phase diagram by equilibrium experiments using zinc, tin and their phosphides. At 700 C, ZnSnP2 is almost stoichiometry,...

369

Available Technologies: Universal Electrochromic Smart Window ...  

Renewable Energy; Environmental Technologies. Monitoring and Imaging; ... nanocrystals of either tin-doped indium oxide (ITO) or aluminum-doped zinc oxide ...

370

Session N: Next Generation Solar Cell Materials and Devices  

Science Conference Proceedings (OSTI)

Jun 22, 2011 ... Aluminum-doped Zinc Oxide (AZO)2 and Indium-doped Tin Oxide (ITO) .... David Young1; Howard Branz1; 1National Renewable Energy Lab;...

371

Microsoft Word - Gerdes.docx  

NLE Websites -- All DOE Office Websites (Extended Search)

tin (Sn), zinc (Zn), and antimony (Sb). The effects of higher hydrocarbons including benzene and naphthalene and process chemicals such as Selexol are also considered. Results...

372

About the EPD  

Science Conference Proceedings (OSTI)

EPD also addresses further processing of nonferrous metals such as copper, nickel, cobalt, precious metals, lead, zinc, and tin and their products by techniques...

373

Second International Conference on Processing Materials for ...  

Science Conference Proceedings (OSTI)

The technical topics include Copper, Nickel, Zinc, Lead and Tin, Rare Metals, Nonferrous Alloys and Light Metals, High-Technology Materials: Electronic,...

374

Thin film cadmium telluride, zinc telluride, and mercury zinc telluride solar cells. Final subcontract report, 1 July 1988--31 December 1991  

DOE Green Energy (OSTI)

This report describes research to demonstrate (1) thin film cadmium telluride solar cells with a quantum efficiency of 75% or higher at 0. 44 {mu}m and a photovoltaic efficiency of 11.5% or greater, and (2) thin film zinc telluride and mercury zinc telluride solar cells with a transparency to sub-band-gap radiation of 65% and a photovoltaic conversion efficiency of 5% and 8%, respectively. Work was directed at (1) depositing transparent conducting semiconductor films by solution growth and metal-organic chemical vapor deposition (MOCVD) technique, (2) depositing CdTe films by close-spaced sublimation (CSS) and MOCVD techniques, (3) preparing and evaluating thin film CdTe solar cells, and (4) preparing and characterizing thin film ZnTe, CD{sub 1-x}Zn{sub 1-x}Te, and Hg{sub 1-x}Zn{sub x}Te solar cells. The deposition of CdS films from aqueous solutions was investigated in detail, and their crystallographic, optical, and electrical properties were characterized. CdTe films were deposited from DMCd and DIPTe at 400{degrees}C using TEGa and AsH{sub 3} as dopants. CdTe films deposited by CSS had significantly better microstructures than those deposited by MOCVD. Deep energy states in CdTe films deposited by CSS and MOCVD were investigated. Thin films of ZnTe, Cd{sub 1- x}Zn{sub x}Te, and Hg{sub 1-x}Zn{sub x}Te were deposited by MOCVD, and their crystallographic, optical, and electrical properties were characterized. 67 refs.

Chu, T.L. [University of South Florida, Tampa, FL (United States)

1992-04-01T23:59:59.000Z

375

HRTEM/AEM and SEM study of fluid-rock interactions: Interaction of copper, silver, selenium, chromium, and cadmium-bearing solutions with geological materials at near surface conditions, with an emphasis on phyllosilicates  

DOE Green Energy (OSTI)

Biotite has been reacted with acidic solutions, at 25'' +/-3''C, bearing silver (Ag{sub 2}SO{sub 4}), selenium (selenite), chromium (hexavalent Cr), and copper (CuSO{sub 4}). The experiments were open to the atmosphere. Transmission electron microscopy (TEM) and scanning electron microscopy (SEM) show that biotite sorbs and reduces Ag+(aq) to metallic silver. Polygonal precipitates and inclusions of metallic silver (with diameters ranging from 10's of angstroms to > {ge} {mu}m) are concentrated on the edges of the biotite flakes and also in the interlayer region. X-ray photoelectron spectroscopy (XPS) of biotites reacted with selenite-bearing solutions show that the oxidation state of selenium sorbed on the surface of biotite is Se{sup 4+}. XPS of biotites reacted with Cr{sup 6+}-bearing solutions show that the oxidation state of chromium sorbed on the surface of biotite is Cr{sup 3+}. Copper-bearing solutions were reacted with low-F biotite in contrast to our previous work with high-F biotite (Olden et al., in press). Results indicate that low-F biotite absorbs more readily and extensively than high-F biotite. Further work on copper-enriched biotite from the chrysocolla zone has revealed that the mode of copper incorporation in biotite is more complex than previously described.

Veblen, D.R.; Ilton, E.S.

1992-05-01T23:59:59.000Z

376

Cycle-life improvement of Zn/NiOOH cells by the addition of Ca(OH) sub 2 to the zinc electrode  

DOE Green Energy (OSTI)

The addition of Ca(OH){sub 2} to the zinc electrode of Zn/NiOOH cells was investigated in order to determine its effect on reducing the rate of Zinc redistribution. Cells containing 0, 10, 25, and 40 mol% Ca(OH){sub 2} in the zinc electrode were constructed and tested. Ca(OH){sub 2} was found to form a calcium zincate complex with the zincate-supersaturated KOH solution created during the discharge half-cycle. As Ca(OH){sub 2} is insoluble in the electrolyte, the formation of this complex (containing two Zn atoms to one Ca) significantly reduces the Zinc redistribution rate. Electrodes with only 10% Ca(OH){sub 2} were found to contain insufficient Ca(OH){sub 2} to complex with enough Zinc to make a dramatic improvement on cycle life. The 25%-Ca(OH){sub 2} electrodes, however, were found to retain their capacity beyond 150 deep discharge cycles, with indication that further Zinc redistribution would occur very slowly. The Zinc utilization of the Ca-containing electrodes showed dramatic improvement over the Ca-free zinc electrodes. 23 refs., 49 figs., 7 tabs.

Jain, R.; McLarnon, F.R.; Cairns, E.J.

1989-08-01T23:59:59.000Z

377

Effects of Different Precursor's Concentration on the Properties of Zinc Oxide Thin Films  

Science Conference Proceedings (OSTI)

Zinc oxide (ZnO) thin films were successfully grown on silicon substrate with different molarities, by a sol-gel method. In the process, the molarities were varied from 0.2-1.0 M and it was found that increasing in molarities had affected the structure of ZnO thin films. The properties of the thin films were characterized and studied by ultraviolet-visible spectroscopy (UV-Vis) and photoluminescence spectrometer (PL). It was found that the molarities affect the optical properties of the resultant ZnO thin films.

Malek, M. F.; Zakaria, N.; Sahdan, M. Z.; Mamat, M. H. [Faculty of Electrical Engineering, Universiti Teknologi MARA, 40450 Shah Alam, Selangor (Malaysia); Khusaimi, Z. [NANO-SciTech Centre, Institute of Science, Universiti Teknologi MARA, 40450 Shah Alam, Selangor (Malaysia); Rusop, M. [Faculty of Electrical Engineering, Universiti Teknologi MARA, 40450 Shah Alam, Selangor (Malaysia); NANO-SciTech Centre, Institute of Science, Universiti Teknologi MARA, 40450 Shah Alam, Selangor (Malaysia)

2010-07-07T23:59:59.000Z

378

Charge Separation of Wurtzite/Zinc-blende Heterojunction GaN Nanowires  

DOE Green Energy (OSTI)

The electronic properties of wurtzite/zinc-blende (WZ/ZB) heterostructure GaN are investigated using first-principles methods. A small component of ZB stacking formed along the growth direction in the WZ GaN nanowires does not show a significant effect on the electronic property, whereas a charge separation of electrons and holes occurs along the directions perpendicular to the growth direction in the ZB stacking. The later case provides an efficient way to separate the charge through controlling crystal structure. These results should have significant implications for most state of the art excitonic solar cells and the tuning region in tunable laser diodes.

Wang, Zhiguo; Li, Jingbo; Gao, Fei; Weber, William J.

2010-08-27T23:59:59.000Z

379

Origin of ferromagnetism enhancement in bi-layer chromium-doped indium zinc oxides  

SciTech Connect

This work demonstrates that by controlling the rapid thermal annealing temperature, amorphous chromium-doped indium zinc oxide films develop an amorphous-crystalline bi-layer structure and show magnetization up to {approx}30 emu/cm{sup 3}. The crystalline layer arises from significant out-diffusion of Zn from surfaces, leading to a large difference in the Zn:In ratio in amorphous and crystalline layers. Doped Cr ions in amorphous and crystalline layers form different valence configurations, creating a charge reservoir which transfers electrons through amorphous-crystalline interfaces and in turn enhances ferromagnetism.

Hsu, C. Y. [Physics Department, National Sun Yat-Sen University, Kaohsiung 804, Taiwan (China)

2012-08-06T23:59:59.000Z

380

Structural and optical properties of zinc oxide film using RF-sputtering technique  

Science Conference Proceedings (OSTI)

This paper reports the fabrication of zinc oxide (ZnO) film using RF-sputtering technique. Determination of the structural properties using High Resolution X-ray Diffraction (HRXRD) confirmed that ZnO film deposited on silicon (Si) substrate has a high quality. This result is in line with the Scanning Electron Microscopy (SEM) and Atomic Force Microscopy (AFM) which were used to image the morphology of the film, in which a rough surface was demonstrated. Photoluminescence (PL) emission is included to study the optical properties of ZnO film that shows two PL peak in the UV region at 371 nm and in visible region at 530 nm respectively.

Hashim, A. J.; Jaafar, M. S.; Ghazai, Alaa J. [Nano-Optoelectronics Research and Technology Laboratory, School of Physics, Universiti Sains Malaysia, 11800 Pinang (Malaysia); Physics Department, Science College, Thi-Qar University (Iraq)

2012-11-27T23:59:59.000Z

Note: This page contains sample records for the topic "zinc tin selenium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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381

Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Volume 1, Bench-scale testing and analysis  

Science Conference Proceedings (OSTI)

AMAX Research & Development Center (AMAX R&D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

Jha, M.C.; Berggren, M.H.

1989-05-02T23:59:59.000Z

382

Selective catalytic reduction system and process for treating NOx emissions using a zinc or titanium promoted palladium-zirconium catalyst  

DOE Patents (OSTI)

A process and system (18) for reducing NO.sub.x in a gas using hydrogen as a reducing agent is provided. The process comprises contacting the gas stream (29) with a catalyst system (38) comprising sulfated zirconia washcoat particles (41), palladium, a pre-sulfated zirconia binder (44), and a promoter (45) comprising at least one of titanium, zinc, or a mixture thereof. The presence of zinc or titanium increases the resistance of the catalyst system to a sulfur and water-containing gas stream.

Sobolevskiy, Anatoly (Orlando, FL); Rossin, Joseph A. (Columbus, OH); Knapke, Michael J. (Columbus, OH)

2011-08-02T23:59:59.000Z

383

Studies on the development of mossy zinc electrodeposits from flowing alkaline electrolytes  

DOE Green Energy (OSTI)

The initiation and characteristics of mossy zinc electrodeposits have been investigated. Batteries with zinc electrodes are candidates for electric vehicle applications; however, this electrode is prone to form non-compact deposits that contribute to capacity loss and battery failure. Moss is deposited when the current density is far from the limiting current. This morphology first appears only after the bulk deposit is approximately 1 {mu}m thick. In this investigation, the effects of flow rate (Re=0--4000), current density (0--50 mA/cm{sup 2}), concentration of the electroactive species (0.25 and 0.5 M), and the concentration of supporting electrolyte (3, 6, and 12 M) on the initiation of moss were examined. The rotating concentric cylinder electrode was employed for most of the experiments; and a flow channel was used to study the development of morphology. After the experiment, the deposit was characterized using microscopic, x-ray diffraction, and profilometric techniques. 94 refs., 72 figs.

Mc Vay, L.

1991-07-01T23:59:59.000Z

384

Development of Zinc/Bromine Batteries for Load-Leveling Applications: Phase 2 Final Report  

DOE Green Energy (OSTI)

This report documents Phase 2 of a project to design, develop, and test a zinc/bromine battery technology for use in utility energy storage applications. The project was co-funded by the U.S. Department of Energy Office of Power Technologies through Sandia National Laboratories. The viability of the zinc/bromine technology was demonstrated in Phase 1. In Phase 2, the technology developed during Phase 1 was scaled up to a size appropriate for the application. Batteries were increased in size from 8-cell, 1170-cm{sup 2} cell stacks (Phase 1) to 8- and then 60-cell, 2500-cm{sup 2} cell stacks in this phase. The 2500-cm{sup 2} series battery stacks were developed as the building block for large utility battery systems. Core technology research on electrolyte and separator materials and on manufacturing techniques, which began in Phase 1, continued to be investigated during Phase 2. Finally, the end product of this project was a 100-kWh prototype battery system to be installed and tested at an electric utility.

CLARK,NANCY H.; EIDLER,PHILLIP

1999-10-01T23:59:59.000Z

385

Transparent conductive indium zinc oxide films prepared by pulsed plasma deposition  

Science Conference Proceedings (OSTI)

Transparent conductive indium zinc oxide films were prepared by pulsed plasma deposition from a ceramic target (90 wt. % In{sub 2}O{sub 3} and 10 wt. % ZnO). The dependences of film properties upon the substrate temperature was investigated using characterization methods including x-ray diffraction, atomic force microscope, Hall measurement, ultraviolet-visible spectroscopy, and x-ray photoelectron spectroscopy. The films grown at room temperature had a rather smooth surface due to the amorphous structure, with a root mean square roughness of less than 1 nm. The atomic ratio of Zn/(Zn + In) in these films is 15.3 at. %, which is close to that in the target, and the chemical states of indium and zinc atoms were In{sup 3+} and Zn{sup 2+}, respectively. The films deposited on a substrate with a temperature of 200 Degree-Sign C exhibited polycrystalline structure and a preferred growth orientation along the (222) plane. Here the electrical properties were improved due to the better crystallinity, with the films exhibiting a minimum resistivity value of 4.2 Multiplication-Sign 10{sup -4}{Omega} cm, a maximum carrier mobility of 45 cm{sup 2} V{sup -1} s{sup -1}, and an optical transmittance over 80% in the visible region.

Wan Runlai; Yang Ming; Zhou Qianfei; Zhang Qun [Department of Materials Science, Fudan University, Shanghai 200433 (China)

2012-11-15T23:59:59.000Z

386

Safety and environmental aspects of zinc--chlorine hydrate batteries for electric-vehicle applications  

DOE Green Energy (OSTI)

Public acceptance of high-performance cost-effective zinc--chlorine hydrate batteries for the random-use electric-vehicle application will require meeting stringent safety and environmental requirements. These requirements revolve mainly around the question of accidental release and spread of toxic amounts of chlorine gas, the only potential hazard in this battery system. Available information in the areas of physiological effects, environmental impact, and governmental regulation of chlorine were reviewed. The design, operation, and safety features of a first commercial electric-vehicle battery were conceived and analyzed from the chlorine release aspect. Two types of accident scenarios were analyzed in terms of chlorine release rates, atmospheric dispersion, health hazard, and possible clean-up operations. The worst-case scenario, a quite improbable accident, involves the spillage of chlorine hydrate onto the ground, while the other scenario, a more probable accident, involves the release of chlorine gas from a ruptured battery case. Heat-transfer and chlorine-dispersion models, developed to analyze these scenarios, establish a firm basis for a comprehenive and factual position statement on this topic. The results of this preliminary study suggest that electric vehicles powered by appropriately designed zinc--chlorine hydrate batteries will pose negligible health or environmental hazards on the nation's streets and highways. 8 figures, 14 tables.

Kodali, S.; Henriksen, G.L.; Whittlesey, C.C.; Warde, C.J.; Carr, P.; Symons, P.C.

1978-03-01T23:59:59.000Z

387

Distribution of toenail selenium levels in young adult Caucasians and African Americans in the United States: The CARDIA Trace Element Study  

SciTech Connect

Background: Data on selenium (Se) levels in American young adults, especially in African Americans, are lacking. Objective: This study presented toenail Se distributions in American young adults of both genders, including both Caucasians and African Americans; and explored potential predictors of toenail Se levels. Data and methods: Data from the Coronary Artery Risk Development in Young Adults study among 4252 American young adults, aged 20-32 in 1987 was used to examine toenail Se levels by instrumental neutron-activation analysis. The distribution of Se levels was described and multivariable linear regression was used to examine potential modifiers of toenail Se concentration within ethnicity-gender subgroups. Results: The geometric mean of toenail Se in this cohort was 0.844 {mu}g/g (95% CI, 0.840-0.849 {mu}g/g) and the median was 0.837 {mu}g/g (95% CI, 0.833-0.844 {mu}g/g). Median levels from lowest to highest quintile were 0.691, 0.774, 0.838, 0.913 and 1.037 {mu}g/g. Se levels varied geographically, and were generally in accordance with its concentrations in local soil. Males, African Americans, current smokers, heavy drinkers and less educated participants were more likely to have low Se levels. Conclusion: This study suggests that toenail Se levels vary geographically depending on soil Se concentrations. In addition to gender, ethnicity and education level, smoking status and alcohol consumption are two important indicators of Se status since they are modifiable lifestyle factors. Findings from this study might aid public health professionals in identifying people at relatively high or low Se levels, so that chronic disease prevention efforts can be directed toward these subgroups. - Research highlights: {yields} Average of toenail Se levels in this cohort was 0.844 {mu}g/g (95% CI, 0.840-0.849 {mu}g/g). {yields} Toenail Se levels vary geographically depending on soil Se concentrations. {yields} Males, African Americans and less educated participants have low Se levels. {yields} Smoking status and alcohol consumption are two important indicators of Se status.

Xun, Pengcheng; Bujnowski, Deborah [Department of Nutrition, Gillings School of Global Public Health and School of Medicine, University of North Carolina at Chapel Hill, 2221 McGavran-Greenberg, Campus Box: 7461, Chapel Hill, NC (United States) [Department of Nutrition, Gillings School of Global Public Health and School of Medicine, University of North Carolina at Chapel Hill, 2221 McGavran-Greenberg, Campus Box: 7461, Chapel Hill, NC (United States); Department of Epidemiology, Gillings School of Global Public Health, University of North Carolina at Chapel Hill, Chapel Hill, NC (United States); Liu, Kiang [Department of Preventive Medicine, Feinberg School of Medicine, Northwestern University, Chicago, IL (United States)] [Department of Preventive Medicine, Feinberg School of Medicine, Northwestern University, Chicago, IL (United States); Steve Morris, J. [Research Reactor Center, University of Missouri-Columbia, Columbia, MO (United States)] [Research Reactor Center, University of Missouri-Columbia, Columbia, MO (United States); Guo, Zhongqin [Department of Epidemiology and Biostatistics, School of Public Health, Ningxia Medical University, Ningxia (China) [Department of Epidemiology and Biostatistics, School of Public Health, Ningxia Medical University, Ningxia (China); Department of Nutrition, Gillings School of Global Public Health and School of Medicine, University of North Carolina at Chapel Hill, 2221 McGavran-Greenberg, Campus Box: 7461, Chapel Hill, NC (United States); He, Ka, E-mail: kahe@unc.edu [Department of Nutrition, Gillings School of Global Public Health and School of Medicine, University of North Carolina at Chapel Hill, 2221 McGavran-Greenberg, Campus Box: 7461, Chapel Hill, NC (United States) [Department of Nutrition, Gillings School of Global Public Health and School of Medicine, University of North Carolina at Chapel Hill, 2221 McGavran-Greenberg, Campus Box: 7461, Chapel Hill, NC (United States); Department of Epidemiology, Gillings School of Global Public Health, University of North Carolina at Chapel Hill, Chapel Hill, NC (United States)

2011-05-15T23:59:59.000Z

388

Preparation of polyimide/zinc oxide nanocomposite films via an ion-exchange technique and their photoluminescence properties  

Science Conference Proceedings (OSTI)

Polyimide (PI) composite films with ZnO nanoparticles embedded in the surface layer were prepared by alkali hydrolyzation following ion exchange in Zn(NO3)2 solution and thermal treatment of the zinc ion-doped PI films in air atmosphere. ...

Shuxiang Mu; Dezhen Wu; Shengli Qi; Zhanpeng Wu

2011-01-01T23:59:59.000Z

389

Start | Author Index 741-7 Speciation and Release Kinetics of Cadmium and Zinc in Thai Paddy Soil.  

E-Print Network (OSTI)

Start | Author Index 741-7 Speciation and Release Kinetics of Cadmium and Zinc in Thai Paddy Soil Ginder-Vogel 1 , Rufus L. Chaney 2 and Donald L. Sparks 1 , (1)Department of Plant and Soil Sciences is harmful to human health. Although Cd has no biological role in rice, rice can take up Cd from soil

Sparks, Donald L.

390

Durability of LDPE nanocomposites with clay, silica, and zinc oxide: part I: mechanical properties of the nanocomposite materials  

Science Conference Proceedings (OSTI)

Three types of LDPE-based nanocomposites with montmorillonite clay, silica, and zinc oxide were prepared by melt blending the nanofiller with the resin. As a prelude to studying their durability, the extent of reinforcement of the LDPE matrix by the ...

Halim Hamid Redhwi, Mohammad Nahid Siddiqui, Anthony L. Andrady, Syed Hussain

2013-01-01T23:59:59.000Z

391

Utility Cycle Testing of a 500-kWh Zinc Chloride Battery at the Battery Energy Storage Test (BEST) Facility  

Science Conference Proceedings (OSTI)

A 500-kWh zinc chloride battery test system completed an entire schedule of 80 simulated utility and customer application cycles--the most diverse and severe known to be successfully performed by any advanced battery system. Encouraged by these results, researchers plan to have a 2-MW demonstration battery system ready for testing in 1986.

1985-10-09T23:59:59.000Z

392

Structure, optical, and electrical properties of indium tin oxide thin films prepared by sputtering at room temperature and annealed in air or nitrogen  

Science Conference Proceedings (OSTI)

Indium tin oxide (ITO) thin films have been grown onto soda-lime glass substrates by sputtering at room temperature with various oxygen to argon partial pressure ratios. After deposition, the samples have been annealed at temperatures ranging from 100 to 500 degree sign C in nitrogen or in air. The structure, optical, and electrical characteristics of the ITO coatings have been analyzed as a function of the deposition and the annealing parameters by x-ray diffraction, spectrophotometry, and Hall effect measurements. It has been found that the as-grown amorphous layers crystallize in the cubic structure by heating above 200 degree sign C. Simultaneously, the visible optical transmittance increases and the electrical resistance decreases, in proportions that depend mainly on the sputtering conditions. The lowest resistivity values have been obtained by annealing at 400 degree sign C in nitrogen, where the highest carrier concentrations are achieved, related to oxygen vacancy creation. Some relationships between the analyzed properties have been established, showing the dependence of the cubic lattice distortion and the infrared optical characteristics on the carrier concentration.

Guillen, C.; Herrero, J. [Departamento de Energia, CIEMAT, Avda Complutense 22, 28040 Madrid (Spain)

2007-04-01T23:59:59.000Z

393

Ti-Doped Indium Tin Oxide Thin Films for Transparent Field-Effect Transistors: Control of Charge-Carrier Density and Crystalline Structure  

Science Conference Proceedings (OSTI)

Indium tin oxide (ITO) films are representative transparent conducting oxide media for organic light-emitting diodes, liquid crystal displays, and solar cell applications. Extending the utility of ITO films from passive electrodes to active channel layers in transparent field-effect transistors (FETs), however, has been largely limited because of the materials' high carrier density (>1 x 10{sup 20} cm{sup 03}), wide band gap, and polycrystalline structure. Here, we demonstrate that control over the cation composition in ITO-based oxide films via solid doping of titanium (Ti) can optimize the carrier concentration and suppress film crystallization. On 120 nm thick SiO{sub 2}/Mo (200 nm)/glass substrates, transparent n-type FETs prepared with 4 at % Ti-doped ITO films and fabricated via the cosputtering of ITO and TiO{sub 2} exhibited high electron mobilities of 13.4 cm{sup 2} V{sup -1} s{sup -1}, a low subthreshold gate swing of 0.25 V decade{sup -1}, and a high I{sub on}/I{sub off} ratio of >1 x 10{sup 8}.

J Kim; K Ji; M Jang; H Yang; R Choi; J Jeong

2011-12-31T23:59:59.000Z

394

Flexible indium zinc oxide/Ag/indium zinc oxide multilayer electrode grown on polyethersulfone substrate by cost-efficient roll-to-roll sputtering for flexible organic photovoltaics  

Science Conference Proceedings (OSTI)

The authors describe the preparation and characteristics of flexible indium zinc oxide (IZO)-Ag-IZO multilayer electrodes grown on flexible polyethersulfone (PES) substrates using a roll-to-roll sputtering system for use in flexible organic photovoltaics. By the continuous roll-to-roll sputtering of the bottom IZO, Ag, and top IZO layers at room temperature, they were able to fabricate a high quality IZO-Ag-IZO multilayer electrode with a sheet resistance of 6.15 {epsilon}/square, optical transmittance of 87.4%, and figure of merit value of 42.03x10{sup -3} {Omega}{sup -1} on the PES substrate. In addition, the IZO-Ag-IZO multilayer electrode exhibited superior flexibility to the roll-to-roll sputter grown single ITO electrode due to the existence of a ductile Ag layer between the IZO layers and stable amorphous structure of the IZO film. Furthermore, the flexible organic solar cells (OSCs) fabricated on the roll-to-roll sputter grown IZO-Ag-IZO electrode showed higher power efficiency (3.51%) than the OSCs fabricated on the roll-to-roll sputter grown single ITO electrode (2.67%).

Park, Yong-Seok; Kim, Han-Ki [Department of Display Materials Engineering, Kyung Hee University, 1 Seochoen-dong, Yongin-si, Gyeonggi-do 446-701 (Korea, Republic of)

2010-01-15T23:59:59.000Z

395

Correlations between lead, cadmium, copper, zinc, and iron concentrations in frozen tuna fish  

Science Conference Proceedings (OSTI)

The presence of metallic pollutants in marine ecosystems has promoted wide research plans in order to evaluate pollution levels in marine organisms. However, little is known concerning environmental and physiological processes that regulate the concentration of trace metals in marine organisms. Even though the toxicity of lead and cadmium is well established, copper, zinc and iron are considered as essential elements for mammals. Little is known about heavy metals, other than mercury, concentrations in fresh and frozen tuna fish. Fifty samples obtained at the entrance of a canning factory in Santa Cruz de Tenerife (Canary Islands), were analyzed by atomic absorption spectrophotometry. Results were treated by applying the Statistical Package for the Social Sciences compiled and linked in the software of a Digital VAX/VMS 11/780 computer.

Galindo, L.; Hardisson, A.; Montelongo, F.G.

1986-04-01T23:59:59.000Z

396

Cost analysis of 50 kWh zinc--chlorine batteries for mobile applications  

DOE Green Energy (OSTI)

The costs comprising the projected selling price of a 50-kWh zinc--chlorine battery for mobile applications were analyzed. This analysis is predicated on a battery whose engineering and design specifications are well crystallized. Such a design has been proposed and a process plan conceived. This, in turn, led to a simulated manufacturing plan. This analysis showed that no critical resources or complex manufacturing operations are required. The projected cost presumes a production level of 25,000 batteries per year. In that context, a selling price was estimated, in mid-1977 dollars, to be $1645 per battery or $33/kWh. This price excludes the battery charger, for which an added $400 ($8/kWh) is considered reasonable. 8 figures, 19 tables.

Catherino, H.; Henriksen, G.L.; Whittlesey, C.C.; Warde, C.J.; Carr, P.; Symons, P.C.

1978-01-01T23:59:59.000Z

397

Effect of supplementation on vitamin A and zinc nutriture of children in northeast (NE) Thailand  

SciTech Connect

Previous surveys of the nutritional status of young children in NE Thailand suggested that they may benefit from vitamin A (VA) and/or zinc (Zn) supplementation. 140 children, with low plasma retinol concentrations were entered in a double-blind study. They were randomized and supplemented with either VA, Zn, VA + Zn or placebo each weekday for 6 mos. All subjects consumed their usual diet that provided adequate protein, less than recommended calories, fat, Zn and VA. Biochemical indices of VA and Zn status increased significantly. The children had adequate VA liver stores as assessed by relative dose response. Zn supplementation resulted in improvement of vision restoration time in dim light using rapid dark adaptometry. VA and Zn synergistically normalized conjunctival epithelium after a 6 mo supplementation. Data suggest that functional improvements of populations with suboptimal VA and Zn nutriture can be accomplished by supplementation with {lt}2 times of RDA of these nutrients.

Udomkesmalee, E.; Dhanamitta, S.; Charoenklatkul, S.; Tantipopipat, S.; Banjong, O.; Rojroongwasinkul, N.; Kramer, T.R.; Smith, J.C. Jr. (Mahidol Univ., Nakhon Pathom (Thailand) USDA, Beltsville, MD (United States))

1991-03-11T23:59:59.000Z

398

Research, development and demonstration of nickel-zinc batteries for electric vehicle propulsion. Annual report, 1979  

DOE Green Energy (OSTI)

Progress achieved under ANL Contract No. 31-109-38-4248 from 16 August 1978 to 16 August 1979 is reported. The first segment of the overall program, component development, consists of four basic tasks proceeding in parallel: nickel electrode development, zinc electrode development, separator development, and sealed cell development. Each of these tasks is reported herein on a self-contained basis. System engineering is the second major subdivision of the effort. It includes the design and testing of all cells, the investigation of charge control devices and techniques, and the complete analysis of all cells for failure modes. It also encompasses the accelerated testing of 20-Ah cells. To date, large numbers of these cells (incorporating separator variations, active material additives and internal design variations) have been subjected to this type of testing. 48 figures, 47 tables. (RWR)

Not Available

1980-06-01T23:59:59.000Z

399

An engineered split M.HhaI-zinc finger fusion lacks the intended methyltransferase specificity  

SciTech Connect

The ability to site-specifically methylate DNA in vivo would have wide applicability to the study of basic biomedical problems as well as enable studies on the potential of site-specific DNA methylation as a therapeutic strategy for the treatment of diseases. Natural DNA methyltransferases lack the specificity required for these applications. Nomura and Barbas [W. Nomura, C.F. Barbas 3rd, In vivo site-specific DNA methylation with a designed sequence-enabled DNA methylase, J. Am. Chem. Soc. 129 (2007) 8676-8677] have reported that an engineered DNA methyltransferase comprised of fragments of M.HhaI methyltransferase and zinc finger proteins has very high specificity for the chosen target site. Our analysis of this engineered enzyme shows that the fusion protein methylates target and non-target sites with similar efficiency.

Meister, Glenna E. [Department of Chemical and Biomolecular Engineering, Johns Hopkins University, 3400 N. Charles Street, Baltimore, MD 21218 (United States); Chandrasegaran, Srinivasan [Department of Environmental Health Sciences, Bloomberg School of Public Health, Johns Hopkins University, 615 North Wolfe Street, Baltimore, MD 21205 (United States); Ostermeier, Marc [Department of Chemical and Biomolecular Engineering, Johns Hopkins University, 3400 N. Charles Street, Baltimore, MD 21218 (United States)], E-mail: oster@jhu.edu

2008-12-05T23:59:59.000Z

400

Electrical effect of titanium diffusion on amorphous indium gallium zinc oxide  

Science Conference Proceedings (OSTI)

In this work, thermal diffusion phenomenon of Ti into amorphous indium gallium zinc oxide ({alpha}-IGZO) was carefully investigated with secondary ion mass spectroscopy, I-V, and R{sub s} measurement systems and HSC chemistry simulation tool. According to the experimental and simulated results, the diffused Ti atoms were easily oxidized due to its lowest oxidation free energy. Since oxygen atoms were decomposed from the {alpha}-IGZO during the oxidation of Ti, the number of oxygen vacancies working as electron-donating sites in {alpha}-IGZO was dramatically increased, contributing to the decrease of resistivity ({rho}) from 1.96 {Omega} cm (as-deposited {alpha}-IGZO) to 1.33 Multiplication-Sign 10{sup -3}{Omega} cm (350 Degree-Sign C annealed {alpha}-IGZO).

Choi, Seung-Ha [School of Electronic and Electrical Engineering, Sungkyunkwan University, Suwon 440-746 (Korea, Republic of); Development Group of Oxide Semiconductor, Samsung Display, Yongin 446-711 (Korea, Republic of); Jung, Woo-Shik [Department of Electrical Engineering, Stanford University, Stanford, California 94305 (United States); Park, Jin-Hong [School of Electronic and Electrical Engineering, Sungkyunkwan University, Suwon 440-746 (Korea, Republic of)

2012-11-19T23:59:59.000Z

Note: This page contains sample records for the topic "zinc tin selenium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Inclusion free cadmium zinc tellurium and cadmium tellurium crystals and associated growth method  

DOE Patents (OSTI)

The present disclosure provides systems and methods for crystal growth of cadmium zinc tellurium (CZT) and cadmium tellurium (CdTe) crystals with an inverted growth reactor chamber. The inverted growth reactor chamber enables growth of single, large, high purity CZT and CdTe crystals that can be used, for example, in X-ray and gamma detection, substrates for infrared detectors, or the like. The inverted growth reactor chamber enables reductions in the presence of Te inclusions, which are recognized as an important limiting factor in using CZT or CdTe as radiation detectors. The inverted growth reactor chamber can be utilized with existing crystal growth techniques such as the Bridgman crystal growth mechanism and the like. In an exemplary embodiment, the inverted growth reactor chamber is a U-shaped ampoule.

Bolotnikov, Aleskey E. (South Setauket, NY); James, Ralph B. (Ridge, NY)

2010-07-20T23:59:59.000Z

402

Internal Electric Field Behavior of Cadmium Zinc Telluride Radiation Detectors Under High Carrier Injection  

Science Conference Proceedings (OSTI)

The behavior of the internal electric-field of nuclear-radiation detectors substantially affects the detector's performance. We investigated the distribution of the internal field in cadmium zinc telluride (CZT) detectors under high carrier injection. We noted the build-up of a space charge region near the cathode that produces a built-in field opposing the applied field. Its presence entails the collapse of the electric field in the rest of detector, other than the portion near the cathode. Such a space-charge region originates from serious hole-trapping in CZT. The device's operating temperature greatly affects the width of the space-charge region. With increasing temperature from 5 C to 35 C, its width expanded from about 1/6 to 1/2 of the total depth of the detector.

Yang, G.; Bolotnikov, A.E.; Camarda, G.S.; Cui, Y.; Hossain, A.; Kim, K.H.; Gul, R.; and James, R.B.

2010-10-26T23:59:59.000Z

403

Changes in Zinc Speciation with Mine Tailings Acidification in a Semiarid Weathering Environment  

Science Conference Proceedings (OSTI)

High concentrations of residual metal contaminants in mine tailings can be transported easily by wind and water, particularly when tailings remain unvegetated for decades following mining cessation, as is the case in semiarid landscapes. Understanding the speciation and mobility of contaminant metal(loid)s, particularly in surficial tailings, is essential to controlling their phytotoxicities and to revegetating impacted sites. In prior work, we showed that surficial tailings samples from the Klondyke State Superfund Site (AZ, USA), ranging in pH from 5.4 to 2.6, represent a weathering series, with acidification resulting from sulfide mineral oxidation, long-term Fe hydrolysis, and a concurrent decrease in total (6000 to 450 mg kg{sup -1}) and plant-available (590 to 75 mg kg{sup -1}) Zn due to leaching losses and changes in Zn speciation. Here, we used bulk and microfocused Zn K-edge X-ray absorption spectroscopy (XAS) data and a six-step sequential extraction procedure to determine tailings solid phase Zn speciation. Bulk sample spectra were fit by linear combination using three references: Zn-rich phyllosilicate (Zn{sub 0.8}talc), Zn sorbed to ferrihydrite (Zn{sub adsFeOx}), and zinc sulfate (ZnSO{sub 4} {center_dot} 7H{sub 2}O). Analyses indicate that Zn sorbed in tetrahedral coordination to poorly crystalline Fe and Mn (oxyhydr)oxides decreases with acidification in the weathering sequence, whereas octahedral zinc in sulfate minerals and crystalline Fe oxides undergoes a relative accumulation. Microscale analyses identified hetaerolite (ZnMn{sub 2}O{sub 4}), hemimorphite (Zn{sub 4}Si{sub 2}O{sub 7}(OH){sub 2} {center_dot} H{sub 2}O) and sphalerite (ZnS) as minor phases. Bulk and microfocused spectroscopy complement the chemical extraction results and highlight the importance of using a multimethod approach to interrogate complex tailings systems.

Hayes, Sarah M.; O’ Day, Peggy A.; Webb, Sam M.; Maier, Raina M.; Chorover, Jon (UCM); (SLAC); (Ariz)

2012-10-09T23:59:59.000Z

404

Development of a multi-regime tribometer and investigation of zinc dialkyldithiophosphate tribofilm development in the presence of overbased calcium sulfonate  

E-Print Network (OSTI)

A custom tribometer was developed to investigate the production of nano-scale films from the anti-wear additive zinc dialkyldithiophosphate (ZDDP). The tribometer was designed to operate in various conditions of lubrication ...

Kariya, H. Arthur (Harumichi Arthur)

2009-01-01T23:59:59.000Z

405

Prospect of advanced lead-acid, nickel/iron and nickel/zinc batteries for electric vehicle applications  

SciTech Connect

Major progress has been achieved in the lead-acid, nickel/iron and nickel/zinc battery technology development since the initiation of the Near-Term EV Battery Project in 1978. Against the specific energy goal of 56 Wh/kg the demonstrated specific energies are 41 Wh/kg for the improved lead-acid batteries, 48 Wh/kg for the improved nickel/iron batteries, and 68 Wh/kg for the improved nickel/zinc batteries. These specific energy values would allow an ETV-1 vehicle to have an urban range of 80 miles in the case of the improved lead-acid batteries, 96 miles for the improved nickel/iron batteries, and 138 miles for the improved nickel/zinc batteries. All represent a significant improvement over the state-of-the-art lead-acid battery capability of about 30 Wh/kg with approximately a 51 mile urban range for the ETV-1 vehicle. The project goal for specific power of 104 W/kg for 30 seconds at a 50% depth of discharge has been achieved for all of the technologies with the improved lead-acid demonstrating 111 W/kg, the improved nickel/iron demonstrating 103 W/kg and the improved nickel/zinc demonstrating 131 W/kg. Again this is a significant improvement over the state-of-the-art lead-acid battery capability of 70 W/kg. Substantial progress has been made against the life cycle goal of 800 cycles as evidenced by the demonstrated lead-acid battery achievement of >295 cycles in ongoing tests, the nickel/iron demonstrated capability of >515 cycles in ongoing tests, and the nickel/zinc demonstrated capability of 179 cycles. Except for the nickel/zinc batteries, the demonstrated cycle life is better than the state-of-the-art lead-acid battery cycle life of about 250 cycles. Future program emphases will be on improving cycle life and further reductions in cost.

Yao, N.P.; Christianson, C.C.; Hornstra, F.

1981-01-01T23:59:59.000Z

406

Cs-Se (Cesium - Selenium)  

Science Conference Proceedings (OSTI)

Cs-Se crystallographic data...Cs-Se crystallographic data Phase Composition, wt% Se Pearson symbol Space group (Cs) 0 cI 2 Im m Cs 2 Se 22.9 oP 12 Pnma Cs 3 Se 2 28 ? ? Cs 5 Se 4 32.2 ? ? CsSe 37.3 ? ? Cs 2 Se 3 47 oC 20 Cmc 2 1 Cs 2 Se 5 59.7 oP 28 P 2 1 2 1 2 1 (Se) 100 hP 3 P 3 1 2 1 High-pressure phase Cs 2 Se 22.9 oF 24 Fdd 2...

407

TMS 2011: Networking Events: Lectures  

Science Conference Proceedings (OSTI)

... iron; the removal of selenium by elemental iron and catalysed iron; and the removal of cadmium, copper, nickel, zinc by co-precipitation with Fe(III) and Al(III).

408

CGC Trace Species Partitioning  

NLE Websites -- All DOE Office Websites (Extended Search)

per square inch gage Sb Antimony scfd Standard cubic feet per day Se Selenium SO 2 SOFC Solid oxide fuel cell Sulfur dioxide V Vanadium vol% Volume percent Zn Zinc C Degrees...

409

The Interactions of Zinc Thiolate Complexes and Exogenous Metal Species: Investigations of Thiolate Bridging and Metal Exchange  

E-Print Network (OSTI)

Small molecule Zn(II) complexes containing N- and S- donor environments may serve as appropriate models for mimicking Zn protein sites, and thus, their reactions with heavy metal ions such as Pt(II) and W(0) may provide insight into possible adduct formation and zinc displacement. To study such possible interactions between zinc finger proteins and platinum-bound DNA, the ZnN2S2 dimeric complex, N,N?-bis(2- mercaptoethyl)-1,4-diazacycloheptane zinc (II), [Zn-1?]2, has been examined for Znbound thiolate reactivity in the presence of Pt(II) nitrogen ? rich compounds. The reactions yielded Zn/Pt di- and tri- nuclear thiolate-bridged adducts and metalexchanged products, which were initially observed via ESI-mass spectrometry (ESI-MS) analysis of reaction solutions, and ultimately verified by comparison to the ESI-MS analysis, 195Pt NMR spectroscopy, and X-ray crystallography of directly synthesized complexes. The isolation of Zn-(?-SR)-Pt-bridged [(Zn(bme-dach)Cl)(Pt(dien))]Cl adduct from these studies is, to our knowledge, the first Zn-Pt bimetallic thiolatebridged model demonstrating the interaction between Zn-bound thiolates and Pt(II). Additional derivatives involving Pd(II) and Au(III) have been explored to parallel the experiments executed with Pt(II). The [Zn-1?]2 was then modified by cleavage with Na+[ICH2CO2]- to produce (N- (3-Thiabutyl)-N?-(3-thiapentaneoate)-1,4-diazacycloheptane) zinc(II), Zn-1?-Ac or ZnN2SS?O, and 1,4-diazacycloheptane-1,4-diylbis(3-thiapentanoato) zinc(II), Zn-1?-Ac2 or ZnN2S?2O2, monomeric complexes (where S = thiolate, S? = thioether). The [Zn-1?]2 di- and Zn-1?-Ac mono-thiolato complexes demonstrated reactivity towards labile-ligand tungsten carbonyl species, (THF)W(CO)5 and (pip)2W(CO)4, to yield, respectively, the [(Zn-1?-Cl)W(CO)4]- complex and the [(Zn-1?-Ac)W(CO)5]x coordination polymer. With the aid of CO ligands for IR spectral monitoring, the products were isolated and characterized spectroscopically, as well as by X-ray diffraction and elemental analysis. To examine the potential for zinc complexes (or zinc-templated ligands) to possibly serve as a toxic metal remediation agents, Zn-1?-Ac and Zn-1?-Ac2 were reacted with Ni(BF4)2. The formation of Zn/Ni exchanged products confirmed the capability of ?free? Ni(II) to displace Zn(II) within the N-, S-, and O- chelate environment. The Zn/Ni exchanged complexes were analyzed by ESI-MS, UV-visible spectroscopy, IR spectroscopy of the acetate regions, and X-ray crystallography. They serve as foundation molecules for more noxious metal exchange / zinc displacement products.

Almaraz, Elky

2009-05-01T23:59:59.000Z

410

Lithium/selenium secondary battery for implantation. Annual technical progress report No. 1, 23 June 1969--22 June 1970. [10 W, 120 Wh, 1. 1 kg, LiF--LiCl--LiI + LiAlO/sub 2/ electrolyte  

DOE Green Energy (OSTI)

A lithium/selenium battery is being developed as an implantable power source for an artificial heart or heart-assist device. Tests of 7.5-cm dia single cells operating at about 370C with a paste electrolyte consisting of LiF--LiCl--LiI and LiAlO/sub 2/ powder yielded energy densities exceeding 0.76 Wh/cm/sup 2/ at an average voltage above 1.7 V. This performance is sufficient to permit the construction of a 10-W, 120-Wh battery weighing about 1.1 kg. An unsealed battery test demonstrated that a battery of five 7.5-cm dia lithium/selenium cells will be capable of at least 12 W of power. In addition, a sealed lithium/selenium battery was operated in an air environment, and was found to be relatively insensitive to motion as well as orientation. Further work is needed on the development of sealed cells and batteries, on increasing the battery power level to 30 W, and on increased cell life.

Cairs, F.J.; Chilenskas, A.A.; Shimotake, H.; Steunenbert, R.K.; Tevebaugh, A.D.

1970-09-01T23:59:59.000Z

411

Reference Data for the Density and Viscosity of Liquid Cadmium, Cobalt, Gallium, Indium, Mercury, Silicon, Thallium, and Zinc  

Science Conference Proceedings (OSTI)

The available experimental data for the density and viscosity of liquid cadmium, cobalt, gallium, indium, mercury, silicon, thallium, and zinc have been critically examined with the intention of establishing both a density and a viscosity standard. All experimental data have been categorized into primary and secondary data according to the quality of measurement, the technique employed and the presentation of the data, as specified by a series of criteria. The proposed standard reference correlations for the density of liquid cadmium, cobalt, gallium, indium, silicon, thallium, and zinc are characterized by percent deviations at the 95% confidence level of 0.6, 2.1, 0.4, 0.5, 2.2, 0.9, and 0.7, respectively. In the case of mercury, since density reference values already exist, no further work was carried out. The standard reference correlations for the viscosity of liquid cadmium, cobalt, gallium, indium, mercury, silicon, thallium, and zinc are characterized by percent deviations at the 95% confidence level of 9.4, 14.0, 13.5, 2.1, 7.3, 15.7, 5.1, and 9.3, respectively.

Assael, Marc J.; Armyra, Ivi J.; Brillo, Juergen; Stankus, Sergei V.; Wu Jiangtao; Wakeham, William A. [Chemical Engineering Department, Aristotle University, 54124 Thessaloniki (Greece); Institut fuer Materialphysik im Weltraum, Deutsches Zentrum fuer Luft- und Raumfahrt, 51170 Koeln (Germany); Kutateladze Institute of Thermophysics, Siberian Brunch of the Russian Academy of Sciences, Lavrentyev ave. 1, 630090 Novosibirsk (Russian Federation); Center of Thermal and Fluid Science, School of Energy and Power Engineering, Xi'an Jiaotong University, Shaanxi 710049 (China); Chemical Engineering Department, Imperial College, London SW7 2BY (United Kingdom)

2012-09-15T23:59:59.000Z

412

Energy and Technolgy Assessment of Zinc and Magnesium Casting Plants, Technical Report Close-out, August 25,2006  

Science Conference Proceedings (OSTI)

Twin City Die Castings Company of Minneapolis, Minnesota, Twin City Die Castings Company was awarded project No. DE-FG36-05GO15097 to perform plant wide assessments of ten (10) die casting facilities that produce zinc and magnesium alloy castings in order to determine improvements and potential cost savings in energy use. Mr. Heider filled the role of team leader for the project and utilized the North American Die Casting Association (NADCA) to conduct audits at team participant plants so as to hold findings specific to each plant proprietary. The intended benefits of the project were to improve energy use through higher operational and process efficiency for the plants assessed. An improvement in energy efficiency of 5 15% was targeted. The primary objectives of the project was to: 1) Expand an energy and technology tool developed by the NADCA under a previous DOE project titled, Energy and Technology Assessment for Die Casting Plants for assessing aluminum die casting plants to be more specifically applicable to zinc and magnesium die casting facilities. 2) Conduct ten (10) assessments of zinc and magnesium die casting plants, within eight (8) companies, utilizing the assessment tool to identify, evaluate and recommend opportunities to enhance energy efficiency, minimize waste, and improve productivity. 3) Transfer the assessment tool to the die casting industry at large.

Twin City Die Castings Company; Tom Heider; North American Die Castings Association

2006-08-25T23:59:59.000Z

413

Growth of Bi doped cadmium zinc telluride single crystals by Bridgman oscillation method and its structural, optical, and electrical analyses  

Science Conference Proceedings (OSTI)

The II-VI compound semiconductor cadmium zinc telluride (CZT) is very useful for room temperature radiation detection applications. In the present research, we have successfully grown Bi doped CZT single crystals with two different zinc concentrations (8 and 14 at. %) by the Bridgman oscillation method, in which one experiment has been carried out with a platinum (Pt) tube as the ampoule support. Pt also acts as a cold finger and reduces the growth velocity and enhances crystalline perfection. The grown single crystals have been studied with different analysis methods. The stoichiometry was confirmed by energy dispersive by x-ray and inductively coupled plasma mass spectroscopy analyses and it was found there is no incorporation of impurities in the grown crystal. The presence of Cd and Te vacancies was determined by cathodoluminescence studies. Electrical properties were assessed by I-V analysis and indicated higher resistive value (8.53x10{sup 8} {Omega} cm) for the crystal grown with higher zinc concentration (with Cd excess) compare to the other (3.71x10{sup 5} {Omega} cm).

Carcelen, V.; Rodriguez-Fernandez, J.; Dieguez, E. [Dpto. Fisica de Materiales, Laboratorio de Crecimiento de Cristales, Facultad de Ciencias, Univ. Autonoma de Madrid, 28049 Cantoblanco (Spain); Hidalgo, P. [Dpto. Fisica de Materiales, Facultad de Ciencias Fisicas, Univ. Complutense de Madrid, 28040 Madrid (Spain)

2010-05-15T23:59:59.000Z

414

Ordered Layered Organic-Inorganic of 4-Chlorophenoxyacetate-Zinc Layered Hydroxide Nanohybrid  

Science Conference Proceedings (OSTI)

Ordered layered organic-inorganic nanostructure composed of zinc layered hydroxide-4-chlorophenoxy acetate (ZLH-4CPA) was prepared by reaction of an organic anion, 4-chlorophenoxy acetate (4CPA) with ZnO under aqueous environment. The concentration of 4CPA was found to be a controlling factor in determining the formation of phase pure, well ordered nanolayered hybrid material. At lower concentration of 4CPA (0.05 M), a mixed phase was observed in which ZnO co-existed with the nanohybrid. At 0.01 M, a pure phase is obtained with high crystallinity but a well ordered nanolayered structure is lacking. A pure phase, well ordered nanolayered hybrid can be clearly observed at 0.2 M 4CPA. ZnO shows well defined grain structure of various sizes at nanometer scale range. Direct reaction between ZnO and 4CPA under aqueous environment resulted in the formation of 4CPA-ZLH nanohybrid with flake-like fibrous structure. On heating at 500 deg. C for 5 h under atmospheric condition, the nanohybrid was transformed back to well defined grain structure, as previously observed for the starting materials, ZnO. This shows that the nanohybrid has ''memory effect'' property. Well ordered nanolayered hybrid with up to 5 harmonics, from which the average basal spacing of 19.03 A of the material was deduced, showing long range order of the layer packing.

Hussein, Mohd Zobir [Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, 43400 Serdang, Selangor (Malaysia); Advanced Materials and Nanotechnology Laboratory, Institute of Advanced Technology (ITMA), Universiti Putra Malaysia, 43400 Serdang, Selangor (Malaysia); Nazarudin, Nor Farhana binti [Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, 43400 Serdang, Selangor (Malaysia); Sarijo, Siti Halimah [Faculty of Applied Science, Universiti Teknologi Mara (UiTM), 40450 Shah Alam, Selangor (Malaysia); Yarmo, Mohd Ambar [Department of Chemistry, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia)

2011-03-30T23:59:59.000Z

415

Investigation of zinc oxide doped with metal impurities for use as thin film conductive phosphors  

E-Print Network (OSTI)

Various technologies for manufacturing flat panel displays are currently being pursued world-wide. These include active matrix LCD, passive matrix LCD, and LED technologies, as well as several field emission approaches. To facilitate the development of a viable flat panel display, low voltage, conductive phosphors which emit blue, red, and green light will be required for the field emission technology. This thesis examines zinc oxide (ZnO) based thin ( ) phosphors for such an application. ZnO is a 11-VI wide bandgap semiconductor which exhibits green luminescence and has been shown to produce red luminescence as well. However, no blue light emission from ZnO thin film phosphors has been reported. An experimental survey has been conducted in which metal dopants were introduced in ZnO. This survey has revealed tungsten doped ZnO to be a previously unreported brilliant blue phosphor with high resistivity. Additional experiments indicated aluminum could be introduced in conjunction with the tungsten to increase the conductivity of the new blue ZnO phosphors. ZnO doped samples with varying amounts of tungsten and aluminum were subsequently prepared and tested. Optimization of the annealing conditions was then studied. The survey results are contained herein. Finally, it should be noted these phosphors have produced light when used as the anode material in vacuum field emission diodes.

Evatt, Steven R.

1994-01-01T23:59:59.000Z

416

Electrical and gas sensing properties of self-aligned copper-doped zinc oxide nanoparticles  

Science Conference Proceedings (OSTI)

Electrical and gas sensing properties of nanocrystalline ZnO:Cu, having Cu X wt% (X = 0.0, 0.5, 1.0, and 1.5) in ZnO, in the form of pellet were investigated. Copper chloride and zinc acetate were used as precursors along with oxalic acid as a precipitating reagent in methanol. Material characterization was done by X-ray diffraction (XRD), scanning electron microscopy (SEM), field emission scanning electron microscopy (FE-SEM) and inductive coupled plasma with optical emission spectrometry (ICP-OES). FE-SEM showed the self-aligned Cu-doped ZnO nano-clusters with particles in the range of 40-45 nm. The doping of 0.5% of copper changes the electrical conductivity by an order of magnitude whereas the temperature coefficient of resistance (TCR) reduces with increase in copper wt% in ZnO. The material has shown an excellent sensitivity for the H{sub 2}, LPG and CO gases with limited temperature selectivity through the optimized operating temperature of 130, 190 and 220 deg. C for H{sub 2}, LPG and CO gases, respectively at 625 ppm gas concentration. The %SF was observed to be 1460 for H{sub 2} at 1% Cu doping whereas the 0.5% Cu doping offered %SF of 950 and 520 for CO and LPG, respectively. The response and recovery time was found to be 6 to 8 s and 16 s, respectively.

Sonawane, Yogesh S. [Thin Film Laboratory, Department of Physics, University of Pune, Pune 411007 (India); Kanade, K.G. [Department of Chemistry, Mahatma Phule College, Pimpari, Pune 411017 (India); Kale, B.B. [Nanocrystalline Materials Laboratory, Center for Materials for Electronics Technology (CMET), Pune 411008 (India)], E-mail: kbbb1@yahoo.co.in; Aiyer, R.C. [Center for Sensor Studies, Department of Physics, University of Pune, Pune 411007 (India)], E-mail: rca@physics.unipune.ernet.in

2008-10-02T23:59:59.000Z

417

Heat induced nanoforms of zinc oxide quantum dots and their characterization  

SciTech Connect

In our studies we observed heat induced phase transitions of Zinc oxide quantum dots at 60, 200, 360 and 400 Degree-Sign C, where all the transitions were irreversible except the transition at 60 Degree-Sign C which wasa reversible one. The phase transition at 60 Degree-Sign C indicated a heat induced conformational change which was supported here by studying polarizing micrographs of ZnO quantum dots thin film. The X-ray diffraction studies of the sample fired at different temperatures as indicated by the thermal analysis were performed in order to understand the changes occurred due to transitions. The study also indicated a new and simple approach to develop ZnO nanorods by just thermal decomposition of the ZnO quantum dots firing in furnace at 200 Degree-Sign C with 2h soaking. In order to have a proper insight of the structural changes we performed scanning electron microscopy. Optical characterization was done by UV-Vis and fluorescence spectrophotometer.

Dey, Anindita [Jadavpur University, Physics Department (India); Basu, Ruma [Jogamaya Devi College, Physics department (India); Das, Sukhen, E-mail: sukhendasju@gmail.com; Nandy, Papiya [Jadavpur University, Physics Department (India)

2012-02-15T23:59:59.000Z

418

Ordered Ground State Wurtzite Alloys from Zinc-Blende Parent Compounds  

DOE Green Energy (OSTI)

The ground state structures of the A{sub x}B{sub 1-x}C wurtzite (WZ) alloys with x=0.25, 0.5, and 0.75 are revealed by a ground state search using the valence-force field model and density-functional theory total-energy calculations. It is shown that the ground state WZ alloy always has a lower strain energy and formation enthalpy than the corresponding zinc-blende (ZB) alloy. Therefore, we propose that the WZ phase can be stabilized through alloying. This idea is supported by the fact that the WZ AlP{sub 0.5}Sb{sub 0.5}, AlP{sub 0.75}Sb{sub 0.25}, ZnS{sub 0.5}Te{sub 0.5}, and ZnS{sub 0.75}Te{sub 0.25} alloys in the lowest-energy structures are more stable than the corresponding ZB alloys. In this example, the alloy adopts a structure distinct from both parent phases.

Xiang, H. J.; Wei, S. H.; Chen, S.; Gong, X. G.

2009-01-01T23:59:59.000Z

419

Impact of hydrogen and oxygen defects on the lattice parameter of chemical vapor deposited zinc sulfide  

SciTech Connect

The lattice parameter of cubic chemical vapor deposited (CVD) ZnS with measured oxygen concentrations < 0.6 at.% and hydrogen impurities of < 0.015 at.% have been measured and found to vary between -0.10% and +0.09% relative to the reference lattice parameter (5.4093 ) of oxygen-free cubic ZnS as reported in the literature. Defects other than substitutional O must be invoked to explain these observed volume changes. The structure and thermodynamic stability of a wide range of native and impurity induced defects in ZnS have been determined by Ab initio calculations. Lattice contraction is caused by S-vacancies, substitutional O on S sites, Zn vacancies, H in S vacancies, peroxy defects, and dissociated water in S-vacancies. The lattice is expanded by interstitial H, H in Zn vacancies, dihydroxy defects, interstitial oxygen, Zn and [ZnHn] complexes (n=1,,4), interstitial Zn, and S2 dumbbells. Oxygen, though present, likely forms substitutional defects for sulfur resulting in lattice contraction rather than as interstitial oxygen resulting in lattice expansion. It is concluded based on measurement and calculations that excess zinc atoms either at anti-sites (i.e. Zn atoms on S-sites) or possibly as interstitial Zn are responsible for the relative increase of the lattice parameter of commercially produced CVD ZnS.

McCloy, John S.; Wolf, Walter; Wimmer, Erich; Zelinski, Brian

2013-01-09T23:59:59.000Z

420

In-Sn (Indium - Tin)  

Science Conference Proceedings (OSTI)

In-Sn crystallographic data...In-Sn crystallographic data Phase Composition, wt% Sn Pearson symbol Space group (In) 0 to 12.4 tI 2 I 4/ mmm β 12.4 to 44.8 tI 2 I 4/ mmm γ 73 to ? hP 5 P 6/ mmm (βSn) ? to 100 tI 4 I 4 1 / amd (αSn) 100 cF 8 Fd m...

Note: This page contains sample records for the topic "zinc tin selenium" from the National Library of EnergyBeta (NLEBeta).
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421

S-Sn (Sulfur - Tin)  

Science Conference Proceedings (OSTI)

S-Sn crystallographic data...29 ? ? βSn 2 S 3 29 ? ? αSn 2 S 3 29 oP 20 Pnma SnS 2 35.1 hP * hP 3 P 6 3 mc P m 1 Metastable phases SnS (thin film) 21.3 cF 8 Fm m Sn 4 S 5 25.3 ? ? Sn 3 S 4 26.4 t ** ?...

422

Effects of source and level of zinc on feedlot performance and carcass characteristics in steers  

E-Print Network (OSTI)

To determine the effects of source and level of dietary Zn on performance, carcass characteristics and tissue Zn concentration, Angus steers (n = 120; initial weight = 325 kg ?2.57) were assigned to diets containing five levels of added Zn (5, 35, 95, 215, or 445 mg/kg) from Zn methionine (ZnMet) or ZnSO4 in a 2 x 5 factorial arrangement of treatments. Total dietary Zn was 30, 60, 120, 240 and 480 mg/kg. Within treatment groups, steers were assigned to one of two kill groups (kill group I = d 77; kill group 2 = d 126). Steers were housed four to a pen and fed ad libitum a 90% concentrate diet of primarily corn and cottonseed meal by electronic Calen gate feeders. At the time of slaughter, the right front metacarpal, a 150 g liver sample and the right kidney were obtained from each steer. Carcass cooler traits were determined 48 h post slaughter and soft tissue from 9-1 0-1 1 rib section was analyzed for water, protein and lipid content. Statistical models for carcass characteristics included carcass weight as a covariate. Steers fed ZnSO4 gained faster (P . I 0) in ADG or feed efficiency due to level of Zn in the diet. Neither source nor level of Zn affected (P > . I 0) carcass characteristics. The composition of the 9-1 0-1 1 rib section was not affected (P > . I 0) due to dietary treatment. Zinc and Cu concentrations in the liver, kidney and bone were not affected (P > . 1 0) by source of Zn. Level of Zn, however, did affect tissue concentrations of Zn and Cu. Liver Zn was higher (P . I 0) by level of dietary Zn.

Nunnery, Greg Alan

1998-01-01T23:59:59.000Z

423

Internal Electric Field Investigations of a Cadmium Zinc Telluride Detector Using Synchrotron X-ray Mapping and Pockels Effect Measurements  

Science Conference Proceedings (OSTI)

Cadmium zinc telluride (CZT) has remained a major focus of research due to its promising application as a room-temperature nuclear radiation detector material. Among the several parameters that substantially affect the detectors' performance, an important one is the distribution of the internal electric field. Brookhaven National Laboratory (BNL) employed synchrotron x-ray microscale mapping and measurements of the Pockels effect to investigate the distribution of the internal electric field in a CZT strip detector. Direct evidence that dislocations can distort the internal electric field of the detector was obtained. Furthermore, it was found that 'star' defects in the CZT crystal, possibly ascribed to dislocation loop punching, cause charge trapping.

Yang, G.; Bolotnikov, A; Camarda, G; Cui, Y; Hossain, A; Yao, H; James, R

2009-01-01T23:59:59.000Z

424

ExpandplusCrystal Structures of Poly(ADP-ribose) Polymerase-1 (PARP-1) Zinc Fingers Bound to DNA  

Science Conference Proceedings (OSTI)

Poly(ADP-ribose) polymerase-1 (PARP-1) has two homologous zinc finger domains, Zn1 and Zn2, that bind to a variety of DNA structures to stimulate poly(ADP-ribose) synthesis activity and to mediate PARP-1 interaction with chromatin. The structural basis for interaction with DNA is unknown, which limits our understanding of PARP-1 regulation and involvement in DNA repair and transcription. Here, we have determined crystal structures for the individual Zn1 and Zn2 domains in complex with a DNA double strand break, providing the first views of PARP-1 zinc fingers bound to DNA. The Zn1-DNA and Zn2-DNA structures establish a novel, bipartite mode of sequence-independent DNA interaction that engages a continuous region of the phosphodiester backbone and the hydrophobic faces of exposed nucleotide bases. Biochemical and cell biological analysis indicate that the Zn1 and Zn2 domains perform distinct functions. The Zn2 domain exhibits high binding affinity to DNA compared with the Zn1 domain. However, the Zn1 domain is essential for DNA-dependent PARP-1 activity in vitro and in vivo, whereas the Zn2 domain is not strictly required. Structural differences between the Zn1-DNA and Zn2-DNA complexes, combined with mutational and structural analysis, indicate that a specialized region of the Zn1 domain is re-configured through the hydrophobic interaction with exposed nucleotide bases to initiate PARP-1 activation.

M Langelier; J Planck; S Roy; J Pascal

2011-12-31T23:59:59.000Z

425

Flow-Assisted Alkaline Battery: Low-Cost Grid-Scale Electrical Storage using a Flow-Assisted Rechargeable Zinc-Manganese Dioxide Battery  

SciTech Connect

GRIDS Project: Traditional consumer-grade disposable batteries are made of Zinc and Manganese, 2 inexpensive, abundant, and non-toxic metals. But these disposable batteries can only be used once. If they are recharged, the Zinc in the battery develops filaments called dendrites that grow haphazardly and disrupt battery performance, while the Manganese quickly loses its ability to store energy. CUNY Energy Institute is working to tame dendrite formation and to enhance the lifetime of Manganese in order to create a long-lasting, fully rechargeable battery for grid-scale energy storage. CUNY Energy Institute is also working to reduce dendrite formation by pumping fluid through the battery, enabling researchers to fix the dendrites as theyre forming. The team has already tested its Zinc battery through 3,000 recharge cycles (and counting). CUNY Energy Institute aims to demonstrate a better cycle life than lithium-ion batteries, which can be up to 20 times more expensive than Zinc-based batteries.

2010-09-15T23:59:59.000Z

426

Enhanced durability of high-temperature desulfurization sorbents for moving-bed applications. Option 2 Program: Development and testing of zinc titanate sorbents  

SciTech Connect

One of the most advantageous configurations of the integrated gasification combined cycle (IGCC) power system is coupling it with a hot gas cleanup for the more efficient production of electric power in an environmentally acceptable manner. In conventional gasification cleanup systems, closely heat exchangers are necessary to cool down the fuel gases for cleaning, sometimes as low as 200--300{degree}F, and to reheat the gases prior to injection into the turbine. The result is significant losses in efficiency for the overall power cycle. High-temperature coal gas cleanup in the IGCC system can be operated near 1000{degree}F or higher, i.e., at conditions compatible with the gasifier and turbine components, resulting is a more efficient overall system. GE is developing a moving-bed, high-temperature desulfurization system for IGCC power systems in which mixed-metal oxides are currently being used as desulfurization sorbents. The objective of this contract is to identify and test fabrication methods and sorbent chemical compositions that enhance the long-term chemical reactivity and mechanical durability of zinc ferrite and other novel sorbents for moving-bed, high-temperature desulfurization of coal-derived gases. Zinc ferrite was studied under the base program of this contract. In the next phase of this program novel sorbents, particularly zinc titanate-based sorbents, are being studied under the remaining optional programs. This topical report summarizes only the work performed under the Option 2 program. In the course of carrying out the program, more than 25 zinc titanate formulations have been prepared and characterized to identify formulations exhibiting enhanced properties over the baseline zinc titanate formulation selected by the US Department of Energy.

Ayala, R.E.

1993-04-01T23:59:59.000Z

427

Processing and Characterization of P-Type Doped Zinc Oxide Thin Films  

E-Print Network (OSTI)

Applications of zinc oxide (ZnO) for optoelectronic devices, including light emitting diodes, semiconductor lasers, and solar cells have not yet been realized due to the lack of high-quality p-type ZnO. In the research presented herein, pulsed laser deposition is employed to grow Ag-doped ZnO thin films, which are characterized in an attempt to understand the ability of Ag to act as a p-type dopant. By correlating the effects of the substrate temperature, oxygen pressure, and laser energy on the electrical and microstructural properties of Ag-doped ZnO films grown on c-cut sapphire substrates, p-type conductivity is achieved under elevated substrate temperatures. Characteristic stacking fault features have been continuously observed by transmission electron microscopy in all of the p-type films. Photoluminescence studies on n-type and p-type Ag-doped ZnO thin films demonstrate the role of stacking faults in determining the conductivity of the films. Exciton emission attributed to basal plane stacking faults suggests that the acceptor impurities are localized nearby the stacking faults in the n-type films. The photoluminescence investigation provides a correlation between microstructural characteristics and electrical properties of Ag- doped ZnO thin films; a link that enables further understanding of the doping nature of Ag impurities in ZnO. Under optimized deposition conditions, various substrates are investigated as potential candidates for ZnO thin film growth, including r -cut sapphire, quartz, and amorphous glass. Electrical results indicated that despite narrow conditions for obtaining p-type conductivity at a given substrate temperature, flexibility in substrate choice enables improved electrical properties. In parallel, N+-ion implantation at elevated temperatures is explored as an alternative approach to achieve p-type ZnO. The ion implantation fluence and temperature have been optimized to achieve p-type conductivity. Transmission electron microscopy reveals that characteristic stacking fault features are present throughout the p-type films, however in n-type N-doped films high-density defect clusters are observed. These results suggest that the temperature under which ion implantation is performed plays a critical role in determining the amount of dynamic defect re- combination that can take place, as well as defect cluster formation processes. Ion implantation at elevated temperatures is shown to be an effective method to introduce increased concentrations of p-type N dopants while reducing the amount of stable post-implantation disorder. Finally, the fabrication and properties of p-type Ag-doped ZnO/n-type ZnO and p-type N-doped ZnO/n-type ZnO thin film junctions were reported. For the N-doped sample, a rectifying behavior was observed in the I-V curve, consistent with N-doped ZnO being p-type and forming a p-n junction. The turn-on voltage of the device was ?2.3 V under forward bias. The Ag-doped samples did not result in rectifying behavior as a result of conversion of the p-type layer to n-type behavior under the n- type layer deposition conditions. The systematic studies in this dissertation provide possible routes to grow p-type Ag-doped ZnO films and in-situ thermal activation of N-implanted dopant ions, to overcome the growth temperature limits, and to push one step closer to the future integration of ZnO-based devices.

Myers, Michelle Anne

2013-05-01T23:59:59.000Z

428

Structural Properties Studies of Zinc Oxide Thin Film Grown on Silicon Carbide by Means of X-ray Diffraction Technique  

Science Conference Proceedings (OSTI)

In this work, the structural properties of the zinc oxide (ZnO) thin film on silicon carbide (6H-SiC) grown by radio frequency sputtering technique are investigated thoroughly by means of X-ray diffraction (XRD) technique. Both conventional XRD phase analysis and rocking curve measurements are carried out in order to determine the crystalline structure and the crystalline quality of the ZnO sample. From the phase analysis, intense peaks correspond to ZnO(002), iC(006) and their multiple reflections, i.e. ZnO(004) and SiC(0012) are observed. This result suggests that the ZnO thin film is in wurzite structure. Through the simulation of XRD rocking curve of the ZnO(002) peak, the lattice mismatch of 5.49% is obtained.

Ching, C. G.; Ng, S. S.; Hassan, Z.; Hassan, H. Abu; Al-Hardan, N. H.; Abdullah, M. J. [Nano-optoelectronics Research and Technology Laboratory, School of Physics, Universiti Sains Malaysia, 11800, Penang (Malaysia)

2011-03-30T23:59:59.000Z

429

Observation and simulation of hard x ray photoelectron diffraction to determine polarity of polycrystalline zinc oxide films with rotation domains  

SciTech Connect

X ray photoelectron diffraction (XPD) patterns of polar zinc oxide (ZnO) surfaces were investigated experimentally using hard x rays and monochromatized Cr K{alpha} radiation and theoretically using a cluster model approach and a dynamical Bloch wave approach. We focused on photoelectrons emitted from the Zn 2p{sub 3/2} and O 1s orbitals in the analysis. The obtained XPD patterns for the (0001) and (0001) surfaces of a ZnO single crystal were distinct for a given emitter and polarity. Polarity determination of c-axis-textured polycrystalline ZnO thin films was also achieved with the concept of XPD, even though the in-plane orientation of the columnar ZnO grains was random.

Williams, Jesse R.; Adachi, Yutaka; Ohashi, Naoki [International Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); NIMS Saint-Gobain Research Center of Excellence for Advanced Materials, NIMS, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan); Pis, Igor [Synchrotron X-ray Station at SPring-8, NIMS, SPring-8, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198 (Japan); Department of Surface and Plasma Science, Faculty of Mathematics and Physics, Charles University, V Holesovickach 2, Prague 8 18000 (Czech Republic); Kobata, Masaaki [Synchrotron X-ray Station at SPring-8, NIMS, SPring-8, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198 (Japan); Winkelmann, Aimo [Max-Planck-Institut fuer Mikrostrukturphysik, Weinberg 2, D-06120 Halle (Saale) (Germany); Matsushita, Tomohiro [Japan Synchrotron Radiation Research Institute (JASRI), SPring-8, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5148 (Japan); Kobayashi, Keisuke [Synchrotron X-ray Station at SPring-8, NIMS, SPring-8, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198 (Japan); Hiroshima Synchrotron Radiation Center, Hiroshima University, 2-313 Kagamiyama, Higashi-Hiroshima, Hiroshima 739-0046 (Japan)

2012-02-01T23:59:59.000Z

430

Ductile polyelectrolyte macromolecule-complexed zinc phosphate conversion crystal pre-coatings and topcoatings embodying a laminate  

DOE Patents (OSTI)

This invention relates to a precoat, laminate, and method for ductile coatings on steel and non-ferrous metals which comprises applying a zinc phosphating coating solution modified by a solid polyelectrolyte selected from polyacrylic acid (PAA), polymethacrylic acid (PMA), polyitaconic acid (PIA), and poly-L-glutamic acid. The contacting of the resin with the phosphating solution is made for a period of up to 20 hours at about 80.degree. C. The polyelectrolyte or the precoat is present in about 0.5-5.0% by weight of the total precoat composition and after application, the precoat base is dried for up to 5 hours at about 150.degree. C. to desiccate. Also, a laminate may be formed where polyurethane (PU) is applied as an elastomeric topcoating or polyfuran resin is applied as a glassy topcoating. It has been found that the use of PAA at a molecular weight of about 2.times.10.sup.5 gave improved ductility modulus effect.

Sugama, Toshifumi (Mastic Beach, NY); Kukacka, Lawrence E. (Port Jefferson, NY); Carciello, Neal R. (Bellport, NY)

1987-01-01T23:59:59.000Z

431

Ductile polyelectrolyte macromolecule-complexed zinc phosphate conversion crystal pre-coatings and topcoatings embodying a laminate  

DOE Patents (OSTI)

This invention relates to a precoat, laminate, and method for ductile coatings on steel and non-ferrous metals which comprises applying a zinc phosphating coating solution modified by a solid polyelectrolyte selected from polyacrylic acid (PAA), polymethacrylic acid (PMA), polyitaconic acid (PIA), and poly-L-glutamic acid. The contacting of the resin with the phosphating solution is made for a period of up to 20 hours at about 80 C. The polyelectrolyte or the precoat is present in about 0.5--5.0% by weight of the total precoat composition and after application, the precoat base is dried for up to 5 hours at about 150 C to desiccate. Also, a laminate may be formed where polyurethane (PU) is applied as an elastomeric topcoating or polyfuran resin is applied as a glassy topcoating. It has been found that the use of PAA at a molecular weight of about 2 [times] 10[sup 5] gave improved ductility modulus effect. 5 figs.

Sugama, T.; Kukacka, L.E.; Carciello, N.R.

1987-04-21T23:59:59.000Z

432

Opto-electrical characterization and X-ray mapping of large-volume cadmium zinc telluride radiation detectors  

Science Conference Proceedings (OSTI)

Large-volume cadmium zinc telluride (CZT) radiation detectors would greatly improve radiation detection capabilities and, therefore, attract extensive scientific and commercial interests. CZT crystals with volumes as large as hundreds of centimeters can be achieved today due to improvements in the crystal growth technology. However, the poor performance of large-volume CZT detectors is still a challenging problem affecting the commercialization of CZT detectors and imaging arrays. We have employed Pockels effect measurements and synchrotron X-ray mapping techniques to investigate the performance-limiting factors for large-volume CZT detectors. Experimental results with the above characterization methods reveal the non-uniform distribution of internal electric field of large-volume CZT detectors, which help us to better understand the responsible mechanism for the insufficient carrier collection in large-volume CZT detectors.

Yang, G.; Bolotnikov, A.E.; Camarda, G.S.; Cui, Y.; Hossain, A.; Yao, H.W.; Kim, K.; and James, R.B.

2009-04-13T23:59:59.000Z

433

It's Elemental - The Periodic Table of Elements - Elements Listed by Atomic  

NLE Websites -- All DOE Office Websites (Extended Search)

Atomic Number Atomic Number 1 Hydrogen H 2 Helium He 3 Lithium Li 4 Beryllium Be 5 Boron B 6 Carbon C 7 Nitrogen N 8 Oxygen O 9 Fluorine F 10 Neon Ne 11 Sodium Na 12 Magnesium Mg 13 Aluminum Al 14 Silicon Si 15 Phosphorus P 16 Sulfur S 17 Chlorine Cl 18 Argon Ar 19 Potassium K 20 Calcium Ca 21 Scandium Sc 22 Titanium Ti 23 Vanadium V 24 Chromium Cr 25 Manganese Mn 26 Iron Fe 27 Cobalt Co 28 Nickel Ni 29 Copper Cu 30 Zinc Zn 31 Gallium Ga 32 Germanium Ge 33 Arsenic As 34 Selenium Se 35 Bromine Br 36 Krypton Kr 37 Rubidium Rb 38 Strontium Sr 39 Yttrium Y 40 Zirconium Zr 41 Niobium Nb 42 Molybdenum Mo 43 Technetium Tc 44 Ruthenium Ru 45 Rhodium Rh 46 Palladium Pd 47 Silver Ag 48 Cadmium Cd 49 Indium In 50 Tin Sn 51 Antimony Sb 52 Tellurium Te 53 Iodine I 54 Xenon Xe 55 Cesium Cs 56 Barium Ba 57 Lanthanum La 58 Cerium Ce

434

Uranium hydrogeochemical and stream sediment reconnaissance data release for the Elk City NTMS Quadrangle, Idaho/Montana, including concentrations of forty-five additional elements  

Science Conference Proceedings (OSTI)

Totals of 1580 water and 1720 sediment samples were collected from 1754 locations in the quadrangle. Elemental concentration, field measurement, weather, geologic, and geographic data for each sample location are listed for waters in Appendix I-A and for sediments in Appendix I-B. Uranium/thorium ratios for sediment samples are also included in Appendix I-B. All elemental analyses were performed at the LASL. Water samples were initially analyzed for uranium by fluorometry. All water samples containing more than 40 parts per billion (ppB) uranium were reanalyzed by delayed-neutron counting (DNC). A supplemental report containing the multielement analyses of water samples will be open filed in the near future. Sediments were analyzed for uranium and thorium as well as aluminum, antimony, arsenic, barium, beryllium, bismuth, cadmium, calcium, cerium, cesium, chlorine, chromium, cobalt, copper, dysprosium, europium, gold, hafnium, iron, lanthanum, lead, lithium, lutetium, magnesium, manganese, nickel, niobium, potassium, rubidium, samarium, selenium, scandium, silver, sodium, strontium, tantalum, terbium, tin, titanium, tungsten, vanadium, ytterbium, zinc, and zirconium. Basic statistics for 40 of these elements are presented. All sediments were analyzed for uranium by delayed-neutron counting. Other elemental concentrations in sediments were determined by neutron-activation analysis for 30 elements, by x-ray fluorescence for 12 elements, and by arc-source emission spectrography for 2 elements. Analytical results for sediments are reported as parts per million.

Broxton, D.E.; Beyth, M.

1980-07-01T23:59:59.000Z

435

Environmental assessment of the HYGAS process. Volume III. Interim report on HYGAS environmental characterization: manual of methods for characterization of HYGAS pilot plant solids, liquids, and gases  

Science Conference Proceedings (OSTI)

The US Department of Energy (DOE) has commissioned the HYGAS environmental assessment program to characterize various solid, liquid, and gaseous streams in the HYGAS pilot plant. The purpose of this manual is to describe the various analytical techniques that have been used to analyze pilot plant streams for environmental species. Many of the techniques have been recommended by the US Environmental Protection Agency or otherwise have been published in ASTM Standards, Standard Methods, and assorted vendor equipment manuals. Complete references have been provided in the text. Analytical techniques for the determination of the following are included: ammonia-nitrogen; biochemical oxygen demand; chemical oxygen demand; chlorides; total cyanide; grease and oil; total organic carbon; phenol; total, suspended, and dissolved solids; sulfide; total sulfur; thiocyanate; total oxygen demand; hydrocyanic acid in gas; hydrogen sulfide in gas; gaseous hydrocarbons; organic compounds in HYGAS light oil and aqueous samples; proximate analysis of coal; ultimate analysis of coal; calorific value; screen analysis; bulk density; and trace elements in coal (arsenic, antimony, selenium, tellurium, barium, beryllium chromium, copper, iron, lithium, manganese, nickel, tin, vanadium, zinc, boron, cadmium, lead, thallium, chlorine, cobalt, fluorine, mercury, and molybdenum). (DMC)

Karst, R.H.; Passaniti, J.L.; Metcalf, T.C.; Salazar, E.V.; Pau, J.C.

1980-11-01T23:59:59.000Z

436

Attempted use of zinc in vivo to protect against nitrogen mustard toxicity in tumor-free and in L1210 leukemia-bearing B6D2F sub 1 mice  

Science Conference Proceedings (OSTI)

The use of alkylating agents in treating cancer is limited by their toxicity to both normal and tumor tissue. Early in vitro and in vivo studies had indicated that zinc could be effective in mitigating this toxicity to normal tissue. The present studies were done to determine the capability of zinc to induce in living tissue a protective response to an alkylating agent, without also contributing to mortality. Tumor-free and leukemia-bearing B6D2F{sub 1} mice were treated with zinc before administration of the alkylating agent nitrogen mustard (HN{sub 2}). Protocols for administration route and frequency and chemical formulation of the zinc were varied. The effect of a phytate-free diet was studied. Two parameters were used to judge the effectiveness of zinc in protecting animals from the toxicity of HN{sub 2}: the number of tumor-free mice who survived and any increase in the median life span of the tumor-bearing mice. Zinc provided a limited degree of protection against HN{sub 2} toxicity in tumor-free mice, but in tumor-bearing animals, the protective response elicited with the protocols examined was too small to provide a significant therapeutic benefit. 6 refs., 3 figs., 2 tabs.

Shackelford, M.E.; Tobey, R.A.

1989-12-01T23:59:59.000Z

437

Initial test results from the RedFlow 5 kW, 10 kWh zinc-bromide module, phase 1.  

DOE Green Energy (OSTI)

In this paper the performance results of the RedFlow zinc-bromide module (ZBM) Gen 2.0 are reported for Phase 1 of testing, which includes initial characterization of the module. This included physical measurement, efficiency as a function of charge and discharge rates, efficiency as a function of maximum charge capacity, duration of maximum power supplied, and limited cycling with skipped strip cycles. The goal of this first phase of testing was to verify manufacturer specifications of the zinc-bromide flow battery. Initial characterization tests have shown that the ZBM meets the manufacturer's specifications. Further testing, including testing as a function of temperature and life cycle testing, will be carried out during Phase 2 of the testing, and these results will be issued in the final report, after Phase 2 testing has concluded.

Ferreira, Summer Rhodes; Rose, David Martin

2012-02-01T23:59:59.000Z

438

K4, Improved Microstructure and Ohmic Contact of Nb Electrode on ...  

Science Conference Proceedings (OSTI)

Obtained results showed the formation of niobium carbide and niobium silicide ..... W1, Shape Transformation of Nanoporous GaN by Annealing: Buried Cavities ... X9, Solution-Processed Zirconium Oxide and Integration with Zinc-Tin Oxide...

439

Electronics - Programmaster.org  

Science Conference Proceedings (OSTI)

Mar 13, 2012 ... Different leaching acid reagents (hydrochloric acid, nitric acid and ... of both nitric acid and aqua regia are capable of dissolving most of the metals content of PWBs. ... base metals such as copper, lead, tin, zinc and aluminum.

440

Technical Categories/Technical Contacts by Tables  

Science Conference Proceedings (OSTI)

... 102.14 Nickel Oxides (powder form). John Sieber, 102.15 Tin Base Alloys (Chip form) 102.16 Titanium Base Alloys (chip and disk forms) 102.17 Zinc ...

2011-12-30T23:59:59.000Z

Note: This page contains sample records for the topic "zinc tin selenium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Mason-0124123 - Argonne National Laboratories, Materials Sicence...  

NLE Websites -- All DOE Office Websites (Extended Search)

measured work function. Materials to be considered in the talk include pure and tin-doped indium oxide (In2O3, ITO), pure and Al-doped zinc oxide (ZnO, AZO), pure and...

442

Properties of In-Doped ZnO Films Grown by Metalorganic Chemical Vapor Deposition on GaN(0001) Templates  

E-Print Network (OSTI)

TCO is amor- phous indium tin oxide (ITO), most commonlythe properties of indium-doped zinc oxide layers grown byoxide, doping, n-type, MOCVD, metalorganic chemical vapor deposition, ZnO: In, indium

Ben-Yaacov, Tammy; Ive, Tommy; Walle, Chris G.; Mishra, Umesh K.; Speck, James S.; Denbaars, Steven P.

2010-01-01T23:59:59.000Z

443

c o l e P o l y t e c h n i q u e Benedict O'Donnell  

E-Print Network (OSTI)

silicon c-Si Crystalline Silicon CVD Chemical Vapor Deposition FF Fill factor % ITO Indium-Tin-Oxide JSC .......................................................................................... 35 4. Thin layers of tin and ITO over stable zinc oxide of energy imports led to increased funding in renewable energy. Whereas research had previously focused

444

Adv. Sci. Technol. (Faenza, Italy) 33, 1037-1050 (2003) TECHNOLOGICAL CHALLENGES FOR TRANSPARENT CONDUCTORS  

E-Print Network (OSTI)

these limiting properties are also discussed. 1. INTRODUCTION A few materials, mostly oxides of tin, indium and to etch TCs. Zinc oxide is the easiest material to etch, tin oxide is the most difficult, and indium oxide in part by the US National Renewable Energy Laboratory. #12;2 2. OPTICAL AND ELECTRONIC PROPERTIES 2

Gordon, Roy

445

Influence of the film properties on the plasma etching dynamics of rf-sputtered indium zinc oxide layers  

Science Conference Proceedings (OSTI)

The etching characteristics of indium zinc oxide (IZO) films were investigated using a high-density plasma in Ar, Ar/Cl{sub 2}, and Ar/CH{sub 4}/H{sub 2} chemistries. The IZO layers were deposited by means of rf magnetron sputtering, in which the target composition and growth temperature were varied to selectively tune the film properties. X-ray diffraction, elastic recoil detection, and Rutherford backscattering spectroscopy were used to determine the crystallization quality, atomic density, and composition of the as-deposited IZO films. As the In/(In+Zn) composition ratio in the IZO layer increases, the etch yield in Ar and Ar/Cl{sub 2} plasmas remains fairly constant, indicating that the etching dynamic is essentially independent of the film properties. In sharp contrast, a strong increase of the IZO etch yield with the In/(In+Zn) fraction is observed in Ar/CH{sub 4}/H{sub 2} plasma due to the preferential desorption of the group-III etch products. By comparing these experimental data to the predictions of a simple rate model accounting for preferential desorption effects, it is concluded that the balance between etching and polymer deposition in the Ar/CH{sub 4}/H{sub 2} plasma plays an important role in the evolution of the IZO etch rate with the In concentration fraction.

Stafford, L.; Lim, W. T.; Pearton, S. J.; Chicoine, M.; Gujrathi, S.; Schiettekatte, F.; Park, Jae-Soung; Song, Ju-Il; Heo, Young-Woo; Lee, Joon-Hyung; Kim, Jeong-Joo; Kravchenko, I. I. [Department of Materials Science and Engineering, University of Florida, Gainesville, Florida 32611 (United States); Departement de Physique, Universite de Montreal, Montreal, Quebec H3C 3J7 (Canada); Department of Inorganic Materials Engineering, Kyungpook National University, Daegu 702-701 (Korea, Republic of); Department of Physics, University of Florida, Gainesville, Florida 32611 (United States)

2007-07-15T23:59:59.000Z

446

Conducting and Optical Properties of Transparent Conducting Indium-Doped Zinc Oxide Thin Films by Sol-Gel Processing  

Science Conference Proceedings (OSTI)

Transparent conducting oxides were successfully prepared from mixed zinc nitrate hexahydrate and indium nitrate hydrate solutions in ethylene glycol using sol-gel technique. The In content in the film was varied (0, 2, 10, 20, 40, 75 and 100 atom %). Films were prepared by spin coating of the liquid precursors followed by thermal decomposition at 400 C after each layer. According to X-ray diffraction (XRD) measurements, the pure ZnO and pure InO films (0 and at 100 % In) were crystalline as-deposited. The crystallinity was suppressed in mixed compositions such that the films with compositions between 10 and 75 at % were amorphous. All the films were transparent with the transmission cut-off frequency near 400 nm, which is characteristic of TCO materials. All as-deposited films were conductive with 0 and 100 atom % In having the lowest resistivities. The resistivity of all compositions were improved by post-deposition reducing anneal in pure Ar at 300 C. The lowest resistivity of 0.2 ?cm was obtained for the pure ZnO after Ar anneal. It was two-orders of magnitude higher than reported in the literature for the In-doped ZnO, which was attributed to the low processing temperature. The resistivities of as-deposited and annealed in Ar films were increased by consequent air anneal at 300 C.

Huang, S.; Kaydanova, T.; Miedaner, A.; Ginley, D.S.

2004-01-01T23:59:59.000Z

447

The darkening of zinc yellow: XANES speciation of chromium in artist;s paints after light and chemical exposures  

Science Conference Proceedings (OSTI)

The color darkening of selected brushstrokes of the masterpiece A Sunday on La Grande Jatte - 1884 (by Georges Seurat) has been attributed to the alteration of the chromate pigment zinc yellow. The pigment originally displays a bright greenish-yellow color but may undergo, after aging, darkening to a dull, ocher tone. We used XANES to probe the oxidation state of Cr on paint reconstructions, and show that color changes are associated with the reduction of Cr(VI) to Cr(III). Paint mixtures containing the pigment and linseed oil to mimic mixtures used in La Grande Jatte were subjected to artificial aging in the presence of light, SO{sub 2}, and variable air humidity - 50 and 90% relative humidity. High relative humidity led to the largest degree of Cr(VI) reduction whereas low relative humidity promoted light-induced alterations. These results are corroborated by visible reflectance measurements on the same laboratory samples and contribute to a better understanding of the chemical reactivity of chromate pigments, which are present in many historical works of art.

Zanella, Luciana; Casadio, Francesca; Gray, Kimberly A.; Warta, Richard; Ma, Qing; Gaillard, Jean-Franois

2012-03-14T23:59:59.000Z

448

Ductile polyelectrolyte macromolecule-complexed zinc phosphate conversion crystal pre-coatings and topcoatings embodying a laminate  

DOE Patents (OSTI)

This invention relates to a precoat, laminate, and method for ductile coatings on steel and non-ferrous metals which comprises applying a zinc phosphating coating solution modified by a solid polyelectrolyte selected from polyacrylic acid (PAA), polymethacrylic acid (PMA), polyitaconic acid (PIA), and poly-L-glutamic acid. The contacting of the resin with the phosphating solution is made for a period of up to 20 hours at about 80/sup 0/C. The polyelectrolyte or the precoat is present in about 0.5 to 5.0% by weight of the total precoat composition and after application, the precoat base is dried for up to 5 hours at about 150/sup 0/C to desiccate. Also, a laminate may be formed where polyurethane (PU) is applied as an elastomeric topcoating or polyfuran resin is applied as a glassy topcoating. It has been found that the use of PAA at a molecular weight of about 2 x 10/sup 5/ gave improved ductility modulus effect.

Sugama, Toshifumi; Kukacka, L.E.; Carciello, N.R.

1985-11-05T23:59:59.000Z

449

Optimization of transparent and reflecting electrodes for amorphous silicon solar cells. Annual subcontract report, April 1, 1994--March 31, 1995  

DOE Green Energy (OSTI)

Transparent and reflecting electrodes are important parts of the structure of amorphous silicon solar cells. We report improved methods for depositing zinc oxide, deposition of tin nitride as a potential reflection-enhancing diffusion barrier between the a-Si and back metal electrodes. Highly conductive and transparent fluorine-doped zinc oxide was successfully produced on small areas by atmospheric pressure CVD from a less hazardous zinc precursor, zinc acetylacetonate. The optical properties measured for tin nitride showed that the back-reflection would be decreased if tin nitride were used instead of zinc oxide as a barrier layer over silver on aluminum. Niobium-doped titanium dioxide was produced with high enough electrical conductivity so that normal voltages and fill factors were obtained for a-Si cells made on it.

Gordon, R.G. [Harvard Univ., Cambridge, MA (United States)

1995-10-01T23:59:59.000Z

450

How Spineless Prickly Pear Cactus Utilize Selenium  

NLE Websites -- All DOE Office Websites (Extended Search)

phytoremediation of inorganic Se pollutants. Researchers from the U.S. Department of Agriculture used ALS Beamline 10.3.2 to study the chemical forms and distribution of Se in the...

451

Demonstration of zinc/air fuel battery to enhance the range and mission of fleet electric vehicles: Preliminary results in the refueling of a multicell module  

DOE Green Energy (OSTI)

We report progress in an effort to develop and demonstrate a refuelable zinc/air battery for fleet electric vehicle applications. A refuelable module consisting of twelve bipolar cells with internal flow system has been refueled at rates of nearly 4 cells per minute refueling time of 10 minutes for a 15 kW, 55 kWh battery. The module is refueled by entrainment of 0.5-mm particles in rapidly flowing electrolyte, which delivers the particles into hoppers above each cell in a parallel-flow hydraulic circuit. The concept of user-recovery is presented as an alternative to centralized service infrastructure during market entry.

Cooper, J.F.; Fleming, D.; Keene, L.; Maimoni, A.; Peterman, K.; Koopman, R.

1994-08-08T23:59:59.000Z

452

Solderability study of 63Sn-37Pb on zinc-plated and cadmium-plated stainless steel for the MC4636 lightning arrestor connector.  

Science Conference Proceedings (OSTI)

Cadmium plating on metal surfaces is commonly used for corrosion protection and to achieve good solderability on the 304L stainless steel shell of the MC4636 lightning arrestor connector (LAC) for the W76-1 system. This study examined the use of zinc as a potential substitute for the cadmium protective surface finish. Tests were performed with an R and RMA flux and test temperatures of 230 C, 245 C, and 260 C. Contact angle, {theta}{sub c}, served as the generalized solderability metric. The wetting rate and wetting time parameters were also collected. The solderability ({theta}{sub c}) of the Erie Plating Cd/Ni coatings was better than that of similar Amphenol coatings. Although the {theta}{sub c} data indicated that both Cd/Ni platings would provide adequate solderability, the wetting rate and wetting time data showed the Amphenol coatings to have better performance. The Zn/Ni coatings exhibited non-wetting under all flux and temperature conditions. Based on the results of these tests, it has been demonstrated that zinc plating is not a viable alternate to cadmium plating for the LAC connectors.

Lopez, Edwin Paul; Vianco, Paul Thomas; Rejent, Jerome Andrew; Martin, Joseph J.

2004-06-01T23:59:59.000Z

453

Determination of Zinc-Based Additives in Lubricating Oils by Flow-Injection Analysis with Flame-AAS Detection Exploiting Injection with a Computer-Controlled Syringe  

E-Print Network (OSTI)

A flow-injection system is proposed for the determination of metal-based additives in lubricating oils. The system, operating under computer control uses a motorised syringe for measuring and injecting the oil sample (200 L) in a kerosene stream, where it is dispersed by means of a packed mixing reactor and carried to an atomic absorption spectrometer which is used as detector. Zinc was used as model analyte. Two different systems were evaluated, one for low concentrations (range 010 ppm) and the second capable of providing higher dilution rates for high concentrations (range 0.02%0.2 % w/w). The sampling frequency was about 30 samples/h. Calibration curves fitted a second-degree regression model (r 2 = 0.996). Commercial samples with high and low zinc levels were analysed by the proposed method and the results were compared with those obtained with the standard ASTM method. The t test for mean values showed no significant differences at the 95 % confidence level. Precision (RSD%) was better than 5 % (2 % typical) for the high concentrations system. The carryover between successive injections was found to be negligible. 1.

Gustavo Pignalosa; Moiss Knochen; Noel Cabrera

2004-01-01T23:59:59.000Z

454

Effects of in situ Remediation on the Speciation and Bioavailability of Zinc in a Smelter Contaminated Soil  

Science Conference Proceedings (OSTI)

We report results from an extensive study on the speciation of zinc (Zn) and its relation to the mobility and bioavailablity of this element in a smelter contaminated soil and an in situ remediated area of this soil 12 yr after the application of cyclonic ash and compost. Emphasis was placed on the role of neoformed precipitates in controlling Zn speciation, mobility and bioavailability under different environmental conditions. Twelve years after remediation, the pH of the treated and non-treated soil differed by only 0.5 pH unit. Using state-of-the-art electron and X-ray microscopies in combination with micro-focused extended X-ray absorption fine structure ({micro}-EXAFS) spectroscopy, no major differences in Zn speciation were found between samples of the treated and non-treated soil. In both soils, 30% to 50% of Zn was present in smelter related minerals (willemite, hemimorphite or gahnite), while 50% to 70% of Zn was incorporated into newly formed Zn precipitates. Contrary to the non-treated soil, the treated soil did not contain gahnite or sphalerite; it is possible that these minerals were dissolved under the higher pH conditions at the time of treatment. Desorption experiments, using a stirred flow technique with a 0.1 mol/L CaCl{sub 2} (pH 6.5) and a HNO{sub 3} (pH 4.0) solution were employed to determine the exchangeable Zn fraction and the Zn fraction which will be mobilized under more extreme weathering conditions, respectively. No significant differences were found in desorption behavior between the treated vs. non-treated soil. Bioavailability tests,