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Note: This page contains sample records for the topic "zinc sulfide aggregation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Extracellular Proteins Promote Zinc Sulfide Aggregation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Extracellular Proteins Promote Zinc Sulfide Aggregation Print Extracellular Proteins Promote Zinc Sulfide Aggregation Print Researchers from the ALS, Berkeley Lab's National Center for Electron Microscopy (NCEM), and Lawrence Livermore National Laboratory analyzed biofilm samples rich in zinc sulfide and dominated by sulfate-reducing bacteria, which were collected from lead-zinc mine waters. The researchers were curious about the relationship of the organic material and metals, particularly how organics affect mobility, and its potential for bioremediation. It is known that some organics promote aggregation. Amine-bearing molecules, for example, can organize sulfide nanoparticles into semiconductor nanowires. The research team used a series of imaging techniques and detectors to analyze aggregates of biogenic zinc sulfide nanocrystals in the biofilms. Their examination yielded excellent results and some surprises. They were able to prove that natural organic matter promotes dense aggregation of the zinc sulfide nanocrystals into much larger spheroids and that the organic matter is preserved in nanometer-scale pores in the spheroids. What was not expected was the presence of proteins in the spheroids, making them a key component in aggregation and an example of extracellular biomineralization.

2

Extracellular Proteins Promote Zinc Sulfide Aggregation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Extracellular Proteins Promote Extracellular Proteins Promote Zinc Sulfide Aggregation Extracellular Proteins Promote Zinc Sulfide Aggregation Print Wednesday, 26 September 2007 00:00 Researchers from the ALS, Berkeley Lab's National Center for Electron Microscopy (NCEM), and Lawrence Livermore National Laboratory analyzed biofilm samples rich in zinc sulfide and dominated by sulfate-reducing bacteria, which were collected from lead-zinc mine waters. The researchers were curious about the relationship of the organic material and metals, particularly how organics affect mobility, and its potential for bioremediation. It is known that some organics promote aggregation. Amine-bearing molecules, for example, can organize sulfide nanoparticles into semiconductor nanowires. The research team used a series of imaging techniques and detectors to analyze aggregates of biogenic zinc sulfide nanocrystals in the biofilms. Their examination yielded excellent results and some surprises. They were able to prove that natural organic matter promotes dense aggregation of the zinc sulfide nanocrystals into much larger spheroids and that the organic matter is preserved in nanometer-scale pores in the spheroids. What was not expected was the presence of proteins in the spheroids, making them a key component in aggregation and an example of extracellular biomineralization.

3

Extracellular Proteins Promote Zinc Sulfide Aggregation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Extracellular Proteins Promote Zinc Sulfide Aggregation Print Extracellular Proteins Promote Zinc Sulfide Aggregation Print Researchers from the ALS, Berkeley Lab's National Center for Electron Microscopy (NCEM), and Lawrence Livermore National Laboratory analyzed biofilm samples rich in zinc sulfide and dominated by sulfate-reducing bacteria, which were collected from lead-zinc mine waters. The researchers were curious about the relationship of the organic material and metals, particularly how organics affect mobility, and its potential for bioremediation. It is known that some organics promote aggregation. Amine-bearing molecules, for example, can organize sulfide nanoparticles into semiconductor nanowires. The research team used a series of imaging techniques and detectors to analyze aggregates of biogenic zinc sulfide nanocrystals in the biofilms. Their examination yielded excellent results and some surprises. They were able to prove that natural organic matter promotes dense aggregation of the zinc sulfide nanocrystals into much larger spheroids and that the organic matter is preserved in nanometer-scale pores in the spheroids. What was not expected was the presence of proteins in the spheroids, making them a key component in aggregation and an example of extracellular biomineralization.

4

Zinc sulfide liquefaction catalyst  

DOE Patents [OSTI]

A process for the liquefaction of carbonaceous material, such as coal, is set forth wherein coal is liquefied in a catalytic solvent refining reaction wherein an activated zinc sulfide catalyst is utilized which is activated by hydrogenation in a coal derived process solvent in the absence of coal.

Garg, Diwakar (Macungie, PA)

1984-01-01T23:59:59.000Z

5

X-ray absorption spectroscopy of the cubic and hexagonal polytypes of zinc sulfide B. Gilbert,1,  

E-Print Network [OSTI]

X-ray absorption spectroscopy of the cubic and hexagonal polytypes of zinc sulfide B. Gilbert,1 Received 18 June 2002; published 26 December 2002 We investigate the sensitivity of x-ray absorption. Experimental spectra and multiple-scattering calculations are reported at the major absorption edges

Haskel, Daniel

6

E-Print Network 3.0 - activated zinc sulfide Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the Initial Reports and Scientific Results portions of Vol- Summary: -14 active zones, geology, A:18-19 age sulfides, B:111-117 vs. uranium content, B:113-114 alteration...

7

Mineralogical and chemical assessment of concrete damaged by the oxidation of sulfide-bearing aggregates: Importance of thaumasite formation on reaction mechanisms  

SciTech Connect (OSTI)

Damages in concrete containing sulfide-bearing aggregates were recently observed in the Trois-Rivieres area (Quebec, Canada), characterized by rapid deterioration within 3 to 5 years after construction. A petrographic examination of concrete core samples was carried out using a combination of tools including: stereomicroscopic evaluation, polarized light microscopy, scanning electron microscopy, X-ray diffraction and electron microprobe analysis. The aggregate used to produce concrete was an intrusive igneous rock with different metamorphism degrees and various proportions of sulfide minerals. In the rock, sulfide minerals were often surrounded by a thin layer of carbonate minerals (siderite). Secondary reaction products observed in the damaged concrete include 'rust' mineral forms (e.g. ferric oxyhydroxides such as goethite, limonite (FeO (OH) nH{sub 2}O) and ferrihydrite), gypsum, ettringite and thaumasite. In the presence of water and oxygen, pyrrhotite oxidizes to form iron oxyhydroxides and sulphuric acid. The acid then reacts with the phases of the cement paste/aggregate and provokes the formation of sulfate minerals. Understanding both mechanisms, oxidation and internal sulfate attack, is important to be able to duplicate the damaging reaction in laboratory conditions, thus allowing the development of a performance test for evaluating the potential for deleterious expansion in concrete associated with sulfide-bearing aggregates.

Rodrigues, A. [Centre de Recherche sur les Infrastructures en Beton (CRIB), Universite Laval, 1065 ave de la Medecine, Quebec, QC, Canada G1V 0A6 (Canada)] [Centre de Recherche sur les Infrastructures en Beton (CRIB), Universite Laval, 1065 ave de la Medecine, Quebec, QC, Canada G1V 0A6 (Canada); Duchesne, J., E-mail: josee.duchesne@ggl.ulaval.ca [Centre de Recherche sur les Infrastructures en Beton (CRIB), Universite Laval, 1065 ave de la Medecine, Quebec, QC, Canada G1V 0A6 (Canada); Fournier, B. [Centre de Recherche sur les Infrastructures en Beton (CRIB), Universite Laval, 1065 ave de la Medecine, Quebec, QC, Canada G1V 0A6 (Canada)] [Centre de Recherche sur les Infrastructures en Beton (CRIB), Universite Laval, 1065 ave de la Medecine, Quebec, QC, Canada G1V 0A6 (Canada); Durand, B. [Institut de recherche d'Hydro-Quebec (IREQ), 1740 boul. Lionel-Boulet, Varennes, QC, Canada J3X 1S1 (Canada)] [Institut de recherche d'Hydro-Quebec (IREQ), 1740 boul. Lionel-Boulet, Varennes, QC, Canada J3X 1S1 (Canada); Rivard, P. [Universite de Sherbrooke, Sherbrooke, QC, Canada J1K 2R1 (Canada)] [Universite de Sherbrooke, Sherbrooke, QC, Canada J1K 2R1 (Canada); Shehata, M. [Ryerson University, 350 Victoria Street, Toronto, ON, Canada M5B 2K3 (Canada)] [Ryerson University, 350 Victoria Street, Toronto, ON, Canada M5B 2K3 (Canada)

2012-10-15T23:59:59.000Z

8

Effect of Short-Term Resuspension Events on the Oxidation of Cadmium, Lead, and Zinc Sulfide Phases in Anoxic Estuarine Sediments  

Science Journals Connector (OSTI)

Effect of Short-Term Resuspension Events on the Oxidation of Cadmium, Lead, and Zinc Sulfide Phases in Anoxic Estuarine Sediments ... Simulated resuspension experiments were performed for periods of 0?24 h on the three unmodified sediments as well as on preparations of the model metal sulfide phases, CdS, FeS, PbS, or ZnS (70 ?mol), that were resuspended for 24 h in seawater in both the absence and the presence of each sediment (1 g dry wt). ... For experiments where the model sulfides were resuspended in seawater (24 h) in the presence of sediments or added following the resuspension of sedi ments in seawater but prior to AVS analysis, recoveries of CdS and ZnS were generally 5?13% lower than in the absence of sediment (Table 2). ...

Stuart L. Simpson; Simon C. Apte; Graeme E. Batley

2000-09-15T23:59:59.000Z

9

ITP Mining: Energy and Environmental Profile of the U.S. Mining Industry: Chapter 6: Lead and Zinc  

Broader source: Energy.gov (indexed) [DOE]

6 6 Lead and Zinc Lead and zinc ores are usually found together with gold and silver. A lead-zinc ore may also contain lead sulfide, zinc sulfide, iron sulfide, iron carbonate, and quartz. When zinc and lead sulfides are present in profitable amounts they are regarded as ore minerals. The remaining rock and minerals are called gangue. Forms of Lead and Zinc Ore The two principal minerals containing lead and zinc are galena and sphalerite. These two minerals are frequently found together along with other sulfide minerals, but one or the other may be predominant. Galena may contain small amounts of impurities including the precious metal silver, usually in the form of a sulfide. When silver is present in sufficient quantities, galena is regarded as a silver ore and called argentiferous galena. Sphalerite is zinc sulfide, but

10

Comparison of nickel doped Zinc Sulfide and/or palladium nanoparticle loaded on activated carbon as efficient adsorbents for kinetic and equilibrium study of removal of Congo Red dye  

Science Journals Connector (OSTI)

Abstract In this study, the efficiency of nickel doped Zinc Sulfide nanoparticle loaded on activated carbon (Ni-ZnS-NP-AC) and palladium nanoparticles loaded on activated carbon (Pd-NP-AC) for the removal of Congo Red (CR) from aqueous solution was investigated. These materials were fully identified and characterized in term of structure, surface area and pore volume with different techniques such XRD, FE-SEM and TEM analysis. The dependency of CR removal percentage to variables such as pH, contact time, amount of adsorbents, CR concentration was examined and optimum values were set as: 0.03 g Ni-ZnS-NP-AC and 0.04 g of Pd-NP-AC at pH of 3 and 2 after mixing for 22 and 26 min for Ni-ZnS-NP-AC and Pd-NP-AC, respectively. Subsequently, it was revealed that isotherm data efficiency can be correlated Langmuir with maximum monolayer adsorption capacities of 286 and 126.6 mg g?1 at room temperature for Ni-ZnS-NP-AC and Pd-NP-AC, respectively. Investigation of correlation between time and rate of adsorption reveal that the CR adsorption onto both adsorbents followed pseudo second order and interparticle diffusion simultaneously.

K. Ahmadi; M. Ghaedi; A. Ansari

2014-01-01T23:59:59.000Z

11

Cadmium zinc sulfide by solution growth  

SciTech Connect (OSTI)

This patent describes a photoelectric cell. It comprises a thin film of CdZnS that forms a continuous coating free of pin holes and has a thickness that is sufficiently thin to provide at least 70% transmission of radiation having a wavelength 400 nm.

Chen, W.S.

1992-05-12T23:59:59.000Z

12

Quantitative evaluation of hydrogen sulfide at 0.3 M and 1.0 M-hydrogen-ion concentration  

E-Print Network [OSTI]

. In the present study, cobalt sulfide was quantitatively re? covered from a solution whose hydrogen-ion concentration -12was calculated to be 6.95 x 10 M. As in the case of zinc sulfide, this was to be expected, since a decreased hydrogen-ion concentration... quantitatively to an electrolysis beaker with distilled water. The copper 28 was deposited on a platinum gauze cathode in 9 hours from a solution containing a 5 ml. excess of 18 M sulfuric acid in 125 ml., and a current of 0.5 ampere. 12. Copper (II) - Zinc...

Machel, Albert R.

1958-01-01T23:59:59.000Z

13

Oxidative Remobilization of Technetium Sequestered by Sulfide...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Remobilization of Technetium Sequestered by Sulfide-Transformed Nano Zerovalent Iron. Oxidative Remobilization of Technetium Sequestered by Sulfide-Transformed Nano Zerovalent...

14

Purification of sulfide oxidase from rat liver  

E-Print Network [OSTI]

of sulfide oxidase, provided an initial precipitation of sulfide oxidase, and after chromatographic procedures a 21 fold purification of the enzyme was obtained....

Pu, Lixia

1994-01-01T23:59:59.000Z

15

Coordinated Aggregation  

Broader source: Energy.gov (indexed) [DOE]

Coordinated Coordinated Aggregation of Distributed Energy Resources Alejandro Dominguez-Garcia Univ of Illinois Pravin Varaiya & Kameshwar Poolla UC Berkeley August 6, 2013 Dominguez-Garcia, Poolla, Varaiya CERTS Review 2013 August 6, 2013 0 / 45 Our Research Group Students Anand Subramanian, Justin Hughes Jared Porter, Zach Lerner Post-docs Ashutosh Nayyar He Hao, Borhan Sanandaji Faculty Alejandro Dominguez-Garcia Kameshwar Poolla, Pravin Varaiya Dominguez-Garcia, Poolla, Varaiya CERTS Review 2013 August 6, 2013 0 / 45 CERTS Research Activities Network case of Risk-Limiting Dispatch Improved Load Forecasting with fine-grain measurements Coordinated Aggregation of Distributed Resources Dominguez-Garcia, Poolla, Varaiya CERTS Review 2013 August 6, 2013 1 / 45 Risk Limiting Dispatch Dominguez-Garcia, Poolla, Varaiya CERTS Review 2013 August

16

Synthesis and Optical Properties of Sulfide Nanoparticles Prepared...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Optical Properties of Sulfide Nanoparticles Prepared in Dimethylsulfoxide. Synthesis and Optical Properties of Sulfide Nanoparticles Prepared in Dimethylsulfoxide. Abstract: Many...

17

Production of zinc pellets  

DOE Patents [OSTI]

Uniform zinc pellets are formed for use in batteries having a stationary or moving slurry zinc particle electrode. The process involves the cathodic deposition of zinc in a finely divided morphology from battery reaction product onto a non-adhering electrode substrate. The mossy zinc is removed from the electrode substrate by the action of gravity, entrainment in a flowing electrolyte, or by mechanical action. The finely divided zinc particles are collected and pressed into pellets by a mechanical device such as an extruder, a roller and chopper, or a punch and die. The pure zinc pellets are returned to the zinc battery in a pumped slurry and have uniform size, density and reactivity. Applications include zinc-air fuel batteries, zinc-ferricyanide storage batteries, and zinc-nickel-oxide secondary batteries.

Cooper, John F. (Oakland, CA)

1996-01-01T23:59:59.000Z

18

Production of zinc pellets  

DOE Patents [OSTI]

Uniform zinc pellets are formed for use in batteries having a stationary or moving slurry zinc particle electrode. The process involves the cathodic deposition of zinc in a finely divided morphology from battery reaction product onto a non-adhering electrode substrate. The mossy zinc is removed from the electrode substrate by the action of gravity, entrainment in a flowing electrolyte, or by mechanical action. The finely divided zinc particles are collected and pressed into pellets by a mechanical device such as an extruder, a roller and chopper, or a punch and die. The pure zinc pellets are returned to the zinc battery in a pumped slurry and have uniform size, density and reactivity. Applications include zinc-air fuel batteries, zinc-ferricyanide storage batteries, and zinc-nickel-oxide secondary batteries. 6 figs.

Cooper, J.F.

1996-11-26T23:59:59.000Z

19

REVISED HYDROGEN SULFIDE DRILLING CONTINGENCY PLAN  

E-Print Network [OSTI]

REVISED HYDROGEN SULFIDE DRILLING CONTINGENCY PLAN OCEAN DRILLING PROGRAM TEXAS A&M UNIVERSITY;PREFACE Attached is the "REVISED HYDROGEN SULFIDE DRILLING CONTINGENCY PLAN" that will be used for ODP coring and drilling operations on legs where hydrogen sulfide is likely to be encountered. Prior

20

CODE OF PRACTICE HYDROGEN SULFIDE  

E-Print Network [OSTI]

. The Immediately Dangerous to Life and Health concentration of 100 ppm has been established by the National Institute for Occupational Safety and Health (NIOSH). Table 1: Health Affects from Short-Term Exposure to Hydrogen Sulfide (reproduced from: Hydrogen Sulphide at the Work Site, Alberta Workplace Health & Safety

Machel, Hans

Note: This page contains sample records for the topic "zinc sulfide aggregation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

CODE OF PRACTICE HYDROGEN SULFIDE  

E-Print Network [OSTI]

.E.L) is 10 parts per million (ppm) for 8 hours and 15 ppm as a ceiling limit. The Immediately Dangerous to Life and Health concentration of 100 ppm has been established by the National Institute for Occupational Safety and Health (NIOSH). Table 1: Health Affects from Short-Term Exposure to Hydrogen Sulfide

Machel, Hans

22

Zinc oxyfluoride transparent conductor  

DOE Patents [OSTI]

Transparent, electrically conductive and infrared-reflective films of zinc oxyfluoride are produced by chemical vapor deposition from vapor mixtures of zinc, oxygen and fluorine-containing compounds. The substitution of fluorine for some of the oxygen in zinc oxide results in dramatic increases in the electrical conductivity. For example, diethyl zinc, ethyl alcohol and hexafluoropropene vapors are reacted over a glass surface at 400.degree. C. to form a visibly transparent, electrically conductive, infrared reflective and ultraviolet absorptive film of zinc oxyfluoride. Such films are useful in liquid crystal display devices, solar cells, electrochromic absorbers and reflectors, energy-conserving heat mirrors, and antistatic coatings.

Gordon, Roy G. (Cambridge, MA)

1991-02-05T23:59:59.000Z

23

Hydrogen Production from Thermocatalytic Hydrogen Sulfide Decomposition  

Science Journals Connector (OSTI)

Experimental data on hydrogen production from hydrogen sulfide decomposition over various solid catalysts at ... The possibilities given by surface modification by vacuum methods (electron beam evaporation and ma...

O. K. Alexeeva

2002-01-01T23:59:59.000Z

24

Sulfidation of coal gasifier heat exchanger alloys  

Science Journals Connector (OSTI)

Three steels, viz., INCOLOY* 800H, Fecralloy,† and AlSI 310, were exposed to a simulated low Btu coal gasifier product gas at 450 °C. Sulfidation...

S. R. J. Saunders; S. Schlierer

1986-03-01T23:59:59.000Z

25

Use of ferric sulfate: acid media for the desulfurization of model compounds of coal. [Dibenzothiophene, diphenyl sulfide, di-n-butyl sulfide  

SciTech Connect (OSTI)

The objective of this work has been to investigate the ability of ferric sulfate-acid leach systems to oxidize the sulfur in model compounds of coal. Ferric iron-acid leach systems have been shown to be quite effective at removal of inorganic sulfur in coal. In this study, the oxidative effect of ferric iron in acid-leach systems was studied using dibenzothiophene, diphenyl sulfide, and di-n-butyl sulfide as models of organic sulfur groups in coal. Nitrogen and oxygen, as well as various transition metal catalysts and oxidants, were utilized in this investigation. Dibenzothiophene was found to be quite refractory to oxidation, except in the case where metavanadate was added, where it appears that 40% oxidation to sulfone could have occurred per hour at 150/sup 0/C and mild oxygen pressure. Diphenyl sulfide was selectively oxidized to sulfoxide and sulfone in an iron and oxygen system. Approximately 15% conversion to sulfone occurred per hour under these conditions. Some of the di-n-butyl sulfide was cracked to 1-butene and 1-butanethiol under similar conditions. Zinc chloride and ferric iron were used at 200/sup 0/C in an attempt to desulfonate dibenzothiophene sulfone, diphenyl sulfone, and di-n-butyl sulfone. Di-n-butyl sulfone was completely desulfurized on one hour and fragmented to oxidized parafins, while dibenzothiophene sulfone and diphenyl sulfone were unaffected. These results suggest that an iron-acid leach process could only selectively oxidize aryl sulfides under mild conditions, representing only 20% of the organic sulfur in coal (8% of the total sulfur). Removal through desulfonation once selective sulfur oxidation had occurred was only demonstrated for alkyl sulfones, with severe oxidation of the fragmented paraffins also occurring in one hour.

Clary, L.R.; Vermeulen, T.; Lynn, S.

1980-12-01T23:59:59.000Z

26

Improved zinc electrode and rechargeable zinc-air battery  

DOE Patents [OSTI]

The invention comprises an improved rechargeable zinc-air cell/battery having recirculating alkaline electrolyte and a zinc electrode comprising a porous foam support material which carries the active zinc electrode material. 5 figs.

Ross, P.N. Jr.

1988-06-21T23:59:59.000Z

27

Thiophene Hydrogenation to Tetrahydrothiophene over Tungsten Sulfide Catalysts  

Science Journals Connector (OSTI)

Independent reactions of thiophene reduction to tetrahydrothiophene and thiophene hydrogenolysis to form hydrogen sulfide...4...hydrocarbons are shown to occur over supported tungsten sulfide catalysts and unsupp...

A. V. Mashkina

2003-03-01T23:59:59.000Z

28

Biogenic formation of photoactive arsenic-sulfide nanotubes by...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

formation of photoactive arsenic-sulfide nanotubes by Shewanella sp. strain HN-41 . Biogenic formation of photoactive arsenic-sulfide nanotubes by Shewanella sp. strain HN-41 ....

29

Durable regenerable sorbent pellets for removal of hydrogen sulfide from coal gas  

DOE Patents [OSTI]

Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

Siriwardane, Ranjani V. (Morgantown, WV)

1997-01-01T23:59:59.000Z

30

Durable regenerable sorbent pellets for removal of hydrogen sulfide coal gas  

DOE Patents [OSTI]

Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form, usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

Siriwardane, Ranjani V. (Morgantown, WV)

1999-01-01T23:59:59.000Z

31

Cedar Key Aquaculture Workshop Sulfide Concentrations in Sediments  

E-Print Network [OSTI]

Cedar Key Aquaculture Workshop Sulfide Concentrations in Sediments and Water: Influence on Hard;ObjectivesObjectives Examine sediment sulfide levels in the SuwanneeExamine sediment sulfide levels of sulfide on hard clam survivalsurvival #12;MethodsMethods SedimentSediment porewaterporewater samples

Florida, University of

32

Zinc phosphate conversion coatings  

DOE Patents [OSTI]

Zinc phosphate conversion coatings for producing metals which exhibit enhanced corrosion prevention characteristics are prepared by the addition of a transition-metal-compound promoter comprising a manganese, iron, cobalt, nickel, or copper compound and an electrolyte such as polyacrylic acid, polymethacrylic acid, polyitaconic acid and poly-L-glutamic acid to a phosphating solution. These coatings are further improved by the incorporation of Fe ions. Thermal treatment of zinc phosphate coatings to generate .alpha.-phase anhydrous zinc phosphate improves the corrosion prevention qualities of the resulting coated metal.

Sugama, Toshifumi (Wading River, NY)

1997-01-01T23:59:59.000Z

33

Zinc phosphate conversion coatings  

DOE Patents [OSTI]

Zinc phosphate conversion coatings for producing metals which exhibit enhanced corrosion prevention characteristics are prepared by the addition of a transition-metal-compound promoter comprising a manganese, iron, cobalt, nickel, or copper compound and an electrolyte such as polyacrylic acid, polymethacrylic acid, polyitaconic acid and poly-L-glutamic acid to a phosphating solution. These coatings are further improved by the incorporation of Fe ions. Thermal treatment of zinc phosphate coatings to generate {alpha}-phase anhydrous zinc phosphate improves the corrosion prevention qualities of the resulting coated metal. 33 figs.

Sugama, T.

1997-02-18T23:59:59.000Z

34

Lead, zinc, and strontium in limestone cap rock from Tatum salt dome, Mississippi  

SciTech Connect (OSTI)

Limestone cap rock at Tatum salt dome, Mississippi, contains disseminated pyrite, sphalerite, and galena, and disseminated to massive amounts of strontianite (SrCO/sub 3/) and celestite (SrSO/sub 4/). Sulfide minerals are locally present in bitumen-rich areas of the upper, massive portion of the limestone cap rock, whereas strontium minerals are disseminated throughout this zone. However, sulfide and strontium minerals are most abundant in the lower banded portion of the limestone cap rock, which consists of alternating subhorizontal light and dark-colored bands. The dark bands are composed of calcite of variable grain size, sulfides, quartz, dolomite, albite, and up to 1% bitumen that apparently formed by the biodegradation of crude oil. Lighter bands are composed of variable amounts of coarsely crystalline, euhedral calcite, strontianite, and celestite resulting in strontium (Sr) contents of up to 30% locally. Banded limestone cap rock at Tatum dome formed at the top of the actively dissolving anhydrite zone by a combination of sulfate reduction and oxidation of liquid hydrocarbons by bacteria to cause the precipitation of calcite and sulfide minerals and the accumulation of insoluble residue from the anhydrite (quartz, albite, dolomite). Lead and zinc in the sulfide minerals could have been derived from the dissolving anhydrite, but the abundance of Sr minerals present requires an external source. Present-day oil field brines in central Mississippi contain up to 3000 ppm Sr, and basin brines of similar composition apparently contributed Sr to the cap-rock environment during formation.

Saunders, J.A.

1988-09-01T23:59:59.000Z

35

Photovoltaic cells employing zinc phosphide  

DOE Patents [OSTI]

A photovoltaic cell having a zinc phosphide absorber. The zinc phosphide can be a single or multiple crystal slice or a thin polycrystalline film. The cell can be a Schottky barrier, heterojunction or homojunction device. Methods for synthesizing and crystallizing zinc phosphide are disclosed as well as a method for forming thin films.

Barnett, Allen M. (Newark, DE); Catalano, Anthony W. (Wilmington, DE); Dalal, Vikram L. (Newark, DE); Masi, James V. (Wilbraham, MA); Meakin, John D. (Newark, DE); Hall, Robert B. (Newark, DE)

1984-01-01T23:59:59.000Z

36

Regional Comparisons, Spatial Aggregation,  

Gasoline and Diesel Fuel Update (EIA)

Regional Regional Comparisons, Spatial Aggregation, and Asymmetry of Price Pass-Through in U.S. Gasoline Markets MICHAEL YE*, JOHN ZYREN**, JOANNE SHORE**, AND MICHAEL BURDETTE** Abstract Spot to retail price pass-through behavior of the U.S. gasoline market was investigated at the national and regional levels, using weekly wholesale and retail motor gasoline prices from January 2000 to the present. Asymmetric pass-through was found across all regions, with faster pass-through when prices are rising. Pass-through patterns, in terms of speed and time for completion, were found to vary from region to region. Spatial aggregation was investigated at the national level and the East Coast with the aggregated cumulative pass-through being greater than the volume-weighted regional pass-through when spot prices increase. These results are useful to the petroleum industry, consumers,

37

Supercritical Water Desulfurization of Organic Sulfides Is Consistent with Free-Radical Kinetics  

Science Journals Connector (OSTI)

Pushkaraj R. Patwardhan †, Michael T. Timko †, Caleb A. Class †, Robin E. Bonomi †, Yuko Kida †, Hector H. Hernandez ‡, Jefferson W. Tester §, and William H. Green *† ... In contrast to sulfides and disulfides, they observed that ionic reactions dominated mercaptan decomposition and resulted in greater conversions in aqueous medium. ... Model compounds were selected to represent the various classes of sulfur compounds present in crude oil: an alkyl sulfide (hexyl sulfide), a cyclic sulfide (tetrahydrothiophene), an alkyl aryl sulfide (isopropyl phenyl sulfide), three aromatic sulfides (dibenzyl sulfide, benzyl phenyl sulfide, and diphenyl sulfides), and two thiophenic compounds (thiophene and dibenzothiophene). ...

Pushkaraj R. Patwardhan; Michael T. Timko; Caleb A. Class; Robin E. Bonomi; Yuko Kida; Hector H. Hernandez; Jefferson W. Tester; William H. Green

2013-09-20T23:59:59.000Z

38

Process for producing cadmium sulfide on a cadmium telluride surface  

DOE Patents [OSTI]

A process is described for producing a layer of cadmium sulfide on a cadmium telluride surface to be employed in a photovoltaic device. The process comprises providing a cadmium telluride surface which is exposed to a hydrogen sulfide plasma at an exposure flow rate, an exposure time and an exposure temperature sufficient to permit reaction between the hydrogen sulfide and cadmium telluride to thereby form a cadmium sulfide layer on the cadmium telluride surface and accomplish passivation. In addition to passivation, a heterojunction at the interface of the cadmium sulfide and the cadmium telluride can be formed when the layer of cadmium sulfide formed on the cadmium telluride is of sufficient thickness. 12 figs.

Levi, D.H.; Nelson, A.J.; Ahrenkiel, R.K.

1996-07-30T23:59:59.000Z

39

Comparative studies of hydrodenitrogenation by mixed metal sulfide catalysts  

E-Print Network [OSTI]

. , Sanchez, K. M. , and Reibenspies, J. , "Synthesis and characterization of [Et4N][M(CO)5SR] and [Et4N]2[M2 (CO) 8 (SR) 2] complexes (M = Cr, Mo, W) . Ligand substitution... to mimic the commercial catalyst (ie. no sulfide bridges prior to activation) l a Ni/Mo sulfide catalyst which consisted of Ni and Mo atoms brought in intimate contact by sulfide bridges; Ni/Mo and Co/Mo organometallic catalysts whose central metal had...

Luchsinger, Mary Margaret

1990-01-01T23:59:59.000Z

40

A paradox resolved: Sulfide acquisition by roots of seep tubeworms sustains net chemoautotrophy  

Science Journals Connector (OSTI)

...numbers indicate consumption and negative numbers...require sulfide to fuel autotrophic carbon...In the split-vessel respiration experiments...production to consumption) when sulfide...animal biomass to vessel volume necessitated...sulfide and oxygen consumption rates...

John K. Freytag; Peter R. Girguis; Derk C. Bergquist; Jason P. Andras; James J. Childress; Charles R. Fisher

2001-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "zinc sulfide aggregation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

E-Print Network 3.0 - antimony sulfide colloid Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

separates, B:33 sulfides, B:37, 39 sulfides and sediments, B:45... -14 active zones, geology, A:18-19 age sulfides, B:111-117 vs. uranium content, B:113-114 alteration...

42

E-Print Network 3.0 - antimony sulfides Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

separates, B:33 sulfides, B:37, 39 sulfides and sediments, B:45... -14 active zones, geology, A:18-19 age sulfides, B:111-117 vs. uranium content, B:113-114 alteration...

43

Teichert Aggregates | Open Energy Information  

Open Energy Info (EERE)

Teichert Aggregates Teichert Aggregates Jump to: navigation, search Name Teichert Aggregates Facility Teichert Aggregates Sector Wind energy Facility Type Community Wind Facility Status In Service Owner Teichert Aggregates Developer Foundation Windpower Energy Purchaser Teichert Aggregates Location South of Tracy CA Coordinates 37.616169°, -121.356236° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":37.616169,"lon":-121.356236,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

44

Nontoxic and Abundant Copper Zinc Tin Sulfide Nanocrystals for Potential High-Temperature Thermoelectric Energy Harvesting  

E-Print Network [OSTI]

materials is of great interest due to its simplicity and reliability. However, many thermoelectric materials thermoelectric (TE) materials for waste heat recovery and solid-state cooling. However, most of these TE, the best-commercialized thermoelectric bulk material (Bi2Te3-based alloy) has a ZT around 1,2,3 whereas

Chen, Yong P.

45

It's Elemental - The Element Zinc  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Copper Copper Previous Element (Copper) The Periodic Table of Elements Next Element (Gallium) Gallium The Element Zinc [Click for Isotope Data] 30 Zn Zinc 65.38 Atomic Number: 30 Atomic Weight: 65.38 Melting Point: 692.68 K (419.53°C or 787.15°F) Boiling Point: 1180 K (907°C or 1665°F) Density: 7.134 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 4 Group Number: 12 Group Name: none What's in a name? From the German word zink. Say what? Zinc is pronounced as ZINK. History and Uses: Although zinc compounds have been used for at least 2,500 years in the production of brass, zinc wasn't recognized as a distinct element until much later. Metallic zinc was first produced in India sometime in the 1400s by heating the mineral calamine (ZnCO3) with wool. Zinc was rediscovered by

46

Chapter 9 - Zinc and Residue Recycling  

Science Journals Connector (OSTI)

Abstract Annual global production of zinc is more than 13 million tons. More than 50% of this amount is used for galvanizing while the rest is mainly split into brass production, zinc-based alloys, semi manufacturers and zinc compounds such as zinc oxide and zinc sulfate. For the zinc and steel industries, recycling of zinc-coated steel provides an important new source of raw material. Historically, the generation of zinc-rich dusts from steel recycling was a source of loss from the life-cycle (landfill); however, technologies today provide incentive for steel recyclers to minimize waste. Thus, the recycling loop is endless—both zinc and steel can be recycled again and again without losing any of their physical or chemical properties. Depending on the composition of the scrap being recycled, it can either be remelted or returned to the refining process. This chapter describes the main processes for zinc recycling from different scraps and residues.

Jürgen Antrekowitsch; Stefan Steinlechner; Alois Unger; Gernot Rösler; Christoph Pichler; Rene Rumpold

2014-01-01T23:59:59.000Z

47

Social network effects on information aggregation  

E-Print Network [OSTI]

In this thesis, we investigated how sociometric information can be used to improve different methods of aggregating dispersed information. We specifically compared four different approaches of information aggregation: ...

Mulanda, Chilongo D

2006-01-01T23:59:59.000Z

48

Direct Observation of Aggregative Nanoparticle Growth: Kinetic...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Aggregative Nanoparticle Growth: Kinetic Modeling of the Size Distribution and Growth Rate. Direct Observation of Aggregative Nanoparticle Growth: Kinetic Modeling of the Size...

49

Toward a quantitative model for the formation of gravitational magmatic sulfide deposits  

E-Print Network [OSTI]

concentration at sulfide saturation (referred to as sulfur solubility for simplicity) decreases. As the melt of sulfide liquid from a silicate melt, and the coupled growth kinetics and settling dynamics of sulfide liquid layer at the bottom of a magma chamber are referred to as the necessary criteria for sulfide ore

Zhang, Youxue

50

Transition Metal Sulfide Electrocatalysts for PEM Fuel Cells  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Transition Metal Sulfide Transition Metal Sulfide Electrocatalysts for PEM Fuel Cells Hua Zhang 1 , Ysmael Verde-Gómez 1 and Allan J. Jacobson 1 Alejandra Ramirez 2 and Russell R. Chianelli 2 1 Department of Chemistry, University of Houston Houston, TX 77204 2 Materials Research and Technology Institute, University of Texas at El Paso, El Paso, TX 79968 Transition Metal Sulfide Electrocatalysts for PEM Fuel Cells Hua Zhang 1 , Ysmael Verde-Gómez 1 and Allan J. Jacobson 1 Alejandra Ramirez 2 and Russell R. Chianelli 2 1 Department of Chemistry, University of Houston Houston, TX 77204 2 Materials Research and Technology Institute, University of Texas at El Paso, El Paso, TX 79968 March 21, 2003 Objectives ¾ Investigate non-platinum electro-catalysts with CO tolerance ¾ Focus on transition metal sulfides as electro-catalysts

51

Gas-Phase Thiophene Hydrogenation to Tetrahydrothiophene over Sulfide Catalysts  

Science Journals Connector (OSTI)

Thiophene hydrogenation to tetrahydrothiophene over supported transition metal sulfides is studied....T = 240°C and P...= 2 MPa showed that aluminosilicate-supported PdS is one to two orders of magnitude more act...

A. V. Mashkina; L. G. Sakhaltueva

2002-01-01T23:59:59.000Z

52

Design and fabrication of a tin-sulfide annealing furnace  

E-Print Network [OSTI]

A furnace was designed and its heat transfer properties were analyzed for use in annealing thin-film tins-ulfide solar cells. Tin sulfide has been explored as an earth abundant solar cell material, and the furnace was ...

Lewis, Raymond (Raymond A.)

2011-01-01T23:59:59.000Z

53

Utilization of Dimethyl Sulfide as a Sulfur Source with the Aid of Light by Marinobacterium sp. Strain DMS-S1  

Science Journals Connector (OSTI)

...sulfone, methanesulfonate, diethyl sulfide, tetrahydrothiophene, diethyl sulfone, ethanesulfonate, methionine...Methylphenyl sulfide (, TK) Diphenyl sulfide (, TK) Tetrahydrothiophene (, TK) Tetramethylene sulfoxide (, TK) Sulfolane...

Hiroyuki Fuse; Osamu Takimura; Katsuji Murakami; Yukiho Yamaoka; Toshio Omori

2000-12-01T23:59:59.000Z

54

Sulfide catalysts for reducing SO2 to elemental sulfur  

DOE Patents [OSTI]

A highly efficient sulfide catalyst for reducing sulfur dioxide to elemental sulfur, which maximizes the selectivity of elemental sulfur over byproducts and has a high conversion efficiency. Various feed stream contaminants, such as water vapor are well tolerated. Additionally, hydrogen, carbon monoxide, or hydrogen sulfides can be employed as the reducing gases while maintaining high conversion efficiency. This allows a much wider range of uses and higher level of feed stream contaminants than prior art catalysts.

Jin, Yun (Peking, CN); Yu, Qiquan (Peking, CN); Chang, Shih-Ger (El Cerrito, CA)

2001-01-01T23:59:59.000Z

55

Hierarchically Ordered Cadmium Sulfide Nanowires Dispersed in Aqueous Solution  

Science Journals Connector (OSTI)

The paper reports on the preparation, characterization, and dispersion of cadmium sulfide (CdS) nanowires using ordered mesoporous silica, SBA-15, as a template. A homogeneous and stable dispersion of hierarchically ordered CdS nanowires in water ...This work demonstrates the formation of cadmium sulfide (CdS) nanowires. These nanowires are templated by mesoporous SBA-15 and their connectivity is tuned by the number of nanoconnectors (templated by micropores). They form stable dispersions in aqueous sodium dodecyl sulfate (SDS) solutions.

Rajagopalan Thiruvengadathan; Oren Regev

2005-05-17T23:59:59.000Z

56

Hydrogen and Sulfur Production from Hydrogen Sulfide Wastes  

E-Print Network [OSTI]

HYDROGEN AND SULFUR PRODUCTION FROM HYDROGEN SULFIDE WASTES? John B.L. Harkness and Richard D. Doctor, Argonne National Laboratory, Argonne. IL ABSTRACT A new hydrogen sulfide waste-treatment process that uses microwave plasma... to be economically competitive. In addition, the experiments show-that. typical refinery acid-gas streams are compatible with the plasma process and that all by-products can be treated with existing technology. BACKGROUND In 1987, Argonne staff found the first...

Harkness, J.; Doctor, R. D.

57

Process for thin film deposition of cadmium sulfide  

DOE Patents [OSTI]

The present invention teaches a process for depositing layers of cadmium sulfide. The process includes depositing a layer of cadmium oxide by spray pyrolysis of a cadmium salt in an aqueous or organic solvent. The oxide film is then converted into cadmium sulfide by thermal ion exchange of the O.sup.-2 for S.sup.-2 by annealing the oxide layer in gaseous sulfur at elevated temperatures.

Muruska, H. Paul (East Windsor, NJ); Sansregret, Joseph L. (Scotch Plains, NJ); Young, Archie R. (Montclair, NJ)

1982-01-01T23:59:59.000Z

58

Adsorption of carbonyl sulfide from liquid hydrocarbons with activated alumina and other adsorbents  

SciTech Connect (OSTI)

Contamination of Liquid hydrocarbon streams with carbonyl sulfide (COS) is not desirable; particularly in propylene. COS may poison the down stream polymerization catalyst. Thus, it is usually required to reduce the COS concentration to an extremely low level, e.g. 1 ppm or less, for polymer grade propylene. Many technologies generally available for sulfur removal, such as scrubbing and distillation are not applicable to the removal of COS from propylene. The former is not suitable for a low level removal. With the boiling point of COS (-50{sup 0}C) very close to that of propylene (-48{sup 0}C) it is difficult to achieve a very efficient separation with distillation. Adsorption technology provides a very energy efficient process in addition to its ability of the low level removal. Adsorbents selected in this study include activated carbon, molecular sieves, zinc oxide and activated alumina. The results show that activated alumina is far superior in both adsorption capacity and rate. An adsorption mechanism with activated alumina is proposed. It is believed that adsorption of COS takes place simultaneously with the hydrolysis of COS on the alumina surface. Adsorption isotherms of COS up to 100 ppm and the effect of moisture content are also addressed in this study.

Liu, P.K.T. (Alcoa Separations Technology Div., Aluminum Co. of America, Warrendale, PA (US))

1988-01-01T23:59:59.000Z

59

Response of zinc, iron and copper status parameters to supplementation with zinc or zinc and iron in women  

SciTech Connect (OSTI)

Supplementation with zinc at levels available over-the-counter may compromise iron or copper status. This study examined the effects of zinc(50mg/day) or zinc and iron(50 mg each/day) on 18 women aged 25-40. Subjects were matched on initial levels of serum ferritin(SF) and erythrocyte superoxide dismutase(ESOD) and randomly assigned to Group Z (zinc) or F-Z (iron and zinc). The following were measured pretreatment and after 6 and 10 weeks treatment: serum zinc (BZ), salivary sediment zinc (SSZ), hemoglobin (Hgb), hematocrit (Hct), SF, serum ceruloplasmin (Cp) and ESOD. Effects of treatment and weeks of treatment on changes from initial blood and saliva levels were analyzed using AOV. BZ increased (P=0.0144) and ESOD decreased (P=0.0001) with weeks of treatment. Differences due to treatment are presented. No effects were noted on Hgb, Hct or Cp. Intakes of zinc supplements at about 4X RDA appear to decrease copper(ESOD) and iron(SF) status. Use of iron w/zinc may be protective for FE but not Cu, and may compromise zinc (SSZ) status.

Yadrick, K.; Kenney, M.A.; Winterfeldt, E.

1986-03-05T23:59:59.000Z

60

Method for the regeneration of spent molten zinc chloride  

DOE Patents [OSTI]

In a process for regenerating spent molten zinc chloride which has been used in the hydrocracking of coal or ash-containing polynuclear aromatic hydrocarbonaceous materials derived therefrom and which contains zinc chloride, zinc oxide, zinc oxide complexes and ash-containing carbonaceous residue, by incinerating the spent molten zinc chloride to vaporize the zinc chloride for subsequent condensation to produce a purified molten zinc chloride: an improvement comprising the use of clay in the incineration zone to suppress the vaporization of metals other than zinc. Optionally water is used in conjunction with the clay to further suppress the vaporization of metals other than zinc.

Zielke, Clyde W. (McMurray, PA); Rosenhoover, William A. (Pittsburgh, PA)

1981-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "zinc sulfide aggregation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Coregulated Genes Link Sulfide:Quinone Oxidoreductase and Arsenic Metabolism in Synechocystis sp. Strain PCC6803  

Science Journals Connector (OSTI)

...salt-tolerant chemolithoautotrophic sulfide oxidizers found in hot spring biofilms at Mono...using enrichment cultures of sulfide oxidizers closely related to some Thioalkalivibrio...Reyes (Andalusian Molecular Biology and Regenerative Medicine Centre). There is no conflict...

Csaba I. Nagy; Imre Vass; Gábor Rákhely; István Zoltán Vass; András Tóth; Ágnes Duzs; Loredana Peca; Jerzy Kruk; Péter B. Kós

2014-07-14T23:59:59.000Z

62

Essays on aggregate and individual consumption fluctuations  

E-Print Network [OSTI]

This thesis consists of three essays on aggregate and individual consumption fluctuations. Chapter 1 develops a quantitative model to explore aggregate and individual consumption dynamics when the income process exhibits ...

Hwang, Youngjin

2006-01-01T23:59:59.000Z

63

The Weak Aggregating Algorithm and Weak Mixability  

E-Print Network [OSTI]

of the Weak Aggregating Algorithm that covers unbounded games is also described. #12; CONTENTS 2 Contents 1The Weak Aggregating Algorithm and Weak Mixability Yuri Kalnishkan Michael V. Vyugin 1 fyura the Weak Aggregating Algorithm that allows us to obtain additive terms of the form C p n. A modification

Kalnishkan, Yuri

64

SIA: Secure information aggregation in sensor networks  

Science Journals Connector (OSTI)

In sensor networks, data aggregation is a vital primitive enabling efficient data queries. An on-site aggregator device collects data from sensor nodes and produces a condensed summary which is forwarded to the off-site querier, thus reducing the communication ... Keywords: Sensor networks, approximate interactive proofs, information aggregation, security

Haowen Chan; Adrian Perrig; Bartosz Przydatek; Dawn Song

2007-01-01T23:59:59.000Z

65

Radical cations of sulfides and disulfides: An ESR study  

SciTech Connect (OSTI)

Exposure of dilute solutions of dimethylsulfide, methanethiol, tetrahydrothiophene, terbutyl and diterbutyl-sulfides, dimethyl-disulfide, and diterbutyldisulfide, in freon at 77 K to /sup 60/Co ..gamma.. rays gave the corresponding cations. From the reported ESR spectra, g tensors were obtained. It was found that both sulfide and disulfide cations exhibit the same g tensor: (g/sub max/ = 2.034 +- 0.002, g/sub int/ = 2.017 +- 0.001, g/sub min/ = 2.001 +- 0.005). From this result it has been shown that the disulfide cation is planar. This finding was supported by fully optimized geometry ab initio calculations.

Bonazzola, L.; Michaut, J.P.; Roncin, J.

1985-09-15T23:59:59.000Z

66

ARTICLE IN PRESS Modeling hydrogen sulfide emissions across the gas liquid interface  

E-Print Network [OSTI]

production methods in the US have led to the emergence of large- scale commeARTICLE IN PRESS Modeling hydrogen sulfide emissions across the gas­ liquid interface-film theory Hydrogen sulfide Process-based model Lagoon flux Mass transfer a b s t r a c t Hydrogen sulfide (H

Aneja, Viney P.

67

Giant Hydrogen Sulfide Plume in the Oxygen Minimum Zone off Peru Supports Chemolithoautotrophy  

E-Print Network [OSTI]

Giant Hydrogen Sulfide Plume in the Oxygen Minimum Zone off Peru Supports Chemolithoautotrophy sporadically accumulate hydrogen sulfide (H2S), which is toxic to most multicellular organisms and has been feedback loop that could fuel further sulfate reduction and potentially stabilize the sulfidic OMZ waters

Boyer, Edmond

68

Morphology control of zinc regeneration for zinc–air fuel cell and battery  

Science Journals Connector (OSTI)

Abstract Morphology control is crucial both for zinc–air batteries and for zinc–air fuel cells during zinc regeneration. Zinc dendrite should be avoided in zinc–air batteries and zinc pellets are yearned to be formed for zinc–air fuel cells. This paper is mainly to analyze the mechanism of shape change and to control the zinc morphology during charge. A numerical three-dimensional model for zinc regeneration is established with COMSOL software on the basis of ionic transport theory and electrode reaction electrochemistry, and some experiments of zinc regeneration are carried out. The deposition process is qualitatively analyzed by the kinetics Monte Carlo method to study the morphological change from the electrocrystallization point of view. Morphological evolution of deposited zinc under different conditions of direct currents and pulse currents is also investigated by simulation. The simulation shows that parametric variables of the flowing electrolyte, the surface roughness and the structure of the electrode, the charging current and mode affect morphological evolution. The uniform morphology of deposited zinc is attained at low current, pulsating current or hydrodynamic electrolyte, and granular morphology is obtained by means of an electrode of discrete columnar structure in combination with high current and flowing electrolyte.

Keliang Wang; Pucheng Pei; Ze Ma; Huachi Xu; Pengcheng Li; Xizhong Wang

2014-01-01T23:59:59.000Z

69

Precursors of copper/zinc oxide catalysts  

Science Journals Connector (OSTI)

Recent results on hydroxycarbonate precursors of copper/zinc oxide catalysts for methanol synthesis are reinterpreted, taking into account earlier work on these systems.

M.S. Spencer

70

Adsorption of carbonyl sulfide on nickel and tungsten films  

SciTech Connect (OSTI)

The interaction of carbonyl sulfide with evaporated nickel and tungsten films has been investigated in the temperature range 195-450 K using gas pressures ranging from 1 to 13 N m/sup -2/. Rapid but mainly associative chemisorption of COS occurred on both metals at 195 K. Further adsorption of COS on W at temperatures 293-450 K was extremely slow and accompanied by more CO desorption than COS adsorbed. Sulfidation of Ni film by COS occurred at temperatures greater than or equal to 293 K with the liberation of carbon monoxide. The rate of adsorption increased with temperature but was independent of COS pressure. The activation energy (E/sub x/) increased with extent (X) of sulfidation to a limiting value of 97 kJ mol/sup -1/. A linear relationship was obtained from the plot of E/sub x/ against 1/X, suggesting the applicability of Cabrera-Mott theory to the sulfidation of Ni film by COS. 20 references, 2 figures, 1 table.

Saleh, J.M.; Nasser, F.A.K.

1985-07-18T23:59:59.000Z

71

Kinetic study of hydrogen sulfide absorption in aqueous chlorine solution  

E-Print Network [OSTI]

). This technique involves H2S mass transfer in an aqueous phase using a gas-liquid contactor. Since H2S is poorly. This scrubbing liquid is just drained when the salt accumulation due to H2S oxidation into sulfate anions becomes Hydrogen sulfide (H2S) is currently removed from gaseous effluents by chemical scrubbing using water

Paris-Sud XI, Université de

72

(Data in thousand metric tons of zinc content, unless otherwise noted) Domestic Production and Use: The value of zinc mined in 1997, based on contained zinc recoverable from  

E-Print Network [OSTI]

190 ZINC (Data in thousand metric tons of zinc content, unless otherwise noted) Domestic Production by the agriculture, chemical, paint, and rubber industries. Major coproducts of zinc mining and smelting: 1993 1994 1995 1996 1997e Production: Mine, recoverable 488 570 614 600 6071 Primary slab zinc 240 217

73

(Data in thousand metric tons of zinc content, unless otherwise noted) Domestic Production and Use: The value of zinc mined in 2001, based on contained zinc recoverable from  

E-Print Network [OSTI]

188 ZINC (Data in thousand metric tons of zinc content, unless otherwise noted) Domestic Production-fourths of production. Three primary and 12 large- and medium-sized secondary smelters refined zinc metal of commercial principally by the agriculture, chemical, paint, and rubber industries. Major coproducts of zinc mining

74

(Data in thousand metric tons of zinc content, unless otherwise noted) Domestic Production and Use: The value of zinc mined in 2002, based on contained zinc recoverable from  

E-Print Network [OSTI]

190 ZINC (Data in thousand metric tons of zinc content, unless otherwise noted) Domestic Production% of production. Two primary and 13 large- and medium-sized secondary smelters refined zinc metal of commercial principally by the agriculture, chemical, paint, and rubber industries. Major coproducts of zinc mining

75

(Data in thousand metric tons of zinc content, unless otherwise noted) Domestic Production and Use: The value of zinc mined in 1999, based on contained zinc recoverable from  

E-Print Network [OSTI]

190 ZINC (Data in thousand metric tons of zinc content, unless otherwise noted) Domestic Production by the agriculture, chemical, paint, and rubber industries. Major coproducts of zinc mining and smelting: 1995 1996 1997 1998 1999e Production: Mine, recoverable1 614 600 605 722 775 Primary slab zinc 232 226

76

(Data in thousand metric tons of zinc content, unless otherwise noted) Domestic Production and Use: The value of zinc mined in 1998, based on contained zinc recoverable from  

E-Print Network [OSTI]

192 ZINC (Data in thousand metric tons of zinc content, unless otherwise noted) Domestic Production principally by the agriculture, chemical, paint, and rubber industries. Major coproducts of zinc mining--United States: 1994 1995 1996 1997 1998e Production: Mine, recoverable 570 614 598 605 6551 Primary slab zinc

77

Regulation of Zinc Transport in the Choroid Plexus  

E-Print Network [OSTI]

expression by prolactin. These data indicate there is a coordinated regulation of MT-1 and zinc transporters during extracellular zinc depletion or supplementation....

Aquino, Mayra

2014-07-21T23:59:59.000Z

78

THE SYNTHESIS OF MONOCLINIC ZINC DIPHOSPHIDE SINGLE CRYSTALS  

E-Print Network [OSTI]

General Phosphorous Deposit . . . . . . . . . . . . . . . .Ampules Zinc Diphosphide C. Phosphorous Sesquizinc Mechanismi 43, 114 The Zinc-Phosphorous System, L. A. Bitjutskaya, B.

Mowles, Thomas Andrew

2011-01-01T23:59:59.000Z

79

Methods for producing hydrogen (BI) sulfide and/or removing metals  

DOE Patents [OSTI]

The present invention is a process wherein sulfide production by bacteria is efficiently turned on and off, using pH adjustment. The adjustment of pH impacts sulfide production by bacteria by altering the relative amounts of H.sub.2 S and HS-- in solution and thereby control the inhibition of the bacterial metabolism that produces sulfide. This process can be used to make a bioreactor produce sulfide "on-demand" so that the production of sulfide can be matched to its use as a metal precipitation reagent. The present invention is of significance because it enables the use of a biological reactor, a cost effective sulfide production system, by making the biological reactor produce hydrogen sulfide "on demand", and therefore responsive to production schedules, waste stream generation rate, and health and safety requirements/goals.

Truex, Michael J [Richland, WA; Peyton, Brent M [Pullman, WA; Toth, James J [Kennewick, WA

2002-05-14T23:59:59.000Z

80

Original article Improvement of zinc intestinal absorption  

E-Print Network [OSTI]

Original article Improvement of zinc intestinal absorption and reduction of zinc/iron interaction of caseins, improves its absorption and could prevent inhibition by other nutrients such as iron (Fe). The absorption of Zn (100 Ilmol/L) bound to the 1-25 CN ((3-CN(1-25)) of (3-casein, or as ZnS04 was studied using

Boyer, Edmond

Note: This page contains sample records for the topic "zinc sulfide aggregation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Rational Design of Zinc Phosphide Heterojunction Photovoltaics  

E-Print Network [OSTI]

Rational Design of Zinc Phosphide Heterojunction Photovoltaics Thesis by Jeffrey Paul Bosco would meet me with the same energy and enthusiasm regarding the topic of zinc phosphide photovoltaics to the field of earth-abundant photovoltaics has been indispensable to my work. Greg also made a great mentor

Winfree, Erik

82

Fracture model for cemented aggregates  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

A mechanisms-based fracture model applicable to a broad class of cemented aggregates and, among them, plastic-bonded explosive (PBX) composites, is presented. The model is calibrated for PBX 9502 using the available experimental data under uniaxial compression and tension gathered at various strain rates and temperatures. We show that the model correctly captures inelastic stress-strain responses prior to the load peak and it predicts the post-critical macro-fracture processes, which result from the growth and coalescence of micro-cracks. In our approach, the fracture zone is embedded into elastic matrix and effectively weakens the material's strength along the plane of the dominant fracture.

Zubelewicz, Aleksander; Thompson, Darla G.; Ostoja-Starzewski, Martin; Ionita, Axinte; Shunk, Devin; Lewis, Matthew W.; Lawson, Joe C.; Kale, Sohan; Koric, Seid

2013-01-01T23:59:59.000Z

83

Nanoarchitectonics of Molecular Aggregates: Science and Technology  

SciTech Connect (OSTI)

The field of making, studying and using molecular aggregates, in which the individual molecules (monomers) are arranged in a regular fashion, has come a long way. Taking control over the aggregation of small molecules and polymers in bulk, on surfaces and at interfaces pose a considerable challenge for their utilization in modern high tech applications. In this review we provide a detailed insight into recent trends in molecular aggregates from the perspectives of nanoarchitectonics.

Ramanathan, Nathan Muruganathan [ORNL] [ORNL; Hong, Kunlun [ORNL] [ORNL; Ji, Dr. Qingmin [National Institute for Materials Science, Tsukuba, Japan] [National Institute for Materials Science, Tsukuba, Japan; Hill, Dr. Jonathan P [National Institute for Materials Science, Tsukuba, Japan] [National Institute for Materials Science, Tsukuba, Japan; Ariga, Katsuhiko [National Institute for Materials Science, Tsukuba, Japan] [National Institute for Materials Science, Tsukuba, Japan; Yusuke, Yonamine [National Institute for Materials Science, Tsukuba, Japan] [National Institute for Materials Science, Tsukuba, Japan

2014-01-01T23:59:59.000Z

84

Relational Sequence Clustering for Aggregating Similar Agents  

E-Print Network [OSTI]

Relational Sequence Clustering for Aggregating Similar Agents Grazia Bombini, Nicola Di Mauro;2 Grazia Bombini, Nicola Di Mauro, Stefano Ferilli, and Floriana Esposito image segmentation and pattern

Di Mauro, Nicola

85

SES Performance Cycle- Aggregate Results FY 2013  

Broader source: Energy.gov [DOE]

The memorandum releases the FY 2013 aggregate results for the Department's Senior Executive Service members and provides a summary of past results.

86

Aggregation method for motor drive systems  

Science Journals Connector (OSTI)

Abstract When many variable frequency drives are connected to a common switchboard, their aggregated effect on system dynamics can be significant. In this paper, the aggregation method for variable frequency drives and their motors in industrial facilities is proposed, which is suitable for power systems dynamic studies. The proposed method can be applied to various types of motor drive systems. There are two steps involved for the proposed aggregation method: (1) aggregate motor drive systems connected to the same bus, and (2) further combine the aggregated model of motor drive systems from Step 1 with upstream series impedance and/or transformers. Due to involvement of high-order transfer functions in dynamic models of individual motor drive systems, Pade approximation is used as a useful tool in the aggregation process. Using the proposed aggregation method, an equivalent aggregated dynamic model of motor drive systems can be obtained at the substation bus. A case study is conducted in the paper, and the proposed aggregation method is verified to be effective by the case study.

Xiaodong Liang; Wilsun Xu

2014-01-01T23:59:59.000Z

87

Process for the production of hydrogen and carbonyl sulfide from hydrogen sulfide and carbon monoxide using a metal boride, nitride, carbide and/or silicide catalyst  

SciTech Connect (OSTI)

Hydrogen and carbonyl sulfide are produced by a process comprising contacting gaseous hydrogen sulfide with gaseous carbon monoxide in the presence of a metal boride, carbide, nitride and/or silicide catalyst, such as titanium carbide, vanadium boride, manganese nitride or molybdenum silicide.

McGuiggan, M.F.; Kuch, P.L.

1984-05-08T23:59:59.000Z

88

The Role of Carbon in Catalytically Stabilized Transition Metal Sulfides  

SciTech Connect (OSTI)

Since WWII considerable progress has been made in understanding the basis for the activity and the selectivity of molybdenum and tungsten based hydrotreating catalysts. Recently, the focus of investigation has turned to the structure of the catalytically stabilized active catalyst. The surface of the catalytically stabilized MoS2 has been shown to be carbided with the formula MoSxCy under hydrotreating conditions. In this paper we review the basis for this finding and present new data extending the concept to the promoted TMS (transition metal sulfides) systems CoMoC and NiMoC. Freshly sulfided CoMoS and NiMoS catalyst have a strong tendency to form the carbided surface phases from any available carbon source.

Kelty,S.; Berhault, G.; Chianelli, R.

2007-01-01T23:59:59.000Z

89

Highly Attrition Resistant Zinc Oxide-Based Sorbents for H2S Removal by Spray Drying Technique  

SciTech Connect (OSTI)

Primary issues for the fluidized-bed/transport reactor process are high attrition resistant sorbent, its high sorption capacity and regenerability, durability, and cost. The overall objective of this project is the development of a superior attrition resistant zinc oxide-based sorbent for hot gas cleanup in integrated coal gasification combined cycle (IGCC). Sorbents applicable to a fluidized-bed hot gas desulfurization process must have a high attrition resistance to withstand the fast solid circulation between a desulfurizer and a regenerator, fast kinetic reactions, and high sulfur sorption capacity. The oxidative regeneration of zinc-based sorbent usually initiated at greater than 600 C with highly exothermic nature causing deactivation of sorbent as well as complication of sulfidation process by side reaction. Focusing on solving the sorbent attrition and regenerability of zinc oxide-based sorbent, we have adapted multi-binder matrices and direct incorporation of regeneration promoter. The sorbent forming was done with a spray drying technique that is easily scalable to commercial quantity.

Ryu, C.K.; Lee, J.B.; Ahn, D.H.; Kim, J.J.; Yi, C.K.

2002-09-19T23:59:59.000Z

90

The selective adsorption of hydrogen sulfide from natural gas streams  

E-Print Network [OSTI]

, and Mr. Ovid Baker of Magnolia Petroleum Company. The author also wishes to thank the Linde Company for ths Molecular Sieve type adsorbents and technical information on the same. He also wishes to thank Mr. R. D. Henley and We Magnolia Petroleum... Effect of Water Vapor on Adsorptive Capacity of Bed. 31 Table VI Abbreviated Comparison of Adsorbents. 32 INTRODUCTIOM INTRODUC TION The separation of mercaptans and hydrogen sulfide from natural gas produced from sour reservoirs is a problem which...

Fails, James Clayton

2012-06-07T23:59:59.000Z

91

Ring size and strain as a control of reaction selectivity: ethylene sulfide on Mo(110)  

SciTech Connect (OSTI)

The adsorption and reaction of sulfur-containing organic on single-crystal transition-metal surfaces form a subject of current to the authors and others. The primary focus of their work is an investigation of how thermodynamic properties of adsorbate molecules affect the mechanism(s) by which they react. To this end, they have studied the reactions of two saturated cyclic sulfides-trimethylene sulfide (c-C/sub 3/H/sub 6/S) and tetrahydrothiophene (c-C/sub 4/H/sub 8/S)--on Mo(110). On the basis of these studies they proposed that ring strain in the cyclic sulfide controls reaction selectivity on Mo(110). This work concerns the reactions of a third cyclic sulfide, ethylene sulfide (c-C/sub 2/H/sub 4/S), on Mo(110). The results presented here demonstrate that ring size as well as ring strain determines the reaction selectivity of cyclic sulfides on Mo(110).

Roberts, J.T.; Friend, C.M.

1987-12-09T23:59:59.000Z

92

Iron-reducing bacteria accumulate ferric oxyhydroxide nanoparticle aggregates that may support planktonic growth  

E-Print Network [OSTI]

the Super 8 experiment. Nanoparticle aggregates are attachedgroundwater bacteria with nanoparticle aggregates attachedferric oxyhydroxide nanoparticle aggregates that may support

Luef, B.

2014-01-01T23:59:59.000Z

93

Structure, Aggregation and Characterization of Nanoparticles  

Science Journals Connector (OSTI)

...the process is called diffusion-limited aggregation (DLA). DLA is a very general phenomena for all kinds of pattern formation...primary particle aggregation only, the classical version of DLA was derived by Witten and Sander (1981) and is called...

Glenn A. Waychunas

94

Modeling Energy Demand Aggregators for Residential Consumers  

E-Print Network [OSTI]

The current world-wide increase of energy demand cannot be matched by energy production and power grid updateModeling Energy Demand Aggregators for Residential Consumers G. Di Bella, L. Giarr`e, M. Ippolito, A. Jean-Marie, G. Neglia and I. Tinnirello § January 2, 2014 Abstract Energy demand aggregators

Paris-Sud XI, Université de

95

Concentration efficiency of doping in phosphors: Investigation of the copper-and aluminum-doped zinc sulfide  

E-Print Network [OSTI]

Concentration efficiency of doping in phosphors: Investigation of the copper- and aluminum October 2003 We studied the effect of dopant concentration in ZnS:Cu, Al phosphor. Photoluminescent PL intensity of the chemically etched phosphor particles increased up to 140%, which proved the existence

Grujicic, Mica

96

Rechargeable zinc cell with alkaline electrolyte which inhibits shape change in zinc electrode  

DOE Patents [OSTI]

An improved rechargeable zinc cell is described comprising a zinc electrode and another electrode such as, for example, a nickel-containing electrode, and having an electrolyte containing KOH and a combination of KF and K[sub 2]CO[sub 3] salts which inhibits shape change in the zinc electrode, i.e., the zinc electrode exhibits low shape change, resulting in an improved capacity retention of the cell over an number of charge-discharge cycles, while still maintaining high discharge rate characteristics. 8 figures.

Adler, T.C.; McLarnon, F.R.; Cairns, E.J.

1994-04-12T23:59:59.000Z

97

Hydrogen sulfide spatial distribution and exposure in deep-pit swine housing.  

E-Print Network [OSTI]

??The objectives of this research focus on investigating spatial distribution of hydrogen sulfide gas associated with manure removal and agitation events in deep-pit swine production… (more)

Swestka, Randy John

2010-01-01T23:59:59.000Z

98

Removal of Hydrogen Sulfide from Landfill Gas Using a Solar Regenerable Adsorbent.  

E-Print Network [OSTI]

??Landfill gas is a complex mix of gases, containing methane, carbon dioxide, nitrogen and hydrogen sulfide, created by the action of microorganisms within the landfill.… (more)

Kalapala, Sreevani

2014-01-01T23:59:59.000Z

99

Quantum cascade laser spectrometer for trace-gas detection of exhaled Carbonyl Sulfide  

Science Journals Connector (OSTI)

Simultaneous concentration measurements of exhaled carbonyl sulfide and carbon dioxide were demonstrated using a pulsed quantum cascade laser based gas sensor. This sensor has...

Wysocki, Gerard; So, Stephen; McCurdy, Matt; Roller, Chad; Weidmann, Damien; Kosterev, Anatoliy a; Frantz, J Patrick; Curl, Robert F; Tittel, Frank K

100

E-Print Network 3.0 - antimony sulfide thin Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The strata-bound, sulfide- and ... Source: USGS Western Region Coastal and Marine Geology Collection: Geosciences 77 Experimental partitioning of uranium between liquid...

Note: This page contains sample records for the topic "zinc sulfide aggregation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Costs of chronic waterborne zinc exposure and the consequences of zinc acclimation on the gill/zinc interactions of rainbow trout in hard and soft water  

SciTech Connect (OSTI)

Juvenile rainbow trout were exposed to zinc in both moderately hard water and soft water for 30 d. Only the 450 {micro}g/L zinc-exposed fish experienced significant mortality. Zinc exposure caused no effect on growth rate, but growth affected tissue zinc levels. Whole body zinc levels were elevated, but gill sand liver showed no consistent increases relative to controls over the 30 d. Therefore, tissue zinc residues were not a good indicator of chronic zinc exposure. After the 30-d exposure, physiological function tests were performed. Zinc was 5.4 times more toxic in soft water. All zinc-exposed trout had acclimated to the metal, as seen by an increase in the LC50 of 2.2 to 3.9 times over that seen in control fish. Physiological costs related to acclimation appeared to be few. Zinc exposure had no effect on whole body Ca{sup 2+} or Na{sup +} levels, on resting or routine metabolic rates, or on fixed velocity sprint performance. However, critical swimming speed (U{sub Crit}) was significantly reduced in zinc-exposed fish, an effect that persisted in zinc-free water. Using radioisotopic techniques to distinguish new zinc incorporation, the gills were found to possess two zinc pools: a fast turnover pool and a slow turnover pool. The fast pool was much larger in soft water than in hard water, but at most it accounted for < 3.5% of the zinc content of the gills. The size of the slow pool was unknown, but its loading rate was faster in soft water. Chronic zinc exposure was found to increase the size of the fast pool and to increase the loading rate of the slow pool.

Alsop, D.H.; McGeer, J.C.; McDonald, D.G.; Wood, C.M. [McMaster Univ., Hamilton, Ontario (Canada). Dept. of Biology

1999-05-01T23:59:59.000Z

102

In Situ Observation of Directed Nanoparticle Aggregation During...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Observation of Directed Nanoparticle Aggregation During the Synthesis of Ordered Nanoporous Metal in Soft Templates. In Situ Observation of Directed Nanoparticle Aggregation During...

103

Fabrication of water-soluble gold nanoparticle aggregates  

E-Print Network [OSTI]

Mixed monolayer protected gold nanoparticles were linked using octanedithiol to form aggregates containing hundreds of nanoparticles. These aggregates are an interesting material, posing potential applications in the fields ...

Bennett, Samantha E

2006-01-01T23:59:59.000Z

104

Zinc and Health: Current Status and Future Directions Zinc Transport in the Brain: Routes of Zinc Influx and Efflux in Neurons1,2  

E-Print Network [OSTI]

homeostasis. J. Nutr. 130: 1484S--1487S, 2000. KEY WORDS: zinc ion transport heavy metal ions trace and that mediate extracellular zinc toxicity and (3) a plasma membrane transporter potentially present in all elements metal transporters rat Large amounts of zinc are present in the brain, yet very little

105

(Data in thousand metric tons of zinc content unless otherwise noted) Domestic Production and Use: The value of zinc mined in 2006, based on contained zinc recoverable from  

E-Print Network [OSTI]

186 ZINC (Data in thousand metric tons of zinc content unless otherwise noted) Domestic Production accounted for about 80% of total U.S. production. Two primary and 12 large- and medium-sized secondary, and rubber industries. Major coproducts of zinc mining and smelting, in order of decreasing tonnage, were

106

(Data in thousand metric tons of zinc content unless otherwise noted) Domestic Production and Use: The value of zinc mined in 2004, based on contained zinc recoverable from  

E-Print Network [OSTI]

188 ZINC (Data in thousand metric tons of zinc content unless otherwise noted) Domestic Production% of total U.S. production. Two primary and 12 large- and medium-sized secondary smelters refined zinc metal were used principally by the agriculture, chemical, paint, and rubber industries. Major coproducts

107

(Data in thousand metric tons of zinc content, unless otherwise noted) Domestic Production and Use: The value of zinc mined in 2003, based on contained zinc recoverable from  

E-Print Network [OSTI]

188 ZINC (Data in thousand metric tons of zinc content, unless otherwise noted) Domestic Production three-fourths of total U.S. production. Two primary and 12 large- and medium-sized secondary smelters uses. Zinc compounds and dust were used principally by the agriculture, chemical, paint, and rubber

108

(Data in thousand metric tons of zinc content unless otherwise noted) Domestic Production and Use: The value of zinc mined in 2005, based on contained zinc recoverable from  

E-Print Network [OSTI]

190 ZINC (Data in thousand metric tons of zinc content unless otherwise noted) Domestic Production accounted for 86% of total U.S. production. Two primary and 12 large- and medium-sized secondary smelters uses. Zinc compounds and dust were used principally by the agriculture, chemical, paint, and rubber

109

Small Generator Aggregation (Maine) | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Generator Aggregation (Maine) Generator Aggregation (Maine) Small Generator Aggregation (Maine) < Back Eligibility Agricultural Commercial Construction Fed. Government Fuel Distributor General Public/Consumer Industrial Installer/Contractor Institutional Investor-Owned Utility Local Government Low-Income Residential Multi-Family Residential Municipal/Public Utility Nonprofit Residential Retail Supplier Rural Electric Cooperative Schools State/Provincial Govt Systems Integrator Transportation Tribal Government Utility Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Buying & Making Electricity Water Home Weatherization Solar Wind Program Info State Maine Program Type Green Power Purchasing Provider Public Utilities Commission This section establishes requirements for electricity providers to purchase

110

Improved oxidation sulfidation resistance of Fe-Cr-Ni alloys  

DOE Patents [OSTI]

High temperature resistance of Fe-Cr-Ni alloy compositions to oxidative and/or sulfidative conditions is provided by the incorporation of about 1 to 8 wt % of Zr or Nb and results in a two-phase composition having an alloy matrix as the first phase and a fine grained intermetallic composition as the second phase. The presence and location of the intermetallic composition between grains of the matrix provides mechanical strength, enhanced surface scale adhesion, and resistance to corrosive attack between grains of the alloy matrix at temperatures of 500 to 1000/sup 0/C.

Natesan, K.; Baxter, D.J.

1983-07-26T23:59:59.000Z

111

Green Power Network: Community Choice Aggregation (CCA)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Community Choice Aggregation (CCA) Community Choice Aggregation (CCA) Community choice aggregation (CCA) is a state policy that enables local governments to aggregate electricity demand within their jurisdictions in order to procure alternative energy supplies while maintaining the existing electricity provider for transmission and distribution services. Many states passed CCA laws as part of electric restructuring legislation in the late 1990s and early 2000s. States that have passed CCA laws include California (2002), Illinois (2009), Massachusetts (1997), New Jersey (2003), Ohio (1999), and Rhode Island (1997). There are many reasons that a community may choose to develop a CCA, including the option to purchase more green power, reduce electricity cost, and provide power from more local sources.

112

Sulfur isotope and trace element data from ore sulfides in the Noranda district (Abitibi, Canada): implications for volcanogenic massive sulfide deposit genesis  

Science Journals Connector (OSTI)

We examine models for volcanogenic massive sulfide (VMS) mineralization in the ~2.7-Ga Noranda camp, Abitibi subprovince, Superior Province, Canada, using a combination of multiple sulfur isotope and trace ele...

Elizabeth R. Sharman; Bruce E. Taylor; William G. Minarik…

2014-10-01T23:59:59.000Z

113

Atmospheric Environment 42 (2008) 33153331 Measurement and analysis of ammonia and hydrogen sulfide  

E-Print Network [OSTI]

; Hydrogen sulfide; Swine barns; CAFOs 1. Introduction Changes in livestock production methods in the USAtmospheric Environment 42 (2008) 3315­3331 Measurement and analysis of ammonia and hydrogen, where NH3­N ¼ (14 17)NH3) and hydrogen sulfide (H2S) were measured from a finishing swine confinement

Aneja, Viney P.

114

HYDROGEN SULFIDE KINETICS ON PEM FUEL CELL ELECTRODES V. A. Sethuramana  

E-Print Network [OSTI]

HYDROGEN SULFIDE KINETICS ON PEM FUEL CELL ELECTRODES V. A. Sethuramana , L. A. Wiseb , S for the poisoning kinetics of hydrogen sulfide (H2S) on composite solid polymer electrolyte Pt (SPE-Pt) electrode) fuel cells, there is much less in the literature on H2S poisoning. Uribe et al showed

Sethuraman, Vijay A.

115

Dielectric characterization of unstabilized aggregate base materials  

E-Print Network [OSTI]

of the material, water ingress, and ambient temperature (1 0, 11). Moisture Susceptibility Research studies in Texas and Finland have demonstrated that moisture susceptibility is related to the suction properties of soils and aggregates (12, 13). Soil suction.... Research studies in Finland have reported reductions in resilient modulus of up to 75 percent from the dry to the wet states for some poorly performing aggregates (12). For these materials, the extent to which water ingress causes damage is dependent...

Guthrie, William Spencer

1999-01-01T23:59:59.000Z

116

Hydrothermal Synthesis of Pure r-Phase Manganese(II) Sulfide without the Use of Organic Reagents  

E-Print Network [OSTI]

Articles Hydrothermal Synthesis of Pure r-Phase Manganese(II) Sulfide without the Use of Organic for finding carbon-free synthesis methods for metal sulfides. The decomposition of organosulfur, such as manganese sulfide (MnS). Here we report a hydrothermal synthesis method for the formation of MnS in which

117

Modeling of Syngas Reactions and Hydrogen Generation Over Sulfides  

SciTech Connect (OSTI)

The objective of the research is to analyze pathways of reactions of hydrogen with oxides of carbon over sulfides, and to predict which characteristics of the sulfide catalyst (nature of metal, defect structure) give rise to the lowest barriers toward oxygenated hydrocarbon product. Reversal of these pathways entails the generation of hydrogen, which is also proposed for study. In this first year of study, adsorption reactions of H atoms and H{sub 2} molecules with MoS{sub 2}, both in molecular and solid form, have been modeled using high-level density functional theory. The geometries and strengths of the adsorption sites are described and the methods used in the study are described. An exposed MO{sup IV} species modeled as a bent MoS{sub 2} molecule is capable of homopolar dissociative chemisorption of H{sub 2} into a dihydride S{sub 2}MoH{sub 2}. Among the periodic edge structures of hexagonal MoS{sub 2}, the (1{bar 2}11) edge is most stable but still capable of dissociating H{sub 2}, while the basal plane (0001) is not. A challenging task of theoretically accounting for weak bonding of MoS{sub 2} sheets across the Van der Waals gap has been addressed, resulting in a weak attraction of 0.028 eV/MoS{sub 2} unit, compared to the experimental value of 0.013 eV/MoS{sub 2} unit.

Kamil Klier; Jeffery A. Spirko; Michael L. Neiman

2002-09-17T23:59:59.000Z

118

Targeted sensors for investigating mobile Zinc in biology  

E-Print Network [OSTI]

Chapter 1. Sensing Strategies for Detection of Mobile Zinc. Mobile zinc plays important physiological roles in areas such as the hippocampus, prostate, and pancreas. A better understanding of the distribution of intracellular ...

Chyan, Wen, S.B. Massachusetts Institute of Technology

2013-01-01T23:59:59.000Z

119

Characterization of a plasma membrane zinc transporter in rat brain  

E-Print Network [OSTI]

Ireland Ltd. Keywords: Ion transport; Membrane vesicles; Excitotoxicity; Zinc homeostasis; TransitionCharacterization of a plasma membrane zinc transporter in rat brain Robert A. Colvin* Department transport in the brain. This report provides convincing evidence of a zinc transporter in plasma membrane

120

Regenerative zinc/air and zinc/ferricyanide batteries for stationary power applications  

SciTech Connect (OSTI)

The authors report a novel configuration for a zinc-particle, packed-bed anode in which an open structure of high hydraulic permeability is maintained indefinitely in a cell with closely spaced walls by the formation of particle bridges and associated gaps. The configuration minimizes electrolyte pumping costs, allows rapid refueling and partial recharge, and provides for 100% zinc consumption. This approach benefits zinc/air fuel batteries by allowing nearly continuous operation and fuel recycle without commercial infrastructure; it benefits Zn/[Fe(CN){sub 6}]{sup {minus}3} batteries by eliminating shape-change and polarization problems found with planar anodes.

Cooper, J.F.; Keene, L.E.; Noring, J.; Maimoni, A.; Peterman, K.

1994-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "zinc sulfide aggregation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Theoretical Studies on Heavy Metal Sulfides in Solution  

SciTech Connect (OSTI)

'Calculating the stabilities, Raman and UV spectra and acidities of As sulfides in aqueous solution', J. A. Tossell, M. D. Zimmermann and G. R. Helz. Some of the Raman spectra obtained by reacting aqueous As(OH)3 with aqueous bisulfide are shown, taken from Wood, et al. (2002). To interpret these spectra we have carried out an extensive series of calculations, detailed for the case of AsS(SH){sub 2}{sup -} in Table 1 below. By employing state of the art quantum chemical techniques to determine gas-phase harmonic and anharmonic frequencies and solution phase corrections we can accurately match features in the experimental spectrum shown in the top figure. The AsS(SH){sub 2}{sup -}...22 H{sub 2}O nanocluster employed is shown in the lower figure. For this species we have calculated the equilibrium structure and the harmonic vibrational spectrum at the CBSB7 B3LYP level. For the free solute species AsS(SH){sub 2}{sup -} we have carried out a whole series of calculations, evaluating harmonic and anharmonic vibrational frequencies at a number of different quantum mechanical levels. In the spectra below, Fig. 3 and Fig. 5 from Wood, et al. (2002), the features around 700-800 cm{sup -1} are attributed to As-O stretches and those around 350-450 cm{sup -1} to As-S stretches. In the nanocluster an isolated vibrational feature is observed at 425 cm{sup -1}, an As=S stretch, close to the value (415 cm{sup -1}) determined by Wood, et al. (2002). Analysis of the calculated frequencies for AsS(SH){sub 2}{sup -} within a polarizable continuum model yields a similar result. Taking the highest level harmonic results, obtained from a CCSD calculation, and adding anharmonic and PCM corrections at the B3LYP level (designated (3) + (5) - (1) in Table 1) gives a frequency for the intense high frequency As=S stretch within 15 cm{sup -1} of experiment. Although there is still interesting work to be done on the stabilities and the Raman and UV spectra of As sulfides, most of the basic concepts have been worked out and we are therefore proposing to move to a new area, that of humic acids (while continuing our studies complexes formed by As oxides and sulfides, now applied to functional groups present in humic acids).

Tossell, John A.

2007-10-31T23:59:59.000Z

122

Design of maximum density aggregate grading  

Science Journals Connector (OSTI)

An aggregate grading that yields maximum solid density and maximum particle interlock is highly desirable for both bound mixtures, such as asphalt concrete and plain and reinforced concrete, and for unbound mixtures such as those used in base courses. Maximum particle interlock leads to high strength. Whereas minimum voids in a certain material composition is conducive to high strength and low compression. Aggregate grading may be obtained, for instance, from the ASTM, which is based on experience or may be designed according to Lees’ method. In the present work five different types of aggregates were used, each with a variety of chosen grading. It was found that Lees’ method produced the lowest porosity of all types of aggregates as well as for the various employed gradings. Lees’ rational method of aggregate grading, however, is a very lengthy and time-consuming procedure. Therefore, programming of Lees’ method is an essential step to make such an excellent method available to practicing engineers. A program named ‘ratmix’ was developed and has incorporated 58 design graphs of the Lees’ method. ratmix is a comprehensive program for Lees’ rational method; it conducts interpolation for intermediate points within the design graphs as well as between graphs of different properties.

Yahia A Abdel-Jawad; Waddah Salman Abdullah

2002-01-01T23:59:59.000Z

123

A preliminary study of zinc-catalyzed polycarbonate production  

E-Print Network [OSTI]

Company. Adipic acid was pruchased fron MCB Manufacturing Chemists, Inc. 12 2. Synthesized Reagents a. Zinc Adipate from Zinc metal lb. 4 g (0. 251 mol) of zinc filings were dissolved in 50 mL of concentrated hydrochloric acid, generating a solution... Figure 12. Two identical catalytic runs using the same batch of Strem catalyst A comparison between the zinc glutarate and zinc adipate catalyst was then made by comparing the rates of production of the polymer and the cyclic carbonate. The rates...

Griffith, Amy Elizabeth

1992-01-01T23:59:59.000Z

124

Lithium sulfide compositions for battery electrolyte and battery electrode coatings  

SciTech Connect (OSTI)

Method of forming lithium-containing electrolytes are provided using wet chemical synthesis. In some examples, the lithium containing electrolytes are composed of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7. The solid electrolyte may be a core shell material. In one embodiment, the core shell material includes a core of lithium sulfide (Li.sub.2S), a first shell of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7, and a second shell including one of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7 and carbon. The lithium containing electrolytes may be incorporated into wet cell batteries or solid state batteries.

Liang, Chengdu; Liu, Zengcai; Fu, Wujun; Lin, Zhan; Dudney, Nancy J; Howe, Jane Y; Rondinone, Adam J

2014-10-28T23:59:59.000Z

125

Hydrogen Production from Hydrogen Sulfide in IGCC Power Plants  

SciTech Connect (OSTI)

IGCC power plants are the cleanest coal-based power generation facilities in the world. Technical improvements are needed to help make them cost competitive. Sulfur recovery is one procedure in which improvement is possible. This project has developed and demonstrated an electrochemical process that could provide such an improvement. IGCC power plants now in operation extract the sulfur from the synthesis gas as hydrogen sulfide. In this project H{sub 2}S has been electrolyzed to yield sulfur and hydrogen (instead of sulfur and water as is the present practice). The value of the byproduct hydrogen makes this process more cost effective. The electrolysis has exploited some recent developments in solid state electrolytes. The proof of principal for the project concept has been accomplished.

Elias Stefanakos; Burton Krakow; Jonathan Mbah

2007-07-31T23:59:59.000Z

126

Changes in Dimethyl Sulfide Oceanic Distribution due to Climate Change  

SciTech Connect (OSTI)

Dimethyl sulfide (DMS) is one of the major precursors for aerosols and cloud condensation nuclei in the marine boundary layer over much of the remote ocean. Here they report on coupled climate simulations with a state-of-the-art global ocean biogeochemical model for DMS distribution and fluxes using present-day and future atmospheric CO{sub 2} concentrations. They find changes in zonal averaged DMS flux to the atmosphere of over 150% in the Southern Ocean. This is due to concurrent sea ice changes and ocean ecosystem composition shifts caused by changes in temperature, mixing, nutrient, and light regimes. The largest changes occur in a region already sensitive to climate change, so any resultant local CLAW/Gaia feedback of DMS on clouds, and thus radiative forcing, will be particularly important. A comparison of these results to prior studies shows that increasing model complexity is associted with reduced DMS emissions at the equator and increased emissions at high latitudes.

Cameron-Smith, P; Elliott, S; Maltrud, M; Erickson, D; Wingenter, O

2011-02-16T23:59:59.000Z

127

Metal?organic frameworks for the storage and delivery of biologically active hydrogen sulfide  

SciTech Connect (OSTI)

Hydrogen sulfide is an extremely toxic gas that is also of great interest for biological applications when delivered in the correct amount and at the desired rate. Here we show that the highly porous metal-organic frameworks with the CPO-27 structure can bind the hydrogen sulfide relatively strongly, allowing the storage of the gas for at least several months. Delivered gas is biologically active in preliminary vasodilation studies of porcine arteries, and the structure of the hydrogen sulfide molecules inside the framework has been elucidated using a combination of powder X-ray diffraction and pair distribution function analysis.

Allan, Phoebe K.; Wheatley, Paul S.; Aldous, David; Mohideen, M. Infas; Tang, Chiu; Hriljac, Joseph A.; Megson, Ian L.; Chapman, Karena W.; De Weireld, Guy; Vaesen, Sebastian; Morris, Russell E. (St Andrews)

2012-04-02T23:59:59.000Z

128

Zinc ?2-Glycoprotein: A Multidisciplinary Protein  

Science Journals Connector (OSTI)

...in the seminal fluid (18). Hale et al. (44) determined the...Electrophoresis 2007;28:1989-96. 44 Hale LP, Price DT, Sanchez LM...quality index, ATP utilization, gas exchange, and ionic balance...Diabetes 2003;52:2175-81. 136 Hale LP. Zinc alpha-2-glycoprotein...

Md. Imtaiyaz Hassan; Abdul Waheed; Savita Yadav; Tej P. Singh; and Faizan Ahmad

2008-06-01T23:59:59.000Z

129

Process for preparing zinc oxide-based sorbents  

DOE Patents [OSTI]

The disclosure relates to zinc oxide-based sorbents, and processes for preparing and using them. The sorbents are preferably used to remove one or more reduced sulfur species from gas streams. The sorbents comprise an active zinc component, optionally in combination with one or more promoter components and/or one or more substantially inert components. The active zinc component is a two phase material, consisting essentially of a zinc oxide (ZnO) phase and a zinc aluminate (ZnAl.sub.2O.sub.4) phase. Each of the two phases is characterized by a relatively small crystallite size of typically less than about 500 Angstroms. Preferably the sorbents are prepared by converting a precursor mixture, comprising a precipitated zinc oxide precursor and a precipitated aluminum oxide precursor, to the two-phase, active zinc oxide containing component.

Gangwal, Santosh Kumar (Cary, NC); Turk, Brian Scott (Durham, NC); Gupta, Raghubir Prasad (Durham, NC)

2011-06-07T23:59:59.000Z

130

200 North Aggregate Area source AAMS report  

SciTech Connect (OSTI)

This report presents the results of an aggregate area management study (AAMS) for the 200 North Aggregate Area in the 200 Areas of the US Department of Energy (DOE) Hanford Site in Washington State. This scoping level study provides the basis for initiating Remedial Investigation/Feasibility Study (RI/FS) activities under the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) or Resource Conservation and Recovery Act (RCRA) Facility Investigations (RFI) and Corrective Measures Studies (CMS) under RCRA. This report also integrates select RCRA treatment, storage, or disposal (TSD) closure activities with CERCLA and RCRA past practice investigations.

Not Available

1993-06-01T23:59:59.000Z

131

Small file aggregation in a parallel computing system  

DOE Patents [OSTI]

Techniques are provided for small file aggregation in a parallel computing system. An exemplary method for storing a plurality of files generated by a plurality of processes in a parallel computing system comprises aggregating the plurality of files into a single aggregated file; and generating metadata for the single aggregated file. The metadata comprises an offset and a length of each of the plurality of files in the single aggregated file. The metadata can be used to unpack one or more of the files from the single aggregated file.

Faibish, Sorin; Bent, John M.; Tzelnic, Percy; Grider, Gary; Zhang, Jingwang

2014-09-02T23:59:59.000Z

132

E-Print Network 3.0 - anaerobic sulfide oxidation Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

marsh microbial mat geochemistry Summary: 1, p. 114-160. KAMP A., STIEF P. & SCHULZ-VOGT H.N. (2006).- Anaerobic sulfide oxidation... to facultative anaerobic spirochetes may...

133

Three-dimensional defect characterization : focused ion beam tomography applied to tin sulfide thin films  

E-Print Network [OSTI]

Porosity is postulated to be one of the reasons for the low efficiency of tin sulfide-based devices. This work is a preliminary investigation of the effects of two film growth parameters deposition rate and substrate ...

Youssef, Amanda

2014-01-01T23:59:59.000Z

134

Elemental and isotopic compositions of the hydrothermal sulfide on the East Pacific Rise near 13°N  

Science Journals Connector (OSTI)

The mineralogical, elemental, and isotopic characteristics of a hydrothermal sulfide sample from one dredge station (12°42.30?N, 103°54.48?W, water depth 2655 m) on the East Pacific Rise near 13°N were analyze...

ZhiGang Zeng; DaiGeng Chen; XueBo Yin; XiaoYuan Wang…

2010-02-01T23:59:59.000Z

135

Solar Thermal Energy Cycle Based on Sulfur and Sulfide Oxidizing Bacteria  

Science Journals Connector (OSTI)

New solar energy technologies for the production of biomass for the purpose of synthesizing methane, hydrogen and proteins could be based on the solar generation of the inorganic energy source (Fe2+, metal sulfid...

C. C. Bärtels; H. Tributsch

1991-01-01T23:59:59.000Z

136

Photoelectrochemical Hydrogen Production on InP Nanowire Arrays with Molybdenum Sulfide Electrocatalysts  

Science Journals Connector (OSTI)

Photoelectrochemical Hydrogen Production on InP Nanowire Arrays with Molybdenum Sulfide Electrocatalysts ... Several semiconductor nanowire systems, synthesized by different methods, have been investigated by photoelectrochemistry. ... power available from the hydrogen produced and the power supplied by an external source. ...

Lu Gao; Yingchao Cui; Jia Wang; Alessandro Cavalli; Anthony Standing; Thuy T. T. Vu; Marcel A. Verheijen; Jos E. M. Haverkort; Erik P. A. M. Bakkers; Peter H. L. Notten

2014-05-29T23:59:59.000Z

137

Sodium sulfide leaching of low-grade jamesonite concentrate in production of sodium pyroantimoniate  

Science Journals Connector (OSTI)

Sodium sulfide leaching of a low-grade jamesonite concentrate in the production of sodium pyroantimoniate through the air oxidation process and the influencing factors on the leaching rate of antimony were...

Tian-zu Yang PhD; Ming-xi Jiang…

2005-06-01T23:59:59.000Z

138

E-Print Network 3.0 - arsenic sulfides Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the Initial Reports and Scientific Results portions of Vol- Summary: -14 active zones, geology, A:18-19 age sulfides, B:111-117 vs. uranium content, B:113-114 alteration...

139

E-Print Network 3.0 - americium sulfides Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the Initial Reports and Scientific Results portions of Vol- Summary: -14 active zones, geology, A:18-19 age sulfides, B:111-117 vs. uranium content, B:113-114 alteration...

140

inactivation of viral aggregates during water treatment  

E-Print Network [OSTI]

treatment. MS2 virus used as the model organism. peracetic acid (PAA) chosen as disinfectant (400 mM) were used to study the pH effect on disinfection rate constants of PAA/L PAA; all experiments showed pseudo-first order kinetics (fig. 1b): biggest aggregates

Note: This page contains sample records for the topic "zinc sulfide aggregation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Biosynthesis and urinary excretion of methyl sulfonium derivatives of the sulfur mustard analog, 2-chloroethyl ethyl sulfide, and other thioethers  

SciTech Connect (OSTI)

Thioether methyltransferase was previously shown to catalyze the S-adenosylmethionine-dependent methylation of diemthyl selenide, dimethyl telluride, and various thioethers to produce the corresponding methyl onium ions. In this paper we show that the following thioethers are also substrates for this enzyme in vitro: 2-hydroxyethyl ethyl sulfide, 2-chloroethyl ethyl sulfide, thiodiglycol, t-butyl sulfide, and isopropyl sulfide. To demonstrate thioether methylation in vivo, mice were injected with (methyl-{sup 3}H)methionine plus different thioethers, and extracts of lungs, livers, kidneys, and urine were analyzed by high-performance liquid chromatography for the presence of ({sup 3}H)methyl sulfonium ions. The following thioethers were tested, and all were found to be methylated in vivo: dimethyl sulfide, diethyl sulfide, methyl n-propyl sulfide, tetrahydrothiophene, 2-(methylthio)ethylamine, 2-hydroxyethyl ethyl sulfide, and 2-chloroethyl ethyl sulfide. This supports our hypothesis that the physiological role of thioether methyltransferase is to methylate seleno-, telluro-, and thioethers to more water-soluble onium ions suitable for urinary excretion. Conversion of the mustard gas analog, 2-chloroethyl ethyl sulfide, to the methyl sulfonium derivative represents a newly discovered mechanism for biochemical detoxification of sulfur mustards, as this conversion blocks formation of the reactive episulfonium ion that is the ultimate alkylating agent for this class of compounds.

Mozier, N.M.; Hoffman, J.L. (Univ. of Louisville, KY (USA))

1990-12-01T23:59:59.000Z

142

A study of the reactions of arsinic and arsonic acids with hydrogen sulfide and hydrogen selenide  

E-Print Network [OSTI]

A STUDY OF THE REACTIONS OF ARSINIC AND ARSONIC ACIDS WITH HYDROGEN SULFIDE AND HYDROGEN SELENIDE by CYNTHIA ANNETTE APPLEGATE Submitted to the Graduate College of Texas AkM University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE August 1986 Major Subject: Chemistry A STUDY OF THE REACTIONS OF ARSINIC AND ARSONIC ACIDS WITH HYDROGEN SULFIDE AND HYDROGEN SELENIDE A Thesis by CYNTHIA ANNETTE APPLEGATE Approved as to style and content by: Ralph A. ngaro...

Applegate, Cynthia Annette

2012-06-07T23:59:59.000Z

143

Metal sulfide and rare-earth phosphate nanostructures and methods of making same  

DOE Patents [OSTI]

The present invention provides a method of producing a crystalline metal sulfide nanostructure. The metal is a transitional metal or a Group IV metal. In the method, a porous membrane is placed between a metal precursor solution and a sulfur precursor solution. The metal cations of the metal precursor solution and sulfur ions of the sulfur precursor solution react, thereby producing a crystalline metal sulfide nanostructure.

Wong, Stanislaus; Zhang, Fen

2014-05-13T23:59:59.000Z

144

Distributed Audit Secure Data Aggregation for Wireless Sensor Networks  

Science Journals Connector (OSTI)

Data aggregation can reduce the communication overhead and energy expenditure of sensor nodes, as well as ... injection attacks. This paper proposes a distributed audit secure data aggregation protocol. The aggre...

Zhengdao Zhang; Zhiping Zhou

2013-01-01T23:59:59.000Z

145

Optical activity of electronically delocalized molecular aggregates: Nonlocal response formulation  

E-Print Network [OSTI]

Optical activity of electronically delocalized molecular aggregates: Nonlocal response formulation and optical rotation in small optically active molecules, larger conjugated molecules, and molecular aggregates is developed using spatially nonlocal electric and magnetic optical response tensors (r

Mukamel, Shaul

146

(Data in thousand metric tons of zinc content unless otherwise noted) Domestic Production and Use: The value of zinc mined in 2012, based on zinc contained in concentrate, was about  

E-Print Network [OSTI]

188 ZINC (Data in thousand metric tons of zinc content unless otherwise noted) Domestic Production uses. Zinc compounds and dust were used principally by the agricultural, chemical, paint, and rubber industries. Salient Statistics--United States: 2008 2009 2010 2011 2012 e Production: Mine, zinc in ore

147

(Data in thousand metric tons of zinc content unless otherwise noted) Domestic Production and Use: The value of zinc mined in 2010, based on zinc contained in concentrate, was about  

E-Print Network [OSTI]

188 ZINC (Data in thousand metric tons of zinc content unless otherwise noted) Domestic Production uses. Zinc compounds and dust were used principally by the agriculture, chemical, paint, and rubber, and germanium. Salient Statistics--United States: 2006 2007 2008 2009 2010 e Production: Mine, zinc in ore

148

(Data in thousand metric tons of zinc content unless otherwise noted) Domestic Production and Use: The value of zinc mined in 2011, based on zinc contained in concentrate, was about  

E-Print Network [OSTI]

188 ZINC (Data in thousand metric tons of zinc content unless otherwise noted) Domestic Production uses. Zinc compounds and dust were used principally by the agriculture, chemical, paint, and rubber industries. Salient Statistics--United States: 2007 2008 2009 2010 2011 e Production: Mine, zinc in ore

149

(Data in thousand metric tons of zinc content unless otherwise noted) Domestic Production and Use: The value of zinc mined in 2007, based on zinc contained in concentrate, was about  

E-Print Network [OSTI]

190 ZINC (Data in thousand metric tons of zinc content unless otherwise noted) Domestic Production U.S. production. One primary and 12 large- and medium-sized secondary smelters refined zinc metal by the agriculture, chemical, paint, and rubber industries. Major coproducts of zinc mining and smelting, in order

150

(Data in thousand metric tons of zinc content unless otherwise noted) Domestic Production and Use: The value of zinc mined in 2009, based on zinc contained in concentrate, was about  

E-Print Network [OSTI]

184 ZINC (Data in thousand metric tons of zinc content unless otherwise noted) Domestic Production uses. Zinc compounds and dust were used principally by the agriculture, chemical, paint, and rubber, and germanium. Salient Statistics--United States: 2005 2006 2007 2008 2009e Production: Mine, zinc in ore

151

Reduced ternary molybdenum and tungsten sulfides and hydroprocessing catalysis therewith  

DOE Patents [OSTI]

New amorphous molybdenum/tungsten sulfides with the general formula M.sup.n+.sub.2x/n (L.sub.6 S.sub.8)S.sub.x, where L is molybdenum or tungsten and M is a ternary metal, has been developed. Characterization of these amorphous materials by chemical and spectroscopic methods (IR, Raman, PES) shows that the (M.sub.6 S.sub.8).sup.0 cluster units are present. Vacuum thermolysis of the amorphous Na.sub.2x (Mo.sub.6 S.sub.8)S.sub.x .multidot.yMeOH first produces poorly crystalline NaMo.sub.6 S.sub.8 by disproportionation at 800.degree. C. and well-crystallized NaMo.sub.6 S.sub.8 at .gtoreq. 900.degree. C. Ion-exchange of the sodium material in methanol with soluble M.sup.2+ and M.sup.3+ salts (M=Sn, Co, Ni, Pb, La, Ho) produces the M.sup.n+.sub.2x/n (Mo.sub.6 S.sub.8)S.sub.x .multidot.yMeOH compounds. Additionally, the new reduced ternary molybdenum sulfides with the general formula M.sup.n+.sub.2x/n Mo.sub.6 S.sub.8+x (MeOH).sub.y ›MMOS! (M=Sn, Co, Ni) is an effective hydrodesulfurization (HDS) catalyst both as-prepared and after a variety of pretreatment conditions. Under specified pretreatment conditions with flowing hydrogen gas, the SnMoS type catalyst can be stabilized, and while still amorphous, can be considered as "Chevrel phase-like" in that both contain Mo.sub.6 S.sub.8 cluster units. Furthermore, the small cation NiMoS and CoMoS type pretreated catalyst showed to be very active HDS catalysts with rates that exceeded the model unpromoted and cobalt-promoted MoS.sub.2 catalysts.

Hilsenbeck, Shane J. (Ames, IA); McCarley, Robert E. (Ames, IA); Schrader, Glenn L. (Ames, IA); Xie, Xiaobing (College Station, TX)

1999-02-16T23:59:59.000Z

152

(Data in thousand metric tons of zinc content, unless otherwise noted) Domestic Production and Use: The value of zinc mined in 2000, based on contained zinc recoverable from  

E-Print Network [OSTI]

186 ZINC (Data in thousand metric tons of zinc content, unless otherwise noted) Domestic Production three-fourths of production. Three primary and 12 large- and medium-sized secondary smelters refined compounds and dust were used principally by the agriculture, chemical, paint, and rubber industries. Major

153

Preserving quality of service guarantees in spite of flow aggregation  

Science Journals Connector (OSTI)

We investigate how quality of service may be guaranteed to a flow of packets in the presence of flow aggregation. For efficiency, multiple flows, known as the constituent flows, are merged together resulting in a single aggregate flow. After the network ... Keywords: Flow aggregation, quality of service, real-time scheduling

Jorge Arturo Cobb

2002-02-01T23:59:59.000Z

154

Thermodynamics and Structure of Peptide-Aggregates at Membrane Surfaces  

E-Print Network [OSTI]

Thermodynamics and Structure of Peptide- Aggregates at Membrane Surfaces INAUGURALDISSERTATION zur. Introduction 01 1.1 ­ Thermodynamics of Protein Aggregation 01 1.2 ­ Formation of Protein Aggregates 03 1 and P-glycoprotein: Connecting Thermodynamics and Membrane Structure with Functional Activity 23 3

Quake, Stephen R.

155

Synthesis and characterization of reduced tungsten sulfide cluster complexes  

SciTech Connect (OSTI)

Reduction of tungsten(IV) chloride with metals was studied in order to find a high-yield and convenient preparation of {alpha}-tungsten (II) chloride. The reduction of tungsten(IV) chloride with iron metal proved to be the most convenient and reliable synthesis, with a good yield of 60%. The reactions between {alpha}-tungsten(II) chloride and sodium hydrosulfide were investigated. Complete substitution of sulfide for chloride in W{sub 6}Cl{sub 8}{sup 4+} was achieved in the presence of sodium n-butoxide in pyridine solution. Single crystals were grown at elevated temperature (200{degrees}C) in pyridine, and the structure of W{sub 6}S{sub 8}(py){sub 6} was determined by single crystal x-ray techniques. The triethylphosphine (PEt{sub 3}) and tetrahydrothiophene (THT) complexes of W{sub 6}S{sub 8} were established by ligand displacement of pyridine in W{sub 6}S{sub 8}(py){sub 6}. Structures for both W{sub 6}S{sub 8}(PEt{sub 3}){sub 6}. 1.44CH{sub 2}Cl{sub 2} and W{sub 6}S{sub 8}(THT){sub 6} were determined by single crystal x-ray diffraction. These molecular complexes of the W{sub 6}S{sub 8} cluster were also characterized by infrared spectroscopy. 86 refs., 19 figs., 22 tabs.

Zhang, Xiang.

1991-06-27T23:59:59.000Z

156

The oceanic cycle and global atmospheric budget of carbonyl sulfide  

SciTech Connect (OSTI)

A significant portion of stratospheric air chemistry is influenced by the existence of carbonyl sulfide (COS). This ubiquitous sulfur gas represents a major source of sulfur to the stratosphere where it is converted to sulfuric acid aerosol particles. Stratospheric aerosols are climatically important because they scatter incoming solar radiation back to space and are able to increase the catalytic destruction of ozone through gas phase reactions on particle surfaces. COS is primarily formed at the surface of the earth, in both marine and terrestrial environments, and is strongly linked to natural biological processes. However, many gaps in the understanding of the global COS cycle still exist, which has led to a global atmospheric budget that is out of balance by a factor of two or more, and a lack of understanding of how human activity has affected the cycling of this gas. The goal of this study was to focus on COS in the marine environment by investigating production/destruction mechanisms and recalculating the ocean-atmosphere flux.

Weiss, P.S.

1994-12-31T23:59:59.000Z

157

Corrosion of iron in acid solutions with hydrogen sulfide  

SciTech Connect (OSTI)

The influence of pH and the concentration of hydrogen sulfide (H{sub 2}S) on corrosion of iron in acid solutions was studied using a potentiostatic polarization method. The alternating current (AC) impedance technique also was used to characterize the active dissolution process of iron. Results showed the dissolution process was accelerated by H{sub 2}S. The anodic dissolution current (i{sub a}) increased with pH and H{sub 2}S concentration with reaction orders of about n{sub pH} = n{sub H{sub 2}s} = 0.25 when the ratio of H{sub 2}S concentration and hydrogen ion (H{sub 3}O{sup +}) concentration was <10{sup 1.5} i{sub a} reached a maximum and became independent of pH and [H{sub 2}S] when [H{sub 2}S]/H{sub 3}O{sup +} > 10{sup 1.5}. The Nyquist diagram corresponding to the active dissolution process in the Tafel range exhibited two capacitive loops in addition to the well-known, high-frequency capacitive loop. A mechanism was proposed to explain the results in which H{sub 2}S chemisorbed first on the electrode surface and then catalyzed the anodic dissolution of iron in two discharging steps.

Cheng, X.L.; Ma, H.Y.; Zhang, J.P.; Chen, X.; Chen, S.H. [Shandong Univ., Jinan (China). Dept. of Chemistry; Yang, H.Q. [Peking Univ. (China). Dept. of Chemistry

1998-05-01T23:59:59.000Z

158

Fluorescent chemosensors for exploring zinc metalloneurochemistry and detecting mercury in aqueous solution  

E-Print Network [OSTI]

Chapter 1. An Introduction to Zinc Metalloneurochemistry and Zinc Detection in Biology. This chapter presents an overview of zinc neurophysiology and pathology, which provides motivation for the design of new tools and ...

Nolan, Elizabeth M. (Elizabeth Marie), 1978-

2006-01-01T23:59:59.000Z

159

E-Print Network 3.0 - acids determines zinc Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

zinc transporter in rat brain Summary: as 15% of brain zinc is sequestered in synap- tic vesicles 3 associated with excitatory amino acid... .41 mM EGTA. Zinc65 caught on...

160

Aggregated Purchasing - A Clean Energy Strategy  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A number of organizations, including municipalities, state and federal agencies, businesses and even religious organizations are leading the way to a renewable energy future by using their collective buying power to purchase green power. The city of Chicago has formed an alliance with 47 other local government agencies to increase their reliance on clean energy sources. As part of this effort, Chicago has installed solar electric systems on a number of the city's buildings, including the Chicago Center for Green Technology shown here. City of Chicago Aggregated Purchasing-A Clean Energy Strategy SOLAR TODAY Aggregated Purchasing-A Clean Energy Strategy by Lori A. Bird and Edward A. Holt November/December 2002 35 Power generated from renewable resources, also known as "green" power, is

Note: This page contains sample records for the topic "zinc sulfide aggregation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Commercial Pecans: Controlling Rosette, Diseases and Zinc Deficiency  

E-Print Network [OSTI]

Pecan losses from diseases and insufficient zinc nutrition can be prevented by following effective grove management practices. Descriptions of diseases and recommendations for controls are included....

Lee, Thomas A.; Krausz, Joseph P.

2006-04-13T23:59:59.000Z

162

Peel, Kate, Dominik Weiss, and Laura Sigg. Zinc isotope ...  

Science Journals Connector (OSTI)

Zinc isotope composition of settling particles as a proxy for biogeochemical processes in lakes: Insights from the eutrophic Lake Greifen, Switzerland. Kate Peel ...

2009-07-03T23:59:59.000Z

163

ORIGIN OF THE AURIFEROUS BARITE-BASE METAL AND GOETHITE STAGES OF THE SUMMITVILLE HIGH SULFIDATION GOLD DEPOSIT, COLORADO, USA.  

E-Print Network [OSTI]

??The Summitville high-sulfidation gold deposit is hosted by a volcanic dome consisting of the South Mountain Quartz Latite that was erupted 23 Ma ago during… (more)

Russin, Teresa Z.

2009-01-01T23:59:59.000Z

164

Evaluation of superpave fine aggregate specification  

E-Print Network [OSTI]

. CHAPTER I INTRODUCTION. . Statement of the Problem. . Objectives. 2 4 II LITERATURE REVIEW. Background. . Characterization of Material Properties. . NAA Flow Test Method. . Flow Rate Method. . ASTM Method D 3398. . Direct Shear Test... nature of the procedure and its similarity to FAA, this test was not used in this study. ASTM Method D 3398 ASTM D 3398 determines an index of aggregate particle shape and texture, I, . It provides an index value to the relative parficle shape...

Chowdhury, Md. Tahjib-Ul-Arif

2012-06-07T23:59:59.000Z

165

NETL: PPII - Commercial Demonstration of the Manufactured Aggregate  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Demonstration Project Documents - Industrial Applications Demonstration Project Documents - Industrial Applications Commercial Demonstration of the Manufactured Aggregate Processing Technology Utilizing Spray Dryer Ash - Project Brief [PDF-72KB] Universal Aggregates, LLC, King George County, VA PROJECT FACT SHEET Commercial Demonstration of the Manufactured Aggregate Processing Technology Utilizing Spray Dryer Ash [PDF-412KB] (Feb 2008) PROGRAM PUBLICATIONS Final Report Commercial Demonstration of the Manufactured Aggregate Processing Technology Utilizing Spray Dryer Absorber Ash [PDF-4.5MB] (Nov 2007) CCT Reports: Project Performance Summaries, Post-Project Assessments, & Topical Reports Commercial Demonstration of the Manufactured Aggregate Processing Technology Utilizing Spray Dryer Ash: A DOE Assessment [PDF-170KB] (Mar 2008)

166

On the friction coefficient of straight-chain aggregates  

E-Print Network [OSTI]

A methodology to calculate the friction coefficient of an aggregate in the continuum regime is proposed. The friction coefficient and the monomer shielding factors, aggregate-average or individual, are related to the molecule-aggregate collision rate that is obtained from the molecular diffusion equation with an absorbing boundary condition on the aggregate surface. Calculated friction coefficients of straight chains are in very good agreement with previous results, suggesting that the friction coefficients may be accurately calculated from the product of the collision rate and an average momentum transfer,the latter being independent of aggregate morphology. Langevin-dynamics simulations show that the diffusive motion of straight-chain aggregates may be described either by a monomer-dependent or an aggregate-average random force, if the shielding factors are appropriately chosen.

Lorenzo Isella; Yannis Drossinos

2010-07-16T23:59:59.000Z

167

Effect of pH, phosphorus, and water-extractable zinc of soil on plant growth and zinc absorption  

E-Print Network [OSTI]

EFFECT OF pH~ PHOSPHORilS, AND WATER-EXTRACTABLE ZINC OF SOIL ON PLANT GROWTH AND ZINC ABSORPT1ON A Thesis Najafali Karimian Submitted to the Graduate College cf Texas ARM University in partial fulfillment of the requirement for the degree... of MASTER OF SCIENCE December 1970 Major Sub ject: Soil Chemistry EFFECT OF pH, PHOSPHORUS, AND WATER-EXTRACTABLE ZINC OF SOIL ON PLANT GROWTH AND ZINC ABSORPTION A Thesis by NajafaIi Karimian Approved as to sty1e and content by: Chairman Committee...

Karimian, Najafali

2012-06-07T23:59:59.000Z

168

E-Print Network 3.0 - artificial zinc finger Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

for creating designer zinc finger Summary: Heterodimeric DNA methyltransferases as a platform for creating designer zinc finger... hypomethylation. The end-to-end fusion of...

169

E-Print Network 3.0 - air zinc increases Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Forms of Zinc in a Smelter- Summary: , and the application of sewage sludge and agrochemicals, soils are increasingly contaminated with zinc. In Switzerland... 2-64 GEOLOGICAL...

170

Glutamine and zinc methionine supplementation to dairy calves  

E-Print Network [OSTI]

into 4 treatment groups with 5 animals each. The calves were fed milk-replacer diets supplemented with 0 or 1% L-glutamine, 1% glycine, or zinc methionine (40 ppm zinc) for a 45-day-period. Next, calves were subjected to intravenous administration...

Simon, Robin Renee

1999-01-01T23:59:59.000Z

171

COPPER AND ZINC DEFICIENCIES TREATMENT BY INTRAMUSCULAR INJECTIONS IN SHEEP  

E-Print Network [OSTI]

COPPER AND ZINC DEFICIENCIES TREATMENT BY INTRAMUSCULAR INJECTIONS IN SHEEP M. LAMAND Claudine LAB in the injection site. Copper per os dosing is efficient for treating deficient animals (Lamand et al., 1969 consuming. Therefore we tried to per- fect a copper and zinc deficiency treatment allowing the injection

Paris-Sud XI, Université de

172

Recent developments in zinc oxide target chemistry  

SciTech Connect (OSTI)

Zinc oxide targets irradiated with high energy protons at the Los Alamos Meson Physics Facility (LAMPF) contain a number of radioactive spallation products in quantities large enough to warrant recovery. This paper describes methods for recovering {sup 7}Be, {sup 46}Sc, and {sup 48}V from such targets and offers suggestions on possible ways to recover additional isotopes. The proposed methods are based on traditional precipitation and ion exchange techniques, are readily adaptable to hot cell use, and produce no hazardous waste components. The products are obtained in moderate to high yields and have excellent radiopurity.

Heaton, R.C.; Taylor, W.A.; Phillips, D.R.; Jamriska, D.J. Sr.; Garcia, J.B.

1994-04-01T23:59:59.000Z

173

Reduced graphene oxide based silver sulfide hybrid films formed at a liquid/liquid interface  

SciTech Connect (OSTI)

Free-standing, ultra-thin films of silver sulfide and reduced graphene oxide (RGO) based silver sulfide hybrids are prepared at a liquid/liquid interface employing in situ chemical reaction strategy. Ag{sub 2}S and RGO?Ag{sub 2}S hybrid films are characterized by various techniques such as UV-visible and photo luminescence spectroscopy, X-ray diffraction and scanning electron microscopy. The morphology of hybrid films consists of Ag{sub 2}S nanocrystals on RGO surface while Ag{sub 2}S films contains branched network of dendritic structures. RGO?Ag{sub 2}S exhibit interesting optical and electrical properties. The hybrid films absorb in the region 500–650 nm and show emission in the red region. A higher conductance is observed for the hybrid films arising from the RGO component. This simple low cost method can be extended to prepare other RGO based metal sulfides.

Bramhaiah, K., E-mail: jsneena@csmr.res.in; John, Neena S., E-mail: jsneena@csmr.res.in [Centre for Soft Matter Research, P.B. No.1329, Jalahalli, Bangalore-560013 (India)

2014-04-24T23:59:59.000Z

174

Experimental partitioning of uranium between liquid iron sulfide and liquid silicate: Implications for radioactivity in the Earth's core  

E-Print Network [OSTI]

Experimental partitioning of uranium between liquid iron sulfide and liquid silicate: Implications Measurable uranium (U) is found in metal sulfide liquids in equilibrium with molten silicate at conditions shows that K is depleted in the Earth by $50%, while U and Th are slightly enriched (Palme and O

Minarik, William

175

Journal of Power Sources 135 (2004) 184191 A solid oxide fuel cell system fed with hydrogen sulfide  

E-Print Network [OSTI]

Journal of Power Sources 135 (2004) 184­191 A solid oxide fuel cell system fed with hydrogen for a solid oxide fuel cell (SOFC). This paper presents an examination of a simple hydrogen sulfide and natural gas-fed solid oxide fuel cell system. The possibility of utilization of hydrogen sulfide

176

Polarization and corrosion of electrogalvanized steel - evaluation of zinc coatings obtained from waste-derived zinc electrolytes  

SciTech Connect (OSTI)

The corrosion of electrogalvanized 1070 steel wire has been investigated in molar quiescent ammonium chloride and ammonium sulfate under near-neutral conditions. Zinc coatings obtained from waste-derived electrolytes were evaluated vs. coatings from relatively pure zinc electrolytes. The waste source of zinc was brass smelter flue dust. Corrosion rates were measured by Tafel line extrapolation and the polarization resistance technique. Values of the Tafel slopes and the corrosion currents were also compared with those for pure zinc (99.999%). Corrosion rates were found to be affected by the medium employed, pH, and bimetal diameter reduction (drawing). Drawn electrogalvanized stee displays higher values of the Tafel slopes than do the as-plated samples. The Tafel slopes are different from thos obtained on pure zinc. This is assumed to be due to inhomogeneous surface features obtained from additive adsorption (during plating) and residual lubricants used in the drawing process as well as surface structure. The corrosion rates of electrogalvanized samples plated in the waste-derived zinc electrolytes were similar to the corrosion rates of samples plated in relatively pure zinc electrolytes. Therefore, wastes are a potential source of zinc for electrogalvanizing.

Dattilo, M.

1985-11-01T23:59:59.000Z

177

Toxic sulfide concentrations in the sediments and water column of the Suwannee River estuary and its influence on hard clam survival  

E-Print Network [OSTI]

Toxic sulfide concentrations in the sediments and water column of the Suwannee River estuary that is grown to market size in estuarine sediments. Hydrogen sulfide, a natural metabolic poison known of hard clams used in field aquaculture areas in the Suwannee River estuary. Sulfide was found in sediment

Florida, University of

178

Iron sulfide oxidation and the chemistry of acid generation  

SciTech Connect (OSTI)

Acid mine drainage, produced from the oxidation of iron sulfides, often contains elevated levels of dissolved aluminum (Al), iron (Fe), and sulfate (SO{sub 4}) and low pH. Understanding the interactions of these elements associated with acid mine drainage is necessary for proper solid waste management planning. Two eastern oil shales were leached using humidity cell methods. This study used a New Albany Shale (4.6% pyrite) and a Chattanooga Shale (1.5% pyrite) were used. The leachates from the humidity cells were filtered, and the filtrates were analyzed for total concentrations of cations and anions. After correcting for significant solution species and complexes, ion activities were calculated from total concentrations. The results show that the activities of Fe{sup 3+}, Fe{sup 2+}, Al{sup 3+}, and SO{sub 4}{sup 2{minus}} increased due to the oxidation of pyrite. Furthermore, the oxidation of pyrite resulted in a decreased pH and an increased pe + pH (redox-potential). The Fe{sup 3+} and Fe{sup 2+} activities appeared to be controlled by amorphous Fe(OH){sub 3} solid phase above a pH of 6.0 and below pe + pH 11.0. The Fe{sup 3+}, Fe{sup 2+}, and SO{sub 4}{sup 2{minus}} activities reached saturation with respect to FeOHSO{sub 4} solid phase between pH 3.0 and 6.0 and below pe + pH 11.0. Below a pH of 3.0 and above a pe + pH of 11.0, Fe{sup 2+}, Fe{sup 3+}, and SO{sub 4}{sup 2{minus}} activities are supported by FeSO{sub 4}{center dot}7H{sub 2}O solid phase. Above a pH of 6.0, the Al{sup 3+} activity showed an equilibrium with amorphous Al(OH){sub 3} solid phase. Below pH 6.0, Al{sup 3+} and SO{sub 4}{sup 2{minus}} activities are regulated by the AlOHSO{sub 4} solid phase, irrespective of pe + pH. The results of this study suggest that under oxidizing conditions with low to high leaching potential, activities of Al and Fe can be predicted on the basis of secondary mineral formation over a wide range of pH and redox.

Sullivan, P.J.; Yelton, J.L. (Univ. of Wyoming Research Corp., Laramie (United States)); Reddy, K.J. (Univ. of Wyoming, Laramie (United States))

1988-06-01T23:59:59.000Z

179

Fluid membranes can drive linear aggregation of adsorbed spherical nanoparticles  

E-Print Network [OSTI]

Using computer simulations we show that lipid membranes can mediate linear aggregation of spherical nanoparticles binding to it for a wide range of biologically relevant bending rigidities. This result is in net contrast with the isotropic aggregation of nanoparticles on fluid interfaces or the expected clustering of isotropic insertions in biological membranes. We present a phase diagram indicating where linear aggregation is expected, and compute explicitly the free energy barriers associated with linear and isotropic aggregation. Finally, we provide simple scaling arguments to explain this phenomenology.

Andela Šari?; Angelo Cacciuto

2011-12-29T23:59:59.000Z

180

Capillary Break Beneath a Slab: Polyethylene Sheeting over Aggregate...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Capillary Break Beneath a Slab: Polyethylene Sheeting Over Aggregate Southwestern Pennsylvania PROJECT INFORMATION Project Name: Capillary Break Beneath a Slab: Polyethylene...

Note: This page contains sample records for the topic "zinc sulfide aggregation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Electrochemical synthesis and characterization of zinc oxalate nanoparticles  

SciTech Connect (OSTI)

Highlights: ? Synthesis of zinc oxalate nanoparticles via electrolysis of a zinc plate anode in sodium oxalate solutions. ? Design of a Taguchi orthogonal array to identify the optimal experimental conditions. ? Controlling the size and shape of particles via applied voltage and oxalate concentration. ? Characterization of zinc oxalate nanoparticles by SEM, UV–vis, FT-IR and TG–DTA. - Abstract: A rapid, clean and simple electrodeposition method was designed for the synthesis of zinc oxalate nanoparticles. Zinc oxalate nanoparticles in different size and shapes were electrodeposited by electrolysis of a zinc plate anode in sodium oxalate aqueous solutions. It was found that the size and shape of the product could be tuned by electrolysis voltage, oxalate ion concentration, and stirring rate of electrolyte solution. A Taguchi orthogonal array design was designed to identify the optimal experimental conditions. The morphological characterization of the product was carried out by scanning electron microscopy. UV–vis and FT-IR spectroscopies were also used to characterize the electrodeposited nanoparticles. The TG–DTA studies of the nanoparticles indicated that the main thermal degradation occurs in two steps over a temperature range of 350–430 °C. In contrast to the existing methods, the present study describes a process which can be easily scaled up for the production of nano-sized zinc oxalate powder.

Shamsipur, Mojtaba, E-mail: mshamsipur@yahoo.com [Department of Chemistry, Razi University, Kermanshah (Iran, Islamic Republic of); Roushani, Mahmoud [Department of Chemistry, Razi University, Kermanshah (Iran, Islamic Republic of); Department of Chemistry, Ilam University, Ilam (Iran, Islamic Republic of); Pourmortazavi, Seied Mahdi [Faculty of Material and Manufacturing Technologies, Malek Ashtar University of Technology, Tehran (Iran, Islamic Republic of)

2013-03-15T23:59:59.000Z

182

Testing of a refuelable zinc/air bus battery  

SciTech Connect (OSTI)

We report tests of a refuelable zinc/air battery of modular, bipolar-cell design, intended for fleet electric busses and vans. The stack consists of twelve 250-cm{sup 2} cells built of two units: (1) a copper-clad glass-reinforced epoxy board supporting anode and cathode current collectors, and (2) polymer frame providing for air- and electrolyte distribution and zinc fuel storage. The stack was refueled in 4 min. by a hydraulic transfer of zinc particles entrained in solution flow.

Cooper, J.F.; Fleming, D.; Koopman, R.; Hargrove, D.; Maimoni, A.; Peterman, K.

1995-02-22T23:59:59.000Z

183

A Simple Oxygen Detector Using Zinc–Air Battery  

Science Journals Connector (OSTI)

Elementary/Middle School Science; High School/Introductory Chemistry; Demonstrations; Hands-On Learning/Manipulatives; Gases; Laboratory Equipment/Apparatus ... Therefore, Faraday’s law can be confirmed by measuring the change in the volume of O2 consumed or the gained mass of the zinc–air battery with increasing quantity of electricity in a circuit using the zinc–air battery as the power source. ... (2-4) At the operating voltage of the zinc–air battery (1.4 V), the electric current in a circuit, with a small resistance, linearly changes with respect to the atmospheric O2 concentration. ...

Yoong Kin Hooi; Masayoshi Nakano; Nobuyoshi Koga

2013-12-24T23:59:59.000Z

184

Kinetics and mechanism of thiophene hydrodesulfurization over carbon-supported transition metal sulfides  

SciTech Connect (OSTI)

Results of a detailed kinetic study on the thiophene hydrodesulfurization reaction at atmospheric pressure over a set of carbon-supported transition metal sulfides, i.e., the sulfides of Co, Mo, Rh, and the mixed CoMo sulfide, are presented. It is found that (partially) hydrogenated thiophenes, i.e., 2,3-dihydrothiophene, 2,5-dihydrothiophene, and tetrahydrothiophene, are important intermediates in the reaction mechanism. The reaction orders of thiophene suggest that carbon-sulfur bond cleavage is rate limiting for most of the catalysts. The CoMo catalyst may have hydrogenative sulfur removal as the rate limiting step. This catalyst shows a strong decrease in apparent activation energy with temperature to be ascribed to a large change in steady state surface coverage by thiophene (or H{sub 2}S) as a function of temperature. This is consistent with a strong interaction between catalyst and thiophene. The Rh catalyst most probably shows a phase transition leading to different kinetic parameters. A strong interaction between the metal sulfide and thiophene is important for a high HDS activity. 38 refs., 4 figs., 5 tabs.

Hensen, E.J.M.; Vissenberg, M.J.; Beer, V.H.J. de [Eindhoven Univ. of Technology (Netherlands)] [and others] [Eindhoven Univ. of Technology (Netherlands); and others

1996-10-01T23:59:59.000Z

185

Coadsorption as a probe of mechanism: cyclic sulfides and straight chain thiols on Mo(110)  

SciTech Connect (OSTI)

The authors reported that tetrahydrothiophene and trimethylene sulfide undergo desulfurization on Mo(110) to form gaseous alkanes and alkenes in a temperature-programmed reaction experiment. In both cases, straight chain alkane evolution preceded alkene evolution. They proposed that the intermediate leading to straight chain alkanes and alkenes from these two cyclic sulfides is a surface thiolate. The thiolate undergoes competitive C/sub 1/-hydrogenation to alkane and C/sub 2/-dehydrogenation to alkene, depending on the surface hydrogenation concentration. They report here that coadsorbed cyclic sulfides C/sub n/H/sub 2n/S (n = 3, 4) and linear thiols C/sub m/H/sub 2m+1/SH(m = 2, 3, 4) react during a temperature-programmed reaction experiment to form alkanes C/sub n/H/sub 2n+2/ and C/sub m/H/sub 2m+2/ at exactly the same temperature. These experiments lend powerful support to their proposal that cyclic sulfides and straight chain thiols react on Mo(110) by way of a thiolate intermediate.

Roberts, J.T.; Friend, C.M.

1987-07-08T23:59:59.000Z

186

Methylation of Mercury by Bacteria Exposed to Dissolved, Nanoparticulate, and Microparticulate Mercuric Sulfides  

E-Print Network [OSTI]

Methylation of Mercury by Bacteria Exposed to Dissolved, Nanoparticulate, and Microparticulate in the environment is partly controlled by the bioavailability of inorganic divalent mercury (Hg(II)) to anaerobic matter to form chemical species that include organic-coated mercury sulfide nanoparticles as reaction

187

Thermal Processing Techniques to Improve Metal Sulfide Mixed Alcohol Catalyst Performance  

SciTech Connect (OSTI)

Research over several decades by several institutions has shown that alkali-promoted metal sulfide catalysts are capable of producing mixed alcohols from syngas with high selectivity and yield. Unfortunately, process models suggest that syngas to mixed alcohol processes, and especially thermochemical biomass to mixed alcohol processes, require improvements to sulfide catalyst activity and/or selectivity for acceptable economics. These improvements, if incremental, cannot result in increased process complexity, capital expenditure, or catalyst costs. It is well accepted among catalyst researchers that thermal processing techniques like calcining and reduction can have profound effects on the properties and performance of finished catalysts, and that small variations in thermal processing do not usually affect the overall cost of the catalyst. Metal sulfide catalysts are no exception but surprisingly, little attention has been given to the effects of thermal treatment on bulk metal sulfide mixed alcohol catalysts. This presentation will discuss how parameters like temperature, dwell time, metal ratios, and purge gas affect the performance and physical properties of K-Co/Mo catalysts.

Hensley, J.; Menart, M.; Costelow, K.; Thibodeaux, J.; Yung, M.

2011-01-01T23:59:59.000Z

188

Quantitative Microbial Community Analysis of Three Different Sulfidic Mine Tailing Dumps Generating Acid Mine Drainage  

Science Journals Connector (OSTI)

...years, an oxidized zone with depleted sulfide content, low pH...archaeum, isolated from a uranium mine in Germany. Syst. Appl...processes, techniques, and health issues. The Society of Economic...1995. Microbial diversity in uranium mine waste heaps. Appl. Environ...

Dagmar Kock; Axel Schippers

2008-06-27T23:59:59.000Z

189

HIGH TEMPERATURE SULFIDATION BEHAVIOR OF LOW Al IRON-ALUMINUM COMPOSITIONS  

E-Print Network [OSTI]

HIGH TEMPERATURE SULFIDATION BEHAVIOR OF LOW Al IRON-ALUMINUM COMPOSITIONS S.W. Banovic, J.N. Du (Received January 5, 1998) (Accepted March 23, 1998) Introduction Iron-aluminum weld overlay coatings, the application of iron-aluminum alloys is currently limited due to hydrogen cracking susceptibility subsequent

DuPont, John N.

190

Gas Chromatographic Analysis of Low Molecular Weight Alkyl Thiols and Sulfides Separated on Open Tubular Columns  

Science Journals Connector (OSTI)

......O.Z /98 Figure 1. Open Tubular Column Separation of Thiols and Sulfides. 1. Adams, D. F., and Koppe, R. H., Tappi 42, No. 7: 601 (July 1959). 2. Levey, E. J., and Stahl, W. A., Anal Chem. 33, No. 6: 707 (1961). 3. Fredericks......

Robert W. Freedman

1968-09-01T23:59:59.000Z

191

Organizing the Aggregate: Languages for Spatial Computing  

E-Print Network [OSTI]

As the number of computing devices embedded into engineered systems continues to rise, there is a widening gap between the needs of the user to control aggregates of devices and the complex technology of individual devices. Spatial computing attempts to bridge this gap for systems with local communication by exploiting the connection between physical locality and device connectivity. A large number of spatial computing domain specific languages (DSLs) have emerged across diverse domains, from biology and reconfigurable computing, to sensor networks and agent-based systems. In this paper, we develop a framework for analyzing and comparing spatial computing DSLs, survey the current state of the art, and provide a roadmap for future spatial computing DSL investigation.

Beal, Jacob; Usbeck, Kyle; Viroli, Mirko; Correll, Nikolaus

2012-01-01T23:59:59.000Z

192

Zinc oxide thin film acoustic sensor  

SciTech Connect (OSTI)

This paper reports the implementation of (750 nm) thickness of Zinc Oxide (ZnO) thin film for the piezoelectric pressure sensors. The film was prepared and deposited employing the spray pyrolysis technique. XRD results show that the growth preferred orientation is the (002) plane. A polycrystalline thin film (close to mono crystallite like) was obtained. Depending on the Scanning Electron Microscopy photogram, the film homogeneity and thickness were shown. The resonance frequency measured (about 19 kHz) and the damping coefficient was calculated and its value was found to be about (2.5538), the thin film be haves as homogeneous for under and over damped. The thin film pressure sensing was approximately exponentially related with frequency, the thin film was observed to has a good response for mechanical stresses also it is a good material for the piezoelectric properties.

Mohammed, Ali Jasim; Salih, Wafaa Mahdi; Hassan, Marwa Abdul Muhsien; Nusseif, Asmaa Deiaa; Kadhum, Haider Abdullah [Department of Physics , College of Science, Al-Mustansiriyah University, Baghdad (Iraq); Mansour, Hazim Louis [Department of Physics , College of Education, Al-Mustansiriyah University, Baghdad (Iraq)

2013-12-16T23:59:59.000Z

193

Experimental pressure solution compaction of synthetic halite/calcite aggregates  

E-Print Network [OSTI]

Experimental pressure solution compaction of synthetic halite/calcite aggregates Sergey Zubtsova of weakening of sediment-like aggregates by addition of hard particles. Sieved mixtures of calcite and halite solution. The individual halite grains deform easily by pressure solution creep whereas calcite grains act

194

Controlling Nanoparticle Aggregation in Colloidal Microwave Absorbers via Interface Chemistry  

E-Print Network [OSTI]

Controlling Nanoparticle Aggregation in Colloidal Microwave Absorbers via Interface Chemistry Brian ABSTRACT Interface chemistry can be implemented to modulate the aggregation and dispersion of nanoparticles of superparamagnetic magnetite nanoparticles in organic and aqueous solutions. With decrease in solution pH, individual

Stowell, Michael

195

Safe Overprovisioning: Using Power Limits to Increase Aggregate Throughput  

E-Print Network [OSTI]

-scalable system components allow for dynamically controlling power consumption with an accompanying ef- fect disruptions occur along with the ability to monitor aggregate power usage [4]. Hardware provides a meansSafe Overprovisioning: Using Power Limits to Increase Aggregate Throughput Mark E. Femal

Reeves, Douglas S.

196

Low energy WSN data aggregation algorithm based on improved aggregation tree model  

Science Journals Connector (OSTI)

To keep the data synchronisation and fidelity of each node in wireless sensor network (WSN), we propose a router-combined data fusion algorithm based on broadcast tree. The approximation algorithm is used to transform the optimum aggregation tree into NP-C problem to solve the smallest Steiner tree. Then the cluster-based optimising directed diffusion routing is adopted to construct aggregation tree for data fusion. At the fusion phase, we introduce consensus factor to support degree matrix, to replace original constant factor and provide more weight effect for reliable sensor. The improved support degree matrix will measure the support degree of each sensor to form a novel weighted fusion algorithm. The analyses on simulation show that our fusion algorithm can make data fusion effectively, which also has higher performance in delay, energy and accuracy.

Pinghui Zou; Yun Liu

2014-01-01T23:59:59.000Z

197

Performance-based approach to evaluate alkali-silica reaction potential of aggregate and concrete using dilatometer method  

E-Print Network [OSTI]

....................................................... 27 Aggregate Testing................................................................... 28 Cement-Aggregate Combination Testing ............................... 31 Gel Identification............................................................. 110 Chemistry of Pore Solution in Concrete ...................................... 113 Solubility of ASR Gel.................................................................. 113 Determination of Aggregate...

Shon, Chang Seon

2009-05-15T23:59:59.000Z

198

Dispenser Printed Zinc Microbattery with an Ionic Liquid Gel Electrolyte  

E-Print Network [OSTI]

thin-film rechargeable batteries. Materials Science andMicroscopic Nickel-Zinc Batteries for Use in AutonomousM, and RJ Brodd. “What Are Batteries, Fuel Cells, and

Ho, Christine Chihfan

2010-01-01T23:59:59.000Z

199

The effects of alcohol use on zinc status  

E-Print Network [OSTI]

Alcohol consumption has been shown to have adverse affects on bone growth and maintenance, although the mechanism has not been elucidated. The objective of this research was to look at the relationship between zinc and alcohol as a possible...

Chapman, Lisa Louise

1998-01-01T23:59:59.000Z

200

AN INVENTORY OF PHOTOGRAPHS OF ZINC ELECTRODEPOSITED FROM ACID ELECTROLYTES  

E-Print Network [OSTI]

Electrical circuit diagram Experimental apparatus Limiting current plaT7~us, 0.05 Levich plot (i vs. :;Electrical Circuit Diagrams Striated Zinc Deposit (GOULD, Inc. Photograph) Typical Striated Deposits Striation Length vs.

Faltemier, J.L.

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "zinc sulfide aggregation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Optoelectronics Devices Based on Zinc Oxide Thin Films and Nanostructures  

E-Print Network [OSTI]

is promising for UV optoelectronics, such as photodetectors,for future ZnO optoelectronics. References Ü. Özgür, Ya. I.OF THE DISSERTATION Optoelectronics Devices Based on Zinc

Chu, Sheng

2011-01-01T23:59:59.000Z

202

Synthesis and Characterization of Zinc Oxide Nanoparticles for Ethanol Detection  

Science Journals Connector (OSTI)

Pure phase, zinc oxide (ZnO) nanoparticles were synthesized at lower temperature by microwave assisted auto combustion synthesis method. As-synthesized particles had sizes ~50 nm with spherical shape. Gas respons...

Sachin Tyagi; Sarita Devi; Ashok K. Paul

2014-01-01T23:59:59.000Z

203

Regenerable Hydrogen Chloride Removal Sorbent and Regenerable Multifunctional Hydrogen Sulfide and Hydrogen Chloride Removal Sorbent for High Temperature Gas Streams  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Chloride and Hydrogen Sulfide Hydrogen Chloride and Hydrogen Sulfide Removal Sorbents for High Temperature Gas Streams Opportunity The Department of Energy's National Energy Technology Laboratory (NETL) is seeking licensing partners interested in implementing United States Patent Number 7,767,000 entitled "Regenerable Hydrogen Chloride Removal Sorbent and Regenerable Multifunctional Hydrogen Sulfide and Hydrogen Chloride Removal Sorbent for High Temperature Gas Streams." Disclosed in this patent is the invention of a unique regenerable sorbent process that can remove contaminants from gas produced by the gasification of fossil fuels. Specifically, the process removes hydrogen chloride by using the regenerable sorbent and simultaneously extracts hydrogen chloride compounds and hydrogen

204

Role of Standard Demand Response Signals for Advanced Automated Aggregation  

SciTech Connect (OSTI)

Emerging standards such as OpenADR enable Demand Response (DR) Resources to interact directly with Utilities and Independent System Operators to allow their facility automation equipment to respond to a variety of DR signals ranging from day ahead to real time ancillary services. In addition, there are Aggregators in today’s markets who are capable of bringing together collections of aggregated DR assets and selling them to the grid as a single resource. However, in most cases these aggregated resources are not automated and when they are, they typically use proprietary technologies. There is a need for a framework for dealing with aggregated resources that supports the following requirements: • Allows demand-side resources to participate in multiple DR markets ranging from wholesale ancillary services to retail tariffs without being completely committed to a single entity like an Aggregator; • Allow aggregated groups of demand-side resources to be formed in an ad hoc fashion to address specific grid-side issues and support the optimization of the collective response of an aggregated group along a number of different dimensions. This is important in order to taylor the aggregated performance envelope to the needs to of the grid; • Allow aggregated groups to be formed in a hierarchical fashion so that each group can participate in variety of markets from wholesale ancillary services to distribution level retail tariffs. This paper explores the issues of aggregated groups of DR resources as described above especially within the context of emerging smart grid standards and the role they will play in both the management and interaction of various grid-side entities with those resources.

Lawrence Berkeley National Laboratory; Kiliccote, Sila

2011-11-18T23:59:59.000Z

205

ALKALI AGGREGATE REACTION AND DELAYED ETTRINGITE FORMATION: COMMON FEATURES AND DIFFERENCES  

E-Print Network [OSTI]

ALKALI AGGREGATE REACTION AND DELAYED ETTRINGITE FORMATION: COMMON FEATURES AND DIFFERENCES Renaud Department, Paris, France Abstract Alkali-Aggregate Reaction (AAR) and Delayed Ettringite Formation (DEF effects 1 INTRODUCTION Alkali Aggregate Reaction (AAR) and Delayed Ettringite Formation (DEF) are internal

Paris-Sud XI, Université de

206

E-Print Network 3.0 - adenosine diphosphate-induced aggregation...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

diphosphate-induced aggregation Search Powered by Explorit Topic List Advanced Search Sample search results for: adenosine diphosphate-induced aggregation Page: << < 1 2 3 4 5 > >>...

207

E-Print Network 3.0 - alkali-aggregate reactions strengthening...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Durability Issues K.W. Neale1 Summary: conducted on the FRP rehabilitation of concrete beams suffering from alkali aggregate reaction damage... to alkali aggregate reactions. FRP...

208

E-Print Network 3.0 - aggregation chemistry Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

chemistry Search Powered by Explorit Topic List Advanced Search Sample search results for: aggregation chemistry Page: << < 1 2 3 4 5 > >> 1 Aggregation, Snowflakes, and Viscous...

209

Abundances of Hyperthermophilic Autotrophic Fe(III) Oxide Reducers and Heterotrophs in Hydrothermal Sulfide Chimneys of the Northeastern Pacific Ocean  

Science Journals Connector (OSTI)

...Sulfide Chimneys of the Northeastern Pacific Ocean Published ahead of print on 31...Fuca Ridge in the northeastern Pacific Ocean (see Fig. S1 in the supplemental...three sites in the northeastern Pacific Ocean. FEMS Microbiol. Ecol. 36...

Helene C. Ver Eecke; Deborah S. Kelley; James F. Holden

2008-10-31T23:59:59.000Z

210

Illinois Solar Energy Association - Renewable Energy Credit Aggregation  

Broader source: Energy.gov (indexed) [DOE]

Illinois Solar Energy Association - Renewable Energy Credit Illinois Solar Energy Association - Renewable Energy Credit Aggregation Program Illinois Solar Energy Association - Renewable Energy Credit Aggregation Program < Back Eligibility Commercial Fed. Government Industrial Institutional Local Government Nonprofit Residential Schools State Government Savings Category Solar Buying & Making Electricity Maximum Rebate $105/MWh) Program Info Start Date 01/01/2010 State Illinois Program Type Performance-Based Incentive Rebate Amount $105/MWh '''''RECAP is not currently accepting applications. The most recent solicitation closed April 30th, 2013. Check the program web site for information regarding future solicitations. ''''' The Illinois Solar Energy Association offers the Renewable Energy Credit Aggregation Program (RECAP) to Illinois solar photovoltaic (PV) system

211

Synthesis, Characterization, and Formation Mechanism of Copper Sulfide-Core/Carbon-Sheath Cables by a Simple Hydrothermal Route  

Science Journals Connector (OSTI)

Synthesis, Characterization, and Formation Mechanism of Copper Sulfide-Core/Carbon-Sheath Cables by a Simple Hydrothermal Route ... Copper sulfide-core/carbon-shell cables and spheres have been prepared by a simple hydrothermal method. ... The obtained CuS/C cables and spheres were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, Raman, Fourier transform infrared spectroscopy, photoluminescence, and UV?vis-NIR spectrum analysis. ...

Guang-Yi Chen; Bin Deng; Guo-Bin Cai; Wen-Fei Dong; Wan-Xi Zhang; An-Wu Xu

2008-05-29T23:59:59.000Z

212

The HYSULF{sup SM} process: A valuable hydrogen resource from hydrogen sulfide  

SciTech Connect (OSTI)

The increasing demand for hydrogen to reduce the sulfur content in standard refinery fuels is a very familiar problem to everyone in the industry. This problem could be partially offset by the continuous recycling of the hydrogen portion of hydrogen sulfide. In this regard, Marathon has been developing the HYSULF process. This process uses Redox chemistry under mild operating conditions to convert hydrogen sulfide into hydrogen and sulfur. The process employs two basic steps, i.e., a sulfur production and recovery step and a hydrogen production step. All chemicals and the catalyst used in the HYSULF process are either commercially available or are slight modifications of available materials. Also, the chemistry used in the HYSULF process is similar to that used in commercial desulfurization and gas sweetening processes.

Plummer, M.A. [Marathon Oil Co., Littleton, CO (United States)

1995-09-01T23:59:59.000Z

213

High-Temperature Nano-Derived Micro-Hydrogen Sulfide Sensors  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Temperature Nano-Derived Micro- Temperature Nano-Derived Micro- Hydrogen and -Hydrogen Sulfide Sensors Background The Department of Energy (DOE) National Energy Technology Laboratory (NETL) seeks applications for the University Coal Research (UCR) Program to further develop the understanding of coal utilization. Since the program's inception in 1979, its primary objectives have been to (1) improve our understanding of the chemical and physical processes involved in the conversion and utilization of coal in an environmentally

214

Arsenate and Arsenite Retention and Release in Oxide and Sulfide Dominated Systems  

E-Print Network [OSTI]

Arsenate and Arsenite Retention and Release in Oxide and Sulfide Dominated Systems Principal Investigator: Richard H. Loeppert Co-Investigators: Amita Jain Klaus Raven Jianlin Wang Soil & Crop Sciences Dept. Texas A&M University College Station, TX... Resources Institute. Non-Federal matching funds were provided by the Soil & Crop Sciences Dept., Texas A&M University, College Station, TX. A portion of this report was adapted from a part of a dissertation by Jianlin Wang which will be submitted...

Loeppert, Richard H.; Jain, Amita; Raven, Klaus; Wang, Jianlin

215

Solarthermal and Solar Quasi-Electrolytic Processing and Separations:? Zinc from Zinc Oxide as an Example  

Science Journals Connector (OSTI)

8 Carbonaceous material has been steam reformed in a solar furnace in an endothermic process9 which stores solar energy as an enhanced heating value of the products, hydrogen and/or synthesis gas, without having to burn any of the feedstocks to provide the energy needed to reform them, and methane has been reformed with carbon dioxide by Levy et al.10 to produce synthesis gas and store solar energy in a study aimed at developing a technique for transporting solar heat from the Negev to industrial regions. ... Inasmuch as CO and CO2 are gases, as long as only solid ZnO and C are initially present in a closed container, the solids can react to produce zinc and the appropriate equilibrium mixture of CO, CO2, and zinc vapor in contact with the solid reactants until the sum of the partial pressures of the gaseous components reaches the temperature-dependent unique “saturation pressure” of a ZnO?C mixture. ... A rapid quench would not be needed, though one might choose to cool the product gas quickly by expanding it through a nozzle or turbine rather than in a heat exchanger, to make economic use of its sensible enthalpy. ...

Edward A. Fletcher

1999-04-30T23:59:59.000Z

216

Public Sector Energy Efficiency Aggregation Program | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Public Sector Energy Efficiency Aggregation Program Public Sector Energy Efficiency Aggregation Program Public Sector Energy Efficiency Aggregation Program < Back Eligibility Fed. Government Institutional Local Government Nonprofit Schools State Government Savings Category Other Maximum Rebate $4,000,000 Program Info Expiration Date 3/22/2013 State Illinois Program Type State Grant Program Rebate Amount $500,000-$4,000,000 Provider Illinois Department of Commerce and Economic Opportunity The Illinois Department of Commerce and Economic Opportunity (DCEO) administers the Illinois Energy Now programs, including the Public Sector Energy Efficiency Aggregation Program. The program will allow public sector participants to combine energy efficiency projects in order to simplify the application process and implement projects that might otherwise be

217

Nanocrystal/J-aggregate constructs : chemistry, energy transfer, and applications  

E-Print Network [OSTI]

The interaction of light with matter is one of the most central subjects to modern chemistry. Two types of materials, semiconductor nanocrystals and J-aggregates of cyanine dyes, have been developed chiefly due to their ...

Walker, Brian J. (Brian Jacob)

2011-01-01T23:59:59.000Z

218

Moisture Diffusion in Asphalt Binders and Fine Aggregate Mixtures  

E-Print Network [OSTI]

cost in highway maintenance and vehicle operations. One key mechanism of how moisture reaches the asphalt-aggregate interface is by its permeation or diffusion through the asphalt binder or mastic. Different techniques are available for diffusion...

Vasconcelos, Kamilla L.

2011-08-08T23:59:59.000Z

219

The Belief-Function Approach to Aggregating Audit Evidence  

E-Print Network [OSTI]

In this article, we present the belief-function approach to aggregating audit evidence. The approach uses an evidential network to represent the structure of audit evidence. In turn, it allows us to treat all types of ...

Srivastava, Rajendra P.

1995-01-01T23:59:59.000Z

220

Commercial Building Tenant Energy Usage Aggregation and Privacy  

SciTech Connect (OSTI)

A growing number of building owners are benchmarking their building energy use. This requires the building owner to acquire monthly whole-building energy usage information, which can be challenging for buildings in which individual tenants have their own utility meters and accounts with the utility. Some utilities and utility regulators have turned to aggregation of customer energy use data (CEUD) as a way to give building owners whole-building energy usage data while protecting customer privacy. Meter profile aggregation adds a layer of protection that decreases the risk of revealing CEUD as the number of meters aggregated increases. The report statistically characterizes the similarity between individual energy usage patterns and whole-building totals at various levels of meter aggregation.

Livingston, Olga V.; Pulsipher, Trenton C.; Anderson, David M.; Wang, Na

2014-10-31T23:59:59.000Z

Note: This page contains sample records for the topic "zinc sulfide aggregation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

A representative individual from Arrovian aggregation of parametric individual utilities  

E-Print Network [OSTI]

A representative individual from Arrovian aggregation of parametric individual utilities social choice theory Assumptions Assumption on decisive coalitions Assumptions on individual utility functions Assumptions on the social welfare function Results The socially acceptable utility function

222

Water adsorption on aggregates of spherical aerosol nano particles  

E-Print Network [OSTI]

graphite planer substrate; the result corresponds well with previous simulation work. Adsorption of both noble gas and water onto a single spherical nano particle and aggregates of spherical nano particles has been computed with the developed equation...

Nie, Chu

2005-11-01T23:59:59.000Z

223

Tangible interfaces for manipulating aggregates of digital information  

E-Print Network [OSTI]

This thesis develops new approaches for people to physically represent and interact with aggregates of digital information. These support the concept of Tangible User Interfaces (TUIs), a genre of human-computer interaction ...

Ullmer, Brygg Anders

2002-01-01T23:59:59.000Z

224

Ground Motions from and House Response to Underground Aggregate Mining  

E-Print Network [OSTI]

interest because many urban quarries have gone underground or are considering doing so. Three cracks were to determine future blasting controls for a underground aggregate quarry near Franklin, KY (Revey, 2005

225

Transport and reduction of sulfate and immobilization of sulfide in marine black shales  

SciTech Connect (OSTI)

In fine-grained sediments in which the amount of reduced sulfur retained in stable phases substantially exceeds that present initially in pore waters, rates of sulfate reduction may have equaled or exceeded rates of sulfate transport, resulting in enrichment of [sup 34]S in pore waters and reduction products. Abundance and isotopic compositions of reduced sulfur compounds can be used to calculate the extent of sulfide retention and improve reconstructions of carbon-sulfur oxidation-reduction (redox) budgets. The Miocene Monterey Formation and Upper Devonian New Albany Shale represent distinct types of black shales that accumulated under different conditions of sulfate reduction. Our results suggest that the rate of sulfate reduction was controlled largely by mass transport in the Monterey and by the reduction process itself in the New Albany. Sulfide was more efficiently retained in the Monterey; thus each mole of sulfide in the New Albany represents a greater amount of sedimented organic carbon removed during sulfate reduction. 30 refs., 4 figs., 1 tab.

Zaback, D.A.; Pratt, L.M.; Hayes, J.M. (Indiana Univ., Bloomington (United States))

1993-02-01T23:59:59.000Z

226

Organusulfur Catalysis With Reduced Molybdenum Sulfides Containing the Mo6S8 Cluster  

SciTech Connect (OSTI)

Industrial synthesis of sulfur-containing organic chemicals basically focuses on the broad categories of mercaptans (thiols), alkylsulfides (thioethers), polysulfides, and thiophenes. Of the organo-sulfur compounds produced, by far the most important in terms of quantities produced is methyl mercaptan (methanethiol or MeSH), which is produced mainly for the downstream production of methionine and methanesulfonyl chloride. Higher thiols are also used in the manufacture of rubber and plastics as polymerization regulators, chain transfer agents, or initiators. Other important organosulfur chemicals are dimethyl sulfide (DMS) and dimethyl disulfide (DMDS), both of which are used extensively for presulfiding of industrial hydroprocessing catalysts, and substituted thiophenes which are used as intermediates for production of agrochemicals, dyes, and pharmaceuticals. Thiols are produced commercially at the rate of about 10{sup 4} ton/yr from hydrogen sulfide (H{sub 2}S) and alcohols or olefins, using homogeneous free-radical synthesis, or heterogeneous catalysts based on solid acids or supported metal oxides and/or sulfides. Despite this large production rate, and the industrial importance of the organosulfur compounds, only limited research has been devoted to the development of new catalytic materials for their synthesis. Additionally, for most organosulfur catalytic reactions, only limited information exists about reaction mechanisms, active sites, adsorbed surface species, and especially the nature of the catalysts under reaction conditions.

Thomas Jay Paskach

2002-08-27T23:59:59.000Z

227

Characterization of aggregate shape properties using a computer automated system  

E-Print Network [OSTI]

????????????????????.. 6 The Influence of Aggregate Shape on Pavement Performance... 7 Hot-mix Asphalt Mixtures?...?.?.???........................ 7 Hydraulic Cement Concrete Mixtures????????... 11 Unbound Layers???????.????????........ 14 Identifying Aggregate... base and subbase layers have a significant influence on the engineering properties of the pavement structure in which they are used (Kandhal and Parker 1998; Saeed et al. 2001; Meininger 1998). The form, angularity, and texture of fine and coarse...

Al Rousan, Taleb Mustafa

2005-02-17T23:59:59.000Z

228

E-Print Network 3.0 - ahmtp1 zinc transporters Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

jxberr025 Summary: ) RESEARCH PAPER Poplar maintains zinc homeostasis with heavy metal genes HMA4 and PCS1 Joshua P. Adams1... necessary heavy metals like zinc (Zn) while...

229

Exploring the Zinc Metallome of Cultured Cortical Neurons Using Synchroton Radiation X-Ray Fluorescence Microscopy  

Science Journals Connector (OSTI)

Zinc is abundant in the brain, and dysregulation of zinc ion homeostasis has been implicated in Alzheimer’s disease pathology and neuronal death after brain ischemia. Many studies have established that cytosol...

Robert A. Colvin PhD; Christian J. Stork; Yang V. Li; Barry Lai

2012-01-01T23:59:59.000Z

230

Formation of Biomimetic Porous Calcium Phosphate Coatings on Surfaces of Polyethylene/Zinc Stearate Blends  

E-Print Network [OSTI]

Formation of Biomimetic Porous Calcium Phosphate Coatings on Surfaces of Polyethylene/Zinc Stearate phosphate coating, polyethylene Abstract Studies were undertaken investigating improvements presented in this paper concentrated on adding zinc stearate to polyethylene. Important potential benefits

Drelich, Jaroslaw W.

231

Ratiometric and intensity-based zinc sensors built on rhodol and rhodamine platforms  

E-Print Network [OSTI]

A xanthene-forming condensation reaction yields rhodol and rhodamine dyes carrying a zinc-binding ligand that includes the aniline-type nitrogen donor of the fluorophores. Upon zinc coordination in neutral aqueous solution, ...

Tomat, Elisa

232

End-to-end aggregate authentication of time-series data  

Science Journals Connector (OSTI)

We consider the problem of providing integrity of aggregate result in the presence of an untrusted data aggregator who may introduce errors into data fusion, causing the final aggregate result to far deviate from the true result determined by participating ... Keywords: aggregate authentication, computation over authenticated data, time-series

Di Ma; Yan Zhu; Mengyang Yu

2013-05-01T23:59:59.000Z

233

Evaluation of Pre-sulfided NiMo/?-Al2O3 for Hydrodeoxygenation of Microalgae Oil to Produce Green-diesel  

Science Journals Connector (OSTI)

Evaluation of Pre-sulfided NiMo/?-Al2O3 for Hydrodeoxygenation of Microalgae Oil to Produce Green-diesel ... Energy Fuels, Just Accepted Manuscript ...

Lin Zhou; Adeniyi Lawal

2014-12-05T23:59:59.000Z

234

Zinc finger point mutations within the WT1 gene in Wilms tumor patients  

Science Journals Connector (OSTI)

...Genetics Zinc finger point mutations within the WTI gene in Wilms tumor patients (zinc finger...1992 ABSTRACT A proposed Wilms tumor gene, WTI, which encodes a zinc ringer protein...amino acid change. To our knowl- edge, a WTI gene missense mutation has not been detected...

M H Little; J Prosser; A Condie; P J Smith; V Van Heyningen; N D Hastie

1992-01-01T23:59:59.000Z

235

Separation and Purification Technology 40 (2004) 251257 Copper and zinc sorption by treated oil shale ash  

E-Print Network [OSTI]

Jordanian oil shale ash was used as an adsorbent for the removal of copper and zinc from aqueous solution.V. All rights reserved. Keywords: Oil shale; Ash; Adsorption; Copper and zinc removal 1. IntroductionSeparation and Purification Technology 40 (2004) 251­257 Copper and zinc sorption by treated oil

Shawabkeh, Reyad A.

236

HIGH-CURRENT ZINC-AIR MICROBATTERY BASED ON A MICROMACHINED MULTILAYER LATERAL METALLIC SCAFFOLD  

E-Print Network [OSTI]

HIGH-CURRENT ZINC-AIR MICROBATTERY BASED ON A MICROMACHINED MULTILAYER LATERAL METALLIC SCAFFOLD A, characterized, and compared with commercially available zinc-air batteries. A single layer initial structure maximum energy density [1]. Zinc-air batteries are good candidates for the previously mentioned microscale

237

Optical waveguides in SBN by zinc vapor diffusion  

E-Print Network [OSTI]

at 600'C for a 12. 5 i1m Wide 1000'C Zinc Vapor Diffused SBN:60 Waveguide Measured at X = 0. 81 pm. IV. SBN:60 Amplitude Modulator Results . . . . . V. SBN:60 Mach-Zehnder Interferometer Results. . . . VI. Voltage-Length Product Comparison...: (a) extraordinary (TM), (b) 1. 5 x ordinary (TE). 12. Surface damage on SBN:60 diffused at 1000'C with an SiOz diffusion mask. 13. Zinc in-diffusion in SBN:60 25 . . . . . 26 . . . . . 27 . . . . . 28 29 14. Barium out-diffuison in SBN:60...

Quinn, Jeffrey Dale

1991-01-01T23:59:59.000Z

238

Nano zinc oxide for UV protection of textiles  

Science Journals Connector (OSTI)

This paper describes the effect on the fading of dyed polyester fabrics in artificial sunlight, when the Ultra Violet (UV) component of the radiation was blocked by coating the fabric with zinc oxide nanoparticles, dispersed in an acrylic polymer. Zinc oxide is photoactive and generates superoxide and hydroxyl radicals (Reactive Oxygen Species; ROS) when irradiated with UV in the presence of oxygen and water. The results for the four dyes studied show that different dye chromophores interact differently with ROS. Selection of dyes with anti oxidant properties or addition of other anti oxidants may reduce the adverse effects of ROS.

Lu Sun; John A. Rippon; Peter G. Cookson; Xungai Wang; Ken King; Olga Koulaeva; Reno Beltrame

2008-01-01T23:59:59.000Z

239

RNA binding by the Wilms tumor suppressor zinc finger proteins  

Science Journals Connector (OSTI)

...November 5, 1995) ABSTRACT The Wilms tumor suppressor gene WTI is implicated in the ontogeny of genito-urinary abnormalities, including Denys-Drash syndrome and Wilms tumor of the kidney. WTI encodes Kruppel-type zinc finger proteins that can regulate...

A Caricasole; A Duarte; S H Larsson; N D Hastie; M Little; G Holmes; I Todorov; A Ward

1996-01-01T23:59:59.000Z

240

Zinc-catalyzed copolymerization of carbon dioxide and propylene oxide  

E-Print Network [OSTI]

dioxide has recently been paid attention in the field of extraction, separation, and reaction medium, its aptitude for both a reaction solvent and a reactant was examined in zinc glutarate-catalyzed reactions. As a result, it was proved that supercritical...

Katsurao, Takumi

1994-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "zinc sulfide aggregation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Speciation and bioavailability of zinc in amended sediments  

SciTech Connect (OSTI)

The speciation and bioavailability of zinc (Zn) in smelter-contaminated sediments were investigated as a function of phosphate (apatite) and organic amendment loading rate. Zinc species identified in preamendment sediment were zinc hydroxide-like phases, sphalerite, and zinc sorbed to an iron oxide via X-ray adsorption near edge structure (XANES) spectroscopy. Four months after adding the amendments to the contaminated sediment, hopeite, a Zn phosphate mineral, was identified indicating phosphate was binding and sequestering available Zn and Zn pore water concentrations were decreased at levels of 90% or more. Laboratory experiments indicate organic amendments exhibit a limited effect and may hinder sequestration of pore water Zn when mixed with apatite. The acute toxicity of the sediment Zn was evaluated with Hyalella azteca, and bioaccumulation of Zn with Lumbriculus variegates. The survivability of H. azteca increased as a function of phosphate (apatite) loading rate. In contaminated sediment without apatite, no specimens of H. azteca survived. The bioaccumulation of Zn in L. variegates also followed a trend of decreased bioaccumulation with increased phosphate loading in the contaminated sediment. The research supports an association between Zn speciation and bioavailability.

Williams, Aaron G.B.; Scheckel, Kirk G.; McDermott, Gregory; Gratson, David; Neptune, Dean; Ryan, James A.

2011-12-09T23:59:59.000Z

242

Amorphous hafnium-indium-zinc oxide semiconductor thin film transistors  

Science Journals Connector (OSTI)

We reported on the performance and electrical properties of co-sputtering-processed amorphous hafnium-indium-zinc oxide (?-HfIZO) thin film transistors (TFTs). Co-sputtering-processed ?-HfIZO thin films have shown an amorphous phase in nature. ...

Sheng-Po Chang; San-Syong Shih

2012-01-01T23:59:59.000Z

243

Nanocomposite electrical generator based on piezoelectric zinc oxide nanowires  

E-Print Network [OSTI]

Nanocomposite electrical generator based on piezoelectric zinc oxide nanowires K. Momeni, G. M October 2010; published online 1 December 2010 A nanocomposite electrical generator composed of an array system and loading configuration can generate up to 160% more electric potential than the values reported

Endres. William J.

244

Relationship between the properties of iron sulfides and their catalytic activity  

SciTech Connect (OSTI)

Iron sulfides, such as pyrite, are known catalysts in coal liquefaction and produce significant increases in both conversion and distillate (850 F/sup -/) yield. The main objective of this work is to increase the catalytic activity of iron sulfides by systematically changing the following properties: composition, source, particle size, surface area, morphology and defect level. Several iron sulfides have been synthesized including pyrite (FeS/sub 2/) with 46.6 wt % Fe, pyrrhotite (Fe/sub 1-x/S) with about 60 wt % Fe and mackinawite (Fe/sub 9/S/sub 8/) with 66.2 wt % Fe. The source variations have included commercial material and minerals. The pyrite particle sizes ranged from -350 to -5..mu..m, the pyrite surface areas varied from 2 to >10 m/sup 2//g, the mackinawite surface areas ranged from 40 to 80 m/sup 2//g, and pyrite morphologies included massive material and a concentrate of framboids from Iowa coal. Moessbauer studies of the pyrrhotites in coal liquefaction residues have shown that there is a direct correlation between conversion and the number of vacancies in the pyrrhotite. Pyrites with enhanced defect levels were prepared by explosively shock loading Robena pyrite at 15 GPa. All these materials have been tested in either tubing reactor or autoclave runs with West Virginia Blacksville No. 2 coal and SRC-II heavy distillate (550/sup 0/F/sup +/). The runs were carried out at 425/sup 0/C, 500 psi H/sub 2/ (cold charge) for 30 minutes with a 7.5 wt % catalyst loading. All these materials have shown catalytic effects as compared to uncatalyzed thermal runs.

Stohl, F.V.; Granoff, B.

1981-01-01T23:59:59.000Z

245

Kinetic studies of the water gas shift reaction on a sulfided cobalt/molybdena/alumina catalyst  

SciTech Connect (OSTI)

In this study, the applicability of low temperature oxygen chemisorption (LTOC) to measure the specific surface area of several rare-earth oxides (La, Ce, Pr, Nd, Tb) and the kinetics of the water-gas shift reaction over a sulfided cobalt-molybdena-alumina (AMOCAT 1A) catalyst are investigated. The LTOC results indicate that oxygen is possibly adsorbed in the molecular form, O/sub 2//sup -/, as observed by others after heat treatment of these oxides in vacuum. Lanthana and ceria were found to have ratios of total surface area to LTOC similar to those of chromia and molybdena respectively, after a comparable pretreatment. Furthermore, ceria is deduced to exist as a monolayer on the alumina support at loadings below 12%. An additional hour of reduction after the 6 hours of reduction shows a significant increase in LTOC on lanthana, neodymia and terbia which may be due to phase changes exhibited by these polymorphic oxides. The kinetics of the water-gas shift reaction has been extensively studied on iron oxide (high temperature shift) and copper oxide (low temperature shift) based catalysts. This investigation establishes the kinetics over a sulfided cobalt-molybdena-alumina (AMOCAT 1A) catalyst in the medium temperature shift range, 250-300/sup 0/C. The catalyst was sulfided in-situ in a high pressure integrated Berty reactor system. Reaction rates were measured for different CO/H/sub 2/O feed ratios in the range 0.3-3.0, with and without CO/sub 2/ in the feed. The reaction was carried out at several pressures in the range 5-27 atm. and GHSV's in the range 4800-2400 hr/sup 1/.

Srivatsa, N.R.

1987-01-01T23:59:59.000Z

246

Zinc-oxide-based sorbents and processes for preparing and using same  

DOE Patents [OSTI]

Zinc oxide-based sorbents, and processes for preparing and using them are provided. The sorbents are preferably used to remove one or more reduced sulfur species from gas streams. The sorbents comprise an active zinc component, optionally in combination with one or more promoter components and/or one or more substantially inert components. The active zinc component is a two phase material, consisting essentially of a zinc oxide (ZnO) phase and a zinc aluminate (ZnAl.sub.2O.sub.4) phase. Each of the two phases is characterized by a relatively small crystallite size of typically less than about 500 Angstroms. Preferably the sorbents are prepared by converting a precursor mixture, comprising a precipitated zinc oxide precursor and a precipitated aluminum oxide precursor, to the two-phase, active zinc oxide containing component.

Gangwal, Santosh Kumar (Cary, NC); Turk, Brian Scott (Durham, NC); Gupta, Raghubir Prasael (Durham, NC)

2010-03-23T23:59:59.000Z

247

Incorporating Aggregated PV Systems into the Power Grid | Open Energy  

Open Energy Info (EERE)

Incorporating Aggregated PV Systems into the Power Grid Incorporating Aggregated PV Systems into the Power Grid Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Spain Installed Wind Capacity Website Focus Area: Renewable Energy Topics: Market Analysis Website: www.gwec.net/index.php?id=131 Equivalent URI: cleanenergysolutions.org/content/spain-installed-wind-capacity-website Language: English Policies: Regulations Regulations: Feed-in Tariffs This website presents an overview of total installed wind energy capacity in Spain per year from 2000 to 2010. The page also presents the main market developments from 2010; a policy summary; a discussion of the revision in feed-in tariffs in 2010; and a future market outlook. References Retrieved from "http://en.openei.org/w/index.php?title=Incorporating_Aggregated_PV_Systems_into_the_Power_Grid&oldid=514463

248

Econometric Estimation of the Aggregate Impacts of Energy Efficiency  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Econometric Estimation of the Aggregate Impacts of Energy Efficiency Econometric Estimation of the Aggregate Impacts of Energy Efficiency Programs: Report on a California Pilot Study Speaker(s): Marvin J. Horowitz Date: February 26, 2013 - 2:00pm Location: 90-3075 Seminar Host/Point of Contact: Alan Sanstad The California Public Utilities Commission (CPUC) recently funded a study in which local area aggregated electricity and natural gas consumption in California from 2006 through 2010 were analyzed econometrically. Data were available to estimate electricity energy efficiency program impacts for two of the three large California investor-owned utilities. The findings indicate that net savings from these programs for the 2006-2010 period amounted to 11,391 GWh, or 7.3 percent of annual electricity consumption. This point estimate is 50 percent higher than the CPUC

249

NACP Site-Model and Aggregated Flux Data Published  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Site-Model and Aggregated Flux Data Published Site-Model and Aggregated Flux Data Published The ORNL DAAC is pleased to announce the release of a data set from the North American Carbon Program (NACP): NACP Site: Terrestrial Biosphere Model and Aggregated Flux Data in Standard Format . Data set prepared by D.M. Ricciuto, K. Schaefer, P.E. Thornton, K. Davis, R.B. Cook, Shishi Liu, R. Anderson, M.A. Arain, I. Baker, J.M. Chen, M. Dietze, R. Grant, C. Izaurralde, A.K. Jain, A.W. King, C. Kucharik, Shuguang Liu, E. Lokupitiya, Y. Luo, C. Peng, B. Poulter, D. Price, W. Riley, A. Sahoo, H. Tian, C. Tonitto, and H. Verbeeck. This data set provides standardized output variables for gross primary productivity (GPP), net ecosystem exchange (NEE), leaf area index (LAI), ecosystem respiration (Re), latent heat flux (LE), and sensible heat flux (H) from 24

250

Ferrofluid aggregates phase transitions in the planar magnetic field  

E-Print Network [OSTI]

The influence of the cyclic heating and cooling on properties of the aggregates (aka "ferrofluid clusters") in a ferrofluid, which made on the basis of magnetite nanoparticles, are investigated. The heating of the ferrofluid layer with such aggregates leads to equalization of the concentration between high- and low-concentrated phases. The temperature of the equalization of the phase concentrations was determined at different values of an external constant magnetic field, which was applied parallel to the layer of the ferrofluid. The temperature of the destruction of a periodic structure of the magnetic aggregates, which were formed during cooling of a homogeneous phase of the ferrofluid, was obtained at the different values of the applied external magnetic field.

V. F. Kovalenko; M. V. Petrychuk; B. M. Tanygin; S. I. Shulyma

2014-04-21T23:59:59.000Z

251

PRODUCTION OF CONSTRUCTION AGGREGATES FROM FLUE GAS DESULFURIZATION SLUDGE  

SciTech Connect (OSTI)

The three main conclusions of this report are: (1) The pilot plant successfully demonstrated the continuous, fully-integrated, long-term process operation, including the mixing, pelletizing, and curing steps for aggregate production. The curing vessel, which was designed for the pilot plant test, was operated in a mass flow mode and performed well during pilot plant operation. (2) The pilot plant test demonstrated process flexibility. The same equipment was used to produce lightweight, medium-weight, and road aggregates. The only change was the mix formulation. Aggregates were produced from a variety of mix designs and from FGD sludge with solids concentrations between 45.0% and 56.7% and moisture contents between 55.0% and 43.3%. (3) The pilot plant provided operating data and experience to design and cost a commercial plant, which was not part of the cooperative agreement.

M.M. Wu; D.C. McCoy; R.O. Scandrol; M.L. Fenger; J.A. Withum; R.M. Statnick

2000-05-01T23:59:59.000Z

252

Part I, copper(I) iodide dimethyl sulfide catalyzed 1,4- addition of alkenyl groups from alkenylzirconium and alkenylzinc reagents and their application toward the total synthesis of azaspirene : Part II, aqueous Wittig chemistry employing stabilized ylides and aldehydes  

E-Print Network [OSTI]

50, 1935-1954. A few stable copper(III) species have beenS. ; Bergdahl, M. Direct Copper(I) Iodide Dimethyl SulfideBatta, A. ; Bergdahl, M. Copper(I) Iodide Dimethyl Sulfide

El-Batta, Amer Adnan

2007-01-01T23:59:59.000Z

253

Stabilization of Lead Sulfide Nanoparticles by Polyamines in Aqueous Solutions. A Structural Study of the Dispersions  

Science Journals Connector (OSTI)

† Department of Chemistry, University of Cyprus, P.O. ... (1, 42-45) Excluding some older aqueous procedures, based on sulfur sources such as hydrogen sulfide gas or thioacetamide,(23, 24) optimal size and polydispersity control is currently provided in organic solvents either at high temperatures, using variants of the TOP/TOPO method,(21) or closer to room temperature with oleylamine as a coordinating solvent. ... The pH was equal to 6 in the cases of PAH and PDDA and equal to 10 in the case of PEI, these being the “natural” pH values of the dispersions, obtained immediately upon mixing their components. ...

Elena Koupanou; Silvia Ahualli; Otto Glatter; Angel Delgado; Frank Krumeich; Epameinondas Leontidis

2010-10-14T23:59:59.000Z

254

Removal of hydrogen sulfide as ammonium sulfate from hydropyrolysis product vapors  

SciTech Connect (OSTI)

A system and method for processing biomass into hydrocarbon fuels that includes processing a biomass in a hydropyrolysis reactor resulting in hydrocarbon fuels and a process vapor stream and cooling the process vapor stream to a condensation temperature resulting in an aqueous stream. The aqueous stream is sent to a catalytic reactor where it is oxidized to obtain a product stream containing ammonia and ammonium sulfate. A resulting cooled product vapor stream includes non-condensable process vapors comprising H.sub.2, CH.sub.4, CO, CO.sub.2, ammonia and hydrogen sulfide.

Marker, Terry L; Felix, Larry G; Linck, Martin B; Roberts, Michael J

2014-10-14T23:59:59.000Z

255

Transient fluctuations of intracellular zinc ions in cell proliferation  

SciTech Connect (OSTI)

Zinc is essential for cell proliferation, differentiation, and viability. When zinc becomes limited for cultured cells, DNA synthesis ceases and the cell cycle is arrested. The molecular mechanisms of actions of zinc are believed to involve changes in the availability of zinc(II) ions (Zn{sup 2+}). By employing a fluorescent Zn{sup 2+} probe, FluoZin-3 acetoxymethyl ester, intracellular Zn{sup 2+} concentrations were measured in undifferentiated and in nerve growth factor (NGF)-differentiated rat pheochromocytoma (PC12) cells. Intracellular Zn{sup 2+} concentrations are pico- to nanomolar in PC12 cells and are higher in the differentiated than in the undifferentiated cells. When following cellular Zn{sup 2+} concentrations for 48 h after the removal of serum, a condition that is known to cause cell cycle arrest, Zn{sup 2+} concentrations decrease after 30 min but, remarkably, increase after 1 h, and then decrease again to about one half of the initial concentration. Cell proliferation, measured by an MTT [3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide] assay, decreases after both serum starvation and zinc chelation. Two peaks of Zn{sup 2+} concentrations occur within one cell cycle: one early in the G1 phase and the other in the late G1/S phase. Thus, fluctuations of intracellular Zn{sup 2+} concentrations and established modulation of phosphorylation signaling, via an inhibition of protein tyrosine phosphatases at commensurately low Zn{sup 2+} concentrations, suggest a role for Zn{sup 2+} in the control of the cell cycle. Interventions targeted at these picomolar Zn{sup 2+} fluctuations may be a way of controlling cell growth in hyperplasia, neoplasia, and diseases associated with aberrant differentiation.

Li, Yuan [Division of Human Nutrition, Department of Preventive Medicine and Community Health, The University of Texas Medical Branch, Galveston, TX 77555 (United States)] [Division of Human Nutrition, Department of Preventive Medicine and Community Health, The University of Texas Medical Branch, Galveston, TX 77555 (United States); Maret, Wolfgang, E-mail: womaret@utmb.edu [Division of Human Nutrition, Department of Preventive Medicine and Community Health, The University of Texas Medical Branch, Galveston, TX 77555 (United States) [Division of Human Nutrition, Department of Preventive Medicine and Community Health, The University of Texas Medical Branch, Galveston, TX 77555 (United States); Department of Anesthesiology, The University of Texas Medical Branch, Galveston, TX 77555 (United States)

2009-08-15T23:59:59.000Z

256

Effects of internal mixing and aggregate morphology on optical properties  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Effects of internal mixing and aggregate morphology on optical properties Effects of internal mixing and aggregate morphology on optical properties of black carbon using a discrete dipole approximation model Title Effects of internal mixing and aggregate morphology on optical properties of black carbon using a discrete dipole approximation model Publication Type Journal Article Year of Publication 2013 Authors Scarnato, B., S. Vahidinia, D. T. Richard, and Thomas W. Kirchstetter Journal Atmospheric Chemistry and Physics Volume 12 Pagination 26401-26434 Abstract According to recent studies, internal mixing of black carbon (BC) with other aerosol materials in the atmosphere alters its aggregate shape, absorption of solar radiation, and radiative forcing. These mixing state effects are not yet fully understood. In this study, we characterize the morphology and mixing state of bare BC and BC internally mixed with sodium chloride (NaCl) using electron microscopy and examine the sensitivity of optical properties to BC mixing state and aggregate morphology using a discrete dipole approximation model (DDSCAT). DDSCAT predicts a higher mass absorption coefficient, lower single scattering albedo (SSA), and higher absorption Angstrom exponent (AAE) for bare BC aggregates that are lacy rather than compact. Predicted values of SSA at 550 nm range between 0.18 and 0.27 for lacy and compact aggregates, respectively, in agreement with reported experimental values of 0.25 ± 0.05. The variation in absorption with wavelength does not adhere precisely to a power law relationship over the 200 to 1000 nm range. Consequently, AAE values depend on the wavelength region over which they are computed. In the 300 to 550 nm range, AAE values ranged in this study from 0.70 for compact to 0.95 for lacy aggregates. The SSA of BC internally mixed with NaCl (100-300 nm in radius) is higher than for bare BC and increases with the embedding in the NaCl. Internally mixed BC SSA values decrease in the 200-400 nm wavelength range, a feature also common to the optical properties of dust and organics. Linear polarization features are also predicted in DDSCAT and are dependent on particle morphology. The bare BC (with a radius of 80 nm) presents in the linear polarization a bell shape feature, which is a characteristic of the Rayleigh regime (for particles smaller than the wavelength of incident radiation). When BC is internally mixed with NaCl (100-300 nm in radius), strong depolarization features for near-VIS incident radiation are evident, such as a decrease in the intensity and multiple modes at different angles corresponding to different mixing states.

257

Investigation for determining the curing characteristics of lightweight aggregate concrete  

E-Print Network [OSTI]

reached in froa 65 to 70 days for clay and shale con- ctetece The possibility of the entrapped or absorbed water in the aggregate acting as a self curing agent for lightweight aggregate concrete and the supporting statcscents concerning the slower than... standard 5/8 inch roue@, bullet~ tamping rod, while the beams wars compacted by being roddsd 55 times on each of two equal S inch layers with the standard tamping rod, The concrete an both sides and at the ends of the bxsm mold was spaded with a travel...

Carlton, Thomas Arlis

1955-01-01T23:59:59.000Z

258

Evaluation of synthetic aggregates for use in concrete  

E-Print Network [OSTI]

of synthetic aggregates may result in 4 irregular aggrege. te behavior with respect to those test procedures. Investigators at the Texas Transportation Institute have sug- g sted some new r. echniques to evaluate the synthet. ic ageregate. Some... in firing temperature and retention t5me, although pressure s1aking losses of all ag, regates were very low which indicated that the dehydration process of all aggro ates wa complete. 11. The NuOH test was able to detect the vari. ation of aggre- gate...

Ahmad, Hafizuddin

1970-01-01T23:59:59.000Z

259

Frequency Factors in a Landscape Model of Filamentous Protein Aggregation  

Science Journals Connector (OSTI)

Using quantitative measurements of protein aggregation rates, we develop a kinetic picture of protein conversion from a soluble to a fibrillar state which shows that a single free energy barrier to aggregation controls the addition of protein molecules into amyloid fibrils, while the characteristic sublinear concentration dependence emerges as a natural consequence of finite diffusion times. These findings suggest that this reaction does not follow a simple chemical mechanism, but rather operates in a way analogous to the landscape models of protein folding defined by stochastic dynamics on a characteristic energy surface.

Alexander K. Buell; Jamie R. Blundell; Christopher M. Dobson; Mark E. Welland; Eugene M. Terentjev; Tuomas P. J. Knowles

2010-06-01T23:59:59.000Z

260

Experimental Evaluation of New Generation Aggregate Image Measurement System  

E-Print Network [OSTI]

....................................................................... 90 Fig. 4.10. Half-Normal Plot of the Sphericity of the Light 9.5mm (0.375in) Coarse Aggregate Used in Experiment 5 ..................................................................... 91 Fig. 4.11. Light 4.75mm (ASTM #4 Sieve... of the Angularity of the Dark 1.18 mm (ASTM #16 Sieve) Fine Aggregate Used in Experiment 7 ................................................ 108 Fig. 4.26. Half-Normal Plot of the 2D Form of the Dark 1.18 mm (ASTM #16 Sieve...

Gates, Leslie L.

2010-07-14T23:59:59.000Z

Note: This page contains sample records for the topic "zinc sulfide aggregation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Single Cell Motion in Aggregates of Embryonic Cells  

Science Journals Connector (OSTI)

We investigate the motion of individual pigmented retinal cells in aggregates of neural retinal cells obtained from chicken embryos. Individual cells in aggregates move randomly in the absence of chemical or adhesion gradients: the power spectrum of position and velocity versus time correspond to Brownian motion and the velocities are uncorrelated in time. Thus a quasithermal model of cell migration like the extended Potts model is appropriate. We also measure cell diffusivity and the cell velocity distribution. The results support the idea that collections of embryonic cells behave as liquids with membrane fluctuations playing the role of temperature.

José C. M. Mombach and James A. Glazier

1996-04-15T23:59:59.000Z

262

The 3-stage evolution of the Angouran Zn "oxide"-sulfide deposit, Iran Fakultt Chemie, Technische Universitt Mnchen, Germany albert.gilg@geo.tum.de  

E-Print Network [OSTI]

The 3-stage evolution of the Angouran Zn "oxide"-sulfide deposit, Iran H.A. Gilg Fakultät Chemie@unina.it F. Moore Geological Department, University Shiraz, Iran moor@geology.susc.ac.ir Keywords: Angouran, Iran, sulfide, MVT, smithsonite, hypogene, supergene ABSTRACT: The giant Angouran Zn-Pb deposit (Zanjan

Boni, Maria

263

On the effects of common pollutants on the corrosion of copper-nickel alloys in sulfide polluted seawater  

SciTech Connect (OSTI)

Various pollutants are often introduced in seawater by wet and dry deposition and by improper dumping of municipal wastewater. These pollutants often affect the corrosivity of seawater on copper-based alloys which might be thought to be resistant in this environment and do not receive sufficient research efforts. In the present investigation the effect was determined of some common pollutants such as urea, sodium sulfite, sodium nitrate, sodium phosphate, copper sulfate, lead acetate, ammonium sulfate, and ammonium chloride at a level of 10 ppm and of chlorine at 1 ppm concentration on the corrosion characteristics of the 90Cu-10Ni and the 70Cu-30Ni alloys in seawater, both in the presence and in the absence of 10 ppm sulfide. Both small amplitude cyclic voltammetry (SACV) and the Tafel extrapolation technique were employed as test procedures. All pollutants under investigation have led to an increase in corrosion rate and their effect was more pronounced when sulfide was also present. The effects of pollutants were more intense on 90Cu-10Ni as compared to 70Cu-30Ni alloys. In unpolluted seawater, the worst pollutant for 90Cu-10Ni alloy is sulfide followed by urea and chlorine while for the 70Cu-30Ni alloy, the worst pollutant was ammonium chloride followed by sulfide and sodium phosphate. In unpolluted seawater, the introduction of pollutants led to a corrosion reaction which was under cathodic control except for sulfide where the reaction was under anodic control and resulted in a sharp negative shift in the corrosion potential. In sulfide polluted seawater, the worst pollutant for 90Cu-10Ni alloy was ammonium sulfate followed by urea while for 70Cu-30Ni alloy, the worst pollutant was urea followed by ammonium chloride, ammonium sulfate, and sulfite ions.

Alhajji, J.N.; Reda, M.R. [Kuwait Univ., Safat (Kuwait)

1995-09-01T23:59:59.000Z

264

Preparation of ferric-sulfide-based catalysts using an aerosol technique  

SciTech Connect (OSTI)

Iron sulfides are used as catalysts for direct coal liquefaction. They are reasonably active, cheap, and environmentally benign. This permits their use as once-through, non-regenerated catalysts. Our work in this area is based on the products of disproportionation of ferric sulfide, produced in sufficiently small particle sizes. The small particle sizes have been produced by in-situ impregnation or by using an aerosol reactor. This talk will concentrate on the aerosol process. The resulting particles have been characterized and used as catalysts for coal liquefaction. The effects of precursor solution concentration and the pressure and temperature in the aerosol reactor on the performance of the catalysts have been noted. We have recently investigated the effect of adding small amounts of a second metal to the catalyst. Multi-metal catalysts prepared to date with the aerosol technique include Fe-Cu-S and Fe-Zn-S, each with 10% additive, and Fe-Cu-Zn-S, with 10% Cu and 5% Zn.

Stiller, A.H.; Dadyburjor, D.B.; Stinespring, C.D. [West Virginia Univ., Morgantown, WV (United States)] [and others

1995-12-01T23:59:59.000Z

265

NASA/TM-1998-208419 Buckets: Aggregative, Intelligent Agents  

E-Print Network [OSTI]

May 1998 NASA/TM-1998-208419 Buckets: Aggregative, Intelligent Agents for Publishing Michael L Dominion University, Norfolk, Virginia #12;The NASA STI Program Office ... in Profile Since its founding, NASA has been dedicated to the advancement of aeronautics and space science. The NASA Scientific

Nelson, Michael L.

266

Private Top-Aggregation Protocols Myungsun Kim1  

E-Print Network [OSTI]

- items, data privacy, user privacy 1 Introduction Privacy has become a big concern in many applications jhcheon@snu.ac.kr 4 Department of Electrical Engineering Korea Advanced Institute of Science and Technology yongdaek@ee.kaist.ac.kr Abstract. In this paper, we revisit the private top- data aggregation

267

Tethys: A Distributed Algorithm for Intelligent Aggregation in Sensor Networks  

E-Print Network [OSTI]

energy than a naive, shortest-path tree due to the increased computation energy cost for performing.uiuc.edu, harris@dei.unipd.it, rhk@cs.uiuc.edu Abstract-- One key issue in wireless sensor networks is energy efficiency. Aggregation techniques attempt to minimize the energy expended in communication by processing

Kravets, Robin

268

Finding Aggregate Proximity Relationships and Commonalities in Spatial Data Mining  

E-Print Network [OSTI]

Finding Aggregate Proximity Relationships and Commonalities in Spatial Data Mining Edwin M. Knorr interested in mining spatial data. Due to the ever­growing uses of spatial systems such as GIS's, there are already huge amounts of spatial data accumulated, presenting ample opportunities for data analysis

Knorr, Edwin M.

269

Secure Aggregation for Wireless Networks Lingxuan Hu David Evans  

E-Print Network [OSTI]

. To conserve power, intermediate network nodes should aggregate results from individual sensors. However nodes within the network and use them to transmit false messages. Further, an adversary may compromise of the messages themselves to be unnecessary and focus only on the integrity of the results transmitted

Evans, David

270

Using Aggregate Human Genome Data for Individual Identification  

E-Print Network [OSTI]

Using Aggregate Human Genome Data for Individual Identification Yue Wang, Xintao Wu, Xinghua Shi. For example, 1000 genome project [2] provides the public with free services like browsing and downloading DNA,x.shi}@uncc.edu Abstract--Data privacy in genome-wide association studies (GWAS) is a critical yet under-exploited research

Wu, Xintao

271

A Wily Recruiter in the Battle Against Toxic ? Amyloid Aggregation  

Science Journals Connector (OSTI)

...recruiter in the battle against toxic beta amyloid aggregation. | Comment News | 0 Amyloid beta-Peptides 0 Ligands 0 Piperidines 0 SLF-CR compound 573-58-0 Congo Red EC 5.2.1.- Tacrolimus Binding Proteins | Amyloid beta-Peptides chemistry metabolism...

Ingrid Wickelgren

2004-10-29T23:59:59.000Z

272

Twitinfo: aggregating and visualizing microblogs for event exploration  

Science Journals Connector (OSTI)

Microblogs are a tremendous repository of user-generated content about world events. However, for people trying to understand events by querying services like Twitter, a chronological log of posts makes it very difficult to get a detailed understanding ... Keywords: twitter visualization streaming aggregate sentiment

Adam Marcus; Michael S. Bernstein; Osama Badar; David R. Karger; Samuel Madden; Robert C. Miller

2011-05-01T23:59:59.000Z

273

Vacancy Chains Provide Aggregate Benefits To Coenobita clypeatus Hermit Crabs  

E-Print Network [OSTI]

Vacancy Chains Provide Aggregate Benefits To Coenobita clypeatus Hermit Crabs Sara M. Lewis-dwelling clownfish and cavity-nesting birds. Vacancy chain theory was developed in social sci- ence research to describe how vacancies involving discrete, reusable resources such as apartments or jobs will propagate

Lewis, Sara

274

Effects of internal mixing and aggregate morphology on optical properties  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

3 3 Authors Scarnato, Barbara V., Sanaz Vahidinia, D. T. Richard, and Thomas W. Kirchstetter Journal Atmospheric Chemistry and Physics Volume 13 Start Page 5089 Issue 10 Pagination 5089 - 5101 Date Published 05/2013 Abstract According to recent studies, internal mixing of black carbon (BC) with other aerosol materials in the atmosphere alters its aggregate shape, absorption of solar radiation, and radiative forcing. These mixing state effects are not yet fully understood. In this study, we characterize the morphology and mixing state of bare BC and BC internally mixed with sodium chloride (NaCl) using electron microscopy and examine the sensitivity of optical properties to BC mixing state and aggregate morphology using a discrete dipole approximation model (DDSCAT). DDSCAT is flexible in simulating the geometry and refractive index of particle aggregates. DDSCAT predicts a higher mass absorption coefficient (MAC), lower single scattering albedo (SSA), and higher absorption Angstrom exponent (AAE) for bare BC aggregates that are lacy rather than compact. Predicted values of SSA at 550 nm range between 0.16 and 0.27 for lacy and compact aggregates, respectively, in agreement with reported experimental values of 0.25 ± 0.05. The variation in absorption with wavelength does not adhere precisely to a power law relationship over the 200 to 1000 nm range. Consequently, AAE values depend on the wavelength region over which they are computed. The MAC of BC (averaged over the 200-1000 nm range) is amplified when internally mixed with NaCl (100-300 nm in radius) by factors ranging from 1.0 for lacy BC aggregates partially immersed in NaCl to 2.2 for compact BC aggregates fully immersed in NaCl. The SSA of BC internally mixed with NaCl is higher than for bare BC and increases with the embedding in the NaCl. Internally mixed BC SSA values decrease in the 200-400 nm wavelength range, a feature also common to the optical properties of dust and organics. Linear polarization features are also predicted in DDSCAT and are dependent on particle size and morphology.

275

Efficient Föster energy transfer : from phosphorescent organic molecules to J-aggregate thin film  

E-Print Network [OSTI]

This thesis demonstrates the first ever use of Forster resonance energy transfer (FRET) to increase the quantum efficiency of a electrically pumped J-aggregate light emitting device (JLED). J-aggregate thin films are highly ...

Shirasaki, Yasuhiro

2008-01-01T23:59:59.000Z

276

Roughening due to edge diffusion for irreversible aggregation C. Ratsch,1,2,  

E-Print Network [OSTI]

Roughening due to edge diffusion for irreversible aggregation C. Ratsch,1,2, * M. C. Wheeler,2 for epitaxial growth enhances surface roughening for a model of irreversible aggregation. The reason

Ratsch, Christian

277

Real-time push middleware and mobile application for electric vehicle smart charging and aggregation  

Science Journals Connector (OSTI)

This paper presents a real-time push middleware and mobile application for data and multimedia content delivery to enable electric vehicle smart charging and aggregation. Intelligent aggregation and charge scheduling software can leverage the battery ...

Siddhartha Mal; Rajit Gadh

2013-06-01T23:59:59.000Z

278

Directional Flooding Scheme with Data Aggregation for Energy-Efficient Wireless Sensor Networks  

Science Journals Connector (OSTI)

We propose a directional flooding with data aggregation (DFDA) using hop- ... savings by reducing the redundant transmissions using directional flooding based on hop-count and data aggregation. Our simulation res...

Sung-Hyup Lee; Kang-Won Lee; You-Ze Cho

2008-01-01T23:59:59.000Z

279

Aggregation of ?-crystallins associated with human cataracts via domain swapping at the C-terminal ?-strands  

E-Print Network [OSTI]

The prevalent eye disease age-onset cataract is associated with aggregation of human ?D-crystallins, one of the longest-lived proteins. Identification of the ?-crystallin precursors to aggregates is crucial for developing ...

Das, Payel

280

Analysis of aggregate imaging system (AIMS) measurements and their relationship to asphalt pavement skid resistance  

E-Print Network [OSTI]

texture index and variability in texture within an aggregate source is proposed instead of the British Polish Value (BPV) for classifying aggregates used in pavement surfaces. The second part of the thesis investigates the relationship between shape...

Luce, Anthony David

2009-05-15T23:59:59.000Z

Note: This page contains sample records for the topic "zinc sulfide aggregation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Commercial Building Tenant Energy Usage Data Aggregation and Privacy: Technical Appendix  

SciTech Connect (OSTI)

This technical appendix accompanies report PNNL–23786 “Commercial Building Tenant Energy Usage Data Aggregation and Privacy”. The objective is to provide background information on the methods utilized in the statistical analysis of the aggregation thresholds.

Livingston, Olga V.; Pulsipher, Trenton C.; Anderson, David M.

2014-11-12T23:59:59.000Z

282

Influence of coarse aggregate size, shape and surface texture on rutting of hot mix asphalt concrete  

E-Print Network [OSTI]

The objectives of this study were to: 1 ) Evaluate the influence of coarse aggregate shape and surface texture on deformation characteristics of asphalt concrete, 2) Characterize aggregate elongation, shape and texture using fractal dimensional...

Yeggoni, Mohan

2012-06-07T23:59:59.000Z

283

Combinatorial study of zinc tin oxide thin-film transistors  

SciTech Connect (OSTI)

Groups of thin-film transistors using a zinc tin oxide semiconductor layer have been fabricated via a combinatorial rf sputtering technique. The ZnO:SnO{sub 2} ratio of the film varies as a function of position on the sample, from pure ZnO to SnO{sub 2}, allowing for a study of zinc tin oxide transistor performance as a function of channel stoichiometry. The devices were found to have mobilities ranging from 2 to 12 cm{sup 2}/V s, with two peaks in mobility in devices at ZnO fractions of 0.80{+-}0.03 and 0.25{+-}0.05, and on/off ratios as high as 10{sup 7}. Transistors composed predominantly of SnO{sub 2} were found to exhibit light sensitivity which affected both the on/off ratios and threshold voltages of these devices.

McDowell, M. G.; Sanderson, R. J.; Hill, I. G. [Dalhousie University, Department of Physics, Halifax, Nova Scotia B3H 3J5 (Canada)

2008-01-07T23:59:59.000Z

284

Zinc levels in hair of pre-adolescent females  

E-Print Network [OSTI]

. , and. Hart, E. B. (1934) Am. J. Physiol. ~10 , 146 10. Tucker, H. F. , and Salmon, W. D. (1955) Proc. Soc. Exp. Biol. Med. 88, 613 11. Keilin, D. , and. Mann, T. (1939) Nature (London) 144, 442 12. Orten, J. M. (1966) in Zinc Metabolism (Prasad. A... TABLE A-2 Standard Curve II ? 1974 Samples Zinc ml fo abs o ti on 10X scale 0. 25 0. 50 0 75 1. 0 25 0. 40 0. 9 1. 35 1. 75 3. &5 7 ' 5 10. 0 6. 9 20. 0 extrapolated 7. 0 g. O O 4 50 )0 3. 0 I. O 2. 0 4. 0 6. 0 8. 0 IO. O 12. 0 I...

Earp, Cheryl Fricke

1978-01-01T23:59:59.000Z

285

Intertemporally non?separable monetary?asset risk adjustment and aggregation  

E-Print Network [OSTI]

of monetary assets, and originated the Divisia monetary aggregates to track the theory’s quantity and price aggregator functions nonparametrically. The monetary aggregation theory was extended to risk by Barnett (1995) and Barnett, Hinich, and Yue (2000...). In producing the Divisia index approximations to the theory’s aggregator functions under risk, Barnett, Liu, and Jensen (1997) and Barnett and Liu (2000) showed that a risk adjustment term should be added to the certainty-equivalent user cost in a...

Barnett, William A.; Wu, Shu

2004-01-01T23:59:59.000Z

286

Senior Professional (SL/ST) Performance Cycle- Aggregate Results FY 2013  

Broader source: Energy.gov [DOE]

The memorandum releases the FY 2013 aggregate results for DOE's Senior Professional members and provides a summary of past results.

287

Geochemical, metagenomic and metaproteomic insights into trace metal utilization by methane-oxidizing microbial consortia in sulfidic marine sediments  

SciTech Connect (OSTI)

Microbes have obligate requirements for trace metals in metalloenzymes that catalyze important biogeochemical reactions. In anoxic methane- and sulfide-rich environments, microbes may have unique adaptations for metal acquisition and utilization due to decreased bioavailability as a result of metal sulfide precipitation. However, micronutrient cycling is largely unexplored in cold ( 10 C) and sulfidic (>1 mM H2S) deep-sea methane seep ecosystems. We investigated trace metal geochemistry and microbial metal utilization in methane seeps offshore Oregon and California, USA, and report dissolved concentrations of nickel (0.5-270 nM), cobalt (0.5-6 nM), molybdenum (10-5,600 nM) and tungsten (0.3-8 nM) in Hydrate Ridge sediment porewaters. Despite low levels of cobalt and tungsten, metagenomic and metaproteomic data suggest that microbial consortia catalyzing anaerobic oxidation of methane utilize both scarce micronutrients in addition to nickel and molybdenum. Genetic machinery for cobalt-containing vitamin B12 biosynthesis was present in both anaerobic methanotrophic archaea (ANME) and sulfate-reducing bacteria (SRB). Proteins affiliated with the tungsten-containing form of formylmethanofuran dehydrogenase were expressed in ANME from two seep ecosystems, the first evidence for expression of a tungstoenzyme in psychrotolerant microorganisms. Finally, our data suggest that chemical speciation of metals in highly sulfidic porewaters may exert a stronger influence on microbial bioavailability than total concentration

Glass, DR. Jennifer [California Institute of Technology, Pasadena; Yu, DR. Hang [California Institute of Technology, Pasadena; Steele, Joshua [California Institute of Technology, Pasadena; Dawson, Katherine [California Institute of Technology, Pasadena; Sun, S [University of California, San Diego; Chourey, Karuna [ORNL; Hettich, Robert {Bob} L [ORNL; Orphan, V [California Institute of Technology, Pasadena

2014-01-01T23:59:59.000Z

288

Generation of DNA-Damaging Reactive Oxygen Species via the Autoxidation of Hydrogen Sulfide under Physiologically Relevant  

E-Print Network [OSTI]

Generation of DNA-Damaging Reactive Oxygen Species via the Autoxidation of Hydrogen Sulfide under found that micromolar concentrations of H2S generated single-strand DNA cleavage. Mechanistic studies indicate that this process involved autoxidation of H2S to generate superoxide, hydrogen peroxide, and

Gates, Kent. S.

289

Zinc sorption by iron oxides and soil samples  

E-Print Network [OSTI]

(Head of Department) May 1989 ABSTRACT Zinc Sorption by Iron Oxides and Soil Samples. (May 1989) Markku Juhani Yli-Halla, M. S. University of Helsinki, Finland Chair of Advisory Committee: Dr. Richard H. Loeppert Zn sorption by synthetic Fe oxide... and soil samples was studied. The purpose was to examine the effect of crystallinity and adsorbed silica on Zn adsorption by synthetic Fe oxide using goethite and ferrihydrite as test materials. Zn sorption by acid soil samples from Finland and a...

Yli-Halla, Markku Juhani

1989-01-01T23:59:59.000Z

290

Characterization of polyacrylic acid modified zinc phosphate crystal conversion coatings  

SciTech Connect (OSTI)

Raman spectroscopy and atomic force microscopy have been used to investigate the composition and surface structure of polyacrylic acid modified zinc phosphate crystal conversion coatings on steel. Zinc phosphate coatings are used extensively to provide corrosion protection and to improve adherence of top coatings to steel. Within the last few years it has been demonstrated that addition of high molecular weight polyacrylic acid (PAA) to the phosphating bath can significantly improve both resistance to corrosion and topcoat adherence. It has been reported that the addition of PAA reduces the size of crystallites, which leads to greater film ductility, and therefore to fewer sites for corrosive attack, and that organic molecular segments from the PAA are incorporated into the surface structure and provide additional adhesive bonding with polymeric topcoats. In this work Raman spectra show the compositions of both unmodified and PAA modified films to be zinc phosphate dihydrate, Zn[sub 3](PO[sub 4])[sub 2] [times] 2H[sub 2]O. Atomic force microscopy (AFM) was used to measure the morphologies of single crystallite surfaces. Morphologies of the unmodified and modified films obtained by AFM are in general quite similar, but subtle differences are apparent.

Wragg, J.L.; Chamberlain, J.E.; Chann, L.; White, H.W. (Univ. of Missouri, Columbia, MO (United States). Dept. of Physics and Astronomy); Sugama, T. (Brookhaven National Lab., Upton, NY (United States). Energy Efficiency and Conservation Div.); Manalis, S. (Digital Instruments, Inc., Santa Barbara, CA (United States))

1993-11-05T23:59:59.000Z

291

THE WEATHERING OF A SULFIDE OREBODY: SPECIATION AND FATE OF SOME POTENTIAL CONTAMINANTS  

SciTech Connect (OSTI)

Various potentially toxic trace elements such as As, Cu, Pb and Zn have been remobilized by the weathering of a sulfide orebody that was only partially mined at Leona Heights, California. As a result, this body has both natural and anthropogenically modified weathering profiles only 500 m apart. The orebody is located in a heavily urbanized area in suburban Oakland, and directly affects water quality in at least one stream by producing acidic conditions and relatively high concentrations of dissolved elements (e.g., {approx}500 mg/L Cu, {approx}3700 mg/L Zn). Micrometric-scale mineralogical investigations were performed on the authigenic metal-bearing phases (less than 10 {mu}m in size) using electron-probe micro-analysis (EPMA), micro-Raman, micro X-ray absorption spectroscopy (mXAS), scanning X-ray diffraction (mSXRD) and scanning X-ray fluorescence (mSXRF) mapping techniques. Those measurements were coupled with classical mineralogical laboratory techniques, X-ray diffraction (XRD) and scanning electron microscopy (SEM). Authigenic metal-bearing phases identified are mainly sulfates (jarosite, epsomite, schwertmannite), Fe (oxy-)hydroxides (goethite, hematite and poorly crystalline Fe products) and poorly crystalline Mn (hydr-)oxides. Sulfates and Fe (oxy-)hydroxides are the two main secondary products at both sites, whereas Mn (hydr-) oxides were only observed in the samples from the non-mining site. In these samples, the various trace elements show different affinities for Fe or Mn compounds. Lead is preferentially associated with Mn (hydr-)oxides and As with Fe (oxy-)hydroxides or sulfates. Copper association with Mn and Fe phases is questionable, and the results obtained rather indicate that Cu is present as individual Cu-rich grains (Cu hydroxides). Some ochreous precipitates were found at both sites and correspond to a mixture of schwertmannite, goethite and jarosite containing some potentially toxic trace elements such as Cu, Pb and Zn. According to the trace element distribution and relative abundance of the unweathered sulfides, this orebody still represents a significant reservoir of potential contaminants for the watershed, especially in the non-mining site, as a much greater proportion of sulfides is left to react and because of the lower porosity in this site.

Courtin-Nomade, Alexandra; Grosbois, Cecile; Marcus, Matthew A.; Fakra, Sirine C.; Beny, Jean Michel; Foster, Andrea L.

2010-07-16T23:59:59.000Z

292

Preliminary study of the electrolysis of aluminum sulfide in molten salts  

SciTech Connect (OSTI)

A preliminary laboratory-scale study of the electrolysis of aluminum sulfide in molten salts investigated the (1) solubility of Al/sub 2/S/sub 3/ in molten salts, (2) electrochemical behavior of Al/sub 2/S/sub 3/, and (3) electrolysis of Al/sub 2/S/sub 3/ with the determination of current efficiency as a function of current density. The solubility measurements show that MgCl/sub 2/-NaCl-KCl eutectic electrolyte at 1023 K can dissolve up to 3.3 mol % sulfide. The molar ratio of sulfur to aluminum in the eutectic is about one, which suggests that some sulfur remains undissolved, probably in the form of MgS. The experimental data and thermodynamic calculations suggest that Al/sub 2/S/sub 3/ dissolves in the eutectic to form AlS/sup +/ species in solution. Addition of AlCl/sub 3/ to the eutectic enhances the solubility of Al/sub 2/S/sub 3/; the solubility increases with increasing AlCl/sub 3/ concentration. The electrode reaction mechanism for the electrolysis of Al/sub 2/S/sub 3/ was elucidated by using linear sweep voltammetry. The cathodic reduction of aluminum-ion-containing species to aluminum proceeds by a reversible, diffusion-controlled, three-electron reaction. The anodic reaction involves the two-electron discharge of sulfide-ion-containing species, followed by the fast dimerization of sulfur atoms to S/sub 2/. Electrolysis experiments show that Al/sub 2/S/sub 3/ dissolved in molten MgCl/sub 2/-NaCl-KCl eutectic or in eutectic containing AlCl/sub 3/ can be electrolyzed to produce aluminum and sulfur. In the eutectic at 1023 K, the electrolysis can be conducted up to about 300 mA/cm/sup 2/ for the saturation solubility of Al/sub 2/S/sub 3/. Although these preliminary results are promising, additional studies are needed to elucidate many critical operating parameters before the technical potential of the electrolysis can be accurately assessed. 20 figures, 18 tables.

Minh, N.Q.; Loutfy, R.O.; Yao, N.P.

1983-02-01T23:59:59.000Z

293

Development of experimental methods for the evaluation of aggregate resistance to polishing, abrasion, and breakage  

E-Print Network [OSTI]

Experiment...................................................54 4.2 Aggregate Texture, Before and After Micro-Deval................................................60 4.3 Ranking of the Aggregates Using Three Different Criteria... aggregate resistance to polishing, abrasion, and breakage. ? Chapter III discusses the analysis of variability in AIMS and Micro-Deval measurements. Measurements were conducted at the Texas Transportation Institute (TTI) and Texas Department...

Mahmoud, Enad Muhib

2007-04-25T23:59:59.000Z

294

Synchrotron 3D microtomography of halite aggregates during experimental pressure solution creep and evolution of  

E-Print Network [OSTI]

1 Synchrotron 3D microtomography of halite aggregates during experimental pressure solution creep of the porous network of halite aggregates was imaged during compaction driven by pressure solution creep using. For these purposes, 3D X-ray microtomography (µCT) was successfully applied for visualizing several halite aggregate

Paris-Sud XI, Université de

295

Poster Abstract: Exposing Two Critical Myths about Correlation Aware Data Aggregation I. CORRELATION AWARE DATA GATHERING  

E-Print Network [OSTI]

aware aggregation trees (CAATs). In this paper, we study the energy efficiency of CAATs from a new energy-delay tradeoff from the perspective of aggregation tree structures. Intuitively, with a higher ap, thereby resulting in an aggregation tree with lower energy cost. Therefore, the energy improvement tends

Sivakumar, Raghupathy

296

A Generate-Test-Aggregate parallel programming library for systematic parallel programming  

Science Journals Connector (OSTI)

The Generate-Test-Aggregate (GTA for short) algorithm is modeled following a simple and straightforward programming pattern, for combinatorial problems. First, generate all candidates; second, test and filter out invalid ones; finally, aggregate valid ... Keywords: Functional programming, Generate-Test-Aggregate algorithm, High-level parallel programming, MapReduce, Program calculation, Program transformation

Yu Liu; Kento Emoto; Zhenjiang Hu

2014-02-01T23:59:59.000Z

297

1 INTRODUCTION Delayed Ettringite Formation (DEF) and Alkali-Aggregate Reaction (AAR) are both internal  

E-Print Network [OSTI]

1 INTRODUCTION Delayed Ettringite Formation (DEF) and Alkali-Aggregate Reaction (AAR) are both to produce potentially expansive ettringite in the set concrete. AAR may affect concretes cast with aggregate combined delayed ettringite formation and alkali aggregate reaction R.-P. Martin, J.-C. Renaud & F

Paris-Sud XI, Université de

298

The effect of dietary zinc on the hypothalamo-adenohypophyseal-thyroid axis of male broiler chickens  

E-Print Network [OSTI]

and nonpregnant women consume a diet that contains 15 mg zinc per day (25). Intake of zinc in the United States typically ranges from 8-12 mg per day (2). Thus, some scientists have concluded that the recommended dietary allowance (RDA) for zinc is too high... cell response to available testosterone (12). Basal serum levels of LH and FSH did not differ among the treatment groups, however, zinc-deficient rats had a significantly enhanced gonadotropin (FSH and LH) response compared with all three control...

Dean, Carlton E.

1990-01-01T23:59:59.000Z

299

Flexographically Printed Rechargeable Zinc-based Battery for Grid Energy Storage  

E-Print Network [OSTI]

Integration with photovoltaic cells: Research on integrationpower harvesting using photovoltaic cells for lower-powerof printable photovoltaic cell, zinc-based battery as well

Wang, Zuoqian

2013-01-01T23:59:59.000Z

300

E-Print Network 3.0 - ambient air zinc Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: nanoparticles have a range of potential applications in electronic, optoelectronic and spintronic devices. Zinc... , reflection and electrical properties of the...

Note: This page contains sample records for the topic "zinc sulfide aggregation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

STUDIES OF MICROMORPHOLOGY AND CURRENT EFFICIENCY OF ZINC ELECTRODEPOSITED FROM FLOWING CHLORIDE ELECTROLYTES  

E-Print Network [OSTI]

zinc and chloride by atomic absorption by the spectroscopy.College The atomic absorption spectroscopy was performed ofrandom error is about atomic absorption spectroscopy. Many

Mc Vay, L.

2011-01-01T23:59:59.000Z

302

Zinc oxide nanoparticle-polymeric thin films for dynamic strain sensing  

E-Print Network [OSTI]

010-4940-3 Zinc oxide nanoparticle-polymeric thin ?lms forcharacterized by a unique nanoparticle weight fraction; theinvestigate the effects of nanoparticle weight fractions on

Loh, Kenneth J.; Chang, Donghee

2011-01-01T23:59:59.000Z

303

3-D Atomic-Scale Mapping of Manganese Dopants in Lead Sulfide Nanowires  

SciTech Connect (OSTI)

Dopants in nanowires, whether intentional or unintentional, can ultimately control the material's properties and therefore need to be understood on the atomic scale. We study vapor-liquid-solid grown manganese-doped lead sulfide nanowires by atom-probe tomography for the first time for lead salt materials. The three-dimensional chemical concentration maps at the atomic scale demonstrate a radial distribution profile of Mn ions, with a concentration of only 0.18 at.% and 0.01 at.% for MnCl2 and Mn-acetate precursors, respectively. The ability to characterize these small concentrations of dopant atoms in Pb1-xMnxS nanowires (x = 0.0036 and 0.0002), important for spintronic and thermoelectric devices, sets a platform for similar analyses for all nanostructures. First-principles calculations confirm that Mn atoms substitute for Pb in the PbS structure.

Isheim, Dieter; Kaszpurenko, Jason; Yu, Dong; Mao, Zugang; Seidman, David N.; Arslan, Ilke

2012-03-22T23:59:59.000Z

304

Iron sulfide catalysts for coal liquefaction prepared using a micellar technique  

SciTech Connect (OSTI)

The authors have recently synthesized nanometer-size iron sulfide catalysts using a reverse micellar system. These particles are 40--70 nm in size and were used in laboratory-scale coal-liquefaction experiments. The catalyst particles were impregnated in situ on coal particles. The catalyst loading was 1.67% with respect to coal. The liquefaction run was carried out at 400 C for 30 min, at a pressure of 1,000 psia H{sub 2}(g) measured at ambient temperature (corresponding to approximately 2,000 psia at reaction conditions), tine absence of any solvent or hydrogen donor. The total conversion, as well as the yields of asphaltene plus preasphaltene and oil plus gas, increased after the run, relative to a thermal (noncatalytic) run. The activity of the micellar catalyst is slightly less than that of a nonmicellar catalyst. However, a slightly higher selectivity to oil plus gas is observed with the micellar catalyst.

Chadha, A.; Sharma, R.K.; Stinespring, C.D.; Dadyburjor, D.B. [West Virginia Univ., Morgantown, WV (United States). Dept. of Chemical Engineering] [West Virginia Univ., Morgantown, WV (United States). Dept. of Chemical Engineering

1996-09-01T23:59:59.000Z

305

Synthesis of cadmium sulfide Q particles in water-in-CO{sub 2} microemulsions  

SciTech Connect (OSTI)

Semiconductor nanoparticles of cadmium sulfide were synthesized in ammonium perfluoropolyether (PFPE-NH{sub 4}) stabilized water-in-CO{sub 2} microemulsions. The particle size was tuned by varying the water-to-surfactant molar ratio ({omega}{sub 0}): {omega}{sub 0} ratios of 5 and 10 yielded nanocrystals with exciton energies of 3.86 and 3.09 eV, corresponding to mean particle radii of 0.9 and 1.8 nm, respectively. These exciton energies are significantly higher than the bulk band gap energy for CdS (2.45 eV) due to quantum confinement effects. Effectively, {omega}{sub 0} controls the size of the compartmentalized water droplets in which the particles grow.

Holmes, J.D.; Bhargava, P.A.; Korgel, B.A.; Johnston, K.P.

1999-09-28T23:59:59.000Z

306

Sulfides organic polymer: Novel cathode active material for rechargeable lithium batteries  

Science Journals Connector (OSTI)

Two novel sulfide polymers, poly(2-phenyl-1,3-dithiolane) and poly[1,4-di(1,3-dithiolan-2-yl)benzene], were prepared via facile oxidative-coupling polymerization under ambient conditions, characterized by FT-IR, XRD, TGA and elemental analysis, and were tested as cathode materials in rechargeable lithium battery. The charge–discharge tests showed that the specific capacity of poly[1,4-di(1,3-dithiolan-2-yl)benzene)] was 378 mAh g?1 at the third cycle, and retained at 300 mAh g?1 after 20 cycles. The specific capacity of poly(2-phenyl-1,3-dithiolane) was 117 mAh g?1 at the second cycle, and retained at 100 mAh g?1 after 20 cycles. The results indicated that thiolane group could be used as cathode active function group for lithium secondary batteries and the novel electrode reaction is proposed tentatively.

Jing Yu Zhang; Ling Bo Kong; Li Zhi Zhan; Jing Tang; Hui Zhan; Yun Hong Zhou; Cai Mao Zhan

2007-01-01T23:59:59.000Z

307

Chemical bath deposition of cadmium sulfide on graphene-coated flexible glass substrate  

SciTech Connect (OSTI)

We demonstrate a flexible structure of cadmium sulfide (CdS) on graphene-coated glass substrate, where CdS was deposited by the chemical bath deposition method on defective tri-layer graphene. The defects in graphene, confirmed by micro-Raman spectroscopy, were created by a ultra-violet treatment with varying exposure time from 10 to 60?min. The number of defect sites in the graphene as a seed layer was related to the quality of the CdS thin films determined from the results from X-ray diffraction, optical transmittance, scanning electron microscopy, and room temperature micro-photoluminescence. Our film-on-substrate structure of CdS-graphene-on-glass was maintained up to a tensile strain of 0.3%, where graphene with a high failure strain was employed as a transparent conductive layer.

Seo, Won-Oh; Jung, Younghun; Kim, Jihyun, E-mail: hyunhyun7@korea.ac.kr [Department of Chemical and Biological Engineering, Korea University, Anam-dong, Sungbuk-gu, Seoul 136-713 (Korea, Republic of); Kim, Jiwan [Flexible Display Research Center, Korea Electronics Technology Institute, Yatap-dong, Bundang-gu, Seongnam-si, Gyeonggi-do 463-816 (Korea, Republic of); Kim, Donghwan [Department of Materials Science and Engineering, Korea University, Seoul 136-701 (Korea, Republic of)

2014-03-31T23:59:59.000Z

308

The permanent electric dipole moment of thorium sulfide, ThS  

SciTech Connect (OSTI)

Numerous rotational lines of the (18.26)1-X{sup 1}?{sup +} band system of thorium sulfide, ThS, were recorded near 547.6 nm at a resolution of approximately 30 MHz. Measurements were made under field-free conditions, and in the presence of a static electric field. The field-free spectrum was analyzed to produce rotational and ?-doubling parameters. The Stark shifts induced by the electric field were analyzed to determine permanent electric dipole moments, ?{sup -vector}{sub el}, of 4.58(10) D and 6.72(5) D for the X{sup 1}?{sup +} (v = 0) and (18.26)1 states, respectively. The results are compared with the predictions of previous and new electronic structure calculations for ThS, and the properties of isovalent ThO.

Le, Anh; Steimle, Timothy C., E-mail: Tsteimle@ASU.edu [Department of Chemistry and Biochemistry, Arizona State University, Tempe, Arizona 85287-1604 (United States); Heaven, Michael C. [Department of Chemistry, Emory University, Atlanta, Georgia 30322 (United States)] [Department of Chemistry, Emory University, Atlanta, Georgia 30322 (United States)

2014-01-14T23:59:59.000Z

309

Organic thin film prehistory: looking towards solution phase aggregation |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Organic thin film prehistory: looking towards solution phase aggregation Organic thin film prehistory: looking towards solution phase aggregation Wednesday, November 6, 2013 - 3:00pm SLAC, Redtail Hawk Conference Room 108A Christopher Tassone, SSRL Polymer bulk heterojunction (BHJ) solar cells have attracted significant attention in industry and academia because of their potential for achieving large-area, light-weight, and flexible photovoltaic devices through cost-effective solution deposition techniques. These devices consist of a blend of an absorbing polymer and an electron accepting fullerene, the molecular packing and phase segregation of which heavily influence power conversion efficiency by effecting important processes such as exciton splitting, charge transport, and recombination. Understanding and utilization of molecular interactions to predicatively control the

310

A General Relationship between Disorder, Aggregation, and Charge Transport  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A General Relationship between Disorder, Aggregation, and Charge Transport A General Relationship between Disorder, Aggregation, and Charge Transport in Conjugated Polymers Monday, September 23, 2013 The potential for combining low-cost manufacturing and mechanical robustness with engineering of specific opto-electronic properties has recently spurred great interest in semiconducting polymers. Consequently, devices based on organic semiconductors have reached significant milestones such as ~10% solar power conversion efficiencies as well as electron and hole mobilities exceeding 1 cm2/Vs. Conjugated polymer chains have many degrees of conformational freedom and interact weakly with each other, resulting in complex microstructures in the solid state. Understanding charge transport in such systems, which have both amorphous and ordered

311

Secondary Ion Mass Spectrometry Imaging of Dictyostelium discoideum Aggregation Streams  

SciTech Connect (OSTI)

High resolution imaging mass spectrometry could become a valuable tool for cell and developmental biology, but both, high spatial and mass spectral resolution are needed to enable this. In this report, we employed Bi3 bombardment time-of-flight (Bi3 ToF-SIMS) and C60 bombardment Fourier transform ion cyclotron resonance secondary ion mass spectrometry (C60 FTICR-SIMS) to image Dictyostelium discoideum aggregation streams. Nearly 300 lipid species were identified from the aggregation streams. High resolution mass spectrometry imaging (FTICR-SIMS) enabled the generation of multiple molecular ion maps at the nominal mass level and provided good coverage for fatty acyls, prenol lipids, and sterol lipids. The comparison of Bi3 ToF-SIMS and C60 FTICR-SIMS suggested that while the first provides fast, high spatial resolution molecular ion images, the chemical complexity of biological samples warrants the use of high resolution analyzers for accurate ion identification.

Debord, J. Daniel; Smith, Donald F.; Anderton, Christopher R.; Heeren, Ronald M.; Pasa-Tolic, Ljiljana; Gomer, Richard H.; Fernandez-Lima, Francisco A.

2014-06-09T23:59:59.000Z

312

A new model for neutron reflectometry of adsorbed surfactant aggregates  

SciTech Connect (OSTI)

A new interpretation of neutron reflectivity data for surfactants adsorbed on hydrophilic solid surfaces has been developed. Motivated by recent atomic force microscopy results, a model of the adsorbed layer is constructed based upon an adsorbed layer consisting of discrete, micelle-like surfactant aggregates of well-defined geometries. Scattering length density profiles and reflectivity curves are calculated for conventional, laterally unstructured adsorbed layers (a bilayer), as well as for cylindrical and spherical surfactant aggregates adsorbed on a hydrophilic surface. It is shown that treating such structured surfactant films as bilayers often results in a good fit to neutron reflectivity data, but that fit parameters lead one to underestimate the film thickness and overestimate the fractional surface coverage by the adsorbed film.

Schulz, J.C.; Warr, G.G.; Hamilton, W.A.; Butler, P.D.

1999-12-16T23:59:59.000Z

313

Essays on Real Exchange Rates and Theoretical Monetary Aggregation  

E-Print Network [OSTI]

of Philosophy Committee members William A. Barnett, Chairperson Shu Wu John Keating Jianbo Zhang Yaozhong Hu Date defended: April 1, 2014 The Dissertation Committee for Mingming Zheng certifies that this is the approved version of the following dissertation...Essays on Real Exchange Rates and Theoretical Monetary Aggregation By Mingming Zheng Submitted to the Department of Economics and the Graduate Faculty of the University of Kansas in partial fulfillment of the requirements for the degree of Doctor...

Zheng, Mingming

2014-05-31T23:59:59.000Z

314

PRODUCTION OF CONSTRUCTION AGGREGATES FROM FLUE GAS DESULFURIZATION SLUDGE  

SciTech Connect (OSTI)

Through a cooperative agreement with DOE, the Research and Development Department of CONSOL Inc. (CONSOL R and D) is teaming with SynAggs, Inc. and Duquesne Light to design, construct, and operate a 500 lb/h continuous pilot plant to produce road construction aggregate from a mixture of wet flue gas desulfurization (FGD) sludge, fly ash, and other components. The proposed project is divided into six tasks: (1) Project Management; (2) Mix Design Evaluation; (3) Process Design; (4) Construction; (5) Start-Up and Operation; and (6) Reporting. In this quarter, Tasks 1 and 2 were completed. A project management plan (Task 1) was issued to DOE on October 22, 1998 . The mix design evaluation (Task 2) with Duquesne Light Elrama Station FGD sludge and Allegheny Power Hatfields Ferry Station fly ash was completed. Eight semi-continuous bench-scale tests were conducted to examine the effects of mix formulation on aggregate properties. A suitable mix formulation was identified to produce aggregates that meet specifications of the American Association of State High Transport Officials (AASHTO) as Class A aggregate for use in highway construction. The mix formulation was used in designing the flow sheet of the pilot plant. The process design (Task 3) is approximately 80% completed. Equipment was evaluated to comply with design requirements. The design for the curing vessel was completed by an outside engineering firm. All major equipment items for the pilot plant, except the curing vessel, were ordered. Pilot plant construction (Task 4) was begun in October. The Hazardous Substance Plan was issued to DOE. The Allegheny County (PA) Heat Department determined that an air emission permit is not required for operation of the pilot plant.

NONE

1998-12-01T23:59:59.000Z

315

Grid Integration of Aggregated Demand Response, Part 1: Load Availability  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Grid Integration of Aggregated Demand Response, Part 1: Load Availability Grid Integration of Aggregated Demand Response, Part 1: Load Availability Profiles and Constraints for the Western Interconnection Title Grid Integration of Aggregated Demand Response, Part 1: Load Availability Profiles and Constraints for the Western Interconnection Publication Type Report LBNL Report Number LBNL-6417E Year of Publication 2013 Authors Olsen, Daniel, Nance Matson, Michael D. Sohn, Cody Rose, Junqiao Han Dudley, Sasank Goli, Sila Kiliccote, Marissa Hummon, David Palchak, Paul Denholm, Jennie Jorgenson, and Ookie Ma Date Published 09/2013 Abstract Demand response (DR) has the potential to improve electric grid reliability and reduce system operation costs. However, including DR in grid modeling can be difficult due to its variable and non-traditional response characteristics, compared to traditional generation. Therefore, efforts to value the participation of DR in procurement of grid services have been limited. In this report, we present methods and tools for predicting demand response availability profiles, representing their capability to participate in capacity, energy, and ancillary services. With the addition of response characteristics mimicking those of generation, the resulting profiles will help in the valuation of the participation of demand response through production cost modeling, which informs infrastructure and investment planning.

316

Production of aggregate from non-metallic automotive shredder residues  

Science Journals Connector (OSTI)

In this paper, the results of an experimentation on the production of granules suitable to be used as aggregates in cementitious or asphalt mixes are presented and discussed. The granules were obtained by granulating the non-metallic fraction of automotive shredder residues. In a preliminary separation step the fluff fraction containing mainly inert and non-metallic materials was sieved and analyzed for the metal content. In the following granulation step, the sieved fraction was mixed with binding materials, fly ash and a densifier agent, to produce granules of 5–30 mm of diameter and up to 1400 kg/m3 of specific weight. The granulation was carried out at room temperature in a rotating tank. Concrete samples prepared using as aggregates the produced granules showed a specific weight up to 1800 kg/m3 and a compressive strength up to about 55% of reference samples prepared using a calcareous aggregate, depending on the fluff content of the mixes, and on the nature of the binder and of the other components used.

Vito Alunno Rossetti; Luca Di Palma; Franco Medici

2006-01-01T23:59:59.000Z

317

Alteration of alkali reactive aggregates autoclaved in different alkali solutions and application to alkali-aggregate reaction in concrete  

SciTech Connect (OSTI)

Surface alteration of typical aggregates with alkali-silica reactivity and alkali-carbonate reactivity, i.e. Spratt limestone (SL) and Pittsburg dolomitic limestone (PL), were studied by XRD and SEM/EDS after autoclaving in KOH, NaOH and LiOH solutions at 150 deg. C for 150 h. The results indicate that: (1) NaOH shows the strongest attack on both ASR and ACR aggregates, the weakest attack is with LiOH. For both aggregates autoclaved in different alkali media, the crystalline degree, morphology and distribution of products are quite different. More crystalline products are formed on rock surfaces in KOH than that in NaOH solution, while almost no amorphous product is formed in LiOH solution; (2) in addition to dedolomitization of PL in KOH, NaOH and LiOH solutions, cryptocrystalline quartz in PL involves in reaction with alkaline solution and forms typical alkali-silica product in NaOH and KOH solutions, but forms lithium silicate (Li{sub 2}SiO{sub 3}) in LiOH solution; (3) in addition to massive alkali-silica product formed in SL autoclaved in different alkaline solutions, a small amount of dolomite existing in SL may simultaneously dedolomitize and possibly contribute to expansion; (4) it is promising to use the duplex effect of LiOH on ASR and ACR to distinguish the alkali-silica reactivity and alkali-carbonate reactivity of aggregate when both ASR and ACR might coexist.

Lu Duyou [College of Materials Science and Engineering, Nanjing University of Technology, 5 New Model Road, Nanjing, Jiangsu, 210009 (China) and ICON/CANMET, Natural Resources Canada, 405 Rochester Street, Ottawa, ON, K1A 0G1 (Canada)]. E-mail: duyoulu@njut.edu.cn; Mei Laibao [College of Materials Science and Engineering, Nanjing University of Technology, 5 New Model Road, Nanjing, Jiangsu, 210009 (China); Xu Zhongzi [College of Materials Science and Engineering, Nanjing University of Technology, 5 New Model Road, Nanjing, Jiangsu, 210009 (China); Tang Mingshu [College of Materials Science and Engineering, Nanjing University of Technology, 5 New Model Road, Nanjing, Jiangsu, 210009 (China); Fournier, Benoit [ICON/CANMET, Natural Resources Canada, 405 Rochester Street, Ottawa, ON, K1A 0G1 (Canada)

2006-06-15T23:59:59.000Z

318

Effect of zinc salt on transport, structural, and thermal properties of PEG-based polymer electrolytes for battery application  

Science Journals Connector (OSTI)

Solid polymer polyethylene glycol (PEG)-based electrolytes composed with zinc acetate Zn(CH3COO)2...have been prepared by using solution blending. We proposed a scheme of PEG–zinc acetate for battery application....

Anji Reddy Polu; Ranveer Kumar; Girish M. Joshi

2014-05-01T23:59:59.000Z

319

July 2012 | ucsf global health sciences stuDent Policy brief | scaling uP oral rehyDration salts anD zinc Scaling up oral rehydration salts and zinc to  

E-Print Network [OSTI]

and zinc in Bangladesh, Nepal, and Tanzania.5 The Scaling Up of Zinc for Young Children (SUZY) Project.wpro.who.int/ internet/resources.ashx/CHD/docs/ENAcute_Diarrhoea_reprint.pdf. 3. Every Woman, Every Child. Zinc- hood diarrhoea in Bangladesh:

Klein, Ophir

320

(Data in thousand metric tons of zinc content, unless noted) Domestic Production and Use: The value of zinc mined in 1995 was about $700 million. Essentially all came from  

E-Print Network [OSTI]

188 ZINC (Data in thousand metric tons of zinc content, unless noted) Domestic Production and Use were used principally by the agricultural, chemical, paint, and rubber industries. Major coproducts--United States: 1991 1992 1993 1994 1995e Production: Mine, recoverable 518 523 488 570 600 Primary slab zinc 253

Note: This page contains sample records for the topic "zinc sulfide aggregation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

(Data in thousand metric tons of zinc content, unless otherwise noted) Domestic Production and Use: The value of zinc mined in 1996 was about $800 million. Essentially all came from  

E-Print Network [OSTI]

190 ZINC (Data in thousand metric tons of zinc content, unless otherwise noted) Domestic Production were used principally by the agricultural, chemical, paint, and rubber industries. Major coproducts--United States: 1992 1993 1994 1995 1996e Production: Mine, recoverable 523 488 570 614 6201 Primary slab zinc

322

Zinc and Magnesium in Human Prostate Gland: Normal, Hyperplastic, and Neoplastic  

Science Journals Connector (OSTI)

...hyperplastic gland. In addition, there was a marked...through a mixed-bed ion-exchange resin. All zinc and magnesium...plastic gland. In addition, there was a marked...S. Histochemi cal Demonstration of Zinc in the Dorsolateral...

Ferenc Györkey; Kyung-Whan Min; James A. Huff; and Phyllis Györkey

1967-08-01T23:59:59.000Z

323

pH dependence and compartmentalization of zinc transported across plasma membrane of rat cortical neurons  

E-Print Network [OSTI]

pH dependence and compartmentalization of zinc transported across plasma membrane of rat corticalH dependence and compartmental- ization of zinc transported across plasma membrane of rat cortical neurons. Am; ion transport; transition elements; primary culture IT IS KNOWN THAT Zn2 can enter neurons by two

324

MAGNESIUM AND ZINC BLOOD LEVELS IN MICE SENSITIVE TO AUDIOGENIC SEIZURES  

E-Print Network [OSTI]

MAGNESIUM AND ZINC BLOOD LEVELS IN MICE SENSITIVE TO AUDIOGENIC SEIZURES J.G. HENROTTE G. FRANCK., 1973 ; Durlach, 1976). Thus, it seemed of interest to study the zinc and magnesium levels in the blood the animals contained 2 % of a mineral mixture composed of magnesium hydroxide (13.8 %), Ca diphosphate (70

Paris-Sud XI, Université de

325

Effects of zinc on Salmonella in the layer house environments and laying hens, and the ability of zinc to induce molt in laying hens  

E-Print Network [OSTI]

environments, and its ability to induce a molt in single comb white leghorn hens. In part, the antibacterial properties of zinc may reduce environmental contamination in a poultry house by interrupting airborne routes. The first phase involved detecting...

Park, Shinyoung

2005-02-17T23:59:59.000Z

326

Analysis of Zinc 65 Contamination after Vacuum Thermal Process  

SciTech Connect (OSTI)

Radioactive contamination with a gamma energy emission consistent with {sup 65}Zn was detected in a glovebox following a vacuum thermal process. The contaminated components were removed from the glovebox and subjected to examination. Selected analytical techniques were used to determine the nature of the precursor material, i.e., oxide or metallic, the relative transferability of the deposit and its nature. The deposit was determined to be borne from natural zinc and was further determined to be deposited as a metallic material from vapor.

Korinko, Paul S.; Tosten, Michael H.

2013-01-01T23:59:59.000Z

327

The Interactions of Zinc Thiolate Complexes and Exogenous Metal Species: Investigations of Thiolate Bridging and Metal Exchange  

E-Print Network [OSTI]

formation and zinc displacement. To study such possible interactions between zinc finger proteins and platinum-bound DNA, the ZnN2S2 dimeric complex, N,N?-bis(2- mercaptoethyl)-1,4-diazacycloheptane zinc (II), [Zn-1?]2, has been examined for Znbound thiolate...

Almaraz, Elky

2010-07-14T23:59:59.000Z

328

Assessing the Role of Iron Sulfides in the Long Term Sequestration of U by Sulfate Reducing Bacteria  

SciTech Connect (OSTI)

This four-year project’s overarching aim was to identify the role of biogenic and synthetic iron-sulfide minerals in the long-term sequestration of reduced U(IV) formed under sulfate-reducing conditions when subjected to re-oxidizing conditions. As stated in this final report, significant progress was achieved through the collaborative research effort conducted at Arizona State University (ASU) and the University of Michigan (UM).

Rittman, Bruce; Zhou, Chen; Vannela, Raveender

2013-12-31T23:59:59.000Z

329

Adenylate pool and radiological tracer studies of the metabolism of micro-metazoans of the sulfide system  

E-Print Network [OSTI]

. The Kruskal-Wallis test revealed no significant differences in distributional patterns between the day and night samples of all species examined. Actual day to day and night to night variability accounted for most of the total sample variance... significantly in the absence of oxygen. With oxygen present, Solenofilomor ha was able to maintain relatively high ATP concentrations regardless of the presence or absence of sulfide (ANOVA, Kruskal Wallis P&. 05). (Figure 2) No significant differences were...

Fox, Catherine Alice

2012-06-07T23:59:59.000Z

330

Sulfide, phosphate, and minor element enrichment in the New Albany Shale (Devonian-Mississippian) of southern Indiana  

SciTech Connect (OSTI)

The upper part of the New Albany Shale is divided into three members, which in ascending order are: (1) the Morgan Trail Member, a laminated brownish-black shale; (2) the Camp Run Member, an interbedded brownish-black and greenish-gray shale; and (3) the Clegg Creek Member, also a laminated brownish-black shale. The Morgan Trail and Camp Run Members contain 5 to 6% total organic carbon (TOC) and 2% sulfide sulfur. Isotopic composition of sulfide in these members ranges from -5.0 to -20.0%. C/S plots indicate linear relationships between abundances of these elements characteristic of sediments deposited in a noneuxinic marine environment. The Clegg Creek Member contains 10 to 15% TOC and 2 to 6% sulfide sulfur. Isotopic composition of sulfide ranges from -5.0 to -40.0%. The most negative values are characteristic of syngenetic pyrite formed within an anoxic water column. Abundances of carbon and sulfur are higher and uncorrelated in this member, consistent with deposition in an euxinic environment. Further, DOP (degree of pyritization) values suggest that pyrite formation was generally iron limited throughout Clegg Creek deposition, but sulfur isotopes indicate that syngenetic (water column) pyrite becomes an important component in the sediment only in the upper part of the member. At the top of the Clegg Creek Member a zone of phosphate nodules and trace metal enrichment coincides with maximal TOC values. During euxinic deposition, phosphate and trace metals accumulated below the chemocline due to limited vertical circulation in the water column. Phosphate and trace metals released for organic matter during early diagenesis resulted in precipitation of metal-rich phosphate nodules.

Beier, J.A.

1988-01-01T23:59:59.000Z

331

Biogeochemical cycling in an organic-rich coastal marine basin. 7. Sulfur mass balance, oxygen uptake and sulfide retention  

SciTech Connect (OSTI)

Sulfur and oxygen fluxes were quantified in the seasonally varying anoxic marine sedimentary system of Cape Lookout Bight, N.C., U.S.A. Over the three year study period, 1981-1983, the mean annual sulfate reduction rate was determined to be 18.2 +/- 1.6 moles x m/sup -2/ x y/sup -1/. This value, added to the estimate of the detrital sulfur input of 1.2 +/- 4.4 gave a total sulfur input of 19.4 +/- 4.7 moles x m/sup -1/ x y/sup 2/)/sup 1/. The sulfide flux to the sediment-water interface, measured in anaerobic benthic chambers was 4.6 +/- 0.5 moles x m/sup -2/ x y/sup -1/, and represented 37% of the annual oxygen uptake rate of 25.2 +/- 2.8 moles x m/sup -2/ x y/sup -1/. The sulfide burial rate, determined to be 15.5 +/- 3.1 moles x m/sup -2/ x y/sup -1/, was within 5% of the value predicted by summing the fluxes at the sediment-water interface. The C/S weight ratio of sediment below the depth of diagenetic reaction was determined to be 2.75. The sulfide retention rate in these rapidly accumulating sediments (10 cm/yr) was 77 +/- 19%. Comparison of this result with previous studies shows that rapid sediment accumulation and the lack of bioturbation control this unusually high degree of sulfide retention.

Chanton, J.P.; Martens, C.S.

1987-05-01T23:59:59.000Z

332

Nickel-cobalt-iron-copper sulfides and arsenides in solution-collapse breccia pipes, northwestern Arizona  

SciTech Connect (OSTI)

An extensive suite of Ni-Co-Fe-Cu sulfides and arsenides lies within the matrix of solution-collapse breccias buried deep within the plateaus of the Grand Canyon region. Ceilings over large caverns in the Redwall collapsed, brecciating the overlying sandstone and forming cylindrical breccia pipes up to 300 ft in diameter that extend vertically as much as 3,000 ft. These highly permeable breccias served as a host for the precipitation of a suite of over 100 minerals, including uraninite, sphalerite, galena and various copper phases, in addition to the Ni-Co-bearing-phase discussed here. Intricately zoned crystals of small (<1 mm), euhedral Ni-Co-Fe-As-S minerals were the first to form during the second major episode of mineralization in these pipes. Several of these phases replace minerals, such as barite and anhydrite, from the first episode. Extensive microprobe work has been done on samples from two breccia pipe mines, the Hack 2 and Orphan, which are about 50 miles apart. Mineral compositions are similar except that no copper is found in the Ni-Co-Fe phases from the Hack 2 mine, while pyrites containing 1 wt % Cu are common from the Orphan, which was mined for copper. In some of these pyrites', Cu is dominant and the mineral is actually villamaninite. Pyrites from both mines characteristically contain 0.5 to 3 wt % As. Metal contents in zones pyrite-bravoite-vaesite (M[sub 1]S[sub 2]) crystals at the Hack 2 mine range from Fe[sub 1] to Fe[sub .12], Ni[sub 0] to Ni[sub .86], and Co[sub 0] to Co[sub .10]. The metal content for polydymite-siegenite-violarite averages about (Ni[sub 2.33]Co[sub .39]Fe[sub .23])(S[sub 3.9]As[sub .1]). Orphan mine pyrite-bravoite-vaesite-villamaninite ranges in composition from pure FeS[sub 2] to (Ni[sub .6]Fe[sub .21]Co[sub .17])S[sub 2], and (Cu[sub .46]Ni[sub .27]Fe[sub .21]Co[sub .13])S[sub 2]. Of all the sulfides or arsenides found in these breccia pipes, only nickeline consistently occurs as the pure end member.

Wenrich, K.J. (Geological Survey, Denver, CO (United States)); Hlava, P.F. (Sandia National Labs., Albuquerque, NM (United States))

1993-04-01T23:59:59.000Z

333

Aggregated Purchasing and Workplace Charging Can Drive EV Market Growth  

Broader source: Energy.gov [DOE]

On Tuesday, November 18, Energy Secretary Moniz joined Senior Advisor to the President John Podesta, Edison Electric Institute (EEI) President Tom Kuhn, and Pacific Gas and Electric (PG&E) CEO Tony Earley for a special event at the White House to announce several new developments in advancing the use of electric vehicles. These developments included the Energy Department announcing a Notice of Intent for a potential funding opportunity announcement for aggregated purchasing of alternative fuel and advanced technology vehicles 70 EEI members committing 5% of their annual fleet budgets to plug-in electric vehicles, 150 members of the Workplace Charging Challenge, and a new plug-in hybrid electric bucket truck.

334

A framework for a coarse aggregate classification system  

E-Print Network [OSTI]

. Fookes et al. (17) proposed a classification system for near-shore carbonate sediment rocks in 1975. This system was based on the grain size and "post depositional induration" of rocks. Clarke et aL (17) expanded the system developed by Fookes in 1977..., provision of petrological data is added as supplementary information in this system. This data is recommended to be provided only when a possible alkali-silica reactivity is suspected or to identify any potential problems related to aggregates. Table 2. 7...

Peapully, Srikrishna

2012-06-07T23:59:59.000Z

335

Precursors of the copper-zinc oxide methanol synthesis catalysts  

Science Journals Connector (OSTI)

The coprecipitated hydroxycarbonate precursor of the methanol synthesis and shift reaction catalyst based on 30 at.% copper and 70 at.% zinc oxide, which was previously reported to be a mixture of hydrozincite Zn5(CO3)2(OH)6 and rosasite (Cu,Zn)2(CO3)(OH)2 (R. G. Herman, K. Klier, G. W. Simmons, B. P. Finn, J. B. Bulko, and T. P. Kobylinski, J. Catal. 56, 407, 1979) or a single-phase hydrozincite (G. Petrini, F. Montino, A. Bossi, and G. Gaybassi, in “Studies in Surface Science and Catalysis. Preparation of Catalysis III” (G. Poncelet, P. Grange, and P. A. Jacobs, Eds.), Vol. 16, p. 735. Elsevier, The Netherlands, 1983), is herein shown to be a single-phase aurichalcite (Cu0.3Zn0.7)5(CO3)2(OH)6. The orthorhombic B2212 aurichalcite is crystallograpically distinct from the monoclinic \\{C2m\\} hydrozincite, although these two compounds have the same ratio of metal ions to carbonate and hydroxyl anions. Both aurichalcite and hydrozincite are chemically and structurally distinct from the monoclinic \\{P21a\\} rosasite. The earlier erroneous assignments are attributed to the structural similarity of the three hydroxycarbonates in question. An energy-dispersive characteristic X-ray emission analysis of individual particles in the scanning transmission electron microscope reveals a uniform distribution of copper and zinc at the analytical concentration CuZn = 3070. Precursors with less than 30% copper consist of mixtures of aurichalcite and hydrozincite.

P.B. Himelfarb; G.W. Simmons; K. Klier; R.G. Herman

1985-01-01T23:59:59.000Z

336

Zinc oxide nanoparticles as novel alpha-amylase inhibitors  

Science Journals Connector (OSTI)

Amylase inhibitors also known as starch blockers contain substances that prevent dietary starches from being absorbed by the body via inhibiting breakdown of complex sugars to simpler ones. In this sense these materials are projected as having potential applications in diabetes control. In this context we report on zinc oxide nanoparticles as possible alpha-amylase inhibitors. Zinc oxide nanoparticles have been synthesized using soft-chemistry approach and 1-thioglycerol was used as a surfactant to yield polycrystalline nanoparticles of size ? 18 ? nm stabilized in wurtzite structure. Conjugation study and structural characterization have been done using x-ray diffraction technique Fourier transform infrared spectroscopy UV-visible spectroscopy and transmission electron microscopy. Cytotoxicity studies on human fibrosarcoma (HT-1080) and skin carcinoma (A-431) cell lines as well as mouse primary fibroblast cells demonstrate that up to a dose of 20 ? ? g / ml ZnOnanoparticles are nontoxic to the cells. We report for the first time the alpha-amylase inhibitory activity of ZnOnanoparticles wherein an optimum dose of 20 ? ? g / ml was sufficient to exhibit 49% glucose inhibition at neutral p H and 35 ? ° C temperature. This inhibitory activity was similar to that obtained with acarbose (a standard alpha-amylase inhibitor) thereby projecting ZnOnanoparticles as novel alpha-amylase inhibitors.

Sandip Dhobale; Trupti Thite; S. L. Laware; C. V. Rode; Soumya J. Koppikar; Ruchika-Kaul Ghanekar; S. N. Kale

2008-01-01T23:59:59.000Z

337

Induced Positron Annihiliation Investigation of Cadmium Zinc Telluride Crystal Microstructures  

SciTech Connect (OSTI)

Cadmium-Zinc-Telluride (CZT) crystals are used in semiconductor radiation detectors for the detection of x-ray and gamma radiation. However, production of detector grade crystals is difficult as small variations in compositional uniformity and primarily the zinc content can significantly affect the ability of the CZT crystal to function as a radiation detector. Currently there are no known nondestructive methods that can be used to identify detector grade crystals. The current test method is to fabricate and test the detector to determine if the crystal is sufficiently uniform and of the correct composition to be considered a detector grade crystal. Consequently, nondestructive detection methods are needed to identify detector grade crystals prior to the fabrication process. The purpose of this feasibility study was to perform a preliminary assessment of the ability of several new, nondestructive technologies based on Induced Positron Annihilation (IPA) to determine if detector grade CZT crystals can be identified. Results of measurements performed on specimens from Fisk University and EV Products, Inc. indicate that both the near surface Distributed Source Positron Annihilation (up to 3 mm penetration) and the volumetric Photon Induced Positron Annihilation methods may be suitable for determining CZT crystal quality. Further work on CZT crystals with a broader range of compositions and detector characteristics is needed to provide a well defined, calibrated, method for assessing CZT crystal quality.

D. W. Akers

2005-06-01T23:59:59.000Z

338

Third order nonlinear optical properties of bismuth zinc borate glasses  

SciTech Connect (OSTI)

Third order nonlinear optical characterization of bismuth zinc borate glasses are reported here using different laser pulse durations. Bismuth zinc borate glasses with compositions xBi{sub 2}O{sub 3}-30ZnO-(70-x) B{sub 2}O{sub 3} (where x?=?30, 35, 40, and 45?mol. %) have been prepared by melt quenching method. These glasses were characterized by Raman, UV-Vis absorption, and Z scan measurements. Raman and UV-Vis spectroscopic results indicate that non-bridging oxygens increase with increase of bismuth content in the glass. Nonlinear absorption and refraction behavior in the nanosecond (ns), picosecond (ps), and femtosecond (fs) time domains were studied in detail. Strong reverse saturable absorption due to dominant two-photon absorption (TPA) was observed with both ps and fs excitations. In the case of ns pulse excitations, TPA and free-carrier absorption processes contribute for the nonlinear absorption. Two-photon absorption coefficient (?) and the absorption cross section due to free carriers (?{sub e}) are estimated by theoretical fit of the open aperture Z-scan measurements and found to be dependent on the amount of bismuth oxide in the glass composition. In both ns and fs regimes the sign and magnitude of the third order nonlinearity are evaluated, and the optical limiting characteristics are also reported.

Shanmugavelu, B.; Ravi Kanth Kumar, V. V., E-mail: ravi.phy@pondiuni.edu.in [Department of Physics, Pondicherry University, Puducherry 605 014 (India); Kuladeep, R.; Narayana Rao, D. [School of Physics, University of Hyderabad, Hyderabad 500046, Andhra Pradesh (India)

2013-12-28T23:59:59.000Z

339

STATEMENT OF CONSIDERATIONS REQUEST BY UNIVERSAL AGGREGATES, LLC, FOR AN ADVANCE WAIVER OF  

Broader source: Energy.gov (indexed) [DOE]

UNIVERSAL AGGREGATES, LLC, FOR AN ADVANCE WAIVER OF UNIVERSAL AGGREGATES, LLC, FOR AN ADVANCE WAIVER OF DOMESTIC AND FOREIGN INVENTION RIGHTS UNDER DOE COOPERATIVE AGREEMENT NO. DE-FC26-02NT41421; W(A)-02-049, CH-1108 The Petitioner, Universal Aggregates, LLC, was awarded this cooperative agreement for the performance of work entitled, "Commercial Demonstration of the Manufactured Aggregate Processing Technology Utilizing Spray Dryer Ash." The purpose of the cooperative agreement is to design, construct and operate a lightweight aggregate manufacturing plant at the Birchwood Power Facility in King George, Virginia. A successful demonstration would lead to additional lightweight aggregate manufacturing facilities in the United States. There are currently twenty-one spray dryer facilities operating in the United States that produce an adequate amount of spray

340

CHEMICAL STABILITY OF POLYPHENYLENE SULFIDE IN THE NEXT GENERATION SOLVENT FOR CAUSTIC-SIDE SOLVENT EXTRACTION  

SciTech Connect (OSTI)

The Office of Waste Processing, within the Office of Technology Innovation and Development, is funding the development of an enhanced solvent for deployment at the Savannah River Site for removal of cesium from High Level Waste. For simplicity, this solvent is referred to as the Next Generation Solvent (NGS). The technical effort is collaboration between Oak Ridge National Laboratory (ORNL), Savannah River National Laboratory (SRNL), and Argonne National Laboratory. The initial deployment target envisioned for the technology was within the Modular Caustic-Side Solvent Extraction Unit (MCU). Deployment of a new chemical within an existing facility requires verification that the chemical components are compatible with the installed equipment. In the instance of a new organic solvent, the primary focus is on compatibility of the solvent with polyphenylene sulfide (PPS), the polymer used in the coalescers within MCU. This report provides the data from exposing PPS polymer to NGS. The test was conducted over a three month period. PPS is remarkably stable in the presence of the next generation solvent. Testing showed no indication of swelling or significant leaching. Preferential sorption of the Modifier on PPS was observed but the same behavior occurs with the baseline solvent. Therefore, PPS coalescers exposed to the NGS are expected to perform comparably to those in contact with the baseline solvent.

Fondeur, F.; Fink, S.

2011-12-08T23:59:59.000Z

Note: This page contains sample records for the topic "zinc sulfide aggregation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts  

SciTech Connect (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 130-156 seconds at 120-140 C to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases, evaluate removal capabilities of hydrogen sulfide and COS from coal gases with formulated catalysts, and develop an economic regeneration method of deactivated catalysts. Simulated coal gas mixtures consist of 3,300-3,800-ppmv hydrogen sulfide, 1,600-1,900 ppmv sulfur dioxide, 18-21 v% hydrogen, 29-34 v% CO, 8-10 v% CO{sub 2}, 5-18 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 114-132 SCCM. The temperature of the reactor is controlled in an oven at 120-140 C. The pressure of the reactor is maintained at 116-129 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is

K. C. Kwon

2007-09-30T23:59:59.000Z

342

Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts  

SciTech Connect (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash coat, and catalytic metals, to develop a regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor. The task of developing kinetic rate equations and modeling the direct oxidation process to assist in the design of large-scale plants will be abandoned since formulation of catalysts suitable for the removal of H{sub 2}S and COS is being in progress. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 46-570 seconds under reaction conditions to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases and evaluate their capabilities in reducing hydrogen sulfide and COS in coal gases. Simulated coal gas mixtures consist of 3,200-4,000-ppmv hydrogen sulfide, 1,600-20,000-ppmv sulfur dioxide, 18-27 v% hydrogen, 29-41 v% CO, 8-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of simulated coal gas mixtures to the reactor are 30 - 180 cm{sup 3}/min at 1 atm and 25 C (SCCM). The temperature of the reactor is controlled in an oven at 120-155 C. The pressure of the reactor is maintained at 40-210 psia. The molar ratio

K.C. Kwon

2009-09-30T23:59:59.000Z

343

Transition-metal doped sulfide, selenide, and telluride laser crystal and lasers  

DOE Patents [OSTI]

A new class of solid state laser crystals and lasers are formed of transition metal doped sulfide, selenide, and telluride host crystals which have four fold coordinated substitutional sites. The host crystals include II-VI compounds. The host crystal is doped with a transition metal laser ion, e.g., chromium, cobalt or iron. In particular, Cr{sup 2+}-doped ZnS and ZnSe generate laser action near 2.3 {micro}m. Oxide, chloride, fluoride, bromide and iodide crystals with similar structures can also be used. Important aspects of these laser materials are the tetrahedral site symmetry of the host crystal, low excited state absorption losses and high luminescence efficiency, and the d{sup 4} and d{sup 6} electronic configurations of the transition metal ions. The same materials are also useful as saturable absorbers for passive Q-switching applications. The laser materials can be used as gain media in amplifiers and oscillators; these gain media can be incorporated into waveguides and semiconductor lasers. 18 figs.

Krupke, W.F.; Page, R.H.; DeLoach, L.D.; Payne, S.A.

1996-07-30T23:59:59.000Z

344

Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts  

SciTech Connect (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2} in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. To achieve the above-mentioned objectives using a monolithic catalyst reactor, experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 40-560 seconds at 120-150 C to evaluate effects of reaction temperatures, total pressure, space time, and catalyst regeneration on conversion of hydrogen sulfide into elemental sulfur and formation of COS. Simulated coal gas mixtures consist of 3,600-4,000-ppmv hydrogen sulfide, 1,800-2,000 ppmv sulfur dioxide, 23-27 v% hydrogen, 36-41 v% CO, 10-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 30-180 SCCM. The temperature of the reactor is controlled in an oven at 120-150 C. The pressure of the reactor is maintained at 40-210 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is mai

K. C. Kwon

2006-09-30T23:59:59.000Z

345

Pyrophyllite and pyrophyllite raw materials in the sulfide-bearing areas of the Urals  

Science Journals Connector (OSTI)

Pyrophyllite, Al2(Si4O10) (OH)2, was discovered for the first time in the Urals, in 1829, occurring in quartz veins of the Berezovsk gold-beresite deposit. At present, 6 types of pyrophyllite mineralization occurrences are known in the region. Pyrophyllite-containing metasomatites in areas with massive sulfide mineralization are the most interesting for practical purposes. They are confined to Devonian palaeo-island arcs formed on the margin of the Urals palaeo-ocean. While studying the Gay and Kul-Yurt-Tau deposits, it was discovered that productive metasomatites occur in the flanks and roofs of rhyolite-dacite domes. Depending on the ratio of pyrophyllite, diaspore, sericite, kaolinite and quartz, several types of pyrophyllite raw material can be distinguished. Quartz-sericite-pyrophyllitic rocks are the most suitable for ceramic production. They have an elevated content of alkalis that promote sintering in the range of 1100 to 1200°C. Pyrophyllitic, pyrophyllite-diasporic, and pyrophyllite-quartz varieties can be used for production of fireproof materials. Sometimes, besides ordinary pyrophyllite of the 2M + 1Tc polytype, chromiferous pyrophyllite of the 1Tc polytype is present. Processes like synvolcanic metasomatism, dynamometamorphism and atmospheric weathering have played an important role in the formation of pyrophyllite ore bodies.

V.V. Zaykov; V.N. Udachin

1994-01-01T23:59:59.000Z

346

E-Print Network 3.0 - aggregated amyloid beta Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

search results for: aggregated amyloid beta Page: << < 1 2 3 4 5 > >> 1 NATURE NANOTECHNOLOGY | ADVANCE ONLINE PUBLICATION | www.nature.comnatureology 1 wide range of natural...

347

E-Print Network 3.0 - aggregated immunoglobulin e-receptor Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

immunoglobulin e-receptor Search Powered by Explorit Topic List Advanced Search Sample search results for: aggregated immunoglobulin e-receptor Page: << < 1 2 3 4 5 > >> 1...

348

Energy landscapes for protein folding, binding, and aggregation : simple funnels and beyond  

E-Print Network [OSTI]

coordinates capture protein folding on smooth landscapes.in the Prediction of Protein Folding Kinetics. Proc. Natl.Landscapes for Protein Folding, Binding, and Aggregation:

Cho, Samuel Sung-Il

2007-01-01T23:59:59.000Z

349

Optimal Participation of DR Aggregators in Day-Ahead Energy and Demand Response Exchange Markets  

Science Journals Connector (OSTI)

Aggregating the Demand Response (DR) is approved as an effective ... transmission system operator, distributors, and retailers in Demand Response eXchange (DRX) market, in addition to...

Ehsan Heydarian-Forushani…

2014-01-01T23:59:59.000Z

350

E-Print Network 3.0 - amyloid beta aggregation Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

search results for: amyloid beta aggregation Page: << < 1 2 3 4 5 > >> 1 NATURE NANOTECHNOLOGY | ADVANCE ONLINE PUBLICATION | www.nature.comnatureology 1 wide range of natural...

351

E-Print Network 3.0 - anionic surfactant aggregation Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Chemical Society. 1155 Sixteenth Street Summary: -organized aggregate. Therefore, the self-assembly behavior of bivalent or multivalent cationic-anionic surfactant......

352

E-Print Network 3.0 - aggregation prone regions Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Massachusetts Institute of Technology (MIT) Collection: Biology and Medicine 7 Protein folding in the cell: reshaping the folding funnel Summary: , as a second aggregation'...

353

E-Print Network 3.0 - aggregate concrete beams Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

concrete beams Search Powered by Explorit Topic List Advanced Search Sample search results for: aggregate concrete beams Page: << < 1 2 3 4 5 > >> 1 Technical Report Documentation...

354

E-Print Network 3.0 - affect aggregate turnover Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of GRSP research has focused on its relationship with aggregate water stability... ecosystem warming positively affects arbuscular mycor- rhizae but ... Source: Rilli, Matthias...

355

Integration of an Aggregate Flow Model with a Traffic Flow Simulator  

E-Print Network [OSTI]

Evaluation Tool (FACET). Using delay predictions, system metrics, and a visualization of the aggregated) solutions for weather disturbances. I. Introduction A. The Need for System Modeling. TFM initiatives

356

Impact of Transportation on Cost, Energy and Particulate Emissions for Recycled Concrete Aggregate.  

E-Print Network [OSTI]

??IMPACT OF TRANSPORTATION ON COST, ENERGY AND PARTICULATE EMISSIONS FOR RECYCLED CONCRETE AGGREGATE Transportation distances can have a huge impact on cost, energy, and particulate… (more)

Hameed, Mohamed

2009-01-01T23:59:59.000Z

357

E-Aggregation: The Present and Future of Online Financial Services in Asia-Pacific  

E-Print Network [OSTI]

Many financial institutions have built websites to inform and attract customers. Financial aggregation present an opportunity by which they can build stronger ...

Fujii, Hiroshi

2003-02-10T23:59:59.000Z

358

Effect of morphology and solvent on two-photon absorption of nano zinc oxide  

SciTech Connect (OSTI)

Highlights: ? ZnO nanospheres and triangular structures synthesis by novel precipitation technique. ? The effect of precursor concentration on the size and shape of nano ZnO. ? Open aperture Z-scan measurements of the ZnO nanoparticle dispersions. ? Nanospheres exhibit higher two photon absorption coefficient than triangular nanostructures. ? Nanospheres dispersed in water exhibit higher two photon absorption coefficient than its dispersion in 2-propanol. - Abstract: In this paper, we report the effect of morphology and solvent on the two-photon absorption of nano zinc oxide. Zinc oxide nanoparticles in two different morphologies like nanospheres and triangular nanostructures are synthesized by novel precipitation technique and their two-photon absorption coefficient is measured using open aperture Z-scan technique. Experimental results show that the zinc oxide nanospheres exhibit higher two-photon absorption coefficient than the zinc oxide triangular nanostructures. The zinc oxide nanospheres dispersed in water exhibit higher two-photon absorption coefficient than that of its dispersion in 2-propanol. The zinc oxide nanospheres dispersed in water shows a decrease in two-photon absorption coefficient with an increase in on-axis irradiance. The result confirms the dependence of shape and solvent on the two-photon absorption of nano zinc oxide.

Kavitha, M.K. [Department of Chemistry, Indian Institute of Space Science and Technology, Valiamala, Thiruvananthapuram 695547, Kerala (India); Haripadmam, P.C.; Gopinath, Pramod; Krishnan, Bindu [Department of Physics, Indian Institute of Space Science and Technology, Valiamala, Thiruvananthapuram 695547, Kerala (India); John, Honey, E-mail: honey@iist.ac.in [Department of Chemistry, Indian Institute of Space Science and Technology, Valiamala, Thiruvananthapuram 695547, Kerala (India)

2013-05-15T23:59:59.000Z

359

The magnetic properties of the iron-rich, iron-nickel-zinc alloys  

E-Print Network [OSTI]

this density. The samples were again sealed in steel jackets with a 12 small amount of zinc to maintain the vapor pressure high enough to al- low the impregnated zinc to remain in the samples. The jacketed speci- 0 mens were heated to 1000 C for two hours.... This curve indicated that the coercive force is strongly affected by the zinc content of the al- loy. Fig, 12 is a plot of hardness against nickel content. The 10 w/o Zn al'loys gave the greatest hardness with low nickel content. As the nickel content...

Gupton, Paul Stephen

1961-01-01T23:59:59.000Z

360

COMMERCIAL DEMONSTRATION OF THE MANUFACTURED AGGREGATE PROCESSING TECHNOLOGY UTILIZING SPRAY DRYER ASH  

SciTech Connect (OSTI)

Universal Aggregates, LLC proposes to design, construct and operate a lightweight aggregate manufacturing plant at the Birchwood Power Facility in King George, Virginia. The installation and start-up expenses for the Birchwood Aggregate Facility are $19.5 million. The DOE share is $7.2 million (37%) and the Universal Aggregates share is $12.3 (63%). The project team consists of CONSOL Energy Inc., P.J. Dick, Inc., SynAggs, LLC, and Universal Aggregates, LLC. The Birchwood Facility will transform 115,000 tons per year of spray dryer by-products that are currently being disposed of in an offsite landfill into 167,000 tons of a useful product, lightweight aggregates that can be used to manufacture lightweight aggregates that can be used to manufacture lightweight and medium weight masonry blocks. In addition to the environmental benefits, the Birchwood Facility will create nine (9) manufacturing jobs plus additional employment in the local trucking industry to deliver the aggregate to customers or reagents to the facility. A successful demonstration would lead to additional lightweight aggregate manufacturing facilities in the United States. There are currently twenty-one (21) spray dryer facilities operating in the United States that produce an adequate amount of spray dryer by-product to economically justify the installation of a lightweight aggregate manufacturing facility. Industry sources believe that as additional scrubbing is required, dry FGD technologies will be the technology of choice. Letters from potential lightweight aggregate customers indicate that there is a market for the product once the commercialization barriers are eliminated by this demonstration project.

Roy Scandrol

2003-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "zinc sulfide aggregation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

COMMERCIAL DEMONSTRATION OF THE MANUFACTURED AGGREGATE PROCESSING TECHNOLOGY UTILIZING SPRAY DRYER ASH  

SciTech Connect (OSTI)

Universal Aggregates, LLC proposes to design, construct and operate a lightweight aggregate manufacturing plant at the Birchwood Power Facility in King George, Virginia. The installation and start-up expenses for the Birchwood Aggregate Facility are $19.5 million. The DOE share is $7.2 million (37%) and the Universal Aggregates share is $12.3 (63%). The project team consists of CONSOL Energy Inc., P.J. Dick, Inc., SynAggs, LLC, and Universal Aggregates, LLC. The Birchwood Facility will transform 115,000 tons per year of spray dryer by-products that are currently being disposed of in an offsite landfill into 167,000 tons of a useful product, lightweight aggregates that can be used to manufacture lightweight aggregates that can be used to manufacture lightweight and medium weight masonry blocks. In addition to the environmental benefits, the Birchwood Facility will create eight (8) manufacturing jobs plus additional employment in the local trucking industry to deliver the aggregate to customers or reagents to the facility. A successful demonstration would lead to additional lightweight aggregate manufacturing facilities in the United States. There are currently twenty-one (21) spray dryer facilities operating in the United States that produce an adequate amount of spray dryer by-product to economically justify the installation of a lightweight aggregate manufacturing facility. Industry sources believe that as additional scrubbing is required, dry flue gas desulfurization (FGD) technologies will be the technology of choice. Letters from potential lightweight aggregate customers indicate that there is a market for the product once the commercialization barriers are eliminated by this demonstration project.

Roy Scandrol

2003-04-01T23:59:59.000Z

362

Zinc oxysulfide ternary alloy nanocrystals: A bandgap modulated photocatalyst  

SciTech Connect (OSTI)

Herein, we report a green economic route for the synthesis of a series of Zinc Oxysulfide (ZOS) (ZnO{sub 1-x}S{sub x}; 0 {<=} x {>=} 1; x = Sulfur) alloys nanoparticles. The crystallographic features of ZnO, ZOS, and ZnS confirmed by X-Ray Diffraction and validated by Transmission Electron Microscopy reveal the variation of lattice spacing in binary and ternary compositions with homogenous elemental distribution. The photocatalytic analysis of ZOS (0.4) is performed and compared with Degussa P25 to ascertain its photocatalytic activity against methyl orange under irradiation of 365 nm UV-Vis light. A bandgap of 2.7 eV for ZOS (0.4) aptly establishes its prospects for sunlight driven photocatalysis.

Pandey, Shiv K. [Department of Chemistry, MN National Institute of Technology, Allahabad (India) [Department of Chemistry, MN National Institute of Technology, Allahabad (India); Nanotechnology Application Centre, University of Allahabad, Allahabad (India); Pandey, Shipra; Pandey, Avinash C. [Nanotechnology Application Centre, University of Allahabad, Allahabad (India)] [Nanotechnology Application Centre, University of Allahabad, Allahabad (India); Mehrotra, G. K. [Department of Chemistry, MN National Institute of Technology, Allahabad (India)] [Department of Chemistry, MN National Institute of Technology, Allahabad (India)

2013-06-10T23:59:59.000Z

363

Study on thermal annealing of cadmium zinc telluride (CZT) crystals  

SciTech Connect (OSTI)

Cadmium Zinc Telluride (CZT) has attracted increasing interest with its promising potential as a room-temperature nuclear-radiation-detector material. However, different defects in CZT crystals, especially Te inclusions and dislocations, can degrade the performance of CZT detectors. Post-growth annealing is a good approach potentially to eliminate the deleterious influence of these defects. At Brookhaven National Laboratory (BNL), we built up different facilities for investigating post-growth annealing of CZT. Here, we report our latest experimental results. Cd-vapor annealing reduces the density of Te inclusions, while large temperature gradient promotes the migration of small-size Te inclusions. Simultaneously, the annealing lowers the density of dislocations. However, only-Cd-vapor annealing decreases the resistivity, possibly reflecting the introduction of extra Cd in the lattice. Subsequent Te-vapor annealing is needed to ensure the recovery of the resistivity after removing the Te inclusions.

Yang, G.; Bolotnikov, A.E.; Fochuk, P.M.; Camarda, G.S.; Cui, Y.; Hossain, A.; Kim, K.; Horace, J.; McCall, B.; Gul, R.; Xu, L.; Kopach, O.V.; and James, R.B.

2010-08-01T23:59:59.000Z

364

PREPRINT QUASIPARTICLE AGGREGATION I N THE FRACTIONAL QUANTUM HALL EFFECT  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

91618 91618 PREPRINT QUASIPARTICLE AGGREGATION I N THE FRACTIONAL QUANTUM HALL EFFECT R. B. Laughlin This paper was prepared for submittal to the Proceedings of the 17th International Conference on the Physics of Semi conductors San Francisco, California August 6-10, 1984 October 10, 1984 This is a preprint of a paper intended for publication in a journal or proceedings. Since changes may be made before publication, this preprint is made available with the un- derstanding that it will not be cited or reproduced without the permission of the author. DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency Thereof, nor any of their employees,

365

Selective Catalytic Oxidation of Hydrogen Sulfide to Elemental Sulfur from Coal-Derived Fuel Gases  

SciTech Connect (OSTI)

The development of low cost, highly efficient, desulfurization technology with integrated sulfur recovery remains a principle barrier issue for Vision 21 integrated gasification combined cycle (IGCC) power generation plants. In this plan, the U. S. Department of Energy will construct ultra-clean, modular, co-production IGCC power plants each with chemical products tailored to meet the demands of specific regional markets. The catalysts employed in these co-production modules, for example water-gas-shift and Fischer-Tropsch catalysts, are readily poisoned by hydrogen sulfide (H{sub 2}S), a sulfur contaminant, present in the coal-derived fuel gases. To prevent poisoning of these catalysts, the removal of H{sub 2}S down to the parts-per-billion level is necessary. Historically, research into the purification of coal-derived fuel gases has focused on dry technologies that offer the prospect of higher combined cycle efficiencies as well as improved thermal integration with co-production modules. Primarily, these concepts rely on a highly selective process separation step to remove low concentrations of H{sub 2}S present in the fuel gases and produce a concentrated stream of sulfur bearing effluent. This effluent must then undergo further processing to be converted to its final form, usually elemental sulfur. Ultimately, desulfurization of coal-derived fuel gases may cost as much as 15% of the total fixed capital investment (Chen et al., 1992). It is, therefore, desirable to develop new technology that can accomplish H{sub 2}S separation and direct conversion to elemental sulfur more efficiently and with a lower initial fixed capital investment.

Gardner, Todd H.; Berry, David A.; Lyons, K. David; Beer, Stephen K.; Monahan, Michael J.

2001-11-06T23:59:59.000Z

366

Exploring Aggregate Effect with Weighted Transcoding Graphs for Efficient Cache Replacement in Transcoding Proxies  

E-Print Network [OSTI]

Exploring Aggregate Effect with Weighted Transcoding Graphs for Efficient Cache Replacement University Taipei, Taiwan, ROC E-mail: {cychang@arbor.ee.ntu.edu.tw; mschen@cc.ee.ntu.edu.tw} Abstract This paper explores the aggregate effect when caching multiple versions of the same Web object

Chen, Ming-Syan

367

Polymer Thermodynamics and Chain Structure Polymers display some similarities and some differences with nano-aggregates.  

E-Print Network [OSTI]

for aggregates and by the late Paul Flory of Stanford for polymer coils. Since the spring constant of a polymer of a polymer coil is largely determined by entropy, an individual polymer coil displays an increasing spring an aggregate in nanomaterials and a polymer coil in Polymer Science. The mass-fractal or minimum dimension

Beaucage, Gregory

368

Structure and dynamics of the aggregation mechanism of the Parkinsons disease-associated protein  

E-Print Network [OSTI]

Structure and dynamics of the aggregation mechanism of the Parkinson´s disease-associated protein containing amyloid-like aggregates of the protein -synuclein (S) are deposited in the pigmented nuclei S to oligomeric neurotoxic forms of the protein are largely unknown. The major aim of this thesis has been

Jahn, Reinhard

369

In Situ Monitoring of 3D In Vitro Cell Aggregation Using An Optical Imaging System  

E-Print Network [OSTI]

analysis. We describe a system for the imaging and analysis of cell aggregation, over long periods, within and motion of the aggregates within the bio- reactor were obtained. Detailed size and population data have feedback system to control the growth of 3D cell cultures for repeatable, reliable, and quality controlled

Waters, Sarah

370

APPLICATION OF SYMBOLIC PIECEWISE AGGREGATE APPROXIMATION (PAA) ANALYSIS TO ECG SIGNALS  

E-Print Network [OSTI]

APPLICATION OF SYMBOLIC PIECEWISE AGGREGATE APPROXIMATION (PAA) ANALYSIS TO ECG SIGNALS Burcu) with Piecewise Aggregate Approximation (PAA). The same ECG series is symbolized first by PLA and then PAA. Coarsing the series by PLA proved to be more problematic than PAA. At coarser scales, details are lost

Kumova, Bora

371

Improved climate forecast accuracy: implications for the aggregate sorghum supply curve  

E-Print Network [OSTI]

for 19 sites, one in Australia (Jondaryan) and 18 in Texas, with and without SO information for five prices and three SO events. From these site yields expected aggregate supply curves weighted by hectares for Texas and Jondaryan are developed. Aggregated...

Hill, Harvey S. J.

2012-06-07T23:59:59.000Z

372

Power-aware MPI Task Aggregation Prediction for High-End Computing Systems Dimitrios S. Nikolopoulos  

E-Print Network [OSTI]

across the cores of multiple nodes impacts both execution time and energy. Current job management systems solutions. Task aggregation significantly impacts energy consump- tion. A job uses fewer nodes with a higher the execution time and energy implications of task aggregation (i.e., grouping multiple tasks within the same

373

Performance Enhancement of a Graphene-Zinc Phosphide Solar Cell Using the Electric Field-Effect  

E-Print Network [OSTI]

Performance Enhancement of a Graphene-Zinc Phosphide Solar Cell Using the Electric Field, University of California, Berkeley, California 94720, United States Material Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States § Department of Applied Physics

Javey, Ali

374

Understanding Zinc Quantification with Existing and Advanced Ditopic Fluorescent Zinpyr Sensors  

E-Print Network [OSTI]

Treatment of aqueous zinc solutions with incremental additions of a ditopic fluorescent sensor of the Zinpyr family, based on pyridine/pyrazine-containing metal recognition units, affords a fluorescence titration curve ...

Buccella, Daniela

375

Mixed sulphide–oxide lead and zinc ores: Problems and solutions  

Science Journals Connector (OSTI)

Mixed sulphide–oxide lead and zinc ores are most often found in the transition, and occasionally in the oxidised, zones of lead–zinc ore-bodies. They are of great importance because there are numerous unexploited or abandoned reserves of these ores in the world. However they present difficulties for conventional mineral processing due to complex mineralogy. In this paper, the specific problems associated with these types of ores are described and methods for solving these problems, combining economic and technical considerations, are discussed. The results of experiments carried out at laboratory scale are presented, in which the dissolution of mixed ore in sulphuric acid without oxidising agents was investigated. The results show the feasibility of zinc recovery from mixed sulphide–oxide lead and zinc ores, which underlines the potential of this approach. We also propose a conceptual flow diagram for the hydrometallurgical processing of these ores.

S. Moradi; A.J. Monhemius

2011-01-01T23:59:59.000Z

376

Ribosomal Zinc Finger Proteins: The Structure and the Function of Yeast YL37a  

Science Journals Connector (OSTI)

Zinc finger motifs are common in ribosomal proteins: they are widely distributed in nature, having been found amongst the proteins of both subunits of the ribosomes of all species examined in the three kingdom...

John Dresios; Yuen-Ling Chan; Ira G. Wool

2005-01-01T23:59:59.000Z

377

Comparison of Nanocomposites Prepared from Sodium, Zinc, and Lithium Ionomers of Ethylene/Methacrylic Acid Copolymers  

Science Journals Connector (OSTI)

Morphology and mechanical properties of nanocomposites prepared by melt mixing a montmorillonite-based organoclay with lithium, sodium, and zinc ionomers of poly(ethylene-co-methacrylic acid) are presented here. The effect of the type of neutralizing ...

Rhutesh K. Shah; D. R. Paul

2006-03-31T23:59:59.000Z

378

Dependence of the activation energy of vacancy formation on the zinc content in alpha brasses  

Science Journals Connector (OSTI)

Observations on quenched-in resistivity in alpha brasses showed an apparent decrease in the activation energy of vacancy formation with increasing zinc content from a value of 0·85 eV ... up to a concentration of...

R. Kamel; T. H. Youssef

1968-01-01T23:59:59.000Z

379

E-Print Network 3.0 - aluminum-doped zinc oxide Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

for the first time at 800 Torr... reserved. Keywords: Transparent-conducting oxide (TCO); AlZnO; PECVD 1. Introduction Aluminum-doped zinc... PECVD for the deposition of ......

380

Spin-dependent electron transport in zinc- and manganese-doped adenine molecules  

SciTech Connect (OSTI)

The spin-dependent electron transport properties of zinc- and manganese-doped adenine molecules connected to zigzag graphene leads are studied in the zero bias regime using the non-equilibrium Green's function method. The conductance of the adenine molecule increased and became spin-dependent when a zinc or manganese atom was doped into the molecules. The effects of a transverse electric field on the spin-polarization of the transmitted electrons were investigated and the spin-polarization was controlled by changing the transverse electric field. Under the presence of a transverse electric field, both the zinc- and manganese-doped adenine molecules acted as spin-filters. The maximum spin-polarization of the manganese-doped adenine molecule was greater than the molecule doped with zinc.

Simchi, Hamidreza, E-mail: simchi@iust.ac.ir [Department of Physics, Iran University of Science and Technology, Narmak, Tehran 16844 (Iran, Islamic Republic of); Semiconductor Technology Center, Tehran 16844 (Iran, Islamic Republic of); Esmaeilzadeh, Mahdi, E-mail: mahdi@iust.ac.ir; Mazidabadi, Hossein [Department of Physics, Iran University of Science and Technology, Narmak, Tehran 16844 (Iran, Islamic Republic of)

2014-01-28T23:59:59.000Z

Note: This page contains sample records for the topic "zinc sulfide aggregation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

CATALYTIC LIQUEFACTION BY ZINC CHLORIDE MELTS AT PRE-PYROLYSIS TEMPERATURE  

E-Print Network [OSTI]

3% Zn and 14% CH oH (50 g coal 9 300 g melt) Atomic TempVermeulen, "High-Yield Coal Conversion in a Zinc Chloride/H. Shinn, and T. Vermeulen, "Coal Lic;uefaction Catalysis by

Vermeulen, T.

2012-01-01T23:59:59.000Z

382

C:\Documents and Settings\burris\My Documents\My Files\Eco-SSLs\Contaminant Specific Documents\Zinc\June 2007\Eco-SSL for Zinc  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Zinc Zinc Interim Final OSWER Directive 9285.7-73 U.S. Environmental Protection Agency Office of Solid Waste and Emergency Response 1200 Pennsylvania Avenue, N.W. Washington, DC 20460 June 2007 This page intentionally left blank i TABLE OF CONTENTS 1.0 INTRODUCTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 2.0 SUMMARY OF ECO-SSLs FOR ZINC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 3.0 ECO-SSL FOR TERRESTRIAL PLANTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 4.0 ECO-SSL FOR SOIL INVERTEBRATES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 5.0 ECO-SSL FOR AVIAN WILDLIFE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 5.1 Avian TRV . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 5.2 Estimation of Dose and Calculation of the Eco-SSL . . . . . . . . . . . . . . . . . . . . . . . 14 6.0 ECO-SSL FOR MAMMALIAN WILDLIFE .

383

The effect of phosphorus and zinc on mineral nutrition and growth of flax plants  

E-Print Network [OSTI]

THE EFFECT OF PHOSPHORUS AND ZINC ON NINERAL NUTRITICN AND GROWTH OF FLAX PLANTS A THESIS PAUL B. I'IATOCHA, JR. Submitted to the Graduate College of the Texas AkN University in partial fulfillment oi' the requirements for the degree... of PASTER QF SCIENCE January 1967 Najor Subject: Agronomy THE EFFECT OF PHOSPHORUS AND ZINC GN MINERAL NUTRITION AND GROMTH OF FLAX PLANTS A Thesis PAUL B. MATOCHA, JR. Approved as to style and content by: (Chairman of Committee) ~v...

Matocha, Paul B

1967-01-01T23:59:59.000Z

384

Detector Performance of Ammonium-Sulfide-Passivated CdZnTe and CdMnTe Materials  

SciTech Connect (OSTI)

Dark currents, including those in the surface and bulk, are the leading source of electronic noise in X-ray and gamma detectors, and are responsible for degrading a detector's energy resolution. The detector material itself determines the bulk leakage current; however, the surface leakage current is controllable by depositing appropriate passivation layers. In previous research, we demonstrated the effectiveness of surface passivation in CZT (CdZnTe) and CMT (CdMnTe) materials using ammonium sulfide and ammonium fluoride. In this research, we measured the effect of such passivation on the surface states of these materials, and on the performances of detectors made from them.

Kim, K.H.; Bolotnikov, A.E.; Camarda, G.S.; Marchini, L.; Yang, G.; Hossain, A.; Cui, Y.; Xu, L.; and James, R.B.

2010-08-01T23:59:59.000Z

385

(Data in thousand metric tons of zinc content unless otherwise noted) Domestic Production and Use: The value of zinc mined in 2013, based on zinc contained in concentrate, was about  

E-Print Network [OSTI]

materials included galvanizing residues and crude zinc oxide processed from electric arc furnace dust. Import Sources (2009­12): Ore and concentrate: Peru, 76%; Ireland, 8%; Mexico, 8%; Canada, 7%; and other, 1%. Metal: Canada, 72%; Mexico, 13%; Peru, 7%; Spain, 2%; and other, 6%. Waste and scrap: Canada, 65

386

Effects of a sulfide system produced by a natural brine seep on sandy-bottom community structure at the East Flower Garden Bank, northwest Gulf of Mexico  

E-Print Network [OSTI]

EFFECTS OF A SULFIDE SYSTEM PRODUCED BY A NATURAL BRINE SEEP ON SANDY-BOTTOM COI'1MUNITY STRUCTURE AT THE EAST FLOWER GARDEN BANK, NORTHWEST GULF OF MEXICO A Thesis by EDWARD ANDREW WOODS Submitted to the Graduate College of Texas ASM... University in partia 1 fulfillment of the requirement for the degree of MASTER OF SCIENCE August 1982 Major Subject: Oceanography EFFECTS OF A SULFIDE SYSTEM PRODUCED BY A NATURAL BRINE SEEP ON SANDY-BOTTOM COMMUNITY STRUCTURE AT THE EAST FLOWER...

Woods, Edward Andrew

2012-06-07T23:59:59.000Z

387

Retaining the 3D Framework of Zinc Sponge Anodes upon Deep Discharge in Zn–Air Cells  

Science Journals Connector (OSTI)

zinc; zinc?air; batteries; morphology; energy; three-dimensional architecture ... Zinc-based batteries offer many appealing characteristics, including low-cost components, water-based electrolytes, and high energy density, yet their broader applicability has been limited by suboptimal performance of the Zn anode, which undergoes complex chemical and electrochemical reactions during operation. ... discharge depth-of-discharge specific capacityaverage dischargespecific energy Rcell,initialc Rcell,post?dischargec ...

Joseph F. Parker; Eric S. Nelson; Matthew D. Wattendorf; Christopher N. Chervin; Jeffrey W. Long; Debra R. Rolison

2014-10-28T23:59:59.000Z

388

Ordered Nucleation Sites for the Growth of Zinc Oxide Nanofibers  

SciTech Connect (OSTI)

Organic photovoltaics (OPVs) offer a promising route to low cost photovoltaic (PV) technology that can be inexpensively manufactured on a large scale for use in power generation and commercial products. Solar power conversion efficiencies of laboratory scale OPV devices have recently reached ~5%; however, projected efficiencies of at least 10% will be required for commercialization. An analogous approach that has arisen recently that can potentially increase efficiencies employs metal oxide semiconductors as the electron acceptor, creating a hybrid organic-inorganic device. This approach offers the advantage that the conduction band of the oxide can be tuned in a systematic way through doping, thus potentially achieving higher photovoltages in the device. Additionally, nanostructures of these materials can be easily grown from precursor solutions, providing a technique to precisely control the nanoscale geometry. This work focuses on using ZnO, which is known to have high electron mobility (>100 cm2/Vs), as the electron acceptor. Nanofibers of ZnO can be grown from precursors such as zinc acetate or zinc nitrate to form arrays of nanofibers into which a conjugated polymer can be intercalated to form a composite PV device. The morphology of the nanofiber array is critical to the performance of the device, but current methods of nanofiber growth from a flat, polycrystalline nucleation layer allow for little morphological control. To overcome this limitation, we have created ordered arrays of ZnO nucleation sites with controllable size and spacing. Toluene solutions of diblock copolymer micelles with ZnCl2 incorporated into the micellar cores were spin-coated onto glass substrates and etched with an O2 plasma to yield hexagonally ordered arrays of ZnO nanoparticles that functioned as nucleation sites. Changing the concentration of ZnCl2 and the molecular weight and ratio of the diblock copolymer resulted in systematic variation in the size and spacing of the nucleation sites. Thermal anneal treatment provided further modification of the nucleation layer, from which ZnO nanofibers were successfully grown from solution, although at present it is not known if the geometry of the as-grown ZnO nanofibers precisely reflects that of the underlying nucleation layer. This work provides a simple and useful method for potentially controlling the nucleation of ZnO nanofibers to be used in hybrid ZnO/organic nanocomposite PV devices.

Wang, J.; Ginley, D.S.; Shaheen, S.

2006-01-01T23:59:59.000Z

389

DURABILITY EVALUATION AND PRODUCTION OF MANUFACTURED AGGREGATES FROM COAL COMBUSTION BY-PRODUCTS  

SciTech Connect (OSTI)

Under the cooperative agreement with DOE, the Research and Development Department of CONSOL Energy (CONSOL R&D), teamed with Universal Aggregates, LLC, to conduct a systematic study of the durability of aggregates manufactured using a variety of flue gas desulfurization (FGD), fluidized-bed combustion (FBC) and fly ash specimens with different chemical and physical properties and under different freeze/thaw, wet/dry and long-term natural weathering conditions. The objectives of the study are to establish the relationships among the durability and characteristics of FGD material, FBC ash and fly ash, and to identify the causes of durability problems, and, ultimately, to increase the utilization of FGD material, FBC ash and fly ash as a construction material. Manufactured aggregates made from FGD material, FBC ash and fly ash, and products made from those manufactured aggregates were used in the study. The project is divided into the following activities: sample collection and characterization; characterization and preparation of manufactured aggregates; determination of durability characteristics of manufactured aggregates; preparation and determination of durability characteristics of manufactured aggregate products; and data evaluation and reporting.

M. M. Wu

2005-02-01T23:59:59.000Z

390

Assessment of sustainable development in the EU 27 using aggregated SD index  

Science Journals Connector (OSTI)

Abstract In the European Union the sustainable development is a fundamental and overarchingobjective enshrined in the Treaty and measuring progress towards sustainable development is an integral part of the EU Sustainable Development Strategy. Eurostat produce a monitoring report every two years based on the EU set of sustainable development indicators (SDIs). The main objective of this paper is to create an aggregated index of the sustainable development from EU set of \\{SDIs\\} for each 27 EU country based on the PCA. The headline indicator economic growth was not involved because its increase is not expressly followed by positive change in other \\{SDIs\\} from social, economic and environmental fields. The aggregated SD index enables to get an overall picture about the position of each of the 27 EU countries and its development in terms of the sustainability over time as assumed in the EU Sustainable Development Strategy. Sweden, Denmark, Netherland, and Great Britain have repeatedly reached the highest value of aggregated SD index. The highest positive change in the aggregated SD index has occurred in countries with the lowest value of aggregated SD index. Moreover, we put this new aggregated index in relation with economic growth and found that there is a negative correlation between aggregated SD index and the economic growth for most of the 27 EU countries.

Paula Bolcárová; Stanislav Kološta

2015-01-01T23:59:59.000Z

391

Structural basis for the selective nuclear import of the C2H2 zinc-finger protein Snail by importin  

Science Journals Connector (OSTI)

The X-ray structure of the complex of the nuclear transporter importin with the zinc-finger-type transcription regulator Snail1 is reported.

Choi, S.

2014-03-19T23:59:59.000Z

392

A new spatio-temporal prediction approach based on aggregate queries  

Science Journals Connector (OSTI)

The prediction of spatio-temporal data streams which is based on aggregate queries has been an important research direction in the research field of databases. More and more methods have been proposed to obtain approximate aggregate results. However, they will consume a lot of time and storage space. This paper proposes Dynamic Sketch (DS) index by using modified method of Adaptive Multi-dimensional Histogram (AMH*) to intelligently partition static sketch which can improve the approximate quality of aggregate queries in road networks. Then, based on DS index, this paper proposes a new prediction approach over data streams in road networks using Self-Adaptive Exponential Smoothing (SAES).

Jun Feng; Zhonghua Zhu; Yaqing Shi; Liming Xu

2013-01-01T23:59:59.000Z

393

Method for the production of cementitious compositions and aggregate derivatives from said compositions  

DOE Patents [OSTI]

Method for the production of cementitious compositions and aggregate derivatives of said compositions, and cementitious compositions and aggregates produced by said method, wherein fluidized bed combustion residue and pozzolanic material, such as pulverized coal combustion system fly ash, are incorporated in a cementitious mix. The mix is cast into desired shape and cured. If desired, the shape may then be crushed so as to result in a fluidized bed combustion residue-fly ash aggregate material or the shape may be used by itself.

Minnick, L. John (Box 271, Plymouth Meeting, PA 19462)

1981-01-01T23:59:59.000Z

394

Thermodynamics of Peptide Aggregation Processes. An Analysis from Perspectives of Three Statistical Ensembles  

E-Print Network [OSTI]

We employ a mesoscopic model for studying aggregation processes of protein-like hydrophobic-polar heteropolymers. By means of multicanonical Monte Carlo computer simulations, we find strong indications that peptide aggregation is a phase separation process, in which the microcanonical entropy exhibits a convex intruder due to nonnegligible surface effects of the small systems. We analyze thermodynamic properties of the conformational transitions accompanying the aggregation process from the multicanonical, canonical, and microcanonical perspective. It turns out that the microcanonical description is particularly advantageous as it allows for unraveling details of the phase-separation transition in the thermodynamic region, where the temperature is not a suitable external control parameter anymore.

Christoph Junghans; Michael Bachmann; Wolfhard Janke

2007-12-06T23:59:59.000Z

395

Ambient temperature cadmium zinc telluride radiation detector and amplifier circuit  

DOE Patents [OSTI]

A low noise, low power consumption, compact, ambient temperature signal amplifier for a Cadmium Zinc Telluride (CZT) radiation detector. The amplifier can be used within a larger system (e.g., including a multi-channel analyzer) to allow isotopic analysis of radionuclides in the field. In one embodiment, the circuit stages of the low power, low noise amplifier are constructed using integrated circuit (IC) amplifiers , rather than discrete components, and include a very low noise, high gain, high bandwidth dual part preamplification stage, an amplification stage, and an filter stage. The low noise, low power consumption, compact, ambient temperature amplifier enables the CZT detector to achieve both the efficiency required to determine the presence of radio nuclides and the resolution necessary to perform isotopic analysis to perform nuclear material identification. The present low noise, low power, compact, ambient temperature amplifier enables a CZT detector to achieve resolution of less than 3% full width at half maximum at 122 keV for a Cobalt-57 isotope source. By using IC circuits and using only a single 12 volt supply and ground, the novel amplifier provides significant power savings and is well suited for prolonged portable in-field use and does not require heavy, bulky power supply components.

McQuaid, James H. (Livermore, CA); Lavietes, Anthony D. (Hayward, CA)

1998-05-29T23:59:59.000Z

396

Degradation characteristics of air cathode in zinc air fuel cells  

Science Journals Connector (OSTI)

Abstract The zinc air fuel cell (ZAFC) is a promising candidate for electrical energy storage and electric vehicle propulsion. However, its limited durability has become a major obstacle for its successful commercialization. In this study, 2-cell stacks, 25 cm² cells and three-electrode half-cells are constructed to experimentally investigate the degradation characteristics of the air cathode. The results of electrochemical tests reveal that the peak power density for the 25 cm2 cell with a new air cathode is 454 mW cm?2, which is twice as the value of the used air cathode. The electrochemical impedance analysis shows that both the charge transfer resistance and the mass transfer resistance of the used air cathodes have increased, suggesting that the catalyst surface area and gas diffusion coefficient have decreased significantly. Additionally, the microstructure and morphology of the catalytic layer (CL) and gas diffusion layer (GDL) are characterized by scanning electron microscopes (SEM). SEM results confirm that the micropores in CL and GDL of the used air cathode are seriously clogged, and many catalyst particles are lost. Therefore, the performance degradation is mainly due to the clogging of micropores and loss of catalyst particles. Furthermore, hypotheses of degradation mechanism and mitigation strategies for GDL and CL are discussed briefly.

Ze Ma; Pucheng Pei; Keliang Wang; Xizhong Wang; Huachi Xu; Yongfeng Liu; Guanlin peng

2015-01-01T23:59:59.000Z

397

Ambient temperature cadmium zinc telluride radiation detector and amplifier circuit  

DOE Patents [OSTI]

A low noise, low power consumption, compact, ambient temperature signal amplifier for a Cadmium Zinc Telluride (CZT) radiation detector is disclosed. The amplifier can be used within a larger system (e.g., including a multi-channel analyzer) to allow isotopic analysis of radionuclides in the field. In one embodiment, the circuit stages of the low power, low noise amplifier are constructed using integrated circuit (IC) amplifiers , rather than discrete components, and include a very low noise, high gain, high bandwidth dual part preamplification stage, an amplification stage, and an filter stage. The low noise, low power consumption, compact, ambient temperature amplifier enables the CZT detector to achieve both the efficiency required to determine the presence of radionuclides and the resolution necessary to perform isotopic analysis to perform nuclear material identification. The present low noise, low power, compact, ambient temperature amplifier enables a CZT detector to achieve resolution of less than 3% full width at half maximum at 122 keV for a Cobalt-57 isotope source. By using IC circuits and using only a single 12 volt supply and ground, the novel amplifier provides significant power savings and is well suited for prolonged portable in-field use and does not require heavy, bulky power supply components. 9 figs.

McQuaid, J.H.; Lavietes, A.D.

1998-05-26T23:59:59.000Z

398

Adhesion properties of polyelectrolyte-chemisorbed zinc phosphate conversion coatings  

SciTech Connect (OSTI)

It has been reported that when mild carbon cold-rolled steels are immersed in the Zn/sub 3/(PO/sub 4/)/sub 2/ . 2H/sub 2/O-H/sub 3/PO/sub 4/-H/sub 2/O solution systems, the surface microfeatures of crystalline zinc phosphate (Zn . Ph) conversion coating deposited on the steel substrate surface were characterized by large rectangular-like crystal arrays of insoluble Zn . Ph hydrate. Deformation failures of layers having low stiffness characteristics appear to be directly related to the development of micropores and fissures which reduce the effectiveness of the corrosion-resistant coatings. Thus, it is necessary to increase the flexural modulus of the layers in order to restrain the physical deformation failures of the crystalline precoats. The brittle characteristics of the Zn . Ph can be modified by the introduction of the polyacrylic acid (PAA) macromolecules into the phosphating solutions. The incorporation of PAA, which is generally expressed as a polyelectrolyte macromolecule, was shown to form a highly dense fine crystal topography, suggesting that the crystal formation results in an improvement in the stiffness and ductility characteristics of the normally brittle Zn . Ph layers. Accordingly, emphasis of the present paper is given to the finding as to how the molecular structures and functional species of polyelectrolytes act to suppress crystal growth of Zn . Ph and improve interfacial bond durability of Zn . Ph-to-polymeric adhesive joints. 2 refs., 5 figs.

Sugama, T.

1986-10-01T23:59:59.000Z

399

Threshold concentrations in zinc-doped lithium niobate crystals and their structural conditionality  

SciTech Connect (OSTI)

On the basis of precise X-ray diffraction study of lithium niobate single crystals of congruent composition and four zinc-doped (at 2.8, 5.2, 7.6, and 8.2 mol %) crystals, structural conditionality of the threshold concentrations of the dopant has been established. At these concentrations, the mechanism of zinc incorporation into crystal changes. As the zinc concentration increases, this element first substitutes excess niobium, localized in lithium positions, with a simultaneous decrease in the number of vacancies in these positions. Then zinc substitutes lithium with formation of new lithium vacancies. When a certain limit on the number of vacancies is reached, zinc begins to substitute niobium in its main positions. This process is naturally accompanied by a decrease in the number of vacancies to their complete disappearance and formation of a self-compensating crystal. The character of the dependence of the crystal physical properties on the dopant concentration changes specifically when the impurity concentration passes through the threshold values.

Chernaya, T. S.; Volk, T. R.; Verin, I. A.; Simonov, V. I., E-mail: simonov@ns.crys.ras.ru [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation)

2008-07-15T23:59:59.000Z

400

Carbon and oxygen isotope halos in the host limestone, El Mochito Zn-Pb-(Ag) skarn massive sulfide-oxide deposit, Honduras  

Science Journals Connector (OSTI)

...sulfide-oxide deposit, Honduras Rodrigo Vazquez Torsten W. Vennemann...deposit, Honduras Vazquez Rodrigo Author University of Michigan...Valanginian Barriasien Todos Santos Fm, Upper Jurassic Middle...Yojoa Nueva Main I 4000 Todos Santos Fm. Faults 6000 8000 10000...

Rodrigo Vazquez; Torsten W. Vennemann; Stephen E. Kesler; Norman Russell

Note: This page contains sample records for the topic "zinc sulfide aggregation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Reply to comments by L.J. Cabri on "Changes in sulfides and platinum-group minerals with the degree of alteration  

E-Print Network [OSTI]

is not applicable for our purpose. In our studies, the mass balance calculation is secondary to the petrogenetic) and Ni deposits, we carried out our mass balance calculations using whole-rock analy- ses combined-012-0423-6 #12;use the whole-rock analyses for mass balance calculations because sulfide minerals make up a small

Long, Bernard

402

Electron Density Distributions Calculated for the Nickel Sulfides Millerite, Vaesite, and Heazlewoodite and Nickel Metal: A Case for the Importance of Ni-Ni Bond Paths for  

E-Print Network [OSTI]

Electron Density Distributions Calculated for the Nickel Sulfides Millerite, Vaesite, and Heazlewoodite and Nickel Metal: A Case for the Importance of Ni-Ni Bond Paths for Electron Transport G. V. Gibbs point properties (the electron density (F) and the Hessian of F at the bond critical points (bcp

Downs, Robert T.

403

E-Print Network 3.0 - alpha-synuclein processing aggregation...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

FEBS Lett. 2002;522(1-3):9-13. 25... and Aggregation of Alpha-Synuclein in Organic Solvents: Modeling the Effects of Membranes. Biochemistry. 2003... the conformation of...

404

Near-infrared photodetector consisting of J-aggregating cyanine dye and metal oxide thin films  

E-Print Network [OSTI]

We demonstrate a near-infrared photodetector that consists of a thin film of the J-aggregating cyanine dye, U3, and transparent metal-oxide charge transport layers. The high absorption coefficient of the U3 film, combined ...

Osedach, Timothy P.

405

The development of correlations between HMA pavement performance and aggregate shape properties  

E-Print Network [OSTI]

. The performance of these mixes was evaluated in three projects carried out by the Federal Highway Administration (FHWA) and the Texas Transportation Institute (TTI). During this research, a database of the volumetric, performance, and aggregate shape measurements...

McGahan, Jeremy

2006-04-12T23:59:59.000Z

406

Detection and Quantification of Expansive Clay Minerals in Geologically-Diverse Texas Aggregate Fines  

E-Print Network [OSTI]

and asphalt concretes. The Texas Department of Transportation (TXDOT) and Texas A&M Transportation Institute (TTI) evaluated the methylene blue adsorption test for its potential to identify and estimate quantities of expansive clays in aggregate stockpiles...

Russell, George 1983-

2012-11-28T23:59:59.000Z

407

E-Print Network 3.0 - aggregating devices fads Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

3 4 5 > >> 1 Simulating the effect of FAD density on large scale movements Summary: of fish aggregated around FAD 9 ton ( Doray et al. 2008) The influence distance of a FAD (a...

408

The use of the Canberra metrics to aggregate metrics to sustainability  

Science Journals Connector (OSTI)

A final example is chosen from a recent work of Sikdar et al. (2012) where the modified form of the Euclidean distance given by Eq. 5...is used to aggregate the sustainability indicators for the automotive shredder

Humberto S. Brandi; R. J. Daroda…

2014-06-01T23:59:59.000Z

409

Characterization of aggregate resistance to degradation in stone matrix asphalt mixtures  

E-Print Network [OSTI]

Stone matrix asphalt (SMA) mixtures rely on stone-on-stone contacts among particles to resist applied forces and permanent deformation. Aggregates in SMA should resist degradation (fracture and abrasion) under high stresses at the contact points...

Gatchalian, Dennis

2006-04-12T23:59:59.000Z

410

Aggregation of U.S. Population Centers Using Climate Parameters Related to Building Energy Use  

Science Journals Connector (OSTI)

A technique for aggregating population centers into groups based on selected climate parameters is presented. Climate information on the 125 largest Standard Metropolitan Statistical Areas (SMSAs) in the United States is used to assign each SMSA ...

Brandt Andersson; William L. Carroll; Marlo R. Martin

1986-05-01T23:59:59.000Z

411

E-Print Network 3.0 - aggregates rock and stone Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

12;15 Figure A. 10: Picture BB07C1B... Beam Mark: BB07 Cut Location and View: Concrete Type: Self consolidating Aggregate: River Rock Cut ID... : Self consolidating...

412

MASCP Gator: an aggregation portal for the visualization of Arabidopsis proteomics data  

E-Print Network [OSTI]

Bioinformatics MASCP Gator: An Aggregation Portal for theExcellence known as the MASCP Gator and can be accessed atVol. 155, 2011 MASCP Gator (MASCP Gator) that summarizes

Joshi, Hiren

2012-01-01T23:59:59.000Z

413

AIDA: Adaptive Application Independent Data Aggregation in Wireless Sensor Networks1  

E-Print Network [OSTI]

aggregation, sensor networks, adaptive algorithms, feedback control, energy conservation, congestion control such as small instruction and data memory, constrained energy resources, short communication radii, and a low paradigm in distributed wireless communication technology, have been proposed for various applications

Stankovic, John A.

414

Simulation of three–pulse–echo and fluorescence depolarization in photosynthetic aggregates  

Science Journals Connector (OSTI)

...The dimer is the smallest pigment-proteins complex, consisting of two short polypeptides...orientations are distributed randomly, the ensemble average of the anisotropy should vary...theory treats dynamical pro- cesses in disordered aggregates such as nuclear relaxation...

1998-01-01T23:59:59.000Z

415

Wind speed equalization-based incoming wind classification by aggregating DFIGs  

Science Journals Connector (OSTI)

With the development of wind energy, it is necessary to develop equivalent models to represent dynamic behaviors of wind farms in power systems. The equivalent wind method is investigated for the aggregation o...

Zhaojun Meng; Feng Xue; Xueming Li

2013-06-01T23:59:59.000Z

416

A Novel Aggregation Technique Using Mechanical Torque Compensating Factor for DFIG Wind Farms  

Science Journals Connector (OSTI)

A novel aggregated model for wind farms consisting of wind turbines equipped with doubly fed induction generators (DFIG) is proposed in this paper. In ... a large scale offshore wind farm comprising 72 DFIG wind ...

M. A. Chowdhury

2014-01-01T23:59:59.000Z

417

E-Print Network 3.0 - aggregating brain cell Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

brain cell Search Powered by Explorit Topic List Advanced Search Sample search results for: aggregating brain cell Page: << < 1 2 3 4 5 > >> 1 Proc. Natl. Acad. Sci. USA Vol. 81,...

418

New production process for insulation blocks composed of EPS and lightweight concrete containing pumice aggregate  

Science Journals Connector (OSTI)

This study introduces a new production method for production of the insulation blocks made of pumice aggregate, lightweight concrete and expanded polystyrene foam (EPS). Products produced via this method ... × he...

Ali Sariisik; Gencay Sariisik

2012-09-01T23:59:59.000Z

419

Structure and Dynamics of Anaerobic Bacterial Aggregates in a Gas-Lift Reactor  

Science Journals Connector (OSTI)

...Consequently, the mechanical strength of aggregates is affected...Such mechanical effects by gas bubbles arising within biofilms...shearing forces, cell lysis, gas production, etc.) may...W. F. Kossen. 1980. Gas production by immobilized...

H. H. Beeftink; P. Staugaard

1986-11-01T23:59:59.000Z

420

Weathering and aggregate suitability—A case history from the “Victoria” project, Sri Lanka  

Science Journals Connector (OSTI)

The Victoria Project under construction near Kandy in Sri Lanka, required 1.7 million tonnes of aggregate to be quarried in slightly weathered gneiss. This paper describes an investigation into the strength an...

C. Stevens

1984-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "zinc sulfide aggregation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Exciton coherence length fluctuations in chromophore aggregates probed by multidimensional optical spectroscopy  

E-Print Network [OSTI]

Exciton coherence length fluctuations in chromophore aggregates probed by multidimensional optical 10 May 2010; published online 2 July 2010 The coherent third order optical response of molecular integral over stochastic bath paths described by the stochastic Liouville equations. Coherent two

Mukamel, Shaul

422

Attractive Interactions between Reverse Aggregates and Phase Separation in Concentrated Malonamide Extractant Solutions  

Science Journals Connector (OSTI)

Using small angle X-ray scattering, conductivity, and phase behavior determination, we show that concentrated solutions of molanamide extractants, dimethyldibutyltetradecylmalonamide (DMDBTDMA), are organized in reverse oligomeric aggregates which have ...

C. Erlinger; L. Belloni; Th. Zemb; C. Madic

1999-03-09T23:59:59.000Z

423

E-Print Network 3.0 - aggregate health care Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

health care Search Powered by Explorit Topic List Advanced Search Sample search results for: aggregate health care Page: << < 1 2 3 4 5 > >> 1 HUNTER COLLEGE OF THE CITY UNIVERSITY...

424

Development of a general model of aggregate rebound for dry-mix shotcrete—(Part II)  

Science Journals Connector (OSTI)

A mechanical model previously developed is briefly described and linked to particle velocity versus size relationships experimentally obtained, allowing prediction of the energy of rebound of an aggregate particl...

Hugo S. Armelin Ph.D. Candidate; Professor Nemkumar Banthia

1998-04-01T23:59:59.000Z

425

Commercial Demonstration of the Manufactured Aggregate Processing Technology Utilizing Spray Dryer Ash  

SciTech Connect (OSTI)

Universal Aggregates LLC (UA) was awarded a cost sharing Co-operative Agreement from the Department of Energy (DOE) through the Power Plant Improvement Initiative Program (PPII) to design, construct and operate a lightweight aggregate manufacturing plant at the Birchwood Power Facility in King George, Virginia in October 2001. The Agreement was signed in November 2002. The installation and start-up expenses for the Birchwood Aggregate Facility are $19.5 million. The DOE share is $7.2 million (37%) and the UA share is $12.3 million (63%). The original project team consists of UA, SynAggs, LLC, CONSOL Energy Inc. and P. J. Dick, Inc. Using 115,000 ton per year of spray dryer ash (SDA), a dry FGD by-product from the power station, UA will produce 167,000 tons of manufactured lightweight aggregate for use in production of concrete masonry units (CMU). Manufacturing aggregate from FGD by-products can provide an economical high-volume use and substantially expand market for FGD by-products. Most of the FGD by-products are currently disposed of in landfills. Construction of the Birchwood Aggregate Facility was completed in March 2004. Operation startup was begun in April 2004. Plant Integration was initiated in December 2004. Integration includes mixing, extrusion, curing, crushing and screening. Lightweight aggregates with proper size gradation and bulk density were produced from the manufacturing aggregate plant and loaded on a stockpile for shipment. The shipped aggregates were used in a commercial block plant for CMU production. However, most of the production was made at low capacity factors and for a relatively short time in 2005. Several areas were identified as important factors to improve plant capacity and availability. Equipment and process control modifications and curing vessel clean up were made to improve plant operation in the first half of 2006. About 3,000 tons of crushed aggregate was produced in August 2006. UA is continuing to work to improve plant availability and throughput capacity and to produce quality lightweight aggregate for use in commercial applications.

Milton Wu; Paul Yuran

2006-12-31T23:59:59.000Z

426

Prevalence of gout with comorbidity aggregations in southern Taiwan  

Science Journals Connector (OSTI)

AbstractObjective Comorbidity is an important concern for chronic gout patients. We evaluated the relationship between comorbidity profiles and gout in Taiwan aborigines and Taiwanese Han. Methods We used the claims data from the Taiwan national health insurance database for 2004 to 2006. Physician-diagnosed gout and comorbidities were coded using the International Classification of Diseases, Ninth Revision, Clinical Modification (ICD-9-CM). Total sampling from Pingtung County of southern Taiwan included 37,482 aborigines (gout cases, n = 3906 and controls, n = 33,576) and 37,451 Han (gout cases, n = 1115 and controls, n = 36,336). Results In 2006, the gout prevalences were 10.42% and 2.98% (prevalence ratio [PR] = 3.50) in the aborigines and Han general populations, respectively. The prevalences of uric acid nephrolithiasis and tophi were higher in aborigines (0.42% and 0.30%, respectively) than in Han (0.09% and 0.04%, respectively). When stratified by comorbidity status, the prevalences of gout were 4.49% and 27.34% in aborigines and 1.52% and 9.44% in Han (approximate PR = 3.00). Similarly, the prevalence ratios of gout in the comorbidity group, compared with the non-comorbidity group, were 6.09 in aborigines and 6.23 in Han. Multivariate odds ratios [ORs] showed that hypercholesterolemia, hyperglyceridemia, essential hypertension and renal insufficiency were the common comorbidities of gout (OR ? 1.63); heart failure exerted a significant effect only in aborigines (OR = 1.55). For five comorbidity factors, patients with multiple comorbidities had higher gout prevalence (maximum OR = 12.90). Conclusion Gout prevalence was higher in aborigines, both with and without comorbidities, than in Han. The comorbid diseases and comorbidity aggregations showed a substantial association with gout occurrence in both ethnicities.

Fang-Yi Tu; Gau-Tyan Lin; Su-Shin Lee; Yi-Ching Tung; Hung-Ping Tu; Hung-Che Chiang

2014-01-01T23:59:59.000Z

427

Scaling Irregular Applications through Data Aggregation and Software Multithreading  

SciTech Connect (OSTI)

Bioinformatics, data analytics, semantic databases, knowledge discovery are emerging high performance application areas that exploit dynamic, linked data structures such as graphs, unbalanced trees or unstructured grids. These data structures usually are very large, requiring significantly more memory than available on single shared memory systems. Additionally, these data structures are difficult to partition on distributed memory systems. They also present poor spatial and temporal locality, thus generating unpredictable memory and network accesses. The Partitioned Global Address Space (PGAS) programming model seems suitable for these applications, because it allows using a shared memory abstraction across distributed-memory clusters. However, current PGAS languages and libraries are built to target regular remote data accesses and block transfers. Furthermore, they usually rely on the Single Program Multiple Data (SPMD) parallel control model, which is not well suited to the fine grained, dynamic and unbalanced parallelism of irregular applications. In this paper we present {\\bf GMT} (Global Memory and Threading library), a custom runtime library that enables efficient execution of irregular applications on commodity clusters. GMT integrates a PGAS data substrate with simple fork/join parallelism and provides automatic load balancing on a per node basis. It implements multi-level aggregation and lightweight multithreading to maximize memory and network bandwidth with fine-grained data accesses and tolerate long data access latencies. A key innovation in the GMT runtime is its thread specialization (workers, helpers and communication threads) that realize the overall functionality. We compare our approach with other PGAS models, such as UPC running using GASNet, and hand-optimized MPI code on a set of typical large-scale irregular applications, demonstrating speedups of an order of magnitude.

Morari, Alessandro; Tumeo, Antonino; Chavarría-Miranda, Daniel; Villa, Oreste; Valero, Mateo

2014-05-30T23:59:59.000Z

428

Application of the Modified Methylene Blue Test to Detect Clay Minerals in Coarse Aggregate Fines  

E-Print Network [OSTI]

APPLICATION OF THE MODIFIED METHYLENE BLUE TEST TO DETECT CLAY MINERALS IN COARSE AGGREGATE FINES A Thesis by BRANDON THOMAS PITRE Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment...: Civil Engineering Copyright 2012 Brandon Thomas Pitre ii ABSTRACT The purpose of this study was to implement a new, rapid field method to effectively and accurately detect harmful clay minerals in aggregate fines by using the modified...

Pitre, Brandon

2012-12-04T23:59:59.000Z

429

A new mineralogical approach to predict coefficient of thermal expansion of aggregate and concrete  

E-Print Network [OSTI]

the construction allows for accurate prediction of the potential thermal change on crack development and crack width and enhances the overall design process. Siliceous gravel use results in larger crack width than does the limestone and at low temperature... increment between the contacts to the flask volume, the amount of aggregate in the flask, and the thermal characteristics of the aggregate. For measurements made below the freezing point of water, a non-reactive liquid, such as toluene, which does...

Neekhra, Siddharth

2005-02-17T23:59:59.000Z

430

Algorithms for on-line aggregate production plan revision with stochastic autocorrelated demand  

E-Print Network [OSTI]

Tep Sastri (Chair of Committee) J / ' l Dick Simmons (Member) Alberto Garcia. -Diaz ( Xlember ) G. K. Bennett (Head of Department) December 1989 ABSTRACT Algoritlnns for On-line Aggregate Production Plan Rev1sion with Stochastic... Autocorrelated Denrand. (December 1989) Zixuan Ding, B. S. , East China Petroleum University Chair of Advisory Com1nittee: Dr. Tep Sastri Aggregate production plan revision in the environment of autocorrelated stochastic demand is con1plex but. at the sa1ne...

Ding, Zixuan

2012-06-07T23:59:59.000Z

431

Modeling the elastic and plastic response of single crystals and polycrystalline aggregates  

E-Print Network [OSTI]

MODELING THE ELASTIC AND PLASTIC RESPONSE OF SINGLE CRYSTALS AND POLYCRYSTALLINE AGGREGATES A Thesis by PARAG VILAS PATWARDHAN Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE December 2003 Major Subject: Mechanical Engineering MODELING THE ELASTIC AND PLASTIC RESPONSE OF SINGLE CRYSTALS AND POLYCRYSTALLINE AGGREGATES A Thesis by PARAG VILAS...

Patwardhan, Parag Vilas

2005-02-17T23:59:59.000Z

432

Aggregation in solvent extraction systems containing a malonamide, a dialklphosphoric acid and their mixtures.  

SciTech Connect (OSTI)

Aggregation phenomena in n-alkane solutions of di-n-hexylphosphoric acid (HDHP), N,N{prime}-dimethyl-N,N{prime}-dioctylhexylethoxymalonamide (DMDOHEMA), and their mixtures, were investigated by electrospray ionization-mass spectrometry (ESI-MS), vapor pressure osmometry (VPO), and small-angle X-ray and neutron scattering (SAXS and SANS). The objective of the study was to probe the formation of mixed HDHP-DMDOHEMA species before and after extraction of trivalent lanthanide and actinide (M{sup 3+}) nitrates. The most important species formed by HDHP upon metal extraction has the composition M(DHP){sub 3}(HDHP){sub 3}(H{sub 2}O). These species exist as spherical aggregates of the reverse micelle type with a polar core diameter of -7 {angstrom} and total diameter of -11 to -15 {angstrom}. The aggregation of DMDOHEMA is a progressive phenomenon, with an average aggregation number of -2 in the 0.2 to 0.6 M range and larger aggregates forming at higher concentrations. The metal loaded DMDOHEMA aggregates can be considered as interacting spheres with a polar core diameter between -11 and -16 {angstrom}, depending on composition, a total diameter of up to -25 {angstrom}, and a weight-average aggregation number of -9. The results obtained in this work provide strong evidence for the formation of mixed aggregates when mixtures of HDHP and DMDOHEMA are used for the extraction of trivalent Ln and An cations. These mixed reverse micelles have a diameter between 19 and 24 {angstrom} with a polar core diameter of 10 and to 14 {angstrom}. The most recurrent micellar composition is 2 HDHP and either 4 or 5 DMDOHEMA molecules.

Antonio, M. R.; Chiarizia, R.; Gannaz, B.; Berthon, L.; Zorz, N.; Hill, C.; Cote, G.; Chemical Sciences and Engineering Division; CEA-Valrho; Univ. Pierre et Marie

2008-01-01T23:59:59.000Z

433

Reduced-Order Modeling of Aggregated Thermostatic Loads With Demand Response  

SciTech Connect (OSTI)

Demand Response is playing an increasingly important role in smart grid control strategies. Modeling the behavior of populations of appliances under demand response is especially important to evaluate the effectiveness of these demand response programs. In this paper, an aggregated model is proposed for a class of Thermostatically Controlled Loads (TCLs). The model efficiently includes statistical information of the population, systematically deals with heterogeneity, and accounts for a second-order effect necessary to accurately capture the transient dynamics in the collective response. However, an accurate characterization of the collective dynamics however requires the aggregate model to have a high state space dimension. Most of the existing model reduction techniques require the stability of the underlying system which does not hold for the proposed aggregated model. In this work, a novel model reduction approach is developed for the proposed aggregated model, which can significantly reduce its complexity with small performance loss. The original and the reducedorder aggregated models are validated against simulations of thousands of detailed building models using GridLAB-D, which is a realistic open source distribution simulation software. Index Terms – demand response, aggregated model, ancillary

Zhang, Wei; Lian, Jianming; Chang, Chin-Yao; Kalsi, Karanjit; Sun, Yannan

2012-12-12T23:59:59.000Z

434

A zinc-air battery and flywheel zero emission vehicle  

SciTech Connect (OSTI)

In response to the 1990 Clean Air Act, the California Air Resources Board (CARB) developed a compliance plan known as the Low Emission Vehicle Program. An integral part of that program was a sales mandate to the top seven automobile manufacturers requiring the percentage of Zero Emission Vehicles (ZEVs) sold in California to be 2% in 1998, 5% in 2001 and 10% by 2003. Currently available ZEV technology will probably not meet customer demand for range and moderate cost. A potential option to meet the CARB mandate is to use two Lawrence Livermore National Laboratory (LLNL) technologies, namely, zinc-air refuelable batteries (ZARBs) and electromechanical batteries (EMBs, i. e., flywheels) to develop a ZEV with a 384 kilometer (240 mile) urban range. This vehicle uses a 40 kW, 70 kWh ZARB for energy storage combined with a 102 kW, 0.5 kWh EMB for power peaking. These technologies are sufficiently near-term and cost-effective to plausibly be in production by the 1999-2001 time frame for stationary and initial vehicular applications. Unlike many other ZEVs currently being developed by industry, our proposed ZEV has range, acceleration, and size consistent with larger conventional passenger vehicles available today. Our life-cycle cost projections for this technology are lower than for Pb-acid battery ZEVs. We have used our Hybrid Vehicle Evaluation Code (HVEC) to simulate the performance of the vehicle and to size the various components. The use of conservative subsystem performance parameters and the resulting vehicle performance are discussed in detail.

Tokarz, F.; Smith, J.R.; Cooper, J.; Bender, D.; Aceves, S.

1995-10-03T23:59:59.000Z

435

One-Step Synthesis of Graphene/Polypyrrole Nanofiber Composites as Cathode Material for a Biocompatible Zinc/Polymer Battery  

Science Journals Connector (OSTI)

One-Step Synthesis of Graphene/Polypyrrole Nanofiber Composites as Cathode Material for a Biocompatible Zinc/Polymer Battery ... Miniature or flexible aqueous metal–air batteries are currently considered to be one of the most promising candidates for powering mIMDs, which mainly include the zinc–air battery system and the magnesium–air battery system. ...

Sha Li; Kewei Shu; Chen Zhao; Caiyun Wang; Zaiping Guo; Gordon Wallace; Hua Kun Liu

2014-09-08T23:59:59.000Z

436

Contribution of calcium-conducting channels to the transport of zinc ions Alexandre Bouron 1,2,3  

E-Print Network [OSTI]

1 Contribution of calcium-conducting channels to the transport of zinc ions Alexandre Bouron 1. The mechanisms controlling its transport through the plasma membrane are far from being completely understood in the cellular uptake of zinc. These ion channels are currently described as systems dedicated to the transport

437

The insert of zinc oxide thin film in indium tin oxide anode for organic electroluminescence devices q  

E-Print Network [OSTI]

structure including a trans- parent anode, an organic active layer, and a metallic cathode. It has recently zinc oxide films have been actively investigated as alternate materials to ITO because zinc oxide consisted of Al as a cathode, Al2O3 as an electro transport layer, Alq3 as a luminously layer, TPD as a hole

Boo, Jin-Hyo

438

Co-sputtered Aluminum Doped Zinc Oxide Thin Film as Transparent Anode for Organic Light-emitting Diodes  

E-Print Network [OSTI]

Co-sputtered Aluminum Doped Zinc Oxide Thin Film as Transparent Anode for Organic Light and Technology, Clear Water Bay, Kowloon, Hong Kong, China ABSTRACT Aluminum doped zinc oxide (AZO that MTDATA matches better with AZO than CuPc, which served as hole injection layer. Keywords: Aluminum doped

439

Zinc Deficiency Linked to Increased Risk of Less-Common Form of Esophageal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

National Cancer Institute National Cancer Institute Journal of the NCI X-ray Microscopy Group Zinc Deficiency Linked to Increased Risk of Less-Common Form of Esophageal Cancer Researchers at the National Cancer Institute (NCI), part of the National Institutes of Health, using x-ray fluorescence spectroscopy at X-ray Operations and Research beamline 2-BM at the U.S. Department of Energy's Advanced Photon Source have found that zinc deficiency in humans is associated with an increased risk of developing esophageal squamous cell carcinoma, an often-fatal form of esophageal cancer that has about 7,000 cases a year. NCI researchers used a novel approach to measure the concentration of zinc and other elements directly in the esophageal tissue. Their results, appearing in the February 15, 2005, Journal of the National

440

Selenium, Cadmium, Copper, and Zinc Concentrations in Sediments and Mullet (Mugil cephalus) from the Southern Basin of Lake Macquarie, NSW, Australia  

E-Print Network [OSTI]

Selenium, Cadmium, Copper, and Zinc Concentrations in Sediments and Mullet (Mugil cephalus) from. Selenium, cadmium, copper, and zinc concentrations were measured in sediments and the tissues of mullet­19; cadmium, 14­42; copper, 1.5­3.6; zinc, 0.77­2.2 times background). Selenium, cadmium, and copper in Lake

Canberra, University of

Note: This page contains sample records for the topic "zinc sulfide aggregation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

8 - Hydrothermal Synthesis and Crystal Growth of Fluorides, Sulfides, Tungstates, Molybdates, and Related Compounds (Coordinated Complex Crystals, Part II)  

Science Journals Connector (OSTI)

In Chapter 8 we deal with fluorides, sulfides, tungstates, titanates, molybdates, tantalates, neobates, selenides, and related compounds. The synthesis of these compounds did not carry much geological significance in the past; hence, their synthesis began in the middle of the twentieth century. However, the interest was purely academic. Today, these compounds have a great technological significance. Although the synthesis of these compounds is being studied extensively worldwide, interest is more confined to the nanosize crystals rather than the bulk single crystals growth. Some of these coordinated complexes with reductions in the size and the establishment of core-shell structures carry special characteristics useful as sensors, quantum dots, imagers, semiconductors over a wide band gap region, and so on. Keywords hermothermal phase equilibria; rich substitutional chemistry; antiferromagnetic behavior; rare earth flurides; oxyfluorinated compounds; photoconductivity

K. Byrappa; Masahiro Yoshimura

2013-01-01T23:59:59.000Z

442

Size Dependence of a Temperature-Induced Solid-Solid Phase Transition in Copper(I) Sulfide  

SciTech Connect (OSTI)

Determination of the phase diagrams for the nanocrystalline forms of materials is crucial for our understanding of nanostructures and the design of functional materials using nanoscale building blocks. The ability to study such transformations in nanomaterials with controlled shape offers further insight into transition mechanisms and the influence of particular facets. Here we present an investigation of the size-dependent, temperature-induced solid-solid phase transition in copper sulfide nanorods from low- to high-chalcocite. We find the transition temperature to be substantially reduced, with the high chalcocite phase appearing in the smallest nanocrystals at temperatures so low that they are typical of photovoltaic operation. Size dependence in phase trans- formations suggests the possibility of accessing morphologies that are not found in bulk solids at ambient conditions. These other- wise-inaccessible crystal phases could enable higher-performing materials in a range of applications, including sensing, switching, lighting, and photovoltaics.

Rivest, Jessy B; Fong, Lam-Kiu; Jain, Prashant K; Toney, Michael F; Alivisatos, A Paul

2011-07-24T23:59:59.000Z

443

Alteration of alkali reactive aggregates autoclaved in different alkali solutions and application to alkali-aggregate reaction in concrete (II) expansion and microstructure of concrete microbar  

SciTech Connect (OSTI)

The effect of the type of alkalis on the expansion behavior of concrete microbars containing typical aggregate with alkali-silica reactivity and alkali-carbonate reactivity was studied. The results verified that: (1) at the same molar concentration, sodium has the strongest contribution to expansion due to both ASR and ACR, followed by potassium and lithium; (2) sufficient LiOH can completely suppress expansion due to ASR whereas it can induce expansion due to ACR. It is possible to use the duplex effect of LiOH on ASR and ACR to clarify the ACR contribution when ASR and ACR may coexist. It has been shown that a small amount of dolomite in the fine-grained siliceous Spratt limestone, which has always been used as a reference aggregate for high alkali-silica reactivity, might dedolomitize in alkaline environment and contribute to the expansion. That is to say, Spratt limestone may exhibit both alkali-silica and alkali-carbonate reactivity, although alkali-silica reactivity is predominant. Microstructural study suggested that the mechanism in which lithium controls ASR expansion is mainly due to the favorable formation of lithium-containing less-expansive product around aggregate particles and the protection of the reactive aggregate from further attack by alkalis by the lithium-containing product layer.

Lu Duyou [College of Materials Science and Engineering, Nanjing University of Technology, 5 New Model Road, Nanjing, 210009 (China)]. E-mail: duyoulu@njut.edu.cn; Mei Laibao [College of Materials Science and Engineering, Nanjing University of Technology, 5 New Model Road, Nanjing, 210009 (China); Xu Zhongzi [College of Materials Science and Engineering, Nanjing University of Technology, 5 New Model Road, Nanjing, 210009 (China); Tang Mingshu [College of Materials Science and Engineering, Nanjing University of Technology, 5 New Model Road, Nanjing, 210009 (China); Mo Xiangyin [Analysis and Test Central, Nanjing Normal University, 122 Ninghai Road, Nanjing, 210097 (China); Fournier, Benoit [ICON/CANMET, Natural Resources Canada, 405 Rochester Street, Ottawa, ON, K1A 0G1 (Canada)

2006-06-15T23:59:59.000Z

444

Characterization and activity of ferric-sulfide-based catalyst in model reactions of direct coal liquefaction: Effect of preparation conditions  

SciTech Connect (OSTI)

The authors studied the activity of various ferric-sulfide-based catalysts in model hydrogenation and cracking reactions under conditions typical of direct coal liquefaction (DCL). The catalysts used were mixtures of FeS{sub 2} (pyrite, PY) and nonstoichiometric FeS{sub x} (pyrrhotite, PH) obtained by high-temperature disproportionation of ferric sulfide in a nitrogen atmosphere or a hydrogen atmosphere. The structural changes in the catalyst were also examined, both before and after the model reactions. The cracking functionality of the catalysts was studied by using cumene, and the hydrocracking functionality was studied by using diphenylmethane. Phenanthrene was used as a model compound for hydrogenation and hydrogen shuttling. Phenanthrene hydrogenation was studied in the presence of H{sub 2}(g), and hydrogen shuttling was studied when a hydrogen donor (tetralin) was present in the absence of H{sub 2}(g). All the model reactions were performed under conditions typical of DCL: 400 C and 1,000 psig for 30 min. The surface and bulk of the catalysts were characterized by Auger electron spectroscopy, scanning electron microscopy, energy-dispersive X-ray spectroscopy, and atomic absorption spectroscopy. The performance of the catalysts was found to vary with the type of reaction, the initial ratio of FeS{sub x} to FeS{sub 2} (PH/PY) found in the catalyst, and the catalyst age. Catalysts freshly prepared in a nitrogen atmosphere were most active for model hydrogenation and hydrocracking runs. Catalysts freshly prepared in hydrogen were most active in shuttling. A simple model was developed to explain changes in the surface and bulk of the catalysts.

Chadha, A.; Stinespring, C.D.; Stiller, A.H.; Zondlo, J.W.; Dadyburjor, D.B. [West Virginia Univ., Morgantown, WV (United States). Dept. of Chemical Engineering] [West Virginia Univ., Morgantown, WV (United States). Dept. of Chemical Engineering

1997-02-01T23:59:59.000Z

445

The Copper Sulfide Coating on Polyacrylonitrile with Chelating Agents by an Electroless Deposition Method and its EMI Shielding Effectiveness  

SciTech Connect (OSTI)

In this study, a variety of concentrations of chelating agents were added to obtain the anchoring effect and chelating effect in the electroless plating bath. The mechanism of the Cu{sub x(x=1,2)}S growth and the electromagnetic interference shielding effectiveness (EMI SE) of the composite were studied. It was found that the vinyl acetate residued in PAN substrate would be purged due to the swelling effect by chelating agents solution. And then, the anchoring effect occurred due to the hydrogen bonding between the pits of PAN substrate and the chelating agent. Consequently, the copper sulfide layer deposited by the electroless plating reaction with EDTA and TEA. The swelling degree (S{sub d}) was proposed and evaluated from the FT-IR spectra. The relationship between swelling degree of the PAN films and EDTA (C) is expressed as: S{sub d} = 0.13+0.90xe and (-15.15C). And TEA series is expressed as: S{sub d} = 0.07+1.00xe and (-15.15C). On the other hand, the FESEM micrograph showed that the average thickness of copper sulfide increased from 76 nm to 383 nm when the concentration of EDTA increased from 0.00M to 0.20M. Consequently, the EMI SE of the composites increased from 10{approx}12 dB to 25{approx}27 dB. The GIA-XRD analyze indicated that the deposited layer consisted of CuS and Cu{sub 2}S.

Roan, M.-L. [Department of Electro-optical Engineering, Lan-Yan Institute of Technology, Taiwan (China); Chen, Y.-H.; Huang, C.-Y. [Department of Materials Engineering, Tatung University, Taiwan (China)

2008-08-28T23:59:59.000Z

446

The mass transfer and kinetics for zinc deposition from bromide media  

E-Print Network [OSTI]

Bro, I. 0 MNctBr 7. 0 5. 0 5 E 40 3. 0 2. 0 I. O 4 8 12 16 20 24 I/~ Vw (RAD/S) Figure 8. Limiting currents for zinc deposition as a function of the square root of rotational speed. 34 Table 1. Analysis of the Zn Diffusion Coefficient +2...THE MASS TRANSFER AND KINETICS FOR ZINC DEPOSITION FROM BROMIDE MEDIA A Thesis by MARK ALAN EDMUND Approved as to style and content by: (Chairman of Comnittee) (Member (Member) (Member) (Head of Department) May 1980 1385319 ABSTRACT...

Edmund, Mark Alan

1980-01-01T23:59:59.000Z

447

Humectants To Augment Current From Metallized Zinc Cathodic Protection Systems on Concrete  

SciTech Connect (OSTI)

Cathodic protection (CP) systems using thermal-sprayed zinc anodes are employed to mitigate the corrosion process in reinforced concrete structures. However, the performance of the anodes is improved by moisture at the anode-concrete interface. Research was conducted to investigate the effect of hydrophilic chemical additives, humectants, on the electrical performance and service life of zinc anodes. Lithium bromide and lithium nitrate were identified as feasible humectants with lithium bromide performing better under galvanic CP and lithium nitrate performing better under impressed current CP. Both humectants improved the electrical operating characteristics of the anode and increased the service life by up to three years.

Holcomb, Gordon R.; Covino Jr., Bernard S.; Cramer, Stephen D.; Russell, James H. Russell; Bullard, Sophie J.; Collins, W. Keith; Bennett, Jack E. (J.E. Bennett Consulting, Inc.); Soltesz, Steven M. (ODOT); Laylor, H. Martin (ODOT)

2002-12-01T23:59:59.000Z

448

Fluidizable zinc titanate materials with high chemical reactivity and attrition resistance  

DOE Patents [OSTI]

Highly durable and chemically reactive zinc titanate materials are prepared in a particle size range of 50 to 400 .mu.m suitable for a fluidized-bed reactor for removing reduced sulfur species in a gaseous form by granulating a mixture of fine zinc oxide and titanium oxide with inorganic and organic binders and by optional additions of small amounts of activators such as CoO and MoO.sub.3 ; and then indurating it at 800.degree. to 900.degree. C. for a time sufficient to produce attrition-resistant granules.

Gupta, Raghubir P. (Durham, NC); Gangwal, Santosh K. (Durham, NC); Jain, Suresh C. (Morgantown, WV)

1993-01-01T23:59:59.000Z

449

Characteristics of polyacrylic acid-complexed zinc phosphate conversion films deposited on metal surfaces  

SciTech Connect (OSTI)

When water-soluble polyacrylic acid (PAA) macromolecules having MW 90,000 to 250,000 are introduced into zinc phosphating liquids, significant improvements in the properties of conventional crystalline zinc phosphate conversion films deposited on carbon steel surfaces can be obtained. The improvements include the controllability of the crystal dimensions, the degree of crystallinity, and the coating weight. The conversion complex formation plays an essential role in increasing the ductility of the normally brittle conventional crystal films. Furthermore, the thickness (20 to 40 A) and surface roughness of the thin PAA overlayer significantly acts to enhance the adhesive force at the interface between organic polymer topcoats and the complex coating.

Sugama, T.; Kukacka, L.E.; Carciello, N.

1984-01-01T23:59:59.000Z

450

The pH dependence of dihydroorotic acid synthesis catalyzed by zinc and cobalt dihydroorotase  

E-Print Network [OSTI]

THE pH DEPENDENCE (P DIHYDROGRCTIC ACID SYNTHESIS CATALYZED BY ZINC AND COBALT DIHYDROORC1IASE A Thesis by RITA ROY CHOUDHJRY ~roved style and content: ( zrrren af Ccmittee) (Manter ) ( ) ( of Iepsrt~t) Ann~st I984 The pH Dependence... of Dihydroorotic Acid Synthesis Catalyzed by Zinc and Cobalt Dihydroorotase. (August 1984 ) Rita Roy Choudhury, N. Sc, University of Banbay Chairman af Advisory Ccmitee: Dr. E. G. Sander Dihydroorotase (1-5, 6 dihydroorotate mnidohydrolase E. C. 3. 5. 2. 3...

Roy Choudhury, Rita

1984-01-01T23:59:59.000Z

451

Single Membrane Reactor Configuration for Separation of Hydrogen, Carbon Dioxide and Hydrogen Sulfide  

SciTech Connect (OSTI)

The objective of the project was to develop a novel complementary membrane reactor process that can consolidate two or more downstream unit operations of a coal gasification system into a single module for production of a pure stream of hydrogen and a pure stream of carbon dioxide. The overall goals were to achieve higher hydrogen production efficiencies, lower capital costs and a smaller overall footprint than what could be achieved by utilizing separate components for each required unit process/operation in conventional coal-to-hydrogen systems. Specifically, this project was to develop a novel membrane reactor process that combines hydrogen sulfide removal, hydrogen separation, carbon dioxide separation and water-gas shift reaction into a single membrane configuration. The carbon monoxide conversion of the water-gas-shift reaction from the coal-derived syngas stream is enhanced by the complementary use of two membranes within a single reactor to separate hydrogen and carbon dioxide. Consequently, hydrogen production efficiency is increased. The single membrane reactor configuration produces a pure H{sub 2} product and a pure CO{sub 2} permeate stream that is ready for sequestration. This project focused on developing a new class of CO{sub 2}-selective membranes for this new process concept. Several approaches to make CO{sub 2}-selective membranes for high-temperature applications have been tested. Membrane disks using the technique of powder pressing and high temperature sintering were successfully fabricated. The powders were either metal oxide or metal carbonate materials. Experiments on CO{sub 2} permeation testing were also performed in the temperature range of 790 to 940 C for the metal carbonate membrane disks. However, no CO{sub 2} permeation rate could be measured, probably due to very slow CO{sub 2} diffusion in the solid state carbonates. To improve the permeation of CO{sub 2}, one approach is to make membranes containing liquid or molten carbonates. Several different types of dual-phase membranes were fabricated and tested for their CO{sub 2} permeation in reducing conditions without the presence of oxygen. Although the flux was quite low, on the order of 0.01-0.001 cc STP/cm{sup 2}/min, the selectivity of CO{sub 2}/He was almost infinite at temperatures of about 800 C. A different type of dual-phase membrane prepared by Arizona State University (ASU) was also tested at GTI for CO{sub 2} permeation. The measured CO{sub 2} fluxes were 0.015 and 0.02 cc STP/cm{sup 2}/min at 750 and 830 C, respectively. These fluxes were higher than the previous flux obtained ({approx}0.01 cc STP/cm{sup 2}/min) using the dual-phase membranes prepared by GTI. Further development in membrane development should be conducted to improve the CO{sub 2} flux. ASU has also focused on high temperature permeation/separation experiments to confirm the carbon dioxide separation capabilities of the dual-phase membranes with La{sup 0.6}Sr{sub 0.4}Co{sub 0.8}Fe{sub 0.2}O{sub 3-{delta}} (LSCF6482) supports infiltrated with a Li/Na/K molten carbonate mixture (42.5/32.5/25.0 mole %). The permeation experiments indicated that the addition of O{sub 2} does improve the permeance of CO{sub 2} through the membrane. A simplified membrane reactor model was developed to evaluate the performance of the process. However, the simplified model did not allow the estimation of membrane transport area, an important parameter for evaluating the feasibility of the proposed membrane reactor technology. As a result, an improved model was developed. Results of the improved membrane reactor model show that the membrane shift reaction has promise as a means to simplify the production of a clean stream of hydrogen and a clean stream of carbon dioxide. The focus of additional development work should address the large area required for the CO{sub 2} membrane as identified in the modeling calculations. Also, a more detailed process flow diagram should be developed that includes integration of cooling and preheating feed streams as well as particulate removal so that stea

Micheal Roberts; Robert Zabransky; Shain Doong; Jerry Lin

2008-05-31T23:59:59.000Z

452

Microstructured block copolymer surfaces for control of microbe capture and aggregation  

SciTech Connect (OSTI)

The capture and arrangement of surface-associated microbes is influenced by biochemical and physical properties of the substrate. In this report, we develop lectin-functionalized substrates containing patterned, three-dimensional polymeric structures of varied shapes and densities and use these to investigate the effects of topology and spatial confinement on lectin-mediated microbe capture. Films of poly(glycidyl methacrylate)-block-4,4-dimethyl-2-vinylazlactone (PGMA-b-PVDMA) were patterned on silicon surfaces into line or square grid patterns with 5 m wide features and varied edge spacing. The patterned films had three-dimensional geometries with 900 nm film thickness. After surface functionalization with wheat germ agglutinin, the size of Pseudomonas fluorescens aggregates captured was dependent on the pattern dimensions. Line patterns with edge spacing of 5 m or less led to the capture of individual microbes with minimal formation of aggregates, while grid patterns with the same spacing also captured individual microbes with further reduction in aggregation. Both geometries allowed for increases in aggregate size distribution with increased in edge spacing. These engineered surfaces combine spatial confinement with affinity-based microbe capture based on exopolysaccharide content to control the degree of microbe aggregation, and can also be used as a platform to investigate intercellular interactions and biofilm formation in microbial populations of controlled sizes.

Hansen, Ryan R [ORNL] [ORNL; Shubert, Katherine R [ORNL] [ORNL; Morrell, Jennifer L. [University of Tennessee, Knoxville (UTK)] [University of Tennessee, Knoxville (UTK); Lokitz, Bradley S [ORNL] [ORNL; Doktycz, Mitchel John [ORNL] [ORNL; Retterer, Scott T [ORNL] [ORNL

2014-01-01T23:59:59.000Z

453

Phytoextraction of Zinc by Oat (Avena sativa), Barley (Hordeum vulgare), and Indian Mustard (Brassica juncea)  

Science Journals Connector (OSTI)

Phytoextraction of Zinc by Oat (Avena sativa), Barley (Hordeum vulgare), and Indian Mustard (Brassica juncea) ... When the point is reached where barley fails to maintain a high rate of Zn removal, chelate addition could then be used with B. juncea to solubilize residual Zn that had previously been unavailable for uptake. ...

Stephen D. Ebbs; Leon V. Kochian

1998-01-27T23:59:59.000Z

454

ON THE CORROSION RESISTANCE OF POROUS ELECTROPLATED ZINC COATINGS IN DIFFERENT CORROSIVE MEDIA  

E-Print Network [OSTI]

1 ON THE CORROSION RESISTANCE OF POROUS ELECTROPLATED ZINC COATINGS IN DIFFERENT CORROSIVE MEDIA Y(0)546457272. e-mail : fpedraza@univ-lr.fr Abstract The corrosion resistance of an electroplated (EP) Zn coating corrosive media (NaCl, NaOH and rain water). Four different faradaic relaxation processes were clearly

Paris-Sud XI, Université de

455

Events associated with restoration by zinc of meiosis in apomictic Saccharomyces cerevisiae.  

Science Journals Connector (OSTI)

...was not detected in A-P conditions. blance to those reported to accompany heat shock...imperfectly ordered zinc-induced tubulin sheets using cross-correlation and real space...meiotic systems. International Atomic Energy Agency, Vienna. 27. Moens, P. B...

C A Bilinski; J J Miller; S C Girvitz

1983-09-01T23:59:59.000Z

456

Intercombination lines of the zinc isoelectronic sequence for Z = 50–70  

Science Journals Connector (OSTI)

The intercombination lines of the zinc sequence corresponding to the transition 4s4p 3P1?4s2 1S0 have been observed for xenon, lanthanum, neodymium, europium, gadolinium, and ytterbium in the Princeton Large Torus tokamak discharges.

E. Hinnov; P. Beiersdorfer; R. Bell; J. Stevens; S. Suckewer; S. von Goeler; A. Wouters; D. Dietrich; M. Gerassimenko; E. Silver

1987-06-01T23:59:59.000Z

457

Kinetics of Zinc/ Arsenate Co-Sorption at the Goethite-Water Interface. (5827)  

E-Print Network [OSTI]

of aging time. Arsenate and zinc formed adamite-like and koettigite-like surface precipitates on goethite and was cyclic for the adamite and koettigite-like surface precipitates reflecting the concentric and plane-layered structures of adamite and koettigite, respectively. Speaker Information: Markus Grafe, University of Delaware

Sparks, Donald L.

458

Investigation of zinc oxide doped with metal impurities for use as thin film conductive phosphors  

E-Print Network [OSTI]

of a viable flat panel display, low voltage, conductive phosphors which emit blue, red, and green light will be required for the field emission technology. This thesis examines zinc oxide (ZnO) based thin ( ) phosphors for such an application. ZnO is a...

Evatt, Steven R.

1994-01-01T23:59:59.000Z

459

Processing and Characterization of P-Type Doped Zinc Oxide Thin Films  

E-Print Network [OSTI]

Applications of zinc oxide (ZnO) for optoelectronic devices, including light emitting diodes, semiconductor lasers, and solar cells have not yet been realized due to the lack of high-quality p-type ZnO. In the research presented herein, pulsed laser...

Myers, Michelle Anne

2013-03-18T23:59:59.000Z

460

The effect of zinc methionine or copper lysine on stocker calves grazing oat pastures  

E-Print Network [OSTI]

Fourty eight Hereford and Angus stocker steers (average weight 259.7 kg) were placed in twelve, five acre, pastures (four steers per pasture) planted with oat forage for a 91 d grazing trial to determine the effect of supplementing zinc methionine...

Griffeth, Laura Ann

1993-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "zinc sulfide aggregation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Zinc and mechanical prowess in the jaws of Nereis, a marine worm  

E-Print Network [OSTI]

Zinc and mechanical prowess in the jaws of Nereis, a marine worm Helga C. Lichtenegger* , Thomas of the marine polychaete worm Nereis sp. High copper levels in the polychaete worm Glycera dibranchiata recently and mechanical properties such as fracture toughness, wear resistance, and hardness (1). Invertebrate jaws

Lichtenegger, Helga C.

462

STRAIN SENSING WITH PIEZOELECTRIC ZINC OXIDE THIN FILMS FOR VIBRATION SUPPRESSION IN HARD DISK DRIVES  

E-Print Network [OSTI]

was successfully obtained while the suspension was flying on a disk as in normal drive operation. PreliminarySTRAIN SENSING WITH PIEZOELECTRIC ZINC OXIDE THIN FILMS FOR VIBRATION SUPPRESSION IN HARD DISK This paper describes the integration of thin film ZnO strain sensors onto hard disk drive suspensions

Horowitz, Roberto

463

Zinc in the sediments, water and biota of Lake Burley Griffin, Canberra  

E-Print Network [OSTI]

polluted by heavy metals, especially zinc. Benthic invertebrates have been shown to be depauperate in biomass and diversity and this has been attributed to heavy metal pollution (Weatherley et al., 0048) and water (0.018 :I: 0.002 mgikg) with those before remedial works were performed in 1974to control a metal

Canberra, University of

464

Zinc-dependent Interaction between Dishevelled and the Drosophila Wnt Antagonist Naked Cuticle*  

E-Print Network [OSTI]

development, the naked cuticle (nkd) gene attenuates wingless/Wnt signaling through a negative feedback loop mechanism. Fly and vertebrate Nkd proteins contain a putative calcium-binding EF- hand motif, the EFX domain of the chelating agent EDTA abolished the in vitro Nkd-Dsh interaction. Surprisingly zinc, but not calcium

Quake, Stephen R.

465

Fluorophore-linked zinc(II)dipicolylamine coordination complexes as sensors for  

E-Print Network [OSTI]

Fluorophore-linked zinc(II)dipicolylamine coordination complexes as sensors for phosphatidylserine with an attached NBD fluorophore are synthesized and evaluated as fluorescent sensors. The sensors do not respond in the presence of anionic vesicles. A sensor with two Zn2C ­DPA units and a hydrophilic tris(ethyleneoxy) linker

Smith, Bradley D.

466

Sequence-specific modification of mitochondrial DNA using a chimeric zinc finger methylase  

Science Journals Connector (OSTI)

...fingers F1, F2, and F3 are listed below with a single-letter code. The fingers F1, F2, and F3 are represented by {alpha}-helix and two {beta}-strands stabilized by a zinc ion...tag-specific primer containing additionally NES sequence from NS2 protein of Minute virus of mice (VDEMTKKFGTLTIHDTEK) and BamHI...

Michal Minczuk; Monika A. Papworth; Paulina Kolasinska; Michael P. Murphy; Aaron Klug

2006-01-01T23:59:59.000Z

467

Engineering a DNA-cleaving DNAzyme and PCR into a simple sensor for zinc ion detection  

Science Journals Connector (OSTI)

The development of a simple sensor (9NL27-Zn) based on DNAzyme and PCR and aimed at the detection of low concentrations of zinc (II) ions is described. A specific Zn(II)-dependent DNAzyme (9NL27) with DNA-clea...

Jiacui Xu; Yanhong Sun; Yongjie Sheng; Yanqun Fei…

2014-05-01T23:59:59.000Z

468

Deprotonative metallation of ferrocenes using mixed lithium-zinc and lithium-cadmium combinations  

E-Print Network [OSTI]

). It is pertinent to mention that lithium bases were previously used to deprotonate the acetal 3, albeit at lower1 Deprotonative metallation of ferrocenes using mixed lithium-zinc and lithium-cadmium combinations on the web Xth XXXXXXXXX 200X DOI: 10.1039/b000000x A mixed lithium-cadmium amide and a combination

Boyer, Edmond

469

Hydrometallurgical process for recovering iron sulfate and zinc sulfate from baghouse dust  

DOE Patents [OSTI]

A process for recovering zinc-rich and iron-rich fractions from the baghouse dust that is generated in various metallurgical operations, especially in steel-making and other iron-making plants, comprises the steps of leaching the dust by hot concentrated sulfuric acid so as to generate dissolved zinc sulfate and a precipitate of iron sulfate, separating the precipitate from the acid by filtration and washing with a volatile liquid, such as methanol or acetone, and collecting the filtered acid and the washings into a filtrate fraction. The volatile liquid may be recovered by distillation, and the zinc may be removed from the filtrate by alternative methods, one of which involves addition of a sufficient amount of water to precipitate hydrated zinc sulfate at 10 C, separation of the precipitate from sulfuric acid by filtration, and evaporation of water to regenerate concentrated sulfuric acid. The recovery of iron may also be effected in alternative ways, one of which involves roasting the ferric sulfate to yield ferric oxide and sulfur trioxide, which can be reconverted to concentrated sulfuric acid by hydration. The overall process should not generate any significant waste stream. 1 figure.

Zaromb, S.; Lawson, D.B.

1994-02-15T23:59:59.000Z

470

Effects of Zinc Deficiency on Cellular Processes and Morphology in Ehrlich Ascites Tumor Cells  

Science Journals Connector (OSTI)

...nmol/mg after a 1 hr incubation as...drinking zinc (80 and 160 @.sg/mb...is required to rebate this observation...electron transport and State 3 oxidative...0 5 0 50 100 500 Zn ng atoms/mg...with cells for 1 hr prior to addition...values of 0.105 and 0.110 @.ig...

Leon A. Saryan; Daniel T. Minkel; Patricia J. Dolhun; Barbara L. Calhoun; Susan Wielgus; Marilyn Schaller; and David H. Petering

1979-07-01T23:59:59.000Z

471

Zinc sorption to biogenic hexagonal-birnessite particles within a hydrated bacterial biofilm  

E-Print Network [OSTI]

Zinc sorption to biogenic hexagonal-birnessite particles within a hydrated bacterial biofilm Brandy oxides found in streams, wetlands, soils, and aquifers. We investigated the mecha- nisms of Zn sorption experiments were conducted at pH 6.9 to characterize Zn sorption to this biogenic Mn oxide, and to determine

472

Computational Investigation of Irreversible Inactivation of the Zinc-Dependent Protease Carboxypeptidase A  

E-Print Network [OSTI]

- + CH3Cl SN2 reaction fragment. Point charge models representing the active site reproduced energetics from full MO calculations at 12.0 Ã? separation between the zinc and the central carbon of the SN2 of this structure led to the barrierless SN2 displacement of the iodide of the inhibitor by Glu-270, assisted

Schlegel, H. Bernhard

473

Oxidation of zinc in alkaline solutions studied by electrochemical impedance spectroscopy  

SciTech Connect (OSTI)

Electrochemical dissolution and passivation reactions of zinc have been studied in 1.0 M KOH solutions by electrochemical impedance spectroscopy. Equivalent circuits have been worked out by simulating the impedance data and using the results to model the dissolution and passivation reactions. A Tafel plot constructed from the charge-transfer resistances provides an exchange current of 0.11 A/cm{sup 2} and an {alpha} value of 0.36 for zinc oxidation. The maximum rate of zinc oxidation is observed at about {minus}1.30 V vs. the Hg/HgO reference electrode as judged from the charge-transfer resistance minimum obtained from impedance measurements. A negative polarization resistance with a reverse semicircle on the Nyquist plot illustrates the transition process from an active to passive potential region at {minus}1.10 V. At high anodic over-potentials, the zinc electrode behaved as a semiconductor electrode due to a compact ZnO passive film formed on the electrode surface.

Cai, M.; Park, S.M. [Univ. of New Mexico, Albuquerque, NM (United States). Dept. of Chemistry

1996-12-01T23:59:59.000Z

474

Grid Integration of Aggregated Demand Response, Part 1: Load Availability Profiles and Constraints for the Western Interconnection  

E-Print Network [OSTI]

is estimated. Keywords: Demand response, ancillary services,of Aggregated Demand Response, Part 1: Load Availabilityof Energy (DOE) Demand Response and Energy Storage

Olsen, Daniel J.

2014-01-01T23:59:59.000Z

475

HIGH-DENSITY CONCRETE WITH CERAMIC AGGREGATE BASED ON DEPLETED URANIUM DIOXIDE  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

DENSITY CONCRETE WITH CERAMIC AGGREGATE BASED ON DEPLETED URANIUM DENSITY CONCRETE WITH CERAMIC AGGREGATE BASED ON DEPLETED URANIUM DIOXIDE S.G. Ermichev, V.I. Shapovalov, N.V.Sviridov (RFNC-VNIIEF, Sarov, Russia) V.K. Orlov, V.M. Sergeev, A. G. Semyenov, A.M. Visik, A.A. Maslov, A. V. Demin, D.D. Petrov, V.V. Noskov, V. I. Sorokin, O. I. Uferov (VNIINM, Moscow, Russia) L. Dole (ORNL, Oak Ridge, USA) Abstract - Russia is researching the production and testing of concretes with ceramic aggregate based on depleted uranium dioxide (UO 2 ). These DU concretes are to be used as structural and radiation-shielded material for casks for A-plant spent nuclear fuel transportation and storage. This paper presents the results of studies aimed at selection of ceramics and concrete composition, justification of their production technology, investigation of mechanical properties, and chemical stability.

476

Aggregated TiO2 Based Nanotubes for Dye Sensitized Solar Cells  

SciTech Connect (OSTI)

One-dimensional (1D) semiconducting oxides have attracted great attention for dye sensitized solar cells (DSCs), but the overall performance is still quite limited as compared to TiO2 nanocrystalline DSCs. Here, we report the synthesis of aggregated TiO2 based nanotubes with controlled morphologies and crystalline structures to obtain an overall power conversion efficiency of 9.9% using conventional dye without any additional chemical treatment steps. The high efficiency is attributed to the unique aggregate structure for light harvesting, optimized high surface area, and good crystallinity of the nanotube aggregates obtained through proper thermal annealing. This study demonstrates that high efficiency DSCs can be obtained with 1D nanomaterials, and provides lessons on the importance of optimizing both the nanocrystalline structure and the overall microscale morphology.

Nie, Zimin; Zhou, Xiaoyuan; Zhang, Qifeng; Cao, Guozhong; Liu, Jun

2013-11-01T23:59:59.000Z

477

Chain-aggregate aerosols in smoke from the Kuwait oil fires  

SciTech Connect (OSTI)

Electrooptical scattering was used to detect aggregated particle chains in the smoke from the Kuwait oil fires. Nonsphericity was detected by the change in light scattering brought about by induced alignment of particles when subjected to a pulsed, bipolar electric field. Measured parameters included the steady state enhancement of light scattering for complete orientation of the particles, and the rotational diffusion constant, calculated from the time required for the particles to relax to a random orientation after the electric field was removed. Chain aggregates of soot formed within seconds of combustion for those fires producing black smoke. These aggregates agglomerated to some extent in the smoke near the fires, but then remained relatively unchanged for several hours of travel downwind. Very little nonsphericity was detected for particles in the plume of white smoke, which consisted primarily of salt brine products emitted along with the oil. 10 refs., 4 figs., 1 tab.

Weiss, R.E. [Radiance Research, Inc., Seattle, WA (United States); Kapustin, V.N. [Institute of Atmospheric Physics, Moscow (Russian Federation); Hobbs, P.V. [Univ. of Washington, Seattle, WA (United States)

1992-09-20T23:59:59.000Z

478

PF-OLA: A High-Performance Framework for Parallel On-Line Aggregation  

E-Print Network [OSTI]

On-line aggregation provides estimates to the final result of a computation during the actual processing. The user can stop the computation as soon as the estimate is accurate enough, typically early in the execution. This allows for the interactive data exploration of the largest datasets. In this paper we introduce the first framework for parallel on-line aggregation in which the estimation does not incur any overhead on top of the actual execution. We define a generic interface to express any estimation model that abstracts completely the execution details. We design a novel estimator specifically targeted at parallel on- line aggregation. When executed by the framework over an 8TB TPC-H instance, the estimator provides accurate confidence bounds early in the execution even when the cardinality of the final result is seven orders of magnitude smaller than the dataset size and without incurring any overhead.

Qin, Chengjie

2012-01-01T23:59:59.000Z

479

Stabilizing effect of small concentrations of PAMAM dendrimers at the insulin aggregation  

Science Journals Connector (OSTI)

Abstract Dendrimers’ action on proteins and peptides has a dual and controversial character. On one hand, they dissolve prion protein and amyloid fibrils aggregates, which are otherwise only soluble in solvents containing both detergents and high denaturant concentrations. On the other hand they are able to destabilize proteins in generation dependent manner. In present work we estimated the influence of small concentrations (up to 1.4 ?g/ml) of cationic, neutral and anionic poly(amidoamine) dendrimers of 3rd and 4th generations on dithiotreitol induced aggregation of insulin. It was found that cationic dendrimers decreased the insulin aggregation, while anionic and neutral ones did not. At the same time, destabilizing effect of dendrimers on insulin structure was not observed. The conclusion was made that small concentrations of dendrimers can be applied to prevent or decrease the formation of misfolded structures of protein.

Olga Nowacka; Dzmitry Shcharbin; Barbara Klajnert-Maculewicz; Maria Bryszewska

2014-01-01T23:59:59.000Z

480

Aggregation of dialkyl-substituted diphosphonic acids and its effect on metal ion extraction.  

SciTech Connect (OSTI)

Solvent extraction reagents containing the diphosphonic acid group exhibit an extraordinary affinity for tri-, tetra- and hexavalent actinides. Their use has been considered for actinide separation and pre-concentration procedures. Solvent extraction data obtained with P,P{prime}-di(2-ethylhexyl) methane-, ethane- and butanediphosphonic acids exhibit features that are difficult to explain without Knowledge of the aggregation state of the extractants. Information about the aggregation of the dialkyl-substituted diphosphonic acids in aromatic diluents has been obtained using the complementary techniques of vapor pressure osmometry (VPO), small angle neutron scattering (SANS), infrared spectroscopy and molecular mechanics. The results from these techniques provide an understanding of the aggregation behavior of these extractants that is fully compatible with the solvent extraction data. The most important results and their relevance to solvent extraction are reviewed in this paper.

Chiarizia, R.; Barrans, R. E., Jr.; Ferraro, J. R. Herlinger, A. W.; McAlister, D. R.

1999-10-22T23:59:59.000Z

Note: This page contains sample records for the topic "zinc sulfide aggregation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Free energy, enthalpy, and entropy changes for the transference of zinc chloride from enthylene glycol to water solutions  

E-Print Network [OSTI]

in ethylene glycol is coupled with a silver-silver chloride half-cell, also containing zinc chloride dissolved in ethylene glycol, and if a similar cell with zinc chloride in aqueous solution are put back to back by use of a common amalgam reservoir...FREE ENERGY, ENTlDKPY, AND ENTROPY CHANGES FOR THE TRANCE OF ZINC CHLORIDE FROM ETHYLENE GLYCOL TO WATER SOLUTIONS A Thesis JOHN NICHOLAS'8 LOMONTE Submitted to the Graduate School of' the Agricultural and. Mechanical College of' Texas...

Lomonte, John Nicholas

1960-01-01T23:59:59.000Z

482

A method for designing customer-oriented demand response aggregation service  

Science Journals Connector (OSTI)

Abstract Demand response (DR), which controls electric usage of customers when electric system reliability is jeopardised, attracts much societal attention. To realise a pragmatic DR, aggregators have to make well-customised requests for power saving to keep each customer comfortable in energy use. An engineering method is proposed here to design a DR aggregation service from the viewpoint of various customers’ comfort. The idea is to use an optimum resource allocation method that can provide quantitative information on how much electric power should be saved by each customer. The application validated the effectiveness of the proposed method.

Yoshiki Shimomura; Yutaro Nemoto; Fumiya Akasaka; Ryosuke Chiba; Koji Kimita

2014-01-01T23:59:59.000Z

483

Studies of high temperature ternary phases in mixed-metal-rich early transition metal sulfide and phosphide systems  

SciTech Connect (OSTI)

Investigations of ternary mixed early transition metal-rich sulfide and phosphide systems resulted in the discovery of new structures and new phases. A new series of Zr and Hf - group V transition metal - sulfur K-phases was synthesized and crystallographically characterized. When the group V transition metal was Nb or Ta, the unit cell volume was larger than any previously reported K-phase. The presence of adventitious oxygen was determined in two K-phases through a combination of neutron scattering and X-ray diffraction experiments. A compound Hf{sub 10}Ta{sub 3}S{sub 3} was found to crystallize in a new-structure type similar to the known gamma brasses. This structure is unique in that it is the only reported {open_quotes}stuffed{close_quotes} gamma-brass type structure. The metal components, Hf and Ta, are larger in size and more electropositive than the metals found in normal gamma brasses (e.g. Cu and Zn) and because of the larger metallic radii, sulfur can be incorporated into the structure where it plays an integral role in stabilizing this phase relative to others. X-ray single-crystal, X-ray powder and neutron powder refinements were performed on this structure. A new structure was found in the ternary Nb-Zr-P system which has characteristics in common with many known early transition metal-rich sulfides, selenides, and phosphides. This structure has the simplest known interconnection of the basic building blocks known for this structural class. Anomalous scattering was a powerful tool for differentiating between Zr and Nb when using Mo K{alpha} X-radiation. The compounds ZrNbP and HfNbP formed in the space group Prima with the simple Co{sub 2}Si structure which is among the most common structures found for crystalline solid materials. Solid solution compounds in the Ta-Nb-P, Ta-Zr-P, Nb-Zr-P, Hf-Nb-P, and Hf-Zr-S systems were crystallographically characterized. The structural information corroborated ideas about bonding in metal-rich compounds.

Marking, G.A.

1994-01-04T23:59:59.000Z

484

Effect of hydrogen sulfide on chemical looping of coal-derived synthesis gas over bentonite-supported metal---oxide oxygen carriers  

SciTech Connect (OSTI)

The effect of hydrogen sulfide (H2S) on the chemical looping combustion of coal-derived synthesis gas with bentonite-supported metal oxidesssuch as iron oxide, nickel oxide, manganese oxide, and copper oxideswas investigated by thermogravimetric analysis, mass spectrometry, and X-ray photoelectron spectroscopy (XPS). During the reaction with synthesis gas containing H2S, metal-oxide oxygen carriers were first reduced by carbon monoxide and hydrogen, and then interacted with H2S to form metal sulfide, which resulted in a weight gain during the reduction/sulfidation step. The reduced/sulfurized compounds could be regenerated to form sulfur dioxide and oxides during the oxidation reaction with air. The reduction/oxidation capacities of iron oxide and nickel oxide were not affected by the presence of H2S, but both manganese oxide and copper oxide showed decreased reduction/oxidation capacities. However, the rates of reduction and oxidation decreased in the presence of H2S for all four metal oxides.

Tian, H.; Simonyi, T.; Poston, J.; Siriwardane, R.

2009-01-01T23:59:59.000Z

485

Effect of hydrogen sulfide on chemical looping combustion of coal-derived synthesis gas over bentonite-supported metal-oxide oxygen carriers  

SciTech Connect (OSTI)

The effect of hydrogen sulfide (H{sub 2}S) on the chemical looping combustion of coal-derived synthesis gas with bentonite-supported metal oxides - such as iron oxide, nickel oxide, manganese oxide, and copper oxide - was investigated by thermogravimetric analysis, mass spectrometry, and X-ray photoelectron spectroscopy (XPS). During the reaction with synthesis gas containing H{sub 2}S, metal-oxide oxygen carriers were first reduced by carbon monoxide and hydrogen, and then interacted with H{sub 2}S to form metal sulfide, which resulted in a weight gain during the reduction/sulfidation step. The reduced/sulfurized compounds could be regenerated to form sulfur dioxide and oxides during the oxidation reaction with air. The reduction/oxidation capacities of iron oxide and nickel oxide were not affected by the presence of H{sub 2}S, but both manganese oxide and copper oxide showed decreased reduction/oxidation capacities. However, the rates of reduction and oxidation decreased in the presence of H{sub 2}S for all four metal oxides.

Tian, H.J.; Simonyi, T.; Poston, J.; Siriwardane, R. [US DOE, Morgantown, WV (United States). National Energy Technology Laboratory

2009-09-15T23:59:59.000Z

486

Floating mucus aggregates derived from benthic microorganisms on rocky intertidal reefs: Potential as food sources for benthic animals  

Science Journals Connector (OSTI)

Mucus films, flocs or foams consisting of fine sand, algae and detritus frequently occur in the surface waters of rocky intertidal reef flats during incoming tide. These masses are referred to as mucus aggregates. We examined the developmental process of mucus aggregates and their abundance, distribution, migration and trophic composition. The trophic composition of mucus aggregates was then compared to those of sediments to evaluate their potential nutritional value for benthic animals. The organic matter content, chlorophyll a concentration, microalgal density and bacteria-derived fatty acid contents of mucus aggregates were higher than those observed in sediment, suggesting that mucus aggregates contain not only high levels of organic matter but also dense concentrations of microalgae and bacteria; therefore, mucus aggregates may serve as a qualitatively more energetic food source for benthic fauna compared to sediments. Benthic diatoms were the most abundant organisms in mucus aggregates. Large numbers of diatoms were trapped in fine mineral particles and mucilage-like strings, suggesting that a portion of the mucus is secreted by these benthic microalgae. Mucus aggregate accounted for only 0.01–3.9% of the daily feeding requirements of the dominant detritivore, Ophiocoma scolopendrina (Echinodermata: Ophiuroidea) over the entire sampling area. In contrast, for the species population on the back reef, where mucus aggregates ultimately accumulate, mucus aggregates provided from 0.4 to 113.3% of food for this species. These results suggest that mucus aggregate availability varies spatiotemporally and that they do not always provide adequate food sources for O. scolopendrina populations.

Y. Tamura; M. Tsuchiya

2011-01-01T23:59:59.000Z

487

Natural and synthetic double-stranded DNA binding studies of macrocyclic tetraamine zinc(II) complexes appended with polyaromatic groups  

Science Journals Connector (OSTI)

...?The characteristic binding mode of zinc(II) complexes of macrocyclic tetraamines (1,4,7,10-tetraazacyclododecane, cyclen) appended with one or two arylmethyl group(s) [(4-quinolyl)methyl-, 1,7-bis(4-quinolyl)...

Emiko Kikuta; Naomi Katsube; E. Kimura

1999-08-01T23:59:59.000Z

488

Influence of Activation (Reduction) Conditions on the Catalytic Activity of Copper-Zinc Catalysts of NTK-10 Series  

Science Journals Connector (OSTI)

X-ray phase analysis and the temperature-programmed reduction method were applied to study the activation (reduction) of copper-zinc catalysts of the NTK-10 series. The catalytic activity of catalysts reduced ...

P. D. Androsov; I. A. Mamaeva; E. Z. Golosman

2004-07-01T23:59:59.000Z

489

Summary and assessment of METC zinc ferrite hot coal gas desulfurization test program, final report: Volume 2, Appendices  

SciTech Connect (OSTI)

The Morgantown Energy Technology Center (METC) has conducted a test program to develop a zinc ferrite-based high temperature desulfurization process which could be applied to fuel gas entering downstream components such as molten carbonate fuel cells or gas turbines. As a result of prior METC work with iron oxide and zinc oxide sorbents, zinc ferrite evolved as a candidate with the potential for high capacity, low equilibrium levels of H/sub 2/S, and structural stability after multiple regenerations. The program consisted of laboratory-scale testing with a two-inch diameter reactor and simulated fixed-bed gasifier gas; bench-scale testing with a six-inch diameter reactor and actual gas from the METC 42-inch fixed bed gasifier; as well as laboratory-scale testing of zinc ferrite with simulated fluidized bed gasifier gas. Data from sidestream testing are presented. 18 refs.

Underkoffler, V.S.

1986-12-01T23:59:59.000Z

490

Design and synthesis of novel functionalized sensors for the biological imaging of zinc(II) and nitric oxide  

E-Print Network [OSTI]

CHAPTER 1: Fluorescent Sensors for the Biological sensing of Zinc(II) A variety of fluorescent techniques have been developed for the in vivo sensing of Zn2+. This chapter presents a brief overview of techniques used to ...

Won, Annie C., 1983-

2005-01-01T23:59:59.000Z

491

Zinc Treatment Effects on Corrosion Behavior of 304 Stainless Steel in High Temperature, Hydrogenated Water  

SciTech Connect (OSTI)

Trace levels of soluble zinc(II) ions (30 ppb) maintained in mildly alkaline, hydrogenated water at 260 C were found to lower the corrosion rate of austenitic stainless steel (UNS S30400) by about a factor of five, relative to a non-zinc baseline test after 10,000 hr. Characterizations of the corrosion oxide layer via grazing incidence X-ray diffraction and X-ray photoelectron spectroscopy in combination with argon ion milling and target factor analysis, confirmed the presence of two spinel oxide phases and minor amounts of recrystallized nickel. Based on the distribution of the three oxidized alloying constituents (Fe, Cr, Ni) with respect to depth and oxidation state, it was concluded that: (a) corrosion occurs in a non-selective manner, but approximately 30% of the oxidized iron is released to the water, and (b) the two spinel oxides exist as a ferrite-based outer layer (Ni{sub 0.1}Zn{sub 0.6}Fe{sub 0.3})(Fe{sub 0.95}Cr{sub 0.05}){sub 2}O{sub 4} on top of a chromite-based inner layer (Ni{sub 0.1}Zn{sub 0.2}Fe{sub 0.7})(Fe{sub 0.4}Cr{sub 0.6}){sub 2}O{sub 4}. These results suggest that immiscibility in the Fe{sub 3}O{sub 4}-ZnFe{sub 2}O{sub 4} binary may play a role in controlling the zinc content of the outer layer. On the other hand, the lower corrosion rate caused by zinc additions is believed to be a consequence of corrosion oxide film stabilization due to the substitution reaction equilibrium: z Zn{sup 2+}(aq) + FeCr{sub 2}O{sub 4}(s) {approx} z Fe{sup 2+}(aq) + (Zn{sub z}Fe{sub 1-z})Cr{sub 2}O{sub 4}(s). The liquid-solid distribution coefficient for the reaction, defined by the ratio of total zinc to iron ion concentrations in solution divided by the Zn(II)/Fe(II) ratio in the solid, z/(1-z), was found to be 0.184. This interpretation is consistent with the benefits of zinc treatment being concentration dependent.

S.E. Ziemniak; M. Hanson

2001-03-20T23:59:59.000Z

492

Investigation of carbon nanotubes decorated with cobalt sulfides of different phases as nanocomposite catalysts in dye-sensitized solar cells  

Science Journals Connector (OSTI)

Abstract In this study, nanocomposites of cobalt sulfide and carbon nanotube (CNT) in the forms of CNT@CoS1.097 and CNT@Co9S8 were deposited on fluorine-doped SnO2 (FTO)-coated glasses by using a facile spray-coating approach, followed by annealing under N2 atmosphere at 400 and 600 °C, respectively; and employed as counter electrodes (CEs) for dye-sensitized solar cells (DSCs). According to the electrochemical properties of \\{CEs\\} quantified by cyclic voltammetry, electrochemical impedance spectroscopy, and Tafel polarization measurements, the CNT@Co9S8 CE showed a superior electrocatalytic activity towards triiodide (I3) reduction to that of the CNT@CoS1.097 CE. As a result, the DSC based on the CNT@Co9S8 CE achieved an impressive photovoltaic conversion efficiency of 7.78%, which was even higher than those of the \\{DSCs\\} assembled with the CNT@CoS1.097 CE (7.29%) and Pt CE (7.46%). This signifies that the CNT@Co9S8 was indeed an efficient and cost-effective Pt-like alternative CE for I3 reduction reaction in DSCs.

Sheng-Yen Tai; Man-Ning Lu; Hsin-Ping Ho; Yaoming Xiao; Jeng-Yu Lin

2014-01-01T23:59:59.000Z

493

Study of benzotriazole as corrosion inhibitors of carbon steel in chloride solution containing hydrogen sulfide using electrochemical impedance spectroscopy (EIS)  

SciTech Connect (OSTI)

Corrosion and inhibition studies on API 5LX65 carbon steel in chloride solution containing various concentrations of benzotriazole has been conducted at temperature of 70°C using Electrochemical Impedance Spectroscopy (EIS). Corroded carbon steel surface with and without inhibitor have been observed using X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), and Energy Dispersive Spectroscopy (EDS). The objectives of this research are to study the performance of benzotriazole as corrosion inhibitors. The experimental results of carbon steel corrosion in 3.5% NaCl solution containing 500 mg/l H{sub 2}S at different BTAH concentrations showed that corrosion rate of carbon steel decreases with increasing of BTAH concentrations from 0 to 10 mmol/l. The inhibition efficiency of BTAH was found to be affected by its concentration. The optimum efficiency obtained of BTAH is 93% at concentration of 5 mmol/l. The result of XRD and EDS analysis reveal the iron sulfide (FeS) formation on corroded carbon steel surface without inhibitor. The EDS spectrum show the Nitrogen (N) bond on carbon steel surface inhibited by BTAH.

Solehudin, Agus, E-mail: asolehudin@upi.edu [Department of Mechanical Engineering Education, Indonesia University of Education (UPI), Bandung, West Java (Indonesia); Nurdin, Isdiriayani [Department of Chemical Engineering, Bandung Institute of Technology, Bandung, West Java (Indonesia)

2014-03-24T23:59:59.000Z

494

Lithium/iron sulfide batteries for electric-vehicle propulsion and other applications. Progress report, October 1979-March 1980  

SciTech Connect (OSTI)

The research and development activities of the program at Argonne National Laboratory (ANL) on lithium/iron sulfide batteries during the period October 1979-March 1980 is described. Although the major emphasis is currently on batteries for electric-vehicle propulsion, stationary energy-storage applications are also under investigation. The individual battery cells, which operate at 400 to 500/sup 0/C, are of a vertically oriented, prismatic design with two or more positive electrodes of FeS or FeS/sub 2/, facing negative electrodes of lithium-aluminum or lithium-silicon alloy, and molten LiCl-KCl electrolyte. The ANL program consists of cell chemistry studies, materials engineering, and component and auxiliary systems development. Important elements of this program are studies of the effects of design modifications on cell performance and post-test examinations of cells. During the reporting period, cell and battery development work has been aimed primarily at the first phase of the Mark II electric-vehicle battery program, which consists of an effort to develop high-reliability cells having boron nitride felt separators. Later in the Mark II program, the cells will be tested in 10-cell modules. Work on stationary energy-storage batteries during this period has consisted mainly of conceptual design studies. 23 figures, 9 tables.

None

1980-08-01T23:59:59.000Z

495

Corrosion behavior of an HVOF-sprayed Fe3Al coating in a high-temperature oxidizing/sulfidizing environment  

SciTech Connect (OSTI)

An iron aluminide (Fe3Al) intermetallic coating was deposited onto a F22 (2.25Cr-1Mo) steel substrate using a JP-5000 high velocity oxy-fuel (HVOF) thermal spray system. The as-sprayed coating was examined by electron microscopy and X-ray diffraction and was characterized in terms of oxidation and adhesion. Fe3Al-coated steel specimens were exposed to a mixed oxidizing/sulfidizing environment at 500, 600, 700, and 800DGC for approximately seven days. The gaseous environment consisted of N2-10%CO-5%CO2-2%H2O-0.12%H2S (by volume). All specimens gained mass after exposure to the environment and the mass gains were found to be inversely proportional to temperature increases. Representative specimens exposed at each temperature were cross-sectioned and subjected to examination under a scanning electron microscope (SEM) and X-ray mapping. Results are presented in terms of corrosion weight gain and corrosion product formation. The purpose of the research presented here was to evaluate the effectiveness of an HVOF-sprayed Fe3Al coating in protecting a steel substrate exposed to a fossil energy environment.

Covino, Bernard S., Jr.; Bullard, Sophie J.; Cramer, Stephen D.; Holcomb, Gordon R.; Ziomek-Moroz, Margaret; Shrestha, S. (TWI Ltd.); Harvey, D. (TWI Ltd.)

2005-01-01T23:59:59.000Z

496

Unsupervised Rank Aggregation with Domain-Specific Expertise Alexandre Klementiev, Dan Roth, Kevin Small, and Ivan Titov  

E-Print Network [OSTI]

Unsupervised Rank Aggregation with Domain-Specific Expertise Alexandre Klementiev, Dan Roth, Kevin of judges is re- peatedly asked to (partially) rank sets of objects according to given criteria, and assume that the judges' expertise depends on the objects' domain. Learning to aggregate their rankings with the goal

Titov, Ivan

497

Synchrotron 3D microtomography of halite aggregates during experimental pressure solution creep and evolution of the permeability  

E-Print Network [OSTI]

Synchrotron 3D microtomography of halite aggregates during experimental pressure solution creep and permeability variations in the upper crust. The three- dimensional geometry of the porous network of halite), Synchrotron 3D microtomography of halite aggregates during experimental pressure solution creep and evolution

498

Wind Aggregation Via Risky Power Markets Yue Zhao, Member, IEEE, Junjie Qin, Student Member, IEEE, Ram Rajagopal, Member, IEEE,  

E-Print Network [OSTI]

.g., Cali- fornia and parts of Europe) is to take all wind power generation into the system as negative load1 Wind Aggregation Via Risky Power Markets Yue Zhao, Member, IEEE, Junjie Qin, Student Member, IEEE Abstract--Aggregation of diverse wind power sources can effectively reduce their uncertainty, and hence

Zhao, Yue

499

Biomimetic growth of strontium oxalate aggregates with unusual morphologies in the presence of poly(methacrylic acid)  

E-Print Network [OSTI]

Paper Biomimetic growth of strontium oxalate aggregates with unusual morphologies in the presence-like strontium oxalate dihydrate (SOD) crystals. The formation of the unusual aggregated structures showed fractal structures.20 In the present work, we investigated the crystallization of strontium

Qi, Limin

500

E-Span and LPT for data aggregation in wireless sensor networks Weinan Marc Lee *, Vincent W.S. Wong  

E-Print Network [OSTI]

cost and improves energy efficiency. In this paper, we propose two different tree structures to facilitate data aggregation. We first propose E-Span, which is an energy-aware spanning tree algorithm. In E energy are chosen as the aggregating parents. LPT also includes a self-healing feature by which the tree

Wong, Vincent