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1

Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah, November 2005 Through February 2008  

Energy.gov (U.S. Department of Energy (DOE))

Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah, November 2005 Through February 2008

2

Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah,  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Dispersivity Testing of Zero-Valent Iron Treatment Cells: Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah, November 2005 Through February 2008 Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah, November 2005 Through February 2008 Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah, November 2005 Through February 2008 Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah, November 2005 Through February 2008 More Documents & Publications Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable

3

Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable Reactive Barrier, Monticello, Utah  

Energy.gov (U.S. Department of Energy (DOE))

Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable Reactive Barrier, Monticello, Utah

4

Pilot-Scale Demonstration of Hybrid Zero-Valent Iron Water Treatment Technology: Removing Trace Metals from Flue Gas Desulfurization (FGD) Wastewater  

Science Conference Proceedings (OSTI)

In previous laboratory- and field bench-scale tests, the hybrid zero-valent iron (hZVI) process had been demonstrated capable of removing selenium, mercury, nitrates, and other pollutants from flue gas desulfurization (FGD) wastewater. By incorporating zero-valent iron (ZVI) with magnetite and certain Fe(II) species, the hZVI technology creates a highly reactive mixture that can transform and immobilize various trace metals, oxyanions, and other impurities from aqueous streams. To further evaluate ...

2013-04-09T23:59:59.000Z

5

Degradation of organic and inorganic contaminants by zero valent iron  

E-Print Network (OSTI)

Reduction of trichloroethylene (TCE), chromium (VI), and 2,4 dinitrotoluene (2,4-DNT) by zero valent iron and palladized iron under anaerobic conditions was investigated. Reduction experiments of the contaminants were carried out individually and in combination. All three target contaminants were effectively reduced by both iron (Feo) and palladized iron (Pd/Fe'). However, the rate of reduction by Pd/Fe' was found to be much faster than that by Feo. The reduction of all the contaminants in mixed waste was found to be slower than in the individual experiments, but the difference was most significant in the 2,4-DNT reduction. This observation indicates that there may be a possibility of competition for reactive sites among the contaminants and precipitation resulting from CR(VI) reduction may coat iron surfaces, which may ultimately slow the whole zero valent metals (ZVMS) treatment process in remediating mixed waste sites. The 20 mg/L of CR(VI) was reduced below detection limits in 10 hours by Fe' and in 1.5 hours by the same amount of Pd/Fe' in individual experiment. An initial concentration of 20 mg/L of TCE was reduced below detection limits in 72 hours by Pd/Fe' whereas only 62% of TCE was reduced by the same amount of Fe' in 144 hours in individual experiment. The reaction orders of 1.84 and 2.04 for total TCE loss alone and in mixed waste by Fe' indicates that the reaction mechanisms are complex. The reduction of 72 mg/L of 2,4-DNT proceeded to below detection limits within 3 hours by both Fe' and Pd/Feo. The only product observed in the reduction of 2,4-DNT was 2,4-diaminotoluene (2,4-DAT). The 2,4-DAT produced accounted for 83-100% and only 42-54% of the initial mass of 2@4.DNT under anaerobic and aerobic conditions respectively. Since no degradation of 2,4-DAT alone occurred, these results indicate the possibility of other intermediates or products formation under aerobic conditions. Overall, the results demonstrated the potential application of ZVMs in reducing mixed wastes containing both inorganic and organic contaminant interactions before implementing a ZVMs treatment system, which may help in designing a proper remedial system.

Malla, Deepak Babu

1997-01-01T23:59:59.000Z

6

Zero Valent Iron: Impact of Anions Present during Synthesis on Subsequent Nanoparticle Reactivity  

SciTech Connect

Zero-valent iron particles are an effective remediation technology for groundwater contaminated with halogenated organic compounds. In particular, nano-scale zero-valent iron is a promising material for remediation due to its high specific surface area, which results in faster rate constants and more effective use of the iron. An aspect of iron nanoparticle reactivity that has not been explored is the impact of anions present during iron metal nanoparticle synthesis. Solutions containing chloride, phosphate, sulfate, and nitrate anions and ferric ions were used to generate iron oxide nanoparticles. The resulting materials were dialyzed to remove dissolved byproducts and then dried and reduced by hydrogen gas at high temperature. The reactivity of the resulting zero valent iron nanoparticles was quantified by monitoring the kinetics as well as products of carbon tetrachloride reduction, and significant differences in reactivity and chloroform yield were observed. The reactivity of nanoparticles prepared in the presence of sulfate and phosphate demonstrated the highest reactivity and chloroform yield. Furthermore, substantial variations in the solid-state products of oxidation (magnetite, iron sulfide, and goethite, among others) were also observed.

Moore, Kirsten; Forsberg, Brady; Baer, Donald R.; Arnold, William A.; Penn, R. Lee

2011-10-01T23:59:59.000Z

7

Reduction and Immobilization of Radionuclides and Toxic Metal Ions Using Combined Zero Valent Iron and Anaerobic Bacteria  

Science Conference Proceedings (OSTI)

The use of zero valent iron, permeable reactive barriers (PRBs) for groundwater remediation continues to increase. AN exciting variation of this technology involves introducing anaerobic bacteria into these barriers so that both biological and abiotic pollutant removal processes are functional. This work evaluated the hypothesis that a system combining a mixed culture of sulfate reducing bacteria (SRB) with zero valent iron would have a greater cr(VI) removal efficiency and a greater total Cr(VI) removal capacity than a zero valent iron system without the microorganisms. Hence, the overall goal of this research was to compare the performance of these types of systems with regard to their Cr(VI) removal efficiency and total Cr(VI) removal capacity. Both batch and continuous flow reactor systems were evaluated.

Lenly J. Weathers; Lynn E. Katz

2002-05-29T23:59:59.000Z

8

Injection of Zero Valent Iron into an Unconfined Aquifer Using Shear-Thinning Fluids  

Science Conference Proceedings (OSTI)

Approximately 190 kg of two micron-diameter zero-valent iron (ZVI) particles were injected into a test zone in the top two meters of an unconfined aquifer within a trichloroethene (TCE) source area. A shear-thinning fluid was used to enhance ZVI delivery in the subsurface to a radial distance of up to four meters from a single injection well. The ZVI particles were mixed in-line with the injection water, shear-thinning fluid, and a low concentration of surfactant. ZVI was observed at each of the seven monitoring wells within the targeted radius of influence during injection. Additionally, all wells within the targeted zone showed low TCE concentrations and primarily dechlorination products present 44 days after injection. These results suggest that ZVI can be directly injected into an aquifer with shear-thinning fluids and extends the applicability of ZVI to situations where other emplacement methods may not be viable.

Truex, Michael J.; Vermeul, Vincent R.; Mendoza, Donaldo P.; Fritz, Brad G.; Mackley, Rob D.; Oostrom, Martinus; Wietsma, Thomas W.; Macbeth, Tamzen

2011-02-18T23:59:59.000Z

9

Modelling the remediation of contaminated groundwater using zero-valent iron barrier  

Science Conference Proceedings (OSTI)

This paper presents results of modelling studies on remediation of groundwater contaminated with uranium using a zero-valent iron permeable reactive barrier (ZVI PRB) at the U.S. Oak Ridge Y-12 site that are used to establish modelling techniques that are of value to other sites such as in the UK. A systematic modelling methodology has been developed to study the problem by using a suite of modelling tools. Firstly a conceptual basis of the main chemical processes representing the remediation of uranium by the ZVI PRB is developed. Two main effects involving reduction and corrosion have been identified as being relevant for the remediation processes. These are then formulated and implemented using the reactive chemical model PHREEQC to provide underpinning chemical input parameters for subsequent reactive solute transport modelling using the TRAFFIC and PHAST codes. Initial results shows that modelling can be a very cost-effective means to study the hydrogeological and geochemical processes involved and to aid understanding of the remediation concept. The modelling approaches presented and lessons learnt are thought to be relevant to other cases of contaminated land study and are likely to be of value to site management concepts which consider on-site disposal of contaminated soils and materials. (authors)

Kwong, S.; Small, J.; Tahar, B. [Nexia Solutions Ltd., Hinton House, Risley, Warrington, WA (United Kingdom)

2007-07-01T23:59:59.000Z

10

Performance of a Permeable Reactive Barrier Using Granular Zero-Valent  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Performance of a Permeable Reactive Barrier Using Granular Performance of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site Performance of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site Performance of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site Performance of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site More Documents & Publications Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing

11

Aerosol synthesis of nano and micro-scale zero valent metal particles from oxide precursors  

SciTech Connect

In this work a novel aerosol method, derived form the batch Reduction/Expansion Synthesis (RES) method, for production of nano / micro-scale metal particles from oxides and hydroxides is presented. In the Aerosol-RES (A-RES) method, an aerosol, consisting of a physical mixture of urea and metal oxide or hydroxides, is passed through a heated oven (1000 C) with a residence time of the order of 1 second, producing pure (zero valent) metal particles. It appears that the process is flexible regarding metal or alloy identity, allows control of particle size and can be readily scaled to very large throughput. Current work is focused on creating nanoparticles of metal and metal alloy using this method. Although this is primarily a report on observations, some key elements of the chemistry are clear. In particular, the reducing species produced by urea decomposition are the primary agents responsible for reduction of oxides and hydroxides to metal. It is also likely that the rapid expansion that takes place when solid/liquid urea decomposes to form gas species influences the final morphology of the particles.

Phillips, Jonathan [Los Alamos National Laboratory; Luhrs, Claudia [UNM; Lesman, Zayd [UNM; Soliman, Haytham [UNM; Zea, Hugo [UNM

2010-01-01T23:59:59.000Z

12

Construction Summary and As-Built Report for Ground Water Treatment System  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Construction Summary and As-Built Report for Ground Water Treatment Construction Summary and As-Built Report for Ground Water Treatment System Monticello, Utah, Permeable Reactive Barrier Site Construction Summary and As-Built Report for Ground Water Treatment System Monticello, Utah, Permeable Reactive Barrier Site Construction Summary and As-Built Report for Ground Water Treatment System Monticello, Utah, Permeable Reactive Barrier Site Construction Summary and As-Built Report for Ground Water Treatment System Monticello, Utah, Permeable Reactive Barrier Site More Documents & Publications Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah, November 2005 Through February 2008 Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable Reactive Barrier, Monticello, Utah Performance Assessment and Recommendations for Rejuvenation of a Permeable

13

Shape effects of iron nanowires on hyperthermia treatment  

Science Conference Proceedings (OSTI)

This research discusses the influence ofmorphology of nanomagneticmaterials (one-dimensional iron nanowires and zero-dimensional iron nanoparticles) on heating efficiency of the hyperthermia treatment. One-dimensional iron nanowires, synthesized by reducing ...

Wei-Syuan Lin, Hong-Ming Lin, Hsiang-Hsin Chen, Yeu-Kuang Hwu, Yuh-Jing Chiou

2013-01-01T23:59:59.000Z

14

Ground-Water Table and Chemical Changes in an Alluvial Aquifer During  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Ground-Water Table and Chemical Changes in an Alluvial Aquifer Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells More Documents & Publications Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Cañon City, Colorado, Uranium

15

Ground-Water Table and Chemical Changes in an Alluvial Aquifer During  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Ground-Water Table and Chemical Changes in an Alluvial Aquifer Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells More Documents & Publications Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Cañon City, Colorado, Uranium

16

THE EFFECT OF SMECTITE ON THE CORROSION OF IRON METAL  

SciTech Connect

The combination of zero-valent iron and a clay-type amendment is often observed to have a synergistic effect on the rate of reduction reactions. In this paper, electrochemical techniques are used to determine the mechanism of interaction between the iron and smectite clay minerals. Iron electrodes coated with an evaporated smectite suspension (clay-modified iron electrodes, CMIEs) were prepared using five different smectites: SAz-1, SWa-1, STx-1, SWy-1, and SHCa-1. All the smectites were exchanged with Na+ and one sample of SWy-1 was also exchanged with Mg2+. Potentiodynamic potential scans and cyclic voltammograms were taken using the CMIEs and uncoated but passivated iron electrodes. These electrochemical experiments, along with measurements of the amount of Fe2+ and Fe3+ sorbed in the smectite coating, suggested that the smectite removed the passive layer of the underlying iron electrode during the evaporation process. Cyclic voltammograms taken after the CMIEs were biased at the active-passive transition potential for varying amounts of time suggested that the smectite limited growth of a passive layer, preventing passivation. These results are attributed to the Broensted acidity of the smectite as well as to its ability to sorb iron cations. Oxides that did form on the surface of the iron in the presence of the smectite when it was biased anodically seemed to be different than those that form on the surface of an uncoated iron electrode under otherwise similar conditions; this difference suggested that the smectite reacted with the Fe2+ formed from the oxidation of the underlying iron. No significant correlation could be found between the ability of the smectite to remove the iron passive film and the smectite type. The results have implications for the mixing of sediments and iron particles in permeable reactive barriers, underground storage of radioactive waste in steel canisters, and the use of smectite supports in preventing aggregation of nano-sized zero-valent iron.

Balko, Barbara A.; Bosse, Stephanie A.; Cade, Anne E.; Jones-Landry, Elise F.; Amonette, James E.; Daschbach, John L.

2012-04-24T23:59:59.000Z

17

Biological Treatment of Ammonia-Rich Wastewaters by Natural Microbial Communities in the ATOXIC/ASSET Purification System  

Science Conference Proceedings (OSTI)

Analyses of bacterial and archaeal 16S rRNA genes along with high throughput 454 pyrosequencing technology were used to identify microbial communities present at a novel passive wastewater treatment system designed to remove ammonium, nitrate, and heavy metals from fossil plant effluents. Seasonal changes in microbial community composition were observed, however significant (p=0.001) changes were detected in bacterial and archaeal communities consistent with ammonium removal throughout the treatment systems. Phylogenetic analysis of 16S rRNA gene sequences revealed presence of potential ammonium-oxidizing bacteria (AOB), Nitrosomonas, Nitrosococcus, Planctomycetes, and OD1. Other bacteria, such as Nitrospira, Nitrococcus, Nitrobacter, Thiobacillus, -Proteobacteria, Firmicutes, Acidobacteria, which play roles in nitrification and denitrification, were also detected. The relative abundance of the potential ammonium-oxidizing archaea (AOA) (Thermoprotei within the phylum Crenarchaeota) increased with ammonium availability at the splitter box and zero-valent iron extraction trenches even though AOB removed half of the ammonium in the trickling filters at the beginning of the treatment system. The microbial community removed the ammonium from the wastewater within both pilot-scale treatment systems, thus the treatment system components provided an effective environment for the treatment of ammonium enriched wastewater from coal burning power plants equipped with selective catalytic reducers for nitrogen oxide removal.

Vishnivetskaya, Tatiana A [ORNL; Fisher, L. Suzanne [Tennessee Valley Authority (TVA); Brodie, Greg A [Tennessee Valley Authority (TVA); Phelps, Tommy Joe [ORNL

2013-01-01T23:59:59.000Z

18

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

51 - 10060 of 28,905 results. 51 - 10060 of 28,905 results. Download Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah, November 2005 Through February 2008 Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah, November 2005 Through February 2008 http://energy.gov/lm/downloads/dispersivity-testing-zero-valent-iron-treatment-cells-monticello-utah Download Microsoft Word- AL2000-05Attachment.doc http://energy.gov/management/downloads/microsoft-word-al2000-05attachmentdoc Download October 2012 APM Newsletter http://energy.gov/management/downloads/october-2012-apm-newsletter Page FAQs Topics: http://energy.gov/management/office-management/employee-services/faqs Download EA-1611: Final Environmental Assessment Interconnection Request for the Colorado Highlands Wind Project

19

Microsoft Word - S04040_tracer.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Dispersivity Testing of Zero-Valent Iron Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah November 2005 Through February 2008 April 2008 DOE LM/1587 2008 - - ESL RPT 2008 02 - - - Work Performed nder DOE Contract No. for the U.S. Department of Energy Office of Legacy Management. by the S.M. Stoller Corporation u DE AM01 07LM00060 - - Approved for public release; distribution is unlimited. This page intentionally left blank DOE-LM/1587-2007 ESL-RPT-2008-02 Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah, November 2005 Through February 2008 April 2008 Work Performed by S.M. Stoller Corporation under DOE Contract No. DE-AM01-07LM00060 for the U.S. Department of Energy Office of Legacy Management, Grand Junction, Colorado This page intentionally left blank

20

Microsoft Word - S04040_tracer.doc  

Office of Legacy Management (LM)

Dispersivity Testing of Zero-Valent Iron Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah November 2005 Through February 2008 April 2008 DOE LM/1587 2008 - - ESL RPT 2008 02 - - - Work Performed nder DOE Contract No. for the U.S. Department of Energy Office of Legacy Management. by the S.M. Stoller Corporation u DE AM01 07LM00060 - - Approved for public release; distribution is unlimited. This page intentionally left blank DOE-LM/1587-2007 ESL-RPT-2008-02 Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah, November 2005 Through February 2008 April 2008 Work Performed by S.M. Stoller Corporation under DOE Contract No. DE-AM01-07LM00060 for the U.S. Department of Energy Office of Legacy Management, Grand Junction, Colorado This page intentionally left blank

Note: This page contains sample records for the topic "zero-valent iron treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Effect of thermal treatment on coke reactivity and catalytic iron mineralogy  

SciTech Connect

Iron minerals in coke can catalyze its gasification and may affect coke behavior in the blast furnace. The catalytic behavior of iron depends largely upon the nature of the iron-bearing minerals. To determine the mineralogical changes that iron could undergo in the blast furnace, cokes made from three coals containing iron present in different mineral forms (clays, carbonates, and pyrite) were examined. All coke samples were heat-treated in a horizontal furnace at 1373, 1573, and 1773 K and then gasified with CO{sub 2} at 1173 K in a fixed bed reactor (FBR). Coke mineralogy was characterized using quantitative X-ray diffraction (XRD) analysis of coke mineral matter prepared by low-temperature ashing (LTA) and field emission scanning electron microscopy combined with energy dispersive X-ray analysis (FESEM/EDS). The mineralogy of the three cokes was most notably distinguished by differing proportions of iron-bearing phases. During heat treatment and subsequent gasification, iron-containing minerals transformed to a range of minerals but predominantly iron-silicides and iron oxides, the relative amounts of which varied with heat treatment temperature and gasification conditions. The relationship between initial apparent reaction rate and the amount of catalytic iron minerals - pyrrhotite, metallic iron, and iron oxides - was linear and independent of heat treatment temperature at total catalyst levels below 1 wt %. The study showed that the coke reactivity decreased with increasing temperature of heat treatment due to decreased levels of catalytic iron minerals (largely due to formation of iron silicides) as well as increased ordering of the carbon structure. The study also showed that the importance of catalytic mineral matter in determining reactivity declines as gasification proceeds. 37 refs., 13 figs., 7 tabs.

Byong-chul Kim; Sushil Gupta; David French; Richard Sakurovs; Veena Sahajwalla [University of New South Wales, Sydney, NSW (Australia). Centre for Sustainable Materials Research and Technology

2009-07-15T23:59:59.000Z

22

IIT Bombay offers to license intellectual property (IP) created through its research and development efforts and which are available in the form of patents, patent applications, design, trademark, copy-  

E-Print Network (OSTI)

cell covered by an anti-reflective 3506/MUM/2010 coating (ARC) layer EE 26 Solar fluid heater 2502/MUM An improved process for water treatment to remove Arsenic, Iron and Phosphate 2336/MUM/2008 by zero valent EE 14 Refrigeration cum water heating system 151/MUM/2002 EE 15 Switchable heat pipe 152/MUM/2002 EE

Narayanan, H.

23

Thermal treatment for increasing magnetostrictive response of rare earth-iron alloy rods  

DOE Patents (OSTI)

Magnetostrictive rods formed from rare earth-iron alloys are subjected to a short time heat treatment to increase their Magnetostrictive response under compression. The heat treatment is preferably carried out at a temperature of from 900.degree. to 1000.degree. C. for 20 minutes to six hours.

Verhoeven, John D. (Ames, IA); McMasters, O. D. (Ames, IA)

1989-07-18T23:59:59.000Z

24

Fate of As, Se, and Hg in a Passive Integrated System for Treatment of Fossil Plant Wastewater  

SciTech Connect

TVA is collaborating with EPRI and DOE to demonstrate a passive treatment system for removing SCR-derived ammonia and trace elements from a coal-fired power plant wastewater stream. The components of the integrated system consist of trickling filters for ammonia oxidation, reaction cells containing zero-valent iron (ZVI) for trace contaminant removal, a settling basin for storage of iron hydroxide floc, and anaerobic vertical-flow wetlands for biological denitrification. The passive integrated treatment system will treat up to 0.25 million gallons per day (gpd) of flue gas desulfurization (FGD) pond effluent, with a configuration requiring only gravity flow to obviate the need for pumps. The design of the system will enable a comparative evaluation of two parallel treatment trains, with and without the ZVI extraction trench and settling/oxidation basin components. One of the main objectives is to gain a better understanding of the chemical transformations that species of trace elements such as arsenic, selenium, and mercury undergo as they are treated in passive treatment system components with differing environmental conditions. This progress report details the design criteria for the passive integrated system for treating fossil power plant wastewater as well as performance results from the first several months of operation. Engineering work on the project has been completed, and construction took place during the summer of 2005. Monitoring of the passive treatment system was initiated in October 2005 and continued until May 18 2006. The results to date indicate that the treatment system is effective in reducing levels of nitrogen compounds and trace metals. Concentrations of both ammonia and trace metals were lower than expected in the influent FGD water, and additions to increase these concentrations will be done in the future to further test the removal efficiency of the treatment system. In May 2006, the wetland cells were drained of FGD water, refilled with less toxic ash pond water, and replanted due to low survival rates from the first planting the previous summer. The goals of the TVA-EPRI-DOE collaboration include building a better understanding of the chemical transformations that trace elements such as arsenic, selenium, and mercury undergo as they are treated in a passive treatment system, and to evaluate the performance of a large-scale replicated passive treatment system to provide additional design criteria and economic factors.

Terry Yost; Paul Pier; Gregory Brodie

2007-12-31T23:59:59.000Z

25

Population dynamics of iron-oxidizing communities in pilot plants for the treatment of acid mine waters  

Science Conference Proceedings (OSTI)

The iron-oxidizing microbial community in two pilot plants for the treatment of acid mine water was monitored to investigate the influence of different process parameters such as pH, iron concentration, and retention time on the stability of the system to evaluate the applicability of this treatment technology on an industrial scale. The dynamics of the microbial populations were followed using T-RFLP (terminal restriction fragment length polymorphism) over a period of several months. For a more precise quantification, two TaqMan assays specific for the two prominent groups were developed and the relative abundance of these taxa in the iron-oxidizing community was verified by real-time PCR. The investigations revealed that the iron-oxidizing community was clearly dominated by two groups of Betaproteobacteria affiliated with the poorly known and not yet recognized species 'Ferrovum myxofaciens' and with strains related to Gallionella ferruginea, respectively. These taxa dominated the microbial community during the whole investigation period and accelerated the oxidation of ferrous iron despite the changing characteristics of mine waters flowing into the plants. Thus, it is assumed that the treatment technology can also be applied to other mine sites and that these organisms play a crucial role in such treatment systems. 32 refs., 4 figs. 1 tab.

Elke Heinzel; Eberhard Janneck; Franz Glombitza; Michael Schlmann; Jana Seifert [TU Bergakademie Freiberg, Freiberg (Germany). Interdisciplinary Ecological Center

2009-08-15T23:59:59.000Z

26

Microsoft Word - S03840_MNT ZVI Treat Cells_Feb08.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Ground-Water Table and Chemical Changes Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells January 2008 DOE LM/1560 2008 - - ESL RPT 2008-01 - - Work Performed nder DOE Contract No. for the U.S. Department of Energy Office of Legacy Management. by the S.M. Stoller Corporation u DE AC01 02GJ79491 - - Approved for public release; distribution is unlimited. Environmental Sciences Laboratory Environmental Sciences Laboratory Environmental Sciences Laboratory Environmental Sciences Laboratory Environmental Sciences Laboratory This page intentionally left blank DOE-LM/1560-2007 ESL-RPT-2008-01 Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells

27

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

71 - 22380 of 26,764 results. 71 - 22380 of 26,764 results. Download Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells http://energy.gov/lm/downloads/ground-water-table-and-chemical-changes-alluvial-aquifer-during Download DOE-STD-3006-2000 Planning and Conduct of Operational Readiness Reviews Replaced by DOE-STD-3006-2010 | Superseding DOE-STD-3006-95 (November 1995) DOE O 425.1B specifies the conditions and circumstances when an Operational Readiness Review (ORR) or a Readiness Assessment (RA) is required as part of a new start or restart process. This standard provides guidance on the

28

Treatment of High-Flow, Low-Iron Mine Drainage with a Semi-Passive...  

NLE Websites -- All DOE Office Websites (Extended Search)

An Aquafix(tm) system used in combination with wetlands (0.40 ha) effectively reduced iron concentrations from between 5 - 6 mgL to less than 1 mgL. At this particular...

29

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Utah A permeable reactive barrier (PRB) of zero-valent iron is helping to clean up groundwater at a former uranium and vanadium ore processing mill at Monticello, Utah. LM...

30

Hydraulic Conductivity of the Monticello Permeable Reactive Barrier  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Hydraulic Conductivity of the Monticello Permeable Reactive Barrier Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update More Documents & Publications Variation in Hydraulic Conductivity Over Time at the Monticello Permeable Reactive Barrier Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Cañon City, Colorado, Uranium

31

Iron (Fe)  

Science Conference Proceedings (OSTI)

Table 19   Linear thermal expansion of iron...Table 19 Linear thermal expansion of iron Temperature Change in length, % (a) Coefficient

32

Investigating the potential for long-term permeable reactive barrier (PRB) monitoring from the electrical signatures associated with the reduction in reactive iron performance  

SciTech Connect

The objective of this work was to conduct laboratory and field experiments to determine the sensitivity of low frequency electrical measurements (resistivity and induced polarization) to the processes of corrosion and precipitation that are believed to limit permeable reactive barrier (PRB) performance. The research was divided into four sets of experiments that were each written up and submitted to a peer-reviewed journal: [1] A laboratory experiment to define the controls of aqueous chemistry (electrolyte activity; pH; valence) and total zero valent iron (Fe0) available surface area on the electrical properties of Fe0 columns. [2] A laboratory experiment to determine the impact of corrosion and precipitation on the electrical response of synthetic Fe0 columns as a result of geochemical reactions with NaSO4 and NaCO3 electrolytes. [3] Laboratory experiments on a sequence of cores retrieved from the Kansas City PRB to determine the magnitude of electrical and geochemical changes within a field active PRB after eight years of operation [4] Field-scale cross borehole resistivity and induced polarization monitoring of the Kansas City PRB to evaluate the potential of electrical imaging as a technology for non-invasive, long-term monitoring of indicators of reduced PRB performance This report first summarizes the findings of the four major experiments conducted under this research. The reader is referred to the four papers in Appendices 1-4 for a full description of each experiment, including motivation and significance, technical details, findings and implications. The deliverables of the project, including the publications, conference papers and new collaborative arrangements that have resulted are then described. Appendices 5-6 contain two technical reports written by co-PI Korte describing (1) supporting geochemical measurements, and (2) the coring procedure, conducted at the Kansas City PRB as part of this project.

Slater, Lee D.; Korte, N.; Baker, J.

2005-12-14T23:59:59.000Z

33

Process for the synthesis of iron powder  

DOE Patents (OSTI)

A process for preparing iron powder suitable for use in preparing the iron-potassium perchlorate heat-powder fuel mixture used in thermal batteries, comprises preparing a homogeneous, dense iron oxide hydroxide precipitate by homogeneous precipitation from an aqueous mixture of a ferric salt, formic or sulfuric acid, ammonium hydroxide and urea as precipitating agent; and then reducing the dense iron oxide hydroxide by treatment with hydrogen to prepare the iron powder. 2 figs.

Welbon, W.W.

1983-11-08T23:59:59.000Z

34

Process for the synthesis of iron powder  

DOE Patents (OSTI)

A process for preparing iron powder suitable for use in preparing the iron-potassium perchlorate heat-powder fuel mixture used in thermal batteries, comprises preparing a homogeneous, dense iron oxide hydroxide precipitate by homogeneous precipitation from an aqueous mixture of a ferric salt, formic or sulfuric acid, ammonium hydroxide and urea as precipitating agent; and then reducing the dense iron oxide hydroxide by treatment with hydrogen to prepare the iron powder.

Not Available

1982-03-06T23:59:59.000Z

35

Process for the synthesis of iron powder  

DOE Patents (OSTI)

A process for preparing iron powder suitable for use in preparing the iron-potassium perchlorate heat-powder fuel mixture used in thermal batteries, comprises preparing a homogeneous, dense iron oxide hydroxide precipitate by homogeneous precipitation from an aqueous mixture of a ferric salt, formic or sulfuric acid, ammonium hydroxide and urea as precipitating agent; and then reducing the dense iron oxide hydroxide by treatment with hydrogen to prepare the iron powder.

Welbon, William W. (Belleair, FL)

1983-01-01T23:59:59.000Z

36

Microbial reduction of iron ore  

DOE Patents (OSTI)

A process is provided for reducing iron ore by treatment with microorganisms which comprises forming an aqueous mixture of iron ore, microorganisms operable for reducing the ferric iron of the iron ore to ferrous iron, and a substrate operable as an energy source for the microbial reduction; and maintaining the aqueous mixture for a period of time and under conditions operable to effect the reduction of the ore. Preferably the microorganism is Pseudomonas sp. 200 and the reduction conducted anaerobically with a domestic wastewater as the substrate. An aqueous solution containing soluble ferrous iron can be separated from the reacted mixture, treated with a base to precipitate ferrous hydroxide which can then be recovered as a concentrated slurry.

Hoffmann, Michael R. (Pasadena, CA); Arnold, Robert G. (Pasadena, CA); Stephanopoulos, Gregory (Pasadena, CA)

1989-01-01T23:59:59.000Z

37

Microbial reduction of iron ore  

DOE Patents (OSTI)

A process is provided for reducing iron ore by treatment with microorganisms which comprises forming an aqueous mixture of iron ore, microorganisms operable for reducing the ferric iron of the iron ore to ferrous iron, and a substrate operable as an energy source for the microbial reduction; and maintaining the aqueous mixture for a period of time and under conditions operable to effect the reduction of the ore. Preferably the microorganism is Pseudomonas sp. 200 and the reduction conducted anaerobically with a domestic wastewater as the substrate. An aqueous solution containing soluble ferrous iron can be separated from the reacted mixture, treated with a base to precipitate ferrous hydroxide which can then be recovered as a concentrated slurry. 11 figs.

Hoffmann, M.R.; Arnold, R.G.; Stephanopoulos, G.

1989-11-14T23:59:59.000Z

38

Advanced hydraulic fracturing methods to create in situ reactive barriers  

Science Conference Proceedings (OSTI)

This article describes the use of hydraulic fracturing to increase permeability in geologic formations where in-situ remedial action of contaminant plumes will be performed. Several in-situ treatment strategies are discussed including the use of hydraulic fracturing to create in situ redox zones for treatment of organics and inorganics. Hydraulic fracturing methods offer a mechanism for the in-situ treatment of gently dipping layers of reactive compounds. Specialized methods using real-time monitoring and a high-energy jet during fracturing allow the form of the fracture to be influenced, such as creation of assymmetric fractures beneath potential sources (i.e. tanks, pits, buildings) that should not be penetrated by boring. Some examples of field applications of this technique such as creating fractures filled with zero-valent iron to reductively dechlorinate halogenated hydrocarbons, and the use of granular activated carbon to adsorb compounds are discussed.

Murdoch, L. [FRX Inc., Cincinnati, OH (United States)]|[Clemson Univ., SC (United States). Dept. of Geological Sciences; Siegrist, B.; Meiggs, T. [Oak Ridge National Lab., TN (United States)] [and others

1997-12-31T23:59:59.000Z

39

Microsoft Word - Appendix G.doc  

Office of Legacy Management (LM)

1 are included in this appendix. 1 are included in this appendix. Appendix G, Page 1 RFLMA Contact Record 2011-01 1 of 5 ROCKY FLATS SITE REGULATORY CONTACT RECORD Purpose: Replace Mound Site Plume Treatment System (MSPTS) media and maintain/repair discharge gallery. Contact Record Approval Date: 1/14/11 Site Contact(s)/Affiliation(s): Scott Surovchak, U.S. Department of Energy (DOE); John Boylan, S.M. Stoller (Stoller); Rick DiSalvo, Stoller Regulatory Contact(s)/Affiliation(s): Carl Spreng, Colorado Department of Public Health and Environment (CDPHE); Vera Moritz, U.S. Environmental Protection Agency (EPA) Discussion: A routine maintenance activity to remove the MSPTS spent treatment media (zero valent iron [ZVI] filings) and replace it with new ZVI media is scheduled for January-February 2011. The last

40

Pilot testing of in situ chemical reduction to treat carbon tetrachloride  

NLE Websites -- All DOE Office Websites (Extended Search)

Pilot testing of in situ chemical reduction to treat carbon tetrachloride Pilot testing of in situ chemical reduction to treat carbon tetrachloride at a former grain storage facility in Missouri March 26, 2013 At a former grain storage facility in Missouri, EVS has initiated a pilot test of an innovative treatment using amended zero-valent iron to achieve in situ chemical reduction of carbon tetrachloride contamination. Carbon tetrachloride concentrations above regulatory levels in soil and groundwater (at 8-89 ft below ground level [BGL]) are confined to a small area of the former facility, on property that is now a county fairground. At present, the contamination poses no known risks to fairgrounds workers or visitors. The deep bedrock aquifers in the area are at minimal risk of contamination. The areas targeted for treatment in the pilot test are localized

Note: This page contains sample records for the topic "zero-valent iron treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Drinking Water Problems: Iron and Manganese  

E-Print Network (OSTI)

Iron and manganese can give water an unpleasant taste, odor and color. In this publication you'll learn how to know whether your water contains iron or manganese and how to eliminate these contaminants with various treatment methods such as aeration and chemical oxidation.

Dozier, Monty; McFarland, Mark L.

2004-02-20T23:59:59.000Z

42

Dispersion enhanced metal/zeolite catalysts  

DOE Patents (OSTI)

Dispersion stabilized zeolite supported metal catalysts are provided as bimetallic catalyst combinations. The catalyst metal is in a reduced zero valent form while the dispersion stabilizer metal is in an unreduced ionic form. Representative catalysts are prepared from platinum or nickel as the catalyst metal and iron or chromium dispersion stabilizer.

Sachtler, Wolfgang M. H. (Evanston, IL); Tzou, Ming-Shin (Evanston, IL); Jiang, Hui-Jong (Evanston, IL)

1987-01-01T23:59:59.000Z

43

Bioremediation of Uranium Plumes with Nano-scale  

E-Print Network (OSTI)

Bioremediation of Uranium Plumes with Nano-scale Zero-valent Iron Angela Athey Advisers: Dr. Reyes Undergraduate Student Fellowship Program April 15, 2011 #12;Main Sources of Uranium Natural · Leaching from(IV) (UO2[s], uraninite) Anthropogenic · Release of mill tailings during uranium mining - Mobilization

Cushing, Jim. M.

44

Iron and Prochlorococcus/  

E-Print Network (OSTI)

Iron availability and primary productivity in the oceans are intricately linked through photosynthesis. At the global scale we understand how iron addition induces phytoplankton blooms through meso-scale iron-addition ...

Thompson, Anne Williford

2009-01-01T23:59:59.000Z

45

Iron Absorption  

NLE Websites -- All DOE Office Websites (Extended Search)

Iron Absorption Iron Absorption Name: Mary Location: N/A Country: N/A Date: N/A Question: I wrote before to Steve and got a answer back. I would like more information. The cirmcustances were that I first had anaemia and then I went for a gastroscopy. The results of which were I had insufficient acid been produced in the stomach. I was told that acid was nessary for the absorbion of iron and it was because of this that I became anaemic. I was told to eat plently of red meat not too many vegetables. Is there any other information you can give me? Replies: It is very difficult to say for sure without seeing you chart and I am not your doctor. But it sounds to me like you are deficient in the vitamin B12. In your stomach you have 3 basic types of cells. One is called chief cells which secrete the precursor of the enzyme pepsin which begins the breakdown of protein. Another is called the parietal cells which secrete your stomach acid and a substance called intrinsic factor. Now-switch to your bone marrow which is where your red blood cells are made. In order for your red blood cells to mature in the bone marrow, vitamin B12 is necessary. B12 can only be obtained from animal food sources such as meat, milk and eggs. Unfortunately, B12 cannot be absorbed in the stomach without intrinsic factor. If there is sufficient B12 present in the diet, it can be stored in the liver. If you aren't eating enough animal sources your B12 will be taken from your liver until you run out. You could also be deficient in intrinsic factor. So while the outcome is anemia (not enough red blood cells) the problem could be from a few different things. Follow your doctor's recommendations and eat more sources of B12

46

Treatability study for removal of leachable mercury in crushed fluorescent lamps  

SciTech Connect

Nonserviceable fluorescent lamps removed from radiological control areas at the Oak Ridge Department of Energy facilities have been crushed and are currently managed as mixed waste (hazardous and radiologically contaminated). We present proposed treatment flowsheets and supporting treatability study data for conditioning this solid waste residue so that it can qualify for disposal in a sanitary landfill. Mercury in spent fluorescent lamps occurs primarily as condensate on high-surface-area phosphor material. It can be solubilized with excess oxidants (e.g., hypochlorite solution) and stabilized by complexation with halide ions. Soluble mercury in dechlorinated saline solution is effectively removed by cementation with zero-valent iron in the form of steel wool. In packed column dynamic flow testing, soluble mercury was reduced to mercury metal and insoluble calomel, loading > 1.2 g of mercury per grain of steel wool before an appreciable breakthrough of soluble mercury in the effluent.

Bostick, W.D.; Beck, D.E.; Bowser, K.T. [and others

1996-02-01T23:59:59.000Z

47

Conditions for making direct reduced iron, transition direct reduced iron and pig iron nuggets in a laboratory furnace - Temperature-time transformations  

Science Conference Proceedings (OSTI)

The pig iron nugget process is gaining in importance as an alternative to the traditional blast furnace. Throughout the process, self-reducing-fluxing dried greenballs composed of iron ore concentrate, reducing-carburizing agent (coal), flux (limestone) and binder (bentonite) are heat-treated. During the heat treatment, dried greenballs are first transformed into direct reduced iron (DRI), then to transition direct reduced iron (TDRI) and finally to pig iron nuggets. The furnace temperature and/or residence time and the corresponding levels of carburization, reduction and metallization dictate these transformations. This study involved the determination of threshold furnace temperatures and residence times for completion of all of the transformation reactions and pig iron nugget production. The experiments involved the heat treatment of self-reducing-fluxing dried greenballs at various furnace temperatures and residence times. The products of these heat treatments were identified by utilizing optical microscopy, apparent density and microhardness measurements.

Anameric, B.; Kawatra, S.K. [Michigan Technological University, Houghton, MI (United States). Dept. of Chemical Engineering

2007-02-15T23:59:59.000Z

48

ZIRCONIUM IRON DISPROPORTIONATION DURING ...  

Science Conference Proceedings (OSTI)

... These Zr3Fe and Zr2Fe button samples were made at LANL by arc melting stoichiometric amounts of zirconium and iron in an argon atmosphere. ...

2012-11-26T23:59:59.000Z

49

Mathematical Modeling for Developing Iron Bath Reactor with H2-C ...  

Science Conference Proceedings (OSTI)

After dispersion treatment with Control-Volume-Method, the whole model was ... Iron Removal from Titanium Ore Through Selective Chlorination and Its...

50

Cast Irons - Programmaster.org  

Science Conference Proceedings (OSTI)

Oct 20, 2011 ... Processing, Microstructure and Properties of Cast Irons and Cast and Forged Specialty Steels: Cast Irons Sponsored by: MS&T Organization

51

Microsoft Word - S02808.doc  

Office of Legacy Management (LM)

Sciences Laboratory Sciences Laboratory Environmental Sciences Laboratory Prepared for U.S. Department of Energy Grand Junction, Colorado Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable Reactive Barrier, Monticello, Utah November 2006 DOE-LM/1379-2006 ESL-RPT-2006-03 Work Performed nder DOE Contract No. for the U.S. Department of Energy Office of Legacy Management. by the S.M. Stoller Corporation u DE AC01 02GJ79491 - - Approved for public release; distribution is unlimited. This page intentionally left blank DOE-LM/1379-2006 ESL-RPT-2006-03 Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable Reactive Barrier, Monticello, Utah November 2006 Work Performed by S.M. Stoller Corporation under DOE Contract No. DE-AC01-02GJ79491

52

Microsoft Word - S02808.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Sciences Laboratory Sciences Laboratory Environmental Sciences Laboratory Prepared for U.S. Department of Energy Grand Junction, Colorado Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable Reactive Barrier, Monticello, Utah November 2006 DOE-LM/1379-2006 ESL-RPT-2006-03 Work Performed nder DOE Contract No. for the U.S. Department of Energy Office of Legacy Management. by the S.M. Stoller Corporation u DE AC01 02GJ79491 - - Approved for public release; distribution is unlimited. This page intentionally left blank DOE-LM/1379-2006 ESL-RPT-2006-03 Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable Reactive Barrier, Monticello, Utah November 2006 Work Performed by S.M. Stoller Corporation under DOE Contract No. DE-AC01-02GJ79491

53

iron and steel making  

Science Conference Proceedings (OSTI)

Gas-Solid Reaction Will Help Solid-Solid ReactionNovel Iron Ore Agglomerate Bearing Semi-Coal-Char (Keynote) [pp. 97-104] T. Usui, H. Konishi, and N.

54

Iron Pots and Kettles  

NLE Websites -- All DOE Office Websites (Extended Search)

Iron Pots and Kettles Iron Pots and Kettles Nature Bulletin No. 544-A November 16, 1974 Forest Preserve District of Cook County George W. Dunne, President Roland F. Eisenbeis, Supt. of Conservation IRON POTS AND KETTLES At Possum Trot Hill, on US 150 west of Danville, a huge iron kettle squats as a monument to what was once an important industry in Illinois. It is one of 80 used from 1824 to 1831 for boiling down brine from salt springs in that vicinity. Salt was a luxury then. About a bushel was produced from one kettleful (100 gallons) of brine and that was worth more than 100 bushels of oats. Those 80 monsters came from Kentucky where iron works had been established to make the utensils and implements desperately needed by pioneer families. About half of them had come up through the Cumberland Gap, on horseback, with only a rifle, an ax, a pot for cooking, some bedding and the clothes on their backs. Every family, in addition to a skillet or spider, and a Dutch oven, coveted a big kettle for making salt, soap, candles and maple syrup, butchering hogs, rendering lard, boiling clothes on wash day, and dyeing homespun material for garments.

55

It's Elemental - The Element Iron  

NLE Websites -- All DOE Office Websites (Extended Search)

Manganese Manganese Previous Element (Manganese) The Periodic Table of Elements Next Element (Cobalt) Cobalt The Element Iron [Click for Isotope Data] 26 Fe Iron 55.845 Atomic Number: 26 Atomic Weight: 55.845 Melting Point: 1811 K (1538°C or 2800°F) Boiling Point: 3134 K (2861°C or 5182°F) Density: 7.874 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 4 Group Number: 8 Group Name: none What's in a name? From the Anglo-Saxon word iron. Iron's chemical symbol comes from the Latin word for iron, ferrum. Say what? Iron is pronounced as EYE-ern. History and Uses: Archaeological evidence suggests that people have been using iron for at least 5000 years. Iron is the cheapest and one of the most abundant of all metals, comprising nearly 5.6% of the earth's crust and nearly all of the

56

EPRI BWR Iron Control Monitoring Final Report  

Science Conference Proceedings (OSTI)

This report summarizes the state of iron control in U.S. BWRs as of July 1999 and documents the implementation and performance status of new iron control technologies. Issues involving the relationship between iron control and radiation dose control, iron control with deep beds, iron control with filters, and iron addition are documented, and areas for future research are noted.

1999-09-16T23:59:59.000Z

57

In Situ Iron Oxide Emplacement for Groundwater Arsenic Remediation  

E-Print Network (OSTI)

Iron oxide-bearing minerals have long been recognized as an effective reactive media for arsenic-contaminated groundwater remediation. This research aimed to develop a technique that could facilitate in situ oxidative precipitation of Fe3+ in a soil (sand) media for generating a subsurface iron oxide-based reactive barrier that could immobilize arsenic (As) and other dissolved metals in groundwater. A simple in situ arsenic treatment process was successfully developed for treating contaminated rural groundwater using iron oxide-coated sand (IOCS). Using imbibition flow, the system facilitated the dispersive transport of ferrous iron (Fe2+) and oxidant solutions in porous sand to generate an overlaying blanket where the Fe2+ was oxidized and precipitated onto the surface as ferric oxide. The iron oxide (FeOx) emplacement process was significantly affected by (1) the initial surface area and surface-bound iron content of the sand, (2) the pH and solubility of the coating reagents, (3) the stability of the oxidant solution, and (4) the chemical injection schedule. In contrast to conventional excavate-and-fill treatment technologies, this technique could be used to in situ replace a fresh iron oxide blanket on the sand and rejuvenate its treatment capacity for additional arsenic removal. Several bench-scale experiments revealed that the resultant IOCS could treat arsenic-laden groundwater for extended periods of time before approaching its effective life cycle. The adsorption capacity for As(III) and As(V) was influenced by (1) the amount of iron oxide accumulated on the sand surface, (2) the system pH, and (3) competition for adsorption sites from other groundwater constituents such as silicon (Si) and total dissolved solids (TDS). Although the IOCS could be replenished several times before exhaustion, the life cycle of the FeOx reactive barrier may be limited by the gradual loss of hydraulic conductivity induced by the imminent reduction of pore space over time.

Abia, Thomas Sunday

2011-12-01T23:59:59.000Z

58

Arsenic Removal from Groundwater Using Iron Electrocoagulation: Effect of  

NLE Websites -- All DOE Office Websites (Extended Search)

Arsenic Removal from Groundwater Using Iron Electrocoagulation: Effect of Arsenic Removal from Groundwater Using Iron Electrocoagulation: Effect of Charge Dosage Rate Title Arsenic Removal from Groundwater Using Iron Electrocoagulation: Effect of Charge Dosage Rate Publication Type Journal Article Refereed Designation Refereed LBNL Report Number LBNL-6221E Year of Publication 2013 Authors Amrose, Susan, Ashok J. Gadgil, Venkat Srinivasan, Kristin Kowolik, Marc Muller, Jessica Huang, and Robert Kostecki Journal Joournal of Environmental Science and Health, Part A: Toxic/Hazardous Substances and Environmental Engineering Volume 48 Issue 9 Pagination 1019-1030 Date Published 04/2013 Keywords arsenic, bangladesh, Cambodia, dosage rate, electrocoagulation, india, water treatment Abstract We demonstrate that electrocoagulation (EC) using iron electrodes can reduce arsenic below 10 μg/L in synthetic Bangladesh groundwater and in real groundwater from Bangladesh and Cambodia while investigating the effect of operating parameters that are often overlooked, such as charge dosage rate. We measure arsenic removal performance

59

Iron pages of HTSC  

Science Conference Proceedings (OSTI)

Experimental data are presented on the superconducting and electronic properties of iron-based high-temperature superconductors in the normal and superconducting states. The following topics are discussed: lattice structure; structure of magnetic vortices; magnetic penetration depth; Fermi surface; isotope effect; and critical magnetic fields both in oxide compounds of 1111 type and oxide-free compounds of 122, 111, and 011 types as a function of the doping level, temperature, and external pressure.

Gasparov, V. A., E-mail: vgasparo@issp.ac.r [Russian Academy of Sciences, Institute of Solid State Physics (Russian Federation)

2010-08-15T23:59:59.000Z

60

Differential Characterization of Ikperejere Iron shale and Iron ...  

Science Conference Proceedings (OSTI)

Kaolinite was found in the iron shale. Trace elements were Mn, Mg, Ti, Ca, Na .... High Temperature Exposure of Oil Well Cements In-Situ EBSD Investigation of...

Note: This page contains sample records for the topic "zero-valent iron treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Enzymes of respiratory iron oxidation  

DOE Green Energy (OSTI)

This report describes experimental progress in characterizing and identifying redox proteins in a number of iron-oxidizing bacteria. Sections of the paper are entitled (1) In Situ electrolysis was explored to achieve enhanced yields of iron-oxidizing bacteria, (2)Structure/function studies were performed on redox-active biomolecules from Thiobacillus ferrooxidans, (3) Novel redox-active biomolecules were demonstrated in other iron autotrophs, and (4) New probes of metalloprotein electron-transfer reactions were synthesized and characterized.

Blake, R. II.

1992-01-01T23:59:59.000Z

62

Seal welded cast iron nuclear waste container  

SciTech Connect

This invention identifies methods and articles designed to circumvent metallurgical problems associated with hermetically closing an all cast iron nuclear waste package by welding. It involves welding nickel-carbon alloy inserts which are bonded to the mating plug and main body components of the package. The welding inserts might be bonded in place during casting of the package components. When the waste package closure weld is made, the most severe thermal effects of the process are restricted to the nickel-carbon insert material which is far better able to accommodate them than is cast iron. Use of nickel-carbon weld inserts should eliminate any need for pre-weld and post-weld heat treatments which are a problem to apply to nuclear waste packages. Although the waste package closure weld approach described results in a dissimilar metal combination, the relative surface area of nickel-to-iron, their electrochemical relationship, and the presence of graphite in both materials will act to prevent any galvanic corrosion problem.

Filippi, Arthur M. (Pittsburgh, PA); Sprecace, Richard P. (Murrysville, PA)

1987-01-01T23:59:59.000Z

63

Electron Correlation in Iron-Based Superconductors  

NLE Websites -- All DOE Office Websites (Extended Search)

Electron Correlation in Iron-Based Superconductors Print In 2008, the discovery of iron-based superconductors stimulated a worldwide burst of activity, leading to about two...

64

About The Iron and Steel Society  

Science Conference Proceedings (OSTI)

The IRON & STEEL SOCIETY (ISS) is a professional and technical society that provides opportunities for networking among iron and steel industry professionals...

65

Iron Recovery from Copper Slag through Oxidation-magnetic ...  

Science Conference Proceedings (OSTI)

Recovery of iron from the copper slag is very essential not only for recycling the valuable ... Characterization of High-arsenic Sludge in Copper Metallurgy Plant ... Characterization of Waste from Ornamental Stones for Use in Mortar ... Effect of Friction Stir Welding Speed and Post Weld Heat Treatment on the Microstructure

66

Verification of Steelmaking Slags Iron Content Final Technical Progress Report  

Science Conference Proceedings (OSTI)

The steel industry in the United States generates about 30 million tons of by-products each year, including 6 million tons of desulfurization and BOF/BOP slag. The recycling of BF (blast furnace) slag has made significant progress in past years with much of the material being utilized as construction aggregate and in cementitious applications. However, the recycling of desulfurization and BOF/BOP slags still faces many technical, economic, and environmental challenges. Previous efforts have focused on in-plant recycling of the by-products, achieving only limited success. As a result, large amounts of by-products of various qualities have been stockpiled at steel mills or disposed into landfills. After more than 50 years of stockpiling and landfilling, available mill site space has diminished and environmental constraints have increased. The prospect of conventionally landfilling of the material is a high cost option, a waste of true national resources, and an eternal material liability issue. The research effort has demonstrated that major inroads have been made in establishing the viability of recycling and reuse of the steelmaking slags. The research identified key components in the slags, developed technologies to separate the iron units and produce marketable products from the separation processes. Three products are generated from the technology developed in this research, including a high grade iron product containing about 90%Fe, a medium grade iron product containing about 60% Fe, and a low grade iron product containing less than 10% Fe. The high grade iron product contains primarily metallic iron and can be marketed as a replacement of pig iron or DRI (Direct Reduced Iron) for steel mills. The medium grade iron product contains both iron oxide and metallic iron and can be utilized as a substitute for the iron ore in the blast furnace. The low grade iron product is rich in calcium, magnesium and iron oxides and silicates. It has a sufficient lime value and can be utilized for acid mine drainage treatment. Economic analysis from this research demonstrates that the results are favorable. The strong demand and the increase of price of the DRI and pig iron in recent years are particularly beneficial to the economics. The favorable economics has brought commercial interests. ICAN Global has obtained license agreement on the technology from Michigan Tech. This right was later transferred to the Westwood Land, Inc. A demonstration pilot plant is under construction to evaluate the technology. Steel industry will benefit from the new supply of the iron units once the commercial plants are constructed. Environmental benefits to the public and the steel industry will be tremendous. Not only the old piles of the slag will be removed, but also the federal responsible abandoned mines from the old mining activities can be remediated with the favorable product generated from the process. Cost can be reduced and there will be no lime required, which can avoid the release of carbon dioxide from lime production process.

J.Y. Hwang

2006-10-04T23:59:59.000Z

67

Iron Mountain Electromagnetic Results  

SciTech Connect

Iron Mountain Mine is located seventeen miles northwest of Redding, CA. After the completion of mining in early 1960s, the mine workings have been exposed to environmental elements which have resulted in degradation in water quality in the surrounding water sheds. In 1985, the EPA plugged ore stoops in many of the accessible mine drifts in an attempt to restrict water flow through the mine workings. During this process little data was gathered on the orientation of the stoops and construction of the plugs. During the last 25 years, plugs have begun to deteriorate and allow acidic waters from the upper workings to flow out of the mine. A team from Idaho National Laboratory (INL) performed geophysical surveys on a single mine drift and 3 concrete plugs. The project goal was to evaluate several geophysical methods to determine competence of the concrete plugs and orientation of the stopes.

Gail Heath

2012-07-01T23:59:59.000Z

68

Visualization at Supercomputing Centers: The Tale of Little Big Iron and the Three Skinny Guys  

SciTech Connect

Supercomputing centers are unique resources that aim to enable scientific knowledge discovery by employing large computational resources - the 'Big Iron.' Design, acquisition, installation, and management of the Big Iron are carefully planned and monitored. Because these Big Iron systems produce a tsunami of data, it's natural to colocate the visualization and analysis infrastructure. This infrastructure consists of hardware (Little Iron) and staff (Skinny Guys). Our collective experience suggests that design, acquisition, installation, and management of the Little Iron and Skinny Guys doesn't receive the same level of treatment as that of the Big Iron. This article explores the following questions about the Little Iron: How should we size the Little Iron to adequately support visualization and analysis of data coming off the Big Iron? What sort of capabilities must it have? Related questions concern the size of visualization support staff: How big should a visualization program be - that is, how many Skinny Guys should it have? What should the staff do? How much of the visualization should be provided as a support service, and how much should applications scientists be expected to do on their own?

Bethel, E Wes [Lawrence Berkeley National Laboratory (LBNL); Brugger, Eric [Lawrence Livermore National Laboratory (LLNL)

2011-01-01T23:59:59.000Z

69

Mechanisms of Iron and Slag Separation in Carbon Composite Iron ...  

Science Conference Proceedings (OSTI)

Chemical Enrichment of Precious Metals in Iron Sulfides Using Microwave Energy Chloridizing ... Co-Gasification Behavior of Metallurgical Coke with High and Low Reactivity .... Thermal Plasma Torches for Metallurgical Applications.

70

Iron Edison Battery Company | Open Energy Information  

Open Energy Info (EERE)

Iron Edison Battery Company Iron Edison Battery Company Jump to: navigation, search Logo: Iron Edison Battery Company Name Iron Edison Battery Company Place Lakewood, Colorado Sector Bioenergy, Carbon, Efficiency, Hydro, Renewable Energy, Solar, Wind energy Product Nickel Iron (Ni-Fe) battery systems Year founded 2011 Number of employees 1-10 Phone number 202-681-4766 Website http://ironedison.com Region Rockies Area References Iron Edison Battery Company[1] Nickel Iron Battery Specifications[2] About the company and the owners[3] Nickel Iron Battery Association[4] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Iron Edison Battery Company is a company based in Lakewood, Colorado. Iron Edison is redefining off-grid energy storage using advanced

71

Energy in Iron and Steel  

Science Conference Proceedings (OSTI)

Energy Technologies and Carbon Dioxide Management: Energy in Iron and Steel ... today imposed by energy, raw materials supply and over supply in the market. ... Through the studies of CCT, TTT and X-ray analysis, it has been successfully...

72

Iron catalyzed coal liquefaction process  

DOE Patents (OSTI)

A process is described for the solvent refining of coal into a gas product, a liquid product and a normally solid dissolved product. Particulate coal and a unique co-catalyst system are suspended in a coal solvent and processed in a coal liquefaction reactor, preferably an ebullated bed reactor. The co-catalyst system comprises a combination of a stoichiometric excess of iron oxide and pyrite which reduce predominantly to active iron sulfide catalysts in the reaction zone. This catalyst system results in increased catalytic activity with attendant improved coal conversion and enhanced oil product distribution as well as reduced sulfide effluent. Iron oxide is used in a stoichiometric excess of that required to react with sulfur indigenous to the feed coal and that produced during reduction of the pyrite catalyst to iron sulfide.

Garg, Diwakar (Macungie, PA); Givens, Edwin N. (Bethlehem, PA)

1983-01-01T23:59:59.000Z

73

Argonne CNM News: Hollow Iron Oxide Nanoparticles for Lithium...  

NLE Websites -- All DOE Office Websites (Extended Search)

Hollow Iron Oxide Nanoparticles for Lithium-Ion Battery Applications Hollow iron oxide nanoparticles Transmission electron micrograph of hollow iron oxide nanoparticles....

74

Pilot-Scale Demonstration of hZVI Process for Treating Flue Gas Desulfurization Wastewater at Plant Wansley, Carrollton, GA  

E-Print Network (OSTI)

The hybrid Zero Valent Iron (hZVI) process is a novel chemical treatment platform that has shown great potential in our previous bench-scale tests for removing selenium, mercury and other pollutants from Flue Gas Desulfurization (FGD) wastewater. This integrated treatment system employs new iron chemistry to create highly reactive mixture of Fe^0, iron oxides (FeOx) and various forms of Fe (II) for the chemical transformation and mineralization of various heavy metals in water. To further evaluate and develop the hZVI technology, a pilot-scale demonstration had been conducted to continuously treat 1-2 gpm of the FGD wastewater for five months at Plant Wansley, a coal-fired power plant of Georgia Power. This demonstrated that the scaled-up system was capable of reducing the total selenium (of which most was selenate) in the FGD wastewater from over 2500 ppb to below 10 ppb and total mercury from over 100 ppb to below 0.01 ppb. This hZVI system reduced other toxic metals like Arsenic (III and V), Chromium (VI), Cadmium (II), Lead (II) and Copper (II) from ppm level to ppb level in a very short reaction time. The chemical consumption was estimated to be approximately 0.2-0.4 kg of ZVI per 1 m^3 of FGD water treated, which suggested the process economics could be very competitive. The success of the pilot test shows that the system is scalable for commercial application. The operational experience and knowledge gained from this field test could provide guidance to further improvement of technology for full scale applications. The hZVI technology can be commercialized to provide a cost-effective and reliable solution to the FGD wastewater and other metal-contaminated waste streams in various industries. This technology has the potential to help industries meet the most stringent environmental regulations for heavy metals and nutrients in wastewater treatment.

Peddi, Phani 1987-

2011-12-01T23:59:59.000Z

75

Iron/Iron Oxide Core/Shell Nanoparticles for MRI and Magnetic ...  

Science Conference Proceedings (OSTI)

Bulk Nanoceramics and Nanocomposites: Processed by Pulsed Electric Current ... Iron/Iron Oxide Core/Shell Nanoparticles for MRI and Magnetic Hyperthermia.

76

Visualization at Supercomputing Centers: The Tale of Little Big Iron and the Three Skinny Guys  

SciTech Connect

Supercomputing Centers (SC's) are unique resources that aim to enable scientific knowledge discovery through the use of large computational resources, the Big Iron. Design, acquisition, installation, and management of the Big Iron are activities that are carefully planned and monitored. Since these Big Iron systems produce a tsunami of data, it is natural to co-locate visualization and analysis infrastructure as part of the same facility. This infrastructure consists of hardware (Little Iron) and staff (Skinny Guys). Our collective experience suggests that design, acquisition, installation, and management of the Little Iron and Skinny Guys does not receive the same level of treatment as that of the Big Iron. The main focus of this article is to explore different aspects of planning, designing, fielding, and maintaining the visualization and analysis infrastructure at supercomputing centers. Some of the questions we explore in this article include:"How should the Little Iron be sized to adequately support visualization and analysis of data coming off the Big Iron?" What sort of capabilities does it need to have?" Related questions concern the size of visualization support staff:"How big should a visualization program be (number of persons) and what should the staff do?" and"How much of the visualization should be provided as a support service, and how much should applications scientists be expected to do on their own?"

Bethel, E. Wes; van Rosendale, John; Southard, Dale; Gaither, Kelly; Childs, Hank; Brugger, Eric; Ahern, Sean

2010-12-01T23:59:59.000Z

77

Cryogenic Treatment of Metal Parts  

SciTech Connect

Cryogenic treatment and its variables have been described. Results of eight engineering tests carried out on cryotreated parts have been presented. Cryogenic treatment of metal parts enhances useful properties which in turn, improves various strengths. Our tests viz. Abrasion, Torsion, Fatigue, Tensile, Shear, Hardness and Impact on Mild steel, Cast Iron, Brass and Copper show that the cryogenic treatment improved useful properties of mild steel parts appreciably but did not show promise with brass and copper parts.

Chillar, Rahul [S. P. College of Engineering, Andheri (W), Mumbai - 400 058 (India); Agrawal, S. C. [Tata Institute of Fundamental Research, Colaba, Mumbai - 400 005 (India)

2006-03-31T23:59:59.000Z

78

Direct Biohydrometallurgical Extraction of Iron from Ore  

Science Conference Proceedings (OSTI)

A completely novel approach to iron extraction was investigated, based on reductive leaching of iron by anaerobic bacteria. Microorganisms were collected from an anaerobic bog where natural seepage of dissolved iron was observed. This mixed culture was used to reduce insoluble iron in a magnetite ore to the soluble ferrous (Fe{sup +2}) state. While dissolution rates were slow, concentrations of dissolved iron as high as 3487 mg/l could be reached if sufficient time was allowed. A factorial study of the effects of trace nutrients and different forms of organic matter indicated that the best dissolution rates and highest dissolved iron concentrations were achieved using soluble carbohydrate (sucrose) as the bacterial food source, and that nutrients other than nitrogen, phosphorus, potassium, sodium, and acetate were not necessary. A key factor in reaching high levels of dissolved iron was maintaining a high level of carbon dioxide in solution, since the solubility of iron carbonates increases markedly as the quantity of dissolved carbon dioxide increases. Once the iron is dissolved, it has been demonstrated that the ferrous iron can then be electroplated from solution, provided that the concentration of iron is sufficiently high and the hydrogen ion concentration is sufficiently low. However, if the leaching solution is electrolyzed directly, organic matter precipitates at the cathode along with the metallic iron. To prevent this problem, the ferrous iron should be separated from the bulk solution in a more concentrated, purified form. One route to accomplishing this is to take advantage of the change in solubility of ferrous iron as a function of carbon dioxide concentration. By cycling the concentration of carbon dioxide in solution, it is possible to produce an iron-rich concentrate that should be suitable for electrolysis. This represents the first viable hydrometallurgical method for leaching iron directly from ore and producing metallic iron.

T.C. Eisele

2005-10-01T23:59:59.000Z

79

Microsoft Word - IronCore  

NLE Websites -- All DOE Office Websites (Extended Search)

November/December 2013 November/December 2013 Percolation Explains How Earth's Iron Core Formed The formation of Earth's metallic core, which makes up a third of our planet's mass, represents the most significant differentiation event in Earth's history. Earth's present layered structure with a metallic core and an overlying silicate mantle would have required mechanisms to separate iron alloy from a silicate phase. Percolation of liquid iron alloy moving through a solid silicate matrix (much as water percolates through porous rock, or even coffee grinds) has been proposed as a possible model for core formation (Figure 1). Many previous experimental results have ruled out percolation as a major core formation mechanism for Earth at the relatively lower pressure conditions in the upper mantle, but

80

Effects of Iron and Manganese Ions on Potentiostatic Current ...  

Science Conference Proceedings (OSTI)

Differential Characterization of Ikperejere Iron shale and Iron Sandstone Deposit Direct Precipitation of ... High Temperature Exposure of Oil Well Cements.

Note: This page contains sample records for the topic "zero-valent iron treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

About The Associate for Iron and Steel Technology - TMS  

Science Conference Proceedings (OSTI)

ABOUT THE ASSOCIATION FOR IRON & STEEL TECHNOLOGY ... that provides opportunities for networking among iron and steel industry professionals and...

82

Iron Availability in the Southern Ocean  

NLE Websites -- All DOE Office Websites (Extended Search)

Iron Availability in the Southern Ocean Iron Availability in the Southern Ocean Print Friday, 21 June 2013 10:08 The Southern Ocean, circling the Earth between Antarctica and the...

83

Classes and Grades of Ductile Iron  

Science Conference Proceedings (OSTI)

Table 1   Ductile iron properties of various industry and international standards...Table 1 Ductile iron properties of various industry and international standards Grade Tensile strength 0.2% offset yield

84

Magnetism Governs Properties of Iron-Based ...  

Science Conference Proceedings (OSTI)

... a group of materials that conduct electricity without resistance at ... theoretical evidence demonstrating how magnetism controls basic aspects of iron ...

2011-04-06T23:59:59.000Z

85

Lithium Iron Phosphate Composites for Lithium Batteries  

The materials can be added at low cost without changing current scalable cathode ... Lithium Iron Phosphate Composites for Lithium Batteries ...

86

Terahertz Properties of Lithium Iron Phosphate Glasses  

Science Conference Proceedings (OSTI)

Presentation Title, Terahertz Properties of Lithium Iron Phosphate Glasses ... Field Assisted Viscous Flow and Crystallization in a Sodium Aluminosilicate Glass.

87

Ligand iron catalysts for selective hydrogenation  

SciTech Connect

Disclosed are iron ligand catalysts for selective hydrogenation of aldehydes, ketones and imines. A catalyst such as dicarbonyl iron hydride hydroxycyclopentadiene) complex uses the OH on the five member ring and hydrogen linked to the iron to facilitate hydrogenation reactions, particularly in the presence of hydrogen gas.

Casey, Charles P. (Madison, WI); Guan, Hairong (Cincinnati, OH)

2010-11-16T23:59:59.000Z

88

Influence of Iron Redox Transformations on Plutonium Sorption to Sediments  

SciTech Connect

Plutonium subsurface mobility is primarily controlled by its oxidation state, which in turn is loosely coupled to the oxidation state of iron in the system. Experiments were conducted to examine the effect of sediment iron mineral composition and oxidation state on plutonium sorption and oxidation state. A pH 6.3 vadose zone sediment containing iron oxides and iron-containing phyllosilicates was treated with various complexants (ammonium oxalate) and reductants (dithionite-citrate-bicarbonate) to selectively leach and/or reduce iron oxide and phyllosilicate phases. Mssbauer spectroscopy was used to identify initial iron mineral composition of the sediment and monitor dissolution and reduction of iron oxides. Sorption of Pu(V) was monitored over one week for each of six treated sediment fractions. Plutonium oxidation state speciation in the aqueous and solid phases was monitored using solvent extraction, coprecipitation, and XANES. Mssbauer spectroscopy showed that the sediment contained 25-30% hematite, 60-65% Al-goethite, and <10%Fe(III) in phyllosilicate; there was no detectable Fe(II). Upon reduction with a strong chemical reductant (dithionite-citrate buffer, DCB), much of the hematite and goethite disappeared and the Fe in the phyllosilicate reduced to Fe(II). The rate of sorption was found to correlate with the 1 fraction of Fe(II) remaining within each treated sediment phase. Pu(V) was the only oxidation state measured in the aqueous phase, irrespective of treatment, whereas Pu(IV) and much smaller amounts of Pu(V) and Pu(VI) were measured in the solid phase. Surface-mediated reduction of Pu(V) to Pu(IV) occurred in treated and untreated sediment samples; Pu(V) remained on untreated sediment surface for two days before reducing to Pu(IV). Similar to the sorption kinetics, the reduction rate was correlated with sediment Fe(II) concentration. The correlation between Fe(II) concentrations and Pu(V) reduction demonstrates the potential impact of changing iron mineralogy on plutonium subsurface transport through redox transition areas. These findings should influence the conceptual models of long-term stewardship of Pu contaminated sites that have fluctuating redox conditions, such as vadose zones or riparian zones.

Hixon, Amy E.; Hu, Yung-Jin; Kaplan, Daniel I.; Kukkadapu, Ravi K.; Nitsche, Heino; Qafoku, Odeta; Powell, Brian A.

2010-10-01T23:59:59.000Z

89

Microsoft Word - S01394_PRB_ZVI.DOC  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

GJ719-2004 GJ719-2004 ESL-RPT-2004-06 Performance of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site September 2004 Prepared by Environmental Sciences Laboratory U.S. Department of Energy Grand Junction, Colorado This page intentionally blank Signature Page Document Number S0139400 PRB Using Granular ZVI-2004 Annual Report U.S. Department of Energy Page iv September 2004 End of current text Document Number S0139400 Contents U.S. Department of Energy PRB Using Granular ZVI-2004 Annual Report September 2004 Page v Contents Signature Page ...............................................................................................................................

90

Water Quality Criteria Development for Iron  

Science Conference Proceedings (OSTI)

The current national water quality criterion for iron a criterion continuous concentration of 1 mg Fe/L was derived 25 years ago. Such ambient water quality criteria are typically derived from toxicity tests in which the reagent grade chemical is dissolved in clean laboratory water. However, due to the complexity of iron speciation in freshwater, adverse effects of iron precipitates on habitat quality, and access of organisms to food, standard toxicity assays may not adequately assess the...

2004-12-27T23:59:59.000Z

91

Bioavailability of Iron, Zinc, Phytate and Phytase Activity during Soaking and Germination of White Sorghum Varieties  

E-Print Network (OSTI)

The changes in phytate, phytase activity and in vitro bioavailability of iron and zinc during soaking and germination of three white sorghum varieties (Sorghum bicolor L. Moench), named Dorado, Shandweel-6, and Giza-15 were investigated. Sorghum varieties were soaked for 20 h and germinated for 72 h after soaking for 20 h to reduce phytate content and increase iron and zinc in vitro bioavailability. The results revealed that iron and zinc content was significantly reduced from 28.16 to 32.16 % and 13.78 to 26.69 % for soaking treatment and 38.43 to 39.18 % and 21.80 to 31.27 % for germination treatments, respectively. Phytate content was significantly reduced from 23.59 to 32.40 % for soaking treatment and 24.92 to 35.27 % for germination treatments, respectively. Phytase enzymes will be activated during drying in equal form in all varieties. The results proved that the main distinct point is the change of phytase activity as well as specific activity during different treatment which showed no significant differences between the varieties used. The in vitro bioavailability of iron

Abd El-moneim M. R. Afify; Hossam S. El-beltagi; Samiha M. Abd El-salam; Azza A. Omran

2010-01-01T23:59:59.000Z

92

Lithium Insertion Chemistry of Some Iron Vanadates  

E-Print Network (OSTI)

in A. Nazri, G.Pistoia (Eds. ), Lithium batteries, Science &structure materials in lithium cells, for a lower limitLithium Insertion Chemistry of Some Iron Vanadates Sbastien

Patoux, Sebastien; Richardson, Thomas J.

2008-01-01T23:59:59.000Z

93

Iron Availability in the Southern Ocean  

NLE Websites -- All DOE Office Websites (Extended Search)

Iron Availability in the Southern Ocean Print The Southern Ocean, circling the Earth between Antarctica and the southernmost regions of Africa, South America, and Australia, is...

94

Crystal Structure of Iron-dependent Halogenase  

NLE Websites -- All DOE Office Websites (Extended Search)

Iron (brown) is coordinated by two histidines, a-ketoglutarate (grey sticks), water (cyan), and chloride (green). The structural analysis revealed a novel coordination...

95

Iron Control in Zinc Pressure Leach Processes  

Science Conference Proceedings (OSTI)

Consequently, the disposal of iron residues is an integral part of the design and operation of zinc refineries. Zinc has been recovered from sulfide concentrates...

96

Method for producing iron-based catalysts  

DOE Patents (OSTI)

A method for preparing an acid catalyst having a long shelf-life is provided comprising doping crystalline iron oxides with lattice-compatible metals and heating the now-doped oxide with halogen compounds at elevated temperatures. The invention also provides for a catalyst comprising an iron oxide particle having a predetermined lattice structure, one or more metal dopants for said iron oxide, said dopants having an ionic radius compatible with said lattice structure; and a halogen bound with the iron and the metal dopants on the surface of the particle.

Farcasiu, Malvina (Pittsburgh, PA); Kaufman, Phillip B. (Library, PA); Diehl, J. Rodney (Pittsburgh, PA); Kathrein, Hendrik (McMurray, PA)

1999-01-01T23:59:59.000Z

97

Cycling Degradation of Lithium Iron Phosphate Cells  

Science Conference Proceedings (OSTI)

Abstract Scope, Significant improvement of electronic conductivity of lithium iron ... commercialization in many applications especially in plug-in electric vehicles.

98

Carbon Emissions: Iron and Steel Industry  

U.S. Energy Information Administration (EIA)

Energy-Related Carbon Emissions for Selected Iron and Steel Industries, 1994. Besides steel mills and blast furnaces, the primary metals industry also ...

99

Evaluation and Treatment of Iron Deficiency Anemia: A Gastroenterological Perspective  

E-Print Network (OSTI)

2008;23: 4. Rockey DC. Occult gastrointestinal bleeding.Summary and Conclusions Occult GI bleeding remains the mostVL. Hemoccult detection of fecal occult blood quantitated by

Zhu, Amy; Kaneshiro, Marc; Kaunitz, Jonathan D.

2010-01-01T23:59:59.000Z

100

Acid Mine Drainage Treatment by Electrodialysis after Iron Removal  

Science Conference Proceedings (OSTI)

... followed by neutralization of the precipitation in the form of metal hydroxides. ... by precipitation as hydroxide, followed by a microfiltration and subsequently...

Note: This page contains sample records for the topic "zero-valent iron treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Iron mobilization in North African dust.  

SciTech Connect

Iron is an essential nutrient for phytoplankton. Although iron-containing dust mobilized from arid regions supplies the majority of the iron to the oceans, the key flux in terms of the biogeochemical response to atmospheric deposition is the amount of soluble or bioavailable iron. Atmospheric processing of mineral aerosols by anthropogenic pollutants (e.g. sulfuric acid) may transform insoluble iron into soluble forms. Previous studies have suggested higher iron solubility in smaller particles, as they are subject to more thorough atmospheric processing due to a longer residence time than coarse particles. On the other hand, the specific mineralogy of iron in dust may also influence the particulate iron solubility in size. Compared to mineral dust aerosols, iron from combustion sources could be more soluble, and found more frequently in smaller particles. Internal mixing of alkaline dust with iron-containing minerals could significantly reduce iron dissolution in large dust aerosols due to the buffering effect, which may, in contrast, yield higher solubility in smaller particles externally mixed with alkaline dust (Ito and Feng, 2010). Here, we extend the modeling study of Ito and Feng (2010) to investigate atmospheric processing of mineral aerosols from African dust. In contrast to Asian dust, we used a slower dissolution rate for African dust in the fine mode. We compare simulated fractional iron solubility with observations. The inclusion of alkaline compounds in aqueous chemistry substantially limits the iron dissolution during long-range transport to the Atlantic Ocean: only a small fraction of iron (<0.2%) dissolves from illite in coarsemode dust aerosols with 0.45% soluble iron initially. In contrast, a significant fraction (1-1.5%) dissolves in fine-mode dust aerosols due to the acid mobilization of the iron-containing minerals externally mixed with carbonate minerals. Consequently, the model generally reproduces higher iron solubility in smaller particles as suggested by measurements over the Atlantic Ocean. Our results imply that the dissolution of iron in African dust is generally slower than that in Asian dust. Conventionally, dust is assumed as the major supply of bioavailable iron with a constant solubility at 1-2% to the remote ocean. Therefore, the timing and location of the atmospheric iron input to the ocean with detailed modeling of atmospheric processing could be different from those previously assumed. Past and future changes in aerosol supply of bioavailable iron might play a greater role in the nutrient supply for phytoplankton production in the upper ocean, as global warming has been predicted to intensify stratification and reduce vertical mixing from the deep ocean. Thus the feedback of climate change through ocean uptake of carbon dioxide as well as via aerosol-cloud interaction might be modified by the inclusion of iron chemistry in the atmosphere.

Ito, A.; Feng, Y. (Environmental Science Division); (Research Inst. for Global Change)

2011-01-01T23:59:59.000Z

102

Possible Processing of High Phosphorous Libyan Iron Ores  

Science Conference Proceedings (OSTI)

Abstract Scope, Libyan Iron ores reserve > 5.0 billion tons, with 48-55% Fe& 1.0 % P& Libyan Previous ... Differential Characterization of Ikperejere Iron shale and Iron Sandstone Deposit ... High Temperature Exposure of Oil Well Cements.

103

Fundamental Research on the Characteristics of Sierra Leone Iron ...  

Science Conference Proceedings (OSTI)

Differential Characterization of Ikperejere Iron shale and Iron Sandstone Deposit Direct Precipitation of Sr-doped LaP3O9 Thin Film Electrolytes for...

104

Reconstruction of Gene Networks of Iron Response in Shewanella oneidensis  

Science Conference Proceedings (OSTI)

It is of great interest to study the iron response of the -proteobacterium Shewanella oneidensis since it possesses a high content of iron and is capable of utilizing iron for anaerobic respiration. We report here that the iron response in S. oneidensis is a rapid process. To gain more insights into the bacterial response to iron, temporal gene expression profiles were examined for iron depletion and repletion, resulting in identification of iron-responsive biological pathways in a gene co-expression network. Iron acquisition systems, including genes unique to S. oneidensis, were rapidly and strongly induced by iron depletion, and repressed by iron repletion. Some were required for iron depletion, as exemplified by the mutational analysis of the putative siderophore biosynthesis protein SO3032. Unexpectedly, a number of genes related to anaerobic energy metabolism were repressed by iron depletion and induced by repletion, which might be due to the iron storage potential of their protein products. Other iron-responsive biological pathways include protein degradation, aerobic energy metabolism and protein synthesis. Furthermore, sequence motifs enriched in gene clusters as well as their corresponding DNA-binding proteins (Fur, CRP and RpoH) were identified, resulting in a regulatory network of iron response in S. oneidensis. Together, this work provides an overview of iron response and reveals novel features in S. oneidensis, including Shewanella-specific iron acquisition systems, and suggests the intimate relationship between anaerobic energy metabolism and iron response.

Yang, Yunfeng [ORNL; Harris, Daniel P [ORNL; Luo, Feng [Clemson University; Joachimiak, Marcin [Clemson University; Wu, Liyou [University of Oklahoma; Dehal, Paramvir [Lawrence Berkeley National Laboratory (LBNL); Jacobsen, Janet [Lawrence Berkeley National Laboratory (LBNL); Yang, Zamin Koo [ORNL; Gao, Haichun [University of Oklahoma; Arkin, Adam [Lawrence Berkeley National Laboratory (LBNL); Palumbo, Anthony Vito [ORNL; Zhou, Jizhong [University of Oklahoma

2009-01-01T23:59:59.000Z

105

Processing, Microstructure and Properties of Cast Irons and Cast ...  

Science Conference Proceedings (OSTI)

... Process Design of the Ductile Cast Iron Cylinder Head for Marine Diesel Engine ... Heavy Section Ductile Iron Castings for Use in Wind Turbine Generators.

106

FischerTropsch Synthesis: Characterization Rb Promoted Iron ...  

Science Conference Proceedings (OSTI)

Nov 1, 2007 ... Abstract Rubidium promoted iron FischerTropsch synthesis (FTS) ... Keywords FischerTropsch synthesis Iron catalyst . Rubidium Active...

107

Arsenic Remediation of Bangladesh Drinking Water using Iron-oxide...  

NLE Websites -- All DOE Office Websites (Extended Search)

Arsenic Remediation of Bangladesh Drinking Water using Iron-oxide Coated Coal Ash Title Arsenic Remediation of Bangladesh Drinking Water using Iron-oxide Coated Coal Ash...

108

Pages that link to "Iron Edison Battery Company" | Open Energy...  

Open Energy Info (EERE)

Share this page on Facebook icon Twitter icon Pages that link to "Iron Edison Battery Company" Iron Edison Battery Company Jump to: navigation, search What links here...

109

Changes related to "Iron Edison Battery Company" | Open Energy...  

Open Energy Info (EERE)

Share this page on Facebook icon Twitter icon Changes related to "Iron Edison Battery Company" Iron Edison Battery Company Jump to: navigation, search This is a list...

110

Iron catalysis in oxidation by ozone - Energy Innovation Portal  

Bookmark Iron catalysis in oxidation by ozone - Energy Innovation Portal on Google; Bookmark Iron catalysis in oxidation by ozone - Energy Innovation ...

111

Climate VISION: Private Sector Initiatives: Iron and Steel: Resources...  

Office of Scientific and Technical Information (OSTI)

Industry Associations American Iron and Steel Institute For over a century, North American steel producers have worked as partners and members of the American Iron and Steel...

112

Preparations of rare earth-iron alloys by thermite reduction  

DOE Patents (OSTI)

An improved method for the preparation of high-purity rare earth-iron alloys by the aluminothermic reduction of a mixture of rare earth and iron fluorides.

Schmidt, Frederick A. (Ames, IA); Peterson, David T. (Ames, IA); Wheelock, John T. (Nevada, IA)

1986-09-16T23:59:59.000Z

113

IRON COATED URANIUM AND ITS PRODUCTION  

DOE Patents (OSTI)

A method of applying a protective coating to a metallic uranium article is given. The method comprises etching the surface of the article with an etchant solution containlng chloride ions, such as a solution of phosphoric acid and hydrochloric acid, cleaning the etched surface, electroplating iron thereon from a ferrous ammonium sulfate electroplating bath, and soldering an aluminum sheath to the resultant iron layer.

Gray, A.G.

1960-03-15T23:59:59.000Z

114

Production of iron from metallurgical waste  

DOE Patents (OSTI)

A method of recovering metallic iron from iron-bearing metallurgical waste in steelmaking comprising steps of providing an iron-bearing metallurgical waste containing more than 55% by weight FeO and FeO equivalent and a particle size of at least 80% less than 10 mesh, mixing the iron-bearing metallurgical waste with a carbonaceous material to form a reducible mixture where the carbonaceous material is between 80 and 110% of the stoichiometric amount needed to reduce the iron-bearing waste to metallic iron, and as needed additions to provide a silica content between 0.8 and 8% by weight and a ratio of CaO/SiO.sub.2 between 1.4 and 1.8, forming agglomerates of the reducible mixture over a hearth material layer to protect the hearth, heating the agglomerates to a higher temperature above the melting point of iron to form nodules of metallic iron and slag material from the agglomerates by melting.

Hendrickson, David W; Iwasaki, Iwao

2013-09-17T23:59:59.000Z

115

THE SOLAR FLARE IRON ABUNDANCE  

SciTech Connect

The abundance of iron is measured from emission line complexes at 6.65 keV (Fe line) and 8 keV (Fe/Ni line) in RHESSI X-ray spectra during solar flares. Spectra during long-duration flares with steady declines were selected, with an isothermal assumption and improved data analysis methods over previous work. Two spectral fitting models give comparable results, viz., an iron abundance that is lower than previous coronal values but higher than photospheric values. In the preferred method, the estimated Fe abundance is A(Fe) = 7.91 {+-} 0.10 (on a logarithmic scale, with A(H) = 12) or 2.6 {+-} 0.6 times the photospheric Fe abundance. Our estimate is based on a detailed analysis of 1898 spectra taken during 20 flares. No variation from flare to flare is indicated. This argues for a fractionation mechanism similar to quiet-Sun plasma. The new value of A(Fe) has important implications for radiation loss curves, which are estimated.

Phillips, K. J. H. [Mullard Space Science Laboratory, University College London, Holmbury St. Mary, Dorking RH6 5NT (United Kingdom); Dennis, B. R., E-mail: kjhp@mssl.ucl.ac.uk, E-mail: Brian.R.Dennis@nasa.gov [NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States)

2012-03-20T23:59:59.000Z

116

Effect of small additions of silicon, iron, and aluminum on the room-temperature tensile properties of high-purity uranium  

DOE Green Energy (OSTI)

Eleven binary and ternary alloys of uranium and very low concentrations of iron, silicon, and aluminum were prepared and tested for room-temperature tensile properties after various heat treatments. A yield strength approximately double that of high-purity derby uranium was obtained from a U-400 ppM Si-200 ppM Fe alloy after beta solution treatment and alpha aging. Higher silicon plus iron alloy contents resulted in increased yield strength, but showed an unacceptable loss of ductility.

Ludwig, R.L.

1983-11-14T23:59:59.000Z

117

X-231A demonstration of in-situ remediation of DNAPL compounds in low permeability media by soil fracturing with thermally enhanced mass recovery or reactive barrier destruction  

Science Conference Proceedings (OSTI)

The overall goal of the program of activities is to demonstrate robust and cost-effective technologies for in situ remediation of DNAPL compounds in low permeability media (LPM), including adaptations and enhancements of conventional technologies to achieve improved performance for DNAPLs in LPM. The technologies sought should be potential for application at simple, small sites (e.g., gasoline underground storage tanks) as well as at complex, larger sites (e.g., DOE land treatment units). The technologies involved in the X-231A demonstration at Portsmouth Gaseous Diffusion Plant (PORTS) utilized subsurface manipulation of the LPM through soil fracturing with thermally enhanced mass recovery or horizontal barrier in place destruction. To enable field evaluation of these approaches, a set of four test cells was established at the X-231A land treatment unit at the DOE PORTS plant in August 1996 and a series of demonstration field activities occurred through December 1997. The principal objectives of the PORTS X-231A demonstration were to: determine and compare the operational features of hydraulic fractures as an enabling technology for steam and hot air enhanced soil vapor extraction and mass recovery, in situ interception and reductive destruction by zero valent iron, and in situ interception and oxidative destruction by potassium permanganate; determine the interaction of the delivered agents with the LPM matrix adjacent to the fracture and within the fractured zone and assess the beneficial modifications to the transport and/or reaction properties of the LPM deposit; and determine the remediation efficiency achieved by each of the technology strategies.

Siegrist, R.L. [Oak Ridge National Lab., TN (United States)] [Oak Ridge National Lab., TN (United States); [Colorado School of Mines, Golden, CO (United States). Environmental Science and Engineering Div.; Lowe, K.S. [Oak Ridge National Lab., Grand Junction, CO (United States). Life Sciences Div.] [Oak Ridge National Lab., Grand Junction, CO (United States). Life Sciences Div.; Murdoch, L.D. [FRx, Inc., Cincinnati, OH (United States)] [FRx, Inc., Cincinnati, OH (United States); [Clemson Univ., SC (United States); Slack, W.W. [FRx, Inc., Cincinnati, OH (United States)] [FRx, Inc., Cincinnati, OH (United States); Houk, T.C. [Lockheed Martin Energy Systems, Piketon, OH (United States)] [Lockheed Martin Energy Systems, Piketon, OH (United States)

1998-03-01T23:59:59.000Z

118

Iron and Steel Energy Intensities  

U.S. Energy Information Administration (EIA) Indexed Site

If you are having trouble, call 202-586-8800 for help. Home > >Energy Users > Energy Efficiency Page > Iron and Steel Energy Intensities First Use of Energy Blue Bullet First Use/Value of Production Blue Bullet First Use/Ton of steel End Uses of Consumption Blue Bullet Total End Use/Value of Production Blue Bullet Total End Use/Ton of Steel Boiler Fuel as End Use Blue Bullet Boiler Fuel /Value of Production Blue Bullet Boiler Fuel /Ton of Steel Process Heating as End Use Blue Bullet Process Heating Fuel /Ton of Steel Blue Bullet Process Heating /Value of Production Machine Drive as End Use Blue Bullet Machine Drive Fuel/Ton of Steel Blue Bullet Machine Drive Fuel /Value of Production Expenditures Blue Bullet Purchased Fuel /Ton of Steel Blue Bullet Purchased Fuel /Value of Production

119

Iron and manganese removal from a groundwater supply  

SciTech Connect

The treatment options and planning techniques used by the town of Castle Rock (Colorado) for a new water treatment facility are described. Castle Rock officials assessed the available treatment options for dissolved iron and manganese removal and selected potassium permanganate as the primary oxidant to be followed by manganese greensand. A backup prechlorination system for oxidation was also installed. In addition, to prevent excess headloss buildup in the manganese greensand filter media, an anthracite carbon cap was used as the top filter medium for precipitate removal. It is recommended that a treatability study be performed to determine individual design criteria to allow for specific site conditions. The town also assessed the capital and operation and maintenance costs for both treatment at individual well fields and a centralized location for treatment of a cluster of well fields. The results indicate that it is more economical to provide centralized water treatment even though there are capital costs associated with piping raw water from the individual well fields to the central facility. 3 refs.

Lorenz, W.; Seifert, K.; Kasch, O.K. (Arber Richard P. Associates, Inc., Denver, CO (USA))

1988-11-01T23:59:59.000Z

120

Dechlorination of TCE with palladized iron  

DOE Patents (OSTI)

The present invention relates to various methods, such as an above-ground method and an in-ground method, of using a palladized iron bimetallic system for the dechlorination of chlorinated organic compounds from effluents containing the same. The use of palladized iron bimetallic system results in the dechlorination of the chlorinated organic compound into environmentally safe reaction products. The present invention also provides kits, devices, and other instruments that use the above-mentioned palladized iron bimetallic system for the dechlorination of chlorinated organic compounds. 10 figs.

Fernando, Q.; Muftikian, R.; Korte, N.

1998-06-02T23:59:59.000Z

Note: This page contains sample records for the topic "zero-valent iron treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Why Sequence Freshwater Iron-Oxidizing Bacteria?  

NLE Websites -- All DOE Office Websites (Extended Search)

Freshwater Iron-Oxidizing Bacteria? Freshwater Iron-Oxidizing Bacteria? The goal of this project is to obtain complete genome sequences for six different freshwater iron (Fe)-oxidizing bacteria (FeOB). Four of these are oxygen-dependent iron-oxidizing β-proteobacteria, and three of these, Sideroxydans lithotrophicus, Gallionella capsiferriformans, and strain TW-2, are capable of chemolithoautotrophic growth (that is, obtaining energy by the oxidation of inorganic compounds) using Fe(II) as sole energy source under microaerobic (low-oxygen) conditions. The fourth organism, Leptothrix cholodnii, is a sheath-forming heterotrophic (i.e., using complex organic compounds for nutrition) organism that oxidizes both Fe(II) and Mn(II) and deposits a ferromanganic coating on its sheath. In addition,

122

Solubility of carbon in nanocrystalline ?-iron  

Science Conference Proceedings (OSTI)

A thermodynamic model for nanocrystalline interstitial alloys is presented. The equilibrium solid solubility of carbon in ?-iron is calculated for given grain size. Inside the strained nanograins local variation of the carbon content is predicted. ...

Alexander Kirchner; Bernd Kieback

2012-01-01T23:59:59.000Z

123

Iron and the ecology of marine microbes  

E-Print Network (OSTI)

Iron is a cofactor of a number biochemical reactions that are essential for life. In the marine environment, this micronutrient is a scarce resource that limits processes of global importance such as photosynthesis and ...

Ventouras, Laure-Anne

2013-01-01T23:59:59.000Z

124

BNL Blood Drives: Iron-rich foods  

NLE Websites -- All DOE Office Websites (Extended Search)

BNL Blood Drives: Iron-Rich Foods Blood Drive Home Seafood: Fish (cod, sardines, tuna, clams, oysters, shrimp) Poultry: Chicken, eggs, yolk Lean Red Meats: Beef, lamb, veal, pork,...

125

C:\Eco-SSLs\Final Guidance November 2003\Contaminant Specific\Iron\Eco-SSL for Iron.wpd  

NLE Websites -- All DOE Office Websites (Extended Search)

Iron Iron Interim Final OSWER Directive 9285.7-69 U. S. Environmental Protection Agency Office of Solid Waste and Emergency Response 1200 Pennsylvania Avenue, N.W. Washington, DC 20460 November 2003 This page intentionally left blank TABLE OF CONTENTS SUMMARY OF ECO-SSLs FOR IRON . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ES - 1 1.0 INTRODUCTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 - 1 2.0 IRON GEOCHEMISTRY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 - 1 2.1 Weathering Processes Affect on Iron . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 - 3 2.2 Soil Conditions Affect on Iron . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 - 4 3.0 EFFECTS OF IRON ON PLANTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 - 1 3.1 Essentiality . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 - 1 3.2 General Effects

126

Development of Bottom-up Representation of Industrial Energy Efficiency Technologies in Integrated Assessment Models for the Iron and Steel Sector  

E-Print Network (OSTI)

scrap, pig iron or direct reduced iron using an electric arcsteel, pig iron or direct reduced iron using an electric arcbuilding materials). Direct reduced iron (DRI) is produced

Xu, T.T.

2011-01-01T23:59:59.000Z

127

In-situ method to remove iron and other metals from Solution in Groundwater down Gradient from Permeable Reactive Barrier  

DOE Patents (OSTI)

This invention is directed to a process for treating the flow of anaerobic groundwater through an aquifer with a primary treatment media, preferably iron, and then passing the treated groundwater through a second porous media though which an oxygenated gas is passed in order to oxygenate the dissolved primary treatment material and convert it into an insoluble material thereby removing the dissolved primary treatment material from the groundwater.

Carpenter, Clay E.; Morrison, Stanley J.

1999-09-22T23:59:59.000Z

128

In-situ method to remove iron and other metals from solution in groundwater down gradient from permeable reactive barrier  

DOE Patents (OSTI)

This invention is directed to a process for treating the flow of anaerobic groundwater through an aquifer with a primary treatment media, preferably iron, and then passing the treated groundwater through a second porous media though which an oxygenated gas is passed in order to oxygenate the dissolved primary treatment material and convert it into an insoluble material thereby removing the dissolved primary treatment material from the groundwater.

Carpenter, Clay E. (Grand Junction, CO); Morrison, Stanley J. (Grand Junction, CO)

2001-07-03T23:59:59.000Z

129

Aluminum stimulates uptake of non-transferrin bound iron and transferrin bound iron in human glial cells  

SciTech Connect

Aluminum and other trivalent metals were shown to stimulate uptake of transferrin bound iron and nontransferrin bound iron in erytholeukemia and hepatoma cells. Because of the association between aluminum and Alzheimer's Disease, and findings of higher levels of iron in Alzheimer's disease brains, the effects of aluminum on iron homeostasis were examined in a human glial cell line. Aluminum stimulated dose- and time-dependent uptake of nontransferrin bound iron and iron bound to transferrin. A transporter was likely involved in the uptake of nontransferrin iron because uptake reached saturation, was temperature-dependent, and attenuated by inhibitors of protein synthesis. Interestingly, the effects of aluminum were not blocked by inhibitors of RNA synthesis. Aluminum also decreased the amount of iron bound to ferritin though it did not affect levels of divalent metal transporter 1. These results suggest that aluminum disrupts iron homeostasis in Brain by several mechanisms including the transferrin receptor, a nontransferrin iron transporter, and ferritin.

Kim, Yongbae [Department of Environmental Health Sciences, Bloomberg School of Public Health, Johns Hopkins University (United States); Department of Preventive Medicine, Soonchunhyan University, Chunan City (Korea, Republic of) ; Olivi, Luisa [School of Pharmacy, Sahmyook University, Seoul (Korea, Republic of) ; Cheong, Jae Hoon [School of Pharmacy, Sahmyook University, Seoul (Korea, Republic of) ; Maertens, Alex [Department of Environmental Health Sciences, Bloomberg School of Public Health, Johns Hopkins University (United States); Bressler, Joseph P. [Department of Environmental Health Sciences, Bloomberg School of Public Health, Johns Hopkins University (United States) and Kennedy-Krieger Institute, Baltimore, MD 21205 (United States)]. E-mail: Bressler@kennedykrieger.org

2007-05-01T23:59:59.000Z

130

Removal of iron from impure graphites  

DOE Green Energy (OSTI)

Iron-impregnated and ash-rich graphites have been purified by leaching with gaseous I/sub 2/ at 900/sup 0/C. With addition of H/sub 2/, the rate of removal of impurity iron can be markedly increased and becomes comparable to that obtained with Cl/sub 2/. I/sub 2/ has an advantage in that it can also volatilize Ca and perhaps Ba and Sr.

Growcock, F.B.; Heiser, J.

1979-01-01T23:59:59.000Z

131

Iron Availability in the Southern Ocean  

NLE Websites -- All DOE Office Websites (Extended Search)

Iron Availability in the Southern Ocean Print Iron Availability in the Southern Ocean Print The Southern Ocean, circling the Earth between Antarctica and the southernmost regions of Africa, South America, and Australia, is notorious for its high-nutrient, low-chlorophyll areas, which are rich in nutrients-but poor in essential iron. Sea life is less abundant in these regions because the growth of phytoplankton-the marine plants that form the base of the food chain-is suppressed. A study by scientists from South Africa's Stellenbosch University, Princeton University, and the Advanced Light Source (ALS) suggests that it is not just a lack of iron, but a lack of iron in an easy-to-use form, that is affecting the ecosystems. The researchers sampled two north-south corridors across the Southern Ocean, traveling an easterly transect between the base of the South African National Antarctic Expeditions (SANAE IV) in Queen Maud Land and Cape Town, and a westerly transect between SANAE IV and South Georgia Island. Along the way they collected particles containing solid iron from a series of ocean systems with different characteristics.

132

Iron Availability in the Southern Ocean  

NLE Websites -- All DOE Office Websites (Extended Search)

Iron Availability in the Southern Ocean Print Iron Availability in the Southern Ocean Print The Southern Ocean, circling the Earth between Antarctica and the southernmost regions of Africa, South America, and Australia, is notorious for its high-nutrient, low-chlorophyll areas, which are rich in nutrients-but poor in essential iron. Sea life is less abundant in these regions because the growth of phytoplankton-the marine plants that form the base of the food chain-is suppressed. A study by scientists from South Africa's Stellenbosch University, Princeton University, and the Advanced Light Source (ALS) suggests that it is not just a lack of iron, but a lack of iron in an easy-to-use form, that is affecting the ecosystems. The researchers sampled two north-south corridors across the Southern Ocean, traveling an easterly transect between the base of the South African National Antarctic Expeditions (SANAE IV) in Queen Maud Land and Cape Town, and a westerly transect between SANAE IV and South Georgia Island. Along the way they collected particles containing solid iron from a series of ocean systems with different characteristics.

133

COPIES: Iron Range Legislative Delegation  

E-Print Network (OSTI)

Dear Legislators: We are pleased to present the annual report on our research regarding the health status of taconite workers and Iron Range community air quality. This report, as in the past, details the progress made by the University of Minnesota School of Public Health and the Natural Resources Research Institute (NRRI) in all research areas, including occupational exposure, mortality and incidence studies, the respiratory health survey of taconite workers and spouses and the environmental study of airborne particles. In addition, this report contains specific information regarding the assessment of mesothelioma as it pertains to exposure to mineral fibers, referred to as elongate mineral particles (EMP). For this report, the EMP measurement is a standard technique that identifies those fibers (EMP) considered long (over 5 microns). Although the research team felt this was the most important exposure to be assessed with the cases of mesothelioma, in the next several months there will be additional analyses that may provide further insight, including exposure to short EMP, silica and respirable dust. A final report is planned for the end of the year when all components are expected to be completed.

Sen Tony Lourey; Rep Tim Mahoney; Rep Sheldon Johnson; Rep David Dill; Rep Mary Murphy; Sen Tom Bakk; Rep John Persell; Rep Tom Anzelc; Sen Tom Saxhaug; Rep Carly Melin; Rep Jason Metsa

2013-01-01T23:59:59.000Z

134

Sludge recycle and reuse in acid mine drainage treatment  

Science Conference Proceedings (OSTI)

Neutralization of acid mine drainage produces vast quantities of iron-rich sludge, and large quantities of unused lime remain in the sludge after treatment. In a study in which sludge was recycled to increase lime utilization, sludge was mixed with raw acid mine drainage and settled out in an intermediate clarifier. The clarifier supernatant was then treated by lime addition, aeration and sedimentation. The low-pH sludge was withdrawn from the intermediate clarifier. The iron was recovered by acidification and used as wastewater coagulant. The recycle scheme resulted in a 30% decrease in lime requirements, and the resultant coagulant performed well when compared with stock iron coagulant solutions.

Keefer, G.B.; Sack, W.A.

1983-03-01T23:59:59.000Z

135

Electron Correlation in Iron-Based Superconductors  

NLE Websites -- All DOE Office Websites (Extended Search)

Electron Correlation in Iron-Based Superconductors Print Electron Correlation in Iron-Based Superconductors Print In 2008, the discovery of iron-based superconductors stimulated a worldwide burst of activity, leading to about two preprints per day ever since. With a maximum superconducting transition temperature (so far) of 55 K, it is natural to wonder if studying the new materials will help uncover one of the deepest mysteries in modern physics-the mechanism of superconductivity in the copper-based "high-temperature superconductors." One clue lies in whether the electrons in the new superconductors are as highly correlated as they are in the high-temperature superconductors. A truly international North American/European/Asian collaboration working at the ALS has now reported results from a combination of x-ray absorption spectroscopy, resonant inelastic x-ray scattering, and systematic theoretical simulations of iron-based superconductors. The team was able to settle the correlations debate by showing that electrons in the iron-based families that were studied favor itinerant (delocalized) states with only moderate correlations.

136

Electron Correlation in Iron-Based Superconductors  

NLE Websites -- All DOE Office Websites (Extended Search)

Electron Correlation in Iron-Based Superconductors Print Electron Correlation in Iron-Based Superconductors Print In 2008, the discovery of iron-based superconductors stimulated a worldwide burst of activity, leading to about two preprints per day ever since. With a maximum superconducting transition temperature (so far) of 55 K, it is natural to wonder if studying the new materials will help uncover one of the deepest mysteries in modern physics-the mechanism of superconductivity in the copper-based "high-temperature superconductors." One clue lies in whether the electrons in the new superconductors are as highly correlated as they are in the high-temperature superconductors. A truly international North American/European/Asian collaboration working at the ALS has now reported results from a combination of x-ray absorption spectroscopy, resonant inelastic x-ray scattering, and systematic theoretical simulations of iron-based superconductors. The team was able to settle the correlations debate by showing that electrons in the iron-based families that were studied favor itinerant (delocalized) states with only moderate correlations.

137

Electron Correlation in Iron-Based Superconductors  

NLE Websites -- All DOE Office Websites (Extended Search)

Electron Correlation in Iron-Based Superconductors Print Electron Correlation in Iron-Based Superconductors Print In 2008, the discovery of iron-based superconductors stimulated a worldwide burst of activity, leading to about two preprints per day ever since. With a maximum superconducting transition temperature (so far) of 55 K, it is natural to wonder if studying the new materials will help uncover one of the deepest mysteries in modern physics-the mechanism of superconductivity in the copper-based "high-temperature superconductors." One clue lies in whether the electrons in the new superconductors are as highly correlated as they are in the high-temperature superconductors. A truly international North American/European/Asian collaboration working at the ALS has now reported results from a combination of x-ray absorption spectroscopy, resonant inelastic x-ray scattering, and systematic theoretical simulations of iron-based superconductors. The team was able to settle the correlations debate by showing that electrons in the iron-based families that were studied favor itinerant (delocalized) states with only moderate correlations.

138

Electron Correlation in Iron-Based Superconductors  

NLE Websites -- All DOE Office Websites (Extended Search)

Electron Correlation in Iron-Based Superconductors Print Electron Correlation in Iron-Based Superconductors Print In 2008, the discovery of iron-based superconductors stimulated a worldwide burst of activity, leading to about two preprints per day ever since. With a maximum superconducting transition temperature (so far) of 55 K, it is natural to wonder if studying the new materials will help uncover one of the deepest mysteries in modern physics-the mechanism of superconductivity in the copper-based "high-temperature superconductors." One clue lies in whether the electrons in the new superconductors are as highly correlated as they are in the high-temperature superconductors. A truly international North American/European/Asian collaboration working at the ALS has now reported results from a combination of x-ray absorption spectroscopy, resonant inelastic x-ray scattering, and systematic theoretical simulations of iron-based superconductors. The team was able to settle the correlations debate by showing that electrons in the iron-based families that were studied favor itinerant (delocalized) states with only moderate correlations.

139

Electron Correlation in Iron-Based Superconductors  

NLE Websites -- All DOE Office Websites (Extended Search)

Electron Correlation in Iron-Based Superconductors Print Electron Correlation in Iron-Based Superconductors Print In 2008, the discovery of iron-based superconductors stimulated a worldwide burst of activity, leading to about two preprints per day ever since. With a maximum superconducting transition temperature (so far) of 55 K, it is natural to wonder if studying the new materials will help uncover one of the deepest mysteries in modern physics-the mechanism of superconductivity in the copper-based "high-temperature superconductors." One clue lies in whether the electrons in the new superconductors are as highly correlated as they are in the high-temperature superconductors. A truly international North American/European/Asian collaboration working at the ALS has now reported results from a combination of x-ray absorption spectroscopy, resonant inelastic x-ray scattering, and systematic theoretical simulations of iron-based superconductors. The team was able to settle the correlations debate by showing that electrons in the iron-based families that were studied favor itinerant (delocalized) states with only moderate correlations.

140

Carbon Emissions: Iron and Steel Industry  

U.S. Energy Information Administration (EIA) Indexed Site

Iron and Steel Industry Iron and Steel Industry Carbon Emissions in the Iron and Steel Industry The Industry at a Glance, 1994 (SIC Code: 3312) Total Energy-Related Emissions: 39.9 million metric tons of carbon (MMTC) -- Pct. of All Manufacturers: 10.7% -- Nonfuel Emissions: 22.2 MMTC Total First Use of Energy: 1,649 trillion Btu -- Pct. of All Manufacturers: 7.6% Nonfuel Use of Energy: 886 trillion Btu (53.7%) -- Coal: 858 trillion Btu (used to make coke) Carbon Intensity: 24.19 MMTC per quadrillion Btu Energy Information Administration, "1994 Manufacturing Energy Consumption Survey" and Emissions of Greenhouse Gases in the United States 1998 Energy-Related Carbon Emissions, 1994 Source of Carbon Carbon Emissions (million metric tons) All Energy Sources 39.9 Coal 22.7

Note: This page contains sample records for the topic "zero-valent iron treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Attrition and carbon formation on iron catalysts  

DOE Green Energy (OSTI)

A serious engineering problem that needs to be addressed in the scale-up of slurry-phase, Fischer-Tropsch reactors is attrition of the precipitated iron catalyst. Attrition, which can break down the catalyst into particles too small to filter, results from both mechanical and chemical forces. This study examines the chemical causes of attrition in iron catalysts. A bench-scale, slurry-phase CSTR is used to simulate operating conditions that lead to attrition of the catalyst. The average particle size and size distribution of the catalyst samples are used to determine the effect of slurry temperature, reducing gas, gas flow rate and time upon attrition of the catalyst. Carbon deposition, a possible contributing factor to attrition, has been examined using gravimetric analysis and TEM. Conditions affecting the rate of carbon deposition have been compared to those leading to attrition of the precipitated iron catalyst.

Kohler, S.D.; Harrington, M.S.; Jackson, N.B. [Sandia National Labs., Albuquerque, NM (United States); Shroff, M.; Kalakkad, D.S.; Datye, A.K. [New Mexico Univ., Albuquerque, NM (United States). Dept. of Chemical and Nuclear Engineering

1994-08-01T23:59:59.000Z

142

Marine Diatoms Survive Iron Droughts in the Ocean by Storing Iron in  

NLE Websites -- All DOE Office Websites (Extended Search)

Marine Diatoms Survive Iron Droughts in Marine Diatoms Survive Iron Droughts in the Ocean by Storing Iron in Ferritin Almost all organisms require iron as a co-factor in numerous metalloproteins and enzymes. In particular, phytoplankton, which are aquatic, free-drifting, single-celled organisms that can harvest energy from the sun, have an elevated demand for iron due to the large role it plays in their photosynthetic machinery. In 30-40% of the world's oceans iron concentrations are low enough to limit the growth of phytoplankton (Martin and Fitzwater 1988; Moore et al. 2002). New sources of iron to these regions are sporadic and typically include atmospheric dust deposition or weak upwelling of deep waters. figure 1 Figure 1: A light micrograph of the marine pennate diatom Pseudo-nitzschia multiseries. Shown are one whole cell and two partial cells connected at the cell tips in a chain. The brown components of the cells are the chloroplasts. Scale bar = 5 mm. (Image courtesy of K. Holtermann)

143

Importance of Iron Mineralogy to Aerosol Solubility: Potential Effects of  

NLE Websites -- All DOE Office Websites (Extended Search)

Importance of Iron Mineralogy to Importance of Iron Mineralogy to Aerosol Solubility: Potential Effects of Aerosol Source on Ocean Photosynthesis figure 1 Figure 1. Dust storm blowing glacial dusts from the Copper River Basin of southeast Alaska into the North Pacific Ocean, which depends on this and other external iron sources to support its biological communities. (Image: NASA MODIS satellite image, Nov. 1, 2006. http://earthobservatory.nasa.gov/IOTD/view.php?id=7094) Iron is one of the most important elements to life. Despite its paramount importance and relative abundance, dissolved iron concentrations are often very low, in part due to the formation of very stable iron minerals in most oxidizing environments. Since soluble iron is available to living organisms, iron deficiencies are widespread, and the factors that influence

144

Authority, polity, and tenuous elites in Iron Age Edom (Jordan)  

E-Print Network (OSTI)

the Iron Age in southern Jordan (Shef?eld), 4754. knauf, e.at Tawilan in southern Jordan (Oxford). bienkowski, p.the Iron Age in southern Jordan: A framework. In Bienkowski,

Porter, Benjamin W.

2004-01-01T23:59:59.000Z

145

Candidate anode materials for iron production by molten oxide electrolysis  

E-Print Network (OSTI)

Molten oxide electrolysis (MOE) has been identified by the American Iron and Steel Institute (AISI) as one of four possible breakthrough technologies to alleviate the environmental impact of iron and steel production. This ...

Paramore, James D

2010-01-01T23:59:59.000Z

146

Lab researchers achieve record pressure for solid iron  

NLE Websites -- All DOE Office Websites (Extended Search)

for solid iron. Lab researchers achieve record pressure for solid iron Breanna Bishop, LLNL, (925) 423-9802, bishop33@llnl.gov High Resolution Image Illustration of the...

147

Demonstration Test of Iron Addition to a Flue Gas Desulfurization (FGD) Absorber to Enhance Mercury Removal  

Science Conference Proceedings (OSTI)

This report documents the findings from a full-scale demonstration test of the effects on trace elements of adding iron to a forced oxidation flue gas desulfurization (FGD) scrubber. Three specific effects were evaluated: lowering mercury emissions to the atmosphere; lowering the concentration of soluble or sub-micron-sized mercury particles in FGD purge water, which could improve removal of mercury in FGD purge water treatment; and lowering the concentration of selenate in FGD purge water, which could i...

2009-12-31T23:59:59.000Z

148

Method of increasing magnetostrictive response of rare earth-iron alloy rods  

DOE Patents (OSTI)

This invention comprises a method of increasing the magnetostrictive response of rare earth-iron (RFe) magnetostrictive alloy rods by a thermal-magnetic treatment. The rod is heated to a temperature above its Curie temperature, viz. from 400.degree. to 600.degree. C.; and, while the rod is at that temperature, a magnetic field is directionally applied and maintained while the rod is cooled, at least below its Curie temperature.

Verhoeven, John D. (Ames, IA); McMasters, O. Dale (Ames, IA); Gibson, Edwin D. (Ames, IA); Ostenson, Jerome E. (Ames, IA); Finnemore, Douglas K. (Ames, IA)

1989-04-04T23:59:59.000Z

149

Iron Catalysis in Oxidations by Ozone - Energy Innovation Portal  

Wind Energy; Partners (27) Visual Patent Search; Success Stories; News; Events; Industrial Technologies Iron Catalysis in Oxidations by Ozone Ames ...

150

Lithium Iron Phosphate Composites for Lithium Batteries | Argonne...  

NLE Websites -- All DOE Office Websites (Extended Search)

Lithium Iron Phosphate Composites for Lithium Batteries Technology available for licensing: Inexpensive, electrochemically active phosphate compounds with high functionality for...

151

Iron 'Veins' Are Secret of Promising New Hydrogen Storage ...  

Science Conference Proceedings (OSTI)

Iron 'Veins' Are Secret of Promising New Hydrogen Storage Material. ... International Journal of Hydrogen Energy, 36 (2011), pp. ...

2012-10-18T23:59:59.000Z

152

Iron distribution and phytoplankton iron limitation in the southern California Current System  

E-Print Network (OSTI)

chl L -1 ) in the southern offshore region. 1.3. Literaturedissolved iron concentrations at an offshore station (~700 km offshore San Diego, CA, July 2007, 29 51 N, 123

King, Andrew Luke

2008-01-01T23:59:59.000Z

153

Thermodynamic Analyses of Iron Oxides Redox Reactions  

Science Conference Proceedings (OSTI)

To clarify such confusions, the elementary thermodynamic data of various iron ... and water vapor are used to calculate the changes of thermodynamic quantities such as .... Heat Transfer Characteristic in a Slag Heat Recovery Chamber ... Numerical Simulation of Electro-magnetic Flow Control Phenomenon in a Tundish.

154

Field Projects: Durango, Colorado | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Long-Term Surveillance - Operations and Maintenance Long-Term Surveillance - Operations and Maintenance » Permeable Reactive Barriers » Field Projects: Durango, Colorado Field Projects: Durango, Colorado Personnel from Sandia National Laboratories in New Mexico installed four permeable reactive barriers PRBs at the Durango, Colorado, Uranium Mill Tailings Radiation Control Act Title I site in October 1995. These PRBs are managed by LM. Foamed zero-valent (ZVI) iron bricks produced by Cercona of America, steel wool, and granular iron have been used as reactive media to remove ammonium, arsenic, cadmium, chromium, manganese, molybdenum, nitrate, radium-226, selenium, uranium, vanadium, and zinc contamination from leachate exiting the uranium mill tailings disposal cell. After passing through the ZVI, the leachate contaminant levels meet the

155

Effects of High Dietary Iron and Gamma Radiation on Oxidative Stress and Bone  

E-Print Network (OSTI)

Astronauts in space flight missions are exposed to increased iron (Fe) stores and galactic cosmic radiation, both of which independently induce oxidative stress. Oxidative stress can result in protein, lipid, and DNA oxidation. Recent evidence has linked oxidative stress to bone loss with aging and estrogen deficiency. Whether the increased iron stores and radiation that astronauts face are exacerbating their extreme bone loss while in space is unclear. We hypothesized that elevated iron levels (induced by feeding a high iron diet) and gamma radiation exposure would independently increase markers of oxidative stress and markers of oxidative damage and result in loss of bone mass, with the combined treatment having additive or synergistic effects. Male Sprague-Dawley rats (15-weeks old, n=32) were randomized to receive an adequate (45 mg Fe/kg diet) or high (650 mg Fe/kg diet) Fe diet for 4 weeks and either 3 Gy (8 fractions, 0.375 Gy each) of 137Cs radiation (?RAD) or sham exposure every other day over 16 days starting on day 14. Serum Fe and catalase and liver Fe and glutathione peroxidase (GPX) were assessed by standard techniques. Immunostaining for 8-hydroxy-2-deoxyguanosine (8-OHdG, marker of DNA adducts) quantified the number of cells with oxidative damage in cortical bone. Bone histomorphometry assessed bone cell activity and cancellous bone microarchitecture in the metaphyseal region. Ex vivo pQCT quantified volumetric bone mineral density (vBMD); bone mechanical strength was assessed by 3-pt bending at the midshaft tibia and compression of the femoral neck. High Fe diet increased liver Fe and decreased volume per total volume (BV/TV). ?RAD decreased osteoid surface per bone surface (OS/BS) and osteocyte density. The combined treatment increased serum catalase, liver GPX, and serum iron and decreased cancellous vBMD and trabecular number (Tb.N). High Fe diet and ?RAD independently increased number of osteocytes stained positive for 8-OHdG, with the combined treatment exhibiting twice as many osteocytes positively stained compared to the control. Higher serum Fe levels were associated with higher oxidative damage (r =0.38) and lower proximal tibial cancellous vBMD (r =0.38). Higher serum catalase levels were associated with higher oxidative damage (r =0.48), lower BV/TV (r =0.40) and lower cancellous vBMD (r =0.39). High dietary iron and fractionated 137Cs ?RAD leads to a moderate elevation in iron stores and results in oxidative damage in bone and are associated with decreased cancellous bone density. Moderate elevations in iron stores are not only found in astronauts, but also naturally occur in healthy human populations. This healthy population with elevated iron stores may also have increased levels of oxidative stress in the body. Elevated levels of oxidative stress not only increase ones risk for accelerated bone loss, but also the risk of developing other chronic diseases such as insulin resistance, hypertension, dyslipidemia, and metabolic syndrome.

Yuen, Evelyn P

2013-05-01T23:59:59.000Z

156

Lithium-aluminum-iron electrode composition  

DOE Patents (OSTI)

A negative electrode composition is presented for use in a secondary electrochemical cell. The cell also includes an electrolyte with lithium ions such as a molten salt of alkali metal halides or alkaline earth metal halides that can be used in high-temperature cells. The cell's positive electrode contains a a chalcogen or a metal chalcogenide as the active electrode material. The negative electrode composition includes up to 50 atom percent lithium as the active electrode constituent in an alloy of aluminum-iron. Various binary and ternary intermetallic phases of lithium, aluminum and iron are formed. The lithium within the intermetallic phase of Al.sub.5 Fe.sub.2 exhibits increased activity over that of lithium within a lithium-aluminum alloy to provide an increased cell potential of up to about 0.25 volt.

Kaun, Thomas D. (Mokena, IL)

1979-01-01T23:59:59.000Z

157

Iron-sulfide redox flow batteries  

Science Conference Proceedings (OSTI)

Iron-sulfide redox flow battery (RFB) systems can be advantageous for energy storage, particularly when the electrolytes have pH values greater than 6. Such systems can exhibit excellent energy conversion efficiency and stability and can utilize low-cost materials that are relatively safer and more environmentally friendly. One example of an iron-sulfide RFB is characterized by a positive electrolyte that comprises Fe(III) and/or Fe(II) in a positive electrolyte supporting solution, a negative electrolyte that comprises S.sup.2- and/or S in a negative electrolyte supporting solution, and a membrane, or a separator, that separates the positive electrolyte and electrode from the negative electrolyte and electrode.

Xia, Guan-Guang; Yang, Zhenguo; Li, Liyu; Kim, Soowhan; Liu, Jun; Graff, Gordon L

2013-12-17T23:59:59.000Z

158

Magnetism and Superconductivity in Iron Pnictides  

Science Conference Proceedings (OSTI)

The discovery of high temperature superconductivity in iron pnictides and chalcogenides has resulted in surprising new insights into high temperature superconductivity and its relationship with magnetism. Here we provide an overview of some of what is known about these materials and in particular about the interplay of magnetism and superconductivity in them. Similarities and contrasts with cuprate superconductors are emphasized and the superconducting pairing is discussed within the framework of spin fluctuation induced pairing.

Singh, David J [ORNL

2012-01-01T23:59:59.000Z

159

Thin Wall Cast Iron: Phase II  

DOE Green Energy (OSTI)

The development of thin-wall technology allows the designers of energy consuming equipment to select the most appropriate material based on cost/material properties considerations, and not solely on density. The technology developed in this research project will permit the designers working for the automotive industry to make a better informed choice between competing materials and thin wall cast iron, thus decreasing the overall cost of the automobile.

Doru M. Stefanescu

2005-07-21T23:59:59.000Z

160

Iron phosphate compositions for containment of hazardous metal waste  

DOE Patents (OSTI)

An improved iron phosphate waste form for the vitrification, containment and long-term disposition of hazardous metal waste such as radioactive nuclear waste is provided. The waste form comprises a rigid iron phosphate matrix resulting from the cooling of a melt formed by heating a batch mixture comprising the metal waste and a matrix-forming component. The waste form comprises from about 30 to about 70 weight percent P{sub 2}O{sub 5} and from about 25 to about 50 weight percent iron oxide and has metals present in the metal waste chemically dissolved therein. The concentration of iron oxide in the waste form along with a high proportion of the iron in the waste form being present as Fe{sup 3+} provide a waste form exhibiting improved chemical resistance to corrosive attack. A method for preparing the improved iron phosphate waste forms is also provided. 21 figs.

Day, D.E.

1998-05-12T23:59:59.000Z

Note: This page contains sample records for the topic "zero-valent iron treatment" from the National Library of EnergyBeta (NLEBeta).
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161

Apparatus and process for water treatment  

DOE Patents (OSTI)

An apparatus is disclosed utilizing permeable treatment media for treatment of contaminated water, along with a method for enhanced passive flow of contaminated water through the treatment media. The apparatus includes a treatment cell including a permeable structure that encloses the treatment media, the treatment cell may be located inside a water collection well, exterior to a water collection well, or placed in situ within the pathway of contaminated groundwater. The passive flow of contaminated water through the treatment media is maintained by a hydraulic connection between a collecting point of greater water pressure head, and a discharge point of lower water pressure head. The apparatus and process for passive flow and groundwater treatment utilizes a permeable treatment media made up of granular metal, bimetallics, granular cast iron, activated carbon, cation exchange resins, and/or additional treatment materials. An enclosing container may have an outer permeable wall for passive flow of water into the container and through the enclosed treatment media to an effluent point. Flow of contaminated water is attained without active pumping of water through the treatment media. Remediation of chlorinated hydrocarbons and other water contaminants to acceptable regulatory concentration levels is accomplished without the costs of pumping, pump maintenance, and constant oversight by personnel.

Phifer, Mark A. (North Augusta, SC); Nichols, Ralph L. (North Augusta, SC)

2001-01-01T23:59:59.000Z

162

Iron Corrosion Observations: Pu(VI)-Fe Reduction Studies  

Science Conference Proceedings (OSTI)

Iron and Pu Reduction: (1) Very different appearances in iron reaction products were noted depending on pH, brine and initial iron phase; (2) Plutonium was associated with the Fe phases; (3) Green rust was often noted at the higher pH; (4) XANES established the green rust to be an Fe2/3 phase with a bromide center; and (5) This green rust phase was linked to Pu as Pu(IV).

Reed, Donald T. [Los Alamos National Laboratory; Swanson, Juliet S. [Los Alamos National Laboratory; Richmann, Michael K. [Los Alamos National Laboratory; Lucchini, Jean-Francois [Los Alamos National Laboratory; Borkowski, Marian [Los Alamos National Laboratory

2012-09-11T23:59:59.000Z

163

Investigation on Modified Humic Substances Based Binders for Iron ...  

Science Conference Proceedings (OSTI)

Presentation Title, Investigation on Modified Humic Substances Based Binders for Iron ... An Electron Microscopy Study of Nanoscale Surface and Sub-Surface...

164

Unusual 'Collapsing' Iron Superconductor Sets Record for Its ...  

Science Conference Proceedings (OSTI)

... superconductor that operates at the highest known temperature for a material in its class.* The discovery inches iron-based superconductors ...

2012-02-07T23:59:59.000Z

165

The Investigation of Sponge Iron Production Parameters by Using ...  

Science Conference Proceedings (OSTI)

May 1, 2007 ... In the present work, the possibilities of coal-based sponge iron production for industrial applications by using domestic lignite coal were...

166

Coal-based Direct Reduction of Iron Concentrate Pellets by ...  

Science Conference Proceedings (OSTI)

Presentation Title, Coal-based Direct Reduction of Iron Concentrate Pellets by Microwave Heating. Author(s), Wang Xia, Huang Zhucheng. On-Site Speaker...

167

Spark Plasma Sintering of Iron and Titanium Powders by ...  

Science Conference Proceedings (OSTI)

Mixtures of titanium and iron powders were activated in kerosene by high-voltage electrical discharges with different electrical discharge numbers.

168

Recent Progress in Molten Oxide Electrolysis for Iron Production  

Science Conference Proceedings (OSTI)

Presentation Title, Recent Progress in Molten Oxide Electrolysis for Iron Production ... Concentrated Solar Power for Producing Liquid Fuels from CO2 and H2O.

169

MATHEMATICAL MODELING OF THE LITHIUM-ALUMINUM, IRON SULFIDE BATTERY  

E-Print Network (OSTI)

and J. Newman, Proc. Syrup. Battery Design and Optimization,123, 1364 (1976). Symp, Battery Design and Optimization, S.~ALUMINUM, IRON SULFIDE BATTERY Contents ACKNOWLEDGEMENTS

Pollard, Richard

2012-01-01T23:59:59.000Z

170

Regenerable Mixed Copper-Iron-Inert Support Oxygen ...  

Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process Contact NETL Technology Transfer Group

171

Mathematical Modeling for Side-Blow Combustion Region in Iron ...  

Science Conference Proceedings (OSTI)

Presentation Title, Mathematical Modeling for Side-Blow Combustion Region in Iron Bath Reactor with H2-C Mixture Reduction. Author(s), Bo Zhang, Hong Xin.

172

Effect of the Raw Material Characteristic of Iron Concentrates on ...  

Science Conference Proceedings (OSTI)

It has important instructing function for China steel mills to import and use iron ... Numerical Simulation of Electromagnetic Fields in Microwave Gas Heating...

173

Niobium Alloying in Grey Cast Iron for Vehicle Brake Discs  

Science Conference Proceedings (OSTI)

Presentation Title, Niobium Alloying in Grey Cast Iron for Vehicle Brake Discs. Author(s) ... Microtexture Analysis of a Hot Rolled Silicon Electric Steel Niobium

174

Low Resistivity Contact to Iron-Pnicitide Superconductors ...  

Iron-pnictide based superconductors have a number of superior properties as compared to other known high temperature ... Geothermal; Hydrogen and Fuel ...

175

Strengthening Sintering of Refractory Iron Ore with Biomass Fuel  

Science Conference Proceedings (OSTI)

Presentation Title, Strengthening Sintering of Refractory Iron Ore with Biomass Fuel. Author(s), Xiaohui Fan, Zhiyun Ji, Min Gan, Xuling Chen, Wenqi Li. On-Site

176

Iron active electrode and method of making same  

DOE Green Energy (OSTI)

An iron active electrode and method of preparing same in which iron sulfate is calcined in an oxidizing atmosphere at a temperature in the range of from about 600/sup 0/C to about 850/sup 0/C for a time sufficient to produce an iron oxide with a trace amount of sulfate are described. The calcined material is loaded into an electrically conductive support and then heated in a reducing atmosphere at an elevated temperature to produce activated iron having a trace amount of sulfide which is formed into an electrode plate.

Jackovitz, J.F.; Seidel, J.; Pantier, E.A.

1981-04-16T23:59:59.000Z

177

Materials Sustainability: Digital Resource Center - Iron and Steel ...  

Science Conference Proceedings (OSTI)

Jul 3, 2008 ... ABSTRACT: Consumption of iron and steel scrap and the health of the scrap industry depend directly on the health of the steelmaking industry.

178

PRODUCTION OF IRON FROM METALLURGICAL WASTE - Energy Innovation Portal  

Building Energy Efficiency ... Solar Thermal; Startup ... heating the agglomerates to a higher temperature above the melting point of iron to form nodules of metallic ...

179

New Iron-based Superconductors Reinforce Link to ...  

Science Conference Proceedings (OSTI)

New Iron-based and Copper-Oxide High-Temperature Superconductors Share Key Magnetic Properties. For Immediate Release: May 28, 2008. ...

2011-05-04T23:59:59.000Z

180

Vitrification of DOE Problematic Wastes Using Iron Phosphate Glasses  

Science Conference Proceedings (OSTI)

Abstract Scope, This work is to formulate and optimize iron phosphate glass compositions which are suitable for vitrifying several specified Hanford HLW and ...

Note: This page contains sample records for the topic "zero-valent iron treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Iron-Air Rechargeable Battery: A Robust and Inexpensive Iron-Air Rechargeable Battery for Grid-Scale Energy Storage  

Science Conference Proceedings (OSTI)

GRIDS Project: USC is developing an iron-air rechargeable battery for large-scale energy storage that could help integrate renewable energy sources into the electric grid. Iron-air batteries have the potential to store large amounts of energy at low costiron is inexpensive and abundant, while oxygen is freely obtained from the air we breathe. However, current iron-air battery technologies have suffered from low efficiency and short life spans. USC is working to dramatically increase the efficiency of the battery by placing chemical additives on the batterys iron-based electrode and restructuring the catalysts at the molecular level on the batterys air-based electrode. This can help the battery resist degradation and increase life span. The goal of the project is to develop a prototype iron-air battery at significantly cost lower than todays best commercial batteries.

None

2010-10-01T23:59:59.000Z

182

Arsenic remediation of drinking water using iron-oxide coated coal bottom ash  

E-Print Network (OSTI)

using Iron-oxide Coated Coal Ash. In Arsenic Contaminationwaterusing iron?oxidecoatedcoalbottomash JohannaL. using iron-oxide coated coal bottom ash JOHANNA L. MATHIEU

MATHIEU, JOHANNA L.

2010-01-01T23:59:59.000Z

183

Iron(II) Oxidation by SO 2 /O 2 in Uranium Leach Solutions  

Science Conference Proceedings (OSTI)

Aug 1, 2003 ... Oxidants are added in uranium leaching in acid media to convert iron(II) in solution to iron(III). Iron(III) has an important role in the leaching of...

184

New trends in industrial energy efficiency in the Mexico iron and steel industry  

E-Print Network (OSTI)

in the iron and steel industry" in 1997 ACEEE Summer Studyin the Mexican Iron and Steel industry are the B O F and theInternational Iron and Steel Industry, Brussels, pp. 47-48

Ozawa, Leticia; Martin, Nathan; Worrell, Ernst; Price, Lynn; Sheinbaum, Claudia

1999-01-01T23:59:59.000Z

185

Electrically insulating phosphate coatings for iron powder based electromagnetic core applications  

E-Print Network (OSTI)

Powdered metals, such as iron, are a common building block for electromagnetic cores. An iron powder was reacted with phosphoric acid to create a layer of iron phosphate on each particle. This electrically insulating ...

Nolan, William Rane

2009-01-01T23:59:59.000Z

186

Void trapping of hydrogen in sintered iron  

DOE Green Energy (OSTI)

The effect of void trapping of hydrogen in iron was studied using the gas-phase permeation technique. Iron membranes of controlled void density, varying from 92% to 98% were prepared by press and sintering of electrolytic iron powder. The presence of internal voids showed no effect on the steady state flux of hydrogen through the membrane. The effective diffusivity, obtained by the time lag method, increased with the increase of input hydrogen partial pressure. This disagreement with the prediction of the theory in literature was explained by the existence of hydrogen in both the diatomic gaseous form and as adsorbed hydrogen. This explanation was further confirmed by examining the dependence of trapped hydrogen concentration with pressure. The linear dependence of trapped hydrogen concentration in voids with external hydrogen partial pressure for samples of 96%, 94% and 92% dense were given respectively by C/sub g/ = (1.5 +- 0.2) x 10/sup 15/ P + (3.2 +- 0.5) x 10/sup 14/ atoms of H/c.c. C/sub g/ = (2.1 +- 0.6) x 10/sup 15/ P + (1.7 +- 0.5) x 10/sup 15/ atoms of H/c.c. C/sub g/ = (4.5 +- 0.3) x 10/sup 15/ P + (6.5 +- 0.2) x 10/sup 15/ atoms of H/c.c. The discrepancy between the reported values and the values predicted by theory was explained by the poisoning of some of the voids by surface oxides.

Wong, K.C.

1976-09-01T23:59:59.000Z

187

Unconventional temperature enhanced magnetism in iron telluride  

SciTech Connect

Discoveries of copper and iron-based high-temperature superconductors (HTSC)1-2 have challenged our views of superconductivity and magnetism. Contrary to the pre-existing view that magnetism, which typically involves localized electrons, and superconductivity, which requires freely-propagating itinerant electrons, are mutually exclusive, antiferromagnetic phases were found in all HTSC parent materials3,4. Moreover, highly energetic magnetic fluctuations, discovered in HTSC by inelastic neutron scattering (INS) 5,6, are now widely believed to be vital for the superconductivity 7-10. In two competing scenarios, they either originate from local atomic spins11, or are a property of cooperative spin-density-wave (SDW) behavior of conduction electrons 12,13. Both assume clear partition into localized electrons, giving rise to local spins, and itinerant ones, occupying well-defined, rigid conduction bands. Here, by performing an INS study of spin dynamics in iron telluride, a parent material of one of the iron-based HTSC families, we have discovered that this very assumption fails, and that conduction and localized electrons are fundamentally entangled. In the temperature range relevant for the superconductivity we observe a remarkable redistribution of magnetism between the two groups of electrons. The effective spin per Fe at T 10 K, in the2 antiferromagnetic phase, corresponds to S 1, consistent with the recent analyses that emphasize importance of Hund s intra-atomic exchange15-16. However, it grows to S 3/2 in the disordered phase, a result that profoundly challenges the picture of rigid bands, broadly accepted for HTSC.

Zalinznyak, I. [Brookhaven National Laboratory (BNL); Xu, Zhijun [ORNL; Tranquada, John M. [Brookhaven National Laboratory (BNL); Gu, G. D. [Brookhaven National Laboratory (BNL); Tsvelik, A. [Brookhaven National Laboratory (BNL); Stone, Matthew B [ORNL

2011-01-01T23:59:59.000Z

188

Charge exchange processes involving iron ions  

DOE Green Energy (OSTI)

A review and evaluation is given of the experimental data which are available for charge exchange processes involving iron ions and neutral H, H/sub 2/ and He. Appropriate scaling laws are presented, and their accuracy estimated for these systems. A bibliography is given of available data sources, as well as of useful data compilations and review articles. A procedure is recommended for providing single approximate formulae to the fusion community to describe total cross sections for electron capture by partially-stripped Fe/sup q+/ ions in collisions with H, H/sub 2/ and He, based on the scaling relationships suggested by Janev and Hvelplund.

Phaneuf, R.A.

1985-01-01T23:59:59.000Z

189

Suspension Hydrogen Reduction of Iron Oxide Concentrates  

DOE Green Energy (OSTI)

The objective of the project is to develop a new ironmaking technology based on hydrogen and fine iron oxide concentrates in a suspension reduction process. The ultimate objective of the new technology is to replace the blast furnace and to drastically reduce CO2 emissions in the steel industry. The goals of this phase of development are; the performance of detailed material and energy balances, thermochemical and equilibrium calculations for sulfur and phosphorus impurities, the determination of the complete kinetics of hydrogen reduction and bench-scale testing of the suspension reduction process using a large laboratory flash reactor.

H.Y. Sohn

2008-03-31T23:59:59.000Z

190

Energy efficiency and carbon dioxide emissions reduction opportunities in the U.S. Iron and Steel sector  

E-Print Network (OSTI)

scrap steel, pig iron, or direct reduced iron (DRI) using anfrom scrap and/or direct reduced iron (DRI, also calledAlternatives Direct reduced iron (DRI), hot briquetted

Worrell, Ernst; Martin, N.; Price, L.

1999-01-01T23:59:59.000Z

191

A Comparison of Iron and Steel Production Energy Use and Energy Intensity in China and the U.S.  

E-Print Network (OSTI)

Mt, net imported Direct-Reduced Iron (DRI) in 2006 was 2.61in Figure 3) pig iron, direct-reduced iron (DRI), pellets,of net imported direct reduced iron Energy used for the

Hasanbeigi, Ali

2012-01-01T23:59:59.000Z

192

Manganese Doping of Magnetic Iron Oxide Nanoparticles: Tailoring Surface Reactivity for a Regenerable Heavy Metal Sorbent  

SciTech Connect

A method for tuning the analyte affinity of magnetic, inorganic nanostructured sorbents for heavy metal contaminants is described. The manganese-doped iron oxide nanoparticle sorbents have a remarkably high affinity compared to the precursor material. Sorbent affinity can be tuned toward an analyte of interest simply by adjustment of the dopant quantity. The results show that following the Mn doping process there is a large increase in affinity and capacity for heavy metals (i.e., Co, Ni, Zn, As, Ag, Cd, Hg, and Tl). Capacity measurements were carried out for the removal of cadmium from river water and showed significantly higher loading than the relevant commercial sorbents tested for comparison. The reduction in Cd concentration from 100 ppb spiked river water to 1 ppb (less than the EPA drinking water limit of 5 ppb for Cd) was achieved following treatment with the Mn-doped iron oxide nanoparticles. The Mn-doped iron oxide nanoparticles were able to load 1 ppm of Cd followed by complete stripping and recovery of the Cd with a mild acid wash. The Cd loading and stripping is shown to be consistent through multiple cycles with no loss of sorbent performance.

Warner, Cynthia L.; Chouyyok, Wilaiwan; Mackie, Katherine E.; Neiner, Doinita; Saraf, Laxmikant; Droubay, Timothy C.; Warner, Marvin G.; Addleman, Raymond S.

2012-02-28T23:59:59.000Z

193

Study on Nucleation and Growth Mechanism of Iron Crystal Grain in ...  

Science Conference Proceedings (OSTI)

Presentation Title, Study on Nucleation and Growth Mechanism of Iron Crystal Grain in Coal-Based Shaft Furnace Direct Reduction Iron Pellets by Microwave...

194

Trophic status of Chlamydomonas reinhardtii influences the impact of iron deficiency on photosynthesis  

E-Print Network (OSTI)

of iron de?ciency on photosynthesis Aimee M. Terauchi rates by suppress- ing photosynthesis but increasing insteadal. 2007). In oxygenic photosynthesis, iron is a cofactor in

Terauchi, Aimee M.; Peers, Graham; Kobayashi, Marilyn C.; Niyogi, Krishna K.; Merchant, Sabeeha S.

2010-01-01T23:59:59.000Z

195

Desulfurization mixture and process for desulfurizing pig iron  

SciTech Connect

Process and composition for desulfurizing pig iron in which the desulfurization agent consists essentially of calcium carbide, a gas-evolving component and fluorspar; the advantage of the process and composition is that it reduces dust pollution and danger of flaming in the handling of the slag after the desulfurization of pig iron.

Freissmuth, A.; Gmohling, W.; Rock, H.

1982-02-16T23:59:59.000Z

196

The release of iron during coal combustion. Milestone report  

Science Conference Proceedings (OSTI)

Iron plays an important role in the formation of both fly ash and deposits in many pulverized-coal-fired boilers. Several authors indicate that iron content is a significant indicator of the slagging propensity of a majority of US bituminous coals, in particular eastern bituminous coals. The pyritic iron content of these coals is shown to be a particularly relevant consideration. A series of investigations of iron release during combustion is reported for a suite of coals ranging in rank from lignite to low-volatile bituminous coal under combustion conditions ranging from oxidizing to inert. Experimental measurements are described in which, under selected conditions, major fractions of the iron in the coal are released within a 25 ms period immediately following coal devolatilization. Mechanistic interpretation of the data suggest that the iron is released as a consequence of oxygen attack on porous pyrrhotite particles. Experimental testing of the proposed mechanism reveals that the release is dependent on the presence of both pyrite in the raw coal and oxygen in the gas phase, that slow preoxidation (weathering) of the pyrite significantly inhibits the iron release, and that iron loss increases as oxygen penetration of the particle increases. Each observation is consistent with the postulated mechanism.

Baxter, L.L. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility

1995-06-01T23:59:59.000Z

197

EnvIRONment and Other Bath Smelting Processes for Treating ...  

Science Conference Proceedings (OSTI)

Although the American Iron and Steel Institute-Department of Energy program is ... definitely superior to the direct-reduced iron and scrap available on the ferrous market. ..... Based on in-house and independent analyses, it should be profitable to run an .... For more information, contact G. Brooks, University of Wollongong,...

198

Iron Phosphate Glass-Containing Hanford Waste Simulant  

SciTech Connect

Resolution of the nations high level tank waste legacy requires the design, construction, and operation of large and technically complex one-of-a-kind processing waste treatment and vitrification facilities. While the ultimate limits for waste loading and melter efficiency have yet to be defined or realized, significant reductions in glass volumes for disposal and mission life may be possible with advancements in melter technologies and/or glass formulations. This test report describes the experimental results from a small-scale test using the research scale melter (RSM) at Pacific Northwest National Laboratory (PNNL) to demonstrate the viability of iron phosphate-based glass with a selected waste composition that is high in sulfates (4.37 wt% SO3). The primary objective of the test was to develop data to support a cost-benefit analysis as related to the implementation of phosphate-based glasses for Hanford low activity waste (LAW) and/or other high-level waste streams within the U.S. Department of Energy complex. The testing was performed by PNNL and supported by Idaho National Laboratory, Savannah River National Laboratory, and Mo-Sci Corporation.

Sevigny, Gary J.; Kimura, Marcia L.; Fischer, Christopher M.; Schweiger, Michael J.; Kim, Dong-Sang

2011-08-01T23:59:59.000Z

199

Iron Phosphate Glass-Containing Hanford Waste Simulant  

SciTech Connect

Resolution of the nation's high-level tank waste legacy requires the design, construction, and operation of large and technically complex one-of-a-kind processing waste treatment and vitrification facilities. While the ultimate limits for waste loading and melter efficiency have yet to be defined or realized, significant reductions in glass volumes for disposal and mission life may be possible with advancements in melter technologies and/or glass formulations. This test report describes the experimental results from a small-scale test using the research-scale melter (RSM) at Pacific Northwest National Laboratory (PNNL) to demonstrate the viability of iron-phosphate-based glass with a selected waste composition that is high in sulfate (4.37 wt% SO3). The primary objective of the test was to develop data to support a cost-benefit analysis related to the implementation of phosphate-based glasses for Hanford low-activity waste (LAW) and/or other high-level waste streams within the U.S. Department of Energy complex. The testing was performed by PNNL and supported by Idaho National Laboratory, Savannah River National Laboratory, Missouri University of Science and Technology, and Mo-Sci Corporation.

Sevigny, Gary J.; Kimura, Marcia L.; Fischer, Christopher M.; Schweiger, M. J.; Rodriguez, Carmen P.; Kim, Dong-Sang; Riley, Brian J.

2012-01-18T23:59:59.000Z

200

Iron Phosphate Glass-Containing Hanford Waste Simulant  

SciTech Connect

Resolution of the nation's high-level tank waste legacy requires the design, construction, and operation of large and technically complex one-of-a-kind processing waste treatment and vitrification facilities. While the ultimate limits for waste loading and melter efficiency have yet to be defined or realized, significant reductions in glass volumes for disposal and mission life may be possible with advancements in melter technologies and/or glass formulations. This test report describes the experimental results from a small-scale test using the research-scale melter (RSM) at Pacific Northwest National Laboratory (PNNL) to demonstrate the viability of iron-phosphate-based glass with a selected waste composition that is high in sulfate (4.37 wt% SO3). The primary objective of the test was to develop data to support a cost-benefit analysis related to the implementation of phosphate-based glasses for Hanford low-activity waste (LAW) and/or other high-level waste streams within the U.S. Department of Energy complex. The testing was performed by PNNL and supported by Idaho National Laboratory, Savannah River National Laboratory, Missouri University of Science and Technology, and Mo-Sci Corporation.

Sevigny, Gary J.; Kimura, Marcia L.; Fischer, Christopher M.; Schweiger, M. J.; Rodriguez, Carmen P.; Kim, Dong-Sang; Riley, Brian J.

2012-01-18T23:59:59.000Z

Note: This page contains sample records for the topic "zero-valent iron treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Iron isotopic fractionation during continental weathering  

SciTech Connect

The biological activity on continents and the oxygen content of the atmosphere determine the chemical pathways through which Fe is processed at the Earth's surface. Experiments have shown that the relevant chemical pathways fractionate Fe isotopes. Measurements of soils, streams, and deep-sea clay indicate that the {sup 56}Fe/{sup 54}Fe ratio ({delta}{sup 56}Fe relative to igneous rocks) varies from +1{per_thousand} for weathering residues like soils and clays, to -3{per_thousand} for dissolved Fe in streams. These measurements confirm that weathering processes produce substantial fractionation of Fe isotopes in the modern oxidizing Earth surface environment. The results imply that biologically-mediated processes, which preferentially mobilize light Fe isotopes, are critical to Fe chemistry in weathering environments, and that the {delta}{sup 56}Fe of marine dissolved Fe should be variable and negative. Diagenetic reduction of Fe in marine sediments may also be a significant component of the global Fe isotope cycle. Iron isotopes provide a tracer for the influence of biological activity and oxygen in weathering processes through Earth history. Iron isotopic fractionation during weathering may have been smaller or absent in an oxygen-poor environment such as that of the early Precambrian Earth.

Fantle, Matthew S.; DePaolo, Donald J.

2003-10-01T23:59:59.000Z

202

Field Projects: Monticello, Utah | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Long-Term Surveillance - Operations and Maintenance Long-Term Surveillance - Operations and Maintenance » Permeable Reactive Barriers » Field Projects: Monticello, Utah Field Projects: Monticello, Utah A permeable reactive barrier (PRB) of zero-valent iron is helping to clean up groundwater at a former uranium and vanadium ore processing mill at Monticello, Utah. LM managed remediation of tailings and tailings-contaminated material at this site. Cleanup of the mill site is regulated under the Comprehensive Environmental Response, Compensation, and Liability Act. Arsenic, molybdenum, nitrate, selenium, uranium, and vanadium are contaminants of concern in groundwater at the site. An Interim Record of Decision designated emplacement of a PRB hydraulically downgradient of the mill site to remove these contaminants. Results of both laboratory and

203

Beneficial Reuse at Bodo Canyon Site | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Services » Environmental Justice » Beneficial Reuse at Bodo Services » Environmental Justice » Beneficial Reuse at Bodo Canyon Site Beneficial Reuse at Bodo Canyon Site The George Washington University Environmental Resource Policy Graduate Program Capstone Project Beneficial Reuse at Bodo Canyon Site Feasibility and Community Support for Photovoltaic Array May 2012 The George Washington University Environmental Resource Policy Graduate Program Capstone Project was an analysis of LM's efforts to support the installation of a commercial solar photovoltaic system at the former uranium mill site near Durango, Colorado. Beneficial Reuse at Bodo Canyon Site More Documents & Publications EA-1770: Final Environmental Assessment Performance of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site

204

Publications  

NLE Websites -- All DOE Office Websites (Extended Search)

6 results: 6 results: BibTex RIS RTF XML Sort by: Author Title Type [ Year (Desc) ] Filters: Author is Donald Lucas [Clear All Filters] 2012 Holder, Amara L., Brietta J. Carter, Regine Goth-Goldstein, Donald Lucas, and Catherine P. Koshland. "Increased Cytotoxicity of Oxidized Flame Soot." Atmospheric Pollution Research 3, no. 1 (2012): 25-31. 2009 Keenan, Christina R., Regine Goth-Goldstein, Donald Lucas, and David L. Sedlak. "Oxidative Stress Induced by Zero-Valent Iron Nanoparticles and Fe(II) in Human Bronchial Epithelial Cells." Environmental Science & Technology 43, no. 12 (2009): 4555-4560. Singer, Brett C., Michael G. Apte, Douglas R. Black, Toshifumi Hotchi, Donald Lucas, Melissa M. Lunden, Anna G. Mirer, Michael Spears, and Douglas P. Sullivan. Natural Gas Variability in California: Environmental Impacts

205

Publications  

NLE Websites -- All DOE Office Websites (Extended Search)

3 results: 3 results: BibTex RIS RTF XML Sort by: Author Title Type [ Year (Desc) ] Filters: Author is Regine Goth-Goldstein [Clear All Filters] 2012 Holder, Amara L., Brietta J. Carter, Regine Goth-Goldstein, Donald Lucas, and Catherine P. Koshland. "Increased Cytotoxicity of Oxidized Flame Soot." Atmospheric Pollution Research 3, no. 1 (2012): 25-31. 2010 Goth-Goldstein, Regine, Marion L. Russell, Donghui Li, Ana P. Müller, Maira Caleffi, Joao Eschiletti, Marcia Graudenz, and Michael D. Sohn. Role of CYP1B1 in PAH-DNA Adduct Formation and Breast Cancer Risk. Berkeley: Lawrence Berkeley National Laboratory, 2010. 2009 Keenan, Christina R., Regine Goth-Goldstein, Donald Lucas, and David L. Sedlak. "Oxidative Stress Induced by Zero-Valent Iron Nanoparticles and

206

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

71 - 21880 of 28,905 results. 71 - 21880 of 28,905 results. Page Field Projects: Monticello, Utah A permeable reactive barrier (PRB) of zero-valent iron is helping to clean up groundwater at a former uranium and vanadium ore processing mill at Monticello, Utah. LM managed remediation of... http://energy.gov/lm/field-projects-monticello-utah Page Carbon Storage Monitoring, Verification and Accounting Research Reliable and cost-effective monitoring, verification and accounting (MVA) techniques are an important part of making geologic sequestration a safe, effective, and acceptable method for greenhouse... http://energy.gov/fe/science-innovation/carbon-capture-and-storage-research/carbon-storage-monitoring-verification-and Article Moab Marks 6-Million-Ton Cleanup Milestone MOAB, Utah - 6,000,000 is a big number, and it marks a significant

207

Electrochemical Deposition of Iron Nanoneedles on Titanium Oxide Nanotubes  

Science Conference Proceedings (OSTI)

Iron as a catalyst has wide applications for hydrogen generation from ammonia, photodecomposition of organics, and carbon nanotube growth. Tuning the size and shape of iron is meaningful for improving the catalysis efficiency. It is the objective of this work to prepare nanostructured iron with high surface area via electrochemical deposition. Iron nanoneedles were successfully electrodeposited on Ti supported TiO2 nanotube arrays in a chlorine-based electrolyte containing 0.15 M FeCl2 {center_dot} 4H2O and 2.0 M HCl. Transmission electron microscopic analysis reveals that the average length of the nanoneedles is about 200 nm and the thickness is about 10 nm. It has been found that a high overpotential at the cathode made of Ti/TiO2 nanotube arrays is necessary for the formation of the nanoneedles. Cyclic voltammetry test indicates that the electrodeposition of iron nanoneedles is a concentration-limited process.

Gan Y. X.; Zhang L.; Gan B.J.

2011-10-01T23:59:59.000Z

208

System and method for producing metallic iron nodules  

SciTech Connect

A method for producing metallic iron nodules by assembling a shielding entry system to introduce coarse carbonaceous material greater than 6 mesh in to the furnace atmosphere at location(s) where the temperature of the furnace atmosphere adjacent at least partially reduced reducible iron bearing material is between about 2200 and 2650.degree. F. (1200 and 1450.degree. C.), the shielding entry system adapted to inhibit emission of infrared radiation from the furnace atmosphere and seal the furnace atmosphere from exterior atmosphere while introducing coarse carbonaceous material greater than 6 mesh into the furnace to be distributed over the at least partially reduced reducible iron bearing material, and heating the covered at least partially reduced reducible iron bearing material in a fusion atmosphere to assist in fusion and inhibit reoxidation of the reduced material during fusion to assist in fusion and inhibit reoxidation of the reduced material in forming metallic iron nodules.

Bleifuss, Rodney L. (Grand Rapids, MN); Englund, David J. (Bovey, MN); Iwasaki, Iwao (Grand Rapids, MN); Lindgren, Andrew J. (Grand Rapids, MN); Kiesel, Richard F. (Hibbing, MN)

2011-09-20T23:59:59.000Z

209

ITP Mining: Energy and Environmental Profile of the U.S. Mining Industry: Chapter 4: Iron  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

4 4 Iron The chemical element iron is the fourth most common element in the Earth's crust and the second most abundant metal. About five percent of the Earth's crust is composed of iron. The metal is chemically active and is found in nature combined with other elements in rocks and soils. In its natural state, iron is chemically bonded with oxygen, water, carbon dioxide, or sulfur in a variety of minerals. Forms of Iron Minerals, Ores, and Rocks Iron occurs mainly in iron-oxide ores. Some ores are a mixture of minerals rich in iron. Other iron ores are less rich and have a large number of impurities. The most important iron ore- forming minerals are: * Magnetite - Magnetite (Fe 3 O 4 ) forms magnetic black iron ore. There are large deposits of

210

Waste Treatment  

Science Conference Proceedings (OSTI)

...rates, and batch collection volume requirements Water conservation possibilities What is required to meet discharge limits Availability and type of treatment chemicals How sludge will be dewatered, dried, and disposed...

211

Theoretical Investigation of Hydrogen Adsorption and dissociation on Iron and Iron Carbide Surfaces Using the ReaxFF Reactive Force Field Method  

SciTech Connect

We have developed a ReaxFF reactive force field to describe hydrogen adsorption and dissociation on iron and iron carbide surfaces relevant for simulation of FischerTropsch (FT) synthesis on iron catalysts. This force field enables large system (>>1000 atoms) simulations of hydrogen related reactions with iron. The ReaxFF force field parameters are trained against a substantial amount of structural and energetic data including the equations of state and heats of formation of iron and iron carbide related materials, as well as hydrogen interaction with iron surfaces and different phases of bulk iron. We have validated the accuracy and applicability of ReaxFF force field by carrying out molecular dynamics simulations of hydrogen adsorption, dissociation and recombination on iron and iron carbide surfaces. The barriers and reaction energies for molecular dissociation on these two types of surfaces have been compared and the effect of subsurface carbon on hydrogen interaction with iron surface is evaluated. We found that existence of carbon atoms at subsurface iron sites tends to increase the hydrogen dissociation energy barrier on the surface, and also makes the corresponding hydrogen dissociative state relatively more stable compared to that on bare iron. These properties of iron carbide will affect the dissociation rate of H{sub 2} and will retain more surface hydride species, thus influencing the dynamics of the FT synthesis process.

Zou, Chenyu; van Duin, Adri C.T.; Sorescu, Dan C.

2012-06-01T23:59:59.000Z

212

Multiple hearth furnace for reducing iron oxide  

SciTech Connect

A multiple moving hearth furnace (10) having a furnace housing (11) with at least two moving hearths (20) positioned laterally within the furnace housing, the hearths moving in opposite directions and each moving hearth (20) capable of being charged with at least one layer of iron oxide and carbon bearing material at one end, and being capable of discharging reduced material at the other end. A heat insulating partition (92) is positioned between adjacent moving hearths of at least portions of the conversion zones (13), and is capable of communicating gases between the atmospheres of the conversion zones of adjacent moving hearths. A drying/preheat zone (12), a conversion zone (13), and optionally a cooling zone (15) are sequentially positioned along each moving hearth (30) in the furnace housing (11).

Brandon, Mark M. (Charlotte, NC); True, Bradford G. (Charlotte, NC)

2012-03-13T23:59:59.000Z

213

System and method for producing metallic iron  

SciTech Connect

A hearth furnace 10 for producing metallic iron material has a furnace housing 11 having a drying/preheat zone 12, a conversion zone 13, a fusion zone 14, and optionally a cooling zone 15, the conversion zone 13 is between the drying/preheat zone 12 and the fusion zone 14. A moving hearth 20 is positioned within the furnace housing 11. A hood or separation barrier 30 within at least a portion of the conversion zone 13, fusion zone 14 or both separates the fusion zone 14 into an upper region and a lower region with the lower region adjacent the hearth 20 and the upper region adjacent the lower region and spaced from the hearth 20. An injector introduces a gaseous reductant into the lower region adjacent the hearth 20. A combustion region may be formed above the hood or separation barrier.

Bleifuss, Rodney L. (Grand Rapids, MN); Englund, David J. (Bovey, MN); Iwasaki, Iwao (Grand Rapids, MN); Fosnacht, Donald R. (Hermantown, MN); Brandon, Mark M. (Charlotte, NC); True, Bradford G. (Charlotte, NC)

2012-01-17T23:59:59.000Z

214

Iron aluminide alloy coatings and joints, and methods of forming  

DOE Patents (OSTI)

Disclosed is a method of joining two bodies together, at least one of the bodies being predominantly composed of metal, the two bodies each having a respective joint surface for joining with the joint surface of the other body, the two bodies having a respective melting point, includes the following steps: (a) providing aluminum metal and iron metal on at least one of the joint surfaces of the two bodies; (b) after providing the aluminum metal and iron metal on the one joint surface, positioning the joint surfaces of the two bodies in juxtaposition against one another with the aluminum and iron positioned therebetween; (c) heating the aluminum and iron on the juxtaposed bodies to a temperature from greater than or equal to 600 C to less than the melting point of the lower melting point body; (d) applying pressure on the juxtaposed surfaces; and (e) maintaining the pressure and the temperature for a time period effective to form the aluminum and iron into an iron aluminide alloy joint which bonds the juxtaposed surfaces and correspondingly the two bodies together. The method can also effectively be used to coat a body with an iron aluminide coating.

Wright, R.N.; Wright, J.K.; Moore, G.A.

1994-09-27T23:59:59.000Z

215

Iron aluminide alloy coatings and joints, and methods of forming  

DOE Patents (OSTI)

A method of joining two bodies together, at least one of the bodies being predominantly composed of metal, the two bodies each having a respective joint surface for joining with the joint surface of the other body, the two bodies having a respective melting point, includes the following steps: a) providing aluminum metal and iron metal on at least one of the joint surfaces of the two bodies; b) after providing the aluminum metal and iron metal on the one joint surface, positioning the joint surfaces of the two bodies in juxtaposition against one another with the aluminum and iron positioned therebetween; c) heating the aluminum and iron on the juxtaposed bodies to a temperature from greater than or equal to 600.degree. C. to less than the melting point of the lower melting point body; d) applying pressure on the juxtaposed surfaces; and e) maintaining the pressure and the temperature for a time period effective to form the aluminum and iron into an iron aluminide alloy joint which bonds the juxtaposed surfaces and correspondingly the two bodies together. The method can also effectively be used to coat a body with an iron aluminide coating.

Wright, Richard N. (Idaho Falls, ID); Wright, Julie K. (Idaho Falls, ID); Moore, Glenn A. (Idaho Falls, ID)

1994-01-01T23:59:59.000Z

216

TECHNOLOGY DEVELOPMENT FOR IRON AND COBALT FISCHER-TROPSCH CATALYSTS  

DOE Green Energy (OSTI)

The impact of activation procedure on the phase composition of precipitated iron Fischer-Tropsch (FT) catalysts has been studied. Catalyst samples taken during activation and FT synthesis have been characterized by Moessbauer spectroscopy. Formation of iron carbide is necessary for high FT activity. Hydrogen activation of precipitated iron catalysts results in reduction to predominantly metallic iron and Fe{sub 3}O{sub 4}. Metallic iron is not stable under FT 3 4 conditions and is rapidly converted to {epsilon}{prime}-Fe{sub 2.2}C. Activation with carbon monoxide or syngas 2.2 with low hydrogen partial pressure reduces catalysts to {chi}-Fe{sub 5}C{sub 2} and a small amount of 5 2 superparamagnetic carbide. Exposure to FT conditions partially oxidizes iron carbide to Fe{sub 3}O{sub 4}; however, catalysts promoted with potassium or potassium and copper maintain a constant carbide content and activity after the initial oxidation. An unpromoted iron catalyst which was activated with carbon monoxide to produce 94% {chi}-Fe{sub 5}C{sub 2}, deactivated rapidly as the carbide was oxidized to Fe{sub 3}O{sub 4}. No difference in activity, stability or deactivation rate was found for {chi}-Fe{sub 5}C{sub 2} and {epsilon}{prime}-Fe{sub 2.2}C.

Burtron H. Davis

1999-04-30T23:59:59.000Z

217

Erosion of white cast irons and stellite  

SciTech Connect

The erosion behavior of dual-phase alloys containing large, hard carbides has been investigated. A series of high Cr-Mo white cast irons with a systematic variation of carbide volume fraction (CVF) and powder metallurgy specimens of Stellite 6 were eroded with alumina, crushed quartz and rounded quartz particles. These erodents were chosen because quartz has a hardness between that of the matrix and the Cr-rich carbides, whereas the hardness of alumina is comparable to that of the carbides. In addition, comparison of the results with crushed quartz and alumina allows an evaluation of the effect of particle hardness while the differences between the rounded and crushed quartz results can be attributed to the shape difference. For all erodents and alloys, the dependence of erosion on angle of incidence was weak. With alumina and rounded quartz erodents, the erosion rate increased with increasing CVF, while the reverse was true with crushed quartz. The crushed quartz erodent gave an erosion rate only slightly lower than that of alumina, indicating that the carbide erosion resistance is not a strong function of erodent particle hardness in this range of hardness. Scanning electron microscope (SEM) observations of the eroded surfaces showed that erosion of the highest-CVF white cast iron alloy with alumina or rounded quartz resulted in depression of the large primary carbides, while with crushed quartz many of the carbides protruded above the matrix. The SEM and erosion rate observations show that with crushed quartz the carbides are more erosion resistant than the eutectic matrix and that the carbides therfore contribute to erosion resistance, while with the other erodents the reverse is true. 17 refs., 15 figs., 2 tabs.

Aptekar, S.S.; Kosel, T.H.

1985-01-01T23:59:59.000Z

218

The development of precipitated iron catalysts with improved stability  

DOE Green Energy (OSTI)

Precipitated iron catalysts are expected to be used in the next generation of slurry reactors for the large-scale production of transportation fuels from synthesis gas. These reactors may operate at higher temperatures and lower H {sub 2}: CO ratios relative to the Sasol Arge reactor. The feasibility of iron catalysts has been demonstrated under relatively mild Arge-type conditions but not under the more severe slurry conditions. The goal of this program is to identify the chemical principles governing the deactivation of precipitated iron catalysts during Fischer-Tropsch synthesis and to use these chemical principles in the design of catalysts suitable for slurry reactors.

Shah, P.P.

1990-01-01T23:59:59.000Z

219

Iron-carbon compacts and process for making them  

DOE Patents (OSTI)

The present invention includes iron-carbon compacts and a process for making them. The process includes preparing a slurry comprising iron powder, furfuryl alcohol, and a polymerization catalyst for initiating the polymerization of the furfuryl alcohol into a resin, and heating the slurry to convert the alcohol into the resin. The resulting mixture is pressed into a green body and heated to form the iron-carbon compact. The compact can be used as, or machined into, a magnetic flux concentrator for an induction heating apparatus.

Sheinberg, Haskell (Santa Fe, NM)

2000-01-01T23:59:59.000Z

220

Cast B2-phase iron-aluminum alloys with improved fluidity  

DOE Patents (OSTI)

Systems and methods are described for iron aluminum alloys. A composition includes iron, aluminum and manganese. A method includes providing an alloy including iron, aluminum and manganese; and processing the alloy. The systems and methods provide advantages because additions of manganese to iron aluminum alloys dramatically increase the fluidity of the alloys prior to solidification during casting.

Maziasz, Philip J. (122 Clark La., Oak Ridge, TN 37830); Paris, Alan M. (P.O. Box 64, Tarrs, PA 15688); Vought, Joseph D. (124 Cove Point Rd., Rockwood, TN 37854)

2002-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "zero-valent iron treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

DOE - Office of Legacy Management -- Knoxville Iron Co - TN 07  

Office of Legacy Management (LM)

Knoxville Iron Co - TN 07 Knoxville Iron Co - TN 07 FUSRAP Considered Sites Site: KNOXVILLE IRON CO. (TN.07 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Knoxville , Tennessee TN.07-1 Evaluation Year: 1994 TN.07-2 TN.07-3 Site Operations: Melted uranium contaminated scrap metal in order to test industrial hygiene procedures in the mid-1950s. TN.07-1 Site Disposition: Eliminated - AEC license TN.07-2 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Limited Quantities of Uranium Contained in Slag Material TN.07-4 Radiological Survey(s): Yes - health and safety monitoring during operations only TN.07-4 Site Status: Eliminated from consideration under FUSRAP Also see Documents Related to KNOXVILLE IRON CO.

222

The Iron Spin Transition in the Earth's Lower Mantle  

NLE Websites -- All DOE Office Websites (Extended Search)

The Iron Spin Transition in the The Iron Spin Transition in the Earth's Lower Mantle The Iron Spin Transition in the Earth's Lower Mantle Print Wednesday, 30 April 2008 00:00 It is now known that the iron present in minerals of the lower mantle of the Earth undergoes a pressure-induced transition with pairing of the spins of its 3d electrons. A team from the University of California, Berkeley, Tel Aviv University, and Lawrence Livermore National Laboratory has used x-ray diffraction at very high pressure to investigate the effects of this transition on the elastic properties of magnesiowüstite (Mg1-xFex)O, the second most abundant mineral in the Earth's lower mantle. The new results suggest that the effect of the spin-pairing transition on magnesiowüstite can be large enough to require a partial revision of the most accepted model of the lower mantle composition.

223

The industrial ecology of the iron casting industry  

E-Print Network (OSTI)

Metal casting is an energy and materials intensive manufacturing process, which is an important U.S. industry. This study analyzes iron casting, in particular, for possible improvements that will result in greater efficiencies ...

Jones, Alissa J. (Alissa Jean)

2007-01-01T23:59:59.000Z

224

Method and system for producing metallic iron nuggets  

Science Conference Proceedings (OSTI)

A method and system for producing metallic iron nuggets may include providing multiple layers of agglomerates, such as briquettes, balls and extrusions, of a reducible mixture of reducing material (such as carbonaceous material) and of a reducible iron bearing material (such as iron oxide) on a hearth material layer (such as carbonaceous material) and providing a coarse overlayer of carbonaceous material over at least some of the agglomerates. Heating the agglomerates of reducible mixture to 1425.degree. C. or 1400.degree. C. or 1375.degree. C. results in formation of an intermediate product of one or more metallic iron nuggets, which may have a sulfur content of less than 0.03%, and slag, which may have less than 5% mass MgO, which may have a ratio of percent by weight sulfur in the slag over percent by weight sulfur in the metallic nuggets of at least about 12 or at least about 15.

Iwasaki, Iwao; Kiesel, Richard F.; Englund, David J; Hendrickson, Dave

2012-12-18T23:59:59.000Z

225

LANSCE | Lujan Center | Highlights | Local iron displacements and  

NLE Websites -- All DOE Office Websites (Extended Search)

Local iron displacements and magnetoelastic coupling in a spin-ladder Local iron displacements and magnetoelastic coupling in a spin-ladder compound Hypothesis: Is magnetoelastic coupling in [FeX4]-based materials, an important ingredient in the emergence of superconductivity? Lujan Center: Combined Total Scattering and magnetic structure determination (HIPD-NPDF) The study of local, average and magnetic structure shows the existenceof highly correlated local iron (Fe) displacements in the spin-ladder iron chalcogenide BaFe2Se3. Built of ferromagnetic [Fe4] plaquettes, the magnetic ground state correlates with local displacements of the Fe atoms. Knowledge of these local displacements is essential for properly understanding the electronic structure of these systems. As with the copper oxide superconductors two decades ago, these

226

Percolation Explains How Earth's Iron Core Formed | Stanford Synchrotron  

NLE Websites -- All DOE Office Websites (Extended Search)

Percolation Explains How Earth's Iron Core Formed Percolation Explains How Earth's Iron Core Formed Wednesday, November 27, 2013 The formation of Earth's metallic core, which makes up a third of our planet's mass, represents the most significant differentiation event in Earth's history. Earth's present layered structure with a metallic core and an overlying silicate mantle would have required mechanisms to separate iron alloy from a silicate phase. Percolation of liquid iron alloy moving through a solid silicate matrix (much as water percolates through porous rock, or even coffee grinds) has been proposed as a possible model for core formation (Figure 1). Many previous experimental results have ruled out percolation as a major core formation mechanism for Earth at the relatively lower pressure conditions in the upper mantle, but until now experimental

227

Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers  

NLE Websites -- All DOE Office Websites (Extended Search)

Mixed Copper-Iron-Inert Support Oxygen Carriers Mixed Copper-Iron-Inert Support Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process Contact NETL Technology Transfer Group techtransfer@netl.doe.gov December 2012 This patent-pending technology, "Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process," provides a metal-oxide oxygen carrier for application in fuel combustion processes that use oxygen. This technology is available for licensing and/or further collaborative research with the U.S. Department of Energy's National Energy Technology Laboratory. Overview Patent Details U.S. Non-Provisional Patent Application No. 13/159,553; titled "Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers for Solid

228

Open Ocean Iron Fertilization for Scientific Study and Carbon Sequestration  

NLE Websites -- All DOE Office Websites (Extended Search)

Ocean Iron Fertilization for Scientific Study and Carbon Sequestration Ocean Iron Fertilization for Scientific Study and Carbon Sequestration K. Coale coale@mlml.calstate.edu (831) 632-4400 Moss Landing Marine Laboratories 8272 Moss Landing Road Moss Landing, California 95039 USA Abstract The trace element iron has been recently shown to play a critical role in nutrient utilization, phytoplankton growth and therefore the uptake of carbon dioxide from the surface waters of the global ocean. Carbon fixation in the surface waters, via phytoplankton growth, shifts the ocean/atmosphere exchange equilibrium for carbon dioxide. As a result, levels of atmospheric carbon dioxide (a greenhouse gas) and iron flux to the oceans have been linked to climate change (glacial to interglacial transitions). These recent findings have led some to suggest that large scale

229

Stability and Reactivity of Iron Sulfide Films in Sour Environments  

Science Conference Proceedings (OSTI)

Abstract Scope, Iron sulfide scales form on steels in the presence of H2S, notably in the extreme environments that exist in the oil and gas fields. Our research...

230

A BP neural network predictor model for desulfurizing molten iron  

Science Conference Proceedings (OSTI)

Desulfurization of molten iron is one of the stages of steel production process. A back-propagation (BP) artificial neural network (ANN) model is developed to predict the operation parameters for desulfurization process in this paper. The primary objective ...

Zhijun Rong; Binbin Dan; Jiangang Yi

2005-07-01T23:59:59.000Z

231

Synthesis of Monolithic Iron Incorporated Silica Aerogels by Ambient ...  

Science Conference Proceedings (OSTI)

With the Fe to Si molar ratio not exceeding 0.10, the bulk density of iron incorporated silica aerogels increased to 0.55g/cm3, while the porosity reduced to 76%...

232

Production of Molybdenum Containing Iron Based Alloys via ...  

Science Conference Proceedings (OSTI)

Chemical Enrichment of Precious Metals in Iron Sulfides Using Microwave Energy Chloridizing ... Co-Gasification Behavior of Metallurgical Coke with High and Low Reactivity .... Thermal Plasma Torches for Metallurgical Applications.

233

Reduction and Separation of High Iron Content Manganese Ore and ...  

Science Conference Proceedings (OSTI)

Chemical Enrichment of Precious Metals in Iron Sulfides Using Microwave Energy Chloridizing ... Co-Gasification Behavior of Metallurgical Coke with High and Low Reactivity .... Thermal Plasma Torches for Metallurgical Applications.

234

CFD Model Development for Gaseous Reduction of Iron Ore Fines ...  

Science Conference Proceedings (OSTI)

Chemical Enrichment of Precious Metals in Iron Sulfides Using Microwave Energy Chloridizing ... Co-Gasification Behavior of Metallurgical Coke with High and Low Reactivity .... Thermal Plasma Torches for Metallurgical Applications.

235

NOx Reduction by Sintering Flue Gas Circulation for Iron Ores  

Science Conference Proceedings (OSTI)

Chemical Enrichment of Precious Metals in Iron Sulfides Using Microwave Energy Chloridizing ... Co-Gasification Behavior of Metallurgical Coke with High and Low Reactivity .... Thermal Plasma Torches for Metallurgical Applications.

236

The relationship between iron and nitrogen fixation in Trichodesmium spp.  

E-Print Network (OSTI)

Trichodesmium spp. are considered the dominant nitrogen (N) fixing cyanobacteria in tropical and subtropical oceans, regimes frequently characterized by low iron (Fe). Limited information exists about what levels of Fe ...

Chappell, Phoebe Dreux

2009-01-01T23:59:59.000Z

237

Process for removing technetium from iron and other metals  

DOE Patents (OSTI)

A process for removing technetium from iron and other metals comprises the steps of converting the molten, alloyed technetium to a sulfide dissolved in manganese sulfide, and removing the sulfide from the molten metal as a slag. 4 figs.

Leitnaker, J.M.; Trowbridge, L.D.

1999-03-23T23:59:59.000Z

238

Process for removing technetium from iron and other metals  

DOE Patents (OSTI)

A process for removing technetium from iron and other metals comprises the steps of converting the molten, alloyed technetium to a sulfide dissolved in manganese sulfide, and removing the sulfide from the molten metal as a slag.

Leitnaker, James M. (Kingston, TN); Trowbridge, Lee D. (Oak Ridge, TN)

1999-01-01T23:59:59.000Z

239

Iron Cycling and Redox Evolution in the Precambrian  

E-Print Network (OSTI)

from neodymium isotopes. Journal of Geology 105, 121-129.iron isotope fractionation in nature. Geology 29, 699-702.from neodymium isotopes. Journal of Geology 105, 121-129.

Planavsky, Noah John

2012-01-01T23:59:59.000Z

240

Automatic control in the iron and steel industry  

Science Conference Proceedings (OSTI)

Basic iron and steel production processes, starting in the blast furnace and followed by steelmaking and rolling procedures, have not been altered greatly, although there have been modifying developments in individual processes, such as a basic oxygen ...

T. Isobe

1970-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "zero-valent iron treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Energy intensity in China's iron and steel sector  

E-Print Network (OSTI)

In this study, I examine the spatial and economic factors that influence energy intensity in China's iron and steel sector, namely industrial value added, renovation investment, coke consumption, and local coke supply. ...

Xu, Jingsi, M.C.P. Massachusetts Institute of Technology

2011-01-01T23:59:59.000Z

242

Polymer-coated iron oxide nanoparticles for medical imaging  

E-Print Network (OSTI)

One of the most versatile and safe materials used in medicine are polymer-coated iron oxide nanoparticles. This dissertation describes several formulations for in vivo imaging applications. The paramagnetic polymer-coated ...

Chen, Suelin, Ph.D. Massachusetts Institute of Technology

2010-01-01T23:59:59.000Z

243

Iron-oxide catalyzed silicon photoanode for water splitting  

E-Print Network (OSTI)

This thesis presents an integrated study of high efficiency photoanodes for water splitting using silicon and iron-oxide. The fundamental limitations of silicon to water splitting applications were overcome by an ultrathin ...

Jun, Kimin

2011-01-01T23:59:59.000Z

244

Progress report and technical evaluation of the ISCR pilot test conducted at the former CCC/USDA grain storage facility in Centralia, Kansas.  

Science Conference Proceedings (OSTI)

In October, 2007, the Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) presented the document Interim Measure Conceptual Design (Argonne 2007a) to the Kansas Department of Health and Environment, Bureau of Environmental Remediation (KDHE/BER), for a proposed non-emergency Interim Measure (IM) at the site of the former CCC/USDA grain storage facility in Centralia, Kansas (Figure 1.1). The IM was recommended to mitigate existing levels of carbon tetrachloride contamination identified in the vadose zone soils beneath the former facility and in the groundwater beneath and in the vicinity of the former facility, as well as to moderate or decrease the potential future concentrations of carbon tetrachloride in the groundwater. The Interim Measure Conceptual Design (Argonne 2007a) was developed in accordance with the KDHE/BER Policy No.BERRS-029, Policy and Scope of Work: Interim Measures (KDHE 1996). The hydrogeologic, geochemical, and contaminant distribution characteristics of the Centralia site, as identified by the CCC/USDA, factored into the development of the nonemergency IM proposal. These characteristics were summarized in the Interim Measure Conceptual Design (Argonne 2007a) and were discussed in detail in previous Argonne reports (Argonne 2002a, 2003, 2004, 2005a,b,c, 2006a,b, 2007b). The identified remedial goals of the proposed IM were as follows: (1) To reduce the existing concentrations of carbon tetrachloride in groundwater in three 'hot spot' areas identified at the site (at SB01, SB05, and SB12-MW02; Figure 1.2) to levels acceptable to the KDHE. (2) To reduce carbon tetrachloride concentrations in the soils near the location of former soil boring SB12 and existing monitoring well MW02 (Figure 1.2) to levels below the KDHE Tier 2 Risk-Based Screening Level (RBSL) of 200 {micro}g/kg for this contaminant. To address these goals, the potential application of an in situ chemical reduction (ISCR) treatment technology, employing the use of the EHC{reg_sign} treatment materials marketed by Adventus Americas, Inc. (Freeport, Illinois), was recommended. The EHC materials are proprietary mixtures of food-grade organic carbon and zero-valent iron that are injected into the subsurface as a slurry (EHC) or in dissolved form (EHC-A) and subsequently released slowly into the formation. The materials are designed to create highly reducing geochemical conditions in the vadose and saturated zones that foster both thermodynamic and biological reductive dechlorination of carbon tetrachloride.

LaFreniere, L. M.; Environmental Science Division

2009-01-14T23:59:59.000Z

245

Spectroscopic Equilibrium of Iron in Metal-Rich Dwarfs  

E-Print Network (OSTI)

We analyze twenty five nearby metal-rich G and late-F dwarfs in order to verify whether the spectroscopic equilibrium (LTE) of iron lines satisfy the observational constraints imposed by the Infrared Flux Method (angular diameters) and Hipparcos parallaxes. The atmospheric parameters derived from iron lines (assuming LTE and employing 1D Kurucz model atmospheres) do not satisfy simultaneously both observational constraints, probably because classical modeling fails to reproduce the detailed line formation of FeI lines.

Jorge Melendez; Ivan Ramirez

2004-09-14T23:59:59.000Z

246

Super-iron Nanoparticles with Facile Cathodic Charge Transfer  

Science Conference Proceedings (OSTI)

Super-irons contain the + 6 valence state of iron. One advantage of this is that it provides a multiple electron opportunity to store additional battery charge. A decrease of particle size from the micrometer to the nanometer domain provides a higher surface area to volume ratio, and opportunity to facilitate charge transfer, and improve the power, voltage and depth of discharge of cathodes made from such salts. However, super-iron salts are fragile, readily reduced to the ferric state, with both heat and contact with water, and little is known of the resultant passivating and non-passivating ferric oxide products. A pathway to decrease the super-iron particle size to the nano-domain is introduced, which overcomes this fragility, and retains the battery capacity advantage of their Fe(VI) valence state. Time and power controlled mechanosynthesis, through less aggressive, dry ball milling, leads to facile charge transfer of super-iron nanoparticles. Ex-situ X-ray Absorption Spectroscopy is used to explore the oxidation state and structure of these iron oxides during discharge and shows the significant change in stability of the ferrate structure to lower oxidation state when the particle size is in the nano-domain.

M Farmand; D Jiang; B Wang; S Ghosh; D Ramaker; S Licht

2011-12-31T23:59:59.000Z

247

Morphological development of oxide-sulfide scales on iron and iron-manganese alloys  

Science Conference Proceedings (OSTI)

Pure iron and alloys containing 2, 15, 25, and 50 wt.% manganese have been reacted at 1073 K in controlled gas atmospheres of SO/sub 2/-CO/sub 2/-CO-N/sub 2/. Equilibrium gas compositions were such that (1) FeS was stable but not FeO, or (2) both FeS and FeO were stable, or (3) FeO was stable but not FeS; in all cases, both MnS and MnO were stable. Under all reaction conditions, pure iron corroded to produce both sulfide and oxide. The resultant scale morphologies were consistent with local solid-gas equilibrium for the case in which both oxide and sulfide were stable but in the other cases indicated that equilibrium was not achieved and that direct reaction with SO/sub 2/(g) was responsible for corrosion. Additions of manganese did not greatly alter the scale morphologies. Under reaction conditions that were oxidizing and sulfidizing, very high levels of manganese were required to reduce the corrosion rate. On the other hand, relatively low levels had a beneficial effect both when FeO but not FeS was thermodynamically stable and similarly when FeS but not FeO was stable.

McAdam, G.; Young, D.J.

1987-10-01T23:59:59.000Z

248

Factors influencing biological treatment of MTBE contaminated ground water  

DOE Green Energy (OSTI)

Methyl tert-butyl ether (MTBE) contamination has complicated the remediation of gasoline contaminated sites. Many sites are using biological processes for ground water treatment and would like to apply the same technology to MTBE. However, the efficiency and reliability of MTBE biological treatment is not well documented. The objective of this study was to examine the operational and environmental variables influencing MTBE biotreatment. A fluidized bed reactor was installed at a fuel transfer station and used to treat ground water contaminated with MTBE and gasoline hydrocarbons. A complete set of chemical and operational data was collected during this study and a statistical approach was used to determine what variables were influencing MTBE treatment efficiency. It was found that MTBE treatment was more sensitive to up-set than gasoline hydrocarbon treatment. Events, such as excess iron accumulation, inhibited MTBE treatment, but not hydrocarbon treatment. Multiple regression analysis identified biomass accumulation and temperature as the most important variables controlling the efficiency of MTBE treatment. The influent concentration and loading of hydrocarbons, but not MTBE, also impacted MTBE treatment efficiency. The results of this study suggest guidelines for improving MTBE treatment. Long cell retention times in the reactor are necessary for maintaining MTBE treatment. The onset of nitrification only occurs when long cell retention times have been reached and can be used as an indicator in fixed film reactors that conditions favorable to MTBE treatment exist. Conversely, if the reactor can not nitrify, it is unlikely to have stable MTBE treatment.

Stringfellow, William T.; Hines Jr., Robert D.; Cockrum, Dirk K.; Kilkenny, Scott T.

2001-09-14T23:59:59.000Z

249

Overview on backfill materials and permeable reactive barriers for nuclear waste disposal facilities.  

SciTech Connect

A great deal of money and effort has been spent on environmental restoration during the past several decades. Significant progress has been made on improving air quality, cleaning up and preventing leaching from dumps and landfills, and improving surface water quality. However, significant challenges still exist in all of these areas. Among the more difficult and expensive environmental problems, and often the primary factor limiting closure of contaminated sites following surface restoration, is contamination of ground water. The most common technology used for remediating ground water is surface treatment where the water is pumped to the surface, treated and pumped back into the ground or released at a nearby river or lake. Although still useful for certain remediation scenarios, the limitations of pump-and-treat technologies have recently been recognized, along with the need for innovative solutions to ground-water contamination. Even with the current challenges we face there is a strong need to create geological repository systems for dispose of radioactive wastes containing long-lived radionuclides. The potential contamination of groundwater is a major factor in selection of a radioactive waste disposal site, design of the facility, future scenarios such as human intrusion into the repository and possible need for retrieving the radioactive material, and the use of backfills designed to keep the radionuclides immobile. One of the most promising technologies for remediation of contaminated sites and design of radioactive waste repositories is the use of permeable reactive barriers (PRBs). PRBs are constructed of reactive material(s) to intercept and remove the radionuclides from the water and decontaminate the plumes in situ. The concept of PRBs is relatively simple. The reactive material(s) is placed in the subsurface between the waste or contaminated area and the groundwater. Reactive materials used thus far in practice and research include zero valent iron, hydroxyapatite, magnesium oxide, and others. As the contaminant moves through the reactive material, the contaminant is either sorbed by the reactive material or chemically reacts with the material to form a less harmful substance. Because of the high risk associated with failure of a geological repository for nuclear waste, most nations favor a near-field multibarrier engineered system using backfill materials to prevent release of radionuclides into the surrounding groundwater.

Moore, Robert Charles; Hasan, Ahmed Ali Mohamed; Holt, Kathleen Caroline; Hasan, Mahmoud A. (Egyptian Atomic Energy Authority, Cairo, Egypt)

2003-10-01T23:59:59.000Z

250

Microstructural Characterization of Nodular Ductile Iron  

SciTech Connect

The objective of this study is to quantify the graphite particle phase in nodular ductile iron (NDI). This study provides the basis for initializing microstructure in direct numerical simulations, as part of developing microstructure-fracture response models. The work presented here is a subset of a PhD dissertation on spall fracture in NDI. NDI is an ideal material for studying the influence of microstructure on ductile fracture because it contains a readily identifiable second-phase particle population, embedded in a ductile metallic matrix, which serves as primary void nucleation sites. Nucleated voids grow and coalesce under continued tensile loading, as part of the micromechanisms of ductile fracture, and lead to macroscopic failure. For this study, we used 2D optical microscopy and quantitative metallography relationships to characterize the volume fraction, size distribution, nearest-neighbor distance, and other higher-order metrics of the graphite particle phase. We found that the volume fraction was {Phi} = 0.115, the average particle diameter was d{sub avg} = 25.9 {mu}m, the Weibull shape and scaling parameters were {beta} = 1.8 and {eta} = 29.1 {mu}m, respectively, the (first) nearest neighbor distance was L{sub nn} = 32.4 {mu}m, the exponential coefficients for volume fraction fluctuations was A{sub {Phi}} = 1.89 and B{sub {Phi}} = -0.59, respectively. Based on reaching a coefficient-of-variation (COV) of 0.01, the representative volume element (RVE) size was determined to be 8.9L{sub nn} (288 {mu}m).

Springer, H K

2012-01-03T23:59:59.000Z

251

Insights into the Structure and Metabolic Function of Microbes That Shape Pelagic Iron-Rich Aggregates ( Iron Snow )  

SciTech Connect

Metaproteomics combined with total nucleic acid-based methods aided in deciphering the roles of microorganisms in the formation and transformation of iron-rich macroscopic aggregates (iron snow) formed in the redoxcline of an acidic lignite mine lake. Iron snow had high total bacterial 16S rRNA gene copies, with 2 x 109 copies g (dry wt)-1 in the acidic (pH 3.5) central lake basin and 4 x 1010 copies g (dry wt)-1 in the less acidic (pH 5.5) northern lake basin. Active microbial communities in the central basin were dominated by Alphaproteobacteria (36.6%) and Actinobacteria (21.4%), and by Betaproteobacteria (36.2%) in the northern basin. Microbial Fe-cycling appeared to be the dominant metabolism in the schwertmannite-rich iron snow, because cloning and qPCR assigned up to 61% of active bacteria as Fe-cycling bacteria (FeB). Metaproteomics revealed 70 unique proteins from central basin iron snow and 283 unique proteins from 43 genera from northern basin. Protein identification provided a glimpse into in situ processes, such as primary production, motility, metabolism of acidophilic FeB, and survival strategies of neutrophilic FeB. Expression of carboxysome shell proteins and RubisCO indicated active CO2 fixation by Fe(II) oxidizers. Flagellar proteins from heterotrophs indicated their activity to reach and attach surfaces. Gas vesicle proteins related to CO2-fixing Chlorobium suggested that microbes could influence iron snow sinking. We suggest that iron snow formed by autotrophs in the redoxcline acts as a microbial parachute, since it is colonized by motile heterotrophs during sinking which start to dissolve schwertmannite.

Lu, S [Friedrich Schiller University Jena, Jena Germany; Chourey, Karuna [ORNL; REICHE, M [Friedrich Schiller University Jena, Jena Germany; Nietzsche, S [Friedrich Schiller University Jena, Jena Germany; Shah, Manesh B [ORNL; Hettich, Robert {Bob} L [ORNL; Kusel, K [Friedrich Schiller University Jena, Jena Germany

2013-01-01T23:59:59.000Z

252

Assessment of Energy Efficiency Improvement and CO2 Emission Reduction Potentials in the Iron and Steel Industry in China  

E-Print Network (OSTI)

Potentials in the Iron and steel Industry in China. Reportfor the U.S. Iron and Steel Industry. An ENERGY STAR Guidein the U.S. Iron and Steel Industry. Report LBNL-41724.

Hasanbeigi, Ali

2013-01-01T23:59:59.000Z

253

Energy Efficiency Improvement and Cost Saving Opportunities for the U.S. Iron and Steel Industry An ENERGY STAR(R) Guide for Energy and Plant Managers  

E-Print Network (OSTI)

scrap steel, pig iron, or direct reduced iron (DRI) using anthe production of direct reduced iron (DRI). DRI is producedDirect current Direct reduced iron Electric arc furnace

Worrell, Ernst

2011-01-01T23:59:59.000Z

254

The Iron Spin Transition in the Earth's Lower Mantle  

NLE Websites -- All DOE Office Websites (Extended Search)

The Iron Spin Transition in the Earth's Lower Mantle Print The Iron Spin Transition in the Earth's Lower Mantle Print It is now known that the iron present in minerals of the lower mantle of the Earth undergoes a pressure-induced transition with pairing of the spins of its 3d electrons. A team from the University of California, Berkeley, Tel Aviv University, and Lawrence Livermore National Laboratory has used x-ray diffraction at very high pressure to investigate the effects of this transition on the elastic properties of magnesiowüstite (Mg1-xFex)O, the second most abundant mineral in the Earth's lower mantle. The new results suggest that the effect of the spin-pairing transition on magnesiowüstite can be large enough to require a partial revision of the most accepted model of the lower mantle composition.

255

The Iron Spin Transition in the Earth's Lower Mantle  

NLE Websites -- All DOE Office Websites (Extended Search)

The Iron Spin Transition in the Earth's Lower Mantle Print The Iron Spin Transition in the Earth's Lower Mantle Print It is now known that the iron present in minerals of the lower mantle of the Earth undergoes a pressure-induced transition with pairing of the spins of its 3d electrons. A team from the University of California, Berkeley, Tel Aviv University, and Lawrence Livermore National Laboratory has used x-ray diffraction at very high pressure to investigate the effects of this transition on the elastic properties of magnesiowüstite (Mg1-xFex)O, the second most abundant mineral in the Earth's lower mantle. The new results suggest that the effect of the spin-pairing transition on magnesiowüstite can be large enough to require a partial revision of the most accepted model of the lower mantle composition.

256

The Iron Spin Transition in the Earth's Lower Mantle  

NLE Websites -- All DOE Office Websites (Extended Search)

The Iron Spin Transition in the Earth's Lower Mantle Print The Iron Spin Transition in the Earth's Lower Mantle Print It is now known that the iron present in minerals of the lower mantle of the Earth undergoes a pressure-induced transition with pairing of the spins of its 3d electrons. A team from the University of California, Berkeley, Tel Aviv University, and Lawrence Livermore National Laboratory has used x-ray diffraction at very high pressure to investigate the effects of this transition on the elastic properties of magnesiowüstite (Mg1-xFex)O, the second most abundant mineral in the Earth's lower mantle. The new results suggest that the effect of the spin-pairing transition on magnesiowüstite can be large enough to require a partial revision of the most accepted model of the lower mantle composition.

257

Mechanical Characterization of Nodular Ductile Iron  

SciTech Connect

The objective of this study is to characterize the strength and fracture response of nodular ductile iron (NDI) and its underlying ferritic matrix phase. Quasistatic and split Hopkinson pressure bar (SHPB) compression tests were performed on NDI and a model material for the NDI matrix phase (Fe-Si alloy). Smooth and notch round bar (NRB) samples were loaded in tension until fracture to determine strain-at-failure with varying stress triaxiality. Multiple tests were performed on each small and large smooth bar samples to obtain fracture statistics with sample size. Fracture statistics are important for initializing simulations of fragmentation events. Johnson-Cook strength models were developed for the NDI and the Fe-Si alloy. NDI strength model parameters are: A = 525 MPa, B = 650 MPa, n = 0.6, and C = 0.0205. The average SHPB experimental strain-rate of 2312/s was used for the reference strain-rate in this model. Fe-Si alloy strength model parameters are: A=560 MPa, B = 625 MPa, n = 0.5, and C = 0.02. The average SHPB experimental strain-rate of 2850/s was used for the reference strain-rate in this model. A Johnson-Cook failure model was developed for NDI with model parameters: D{sub 1} = 0.029, D{sub 2} = 0.44, D{sub 3} = -1.5, and D{sub 4} = D{sub 5} = 0. An exponential relationship was developed for the elongation-at-failure statistics as a function of length-scale with model parameters: S{sub f1} = 0.108, S{sub f2} = -0.00169, and L{sub m} = 32.4 {mu}m. NDI strength and failure models, including failure statistics, will be used in continuum-scale simulations of explosively-driven ring fragmentation. The Fe-Si alloy strength model will be used in mesoscale simulations of spall fracture in NDI, where the NDI matrix phase is captured explicitly.

Springer, H K

2012-01-03T23:59:59.000Z

258

Gas Diffusion in Metals: Fundamental Study of Helium-Point Defect Interactions in Iron and Kinetics of Hydrogen Desorption from Zirconium Hydride  

E-Print Network (OSTI)

Steel irradiated in HFIR, as reproduced from Ref. [irons placed in HFIR. .. 97 Table 6-iron in HFIR. .. 102

Hu, Xunxiang

2013-01-01T23:59:59.000Z

259

Assessment of Energy Efficiency Improvement and CO2 Emission Reduction Potentials in the Iron and Steel Industry in China  

E-Print Network (OSTI)

electricity and fuel prices differ between industries andelectricity and fuel efficiency improvements in the iron and steel industryprice of electricity paid by the iron and steel industry in

Hasanbeigi, Ali

2013-01-01T23:59:59.000Z

260

Characterization of temperature profile in furnace and solubility of iron in silicon  

E-Print Network (OSTI)

A better understanding of the behavior of impurities, such as iron, in silicon can lead to increases in solar cell efficiency. The purpose of this thesis was to study the behavior of iron in silicon via three sub-tasks: ...

Modi, Vrajesh Y

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "zero-valent iron treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

V-021: Cisco IronPort Web / Email Security Appliance Sophos Anti...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

1: Cisco IronPort Web Email Security Appliance Sophos Anti-Virus Multiple Vulnerabilities V-021: Cisco IronPort Web Email Security Appliance Sophos Anti-Virus Multiple...

262

Interactions of Fe(II) with the iron oxidizing bacterium Rhodopseudomonas palustris TIE-1  

E-Print Network (OSTI)

Microbial anaerobic iron oxidation has long been of interest to biologists and geologists, both as a possible mechanism for the creation of banded iron formations before the rise of oxygen, and as a model system for organisms ...

Bird, Lina J. (Lina Joana)

2013-01-01T23:59:59.000Z

263

New trends in industrial energy efficiency in the Mexico iron and steel industry  

E-Print Network (OSTI)

de Ingeniera, U N A M . , Mexico Energy Analysis Program atIndustrial Energy Efficiency in the Mexico: Iron and Steelenergy consumption of the iron and steel industry is the feedstock. In Mexico,

Ozawa, Leticia; Martin, Nathan; Worrell, Ernst; Price, Lynn; Sheinbaum, Claudia

1999-01-01T23:59:59.000Z

264

Arsenic remediation of drinking water using iron-oxide coated coal bottom  

NLE Websites -- All DOE Office Websites (Extended Search)

Arsenic remediation of drinking water using iron-oxide coated coal bottom Arsenic remediation of drinking water using iron-oxide coated coal bottom ash Title Arsenic remediation of drinking water using iron-oxide coated coal bottom ash Publication Type Journal Article Year of Publication 2010 Authors Mathieu, Johanna L., Ashok J. Gadgil, Susan E. Addy, and Kristin Kowolik Journal Environmental Science and Health Keywords airflow and pollutant transport group, arsenic, bangladesh, coal bottom ash, drinking water, indoor environment department, water contaminants, water treatment Abstract We describe laboratory and field results of a novel arsenic removal adsorbent called 'Arsenic Removal Using Bottom Ash' (ARUBA). ARUBA is prepared by coating particles of coal bottom ash, a waste material from coal fired power plants, with iron (hydr)oxide. The coating process is simple and conducted at room temperature and atmospheric pressure. Material costs for ARUBA are estimated to be low (~$0.08 per kg) and arsenic remediation with ARUBA has the potential to be affordable to resource-constrained communities. ARUBA is used for removing arsenic via a dispersal-and-removal process, and we envision that ARUBA would be used in community-scale water treatment centers. We show that ARUBA is able to reduce arsenic concentrations in contaminated Bangladesh groundwater to below the Bangladesh standard of 50 ppb. Using the Langmuir isotherm (R2 = 0.77) ARUBA's adsorption capacity in treating real groundwater is 2.6×10-6 mol/g (0.20 mg/g). Time-to-90% (defined as the time interval for ARUBA to remove 90% of the total amount of arsenic that is removed at equilibrium) is less than one hour. Reaction rates (pseudo-second-order kinetic model, R2 ≥ 0.99) increase from 2.4×105 to 7.2×105 g mol-1 min-1 as the groundwater arsenic concentration decreases from 560 to 170 ppb. We show that ARUBA's arsenic adsorption density (AAD), defined as the milligrams of arsenic removed at equilibrium per gram of ARUBA added, is linearly dependent on the initial arsenic concentration of the groundwater sample, for initial arsenic concentrations of up to 1600 ppb and an ARUBA dose of 4.0 g/L. This makes it easy to determine the amount of ARUBA required to treat a groundwater source when its arsenic concentration is known and less than 1600 ppb. Storing contaminated groundwater for two to three days before treatment is seen to significantly increase ARUBA's AAD. ARUBA can be separated from treated water by coagulation and clarification, which is expected to be less expensive than filtration of micron-scale particles, further contributing to the affordability of a community-scale water treatment center

265

Laboratory evaluations of iron-based hard-facing alloys: A European study: Final report  

SciTech Connect

In order to identify suitable alternative materials for cobalt-base alloys used as hardfacing material for nuclear valves, three corrosion and wear-resistant iron-base alloys were investigated. In detail, comparisons were performed between Everit 50, Antinit DUR 300, Cenium Z 20 and Stellite 6 as to metallurgy, manufacturing properties, corrosive properties in simulated PWR and BWR coolant ( under no-flow and high-flow conditions with and without contamination), tribological properties (at different temperatures, contact pressure levels and for different material combinations) and mechanical properties. Data are given on suitable heat treatment, welding parameters and areas of application for each alloy under consideration. 24 refs., 87 figs., 4 tabs.

Hofmann, P.J.; Friedrich, B.C.

1988-06-01T23:59:59.000Z

266

Recovery of iron oxide from coal fly ash  

DOE Patents (OSTI)

A high quality iron oxide concentrate, suitable as a feed for blast and electric reduction furnaces is recovered from pulverized coal fly ash. The magnetic portion of the fly ash is separated and treated with a hot strong alkali solution which dissolves most of the silica and alumina in the fly ash, leaving a solid residue and forming a precipitate which is an acid soluble salt of aluminosilicate hydrate. The residue and precipitate are then treated with a strong mineral acid to dissolve the precipitate leaving a solid residue containing at least 90 weight percent iron oxide.

Dobbins, Michael S. (Ames, IA); Murtha, Marlyn J. (Ames, IA)

1983-05-31T23:59:59.000Z

267

Electrolytic photodissociation of chemical compounds by iron oxide photochemical diodes  

DOE Patents (OSTI)

Chemical compounds can be dissociated by contacting the same with a p/n type semi-conductor photochemical diode having visible light as its sole source of energy. The photochemical diode consists of low cost, readily available materials, specifically polycrystalline iron oxide doped with silicon in the case of the n-type semi-conductor electrode, and polycrystalline iron oxide doped with magnesium in the case of the p-type electrode. So long as the light source has an energy greater than 2.2 electron volts, no added energy source is needed to achieve dissociation.

Somorjai, Gabor A. (Berkeley, CA); Leygraf, Christofer H. (Berkeley, CA)

1985-01-01T23:59:59.000Z

268

Electrolytic photodissociation of chemical compounds by iron oxide electrodes  

DOE Patents (OSTI)

Chemical compounds can be dissociated by contacting the same with a p/n type semi-conductor diode having visible light as its sole source of energy. The diode consists of low cost, readily available materials, specifically polycrystalline iron oxide doped with silicon in the case of the n-type semi-conductor electrode, and polycrystalline iron oxide doped with magnesium in the case of the p-type electrode. So long as the light source has an energy greater than 2.2 electron volts, no added energy source is needed to achieve dissociation.

Somorjai, Gabor A. (Berkeley, CA); Leygraf, Christofer H. (Berkeley, CA)

1984-01-01T23:59:59.000Z

269

MECHANICAL ALLOYING AND THERMAL TREATMENT FOR PRODUCTION OF ZIRCONIUM IRON HYDROGEN ISOTOPE GETTERS  

DOE Green Energy (OSTI)

The objective of this task was to demonstrate that metal hydrides could be produced by mechanical alloying in the quantities needed to support production-scale hydrogen isotope separations. Three starting compositions (ratios of elemental Zr and Fe powders) were selected and attritor milled under argon for times of 8 to 60 hours. In general, milling times of at least 24 hours were required to form the desired Zr{sub 2}Fe and Zr{sub 3}Fe phases, although a considerable amount of unalloyed Zr and Fe remained. Milling in liquid nitrogen does not appear to provide any advantages over milling in hexane, particularly due to the formation of ZrN after longer milling times. Carbides of Zr formed during some of the milling experiments in hexane. Elemental Zr was present in the as-milled material but not detected after annealing for milling times of 48 and 60 hours. It may be that after intimate mixing of the powders in the attritor mill the annealing temperature was sufficient to allow for the formation of a Zr-Fe alloy. Further investigation of this conversion is necessary, and could provide an opportunity for reducing the amount of unreacted metal powder after milling.

Fox, K.

2008-02-20T23:59:59.000Z

270

A modeling approach for iron concentration in sand filtration effluent using adaptive neuro-fuzzy model  

Science Conference Proceedings (OSTI)

Effluent iron concentration is an important water quality criterion used for the assessment of the performance of rapid sand filters, in addition to other criteria. This study deals with the prediction of effluent iron concentrations by adaptive neuro-fuzzy ... Keywords: ANFIS, Effluent iron concentration, Modeling, Sand filtration

Mehmet akmakci; Cumali Kinaci; Mahmut Bayramo?lu; Y?lmaz Yildirim

2010-03-01T23:59:59.000Z

271

Porous iron and ferric oxide pellets for hydrogen storage: texture and transport characteristics  

Science Conference Proceedings (OSTI)

Materials for hydrogen storage based on the recovery reduction of Fe3O4 to iron and back iron oxidation to Fe3O4 by water vapor were studied. The preparation conditions for cylindrical pellets from ferric oxide/aluminium ... Keywords: hydrogen storage, inverse gas chromatography, steam iron process, transport parameters

Karel Soukup; Jan Rogut; Jacek Grabowski; Marian Wiatowski; Magdalena Ludwik-Parda?a; Petr Schneider; Olga olcov

2010-11-01T23:59:59.000Z

272

Abundance Analysis of Planetary Host Stars I. Differential Iron Abundances  

E-Print Network (OSTI)

We present atmospheric parameters and iron abundances derived from high-resolution spectra for three samples of dwarf stars: stars which are known to host close-in giant planets (CGP), stars for which radial velocity data exclude the presence of a close-in giant planetary companion (no-CGP), as well as a random sample of dwarfs with a spectral type and magnitude distribution similar to that of the planetary host stars (control). All stars have been observed with the same instrument and have been analyzed using the same model atmospheres, atomic data and equivalent width modeling program. Abundances have been derived differentially to the Sun, using a solar spectrum obtained with Callisto as the reflector with the same instrumentation. We find that the iron abundances of CGP dwarfs are on average by 0.22 dex greater than that of no-CGP dwarfs. The iron abundance distributions of both the CGP and no-CGP dwarfs are different than that of the control dwarfs, while the combined iron abundances have a distribution which is very similar to that of the control dwarfs. All four samples (CGP, no-CGP, combined, control) have different effective temperature distributions. We show that metal enrichment occurs only for CGP dwarfs with temperatures just below solar and approximately 300 K higher than solar, whereas the abundance difference is insignificant at Teff around 6000 K.

U. Heiter; R. E. Luck

2003-07-16T23:59:59.000Z

273

Survey of Iron and Nickel Concentrations in PWR Primary Coolant  

Science Conference Proceedings (OSTI)

The concentrations of iron and nickel corrosion products in primary coolant water were measured at eleven different pressurized water reactors. Two reactors experienced anomalies in the axial power distribution during the cycles that were sampled. The axial power distribution anomalies appeared to be associated with high-coolant nickel concentrations early in the fuel cycle.

2001-07-27T23:59:59.000Z

274

Oxide Dispersion Strengthened Iron Aluminide by CVD Coated Powders  

SciTech Connect

This I &I Category2 program developed chemical vapor deposition (CVD) of iron, aluminum and aluminum oxide coated iron powders and the availability of high temperature oxidation, corrosion and erosion resistant coating for future power generation equipment and can be used for retrofitting existing fossil-fired power plant equipment. This coating will provide enhanced life and performance of Coal-Fired Boilers components such as fire side corrosion on the outer diameter (OD) of the water wall and superheater tubing as well as on the inner diameter (ID) and OD of larger diameter headers. The program also developed a manufacturing route for readily available thermal spray powders for iron aluminide coating and fabrication of net shape component by powder metallurgy route using this CVD coated powders. This coating can also be applid on jet engine compressor blade and housing, industrial heat treating furnace fixtures, magnetic electronic parts, heating element, piping and tubing for fossil energy application and automotive application, chemical processing equipment , heat exchanger, and structural member of aircraft. The program also resulted in developing a new fabrication route of thermal spray coating and oxide dispersion strengthened (ODS) iron aluminide composites enabling more precise control over material microstructures.

Asit Biswas Andrew J. Sherman

2006-09-25T23:59:59.000Z

275

Radiofrequency characterization of polydimethylsiloxane - iron oxide based nanocomposites  

Science Conference Proceedings (OSTI)

Colloidal iron oxide nanoparticles with diameters ranging from 15+/-1nm up to 29+/-3nm are used as pure dielectric fillers for nanoparticles-doped nanocomposites. We show that their superparamagnetic behavior allows them to increase the real dielectric ... Keywords: Magnetic nanoparticles, Nanocomposite, Polydimethylsiloxane, Radiofrequency

Ferruccio Pisanello, Rosa De Paolis, Daniela Lorenzo, Simone Nitti, Giuseppina Monti, Despina Fragouli, Athanassia Athanassiou, Liberato Manna, Luciano Tarricone, Massimo De Vittorio, Luigi Martiradonna

2013-11-01T23:59:59.000Z

276

Iron Biomineralization: Implications on the Fate of Arsenic in Landfills  

E-Print Network (OSTI)

these arsenic-bearing solid residuals (ABSR) pass the Toxicity Characteristic Leaching Procedure (TCLP in our laboratory as well as other labs, has shown that the TCLP greatly underestimates the ABSR leaching concentrations of As. Iron reduction led to arsenic release into solution, where arsenic was reduced. #12;Figure

Cushing, Jim. M.

277

Iron Aerogel and Xerogel Catalysts for Fischer-Tropsch Synthesis of Diesel Fuel  

SciTech Connect

Iron aerogels, potassium-doped iron aerogels, and potassium-doped iron xerogels have been synthesized and characterized and their catalytic activity in the Fischer-Tropsch (F-T) reaction has been studied. Iron aerogels and xerogels were synthesized by polycondensation of an ethanolic solution of iron(III) chloride hexahydrate with propylene oxide which acts as a proton scavenger for the initiation of hydrolysis and polycondensation. Potassium was incorporated in the iron aerogel and iron xerogel by adding aqueous K{sub 2}CO{sub 3} to the ethanolic solutions of the Fe(III) precursor prior to addition of propylene oxide. Fischer-Tropsch activities of the catalysts were tested in a fixed bed reactor at a pressure of 100 psi with a H{sub 2}:CO ratio of 2:1. Iron aerogels were found to be active for F-T synthesis, and their F-T activities increased on addition of a K containing promoter. Moessbauer spectroscopic data are consistent with an open, nonrigid iron(III) aerogel structure progressing to an iron carbide/metallic iron catalyst via agglomeration as the F-T synthesis proceeds in the course of a 35 h fixed bed reaction test.

Bali, S.; Huggins, F; Huffman, G; Ernst, R; Pugmire, R; Eyring, E

2009-01-01T23:59:59.000Z

278

V-021: Cisco IronPort Web / Email Security Appliance Sophos Anti-Virus  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

21: Cisco IronPort Web / Email Security Appliance Sophos 21: Cisco IronPort Web / Email Security Appliance Sophos Anti-Virus Multiple Vulnerabilities V-021: Cisco IronPort Web / Email Security Appliance Sophos Anti-Virus Multiple Vulnerabilities November 12, 2012 - 6:00am Addthis PROBLEM: Cisco IronPort Web / Email Security Appliance Sophos Anti-Virus Multiple Vulnerabilities PLATFORM: Cisco IronPort Email Security Appliances (C-Series and X-Series) running Sophos Engine versions 3.2.07.352_4.80 and prior. Cisco IronPort Web Security Appliances (S-Series) running Sophos Engine versions 3.2.07.352_4.80 and prior. ABSTRACT: Cisco Ironport Appliances Sophos Anti-Virus Vulnerabilities. REFERENCE LINKS: Cisco Security Advisory ID: cisco-sa-20121108-sophos Secunia Advisory SA51197 IMPACT ASSESSMENT: High DISCUSSION: Cisco has acknowledged some vulnerabilities in Cisco IronPort Web Security

279

V-021: Cisco IronPort Web / Email Security Appliance Sophos Anti-Virus  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

1: Cisco IronPort Web / Email Security Appliance Sophos 1: Cisco IronPort Web / Email Security Appliance Sophos Anti-Virus Multiple Vulnerabilities V-021: Cisco IronPort Web / Email Security Appliance Sophos Anti-Virus Multiple Vulnerabilities November 12, 2012 - 6:00am Addthis PROBLEM: Cisco IronPort Web / Email Security Appliance Sophos Anti-Virus Multiple Vulnerabilities PLATFORM: Cisco IronPort Email Security Appliances (C-Series and X-Series) running Sophos Engine versions 3.2.07.352_4.80 and prior. Cisco IronPort Web Security Appliances (S-Series) running Sophos Engine versions 3.2.07.352_4.80 and prior. ABSTRACT: Cisco Ironport Appliances Sophos Anti-Virus Vulnerabilities. REFERENCE LINKS: Cisco Security Advisory ID: cisco-sa-20121108-sophos Secunia Advisory SA51197 IMPACT ASSESSMENT: High DISCUSSION: Cisco has acknowledged some vulnerabilities in Cisco IronPort Web Security

280

Use of bimodal carbon distribution in compacts for producing metallic iron nodules  

SciTech Connect

A method for use in production of metallic iron nodules comprising providing a reducible mixture into a hearth furnace for the production of metallic iron nodules, where the reducible mixture comprises a quantity of reducible iron bearing material, a quantity of first carbonaceous reducing material of a size less than about 28 mesh of an amount between about 65 percent and about 95 percent of a stoichiometric amount necessary for complete iron reduction of the reducible iron bearing material, and a quantity of second carbonaceous reducing material with an average particle size greater than average particle size of the first carbonaceous reducing material and a size between about 3 mesh and about 48 mesh of an amount between about 20 percent and about 60 percent of a stoichiometric amount of necessary for complete iron reduction of the reducible iron bearing material.

Iwasaki, Iwao

2012-10-16T23:59:59.000Z

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281

Parkers-Iron Springs, Arkansas: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

Parkers-Iron Springs, Arkansas: Energy Resources Parkers-Iron Springs, Arkansas: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 34.6081427°, -92.3320235° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":34.6081427,"lon":-92.3320235,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

282

What's in the Cage Matters in Iron Antimonide Thermoelectric Materials |  

NLE Websites -- All DOE Office Websites (Extended Search)

Novel Experiments on Cement Yield Concrete Results Novel Experiments on Cement Yield Concrete Results Watching a Glycine Riboswitch "Switch" Polyamorphism in a Metallic Glass Under Pressure, Vanadium Won't Turn Down the Volume New Nanoscale Engineering Breakthrough Points to Hydrogen-Powered Vehicles Science Highlights Archives: 2013 | 2012 | 2011 | 2010 2009 | 2008 | 2007 | 2006 2005 | 2004 | 2003 | 2002 2001 | 2000 | 1998 | Subscribe to APS Science Highlights rss feed What's in the Cage Matters in Iron Antimonide Thermoelectric Materials MARCH 29, 2007 Bookmark and Share Crystal structure of EuFe4Sb12 showing the cage confined Eu atoms (red) and Fe atoms (brown) surrounded by Sb tilted octahedral (Sb atoms are not shown). Thermoelectric materials such as iron antimonide have drawn intense interest because they offer a pollution-free source of electricity and a

283

NETL: News Release - Clean Coal Technology Report Showcases Advanced Iron  

NLE Websites -- All DOE Office Websites (Extended Search)

April 6, 2000 April 6, 2000 Clean Coal Technology Report Showcases Advanced Iron Making Process, Benefits for the Environment Topical Report Profiles Blast Furnace Granular Coal Injection System; Now Available on DOE's Fossil Energy Web Site An advanced iron making technology demonstrated in the U.S. Department of Energy's Clean Coal Technology Program stands out for its potential to provide major environmental and financial benefits to the United States steel industry. Bethlehem Steel Topical Report The Energy Department has profiled the project in a topical report entitled Blast Furnace Granular Coal Injection System Demonstration Project. The report describes the federal government's partnership demonstration project with Bethlehem Steel Corporation, which tested a new method for reducing

284

Arsenic Removal by Photochemical Methods: Nanoparticulate Zerovalent Iron  

NLE Websites -- All DOE Office Websites (Extended Search)

Arsenic Removal by Photochemical Methods: Nanoparticulate Zerovalent Iron Arsenic Removal by Photochemical Methods: Nanoparticulate Zerovalent Iron and Heterogeneous Photocatalysis with TiO2 Speaker(s): Marta Litter Date: November 19, 2010 - 11:00am Location: 90-3122 Seminar Host/Point of Contact: Hugo Destaillats Arsenic in groundwater is a dramatic global problem due to the high incidence of arsenicosis or HACRE (Chronic Endemic Regional Hydro-arsenicism, Hidroarsenicismo Crónico Regional Endémico in Spanish), a severe illness causing skin lesions and cancer in extended regions of the world. For this reason, research on low-cost technologies for As removal to be applied in isolated, poor, rural locations is mandatory. This seminar will present a brief overview of arsenic pollution issues and mitigation needs in Latin America. It will also present results on As(V) removal using

285

The Viscosity of a Liquid Plutonium-Iron Eutectic Alloy  

SciTech Connect

The viscosity of a liquid plutonium-iron eutectic alloy, which contains 9.5 atom per cent iron and melts at 411 degrees C, was determined up to 808 degrees C at Mound Laboratory by an oscillating cup viscosimeter. This type of apparatus employed a right-circular cylindrical cup containing the liquid under investigation attached to a torsion fiber. The dampening effect of the liquid upon the normal oscillations of the pendululm was a function of the viscosity of the liquid. The amplitudes of the oscillations of the pendulum were measured by a photographic technique. The periods of the oscillations were determined by an automatic timing mechanism. The reliability of the viscosimeter was demonstrated by following the expected function of the viscosity of liquid lead and bismuth over a larger temperature range than was previously reported.

Wittenberg, L. J., Jones, L. V., Ofte, D.

1960-04-01T23:59:59.000Z

286

Iron aluminide alloys with improved properties for high temperature applications  

DOE Patents (OSTI)

An improved iron aluminide alloy of the DO[sub 3] type is described that has increased room temperature ductility and improved high elevated temperature strength. The alloy system further is resistant to corrosive attack in the environments of advanced energy conversion systems such as those using fossil fuels. The resultant alloy is relatively inexpensive as contrasted to nickel based and high nickel steels currently utilized for structural components. The alloy system consists essentially of 26--30 at. % aluminum, 0.5--10 at. % chromium, 0.02--0.3 at. % boron plus carbon, up to 2 at. % molybdenum, up to 1 at. % niobium, up to 0.5 at. % zirconium, up to 0.1 at. % yttrium, up to 0.5 at. % vanadium and the balance iron. 3 figs.

McKamey, C.G.; Liu, C.T.

1990-10-09T23:59:59.000Z

287

TECHNOLOGY DEVELOPMENT FOR IRON FISCHER-TROPSCH CATALYSTS  

DOE Green Energy (OSTI)

The goal of the proposed work described in this Final Report was the development of iron-based Fischer-Tropsch catalysts that combined high activity, selectivity and life with physical robustness for slurry phase reactors that will produce either low-alpha or high-alpha products. The work described here has optimized the catalyst composition and pretreatment operation for a low-alpha catalyst. In parallel, work has been conducted to design a high-alpha iron catalyst that is suitable for slurry phase synthesis. Studies have been conducted to define the chemical phases present at various stages of the pretreatment and synthesis stages and to define the course of these changes. The oxidation/reduction cycles that are anticipated to occur in large, commercial reactors have been studied at the laboratory scale. Catalyst performance has been determined for catalysts synthesized in this program for activity, selectivity and aging characteristics.

Davis, B.H.

1998-07-22T23:59:59.000Z

288

IRON-PHOSPHATE GLASS FOR IMMOBILIZATION OF RADIOACTIVE TECHNETIUM  

Science Conference Proceedings (OSTI)

Technetium-99 (Tc-99) can bring a serious environmental threat because of its high fission yield, long half-life, and high solubility and mobility in the ground water. The present work investigated the immobilization of Tc-99 (surrogated by Re) by heat-treating mixtures of an iron-phosphate glass with 1.5 to 6 wt.% KReO{sub 4} at {approx}1000 C. The Re retention in the glass was as high as {approx}1.2 wt. % while the loss of Re by evaporation during melting was {approx}50%. Re was uniformly distributed within the glass. The normalized Re release by the 7-day Product Consistency Test was {approx}0.39 g/m{sup 2}, comparable with that in phosphate-bonded ceramics and borosilicate glasses. These results suggest that iron-phosphate glass can provide a good matrix for immobilizing Tc-99.

KRUGER AA; HRMA PR; XU K; CHOI J; UM W; HEO J

2012-03-19T23:59:59.000Z

289

Iron aluminide alloys with improved properties for high temperature applications  

DOE Patents (OSTI)

An improved iron aluminide alloy of the DO.sub.3 type that has increased room temperature ductility and improved high elevated temperature strength. The alloy system further is resistant to corrosive attack in the environments of advanced energy corrosion systems such as those using fossil fuels. The resultant alloy is relatively inexpensive as contrasted to nickel based and high nickel steels currently utilized for structural components. The alloy system consists essentially of 26-30 at. % aluminum, 0.5-10 at. % chromium, 0.02-0.3 at. % boron plus carbon, up to 2 at. % molybdenum, up to 1 at. % niobium, up to 0.5 at. % zirconium, up to 0.1 at. % yttrium, up to 0.5 at. % vanadium and the balance iron.

McKamey, Claudette G. (Knoxville, TN); Liu, Chain T. (Oak Ridge, TN)

1990-01-01T23:59:59.000Z

290

Iron aluminide alloy container for solid oxide fuel cells  

DOE Patents (OSTI)

A container for fuel cells is made from an iron aluminide alloy. The container alloy preferably includes from about 13 to about 22 weight percent Al, from about 2 to about 8 weight percent Cr, from about 0.1 to about 4 weight percent M selected from Zr and Hf, from about 0.005 to about 0.5 weight percent B or from about 0.001 to about 1 weight percent C, and the balance Fe and incidental impurities. The iron aluminide container alloy is extremely resistant to corrosion and metal loss when exposed to dual reducing and oxidizing atmospheres at elevated temperatures. The alloy is particularly useful for containment vessels for solid oxide fuel cells, as a replacement for stainless steel alloys which are currently used.

Judkins, Roddie Reagan (Knoxville, TN); Singh, Prabhakar (Export, PA); Sikka, Vinod Kumar (Oak Ridge, TN)

2000-01-01T23:59:59.000Z

291

Method for heat treating iron-nickel-chromium alloy  

DOE Patents (OSTI)

A method for heat treating an age-hardenable iron-nickel-chromium alloy to obtain a bimodal distribution of gamma prime phase within a network of dislocations, the alloy consisting essentially of about 25% to 45% nickel, 10% to 16% chromium, 1.5% to 3% of an element selected from the group consisting of molybdenum and niobium, about 2% titanium, about 3% aluminum, and the remainder substantially all iron. To obtain optimum results, the alloy is heated to a temperature of 1025.degree. C. to 1075.degree. C. for 2-5 minutes, cold-worked about 20% to 60%, aged at a temperature of about 775.degree. C. for 8 hours followed by an air-cool, and then heated to a temperature in the range of 650.degree. C. to 700.degree. C. for 2 hours followed by an air-cool.

Merrick, Howard F. (Suffern, NY); Korenko, Michael K. (Rockville, MD)

1982-01-01T23:59:59.000Z

292

Iron aluminide useful as electrical resistance heating elements  

DOE Patents (OSTI)

The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, .ltoreq.1% Cr and either .gtoreq.0.05% Zr or ZrO.sub.2 stringers extending perpendicular to an exposed surface of the heating element or .gtoreq.0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Zr, .ltoreq.1% C, .ltoreq.0.1% B, .ltoreq.30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, .ltoreq.1% oxygen, .ltoreq.3% Cu, balance Fe.

Sikka, Vinod K. (Oak Ridge, TN); Deevi, Seetharama C. (Oak Ridge, TN); Fleischhauer, Grier S. (Midlothian, VA); Hajaligol, Mohammad R. (Richmond, VA); Lilly, Jr., A. Clifton (Chesterfield, VA)

1997-01-01T23:59:59.000Z

293

Iron aluminide useful as electrical resistance heating elements  

DOE Patents (OSTI)

The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, {<=}1% Cr and either {>=}0.05% Zr or ZrO{sub 2} stringers extending perpendicular to an exposed surface of the heating element or {>=}0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, {<=}2% Ti, {<=}2% Mo, {<=}1% Zr, {<=}1% C, {<=}0.1% B, {<=}30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, {<=}1% rare earth metal, {<=}1% oxygen, {<=}3% Cu, balance Fe. 64 figs.

Sikka, V.K.; Deevi, S.C.; Fleischhauer, G.S.; Hajaligol, M.R.; Lilly, A.C. Jr.

1997-04-15T23:59:59.000Z

294

Iron aluminide useful as electrical resistance heating elements  

DOE Patents (OSTI)

The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, .ltoreq.1% Cr and either .gtoreq.0.05% Zr or ZrO.sub.2 stringers extending perpendicular to an exposed surface of the heating element or .gtoreq.0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Zr, .ltoreq.1% C, .ltoreq.0.1% B, .ltoreq.30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, .ltoreq.1% oxygen, .ltoreq.3% Cu, balance Fe.

Sikka, Vinod K. (Oak Ridge, TN); Deevi, Seetharama C. (Oak Ridge, TN); Fleischhauer, Grier S. (Midlothian, VA); Hajaligol, Mohammad R. (Richmond, VA); Lilly, Jr., A. Clifton (Chesterfield, VA)

1999-01-01T23:59:59.000Z

295

Iron aluminide useful as electrical resistance heating elements  

DOE Patents (OSTI)

The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, .ltoreq.1% Cr and either .gtoreq.0.05% Zr or ZrO.sub.2 stringers extending perpendicular to an exposed surface of the heating element or .gtoreq.0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Zr, .ltoreq.1% C, .ltoreq.0.1% B, .ltoreq.30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, .ltoreq.1% oxygen, .ltoreq.3% Cu, balance Fe.

Sikka, Vinod K. (Oak Ridge, TN); Deevi, Seetharama C. (Oak Ridge, TN); Fleischhauer, Grier S. (Midlothian, VA); Hajaligol, Mohammad R. (Richmond, VA); Lilly, Jr., A. Clifton (Chesterfield, VA)

2001-01-01T23:59:59.000Z

296

Technology development for iron F-T catalysts. Final report  

DOE Green Energy (OSTI)

The objectives of this work were twofold. The first objective was to design and construct a pilot plant for preparing precipitated iron oxide F-T precursors and demonstrate that the rate of production from this plant is equivalent to 100 lbs/day of dried metal oxide. Secondly, these precipitates were to be used to prepare catalysts capable of achieving 88% CO + H{sub 2} conversion with {le} 5 mole percent selectivity to methane + ethane.

Frame, R.R.; Gala, H.B.

1994-08-01T23:59:59.000Z

297

Multimuon production in 280 GeV ?+ iron interactions  

Science Conference Proceedings (OSTI)

Results are presented on dimuon and trimuon final states in 280 GeV ?+ iron interactions. Both dimuon and trimuon data show clear evidence for open charm production and suggest strongly that the dominant production process is photon?gluon fusion. Similar amounts of elastic and inelastic (shower energy ?5 GeV) J/? production are measured in the trimuon sample. Elastic J/? production is consistent with photon?gluon fusion plus naive assumptions. Inelastic J/? production is inconsistent with this simple model

The European Muon Collaboration

1980-01-01T23:59:59.000Z

298

Pressure Effects on Two Superconducting Iron-based Families  

SciTech Connect

Insight into the mechanism of high-temperature superconductivity can be gained by pressure-dependent studies of structural, thermodynamics and transport data. The role of pressure may be complicated by the level of hydrostaticity. High-pressure studies on two iron-based families of RFeAsO (R = rare-earth metals) and AFe{sub 2}As{sub 2} (A = alkaline-earth metals) are reviewed here.

Safa-Sefat, Athena [ORNL

2011-01-01T23:59:59.000Z

299

Low resistivity contact to iron-pnictide superconductors  

DOE Patents (OSTI)

Method of making a low resistivity electrical connection between an electrical conductor and an iron pnictide superconductor involves connecting the electrical conductor and superconductor using a tin or tin-based material therebetween, such as using a tin or tin-based solder. The superconductor can be based on doped AFe.sub.2As.sub.2, where A can be Ca, Sr, Ba, Eu or combinations thereof for purposes of illustration only.

Tanatar, Makariy; Prozorov, Ruslan; Ni, Ni; Bud& #x27; ko, Sergey; Canfield, Paul

2013-05-28T23:59:59.000Z

300

Performance and cycling of the iron-ion/hydrogen redox flow cell with  

NLE Websites -- All DOE Office Websites (Extended Search)

Performance and cycling of the iron-ion/hydrogen redox flow cell with Performance and cycling of the iron-ion/hydrogen redox flow cell with various catholyte salts Title Performance and cycling of the iron-ion/hydrogen redox flow cell with various catholyte salts Publication Type Journal Article Year of Publication 2013 Authors Tucker, Michael C., Venkat Srinivasan, Philip N. Ross, and Adam Z. Weber Journal Journal of Applied Electrochemistry Volume 43 Issue 7 Pagination 637 - 644 Date Published 7/2013 ISSN 0021-891X Keywords battery, Flow battery, iron hydrogen cell, progress, redox flow cell Abstract A redox flow cell utilizing the Fe2+/Fe3+ and H-2/H+ couples is investigated as an energy storage device. A conventional polymer electrolyte fuel cell anode and membrane design is employed, with a cathode chamber containing a carbon felt flooded with aqueous acidic solution of iron salt. The maximum power densities achieved for iron sulfate, iron chloride, and iron nitrate are 148, 207, and 234 mW cm(-2), respectively. It is found that the capacity of the iron nitrate solution decreases rapidly during cycling. Stable cycling is observed for more than 100 h with iron chloride and iron sulfate solutions. Both iron sulfate and iron chloride solutions display moderate discharge polarization and poor charge polarization; therefore, voltage efficiency decreases dramatically with increasing current density. A small self-discharge current occurs when catholyte is circulating through the cathode chamber. As a result, a current density above 100 mA cm(-2) is required to achieve high Coulombic efficiency (> 0.9).

Note: This page contains sample records for the topic "zero-valent iron treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Snapshot of iron response in Shewanella oneidensis by gene network reconstruction  

Science Conference Proceedings (OSTI)

Background: Iron homeostasis of Shewanella oneidensis, a gamma-proteobacterium possessing high iron content, is regulated by a global transcription factor Fur. However, knowledge is incomplete about other biological pathways that respond to changes in iron concentration, as well as details of the responses. In this work, we integrate physiological, transcriptomics and genetic approaches to delineate the iron response of S. oneidensis. Results: We show that the iron response in S. oneidensis is a rapid process. Temporal gene expression profiles were examined for iron depletion and repletion, and a gene co-expression network was reconstructed. Modules of iron acquisition systems, anaerobic energy metabolism and protein degradation were the most noteworthy in the gene network. Bioinformatics analyses suggested that genes in each of the modules might be regulated by DNA-binding proteins Fur, CRP and RpoH, respectively. Closer inspection of these modules revealed a transcriptional regulator (SO2426) involved in iron acquisition and ten transcriptional factors involved in anaerobic energy metabolism. Selected genes in the network were analyzed by genetic studies. Disruption of genes encoding a putative alcaligin biosynthesis protein (SO3032) and a gene previously implicated in protein degradation (SO2017) led to severe growth deficiency under iron depletion conditions. Disruption of a novel transcriptional factor (SO1415) caused deficiency in both anaerobic iron reduction and growth with thiosulfate or TMAO as an electronic acceptor, suggesting that SO1415 is required for specific branches of anaerobic energy metabolism pathways. Conclusions: Using a reconstructed gene network, we identified major biological pathways that were differentially expressed during iron depletion and repletion. Genetic studies not only demonstrated the importance of iron acquisition and protein degradation for iron depletion, but also characterized a novel transcriptional factor (SO1415) with a role in anaerobic energy metabolism.

Yang, Yunfeng; Harris, Daniel P.; Luo, Feng; Xiong, Wenlu; Joachimiak, Marcin; Wu, Liyou; Dehal, Paramvir; Jacobsen, Janet; Yang, Zamin; Palumbo, Anthony V.; Arkin, Adam P.; Zhou, Jizhong

2008-10-09T23:59:59.000Z

302

Blood and hair lead in children with different extents of iron deficiency in Karachi  

SciTech Connect

Childhood iron deficiency has a high incidence in Pakistan. Some but not all studies have shown that dietary iron deficiency may cause increased absorption of lead as both compete for the same transporters in the small intestine. Therefore, children in Pakistan, residing in heavily polluted cities like Karachi may be prone to lead poisoning. This hypothesis was tested by investigating blood and hair lead concentrations in children from Karachi who were divided into four groups of iron status; normal, borderline iron deficiency, iron deficiency and iron deficiency anaemia. A prospective observational study was conducted where 269 children were categorized into four groups of iron status using the World Health Organization criteria and one based on soluble transferrin receptor measurements. Blood iron status was determined using a full blood count, serum iron, ferritin, transferrin saturation and soluble transferrin receptor measurements. Blood lead was determined by graphite atomic absorption spectroscopy, whereas hair lead was assessed using an inductively coupled plasma atomic emission spectroscopy technique. Blood lead concentrations were significantly higher in children with iron deficiency anaemia (mean [95% confidence intervals] were 24.9 [22.6-27.2] {mu}g/dL) compared to those with normal iron status (19.1 [16.8-21.4] {mu}g/dL) using WHO criteria. In contrast, hair lead content was not significantly different in children of different iron status. Our findings reinforce the importance of not only reducing environmental lead pollution but also the development of national health strategies to reduce childhood iron deficiency in Pakistan.

Ataur Rahman, Muhammad; Rahman, Bushra [Karachi Institute of Biotechnology and Genetic Engineering, University of Karachi, Karachi-75270 (Pakistan)] [Karachi Institute of Biotechnology and Genetic Engineering, University of Karachi, Karachi-75270 (Pakistan); Saeed Ahmad, Muhammad [School of Healthcare Science, Manchester Metropolitan University, Manchester M1 5GD (United Kingdom)] [School of Healthcare Science, Manchester Metropolitan University, Manchester M1 5GD (United Kingdom); Blann, Andrew [Department of Medicine, City Hospital, Birmingham B18 7QH, United Kingdom. (United Kingdom)] [Department of Medicine, City Hospital, Birmingham B18 7QH, United Kingdom. (United Kingdom); Ahmed, Nessar, E-mail: N.Ahmed@mmu.ac.uk [School of Healthcare Science, Manchester Metropolitan University, Manchester M1 5GD (United Kingdom)] [School of Healthcare Science, Manchester Metropolitan University, Manchester M1 5GD (United Kingdom)

2012-10-15T23:59:59.000Z

303

Brazilian Bentonite Submitted to Mild Acid Treatment  

Science Conference Proceedings (OSTI)

Characterization of Wastes Generated during Stainless Steel Production Charpy Impact Tests in Epoxy ... Differential Characterization of Ikperejere Iron shale and Iron Sandstone Deposit ... High Temperature Exposure of Oil Well Cements.

304

Length-scale Effects in Cascade Damage Production in Iron  

SciTech Connect

Molecular dynamics simulations provide an atomistic description of the processes that control primary radiation damage formation in atomic displacement cascades. An extensive database of simulations describing cascade damage production in single crystal iron has been compiled using a modified version of the interatomic potential developed by Finnis and Sinclair. This same potential has been used to investigate primary damage formation in nanocrystalline iron in order to have a direct comparison with the single crystal results. A statistically significant number of simulations were carried out at cascade energies of 10 keV and 20 keV and temperatures of 100 and 600K to make this comparison. The results demonstrate a significant influence of nearby grain boundaries as a sink for mobile defects during the cascade cooling phase. This alters the residual primary damage that survives the cascade event. Compared to single crystal, substantially fewer interstitials survive in the nanograined iron, while the number of surviving vacancies is similar or slightly greater than the single crystal result. The fraction of the surviving interstitials contained in clusters is also reduced. The asymmetry in the survival of the two types of point defects is likely to alter damage accumulation at longer times.

Stoller, Roger E [ORNL; Osetskiy, Yury N [ORNL; Kamenski, Paul J [ORNL

2009-01-01T23:59:59.000Z

305

The development of precipitated iron catalysts with improved stability  

DOE Green Energy (OSTI)

The goal of this program is to identify the chemical principles governing the deactivation of precipitated iron catalysts during Fischer-Tropsch synthesis and to use these chemical principles in the design of catalysts suitable for slurry reactors. This report covers testing an iron catalyst. During the last quarter, a new precipitated iron catalyst was prepared and tested in the slurry autoclave reactor at various conditions. This catalyst did not noticeably deactivate during 1250 hours of testing. This quarter, the test was extended to include performance evaluations at different conversion levels ranging from 35 to 88% at 265 and 275{degree}C. The conversion levels were varied by changing the feed rate. The catalytic performance at different conversion intervals was then integrated to approximately predict performance in a bubble column reactor. The run was shut down at the end of 1996 hours because of a 24-hour-power outage. When the power was back on, the run was restarted from room temperature. Catalytic performance during the first 300 hours after the restart-up was monitored. Overall product distributions are being tabulated as analytical laboratory data are obtained. 34 figs., 3 tabs.

Not Available

1990-01-01T23:59:59.000Z

306

Mineral ecophysiological evidence for microbial activity in banded iron formation  

Science Conference Proceedings (OSTI)

The phosphorus composition of banded-iron formations (BIFs) has been used as a proxy for Precambrian seawater composition and the paleoeredox state of Earth's surface environment. However, it is unclear whether the phosphorus in BIFs originally entered the sediment as a sorbed component of the iron oxyhydroxide particles, or whether it was incorporated into the biomass of marine phytoplankton. We conducted high-resolution mineral analyses and report here the first detection of an Fe(III) acetate salt, as well as nanocrystals of apatite in association with magnetite, in the 2.48 Ga Dales Gorge Member of the Brockman Iron Formation (a BIF), Hamersley, Western Australia. The clusters of apatite are similar in size and morphology to biogenic apatite crystals resulting from biomass decay in Phanerozoic marine sediments, while the formation of an Fe(III) acetate salt and magnetite not only implies the original presence of biomass in the BIF sediments, but also that organic carbon likely served as an electron donor during bacterial Fe(III) reduction. This study is important because it suggests that phytoplankton may have played a key role in the transfer of phosphorus (and other trace elements) from the photic zone to the seafloor.

Li, Dr. Yi-Liang [University of Tennessee, Knoxville (UTK); Konhauser, Dr, Kurt [University of Alberta; Cole, David R [ORNL; Phelps, Tommy Joe [ORNL

2011-01-01T23:59:59.000Z

307

Versatile and Biomass Synthesis of Iron-based Nanoparticles Supported on Carbon Matrix with High Iron Content and Tunable Reactivity  

SciTech Connect

Iron-based nanoparticles supported on carbon (FeNPs{at}C) have enormous potential for environmental applications. Reported is a biomass-based method for FeNP{at}C synthesis that involves pyrolysis of bleached wood fiber pre-mixed with Fe{sub 3}O{sub 4} nanoparticles. This method allows synthesis of iron-based nanoparticles with tunable chemical reactivity by changing the pyrolysis temperature. The FeNP{at}C synthesized at a pyrolysis temperature of 500 C (FeNP{at}C-500) reacts violently (pyrophoric) when exposed to air, while FeNP{at}C prepared at 800 C (FeNP{at}C-800) remains stable in ambient condition for at least 3 months. The FeNPs in FeNP{at}C-800 are mostly below 50 nm in diameter and are surrounded by carbon. The immediate carbon layer (within 5-15 nm radius) on the FeNPs is graphitized. Proof-of-concept environmental applications of FeNPs{at}C-800 were demonstrated by Rhodamine 6G and arsenate (V) removal from water. This biomass-based method provides an effective way for iron-based nanoparticle fabrication and biomass utilization.

Zhang, Dongmao [ORNL; Shi, Sheldon Q [ORNL; Jiang, Dongping [Mississippi State University (MSU); Che, Wen [Mississippi State University (MSU); Gai, Zheng [ORNL; Howe, Jane Y [ORNL; More, Karren Leslie [ORNL; Arockiasamy, Antonyraj [Mississippi State University (MSU)

2012-01-01T23:59:59.000Z

308

Solvent Tuning of Properties of Iron-Sulfur Clusters in Proteins  

NLE Websites -- All DOE Office Websites (Extended Search)

Solvent Tuning of Properties of Solvent Tuning of Properties of Iron-Sulfur Clusters in Proteins Figure 1. Schematic repre-sentation of the common active-site iron-sulfur cluster structural motif. Proteins containing Fe4S4 iron-sulfur clusters are ubiquitous in nature and catalyze one-electron transfer processes. These proteins have evolved into two classes that have large differences in their electrochemical potentials: high potential iron-sulfur proteins (HiPIPs) and bacterial ferredoxins (Fds). The role of the surrounding protein environment in tuning the redox potential of these iron sulfur clusters has been a persistent puzzle in biological electron transfer [1]. Although HiPIPs and Fds have the same iron sulfur structural motif - a cubane-type structure - (Figure 1), there are large differences in their electrochemical

309

Laboratory study related to the production and properties of pig iron nuggets  

SciTech Connect

Pig iron nuggets were produced in a laboratory-scale furnace at Michigan Technological University. The process was intended to replicate Kobe Steel's ITmk3 direct ironmaking process. These nuggets were produced from pellets that were made from a mixture of iron oxide, coal, flux and a binder and heated in a furnace with a chamber temperature of 1450{sup o}C. The pellets then self-reduced to produce a solid, high-density, highly metallized (96.5% Fe) pig iron. During the nugget production process, a separate liquid slag phase formed that cleanly separated from the molten metal. The physical and chemical properties of the pig iron nuggets were similar to pig iron produced by blast furnaces, which is distinct from direct reduced iron (DRI).

Anameric, B.; Kawatra, S.K. [Michigan Technological University, Houghton, MI (United States). Dept. for Chemical Engineering

2006-02-15T23:59:59.000Z

310

Advances in Glass Formulations for Hanford High-Alumimum, High-Iron and Enhanced Sulphate Management in HLW Streams - 13000  

SciTech Connect

The current estimates and glass formulation efforts have been conservative in terms of achievable waste loadings. These formulations have been specified to ensure that the glasses are homogenous, contain essentially no crystalline phases, are processable in joule-heated, ceramic-lined melters and meet Hanford Tank Waste Treatment and Immobilization Plant (WTP) Contract terms. The WTP?s overall mission will require the immobilization of tank waste compositions that are dominated by mixtures of aluminum (Al), chromium (Cr), bismuth (Bi), iron (Fe), phosphorous (P), zirconium (Zr), and sulphur (S) compounds as waste-limiting components. Glass compositions for these waste mixtures have been developed based upon previous experience and current glass property models. Recently, DOE has initiated a testing program to develop and characterize HLW glasses with higher waste loadings and higher throughput efficiencies. Results of this work have demonstrated the feasibility of increases in waste loading from about 25 wt% to 33-50 wt% (based on oxide loading) in the glass depending on the waste stream. In view of the importance of aluminum limited waste streams at Hanford (and also Savannah River), the ability to achieve high waste loadings without adversely impacting melt rates has the potential for enormous cost savings from reductions in canister count and the potential for schedule acceleration. Consequently, the potential return on the investment made in the development of these enhancements is extremely favorable. Glass composition development for one of the latest Hanford HLW projected compositions with sulphate concentrations high enough to limit waste loading have been successfully tested and show tolerance for previously unreported tolerance for sulphate. Though a significant increase in waste loading for high-iron wastes has been achieved, the magnitude of the increase is not as substantial as those achieved for high-aluminum, high-chromium, high-bismuth or sulphur. Waste processing rate increases for high-iron streams as a combined effect of higher waste loadings and higher melt rates resulting from new formulations have been achieved.

Kruger, Albert A.

2013-01-16T23:59:59.000Z

311

Discovery of a red and blue shifted iron disk line in the galactic jet source GRO J1655-40  

E-Print Network (OSTI)

We report the discovery of emission features in the X-ray spectrum of GRO J1655-40 obtained with RXTE during the observation of 1997, Feb 26. We have fitted the features firstly by two Gaussian lines which in four spectra analysed have average energies of 5.85 +/- 0.08 keV and 7.32 +/- 0.13 keV, strongly suggestive that these are the red and blue shifted wings of an iron disk line. These energies imply a velocity of ~0.33 c. The blue wing is less bright than in the calculated profiles of disk lines near a black hole subject to Doppler boosting, however known Fe absorption lines in GRO J1655-40 at energies between ~7 and 8 keV can reduce the apparent brightness of the blue wing. Secondly, we have fitted the spectra using the disk line model of Laor based on a full relativistic treatment plus an absorption line, and show that good fits are obtained. This gives a restframe energy of the disk line between 6.4 and 6.8 keV indicating that the line is iron K_alpha emission probably of significantly ionized material. The Laor model shows that the line originates in a region of the accretion disk extending from ~10 Schwarzschild radii from the black hole outwards. The line is direct evidence for the black hole nature of the compact object and is the first discovery of a highly red and blue shifted iron disk line in a Galactic source.

M. Balucinska-Church; M. J. Church

1999-12-17T23:59:59.000Z

312

Enzymes of respiratory iron oxidation. Progress report, March 1990--June 1992  

DOE Green Energy (OSTI)

This report describes experimental progress in characterizing and identifying redox proteins in a number of iron-oxidizing bacteria. Sections of the paper are entitled (1) In Situ electrolysis was explored to achieve enhanced yields of iron-oxidizing bacteria, (2)Structure/function studies were performed on redox-active biomolecules from Thiobacillus ferrooxidans, (3) Novel redox-active biomolecules were demonstrated in other iron autotrophs, and (4) New probes of metalloprotein electron-transfer reactions were synthesized and characterized.

Blake, R. II

1992-12-31T23:59:59.000Z

313

Preservation of iron(II) by carbon-rich matrices in a hydrothermal plume  

SciTech Connect

Hydrothermal venting associated with mid-ocean ridge volcanism is globally widespread. This venting is responsible for a dissolved iron flux to the ocean that is approximately equal to that associated with continental riverine runoff. For hydrothermal fluxes, it has long been assumed that most of the iron entering the oceans is precipitated in inorganic forms. However, the possibility of globally significant fluxes of iron escaping these mass precipitation events and entering open-ocean cycles is now being debated, and two recent studies suggest that dissolved organic ligands might influence the fate of hydrothermally vented metals. Here we present spectromicroscopic measurements of iron and carbon in hydrothermal plume particles at the East Pacific Rise mid-ocean ridge. We show that organic carbon-rich matrices, containing evenly dispersed iron(II)-rich materials, are pervasive in hydrothermal plume particles. The absence of discrete iron(II) particles suggests that the carbon and iron associate through sorption or complexation. We suggest that these carbon matrices stabilize iron(II) released from hydrothermal vents in the region, preventing its oxidation and/or precipitation as insoluble minerals. Our findings have implications for deep-sea biogeochemical cycling of iron, a widely recognized limiting nutrient in the oceans.

Toner, Brandy M.; Fakra, Sirine C.; Manganini, Steven J.; Santelli, Cara M.; Marcus, Matthew A.; Moffett, James W.; Rouxel, Olivier; German, Christopher R.; Edwards, Katrina J.

2008-09-20T23:59:59.000Z

314

Iron-Carbon Phase Diagram: A Century at Variance with Chemical ...  

Science Conference Proceedings (OSTI)

Abstract Scope, For about a century thermodynamically absurd facts have been propagated in conjunction with the iron-carbon phase diagram. These facts...

315

Reduction of soot emissions by iron pentacarbonyl in isooctane diffusion flames  

Science Conference Proceedings (OSTI)

Light-scattering measurements, in situ laser-induced fluorescence, and thermophoretic sampling with transmission electron microscopy (TEM) analysis, were performed in laboratory isooctane diffusion flames seeded with 4000 ppm iron pentacarbonyl. These measurements allowed the determination of the evolution of the size, number density, and volume fraction of soot particles through the flame. Comparison to unseeded flame data provided a detailed assessment of the effects of iron addition on soot particle inception, growth, and oxidation processes. Iron was found to produce a minor soot-enhancing effect at early residence times, while subsequent soot particle growth was largely unaffected. It is concluded that primarily elemental iron is incorporated within the soot particles during particle inception and growth. However, iron addition was found to enhance the rate of soot oxidation during the soot burnout regime, yielding a two-thirds reduction in overall soot emissions. In situ spectroscopic measurements probed the transient nature of elemental iron throughout the flame, revealing significant loss of elemental iron, presumably to iron oxides, with increasing flame residence, suggesting catalysis of soot oxidation via iron oxide species. (author)

Kim, K.B.; Masiello, K.A.; Hahn, D.W. [Department of Mechanical and Aerospace Engineering, University of Florida, Gainesville, FL 32611 (United States)

2008-07-15T23:59:59.000Z

316

Corrosion Products of Iron Wire Arterial Implants from In Vivo and In ...  

Science Conference Proceedings (OSTI)

In the present study, iron wire was implanted into either the abdominal rat aortic wall or ... Fabrication of a Cellulosic Nanocomposite Scaffold with Improved...

317

Sticking of Iron Ore Pellets in Direct Reduction with Coal Gas  

Science Conference Proceedings (OSTI)

Abstract Scope, A series of reduction experiments of iron ore pellets with coal gasification gas were carried out in a laboratory scale shaft furnace. The sticking

318

Impacts of increasing anthropogenic soluble iron and nitrogen deposition on ocean biogeochemistry  

E-Print Network (OSTI)

and sulfur deposition on ocean acidification and thethe tropical North Atlantic Ocean, J. Geophys. Res. , 105,and iron inputs to the ocean, Global Biogeochem. Cycles, 19,

2009-01-01T23:59:59.000Z

319

Effect of PCI blending on combustion characteristics for iron-making.  

E-Print Network (OSTI)

??The PCI technology is well established for reducing the consumption of economic and environmentally expensive coke in blast furnace iron-making. Often, coal blends show unexpected (more)

Gill, Trilochan Singh

2009-01-01T23:59:59.000Z

320

Moving towards Sustainability: Improving Material Flows in the Iron Casting Industry.  

E-Print Network (OSTI)

??ustainable engineering solutions were developed to improve the sustainability of the iron casting process. These engineering solutions aimed to modify the material and energy flow (more)

Huang, He

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "zero-valent iron treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Clean iron production and machining technology. Year 1 summary report, January 1--December 31, 1995  

SciTech Connect

The first phase of this project was conducted to develop a technique for evaluating the machinability of gray and ductile iron. That technique was then used to measure the machinability of a variety of irons and determine the processing factors that influenced and controlled machinability. The procedure developed to evaluate machinability involved drilling holes with a feed rate of 0.009 in/rev at various surface speeds. High speed steel drills were used so wear was observed more quickly. Microcarbides present in the irons were found to dominate the machinability. Pearlitic irons considered to have ``acceptable`` machinability (indicated either by tool life measured in the laboratory using high speed steel (HSS) drills or reports from commercial machine shops using other cutters) were found to contain from 8.9 to 10.5% by weight microscopic carbides. The tool wear rate increased when machining at higher surface speeds or machining irons containing higher weight percentage of microcarbides. All irons containing above 11.5% microcarbides consistently exhibited poor machinability. Tool wear results obtained using cubic boron nitride (CBN) cutters paralleled those obtained with HSS. Higher iron microcarbide concentrations produced faster tool wear. Experiments are now being formulated to explore methods of improving iron machinability. Future work will extend the study to ductile irons.

1996-03-05T23:59:59.000Z

322

Iron Works Advance 1750-1910 in Central Canada, Contrasted With ...  

Science Conference Proceedings (OSTI)

... center for Central Canada, based on local pig iron and on WI imports (later, .... of Special-shape Tundish with Gas Curtain, Retaining Wall and Retaining Dam.

323

NERSC User Group 2013 Big Bang, Big Data, Big Iron Planck Satellite...  

NLE Websites -- All DOE Office Websites (Extended Search)

User Group 2013 Big Bang, Big Data, Big Iron Planck Satellite Data Analysis At NERSC Julian Borrill Computational Cosmology Center, Berkeley Lab & Space Sciences Laboratory, UC...

324

Anisotropy of the Fracture Behaviour of Severly Deformed Iron and a ...  

Science Conference Proceedings (OSTI)

Anisotropy of the Fracture Behaviour of Severly Deformed Iron and a Pearlitic Rail Steel Atom Probe Tomography: A New Insight into the Partition and...

325

Method for the Production of Mineral Wool andIron from ...  

Method for the Production of Mineral Wool and Iron from Serpentine Ore Overview This invention discloses a method to fabricate a product that has the potential

326

ESS 2012 Peer Review - Iron-Air Rechargeable Battery for Grid...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

A Robust and Inexpensive Iron-Air Rechargeable Battery for Grid-Scale Energy Storage Lead: University of Southern California, Loker Hydrocarbon Research Institute Sub-Awardee: Jet...

327

Theory of spin-fluctuation induced superconductivity in iron-based superconductors.  

E-Print Network (OSTI)

??In this dissertation we focus on the investigation of the pairing mechanism in the recently discovered high-temperature superconductor, iron pnictides. Due to the proximity to (more)

Zhang, Junhua

2011-01-01T23:59:59.000Z

328

Discovery of a red and blue shifted iron disk line in the galactic jet source GRO J1655-40  

E-Print Network (OSTI)

We report the discovery of emission features in the X-ray spectrum of GRO J1655-40 obtained with RXTE during the observation of 1997, Feb 26. We have fitted the features firstly by two Gaussian lines which in four spectra analysed have average energies of 5.85 +/- 0.08 keV and 7.32 +/- 0.13 keV, strongly suggestive that these are the red and blue shifted wings of an iron disk line. These energies imply a velocity of ~0.33 c. The blue wing is less bright than in the calculated profiles of disk lines near a black hole subject to Doppler boosting, however known Fe absorption lines in GRO J1655-40 at energies between ~7 and 8 keV can reduce the apparent brightness of the blue wing. Secondly, we have fitted the spectra using the disk line model of Laor based on a full relativistic treatment plus an absorption line, and show that good fits are obtained. This gives a restframe energy of the disk line between 6.4 and 6.8 keV indicating that the line is iron K_alpha emission probably of significantly ionized material....

Balucinska-Church, M

1999-01-01T23:59:59.000Z

329

Effect of temperature and iron-oxide nano-particle inclusions on the ultrasound vaporization pressure of perfluorocarbon droplets for disease detection and therapy  

E-Print Network (OSTI)

Temperature and Iron-Oxide Nano-particle inclusions on the22 1.9.1 Why Iron-Oxide NanoTemperature and Iron-Oxide Nano-particle inclusions on the

Amirriazi, Seyed Saleh

2009-01-01T23:59:59.000Z

330

Phosphate influences cycling of iron and carbon in the environment |  

NLE Websites -- All DOE Office Websites (Extended Search)

Science Science Computing, Environment & Life Sciences Energy Engineering & Systems Analysis Photon Sciences Physical Sciences & Engineering Energy Frontier Research Centers Science Highlights Postdoctoral Researchers Phosphate influences cycling of iron and carbon in the environment August 30, 2013 Tweet EmailPrint Aquatic and terrestrial environments are dynamic systems where coupled microbiological, geochemical, and hydrological processes define the complex interactions that drive the biogeochemical cycling of water and the major and minor elements. Therefore, a thorough understanding of these complex interactions is critical for predicting the biogeochemical cycling of carbon, nutrients, heavy metals, radionuclides, and other contaminants; managing water quality; and understanding the interactions between

331

Chemistry and Electronic Structure of Iron-Based Superconductors  

Science Conference Proceedings (OSTI)

The solid state provides a richly varied fabric for intertwining chemical bonding, electronic structure, and magnetism. The discovery of superconductivity in iron pnictides and chalcogenides has revealed new aspects of this interplay, especially involving magnetism and superconductivity. Moreover, it has challenged prior thinking about high-temperature superconductivity by providing a set of materials that differ in many crucial aspects from the previously known cuprate superconductors. Here we review some of what is known about the superconductivity and its interplay with magnetism, chemistry, and electronic structure in Fe-based superconductors.

Safa-Sefat, Athena [ORNL; Singh, David J [ORNL

2011-01-01T23:59:59.000Z

332

New iron catalyst for preparation of polymethylene from synthesis gas  

DOE Patents (OSTI)

This invention relates to a process for synthesizing hydrocarbons; more particularly, the invention relates to a process for synthesizing long-chain hydrocarbons known as polymethylene from carbon monoxide and hydrogen or from carbon monoxide and water or mixtures thereof in the presence of a catalyst comprising iron and platinum or palladium or mixtures thereof which may be supported on a solid material, preferably an inorganic refractory oxide. This process may be used to convert a carbon monoxide containing gas to a product which could substitute for high density polyethylene.

Sapienza, R.S.; Slegeir, W.A.

1988-03-31T23:59:59.000Z

333

NONEQUILIBRIUM FLUCTUATIONS IN SHOCK COMPRESSION OF POLYCRYSTALLINE ALPHA-IRON  

Science Conference Proceedings (OSTI)

We report a numerical study of heterogeneous and nonequilibrium fluctuations in shock compression of {alpha}-iron at the grain level. A quasi-molecular code called DM2 is used to model the interactions of a plane shock wave with grain boundaries and crystal anisotropy over the pressure range of 5-45 GPa. Highly transient eddies that were reported earlier are again observed. We show new features through an elementary statistical analysis. They are (1) a characteristic decay constant for the non-equilibrium fluctuation on the order of 20ns, (2) a resonance phenomenon at an intermediate shock pressure, and (3) a more uniform shock structure for very high pressures.

Y. HORIE; K. YANO

2001-06-01T23:59:59.000Z

334

Feedwater Iron Optimization: Quad Cities Generating Station Unit 1  

Science Conference Proceedings (OSTI)

EPRI's BWR Water Chemistry Guidelines 2004 Revisions (report 1008192) recommends feedwater iron control in the range of 0.1 ppb 1.0 ppb for plants operating with reducing chemistry conditions for intergranular stress corrosion cracking (IGSCC) mitigation. Since all U.S. plants now operate under moderate hydrogen water chemistry (HWC-M) or noble metals chemical addition and hydrogen water chemistry (NMCA+HWC), it is appropriate to target the lower end of the range (0.1 0.5 ppb) to minimize zinc requiremen...

2008-08-18T23:59:59.000Z

335

GLASSES CONTAINING IRON (II III) OXIDES FOR IMMOBILIZATION OF RADIOACTIVE TECHNETIUM  

SciTech Connect

Technetium-99 (Tc-99) has posed serious environmental threats as US Department of Energy's high-level waste. This work reports the vitrification of Re, as surrogate for Tc-99, by iron-borosilicate and iron-phosphate glasses, respectively. Iron-phosphate glasses can dissolve Re as high as {approx} 1.2 wt. %, which can become candidate waste forms for Tc-99 disposal, while borosilicate glasses can retain less than 0.1 wt. % of Re due to high melting temperature and long melting duration. Vitrification of Re as Tc-99's mimic was investigated using iron-borosilicate and iron-phosphate glasses. The retention of Re in borosilicate glasses was less than 0.1 wt. % and more than 99 wt. % of Re were volatilized due to high melting temperature and long melting duration. Because the retention of Re in iron-phosphate glasses is as high as 1.2 wt. % and the volatilization is reduced down to {approx}50 wt. %, iron-phosphate glasses can be one of the glass waste form candidates for Tc (or Re) disposal. The investigations of chemical durability and leaching test of iron-phosphate glasses containing Re are now underway to test the performance of the waste form.

KRUGER AA; HEO J; XU K; CHOI JK; HRMA PR; UM W

2011-11-07T23:59:59.000Z

336

Kiel Policy Brief Ocean Iron Fertilization: An Option for Mitigating Climate Change?  

E-Print Network (OSTI)

The world is very likely to experience a range of adverse climate change impacts in the coming decades and ocean iron fertilization is discussed as one measure to contribute to the mitigation of these impacts. Ocean iron fertilization aims at stimulating phytoplankton growth in certain parts of the ocean, thus enhancing oceanic CO2 uptake and reducing atmospheric CO2 concentrations.

Christine Bertram

2009-01-01T23:59:59.000Z

337

Attrition resistant bulk iron catalysts and processes for preparing and using same  

DOE Patents (OSTI)

An attrition resistant precipitated bulk iron catalyst is prepared from iron oxide precursor and a binder by spray drying. The catalysts are preferably used in carbon monoxide hydrogenation processes such as Fischer-Tropsch synthesis. These catalysts are suitable for use in fluidized-bed reactors, transport reactors and, especially, slurry bubble column reactors.

Jothimurugesan, Kandaswamy (Ponca City, OK); Goodwin, Jr., James G. (Clemson, SC); Gangwal, Santosh K. (Cary, NC)

2007-08-21T23:59:59.000Z

338

Spectral induced polarization and electrodic potential monitoring of microbially mediated iron sulfide transformations  

Science Conference Proceedings (OSTI)

Stimulated sulfate-reduction is a bioremediation technique utilized for the sequestration of heavy metals in the subsurface.We performed laboratory column experiments to investigate the geoelectrical response of iron sulfide transformations by Desulfo vibriovulgaris. Two geoelectrical methods, (1) spectral induced polarization (SIP), and (2) electrodic potential measurements, were investigated. Aqueous geochemistry (sulfate, lactate, sulfide, and acetate), observations of precipitates (identified from electron microscopy as iron sulfide), and electrodic potentials on bisulfide ion (HS) sensitive silver-silver chloride (Ag-AgCl) electrodes (630 mV) were diagnostic of induced transitions between an aerobic iron sulfide forming conditions and aerobic conditions promoting iron sulfide dissolution. The SIP data showed 10m rad anomalies during iron sulfide mineralization accompanying microbial activity under an anaerobic transition. These anomalies disappeared during iron sulfide dissolution under the subsequent aerobic transition. SIP model parameters based on a Cole-Cole relaxation model of the polarization at the mineral-fluid interface were converted to (1) estimated biomineral surface area to pore volume (Sp), and (2) an equivalent polarizable sphere diameter (d) controlling the relaxation time. The temporal variation in these model parameters is consistent with filling and emptying of pores by iron sulfide biofilms, as the system transitions between anaerobic (pore filling) and aerobic (pore emptying) conditions. The results suggest that combined SIP and electrodic potential measurements might be used to monitor spatiotemporal variability in microbial iron sulfide transformations in the field.

Hubbard, Susan; Personna, Y.R.; Ntarlagiannis, D.; Slater, L.; Yee, N.; O'Brien, M.; Hubbard, S.

2008-02-15T23:59:59.000Z

339

Metallo-carbohedrenes. Chromium, iron, and molybdenum analogues  

Science Conference Proceedings (OSTI)

The formation of especially stable metal-carbon clusters, which have been designated metallo-carbohedrenes by Castleman and co-workers, has previously been reported for the early transition metals (Ti, Zr, Hf, V). Clusters having the formula M[sub 8]C[sub 12] were recognized as especially stable species which were formed in plasmas containing the metal and a carbon-containing precursor. A similar laser induced plasma technique is employed to synthesize chromium, molybdenum, and iron analogues of these so-called [open quotes]met-cars[close quotes] clusters and to study their photodissociation behavior. These observations suggest that met-cars cluster formation is a more general phenomenon than previously recognized. While chromium and molybdenum form the [open quotes]super-magic[close quotes] 8/12 stochiometry efficiently, met-cars formation competes with other special stoichiometries in the iron clusters. Implications for the bonding properties in met-cars systems are discussed. 22 refs., 5 figs.

Pilgrim, J.S.; Duncan, M.A. (Univ. of Georgia, Athens (United States))

1993-07-28T23:59:59.000Z

340

Deactivation by carbon of iron catalysts for indirect liquefaction  

DOE Green Energy (OSTI)

This report describes recent progress in a fundamental, three-year investigation of carbon formation and its effects on the activity and selectivity of promoted iron catalysts for Fischer-Tropsch (FT) synthesis, the objectives of which are: determine rates and mechanisms of carbon deactivation of unsupported Fe and Fe/K catalysts during CO hydrogenation over a range of CO concentrations, CO:H{sub 2} ratios, and temperatures; model the rates of deactivation of the same catalysts in fixed-bed reactors. During the thirteenth quarter design of software for a computer-automated reactor system to be used in the kinetic and deactivation studies was continued. Further progress was made toward the completion of the control language, control routines, and software for operating this system. Progress was also made on the testing of the system hardware and software. H{sub 2} chemisorption capacities and activity selectivity data were also measured for three iron catalysts promoted with 1% alumina. 47 refs., 8 figs., 1 tab.

Bartholomew, C.H.

1990-10-11T23:59:59.000Z

Note: This page contains sample records for the topic "zero-valent iron treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Technology development for iron Fischer-Tropsch catalysts  

DOE Green Energy (OSTI)

Objectives are to develop active, stable iron Fischer-Tropsch catalysts for use in slurry-phase synthesis reactors and to develop a scaleup procedure for large-scale synthesis of such catalysts for process development and long-term testing in slurry bubble-column reactors. For a H[sub 2]-CO in molar ratio of 0.5 to 1.0, catalyst performance target is 88% CO+H[sub 2] conversion at a minimum space velocity of 2.4 NL/hr/gFe, with no more than 4% methane/ethane selectivity and 1% conversion loss per week. During this period, it was found that the performance of the slurry-phase iron and copper oxide-based catalyst depends on the amount of K. Five catalysts with differing K contents were studied. The catalysts with the lowest K were more active than the ones with higher K levels. The one with the middle K level was judged best.

Frame, R.R.

1991-01-01T23:59:59.000Z

342

TECHNOLOGY DEVELOPMENT FOR IRON FISCHER-TROPSCH CATALYSIS  

DOE Green Energy (OSTI)

The goal of the proposed work is the development of iron-based Fischer-Tropsch catalysts that combined high activity, selectivity and life with physical robustness for slurry phase reactors that will produce either low-alpha or high-alpha products. The catalyst that is developed will be suitable for testing at the Advanced Fuels Development Facility at LaPorte, Texas or similar sized plant. Previous work by the offeror has produced a catalyst formulation that is 1.5 times as active as the ''standard-catalyst'' developed by German workers for slurry phase synthesis. The proposed work will optimize the catalyst composition and pretreatment operation for this low-alpha catalyst. In parallel, work will be conducted to design a high-alpha iron catalyst that is suitable for slurry phase synthesis. Studies will be conducted to define the chemical phases present at various stages of the pretreatment and synthesis stages and to define the course of these changes. The oxidation/reduction cycles that are anticipated to occur in large, commercial reactors will be studied at the laboratory scale. Catalyst performance will be determined for catalysts synthesized in this program for activity, selectivity and aging characteristics.

Burtron H. Davis

1998-04-01T23:59:59.000Z

343

Technology development for iron fischer-tropsch catalysis  

SciTech Connect

The goal of the proposed work is the development of iron-based Fischer-Tropsch catalysts that combined high activity, selectivity and life with physical robustness for slurry phase reactors that will produce either low-alpha or high-alpha products. The catalyst that is developed will be suitable for testing at the Advanced Fuels Development Facility at LaPorte, Texas or similar sized plant. Previous work by the offeror has produced a catalyst formulation that is 1.5 times as active as the `standard-catalyst` developed by German workers for slurry phase synthesis. The proposed work will optimize the catalyst composition and pretreatment operation for this low- alpha catalyst. In parallel, work will be conducted to design a high- alpha iron catalyst that is suitable for slurry phase synthesis. Studies will be conducted to define the chemical phases present at various stages of the pretreatment and synthesis stages and to define the course of these changes. The oxidation/reduction cycles that are anticipated to occur in large, commercial reactors will be studied at the laboratory scale. Catalyst performance will be determined for 5 catalysts synthesized in this program for activity, selectivity and aging characteristics.

Davis, B.H.

1997-05-14T23:59:59.000Z

344

Technology development for iron fisher-tropsch catalysis  

SciTech Connect

The goal of the proposed work is the development of iron-based Fischer-Tropsch catalysts that combined high activity, selectivity and life with physical robustness for slurry phase reactors that will produce either low-alpha or high-alpha products. the catalyst that is developed will be suitable for testing at the Advanced Fuels Development Facility at LaPorte, Texas or similar sized plant. Previous work by the offeror has produced a catalyst formulation that is 1.5 times as active as the standard-catalyst developed by German workers for slurry phase synthesis, The proposed work will optimize the catalyst composition and pretreatment operation for this low-alpha catalyst. In parallel, work will be conducted to design a high-alpha iron catalyst that is suitable for slurry phase synthesis. Studies will be conducted to define the chemical phases present at various stages of the pretreatment and synthesis stages and to define the course of these changes. the oxidation/reduction cycles that are anticipated to occur in large, commercial reactors will be studies at the laboratory scale. Catalyst performance will be determined for catalysts synthesized in this program for activity, selectivity, and aging characteristics.

Davis, B.H.

1997-07-15T23:59:59.000Z

345

Discharge model for the lithium iron-phosphate electrode  

DOE Green Energy (OSTI)

This paper develops a mathematical model for lithium intercalation and phase change in an iron phosphate-based lithium-ion cell in order to understand the cause for the low power capability of the material. The juxtaposition of the two phases is assumed to be in the form of a shrinking core, where a shell of one phase covers a core of the second phase. Diffusion of lithium through the shell and the movement of the phase interface are described and incorporated into a porous electrode model consisting of two different particle sizes. Open-circuit measurements are used to estimate the composition ranges of the single-phase region. Model-experimental comparisons under constant current show that ohmic drops in the matrix phase, contact resistances between the current collector and the porous matrix, and transport limitations in the iron phosphate particle limit the power capability of the cells. Various design options, consisting of decreasing the ohmic drops, using smaller particles, and substituting the liquid electrolyte by a gel are explored, and their relative importance discussed. The model developed in this paper can be used as a means of optimizing the cell design to suit a particular application.

Srinivasan, Venkat; Newman, John

2004-02-28T23:59:59.000Z

346

Calculated power output from a thin iron-seeded plasma  

DOE Green Energy (OSTI)

Ionization equilibrium calculations are carried out for iron ions at a density of 10/sup 12/ cm/sup -3/ in a (hydrogen) plasma with electron density 10/sup 14/ cm/sup -3/, at temperatures from 0.8 to 10 keV. The computed radiated power loss from this plasma due to the iron ions ranges from about 4 W/cm/sup 3/ at the lowest temperature to about 0.4 W/cm/sup 3/ at the highest temperature; loss rates for other electron and ion densities will scale approximately as N/sub e/N/sub Fe/10/sup 26/. The losses are due principally to collisionally excited line radiation (especially ..delta..n = 0 transitions) at low temperatures, and to collisionally excited ..delta..n not equal to 0 transitions and to continuum radiative recombination at high temperatures. Spectra are also computed for diagnostic x-ray K/sub ..cap alpha../ (1s - 2p) transitions; the change in spectral distribution as a function of temperature agrees well with observations in the ST Tokamak. Bound-bound radiative transitions and dielectronic recombination are discussed at length in appendices; the latter process is of great importance in the establishment of ionization equilibrium, and in the excitation of K/sub ..cap alpha../ radiation at the lower temperatures.

Merts, A.L.; Cowan, R.D.; Magee, N.H. Jr.

1976-02-01T23:59:59.000Z

347

Long-Term Performance of a Passive Wastewater Treatment System: The Albright Project  

Science Conference Proceedings (OSTI)

The Albright passive wastewater treatment system, which receives alkaline leachate from a closed coal combustion by-product landfill, has operated continuously for 19 years. It has undergone two major upgrades to incorporate new passive technologies. Monitoring parameters have included pH, alkalinity, acidity, aluminum, iron, manganese, nickel, zinc, total dissolved solids, and total suspended solids, along with several other trace metals present at very low concentrations. This report summarizes the his...

2007-11-12T23:59:59.000Z

348

Onsite Wastewater Treatment Systems: Aerobic Treatment Unit  

E-Print Network (OSTI)

Aerobic units treat wastewater using the same process, only scaled down, as municipal wastewater treatment systems. This publication explains how aerobic units work, what their design requirements are, and how to maintain them.

Lesikar, Bruce J.

2008-10-31T23:59:59.000Z

349

Interplay of superconductivity, magnetism, and density waves in rare-earth tritellurides and iron-based superconducting materials  

E-Print Network (OSTI)

B. Superconductivity . . . . . . . . . . . . . . . . .IV Superconductivity and Magnetism in Iron-PnictideSearch for Pressure Induced Superconductivity in Undoped Ce-

Zocco, Diego Andrs

2011-01-01T23:59:59.000Z

350

Plutonium Tricks Cells by "Pretending" to be Iron | Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

A Chemical Detour to Quantum Criticality A Chemical Detour to Quantum Criticality Metallic Glass: A Crystal at Heart Brain Iron as an Early Predictor of Alzheimer's Disease Osmosis in Colloidal Suspensions Building a Better Battery Science Highlights Archives: 2013 | 2012 | 2011 | 2010 2009 | 2008 | 2007 | 2006 2005 | 2004 | 2003 | 2002 2001 | 2000 | 1998 | Subscribe to APS Science Highlights rss feed Plutonium Tricks Cells by "Pretending" to be Iron JULY 14, 2011 Bookmark and Share Structural models of bovine serum transferrins derived from x-ray studies at the Advanced Photon Source. Natural di-iron transferrin (yellow) and one mixed iron plutonium transferrin (green) are recognized and taken in by cells, while the other mixed plutonium iron transferrin (red) and di-plutonium transferrin (blue) are not recognized.

351

Sorption of Ferric Iron from Siderophore Complexes by Layer Type Manganese  

NLE Websites -- All DOE Office Websites (Extended Search)

Sorption of Ferric Iron from Siderophore Complexes by Layer Type Sorption of Ferric Iron from Siderophore Complexes by Layer Type Manganese Oxides Owen W. Duckworth (North Carolina State University), John R. Bargar (Stanford Synchrotron Radiation Lightsource), and Garrison Sposito (University of California-Berkeley) figure 1 Figure 1. Top: Iron is thought to limit phytoplankton in much of the world's oceans. Bottom: Structure of the iron-siderophore complex ferrioxamine B [Fe(III)HDFOB+]. Image courtesy of Andrzej Jarzecki, Brooklyn College, the City University of New York. Iron is one of several essential nutrients thought to limit phytoplankton growth in large areas of the world's oceans. The growth of marine phytoplankton represents a important linkage in the carbon cycle, accounting for approximately 50% of the total biological uptake of carbon

352

Iron-based Material Paves Way for New Superconductors | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Iron-based Material Paves Way for New Superconductors Iron-based Material Paves Way for New Superconductors Iron-based Material Paves Way for New Superconductors February 12, 2013 - 6:26pm Addthis Brookhaven physicists Weidong Si (left) and Qiang Li look into the vacuum chamber where the new high-field iron-based superconductors are made through a process called pulsed-laser deposition. Brookhaven physicists Weidong Si (left) and Qiang Li look into the vacuum chamber where the new high-field iron-based superconductors are made through a process called pulsed-laser deposition. Michael Hess Michael Hess Former Digital Communications Specialist, Office of Public Affairs How much better is this film? Under an intense 30-tesla magnetic field, the film carried a record-high 200,000 amperes per square centimeter.

353

DOE - Office of Legacy Management -- Rogers Iron Works Co - MO 10  

Office of Legacy Management (LM)

Rogers Iron Works Co - MO 10 Rogers Iron Works Co - MO 10 FUSRAP Considered Sites Site: ROGERS IRON WORKS CO. (MO.10 ) Elimination from consideration under FUSRAP Designated Name: Not Designated Alternate Name: Rogers Iron Co. MO.10-1 Location: Joplin , Missouri MO.10-1 Evaluation Year: 1990 MO.10-2 MO.10-3 Site Operations: Tested C-liner crushing methods. MO.10-1 Site Disposition: Eliminated - Potential for contamination considered remote based on limited quantities of material handled MO.10-3 MO.10-4 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Uranium (Trace Amounts) MO.10-2 Radiological Survey(s): None Indicated Site Status: Elimination from consideration under FUSRAP Also see Documents Related to ROGERS IRON WORKS CO. MO.10-1 - National Lead Company of Ohio Analytical Data Sheet 9908;

354

PHASE II CALDERON PROCESS TO PRODUCE DIRECT REDUCED IRON RESEARCH AND DEVELOPMENT PROJECT  

Science Conference Proceedings (OSTI)

This project was initially targeted to the making of coke for blast furnaces by using proprietary technology of Calderon in a phased approach, and Phase I was successfully completed. The project was then re-directed to the making of iron units. In 2000, U.S. Steel teamed up with Calderon for a joint effort which will last 42 months to produce directly reduced iron with the potential of converting it into molten iron or steel consistent with the Roadmap recommendations of 1998 prepared by the Steel Industry in cooperation with the Department of Energy by using iron ore concentrate and coal as raw materials, both materials being appreciably lower in cost than using iron pellets and coke.

Albert Calderon

2005-01-25T23:59:59.000Z

355

PHASE II CALDERON PROCESS TO PRODUCE DIRECT REDUCED IRON RESEARCH AND DEVELOPMENT PROJECT  

Science Conference Proceedings (OSTI)

This project was initially targeted to the making of coke for blast furnaces by using proprietary technology of Calderon in a phased approach, and Phase I was successfully completed. The project was then re-directed to the making of iron units. In 2000, U.S. Steel teamed up with Calderon for a joint effort to produce directly reduced iron with the potential of converting it into molten iron or steel consistent with the Roadmap recommendations of 1998 prepared by the Steel Industry in cooperation with the Department of Energy by using iron ore concentrate and coal as raw materials, both materials being appreciably lower in cost than using iron pellets, briquettes, sinter and coke.

Albert Calderon

2006-04-19T23:59:59.000Z

356

PHASE II CALDERON PROCESS TO PRODUCE DIRECT REDUCED IRON RESEARCH AND DEVELOPMENT PROJECT  

SciTech Connect

This project was initially targeted to the making of coke for blast furnaces by using proprietary technology of Calderon in a phased approach, and Phase I was successfully completed. The project was then re-directed to the making of iron units. In 2000, U.S. Steel teamed up with Calderon for a joint effort to produce directly reduced iron with the potential of converting it into molten iron or steel consistent with the Roadmap recommendations of 1998 prepared by the Steel Industry in cooperation with the Department of Energy by using iron ore concentrate and coal as raw materials, both materials being appreciably lower in cost than using iron pellets, briquettes, sinter and coke.

Albert Calderon

2006-01-30T23:59:59.000Z

357

PHASE II CALDERON PROCESS TO PRODUCE DIRECT REDUCED IRON RESEARCH AND DEVELOPMENT PROJECT  

SciTech Connect

This project was initially targeted to the making of coke for blast furnaces by using proprietary technology of Calderon in a phased approach, and Phase I was successfully completed. The project was then re-directed to the making of iron units. In 2000, U.S. Steel teamed up with Calderon for a joint effort which will last 42 months to produce directly reduced iron with the potential of converting it into molten iron or steel consistent with the Roadmap recommendations of 1998 prepared by the Steel Industry in cooperation with the Department of Energy by using iron ore concentrate and coal as raw materials, both materials being appreciably lower in cost than using iron pellets and coke.

Albert Calderon; Reina Calderon

2004-01-27T23:59:59.000Z

358

PHASE II CALDERON PROCESS TO PRODUCE DIRECT REDUCED IRON RESEARCH AND DEVELOPMENT PROJECT  

SciTech Connect

This project was initially targeted to the making of coke for blast furnaces by using proprietary technology of Calderon in a phased approach, and Phase I was successfully completed. The project was then re-directed to the making of iron units. In 2000, U.S. Steel teamed up with Calderon for a joint effort which will last 42 months to produce directly reduced iron with the potential of converting it into molten iron or steel consistent with the Roadmap recommendations of 1998 prepared by the Steel Industry in cooperation with the Department of Energy by using iron ore concentrate and coal as raw materials, both materials being appreciably lower in cost than using iron pellets and coke.

Albert Calderon

2004-07-28T23:59:59.000Z

359

PHASE II CALDERON PROCESS TO PRODUCE DIRECT REDUCED IRON RESEARCH AND DEVELOPMENT PROJECT  

Science Conference Proceedings (OSTI)

This project was initially targeted to the making of coke for blast furnaces by using proprietary technology of Calderon in a phased approach, and Phase I was successfully completed. The project was then re-directed to the making of iron units. In 2000, U.S. Steel teamed up with Calderon for a joint effort which will last 42 months to produce directly reduced iron with the potential of converting it into molten iron or steel consistent with the Roadmap recommendations of 1998 prepared by the Steel Industry in cooperation with the Department of Energy by using iron ore concentrate and coal as raw materials, both materials being appreciably lower in cost than using iron pellets and coke.

Albert Calderon

2005-07-29T23:59:59.000Z

360

PHASE II CALDERON PROCESS TO PRODUCE DIRECT REDUCED IRON RESEARCH AND DEVELOPMENT PROJECT  

Science Conference Proceedings (OSTI)

This project was initially targeted to the making of coke for blast furnaces by using proprietary technology of Calderon in a phased approach, and Phase I was successfully completed. The project was then re-directed to the making of iron units. In 2000, U.S. Steel teamed up with Calderon for a joint effort which will last 42 months to produce directly reduced iron with the potential of converting it into molten iron or steel consistent with the Roadmap recommendations of 1998 prepared by the Steel Industry in cooperation with the Department of Energy by using iron ore concentrate and coal as raw materials, both materials being appreciably lower in cost than using iron pellets and coke.

Albert Calderon

2004-04-27T23:59:59.000Z

Note: This page contains sample records for the topic "zero-valent iron treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

PHASE II CALDERON PROCESS TO PRODUCE DIRECT REDUCED IRON RESEARCH AND DEVELOPMENT PROJECT  

Science Conference Proceedings (OSTI)

This project was initially targeted to the making of coke for blast furnaces by using proprietary technology of Calderon in a phased approach, and Phase I was successfully completed. The project was then re-directed to the making of iron units. In 2000, U.S. Steel teamed up with Calderon for a joint effort which will last 42 months to produce directly reduced iron with the potential of converting it into molten iron or steel consistent with the Roadmap recommendations of 1998 prepared by the Steel Industry in cooperation with the Department of Energy by using iron ore concentrate and coal as raw materials, both materials being appreciably lower in cost than using iron pellets and coke.

Albert Calderon

2004-10-28T23:59:59.000Z

362

PHASE II CALDERON PROCESS TO PRODUCE DIRECT REDUCED IRON RESEARCH AND DEVELOPMENT PROJECT  

Science Conference Proceedings (OSTI)

This project was initially targeted to the making of coke for blast furnaces by using proprietary technology of Calderon in a phased approach, and Phase I was successfully completed. The project was then re-directed to the making of iron units. In 2000, U.S. Steel teamed up with Calderon for a joint effort which will last 42 months to produce directly reduced iron with the potential of converting it into molten iron or steel consistent with the Roadmap recommendations of 1998 prepared by the Steel Industry in cooperation with the Department of Energy by using iron ore concentrate and coal as raw materials, both materials being appreciably lower in cost than using iron pellets and coke.

Albert Calderon

2005-01-26T23:59:59.000Z

363

PHASE II CALDERON PROCESS TO PRODUCE DIRECT REDUCED IRON RESEARCH AND DEVELOPMENT PROJECT  

SciTech Connect

This project was initially targeted to the making of coke for blast furnaces by using proprietary technology of Calderon in a phased approach, and Phase I was successfully completed. The project was then re-directed to the making of iron units. In 2000, U.S. Steel teamed up with Calderon for a joint effort which will last 42 months to produce directly reduced iron with the potential of converting it into molten iron or steel consistent with the Roadmap recommendations of 1998 prepared by the Steel Industry in cooperation with the Department of Energy by using iron ore concentrate and coal as raw materials, both materials being appreciably lower in cost than using iron pellets and coke.

Albert Calderon

2003-10-22T23:59:59.000Z

364

Phase II Calderon Process to Produce Direct Reduced Iron Research and Development Project  

Science Conference Proceedings (OSTI)

This project was initially targeted to the making of coke for blast furnaces by using proprietary technology of Calderon in a phased approach, and Phase 1 was successfully completed. The project was then re-directed to the making of iron units. In 2000, U.S. Steel teamed up with Calderon for a joint effort to produce directly reduced iron with the potential of converting it into molten iron or steel consistent with the Roadmap recommendations of 1998 prepared by the Steel Industry in cooperation with the Department of Energy by using iron ore concentrate and coal as raw materials, both materials being appreciably lower in cost than using iron pellets, briquettes, sinter and coke.

Albert Calderon

2007-03-31T23:59:59.000Z

365

Emergency Medical Treatment Required  

E-Print Network (OSTI)

Emergency Medical Treatment Required Non-Emergency Medical Treatment Required If possible, get help present if possible OptaComp will complete the "First Report of Injury or Illness" and authorize medical Investigation Report" to Environmental Health & Safety within 48 hours Emergency Medical Treatment Required

Weston, Ken

366

RESULTS FROM RECENT SCIENCE AND TECHNOLOGY INVESTIGATIONS TARGETING CHROMIUM IN THE 100D AREA HANFORD SITE WASHINGTON USA  

SciTech Connect

Sodium dichromate was used in Hanford's 100D Area during the reactor operations period of 1950 to 1964 to retard corrosion in the reactor cooling systems. Some of the sodium dichromate was released to the environment by spills and/or leaks from pipelines used to deliver the chemical to water treatment plants in the area. As a result, hexavalent chromium [Cr(VI)] has migrated through the vadose zone to the groundwater and contaminated nearly 1 km{sup 2} of groundwater to above the drinking water standard of 48 {micro}g/L. Three technology tests have recently been completed in this area to characterize the source area of the plumes and evaluate alternative methods to remove Cr(VI) from groundwater. These are (1) refine the source area of the southern plume; (2) test electrocoagulation as an alternative groundwater treatment technology; and (3) test the ability to repair a permeable reactive barrier by injecting micron or nanometer-size zero-valent iron (ZVI). The projects were funded by the US Department of Energy as part of a program to interject new technologies and accelerate active cleanup. Groundwater monitoring over the past 10 years has shown that Cr(VI) concentrations in the southern plume have not significantly diminished, strongly indicating a continuing source. Eleven groundwater wells were installed in 2007 and 2008 near a suspected source area and monitored for Cr(VI) and groundwater levels. Interpretation of these data has led to refinement of the source area location to an area of less than 1 hectare (ha, 2.5 acres). Vadose zone soil samples collected during drilling did not discover significant concentrations of Cr(VI), indicating the source is localized, with a narrow wetted path from the surface to the water table. Electrocoagulation was evaluated through a pilot-scale treatability test. Over 8 million liters of groundwater were treated to Cr(VI) concentrations of {le}20 {micro}g/L. The test determined that this technology has the potential to treat Cr(VI) to these low levels, but system reliability and operational complexity rendered electrocoagulation less cost effective than the baseline technology of ion exchange. Laboratory and field tests were conducted to evaluate the practicality of injecting ZVI into the aquifer to increase the lifespan and effectiveness of an existing permeable reactive barrier. From a database of 30 ZVI materials, 6 were chosen and tested in the laboratory to determine their geochemical and physical performance under simulated 100D aquifer conditions. The best-performing ZVI was injected into the aquifer and met the primary goals of communicating the iron at least 7 meters from the injection point and reducing the aquifer to transform mobile Cr(VI) to trivalent chromium Cr(III), which is effectively immobile in the aquifer.

PETERSEN SW; THOMPSON KM; TONKIN MJ

2009-12-03T23:59:59.000Z

367

City of Mountain Iron, Minnesota (Utility Company) | Open Energy  

Open Energy Info (EERE)

Minnesota (Utility Company) Minnesota (Utility Company) Jump to: navigation, search Name City of Mountain Iron Place Minnesota Utility Id 13044 Utility Location Yes Ownership M NERC Location MRO NERC MRO Yes Activity Distribution Yes References EIA Form EIA-861 Final Data File for 2010 - File1_a[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Utility Rate Schedules Grid-background.png General Service Rate Commercial Municipal Service Rate: No Demand meter Commercial Municipal Service Rate: With Demand meter Industrial Off-Peak Water Heating Commercial Power Service Rate Industrial Residential Service Rate Residential Average Rates Residential: $0.0948/kWh Commercial: $0.1180/kWh Industrial: $0.1300/kWh

368

The Superpower behind Iron Oxyfluoride Battery Electrodes | Advanced Photon  

NLE Websites -- All DOE Office Websites (Extended Search)

Watching a Protein as it Functions Watching a Protein as it Functions Shedding Light on Chemistry with a Biological Twist Teasing Out the Nature of Structural Instabilities in Ceramic Compounds Doubling Estimates of Light Elements in the Earth's Core A New Material for Warm-White LEDs Science Highlights Archives: 2013 | 2012 | 2011 | 2010 2009 | 2008 | 2007 | 2006 2005 | 2004 | 2003 | 2002 2001 | 2000 | 1998 | Subscribe to APS Science Highlights rss feed The Superpower behind Iron Oxyfluoride Battery Electrodes APRIL 2, 2013 Bookmark and Share Structural changes probed using operando PDF analysis indicates a partitioning of a FeOF-based electrode into fluorine- and oxygen-rich phases with different reactivity for each component. Innovative materials chemistries continue to drive advances in lithium-ion

369

Climate VISION: Private Sector Initiatives: Iron and Steel: GHG Information  

Office of Scientific and Technical Information (OSTI)

GHG Information GHG Information This section provides various sources describing the energy consumption of the industrial sector and the carbon emissions in particular. Below is an estimate of the million metric tons of carbon dioxide emissions (MMTCO2) based upon the Annual Energy Outlook 2007. According to EIA "Annual Energy Outlook 2007" data, energy-related CO2 emissions projected for the Iron and Steel industry were 133.5 MMTCO2 in 2006. The AEO Supplementary Tables were generated for the reference case of the Annual Energy Outlook 2007 using the National Energy Modeling System, a computer-based model which produces annual projections of energy markets for 2005-2030. The AEO2007 reflects data and information available as of September 15, 2006. Source: Annual Energy Outlook 2007 (PDF 38.44 KB) with

370

Climate VISION: Private Sector Initiatives: Iron and Steel: Resources and  

Office of Scientific and Technical Information (OSTI)

Resources & Links Resources & Links Software Tools Steel Industry of the Future Tools & Publications The Industrial Technologies Program offers a wide array of publications, videos, software, and other information products for improving energy efficiency in the iron and steel industry. DOE BestPractices Software Tools DOE BestPractices offers a range of software tools and databases that help manufacturers assess their plant's steam, compressed air, motor, and process heating systems. DOE Plant Energy Profiler Industry experience has shown that many plant utility personnel do not have an adequate understanding of their energy cost structure and where the major focus should be for any energy savings program. This tool will address this need and enable an engineer assigned to a plant utility to

371

Technology development for iron Fischer-Tropsch catalysts  

DOE Green Energy (OSTI)

Objective is to develop producing active, stable iron Fischer-Tropsch catalysts for use in slurry-phase synthesis reactors and to synthesize such catalysts on a large scale for process development and long-term testing in slurry bubble-column reactors. A mixed oxalate of Fe, Cu, and K was prepared; a catalyst will be prepared from this material. An evaluation run was performed on an Fe-based UCI catalyst, which was shown to produce low levels of C[sub 1] and C[sub 2] paraffins; e.g., at the end of the run, when the catalyst was converting 60% of the CO, the C[sub 1] and C[sub 2] paraffin selectivities were 4.2 and 1.0, respectively.

Frame, R.R.; Gala, H.B.

1992-12-22T23:59:59.000Z

372

All Metal Iron Core For A Low Aspect Ratio Tokamak  

Science Conference Proceedings (OSTI)

A novel concept for incorporating a iron core transformer within a axisymmetric toroidal plasma containment device with a high neutron flux is described. This design enables conceptual design of low aspect ratio devices which employ standard transformer-driven plasma startup by using all-metal high resistance separators between the toroidal field windings. This design avoids the inherent problems of a multiturn air core transformer which will inevitably suffer from strong neutron bombardment and hence lose the integrity of its insulation, both through long term material degradation and short term neutron- induced conductivity.. A full 3-dimensional model of the concept has been developed within the MAXWELL program and the resultant loop voltage calculated. The utility of the result is found to be dependent on the resistivity of the high resistance separators. Useful loop voltage time histories have been obtained using achievable resistivities.

D.A. Gates, C. Jun, I. Zatz, A. Zolfaghari

2010-06-02T23:59:59.000Z

373

Development of Improved Iron-Aluminide Filter Tubes and Elements  

SciTech Connect

The purpose of this Cooperative Research and Development Agreement (CRADA) was to explore and develop advanced manufacturing techniques to fabricate sintered iron-aluminide intermetallic porous bodies used for gas filtration so as to reduce production costs while maintaining or improving performance in advanced coal gasification and combustion systems. The use of a power turbine fired with coal-derived synthesis gas requires some form of gas cleaning in order to protect turbine and downstream components from degradation by erosion, corrosion, and/or deposition. Hot-gas filtration is one form of cleaning that offers the ability to remove particles from the gases produced by gasification processes without having to substantially cool and, possibly, reheat them before their introduction into the turbine. This technology depends critically on materials durability and reliability, which have been the subject of study for a number of years.

Judkins, R.R.; Sutton, T.G.; Miller, C.J.; Tortorelli, P.F.

2008-01-14T23:59:59.000Z

374

Energy and materials flows in the iron and steel industry  

SciTech Connect

Past energy-consumption trends and future energy-conservation opportunities are investigated for the nation's iron and steel industry. It is estimated that, in 1980, the industry directly consumed approximately 2.46 x 10/sup 15/ Btu of energy (roughly 3% of total US energy consumption) to produce 111 million tons of raw steel and to ship 84 million tons of steel products. Direct plus indirect consumption is estimated to be about 3.1 x 10/sup 15/ Btu. Of the set of conservation technologies identified, most are judged to be ready for commercialization if and when the industry's capital formation and profitability problems are solved and the gradual predicted increase in energy prices reduces the payback periods to acceptable levels.

Sparrow, F.T.

1983-06-01T23:59:59.000Z

375

Reduced Beta Decay Rates of Iron Isotopes for Supernova Physics  

SciTech Connect

During the late phases of stellar evolution beta decay on iron isotopes, in the core of massive stars, plays a crucial role in the dynamics of core-collapse. The beta decay contributes in maintaining a 'respectable' lepton-to-baryon ratio (PSI{sub e}) of the core prior to collapse which results in a larger shock energy to power the explosion. It is indeed a fine tuning of the parameter PSI{sub e} at various stages of supernova physics which can lead to a successful transformation of the collapse into an explosion. The calculations presented here might help in fine-tuning of PSI{sub e} for the collapse simulators of massive stars.

Nabi, Jameel-Un [Faculty of Engineering Sciences, GIK Institute of Engineering Sciences and Technology, Topi 23460, N.W.F.P. (Pakistan)

2009-07-07T23:59:59.000Z

376

A Comparison of Iron and Steel Production Energy Use and Energy Intensity  

NLE Websites -- All DOE Office Websites (Extended Search)

A Comparison of Iron and Steel Production Energy Use and Energy Intensity A Comparison of Iron and Steel Production Energy Use and Energy Intensity in China and the U.S. Title A Comparison of Iron and Steel Production Energy Use and Energy Intensity in China and the U.S. Publication Type Report Year of Publication 2011 Authors Hasanbeigi, Ali, Lynn K. Price, Nathaniel T. Aden, Zhang Chunxia, Li Xiuping, and Shangguan Fangqin Date Published June/2011 Publisher Lawrence Berkeley National Laboratory; Iron & Steel Research Institute, Iron and Steel Industry Keywords energy intensity, energy use, Low Emission & Efficient Industry Abstract Production of iron and steel is an energy-intensive manufacturing process. In 2006, the iron and steel industry accounted for 13.6% and 1.4% of primary energy consumption in China and the U.S., respectively (U.S. DOE/EIA, 2010a; Zhang et al., 2010). The energy efficiency of steel production has a direct impact on overall energy consumption and related carbon dioxide (CO2) emissions. The goal of this study is to develop a methodology for making an accurate comparison of the energy intensity (energy use per unit of steelproduced) of steel production. The methodology is applied to the steel industry in China and the U.S. The methodology addresses issues related to boundary definitions, conversion factors, and indicators in order industry energy use to develop a common framework for comparing steel intensity energy use.

377

Nickel-iron battery system safety. Final report  

DOE Green Energy (OSTI)

Eagle-Picher Industries conducted a literature search and experimental tests to characterize the generated flow rates of gaseous hydrogen (GH/sub 2/) and gaseous oxygen (GO/sub 2/) from an electrical vehicle (EV) nickel-iron battery system. The resulting gassing rates were used to experimentally evaluate the flame quenching capabilities of several candidate devices to prevent the propagation of flame within batteries having central watering/venting systems. The battery generated hydrogen (GH/sub 2/) and oxygen (GO/sub 2/) gasses were measured for a complete charge and discharge cycle. The data correlates well with accepted theory during strong overcharge conditions indicating that the measurements are valid for other portions of the cycle. Tests have confirmed that the gas mixture in the cells is always flammable regardless of the battery status. Research of flame arrestor literature yielded little information regarding their operation with hydrogen-oxygen mixtures. It was indicated that a conventional flame arrestor would not be effective over the broad spectrum of gassing conditions presented by a nickel-iron battery. Four different types of protective devices were evaluated. A foam-metal arrestor design was successful in quenching GH/sub 2/-GO/sub 2/ flames, however; the application of this flame arrestor to individual cell or module protection in a battery is problematic. A possible rearrangement of the watering/venting system to accept the partial protection of simple one-way valves is presented. This in combination with the successful foam-metal arrestor as main vent protection, could result in a significant improvement in battery protection. This concept was not tested.

Saltat, R.

1984-06-01T23:59:59.000Z

378

Variable Iron K-alpha Lines in Seyfert 1 Galaxies  

E-Print Network (OSTI)

We find that variability of the iron K-alpha line is common in Seyfert 1 galaxies. Using data from the ASCA archive for objects that have been observed more than once during the mission, we study the time-averaged spectra from individual observations, thereby probing variability on timescales that range from days to years. Since the statistics of the data do not warrant searches for line variability in terms of a complex physical model, we use a a simple Gaussian to model the gross shape of the line, and then use the centroid energy, intensity and equivalent width as robust indicators of changes in the line profile. We find that ~70% of Seyfert 1s (ten out of fifteen) show variability in at least one of these parameters: the centroid energy, intensity, and equivalent width vary in six, four, and eight sources respectively. Due to the low S/N, limited sampling and time averaging, we consider these results to represent lower limits to the rate of incidence of variability. In most cases changes in the line do not appear to track changes in the continuum. In particular, we find no evidence for variability of the line intensity in NGC 4151, suggesting an origin in a region larger than the putative accretion disk, where most of the iron line has been thought to originate. Mkn 279 is investigated on short timescales. The time-averaged effective line energy is 6.5 keV in the galaxy rest frame. As the continuum flux increases by 20% in a few hours, the Fe K line responds with the effective line energy increasing by 0.22 keV (~10,500 km s^-1). Problems with the ASCA and Rosat calibration that affect simultaneous spectral fits are discussed in an appendix.

K. A. Weaver; J. Gelbord; T. Yaqoob

2000-08-31T23:59:59.000Z

379

An Octahedral Coordination Complex of Iron(VI)  

NLE Websites -- All DOE Office Websites (Extended Search)

ferrate.1 Ferrate is a powerful oxidant, which has been used in soil and wastewater treatment, batteries, and disinfectants; however, it is unstable and often indiscriminately...

380

Energy Saving Melting and Revert Reduction Technology: Aging of Graphitic Cast Irons and Machinability  

SciTech Connect

The objective of this task was to determine whether ductile iron and compacted graphite iron exhibit age strengthening to a statistically significant extent. Further, this effort identified the mechanism by which gray iron age strengthens and the mechanism by which age-strengthening improves the machinability of gray cast iron. These results were then used to determine whether age strengthening improves the machinability of ductile iron and compacted graphite iron alloys in order to develop a predictive model of alloy factor effects on age strengthening. The results of this work will lead to reduced section sizes, and corresponding weight and energy savings. Improved machinability will reduce scrap and enhance casting marketability. Technical Conclusions: ???¢???????¢ Age strengthening was demonstrated to occur in gray iron ductile iron and compacted graphite iron. ???¢???????¢ Machinability was demonstrated to be improved by age strengthening when free ferrite was present in the microstructure, but not in a fully pearlitic microstructure. ???¢???????¢ Age strengthening only occurs when there is residual nitrogen in solid solution in the Ferrite, whether the ferrite is free ferrite or the ferrite lamellae within pearlite. ???¢???????¢ Age strengthening can be accelerated by Mn at about 0.5% in excess of the Mn/S balance Estimated energy savings over ten years is 13.05 trillion BTU, based primarily on yield improvement and size reduction of castings for equivalent service. Also it is estimated that the heavy truck end use of lighter castings for equivalent service requirement will result in a diesel fuel energy savings of 131 trillion BTU over ten years.

Von L. Richards

2012-09-19T23:59:59.000Z

Note: This page contains sample records for the topic "zero-valent iron treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Development of an Alternative Treatment Scheme for Sr/TRU Removal: Permanganate Treatment of AN-107 Waste  

SciTech Connect

A number of Hanford tanks received waste containing organic complexants, which increase the volubility of Sr-90 and transuranic (TRU) elements. Wastes from these tanks require additional pretreatment to remove Sr-90 and TRU for immobilization as low activity waste (Waste Envelope C). The baseline pretreatment process for Sr/TRU removal was isotopic exchange and precipitation with added strontium and iron. However, studies at both Battelle and Savannah River Technology Center (SRTC) have shown that the Sr/Fe precipitates were very difficult to filter. This was a result of the formation of poor filtering iron solids. An alternate treatment technology was needed for Sr/TRU removal. Battelle had demonstrated that permanganate treatment was effective for decontaminating waste samples from Hanford Tank SY-101 and proposed that permanganate be examined as an alternative Sr/TRU removal scheme for complexant-containing tank wastes such as AW107. Battelle conducted preliminary small-scale experiments to determine the effectiveness of permanganate treatment with AN-107 waste samples that had been archived at Battelle from earlier studies. Three series of experiments were performed to evaluate conditions that provided adequate Sr/TRU decontamination using permanganate treatment. The final series included experiments with actual AN-107 diluted feed that had been obtained specifically for BNFL process testing. Conditions that provided adequate Sr/TRU decontamination were identified. A free hydroxide concentration of 0.5M provided adequate decontamination with added Sr of 0.05M and permanganate of 0.03M for archived AN-107. The best results were obtained when reagents were added in the sequence Sr followed by permanganate with the waste at ambient temperature. The reaction conditions for Sr/TRU removal will be further evaluated with a 1-L batch of archived AN-107, which will provide a large enough volume of waste to conduct crossflow filtration studies (Hallen et al. 2000a).

RT Hallen; SA Bryan; FV Hoopes

2000-08-04T23:59:59.000Z

382

PHASE II CALDERON PROCESS TO PRODUCE DIRECT REDUCED IRON RESEARCH AND DEVELOPMENT PROJECT  

Science Conference Proceedings (OSTI)

This project was initially targeted to the making of coke for blast furnaces by using proprietary technology of Calderon in a phased approach, and Phase I was successfully completed. The project was then re-directed to the making of iron units. U.S. Steel teamed up with Calderon for a joint effort which will last 30 months to produce directly reduced iron with the potential of converting it into molten iron or steel consistent with the Roadmap recommendations of 1998 prepared by the Steel Industry in cooperation with the Department of Energy.

Albert Calderon

2003-01-28T23:59:59.000Z

383

Phase II Calderon Process to Produce Direct Reduced Iron Research and Development Project  

Science Conference Proceedings (OSTI)

This project was initially targeted to the making of coke for blast furnaces by using proprietary technology of Calderon in a phased approach, and Phase I was successfully completed. The project was then re-directed to the making of iron units. U.S. Steel teamed up with Calderon for a joint effort which will last 42 months to produce directly reduced iron with the potential of converting it into molten iron or steel consistent with the Roadmap recommendations of 1998 prepared by the Steel Industry in cooperation with the Department of Energy.

Albert Calderon

2003-06-30T23:59:59.000Z

384

PHASE II CALDERON PROCESS TO PRODUCE DIRECT REDUCED IRON RESEARCH AND DEVELOPMENT PROJECT  

SciTech Connect

This project was initially targeted to the making of coke for blast furnaces by using proprietary technology of Calderon in a phased approach, and Phase I was successfully completed. The project was then re-directed to the making of iron units. U.S. Steel teamed up with Calderon for a joint effort which will last 30 months to produce directly reduced iron with the potential of converting it into molten iron or steel consistent with the Roadmap recommendations of 1998 prepared by the Steel Industry in cooperation with the Department of Energy.

Albert Calderon

2003-04-28T23:59:59.000Z

385

Numerical study: Iron corrosion-resistance in lead-bismuth eutectic coolant by molecular dynamics method  

Science Conference Proceedings (OSTI)

In this present work, we report numerical results of iron (cladding) corrosion study in interaction with lead-bismuth eutectic coolant of advanced nuclear reactors. The goal of this work is to study how the oxygen can be used to reduce the corrosion rate of cladding. The molecular dynamics method was applied to simulate corrosion process. By evaluating the diffusion coefficients, RDF functions, MSD curves of the iron and also observed the crystal structure of iron before and after oxygen injection to the coolant then we concluded that a significant and effective reduction can be achieved by issuing about 2% number of oxygen atoms to lead-bismuth eutectic coolant.

Arkundato, Artoto; Su'ud, Zaki; Abdullah, Mikrajuddin; Widayani,; Celino, Massimo [Nuclear Physics and Biophysics Research Division, Physics Department Institut Teknologi Bandung, Jl. Ganesha 10, Bandung Physics Department, Faculty of Mathematical and Natural Sciences Universitas (Indonesia); Nuclear Physics and Biophysics Research Division, Physics Department Institut Teknologi Bandung, Jl. Ganesha 10, Bandung (Indonesia); ENEA, CR Cassacia, Via Anguillarese 301, Roma (Italy)

2012-06-06T23:59:59.000Z

386

Computational study: Reduction of iron corrosion in lead coolant of fast nuclear reactor  

SciTech Connect

In this paper we report molecular dynamics simulation results of iron (cladding) corrosion in interaction with lead coolant of fast nuclear reactor. The goal of this work is to study effect of oxygen injection to the coolant to reduce iron corrosion. By evaluating diffusion coefficients, radial distribution functions, mean-square displacement curves and observation of crystal structure of iron before and after oxygen injection, we concluded that a significant reduction of corrosion can be achieved by issuing about 2% of oxygen atoms into lead coolant.

Arkundato, Artoto; Su'ud, Zaki; Abdullah, Mikrajuddin; Widayani [Physics Department, ITB, Bandung (Indonesia) and Physics Department, University of Jember, Jl. Kalimantan III/25, Jember (Indonesia); Physics Department, ITB Jl. Ganesha 10, Bandung (Indonesia)

2012-06-20T23:59:59.000Z

387

Decaking of coal or oil shale during pyrolysis in the presence of iron oxides  

DOE Patents (OSTI)

A method for producing a fuel from the pyrolysis of coal or oil shale in the presence of iron oxide in an inert gas atmosphere. The method includes the steps of pulverizing feed coal or oil shale, pulverizing iron oxide, mixing the pulverized feed and iron oxide, and heating the mixture in a gas atmosphere which is substantially inert to the mixture so as to form a product fuel, which may be gaseous, liquid and/or solid. The method of the invention reduces the swelling of coals, such as bituminous coal and the like, which are otherwise known to swell during pyrolysis.

Khan, M. Rashid (Morgantown, WV)

1989-01-01T23:59:59.000Z

388

Decaking of coal or oil shale during pyrolysis in the presence of iron oxides  

DOE Patents (OSTI)

A method for producing a fuel from the pyrolysis of coal or oil shale in the presence of iron oxide in an inert gas atmosphere is described. The method includes the steps of pulverizing feed coal or oil shale, pulverizing iron oxide, mixing the pulverized feed and iron oxide, and heating the mixture in a gas atmosphere which is substantially inert to the mixture so as to form a product fuel, which may be gaseous, liquid and/or solid. The method of the invention reduces the swelling of coals, such as bituminous coal and the like, which are otherwise known to swell during pyrolysis. 4 figs., 8 tabs.

Rashid Khan, M.

1988-05-05T23:59:59.000Z

389

Mixed Waste Treatment Study  

Science Conference Proceedings (OSTI)

As part of an ongoing integrated mixed waste program, EPRI has documented nuclear utility industry experience in the on-site treatment of mixed waste. This report reviews all available exclusions/exceptions to EPA permitting requirements for environmentally responsible on-site management of mixed waste. Included is a description of emerging mixed waste treatment technologies along with a detailed evaluation of off-site treatment/disposal facilities.

1996-01-31T23:59:59.000Z

390

Demystifying water treatment  

SciTech Connect

Increasingly accountable for the environmental quality and cost of managing their waste and process water streams, customers require more precise data about the constituents in their water. This has forced suppliers to unlock some of the secrets of water treatment. In the open exchange of information, users are trading in esoteric formulations for products that are more chemical efficient and environmentally benign. Factoring more prominently in the water treatment equation are service and supply. This paper reviews some of these simpler treatments.

Hairston, D.

1994-09-01T23:59:59.000Z

391

Arsenic remediation of drinking water using iron-oxide coated coal bottom ash  

Science Conference Proceedings (OSTI)

We describe laboratory and field results of a novel arsenic removal adsorbent called 'Arsenic Removal Using Bottom Ash' (ARUBA). ARUBA is prepared by coating particles of coal bottom ash, a waste material from coal fired power plants, with iron (hydr)oxide. The coating process is simple and conducted at room temperature and atmospheric pressure. Material costs for ARUBA are estimated to be low (~;;$0.08 per kg) and arsenic remediation with ARUBA has the potential to be affordable to resource-constrained communities. ARUBA is used for removing arsenic via a dispersal-and-removal process, and we envision that ARUBA would be used in community-scale water treatment centers. We show that ARUBA is able to reduce arsenic concentrations in contaminated Bangladesh groundwater to below the Bangladesh standard of 50 ppb. Using the Langmuir isotherm (R2 = 0.77) ARUBA's adsorption capacity in treating real groundwater is 2.6x10-6 mol/g (0.20 mg/g). Time-to-90percent (defined as the time interval for ARUBA to remove 90percent of the total amount of arsenic that is removed at equilibrium) is less than one hour. Reaction rates (pseudo-second-order kinetic model, R2>_ 0.99) increase from 2.4x105 to 7.2x105 g mol-1 min-1 as the groundwater arsenic concentration decreases from 560 to 170 ppb. We show that ARUBA's arsenic adsorption density (AAD), defined as the milligrams of arsenic removed at equilibrium per gram of ARUBA added, is linearly dependent on the initial arsenic concentration of the groundwater sample, for initial arsenic concentrations of up to 1600 ppb and an ARUBA dose of 4.0 g/L. This makes it easy to determine the amount of ARUBA required to treat a groundwater source when its arsenic concentration is known and less than 1600 ppb. Storing contaminated groundwater for two to three days before treatment is seen to significantly increase ARUBA's AAD. ARUBA can be separated from treated water by coagulation and clarification, which is expected to be less expensive than filtration of micron-scale particles, further contributing to the affordability of a community-scale water treatment center.

MATHIEU, JOHANNA L.; GADGIL, ASHOK J.; ADDY, SUSAN E.A.; KOWOLIK, KRISTIN

2010-06-01T23:59:59.000Z

392

Water treatment on wheels  

Science Conference Proceedings (OSTI)

Design options and combinations of fixed and mobile demineralization equipment give power plant operators the flexibility to continually optimize their water treatment system to meet rapidly changing needs. The article classifies water treatment service contracts for demineralized water into four categories and presents associated design, economic and operational advantages to power plant designers, constructors, owners and operators. 1 tab.

Taylor, R.T.

2005-09-01T23:59:59.000Z

393

DOE - Office of Legacy Management -- Colorado Fuel and Iron - NY 0-08  

Office of Legacy Management (LM)

Fuel and Iron - NY 0-08 Fuel and Iron - NY 0-08 FUSRAP Considered Sites Site: Colorado Fuel and Iron (NY.0-08 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Watervliet , New York NY.0-08-1 Evaluation Year: 1987 NY.0-08-1 Site Operations: Site was a contractor to DuPont. Exact nature of operations is not clear. No records to indicate that radioactive materials were handled at the site. NY.0-08-1 Site Disposition: Eliminated NY.0-08-1 Radioactive Materials Handled: None Indicated Primary Radioactive Materials Handled: None Indicated Radiological Survey(s): None Indicated Site Status: Eliminated from consideration under FUSRAP Also see Documents Related to Colorado Fuel and Iron NY.0-08-1 - DOE Memorandum/Checklist; S.Jones to the File; Subject:

394

Land UseIron Pollution in Mangrove Habitat of Karachi, Indus Delta  

Science Conference Proceedings (OSTI)

The coastal area of Karachi, Pakistan, which lies at the northwestern part of the Indus delta, is heavily polluted particularly in the mangrove habitat. The present study traces the pathway of trace metal iron from the source to the different ...

S. M. Saifullah; Sarwat Ismail; S. H. Khan; M. Saleem

2004-12-01T23:59:59.000Z

395

U-102: Cisco IronPort Encryption Appliance Input Validation Flaw Permits  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

2: Cisco IronPort Encryption Appliance Input Validation Flaw 2: Cisco IronPort Encryption Appliance Input Validation Flaw Permits Cross-Site Scripting Attacks U-102: Cisco IronPort Encryption Appliance Input Validation Flaw Permits Cross-Site Scripting Attacks February 14, 2012 - 8:00am Addthis PROBLEM: A vulnerability was reported in Cisco IronPort Encryption Appliance. PLATFORM: Version(s): prior to 6.5.3 ABSTRACT: A remote user can conduct cross-site scripting reference LINKS: Vendor URL CVE-2012-0340 Security Tracker ID:1026669 IMPACT ASSESSMENT: Medium Discussion: The interface does not properly filter HTML code from user-supplied input before displaying the input. A remote user can create a specially crafted URL that, when loaded by a target user, will cause arbitrary scripting code to be executed by the target user's browser. The code will originate from

396

Removal of Phosphorus from Lisakovsky Iron Ore by a Roast-Leach ...  

Science Conference Proceedings (OSTI)

Aug 1, 2003 ... Lisakovsky is a 3-billion ton oolitic iron ore deposit in north-central Kazakhstan operated by Orken LLP, a subsidiary of Ispat Karmet and the...

397

A metallurgical study of West African iron monies from Cameroon and Liberia  

E-Print Network (OSTI)

The aim of this thesis is to make a contribution to the study of West African iron monies through examination and analysis of a group of these objects in the collection of the Peabody Museum of Archaeology and Ethnology ...

Papakirillou, Ismini

2009-01-01T23:59:59.000Z

398

ESS 2012 Peer Review - Iron Based Flow Batteries for Low Cost...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

EnergyOffice of Electricity's Energy Storage Program. Iron Based Flow Batteries for Low Cost Grid Level Energy Storage J.S. Wainright, R. F. Savinell, P.I.s Dept. of Chemical...

399

The Antioxidant Vitamins C & EChapter 3 Biochemical and Physiological Interactions of Vitamin C and Iron  

Science Conference Proceedings (OSTI)

The Antioxidant Vitamins C & E The Antioxidant Vitamins C & E Chapter 3 Biochemical and Physiological Interactions of Vitamin C and Iron eChapters Health - Nutrition - Biochemistry Press Downloadable pdf of Chapter

400

Nickel aluminides and nickel-iron aluminides for use in oxidizing environments  

SciTech Connect

Nickel aluminides and nickel-iron aluminides treated with hafnium or zirconium, boron and cerium to which have been added chromium to significantly improve high temperature ductility, creep resistance and oxidation properties in oxidizing environments.

Liu, Chain T. (Oak Ridge, TN)

1988-03-15T23:59:59.000Z

Note: This page contains sample records for the topic "zero-valent iron treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Oxidation of phosphine by iron(III) chloride complexes supported on activated charcoal  

SciTech Connect

It has been discovered that iron(III) chloride complexes supported on activated charcoal oxidize phosphine under normal conditions. The process accelerates as the concentration of the chloride ions and the proton acid increases.

Rakitskaya, T.L.; Kostyukova, I.S.; Red'ko, T.D.

1988-06-01T23:59:59.000Z

402

Influences on the oceanic biogeochemical cycling of the hybrid-type metals, cobalt, iron, and manganese  

E-Print Network (OSTI)

Trace metal cycling is one of many processes that influence ocean ecosystem dynamics. Cobalt, iron, and manganese are redox active trace metal micro-nutrients with oceanic distributions that are influenced by both biological ...

Noble, Abigail Emery

2012-01-01T23:59:59.000Z

403

Separation of Fischer-Tropsch Wax Products from Ultrafine Iron Catalyst Particles  

Science Conference Proceedings (OSTI)

A fundamental filtration study was started to investigate the separation of Fischer-Tropsch Synthesis (FTS) liquids from iron-based catalyst particles. Slurry-phase FTS in slurry bubble column reactor systems is the preferred mode of operation since the reaction is highly exothermic. Consequently, heavy wax products in one approach may be separated from catalyst particles before being removed from the reactor system. Achieving an efficient wax product separation from iron-based catalysts is one of the most challenging technical problems associated with slurry-phase iron-based FTS and is a key factor for optimizing operating costs. The separation problem is further compounded by attrition of iron catalyst particles and the formation of ultra-fine particles.

Amitava Sarkar; James K. Neathery; Burtron H. Davis

2006-12-31T23:59:59.000Z

404

Impacts of increasing anthropogenic soluble iron and nitrogen deposition on ocean biogeochemistry  

E-Print Network (OSTI)

from dust and combustion sources (only biomass burning underCombustion sources of soluble iron were important near industrial and biomasscombustion from power plants and industry dominate. Biofuel and biomass

2009-01-01T23:59:59.000Z

405

Study on Apprasial Model of Iron Ores Based on Multi-level Fuzzy ...  

Science Conference Proceedings (OSTI)

Chemical Enrichment of Precious Metals in Iron Sulfides Using Microwave Energy Chloridizing ... Co-Gasification Behavior of Metallurgical Coke with High and Low Reactivity .... Thermal Plasma Torches for Metallurgical Applications.

406

Study on Swelling Behavior of Iron Ore Pellets in Direct Reduction ...  

Science Conference Proceedings (OSTI)

Chemical Enrichment of Precious Metals in Iron Sulfides Using Microwave Energy Chloridizing ... Co-Gasification Behavior of Metallurgical Coke with High and Low Reactivity .... Thermal Plasma Torches for Metallurgical Applications.

407

Iron-niobium-aluminum alloy having high-temperature corrosion resistance  

DOE Patents (OSTI)

An alloy for use in high temperature sulfur and oxygen containing environments, having aluminum for oxygen resistance, niobium for sulfur resistance and the balance iron, is discussed. 4 figs., 2 tabs.

Hsu, Huey S.

1988-04-14T23:59:59.000Z

408

NOREM Wear-Resistant, Iron-Based Hard-Facing Alloys  

Science Conference Proceedings (OSTI)

Laboratory studies have identified new, iron-based hard-facing alloys, designated NOREM, possessing outstanding resistance to wear and corrosion. On new or refurbished valves, use of these alloys could reduce radiation-field buildup in nuclear power plants.

1989-07-20T23:59:59.000Z

409

NOREM Wear-Resistant, Iron-Based Hard-Facing Alloys  

Science Conference Proceedings (OSTI)

Laboratory studies have identified new, iron-based hard-facing alloys, designated NOREM, possessing outstanding resistance to wear and corrosion. On new or refurbished valves, use of these alloys could reduce radiation-field buildup in nuclear power plants.

1989-07-01T23:59:59.000Z

410

Iron (III) Chloride doping of large-area chemical vapor deposition graphene  

E-Print Network (OSTI)

Chemical doping is an effective method of reducing the sheet resistance of graphene. This thesis aims to develop an effective method of doping large area Chemical Vapor Deposition (CVD) graphene using Iron (III) Chloride ...

Song, Yi, S.M. Massachusetts Institute of Technology

2013-01-01T23:59:59.000Z

411

Data on production and use of DRI: World and U. S. [Direct Reduced Iron  

Science Conference Proceedings (OSTI)

This paper will present data on the production and use direct-reduced iron (DRI) worldwide, focusing primarily on its use in the United States. The author is indebted to the Midrex Corporation for the data on world production of DRI. The U.S. data is his own and he will explain later how it was collected. He uses the term DRI to include all forms of direct-reduced iron, whether briquettes, pellets or lump.

Jensen, H.B.

1993-01-01T23:59:59.000Z

412

Summary of INEL research on the iron-enriched basalt waste form  

SciTech Connect

This report summarizes the knowledge base on the iron-enriched basalt (IEB) waste form developed at the Idaho National Engineering Laboratory (INEL) during 1979--1982. The results presented discuss the applicability of IEB in converting retrieved transuranic (TRU) waste from INEL`s Radioactive Waste Management Complex (RWMC) into a vitreous/ceramic (glassy/rock) stable waste form suitable for permanent disposal in an appropriate repository, such as the Waste Isolation Pilot Plant (WIPP) in New Mexico. Borosilicate glass (BSG), the approved high-level waste form, appears unsuited for this application. Melting the average waste-soil mix from the RWMC produces the IEB composition and attempting to convert IEB to the BSG composition would require additions of substantial B{sub 2}0{sub 3}, Na, and SiO{sub 2} (glass frit). IEB requires processing temperatures of 1400 to 1600{degrees}C, depending upon the waste composition. Production of the IEB waste form, using Joule heated melters, has proved difficult in the past because of electrode and refractory corrosion problems associated with the high temperature melts. Higher temperature electric melters (arc and plasma) are available to produce this final waste form. Past research focused on extensive slag property measurements, waste form leachability tests, mechanical, composition, and microstructure evaluations, as well as a host of experiments to improve production of the waste form. Past INEL studies indicated that the IEB glass-ceramic is a material that will accommodate and stabilize a wide range of heterogeneous waste materials, including long lived radionuclides and scrap metals, while maintaining a superior level of chemical and physical performance characteristics. Controlled cooling of the molten IEB and subsequent heat treatment will produce a glass-ceramic waste form with superior leach resistance.

Reimann, G.A.; Grandy, J.D.; Eddy, T.L.; Anderson, G.L.

1992-01-01T23:59:59.000Z

413

Summary of INEL research on the iron-enriched basalt waste form  

Science Conference Proceedings (OSTI)

This report summarizes the knowledge base on the iron-enriched basalt (IEB) waste form developed at the Idaho National Engineering Laboratory (INEL) during 1979--1982. The results presented discuss the applicability of IEB in converting retrieved transuranic (TRU) waste from INEL's Radioactive Waste Management Complex (RWMC) into a vitreous/ceramic (glassy/rock) stable waste form suitable for permanent disposal in an appropriate repository, such as the Waste Isolation Pilot Plant (WIPP) in New Mexico. Borosilicate glass (BSG), the approved high-level waste form, appears unsuited for this application. Melting the average waste-soil mix from the RWMC produces the IEB composition and attempting to convert IEB to the BSG composition would require additions of substantial B{sub 2}0{sub 3}, Na, and SiO{sub 2} (glass frit). IEB requires processing temperatures of 1400 to 1600{degrees}C, depending upon the waste composition. Production of the IEB waste form, using Joule heated melters, has proved difficult in the past because of electrode and refractory corrosion problems associated with the high temperature melts. Higher temperature electric melters (arc and plasma) are available to produce this final waste form. Past research focused on extensive slag property measurements, waste form leachability tests, mechanical, composition, and microstructure evaluations, as well as a host of experiments to improve production of the waste form. Past INEL studies indicated that the IEB glass-ceramic is a material that will accommodate and stabilize a wide range of heterogeneous waste materials, including long lived radionuclides and scrap metals, while maintaining a superior level of chemical and physical performance characteristics. Controlled cooling of the molten IEB and subsequent heat treatment will produce a glass-ceramic waste form with superior leach resistance.

Reimann, G.A.; Grandy, J.D.; Eddy, T.L.; Anderson, G.L.

1992-01-01T23:59:59.000Z

414

Molten iron oxysulfide as a superior sulfur sorbent. Final report, [September 1989--1993  

Science Conference Proceedings (OSTI)

The studies had as original objective the analysis of conditions for using liquid iron oxysulfide as a desulfuring agent during coal gasification. Ancillary was a comparison of iron oxysulfide with lime as sorbents under conditions where lime reacts with S-bearing gases to form Ca sulfate or sulfide. Primary thrust is to determine the thermodynamic requirements for desulfurization by iron additions (e.g., taconite concentrate) during combustion in gasifiers operating at high equivalence ratios. Thermodynamic analysis of lime-oxygen-sulfur system shows why lime is injected into burners under oxidizing conditions; reducing conditions forms CaS, requiring its removal, otherwise oxidation and release of S would occur. Iron as the oxysulfide liquid has a range of stability and can be used as a desulfurizing agent, if the burner/gasifier operates in a sufficiently reducing regime (high equivalence ratio); this operating range is given and is calculable for a coal composition, temperature, stoichiometry. High moisture or hydrogen contents of the coal yield a poorer degree of desulfurization. Kinetic tests on individual iron oxide particles on substrates or Pt cups with a TGA apparatus fail to predict reaction rates within a burner. Preliminary tests on the Dynamic Containment Burner with acetylene give some promise that this system can produce the proper conditions of coal gasification for use of added iron as a sulfur sorbent.

Hepworth, M.T.

1993-03-31T23:59:59.000Z

415

Lead iron phosphate glass as a containment medium for disposal of high-level nuclear waste  

DOE Patents (OSTI)

Lead-iron phosphate glasses containing a high level of Fe.sub.2 O.sub.3 for use as a storage medium for high-level radioactive nuclear waste. By combining lead-iron phosphate glass with various types of simulated high-level nuclear waste, a highly corrosion resistant, homogeneous, easily processed glass can be formed. For corroding solutions at 90.degree. C., with solution pH values in the range between 5 and 9, the corrosion rate of the lead-iron phosphate nuclear waste glass is at least 10.sup.2 to 10.sup.3 times lower than the corrosion rate of a comparable borosilicate nuclear waste glass. The presence of Fe.sub.2 O.sub.3 in forming the lead-iron phosphate glass is critical. Lead-iron phosphate nuclear waste glass can be prepared at temperatures as low as 800.degree. C., since they exhibit very low melt viscosities in the 800.degree. to 1050.degree. C. temperature range. These waste-loaded glasses do not readily devitrify at temperatures as high as 550.degree. C. and are not adversely affected by large doses of gamma radiation in H.sub.2 O at 135.degree. C. The lead-iron phosphate waste glasses can be prepared with minimal modification of the technology developed for processing borosilicate glass nuclear wasteforms.

Boatner, Lynn A. (Oak Ridge, TN); Sales, Brian C. (Oak Ridge, TN)

1989-01-01T23:59:59.000Z

416

Engineering design and test plan for demonstrating DETOX treatment of mixed wastes  

SciTech Connect

DETOX is a cocatalyzed wet oxidation process in which the catalysts are a relatively great concentration of iron ions (typically as iron(III) chloride) in the presence of small amounts of platinum and ruthenium ions. Organic compounds are oxidized completely to carbon dioxide, water, and (if chlorinated) hydrogen chloride. The process has shown promise as a non-thermal alternative to incineration for treatment and/or volume reduction of hazardous, radioactive, and mixed wastes. Design and fabrication of a demonstration unit capable of destroying 25. Kg/hr of organic material is now in progress. This paper describes the Title 2 design of the demonstration unit, and the planned demonstration effort at Savannah River Site (SRS) and Weldon Spring Site Remedial Action Project (WSSRAP).

Goldblatt, S.; Dhooge, P.

1995-03-01T23:59:59.000Z

417

Iron fortification of flour with a complex ferric orthophosphate  

SciTech Connect

The unexpectedly low bioavailability in humans of elemental iron powder prompted us to search for other Fe compounds suitable for Fe fortification of flour that fulfill the two requirements of insolubility in water (due to high water content of flour) and good bioavailability in humans. Systematic studies of compatibility, solubility, and bioavailability led to this study of a microcrystalline complex ferric orthophosphate (CFOP), Fe/sub 3/H/sub 8/(NH/sub 4/)-(PO/sub 4/)6.6H/sub 2/O, a well-defined compound. This compound was labeled with /sup 59/Fe, and the native Fe in meals was labeled with /sup 55/FeCl3. The ratio of absorbed /sup 59/Fe to absorbed /sup 55/Fe is a direct measure of the fraction of CFOP that joins the nonheme Fe pool and that is made potentially available for absorption. The relative bioavailability of CFOP varied from 30% to 60% when labeled wheat rolls were served with different meals. The CFOP meets practical requirements of an Fe fortificant for flour well, with regard to both compatibility and bioavailability in humans.

Hallberg, L.; Rossander-Hulthen, L.; Gramatkovski, E.

1989-07-01T23:59:59.000Z

418

Microstructure Evolution of Gas Atomized Iron Based ODS Alloys  

SciTech Connect

In a simplified process to produce precursor powders for oxide dispersion-strength- ened (ODS) alloys, gas-atomization reaction synthesis (GARS) was used to induce a surface oxide layer on molten droplets of three differing erritic stainless steel alloys during break-up and rapid solidification. The chemistry of the surface oxide was identified using auger electron spectroscopy (AES) and scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDS). The precursor iron-base powders were consolidated at 850 C and 1,300 C using hot isostatic pressing (HIPing). Consolidation at the lower temperature resulted in a fully dense microstructure, while preventing substantial prior particle-boundary-oxide dissociation. Microstructural analysis of the alloys consolidated at the higher temperature confirmed a significant reduction in prior-particle-boundary-oxide volume fraction, in comparison with the lower-temperature-consolidated sample. This provided evidence that a high-temperature internal oxygen-exchange reaction occurred between the metastable prior particle-boundary-oxide phase (chromium oxide) and the yttrium contained within each prior particle. This internal oxygen-exchange reaction is shown to result in the formation of yttrium-enriched oxide dispersoids throughout the alloy microstructure. The evolving microstructure was characterized using transmission electron microscopy (TEM) and high-energy X-ray diffraction (HE-XRD).

Rieken, J.R.; Anderson, I.E.; Kramer, M.J.; Anderegg, J.W.; Shechtman, D.

2009-12-01T23:59:59.000Z

419

Microstructure Evolution of Gas Atomized Iron Based ODS Alloys  

SciTech Connect

In a simplified process to produce precursor powders for oxide dispersion-strengthened (ODS) alloys, gas-atomization reaction synthesis (GARS) was used to induce a surface oxide layer on molten droplets of three differing erritic stainless steel alloys during break-up and rapid solidification. The chemistry of the surface oxide was identified using auger electron spectroscopy (AES) and scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDS). The precursor iron-base powders were consolidated at 850 C and 1,300 C using hot isostatic pressing (HIPing). Consolidation at the lower temperature resulted in a fully dense microstructure, while preventing substantial prior particle-boundary-oxide dissociation. Microstructural analysis of the alloys consolidated at the higher temperature confirmed a significant reduction in prior-particle-boundary-oxide volume fraction, in comparison with the lower-temperature-consolidated sample. This provided evidence that a high-temperature internal oxygen-exchange reaction occurred between the metastable prior particle-boundary-oxide phase (chromium oxide) and the yttrium contained within each prior particle. This internal oxygen-exchange reaction is shown to result in the formation of yttrium-enriched oxide dispersoids throughout the alloy microstructure. The evolving microstructure was characterized using transmission electron microscopy (TEM) and high-energy X-ray diffraction (HE-XRD).

Rieken, J.R.; Anderson, I.E.; Kramer, M.J.

2011-08-09T23:59:59.000Z

420

Process for removing technetium from iron and other metals  

DOE Patents (OSTI)

Technetium is a radioactive product of the nuclear fission process. During reprocessing of spent or partially spent fuel from nuclear reactors, the technetium can be released and contaminate other, otherwise good, metals. A specific example is equipment in gaseous diffusion uranium enrichment cascades which have been used to process fuel which was returned from reactors, so-called reactor returns. These returns contained volatile technetium compounds which contaminated the metals in the equipment. Present regulations require that technetium be removed before the metal can be re-used at non-radioactive sites. Removing the technetium from contaminated metals has two desirable results. First, the large amount of nonradioactive metal produced by the process herein described can be recycled at a much lower cost than virgin metal can be produced. Second, large amounts of radioactively contaminated metal can be reduced to relatively small amounts of radioactive slag and large amounts of essentially uncontaminated metal. A new and improved process for removing technetium from iron and other metals is described in which between 1/10 atom % and 5 atom % of manganese is added to the contaminated metal in order to replace the technetium.

Leitnaker, James M.; Trowbridge, Lee D.

1997-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "zero-valent iron treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Melter Throughput Enhancements for High-Iron HLW  

Science Conference Proceedings (OSTI)

This report describes work performed to develop and test new glass and feed formulations in order to increase glass melting rates in high waste loading glass formulations for HLW with high concentrations of iron. Testing was designed to identify glass and melter feed formulations that optimize waste loading and waste processing rate while meeting all processing and product quality requirements. The work included preparation and characterization of crucible melts to assess melt rate using a vertical gradient furnace system and to develop new formulations with enhanced melt rate. Testing evaluated the effects of waste loading on glass properties and the maximum waste loading that can be achieved. The results from crucible-scale testing supported subsequent DuraMelter 100 (DM100) tests designed to examine the effects of enhanced glass and feed formulations on waste processing rate and product quality. The DM100 was selected as the platform for these tests due to its extensive previous use in processing rate determination for various HLW streams and glass compositions.

Kruger, A. A. [Department of Energy, Office of River Protection, Richland, Washington (United States); Gan, Hoa [The Catholic University of America, Washington, DC (United States); Joseph, Innocent [The Catholic University of America, Washington, DC (United States); Pegg, Ian L. [The Catholic University of America, Washington, DC (United States); Matlack, Keith S. [The Catholic University of America, Washington, DC (United States); Chaudhuri, Malabika [The Catholic University of America, Washington, DC (United States); Kot, Wing [The Catholic University of America, Washington, DC (United States)

2012-12-26T23:59:59.000Z

422

Water Treatment Plants  

NLE Websites -- All DOE Office Websites (Extended Search)

to see the operation than have us explain it. Basically, most treatment plants remove the solid material and use living organisms and chlorine to clean up the water. Steve Sample...

423

Thermal treatment wall  

DOE Patents (OSTI)

A thermal treatment wall emplaced to perform in-situ destruction of contaminants in groundwater. Thermal destruction of specific contaminants occurs by hydrous pyrolysis/oxidation at temperatures achievable by existing thermal remediation techniques (electrical heating or steam injection) in the presence of oxygen or soil mineral oxidants, such as MnO.sub.2. The thermal treatment wall can be installed in a variety of configurations depending on the specific objectives, and can be used for groundwater cleanup, wherein in-situ destruction of contaminants is carried out rather than extracting contaminated fluids to the surface, where they are to be cleaned. In addition, the thermal treatment wall can be used for both plume interdiction and near-wellhead in-situ groundwater treatment. Thus, this technique can be utilized for a variety of groundwater contamination problems.

Aines, Roger D. (Livermore, CA); Newmark, Robin L. (Livermore, CA); Knauss, Kevin G. (Livermore, CA)

2000-01-01T23:59:59.000Z

424

Estimation of iron-55 volumetric contamination via surrogates produced during Z-machine operations  

E-Print Network (OSTI)

Analysis of the radiation produced by Z-machine nuclear experiments at Sandia National Laboratory and the materials irradiated indicate that the majority of produced radionuclides can easily be detected. One significant exception is volumetric contamination of stainless steel by iron-55. Detecting iron-55 in Z-machine components presents a particular problem due to its low-abundance and the low-energy (5.9 keV) xray it emits. The nuclide is often below the minimum detectable activity (MDA) threshold and resolution criteria of many standard radiation detection devices. Liquid scintillation has proven useful in determining iron-55 presence in loose contamination at concentrations below that of regulatory guidelines, but determination of volumetric iron- 55 contamination remains a significant challenge. Due to this difficulty, an alternate method of detection is needed. The use of radioactive surrogates correlating to iron-55 production is proposed in order to establish an estimate of iron-55 abundance. The primary interaction pathways and interaction probabilities for all likely radionuclide production in the Z-machine were tabulated and radionuclides with production pathways matching those of iron-55 production were noted. For purposes of nuclide identification and adequate detection, abundant gamma emitters with half-lives on the order of days were selected for use as surrogates. Interaction probabilities were compared between that of iron-55 production and a chosen surrogate. Weighting factors were developed to account for the differences in the interaction probabilities over the range of the known energy spectra produced on the device. The selection process resulted in cobalt-55, cobalt-57 and chromium-51 as optimal surrogates for iron-55 detection in both deuterium and non-deuterium loaded interactions. A decay corrected correlation of the surrogates (chromium-51, cobalt-57 and cobalt-55) to iron-55 for deuterium and non-deuterium loaded Z-machine driven reactions was derived. The weighting factors presented here are estimates which are based on rough comparisons of cross-section graphs. Analysis considering factors such as energy spectrum criteria to provide refined weighting factors may be utilized in future work.

Flores-McLaughlin, John

2008-08-01T23:59:59.000Z

425

Portable treatment systems study  

SciTech Connect

In developing their Site Treatment Plans (STPs), many of the Department of Energy installations identified some form of portable treatment, to facilitate compliant disposition of select mixed low-level wastestreams. The Environmental Management Office of Science and Technology requested that a systems study be performed to better define the potential role of portable treatment with respect to mixed low-level waste, highlight obstacles to implementation, and identify opportunities for future research and development emphasis. The study was performed by first establishing a representative set of mixed waste, then formulating portable treatment system concepts to meet the required processing needs for these wastes. The portable systems that were conceptualized were evaluated and compared to a fixed centralized treatment alternative. The system evaluations include a life-cycle cost analysis and an assessment of regulatory, institutional, and technical issues associated with the potential use of portable systems. The results of this study show that when all costs are included, there are no significant cost differences between portable systems and fixed systems. However, it is also emphasized that many uncertainties exist that could impact the cost of implementing portable treatment systems. Portable treatment could be made more attractive through private sector implementation, although there is little economic incentive for a commercial vendor to develop small, specialized treatment capabilities with limited applicability. Alternatively, there may also be valid reasons why fixed units cannot be used for some problematic wastestreams. In any event, there are some site-specific problems that still need to be addressed, and there may be some opportunity for research and development to make a positive impact in these areas.

Sherick, M.J.; Schwinkendorf, W.E.; Bechtold, T.E.; Cole, L.T.

1997-03-01T23:59:59.000Z

426

Alkali Treatment of Acidic Solution from Hanford K Basin Sludge Dissolution  

SciTech Connect

Nitric acid solutions will be created from the dissolution of Hanford K Basin sludge. These acidic dissolver solutions must be made alkaline by treatment with NaOH solution before they are disposed to ~ the Tank Waste Remediation System on the Hanford Site. During the alkali treatments, sodium diuranate, hydroxides of iron and aluminum, and radioelements (uranium, plutonium, and americium) will precipitate from the dissolver solution. Laboratory tests, discussed here, were pefiormed to provide information on these precipitates and their precipitation behavior that is important in designing the engineering flowsheet for the treatment process. Specifically, experiments were conducted to determine the optimum precipitation conditions; the completeness of uranium, plutonium, and americium precipitation; the rate of sedimentation; and the physico-chemical characteristics of the solids formed by alkali treatment of simulated acidic dissolver solutions. These experiments also determined the redistribution of uranium, plutonium, and americium flom the sodium di~ate and iron and al&inurn hydroxide precipitates upon contact with carbonate- and EDTA-bearing simulated waste solutions. Note: EDTA is the tetrasodium salt of ethylenediaminetetraacetate.

AA Bessonov; AB Yusov; AM Fedoseev; AV Gelis; AY Garnov; CH Delegard; GM Plavnik; LN Astafurova; MS Grigoriev; NA Budantseva; NN Krot; SI Nikitenko; TP Puraeva; VP Perminov; VP Shilov

1998-12-22T23:59:59.000Z

427

Dietary fortificant iron intake is negatively associated with quality of life in patients with mildly active inflammatory bowel disease  

E-Print Network (OSTI)

information using the McCance and Widdowson food composition tables [23], and this value was then subtracted from the total iron content declared by the manufacturer to esti- mate fortificant iron content; and (iii) for other foods containing white wheat flour... between IBD patients and healthy control subjects (6.9 1.6 vs 5.3 0.6; pwheat flour and iron derived from other Pancakes, sweet udding Fruit pie Digestive biscuits ingue pie Sponge pudding...

Powell, Jonathan J; Cook, William B; Hutchinson, Carol; Tolkien, Zoe; Chatfield, Mark; Pereira, Dora IA; Lomer, Miranda CE

2013-01-15T23:59:59.000Z

428

A Comparison of Iron and Steel Production Energy Use and Energy Intensity in China and the U.S.  

E-Print Network (OSTI)

indicators of steel sector energy efficiency and intensity.Energy intensity in the iron and steel industry: a comparison of physical and economic indicators,

Hasanbeigi, Ali

2012-01-01T23:59:59.000Z

429

ATTRITION RESISTANT IRON-BASED FISCHER-TROPSCH CATALYSTS  

DOE Green Energy (OSTI)

The Fischer-Tropsch (F-T) reaction provides a way of converting coal-derived synthesis gas (CO+H{sub 2}) to liquid fuels. Since the reaction is highly exothermic, one of the major problems in control of the reaction is heat removal. Recent work has shown that the use of slurry bubble column reactors (SBCRs) can largely solve this problem. Iron-based (Fe) catalysts are preferred catalysts for F-T when using low CO/H2 ratio synthesis gases derived from modern coal gasifiers. This is because in addition to reasonable F-T activity, the F-T catalysts also possess high water gas shift (WGS) activity. However, a serious problem with the use of Fe catalysts in a SBCR is their tendency to undergo attrition. This can cause fouling/plugging of downstream filters and equipment, making the separation of catalyst from the oil/wax product very difficult if not impossible, and results in a steady loss of catalyst from the reactor. The objectives of this research are to develop a better understanding of the parameters affecting attrition resistance of Fe F-T catalysts suitable for use in SBCRs and to incorporate this understanding into the design of novel Fe catalysts having superior attrition resistance. Catalyst preparations will be based on the use of spray drying and will be scalable using commercially available equipment. The research will employ among other measurements, attrition testing and F-T synthesis, including long duration slurry reactor runs in order to ascertain the degree of success of the various preparations. The goal is to develop an Fe catalyst which can be used in a SBCR having only an internal filter for separation of the catalyst from the liquid product, without sacrificing F-T activity and selectivity. The effect of silica addition via coprecipitation and as a binder to a doubly promoted Fischer-Tropsch synthesis iron catalyst (100 Fe/5 Cu/4.2 K) was studied. The catalysts were prepared by coprecipitation, followed by binder addition and drying in a 1 m diameter, 2 m tall spray dryer. The binder silica content was varied from 0 to 20 wt %. A catalyst with 12 wt % binder silica was found to have the highest attrition resistance. F-T reaction studies over 100 hours in a fixed-bed reactor showed that this catalyst maintained around 95 % CO conversion with a methane selectivity of less than 7 wt % and a C5 + selectivity of greater than 73 wt %. The effect of adding precipitated silica from 0 to 20 parts by weight to this catalyst (containing 12 wt % binder silica) was also studied. Addition of precipitated silica was found to be detrimental to attrition resistance and resulted in increased methane and reduced wax formation. An HPR series of proprietary catalysts was prepared to further improve the attrition resistance. Based on the experience gained, a proprietary HPR-43 catalyst has been successfully spray dried in 500 g quantity. This catalyst showed 95 % CO conversion over 125 h and had less than 4 % methane selectivity. Its attrition resistance was one of the highest among the catalyst tested.

James G. Goodwin, Jr.; James J. Spivey; K. Jothimurugesan; Santosh K. Gangwal

1999-03-29T23:59:59.000Z

430

ATTRITION RESISTANT IRON-BASED FISCHER-TROPSCH CATALYSTS  

DOE Green Energy (OSTI)

The Fischer-Tropsch (F-T) reaction provides a way of converting coal-derived synthesis gas (CO+H{sub 2}) to liquid fuels. Since the reaction is highly exothermic, one of the major problems in control of the reaction is heat removal. Recent work has shown that the use of slurry bubble column reactors (SBCRs) can largely solve this problem. Iron-based (Fe) catalysts are preferred catalysts for F-T when using low CO/H{sub 2} ratio synthesis gases derived from modern coal gasifiers. This is because in addition to reasonable F-T activity, the F-T catalysts also possess high water gas shift (WGS) activity. However, a serious problem with the use of Fe catalysts in a SBCR is their tendency to undergo attrition. This can cause fouling/plugging of downstream filters and equipment, making the separation of catalyst from the oil/wax product very difficult if not impossible, and results in a steady loss of catalyst from the reactor. The objectives of this research are to develop a better understanding of the parameters affecting attrition resistance of Fe F-T catalysts suitable for use in SBCRs and to incorporate this understanding into the design of novel Fe catalysts having superior attrition resistance. Catalyst preparations will be based on the use of spray drying and will be scalable using commercially available equipment. The research will employ among other measurements, attrition testing and F-T synthesis, including long duration slurry reactor runs in order to ascertain the degree of success of the various preparations. The goal is to develop an Fe catalyst which can be used in a SBCR having only an internal filter for separation of the catalyst from the liquid product, without sacrificing F-T activity and selectivity. The effect of silica addition via coprecipitation and as a binder to a doubly promoted Fischer-Tropsch synthesis iron catalyst (100 Fe/5 Cu/4.2 K) was studied. The catalysts were prepared by coprecipitation, followed by binder addition and drying in a 1 m diameter, 2 m tall spray dryer. The binder silica content was varied from 0 to 20 wt %. A catalyst with 12 wt % binder silica was found to have the highest attrition resistance. F-T reaction studies over 100 hours in a fixed-bed reactor showed that this catalyst maintained around 95 % CO conversion with a methane selectivity of less than 7 wt % and a C{sub 5}{sup +} selectivity of greater than 73 wt %. The effect of adding precipitated silica from 0 to 20 parts by weight to this catalyst (containing 12 wt % binder silica) was also studied. Addition of precipitated silica was found to be detrimental to attrition resistance and resulted in increased methane and reduced wax formation.

JAMES G. GOODWIN, JR.; JAMES J. SPIVEY; K. JOTHIMURUGESAN; SANTOSH K. GANGWAL

1998-09-17T23:59:59.000Z

431

Attrition Resistant Iron-Based Fischer-Tropsch Catalysts  

DOE Green Energy (OSTI)

The Fischer-Tropsch (F-T) reaction provides a way of converting coal-derived synthesis gas (CO+H{sub 2}) to liquid fuels. Since the reaction is highly exothermic, one of the major problems in control of the reaction is heat removal. Recent work has shown that the use of slurry bubble column reactors (SBCRS) can largely solve this problem. Iron-based (Fe) catalysts are preferred catalysts for F-T when using low CO/H{sub 2} ratio synthesis gases derived from modem coal gasifiers. This is because in addition to reasonable F-T activity, the FT catalysts also possess high water gas shift (WGS) activity. However, a serious problem with the use of Fe catalysts in a SBCR is their tendency to undergo attrition. This can cause fouling/plugging of downstream filters and equipment, making the separation of catalyst from the oil/wax product very difficult if not impossible, and results in a steady loss of catalyst from the reactor. The objectives of this research are to develop a better understanding of the parameters affecting attrition resistance of Fe F-T catalysts suitable for use in SBCRs and to incorporate this understanding into the design of novel Fe catalysts having superior attrition resistance. Catalyst preparations will be based on the use of spray drying and will be scalable using commercially available equipment. The research will employ among other measurements, attrition testing and F-T synthesis, including long duration slurry reactor runs in order to ascertain the degree of success of the various preparations. The goal is to develop an Fe catalyst which can be used in a SBCR having only an internal filter for separation of the catalyst from the liquid product, without sacrificing F-T activity and selectivity.

Jothimurugesan, K. [Hampton Univ., VA (United States). Dept. of Chemical Engineering; Goodwin, J.G. [Univ. of Pittsburgh, PA (United States). Chemical and Petroleum Engineering Dept.; Spivey, J.J.; Gangwal, S.K. [Research Triangle Inst., NC (United States)

1997-03-26T23:59:59.000Z

432

FERRATES: SYNTHESIS, PROPERTIES AND APPLICATIONS IN WATER AND WASTEWATER TREATMENT.  

DOE Green Energy (OSTI)

The higher oxidation states of iron (Fe(VI) and Fe(V) in particular) have been shown to be strongly oxidizing in enzymatic systems, where they can carry out aliphatic hydrogen abstraction. In addition, they have been postulated as intermediates in Fenton-type systems. Fe(VI) itself is relatively stable and has been shown to have potential as an oxidant in the so-called ''green'' treatment of polluted waters. By contrast, Fe(V) is a relatively short-lived transient when produced in aqueous solution in the absence of strongly bonding ligands other than hydroxide, a feature that has limited studies of its reactivity. Fe(VI) has been proposed to be useful in battery design and a very interesting study suggested that ferrate may be able to oxidize insoluble chromium to chromate and thus serve to remove chromium contamination in the Hanford radioactive waste tanks.

CABELLI, D.E.; SHARMA, V.K.

2006-05-19T23:59:59.000Z

433

Iron Speciation and Mixing in Single Aerosol Particles from the Asian Continental Outflow  

Science Conference Proceedings (OSTI)

Bioavailable iron from atmospheric aerosol is an essential nutrient that can control oceanic productivity, thereby impacting the global carbon budget and climate. Particles collected on Okinawa Island during an atmospheric pollution transport event from China were analyzed using complementary single particle techniques to determine the iron source and speciation. Comparing the spatial distribution of iron within ambient particles and standard Asian mineral dust, it was determined that field-collected atmospheric Fe-containing particles have numerous sources, including anthropogenic sources such as coal combustion. Fe-containing particles were found to be internally mixed with secondary species such as sulfate, soot, and organic carbon. The mass weighted average Fe(II) fraction (defined as Fe(II)/[Fe(II)+Fe(III)]) was determined to be 0.33 {+-} 0.08. Within the experimental uncertainty, this value lies close to the range of 0.26-0.30 determined for representative Asian mineral dust. Previous studies have indicated that the solubility of iron from combustion is much higher than that from mineral dust. Therefore, chemical and/or physical differences other than oxidation state may help explain the higher solubility of iron in atmospheric particles.

Moffet, Ryan C.; Furutani, Hiroshi; Rodel, Tobias; Henn, Tobias R.; Sprau, Peter; Laskin, Alexander; Uematsu, Mitsuo; Gilles, Marry K.

2012-04-04T23:59:59.000Z

434

Fischer-Tropsch synthesis: Moessbauer studies of pretreated ultrafine iron oxide catalysts  

SciTech Connect

Moessbauer spectroscopy indicates that a 24 hour-pretreatment in CO at 260{degrees}C and 8 atm. in a tetralin solvent almost completely converts uftrafine iron oxide (about 3 nm) to iron carbide. However, pretreatment in hydrogen under the same conditions resulted in reduction of about 33% of the iron to metallic Fe; the remainder was Fe{sub 3}O{sub 4}. Exposure of the CO pretreated catalyst to a 1:1 HDCO synthesis gas resulted in the gradual reoxidation of the carbides to Fe{sub 3}O{sub 4}. During the first 2 hours of exposure of the H{sub 2} pretreated sample to synthesis gas,.the metallic Fe was converted to iron carbides. Further exposure of the H{sub 2} pretreatment sample to synthesis gas did not result in a composition change of the catalyst. Therefore, it is concluded that iron carbides with different oxidation characteristics were formed in these two cases.

Chenshi Huang; Davis, B.H. (Kentucky Univ., Lexington, KY (United States). Center for Applied Energy Research); Rao, K.R.P.M.; Huffman, G.P.; Huggins, F.E. (Kentucky Univ., Lexington, KY (United States). Inst. for Mining and Minerals Research)

1992-01-01T23:59:59.000Z

435

Method of manufacturing iron aluminide by thermomechanical processing of elemental powders  

DOE Patents (OSTI)

A powder metallurgical process of preparing iron aluminide useful as electrical resistance heating elements having improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The iron aluminide has an entirely ferritic microstructure which is free of austenite and can include, in weight %, 20 to 32% Al, and optional additions such as .ltoreq.1% Cr, .gtoreq.05% Zr or ZrO.sub.2 stringers extending perpendicular to an exposed surface of the heating element, .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Zr, .ltoreq.1% C, .ltoreq.0.1% B, .ltoreq.30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1 % rare earth metal, .ltoreq.1% oxygen, and/or .ltoreq.3% Cu. The process includes forming a mixture of aluminum powder and iron powder, shaping the mixture into an article such as by cold rolling the mixture into a sheet, and sintering the article at a temperature sufficient to react the iron and aluminum powders and form iron aluminide. The sintering can be followed by hot or cold rolling to reduce porosity created during the sintering step and optional annealing steps in a vacuum or inert atmosphere.

Deevi, Seetharama C. (Midlothian, VA); Lilly, Jr., A. Clifton (Chesterfield, VA); Sikka, Vinod K. (Oak Ridge, TN); Hajaligol, Mohammed R. (Richmond, VA)

2000-01-01T23:59:59.000Z

436

Treatment of Waste Soils / Solids  

Science Conference Proceedings (OSTI)

About the 1996 International Symposium on Extraction and Processing for the Treatment and Minimization of Wastes: Treatment of Waste Soils / Solids...

437

Devising wastewater treatment strategies  

Science Conference Proceedings (OSTI)

Troubleshooting a waste water treatment system takes basic knowledge of how the process is designed to work, tools, and a few resources. This paper describes a Seven Steps Program employed fopr troubleshooting. A well-designed troubleshooting program should be comprehensive, thoroughly tested and constantly revisited to maintain a reliable and efficient wastewater treatment system. Such a method includes each of the integral components including biological, human, mechanical, and chemical. This total systems approach can result in improved system operation and better bottom line results.

Hornby, L.E.

1993-05-01T23:59:59.000Z

438

NMR Study in the Iron-Selenide Rb0:74Fe1:6Se2: Determination of the Superconducting Phase as Iron Vacancy-Free Rb0:3Fe2Se2  

E-Print Network (OSTI)

NMR Study in the Iron-Selenide Rb0:74Fe1:6Se2: Determination of the Superconducting Phase as Iron magnetic resonance (NMR) experiments on Rb0:74Fe1:6Se2 reveal clearly distinct spectra originating from a majority antiferromagnetic (AF) and a minority metallic-superconducting (SC) phase. The very narrow NMR

Paris-Sud 11, Université de

439

Wrought Superalloy Heat Treatment  

Science Conference Proceedings (OSTI)

Table 5   Effect of heat treatment on the properties of A-286...tensile strength Elongation % Reduction in area, % MPa ksi MPa ksi Life, h Elongation, % Reduction in area, % 980 °C (1800 °F) for 1 h, oil quench (OQ)

440

Near Tank Treatment System  

Hanford High Level Waste: S/SX Tanks TEM Images of Actual Waste Boehmite 7 (a) 0.2 m (b) 0.2 m (c) 0.5 m (d) 0.2 m U and Mn particles . Near Tank Treatment System

Note: This page contains sample records for the topic "zero-valent iron treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Minnesota Jobs to Come with Efficient Iron Plant | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Minnesota Jobs to Come with Efficient Iron Plant Minnesota Jobs to Come with Efficient Iron Plant Minnesota Jobs to Come with Efficient Iron Plant October 22, 2009 - 11:24am Addthis Eric Barendsen Energy Technology Program Specialist, Office of Energy Efficiency and Renewable Energy In 1957, Marlene Pospeck moved to the town of Hoyt Lakes, Minnesota, a small, quiet community surrounded by forests and lakes where just about everyone knows everyone else. Little did she know she'd become mayor in 1996 and have to lead the town through economic calamity. Marlene's father worked for the local mining company, which opened its doors in the mid-1950s. Her husband worked at the company's plant for 37 years as a machinist, and the couple raised three daughters in Hoyt Lakes. So when Mayor Pospeck heard the mining company was bankrupt in December

442

Dopant Site Determination in Iron Oxide Nanoparticles Utilizing X-ray  

NLE Websites -- All DOE Office Websites (Extended Search)

Dopant Site Determination in Iron Oxide Nanoparticles Utilizing X-ray Dopant Site Determination in Iron Oxide Nanoparticles Utilizing X-ray Absorption Techniques Monday, September 9, 2013 - 11:00am SLAC, Conference Room 137-322 Presented by Dr. Vanessa Pool The dopant behavior of spinels has been investigated for over half a century and yet new insight into this class of materials is still being made today. In this work, the question of dopant site preference is explored for the nanoparticle regime. Iron oxide nanoparticles have numerous exciting applications. To realize these applications, controlling the preferred dopant site and valence within the host material is important. X-ray Absorption Spectroscopy (XAS) and X-ray Magnetic Circular Dichroism (XMCD) are element specific techniques with magnetic contrast that give insights into the material composition. Using both

443

The Fate of Bioavailable Iron in Antarctic Coastal Seas | Advanced Photon  

NLE Websites -- All DOE Office Websites (Extended Search)

A Better Way to Probe Biological Polymorphs A Better Way to Probe Biological Polymorphs Composite Battery Boost Water-Like Properties of Soft Nanoparticle Suspensions Real-Time Capture of Intermediates in Enzymatic Reactions A New Multilayer-Based Grating for Hard X-ray Grating Interferometry Science Highlights Archives: 2013 | 2012 | 2011 | 2010 2009 | 2008 | 2007 | 2006 2005 | 2004 | 2003 | 2002 2001 | 2000 | 1998 | Subscribe to APS Science Highlights rss feed The Fate of Bioavailable Iron in Antarctic Coastal Seas December 11, 2013 Bookmark and Share On the left is an XRF micrograph map of silicon distribution in the diatom Corethron spp. On the right is a map of the distribution of iron in the same diatom. (The images are 66 µm in width.) Lighter colors indicate higher concentrations. Note how the distribution of iron mirrors the

444

DOE - Office of Legacy Management -- Armco-Rustless Iron and Steel - MD 03  

Office of Legacy Management (LM)

Armco-Rustless Iron and Steel - MD Armco-Rustless Iron and Steel - MD 03 FUSRAP Considered Sites Site: Armco-Rustless Iron & Steel (MD.03 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: ARMCO Baltimore Works MD.03-1 Location: Baltimore , Maryland MD.03-2 Evaluation Year: 1987 MD.03-1 Site Operations: Test rolling of uranium billets. MD.03-2 MD.03-3 Site Disposition: Eliminated - Potential for contamination remote due to limited quantity of material and duration of test MD.03-1 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Uranium MD.03-2 Radiological Survey(s): Health and safety monitoring conducted during operations MD.03-2 Site Status: Eliminated from consideration under FUSRAP MD.03-1 Also see

445

Measurements of a crenelated iron pole tip for the VLHC transmission line magnet  

E-Print Network (OSTI)

The Very Large Hadron Collider (VLHC) is under conceptual design in Fermilab. One option under development is a 2-Tesla warm iron 2-in-1 single turn superferric magnet built around an 80 kA superconducting transmission line. A normal-conducting test stand was built to optimize the iron lamination shape for this magnet. It uses a water- cooled copper winding to provide the 100 kA-turns needed to generate 2 Tesla fields in both 20 mm air gaps of the magnet. A magnetic measurement facility has been set up for magnetic field mapping, which includes a flat measurement coil, precision stage for coil motion and integrator. Results from a first test of the "crenelation" technique to mitigate the saturation sextupole in iron magnets are described and future plans are discussed. (5 refs).

Di Marco, J; Kashikhin, V V; Makarov, A A; Schlabach, P; MacKay, W W

1999-01-01T23:59:59.000Z

446

Research, development, and demonstration of nickel-iron batteries for electric vehicle propulsion. Annual report, 1980  

DOE Green Energy (OSTI)

The objective of the Eagle-Picher nickel-iron battery program is to develop a nickel-iron battery for use in the propulsion of electric and electric-hybrid vehicles. To date, the program has concentrated on the characterization, fabrication and testing of the required electrodes, the fabrication and testing of full-scale cells, and finally, the fabrication and testing of full-scale (270 AH) six (6) volt modules. Electrodes of the final configuration have now exceeded 1880 cycles and are showing minimal capacity decline. Full-scale cells have presently exceeded 600 cycles and are tracking the individual electrode tests almost identically. Six volt module tests have exceeded 500 cycles, with a specific energy of 48 Wh/kg. Results to date indicate the nickel-iron battery is beginning to demonstrate the performance required for electric vehicle propulsion.

Not Available

1981-03-01T23:59:59.000Z

447

DEVELOPMENT OF PRECIPITATED IRON FISCHER-TROPSCH CATALYSTS  

SciTech Connect

Despite the current worldwide oil glut, the US will ultimately require large-scale production of liquid (transportation) fuels from coal. Slurry phase Fischer-Tropsch (F-T) technology, with its versatile product slate, may be expected to play a major role in production of transportation fuels via indirect coal liquefaction. Some of the F-T catalysts synthesized and tested at Texas A and M University under DOE Contract No. DE-AC22-89PC89868 were more active than any other known catalysts developed for maximizing production of high molecular weight hydrocarbons (waxes). The objectives of the present contract were to demonstrate repeatability of catalyst performance and reproducibility of preparation procedures of two of these catalysts on a laboratory scale. Improvements in the catalyst performance were attempted through the use of: (a) higher reaction pressure and gas space velocity to maximize the reactor productivity; (b) modifications in catalyst preparation steps; and (c) different pretreatment procedures. Repeatability of catalyst performance and reproducibility of catalyst synthesis procedure have been successfully demonstrated in stirred tank slurry reactor tests. Reactor space-time-yield was increased up to 48% by increasing reaction pressure from 1.48 MPa to 2.17 MPa, while maintaining the gas contact time and synthesis gas conversion at a constant value. Use of calcination temperatures above 300 C, additional CaO promoter, and/or potassium silicate as the source of potassium promoter, instead of potassium bicarbonate, did not result in improved catalyst performance. By using different catalyst activation procedures they were able to increase substantially the catalyst activity, while maintaining low methane and gaseous hydrocarbon selectivities. Catalyst productivity in runs SA-0946 and SA-2186 was 0.71 and 0.86 gHC/g-Fe/h, respectively, and this represents 45-75% improvement in productivity relative to that achieved in Rheinpreussen's demonstration plant unit (the most successful bubble column slurry reactor performance to date), and sets new standards of performance for ''high alpha'' iron catalysts.

Dr. Dragomir B. Bukur; Dr. X. Lang; Dr. S. Chokkaram; Dr. L. Nowicki; G. Wei; Dr. Y. Ding; Dr. B. Reddy; Dr. S. Xiao

1999-07-22T23:59:59.000Z

448

Reducing acid leaching of manganiferous ore: Effect of the iron removal operation on solid waste disposal  

Science Conference Proceedings (OSTI)

The process of reducing acid leaching of manganiferous ore is aimed at the extraction of manganese from low grade manganese ores. This work is focused on the iron removal operation. The following items have been considered in order to investigate the effect of the main operating conditions on solid waste disposal and on the process costs: (i) type and quantity of the base agent used for iron precipitation, (ii) effective need of leaching waste separation prior to the iron removal operation, (iii) presence of a second leaching stage with the roasted ore, which might also act as a preliminary iron removal step, and (iv) effect of tailings washing on the solid waste classification. Different base compounds have been tested, including CaO, CaCO{sub 3}, NaOH, and Na{sub 2}CO{sub 3}. The latter gave the best results concerning both the precipitation process kinetics and the reagent consumption. The filtration of the liquor leach prior to iron removal was not necessary, implying significant savings in capital costs. A reduction of chemical consumption and an increase of manganese concentration in the solution were obtained by introducing secondary leaching tests with the previously roasted ore; this additional step was introduced without a significant decrease of global manganese extraction yield. Finally, toxicity characteristic leaching procedure (TCLP) tests carried out on the leaching solid waste showed: (i) a reduction of arsenic mobility in the presence of iron precipitates, and (ii) the need for a washing step in order to produce a waste that is classifiable as not dangerous, taking into consideration the existing Environmental National Laws.

De Michelis, Ida; Ferella, Francesco [University of L'Aquila, Department of Chemistry, Chemical Engineering and Materials, Monteluco di Roio, 67040 L'Aquila (Italy); Beolchini, Francesca [Polytechnic University of Marche, Department of Marine Sciences, Via Brecce Bianche, 60131 Ancona (Italy)], E-mail: f.beolchini@univpm.it; Veglio, Francesco [University of L'Aquila, Department of Chemistry, Chemical Engineering and Materials, Monteluco di Roio, 67040 L'Aquila (Italy)

2009-01-15T23:59:59.000Z

449

Interim measure conceptual design for remediation at the former CCC/USDA grain storage facility at Centralia, Kansas : pilot test and remedy implementation.  

SciTech Connect

This document presents an Interim Measure Work Plan/Design for the short-term, field-scale pilot testing and subsequent implementation of a non-emergency Interim Measure (IM) at the site of the former grain storage facility operated by the Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) in Centralia, Kansas. The IM is recommended to mitigate both (1) localized carbon tetrachloride contamination in the vadose zone soils beneath the former facility and (2) present (and potentially future) carbon tetrachloride contamination identified in the shallow groundwater beneath and in the immediate vicinity of the former CCC/USDA facility. Investigations conducted on behalf of the CCC/USDA by Argonne National Laboratory have demonstrated that groundwater at the Centralia site is contaminated with carbon tetrachloride at levels that exceed the Kansas Tier 2 Risk-Based Screening Level (RBSL) and the U.S. Environmental Protection Agency's maximum contaminant level of 5.0 {micro}g/L for this compound. Groundwater sampling and analyses conducted by Argonne under a monitoring program approved by the Kansas Department of Health and Environment (KDHE) indicated that the carbon tetrachloride levels at several locations in the groundwater plume have increased since twice yearly monitoring of the site began in September 2005. The identified groundwater contamination currently poses no unacceptable health risks, in view of the absence of potential human receptors in the vicinity of the former CCC/USDA facility. Carbon tetrachloride contamination has also been identified at Centralia in subsurface soils at concentrations on the order of the Kansas Tier 2 RBSL of 200 {micro}g/kg in soil for the soil-to-groundwater protection pathway. Soils contaminated at this level might pose some risk as a potential source of carbon tetrachloride contamination to groundwater. To mitigate the existing contaminant levels and decrease the potential future concentrations of carbon tetrachloride in groundwater and soil, the CCC/USDA recommends initial short-term, field-scale pilot testing of a remedial approach that employs in situ chemical reduction (ISCR), in the form of a commercially available material marketed by Adventus Americas, Inc., Freeport, Illinois (http://www.adventusgroup.com). If the pilot test is successful, it will be followed by a request for KDHE authorization of full implementation of the ISCR approach. In the recommended ISCR approach, the Adventus EHC{reg_sign} material--a proprietary mixture of food-grade organic carbon and zero-valent iron--is introduced into the subsurface, where the components are released slowly into the formation. The compounds create highly reducing conditions in the saturated zone and the overlying vadose zone. These conditions foster chemical and biological reductive dechlorination of carbon tetrachloride. The anticipated effective lifetime of the EHC compounds following injection is 1-5 yr. Although ISCR is a relatively innovative remedial approach, the EHC technology has been demonstrated to be effective in the treatment of carbon tetrachloride contamination in groundwater and has been employed at a carbon tetrachloride contamination site elsewhere in Kansas (Cargill Flour Mill and Elevator, Wellington, Kansas; KDHE Project Code C209670158), with the approval of the KDHE. At Centralia, the CCC/USDA recommends use of the ISCR approach initially in a short-term pilot test addressing the elevated carbon tetrachloride levels identified in one of three persistently highly contaminated areas ('hot-spot areas') in the groundwater plume. In this test, a three-dimensional grid pattern of direct-push injection points will be used to distribute the EHC material (in slurry or aqueous form) throughout the volume of the contaminated aquifer and (in selected locations) the vadose zone in the selected hot-spot area. Injection of the EHC material will be conducted by a licensed contractor, under the supervision of Adventus and Argonne technical personnel. The contractor will be identified upon acceptanc

LaFreniere, L. M.; Environmental Science Division

2007-11-09T23:59:59.000Z

450

Development of Bottom-up Representation of Industrial Energy Efficiency Technologies in Integrated Assessment Models for the Iron and Steel Sector  

E-Print Network (OSTI)

energy savings with discounts rates 10%, 20% and 30% in the U.S. iron and steel industryenergy savings with discounts rates 10%, 20% and 30% in the U.S. iron and steel industry.

Xu, T.T.

2011-01-01T23:59:59.000Z

451

Lead-iron phosphate glass as a containment medium for the disposal of high-level nuclear wastes  

DOE Patents (OSTI)

Disclosed are lead-iron phosphate glasses containing a high level of Fe/sub 2/O/sub 3/ for use as a storage medium for high-level radioactive nuclear waste. By combining lead-iron phosphate glass with various types of simulated high-level nuclear waste

Boatner, L.A.; Sales, B.C.

1984-04-11T23:59:59.000Z

452

Doped, porous iron oxide films and their optical functions and anodic photocurrents for solar water splitting  

SciTech Connect

The fabrication and morphological, optical, and photoelectrochemical characterization of doped iron oxide films is presented. The complex index of refraction and absorption coefficient of polycrystalline films are determined through measurement and modeling of spectral transmission and reflection data using appropriate dispersion relations. Photoelectrochemical characterization for water photo-oxidation reveals that the conversion efficiencies of electrodes are strongly influenced by substrate temperature during their oblique-angle physical vapor deposition. These results are discussed in terms of the films' morphological features and the known optoelectronic limitations of iron oxide films for application in solar water splitting devices.

Kronawitter, Coleman X.; Mao, Samuel S. [Department of Mechanical Engineering, University of California at Berkeley, Berkeley, California 94720, USA and Environmental Energy Technologies Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Antoun, Bonnie R. [Sandia National Laboratories, Livermore, California 94551 (United States)

2011-02-28T23:59:59.000Z

453

Metal matrix composite of an iron aluminide and ceramic particles and method thereof  

DOE Patents (OSTI)

A metal matrix composite comprising an iron aluminide binder phase and a ceramic particulate phase such as titanium diboride, zirconium diboride, titanium carbide and tungsten carbide is made by heating a mixture of iron aluminide powder and particulates of one of the ceramics such as titanium diboride, zirconium diboride, titanium carbide and tungsten carbide in a alumina crucible at about 1450.degree. C. for about 15 minutes in an evacuated furnace and cooling the mixture to room temperature. The ceramic particulates comprise greater than 40 volume percent to about 99 volume percent of the metal matrix composite.

Schneibel, Joachim H. (Maryville, TN)

1997-01-01T23:59:59.000Z

454

Effect of magnetic field on the mechanical properties of magnetostrictive iron-gallium nanowires  

SciTech Connect

This study experimentally investigates the elastic properties of individual iron-gallium nanowires with and without an applied magnetic bias field. The experiments were conducted with a custom manipulator stage designed for use within a scanning electron microscope, where nanowires were mechanically tested both statically and dynamically. Experiments were also performed in the presence of a 20 Oe dc magnetic field in order to identify any variation in wire properties. The results suggest that iron-gallium nanowires possess an elastic modulus very similar to the macroscale value, tensile strengths of more than double the bulk material, and minor magnetic field induced stiffening at low stresses.

Downey, Patrick R.; Flatau, Alison B. [Department of Aerospace Engineering, University of Maryland, 3181 Martin Hall, College Park, Maryland 20742 (United States); McGary, Patrick D.; Stadler, Bethanie J. H. [Department of Electrical and Computer Engineering, University of Minnesota, 200 Union St., Minneapolis, Minnesota 55455 (United States)

2008-04-01T23:59:59.000Z

455

Development of Bottom-up Representation of Industrial Energy Efficiency Technologies in Integrated Assessment Models for the Iron and Steel Sector  

E-Print Network (OSTI)

38 COKEplants where iron ore fines, coke breeze, water treatmentto reduce the amount of coke required. Maximum theoretical

Xu, T.T.

2011-01-01T23:59:59.000Z

456

The Reaction Specificity of Nanoparticles in Solution: Application to the Reaction of Nanoparticulate Iron and Iron-Bimetallic Compounds with Chlorinated Hydrocarbons and Oxyanions  

SciTech Connect

The prospect for better remediation technologies using nanoparticles of iron, iron oxides, and iron with catalytic metals (i.e., bimetallics) has potentially transformative implications for environmental management of DOE sites across the country. Of particular interest is the potential to avoid undesirable products from the degradation of chlorinated solvents by taking advantage of the potential selectivity of nanoparticles to produce environmentally benign products from CCl{sub 4}. Chlorinated solvents are the most frequently reported subsurface contaminants across the whole DOE complex, and carbon tetrachloride (CCl{sub 4}) is the chlorinated solvent that is of greatest concern at Hanford (U. S. Department Energy 2001). In evaluating technologies that might be used at the site, a critical concern will be that CCl{sub 4} reduction usually occurs predominantly by hydrogenolysis to chloroform (CHCl{sub 3}) and methylene chloride (CH{sub 2}Cl{sub 2}), both of which are nearly as problematic as CCl{sub 4} (National Research Council, 1978). Competing reaction pathways produce the more desirable products carbon monoxide (CO) and/or formate (HCOO{sup -}), and possibly CO{sub 2}, but the proportion of reaction that occurs by these pathways is highly variable. Iron-based metallic and oxide nanoparticles have been shown to have enhanced reactivity towards a variety of chemical species, including chlorinated hydrocarbons and reducible oxyanions. Possibly of greater importance is the ability of nanoparticles to select for specific reaction products, potentially facilitating the formation of more environmentally acceptable products. The purpose of this study is to develop a fundamental understanding of the mechanism responsible for the overall particle reactivity and reaction selectivity of reactive metal and oxide nanoparticles. To achieve this objective the project involves the synthesis (using solution and vacuum synthesis methods) and characterization of well-defined nanoparticles, measurements of particle reactivity in solution or vacuum environments, and theory and modeling efforts to rationalize particle structure and reactivity.

None

2005-06-01T23:59:59.000Z

457

Prevention & Treatment  

NLE Websites -- All DOE Office Websites (Extended Search)

Prevention and Treatment Prevention and Treatment These steps may help prevent the spread of respiratory illnesses such as the flu: Stay Healthy Vaccination Antivirals Stay Informed Stay Healthy Cover your nose and mouth with a tissue when you cough or sneeze-throw the tissue away immediately after you use it. Wash your hands often with soap and water, especially after you cough or sneeze. If you are not near water, use an alcohol-based (60-95%) hand cleaner. Avoid close contact with people who are sick. When you are sick, keep your distance from others to protect them from getting sick too. If you get the flu, stay home from work, school, and social gatherings. This will help prevent others from catching your illness. Try not to touch your eyes, nose, or mouth. Germs often spread this way.

458

Waste Treatment Plant Overview  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Hanford Site, located in southeastern Washington state, Hanford Site, located in southeastern Washington state, was the largest of three defense production sites in the U.S. Over the span of 40 years, it was used to produce 64 metric tons of plutonium, helping end World War II and playing a major role in military defense efforts during the Cold War. As a result, 56 million gallons of radioactive and chemical wastes are now stored in 177 underground tanks on the Hanford Site. To address this challenge, the U.S. Department of Energy contracted Bechtel National, Inc., to design and build the world's largest radioactive waste treatment plant. The Waste Treatment and Immobilization Plant (WTP), also known as the "Vit Plant," will use vitrification to immobilize most of Hanford's dangerous tank waste.

459

Iron Dominated Electromagnets: Design, Fabrication, Assembly and Measurements  

SciTech Connect

Medium energy electron synchrotrons used for the production of high energy photons from synchrotron radiation is an accelerator growth industry. Many of these accelerators have been built or are under construction to satisfy the needs of synchrotron light users throughout the world. Because of the long beam lifetimes required for these synchrotrons, these medium energy accelerators require the highest quality magnets of various types. Other accelerators, for instance low and medium energy boosters for high energy physics machines and electron/positron colliders, require the same types of magnets. Because of these needs, magnet design lectures, were organized and presented periodically at biennual classes organized under the auspices of the US Particle Accelerator School (USPAS). These classes were divided among areas of magnet design from fundamental theoretical considerations, the design approaches and algorithms for permanent magnet wigglers and undulators and the design and engineering of conventional accelerator magnets. The conventional magnet lectures were later expanded for the internal training of magnet designers at LLNL at the request of Lou Bertolini. Because of the broad nature of magnet design, Dr. S. Y. Lee, the former Director of the Particle Accelerator School, saw the need for a specialized course covering the various aspects of the design, engineering and fabrication of conventional magnets. This section of the class was isolated and augmented using the LLNL developed material resulting in the class on conventional magnet design. Conventional magnets are defined (for the purposes of this publication) as magnets whose field shape is dominated by the shape of the iron magnet yoke and are excited by coils, usually wound from solid or hollow water-cooled copper or aluminum conductors. This publication collects the lecture notes, written for the first course in the USPAS conventional magnet design course and evolved over subsequent presentations of this same course, and organizes the material roughly divided among two parts. One part is theoretical and computational and attempts to provide a foundation for later chapters which exploit the expressions and algorithms for the engineering and design calculations required to specify magnet conceptual designs. A chapter is devoted to the description and use of one of many magnet codes used to characterize the two dimensional field resulting from various magnet cross-sections. A chapter is included which exploits the two-dimensional theory and applies the mathematics to techniques and systems for magnet measurement. The second part of this publication ranges to practical issues associated with the fabrication of components, assembly, installation and alignment of magnets. This section also includes fabrication practices which respond to personnel and equipment protection needs. Required design calculations are supplemented by examples and problems. A CD is included with tools provided to simplify the computation of some of the more tedious relationships. This CD also includes useful photographs and pictures describing the high volume production of typical magnet types, which if included in the publication will add too many pages and increase the cost of publication. Styles among those facing similar problems will result in a wide variation of individual magnet designs. Designs and technologies will evolve and improve. This publication provides a snapshot of the present technology and presents as examples the magnet designs developed in response to the needs of several projects, the Advanced Light Source at LBNL, PEPII Low Energy Ring and SPEAR3 synchrotron light source at SLAC and the Australian Light Source, currently under construction in Melbourne. In each example, the reasons for fabrication design decisions are itemized and rationalized as much as is reasonable. The examples presented in this publication are provided as starting points which can be used as a design basis for magnets required for future projects. It is hoped that the listing of some design choi

Tanabe, Jack; /SLAC, SSRL

2005-09-19T23:59:59.000Z

460

Hydrogen production from the steam-iron process with direct reduction of iron oxide by chemical looping combustion of coal char  

SciTech Connect

Experimental results performed with a fluidized-bed reactor supported the feasibility of the three processes including direct reduction of iron oxide by char, H{sub 2} production by the steam-iron process, and the oxidation of Fe{sub 3}O{sub 4} resulting from the steam-iron process to the original Fe{sub 2}O{sub 3} by air. Chars resulting from a Chinese lignite loaded with K{sub 2}CO{sub 3} were used successfully as a reducing material, leading to the reduction of Fe{sub 2}O{sub 3} to FeO and Fe for the steam-iron process, which was confirmed by both the off-gases concentrations and X-ray diffractometer analysis. The reduction of Fe{sub 2}O{sub 3} by K-10-char at 1073 K is desirable from the perspective of the carbon conversion rate and high concentration of CO{sub 2}. The carbon in char was completely converted to CO{sub 2} when the mass ratio of Fe{sub 2}O{sub 3}/K-10-char was increased to 10/0.3. The oxidation rate of K-10-char by Fe{sub 2}O{sub 3} without a gasifying agent was comparable to the K-10-char steam gasification rate. The fractions of FeO and Fe in the reduced residue were 43 and 57%, respectively, in the case of 3 g of Fe{sub 2}O{sub 3} and 0.5 g of K-10-char, which was verified by the total H{sub 2} yield equaling 1000 mL/g K-10-char from the steam-iron process. The time that it took to achieve complete oxidation of Fe{sub 3}O{sub 4} to Fe{sub 2}O{sub 3} by air with an 8.7% O{sub 2} concentration at 1073 K was about 15 min. 53 refs., 19 figs., 5 tabs.

Jing-biao Yang; Ning-sheng Cai; Zhen-shan Li [Tsinghua University, Beijing (China). Key Laboratory of Thermal Science and Power Engineering of Ministry of Education

2008-07-15T23:59:59.000Z

Note: This page contains sample records for the topic "zero-valent iron treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Iron-Phosphate Ceramics for Solidification of Mixed Low-Level Waste  

DOE Patents (OSTI)

A method of immobilizing mixed low-level waste is provided which uses low cost materials and has a relatively long hardening period. The method includes: forming a mixture of iron oxide powders having ratios, in mass %, of FeO: Fe{sub 2}O{sub 3}: Fe{sub 3}O{sub 4} equal to 25-40: 40-10: 35-50, or weighing a definite amount of magnitite powder. Metallurgical cinder can also be used as the source of iron oxides. A solution of the orthophosphoric acid, or a solution of the orthophosphoric acid and ferric oxide, is formed and a powder phase of low-level waste and the mixture of iron oxide powders or cinder (or magnetite powder) is also formed. The acid solution is mixed with the powder phase to form a slurry with the ratio of components (mass %) of waste: iron oxide powders or magnitite: acid solution = 30-60: 15-10: 55-30. The slurry is blended to form a homogeneous mixture which is cured at room temperature to form the final product.

Aloy, Albert S.; Kovarskaya, Elena N.; Koltsova, Tatiana I.; Macheret, Yevgeny; Medvedev, Pavel G.; Todd, Terry

1998-08-07T23:59:59.000Z

462

Energy - environmental methods to reduce CO2emissions in Romanian iron and steel industry  

Science Conference Proceedings (OSTI)

This paper presents some energy-environmental methods for reducing the CO2 emissions in Romanian iron and steel processes, both technological, as well as combustion processes, in case of integrated, technological and energetic approach, using ... Keywords: CO2 emissions, emissions reduction, energy-environmental methods, integrated system, mathematical model

Ion Melinte; Mihaela Balanescu

2009-02-01T23:59:59.000Z

463

Iron-phosphate ceramics for solidification of mixed low-level waste  

DOE Patents (OSTI)

A method of immobilizing mixed low-level waste is provided which uses low cost materials and has a relatively long hardening period. The method includes: forming a mixture of iron oxide powders having ratios, in mass %, of FeO:Fe.sub.2 O.sub.3 :Fe.sub.3 O.sub.4 equal to 25-40:40-10:35-50, or weighing a definite amount of magnetite powder. Metallurgical cinder can also be used as the source of iron oxides. A solution of the orthophosphoric acid, or a solution of the orthophosphoric acid and ferric oxide, is formed and a powder phase of low-level waste and the mixture of iron oxide powders or cinder (or magnetite powder) is also formed. The acid solution is mixed with the powder phase to form a slurry with the ratio of components (mass %) of waste:iron oxide powders or magnetite:acid solution=30-60:15-10:55-30. The slurry is blended to form a homogeneous mixture which is cured at room temperature to form the final product.

Aloy, Albert S. (St. Petersburg, RU); Kovarskaya, Elena N. (St. Petersburg, RU); Koltsova, Tatiana I. (St. Petersburg, RU); Macheret, Yevgeny (Idaho Falls, ID); Medvedev, Pavel G. (Ozersk, RU); Todd, Terry (Aberdeen, ID)

2000-01-01T23:59:59.000Z

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Influence of Processing on Microstructure and Properties of Iron Aluminides and Coatings  

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Influence of Processing on Microstructure Influence of Processing on Microstructure and Properties of Iron Aluminides and Coatings Background The search for cleaner processes and greater efficiencies in fossil energy power production has generated efforts to conduct fossil fuel based power production processes at higher operating temperatur