Sample records for year treasury bond

  1. Information Shocks, Liquidity Shocks, Jumps, and Price Discovery: Evidence from the U.S. Treasury Market

    E-Print Network [OSTI]

    Jiang, George J.

    In this paper, we identify jumps in U.S. Treasury-bond (T-bond) prices and investigate what causes such unexpected large price changes. In particular, we examine the relative importance of macroeconomic news announcements ...

  2. It is ten years since... Daniel Bond and Derek R. Lovley's AEM paper `Electricity Production by

    E-Print Network [OSTI]

    Lovley, Derek

    2 It is ten years since... Daniel Bond and Derek R. Lovley's AEM paper `Electricity Production by Geobacter sulfurreducens Attached To Electrodes' was published in 2003. "Science is as much luck as anything to electricity at high columbic efficiencies and that this could be a sustainable process because

  3. Qualified Energy Conservation Bond (QECB) Update: New Guidance...

    Broader source: Energy.gov (indexed) [DOE]

    Lawrence Berkeley National Laboratory Qualified Energy Conservation Bond (QECB) Update: New Guidance from the U.S. Department of Treasury and the Internal Revenue Service...

  4. THE PANCHROMATIC HUBBLE ANDROMEDA TREASURY

    SciTech Connect (OSTI)

    Dalcanton, Julianne J.; Williams, Benjamin F.; Rosenfield, Philip; Weisz, Daniel R.; Gilbert, Karoline M.; Gogarten, Stephanie M. [Department of Astronomy, University of Washington, Box 351580, Seattle, WA 98195 (United States); Lang, Dustin [Department of Astrophysical Sciences, Princeton University, Princeton, NJ 08544 (United States); Lauer, Tod R.; Dong Hui [National Optical Astronomy Observatory, 950 North Cherry Avenue, Tucson, AZ 85719 (United States); Kalirai, Jason S.; Boyer, Martha L.; Gordon, Karl D. [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Seth, Anil C. [Department of Physics and Astronomy, University of Utah, Salt Lake City, UT 84112 (United States); Dolphin, Andrew [Raytheon Company, 1151 East Hermans Road, Tucson, AZ 85756 (United States); Bell, Eric F. [Department of Astronomy, University of Michigan, 500 Church St., Ann Arbor, MI 48109 (United States); Bianchi, Luciana C. [Department of Physics and Astronomy, Johns Hopkins University, Baltimore, MD 21218 (United States); Caldwell, Nelson [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Dorman, Claire E.; Guhathakurta, Puragra [University of California Observatories/Lick Observatory, University of California, 1156 High St., Santa Cruz, CA 95064 (United States); Girardi, Leo [Osservatorio Astronomico di Padova-INAF, Vicolo dell'Osservatorio 5, I-35122 Padova (Italy); and others

    2012-06-01T23:59:59.000Z

    The Panchromatic Hubble Andromeda Treasury is an ongoing Hubble Space Telescope Multi-Cycle Treasury program to image {approx}1/3 of M31's star-forming disk in six filters, spanning from the ultraviolet (UV) to the near-infrared (NIR). We use the Wide Field Camera 3 (WFC3) and Advanced Camera for Surveys (ACS) to resolve the galaxy into millions of individual stars with projected radii from 0 to 20 kpc. The full survey will cover a contiguous 0.5 deg{sup 2}area in 828 orbits. Imaging is being obtained in the F275W and F336W filters on the WFC3/UVIS camera, F475W and F814W on ACS/WFC, and F110W and F160W on WFC3/IR. The resulting wavelength coverage gives excellent constraints on stellar temperature, bolometric luminosity, and extinction for most spectral types. The data produce photometry with a signal-to-noise ratio of 4 at m{sub F275W} = 25.1, m{sub F336W} = 24.9, m{sub F475W} = 27.9, m{sub F814W} = 27.1, m{sub F110W} = 25.5, and m{sub F160W} = 24.6 for single pointings in the uncrowded outer disk; in the inner disk, however, the optical and NIR data are crowding limited, and the deepest reliable magnitudes are up to 5 mag brighter. Observations are carried out in two orbits per pointing, split between WFC3/UVIS and WFC3/IR cameras in primary mode, with ACS/WFC run in parallel. All pointings are dithered to produce Nyquist-sampled images in F475W, F814W, and F160W. We describe the observing strategy, photometry, astrometry, and data products available for the survey, along with extensive testing of photometric stability, crowding errors, spatially dependent photometric biases, and telescope pointing control. We also report on initial fits to the structure of M31's disk, derived from the density of red giant branch stars, in a way that is independent of assumed mass-to-light ratios and is robust to variations in dust extinction. These fits also show that the 10 kpc ring is not just a region of enhanced recent star formation, but is instead a dynamical structure containing a significant overdensity of stars with ages >1 Gyr.

  5. Treasury, Energy Announce Guidance for Tax Treatment of Smart...

    Office of Environmental Management (EM)

    Treasury, Energy Announce Guidance for Tax Treatment of Smart Grid Investment Grants Treasury, Energy Announce Guidance for Tax Treatment of Smart Grid Investment Grants March 10,...

  6. Energy Secretary and Secretary of the Treasury Announce the Award...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Secretary of the Treasury Announce the Award of 1 Billion in Tax Credits to Promote Clean Coal Power Generation and Gasification Technologies Energy Secretary and Secretary of the...

  7. 1. Was your auditor for the Revenue Bond Series 2003A and 2005A financial audit year ended 6/30/12 invited to bid?

    E-Print Network [OSTI]

    IFB13403 1. Was your auditor for the Revenue Bond Series 2003A and 2005A financial audit year for last year's audit? The existing contract budget is structured with hourly rates, so there isn't a set fee structure for each audit. The cumulative total of invoices for the FY 11/12 audit was $16

  8. THE ACS NEARBY GALAXY SURVEY TREASURY

    SciTech Connect (OSTI)

    Dalcanton, Julianne J.; Williams, Benjamin F.; Rosema, Keith; Gogarten, Stephanie M.; Christensen, Charlotte; Gilbert, Karoline; Hodge, Paul [Department of Astronomy, Box 351580, University of Washington, Seattle, WA 98195 (United States); Seth, Anil C. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Dolphin, Andrew [Raytheon, 1151 E. Hermans Road, Tucson, AZ 85756 (United States); Holtzman, Jon [Department of Astronomy, New Mexico State University, Box 30001, 1320 Frenger St., Las Cruces, NM 88003 (United States); Skillman, Evan D.; Weisz, Daniel [Department of Astronomy, University of Minnesota, 116 Church St. SE, Minneapolis, MN 55455 (United States); Cole, Andrew [School of Mathematics and Physics, University of Tasmania, Hobart, Tasmania (Australia); Girardi, Leo [Osservatorio Astronomico di Padova - INAF, Vicolo dell'Osservatorio 5, I-35122 Padova (Italy); Karachentsev, Igor D. [Special Astrophysical Observatory, Russian Academy of Sciences, Nizhnji Arkhyz, Karachai-Circessia Republic 369167 (Russian Federation); Olsen, Knut [NOAO, National Optical Astronomy Observatory 950 N. Cherry Ave., Tucson, AZ 85719 (United States); Freeman, Ken [Mount Stromlo Observatory, Research School of Astronomy and Astrophysics, The Australian National Univ., ACT 0200 (Australia); Gallart, Carme [Inst. de AstrofIsica de Canarias, VIa Lactea, s/n, 38200 La Laguna, Tenerife (Spain); Harris, Jason [Steward Observatory, Univ. of Arizona, 933 North Cherry Avenue, Tucson, AZ 85721 (United States); De Jong, Roelof S. [Space Telescope Science Inst., 3700 San Martin Dr., Baltimore, MD 21218 (United States)], E-mail: jd@astro.washington.edu, E-mail: ben@astro.washington.edu, E-mail: krosema@astro.washington.edu, E-mail: stephanie@astro.washington.edu, E-mail: christensen@astro.washington.edu, E-mail: fabio@astro.washington.edu, E-mail: trq@astro.washington.edu, E-mail: aseth@cfa.harvard.edu (and others)

    2009-07-15T23:59:59.000Z

    The ACS Nearby Galaxy Survey Treasury (ANGST) is a systematic survey to establish a legacy of uniform multi-color photometry of resolved stars for a volume-limited sample of nearby galaxies (D < 4 Mpc). The survey volume encompasses 69 galaxies in diverse environments, including close pairs, small and large groups, filaments, and truly isolated regions. The galaxies include a nearly complete range of morphological types spanning a factor of {approx}10{sup 4} in luminosity and star formation rate. The survey data consist of images taken with the Advanced Camera for Surveys (ACS) on the Hubble Space Telescope (HST), supplemented with archival data and new Wide Field Planetary Camera 2 (WFPC2) imaging taken after the failure of ACS. Survey images include wide field tilings covering the full radial extent of each galaxy, and single deep pointings in uncrowded regions of the most massive galaxies in the volume. The new wide field imaging in ANGST reaches median 50% completenesses of m {sub F475W} = 28.0 mag, m {sub F606W} = 27.3 mag, and m {sub F814W} = 27.3 mag, several magnitudes below the tip of the red giant branch (TRGB). The deep fields reach magnitudes sufficient to fully resolve the structure in the red clump. The resulting photometric catalogs are publicly accessible and contain over 34 million photometric measurements of >14 million stars. In this paper we present the details of the sample selection, imaging, data reduction, and the resulting photometric catalogs, along with an analysis of the photometric uncertainties (systematic and random), for both ACS and WFPC2 imaging. We also present uniformly derived relative distances measured from the apparent magnitude of the TRGB.

  9. July 18, 2012 Qualified Energy Conservation Bond (QECB) Update: New

    E-Print Network [OSTI]

    July 18, 2012 Qualified Energy Conservation Bond (QECB) Update: New Guidance from the U.S. Department of Treasury and the Internal Revenue Service Qualified Energy Conservation Bonds (QECBs a range of energy conservation projects at very attractive borrowing rates over long contract terms

  10. YEAR

    National Nuclear Security Administration (NNSA)

    8 YEAR 2013 Males 27 Females 11 YEAR 2013 SES 1 EN 05 1 EN 04 11 NN (Engineering) 8 NQ (ProfTechAdmin) 15 NU (TechAdmin Support) 2 YEAR 2013 American Indian Alaska Native Male...

  11. YEAR

    National Nuclear Security Administration (NNSA)

    96 YEAR 2013 Males 69 Females 27 YEAR 2013 SES 1 EJEK 9 EN 04 27 NN (Engineering) 26 NQ (ProfTechAdmin) 30 NU (TechAdmin Support) 3 YEAR 2013 American Indian Alaska Native Male...

  12. YEAR

    National Nuclear Security Administration (NNSA)

    1 YEAR 2014 Males 48 Females 33 PAY PLAN YEAR 2014 SES 1 EJEK 8 EN 04 10 EN 03 1 NN (Engineering) 27 NQ (ProfTechAdmin) 29 NU (TechAdmin Support) 5 YEAR 2014 American Indian...

  13. YEAR

    National Nuclear Security Administration (NNSA)

    8 YEAR 2014 Males 18 Females 10 PAY PLAN YEAR 2014 SES 1 EN 05 1 EN 04 4 NN (Engineering) 12 NQ (ProfTechAdmin) 9 NU (TechAdmin Support) 1 YEAR 2014 American Indian Alaska...

  14. YEAR

    National Nuclear Security Administration (NNSA)

    5 YEAR 2014 Males 61 Females 24 PAY PLAN YEAR 2014 SES 1 EJEK 8 EN 04 22 NN (Engineering) 23 NQ (ProfTechAdmin) 28 NU (TechAdmin Support) 3 YEAR 2014 American Indian Alaska...

  15. YEAR

    National Nuclear Security Administration (NNSA)

    0 YEAR 2013 Males 48 Females 32 YEAR 2013 SES 2 EJEK 7 EN 04 11 EN 03 1 NN (Engineering) 23 NQ (ProfTechAdmin) 33 NU (TechAdmin Support) 3 YEAR 2013 American Indian Alaska...

  16. YEAR

    National Nuclear Security Administration (NNSA)

    31 YEAR 2013 Males 20 Females 11 YEAR 2013 SES 2 EN 04 4 NN (Engineering) 12 NQ (ProfTechAdmin) 12 NU (TechAdmin Support) 1 YEAR 2013 American Indian Alaska Native Male (AIAN,...

  17. YEAR

    National Nuclear Security Administration (NNSA)

    2014 Males 81 Females 45 PAY PLAN YEAR 2014 SES 1 SL 1 EJEK 25 EN 04 26 EN 03 2 NN (Engineering) 23 NQ (ProfTechAdmin) 44 NU (TechAdmin Support) 4 YEAR 2014 American Indian...

  18. YEAR

    National Nuclear Security Administration (NNSA)

    25 Females 10 YEAR 2014 SES 1 EN 04 11 NN (Engineering) 8 NQ (ProfTechAdmin) 13 NU (TechAdmin Support) 2 YEAR 2014 American Indian Alaska Native Male (AIAN M) 0 American Indian...

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    National Nuclear Security Administration (NNSA)

    3 YEAR 2014 Males 59 Females 24 PAY PLAN YEAR 2014 SES 1 EJEK 4 EN 05 3 EN 04 22 EN 03 8 NN (Engineering) 15 NQ (ProfTechAdmin) 27 NU (TechAdmin Support) 3 YEAR 2014 American...

  20. YEAR

    National Nuclear Security Administration (NNSA)

    8 YEAR 2013 Males 62 Females 26 YEAR 2013 SES 1 EJEK 3 EN 05 1 EN 04 28 EN 03 1 NN (Engineering) 25 NQ (ProfTechAdmin) 27 NU (TechAdmin Support) 2 YEAR 2013 American Indian...

  1. YEAR

    National Nuclear Security Administration (NNSA)

    5 YEAR 2013 Males 58 Females 27 YEAR 2013 SES 1 EJEK 4 EN 05 3 EN 04 21 EN 03 8 NN (Engineering) 16 NQ (ProfTechAdmin) 28 NU (TechAdmin Support) 4 YEAR 2013 American Indian...

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    National Nuclear Security Administration (NNSA)

    8 Females 25 PAY PLAN YEAR 2014 SES 1 EJEK 3 EN 05 1 EN 04 25 EN 03 1 NN (Engineering) 25 NQ (ProfTechAdmin) 25 NU (TechAdmin Support) 2 YEAR 2014 American Indian Alaska Native...

  3. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S. 200874 YEAR4 YEAR

  4. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S. 200874 YEAR4 YEAR7

  5. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S. 200874 YEAR43 YEAR

  6. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S.3 YEAR 20144 YEAR

  7. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S.3 YEAR8 YEAR 2013

  8. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S.3 YEAR8 YEAR 20138

  9. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S.3 YEAR8 YEAR 201387

  10. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S.3 YEAR8 YEAR

  11. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S.3 YEAR8 YEAR558

  12. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S.3 YEAR8 YEAR558563

  13. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S.3 YEAR85573380 YEAR

  14. YEAR

    National Nuclear Security Administration (NNSA)

    YEAR 2012 2013 SES 2 1 -50.00% EN 05 0 1 100.00% EN 04 4 4 0.00% NN (Engineering) 13 12 -7.69% NQ (ProfTechAdmin) 13 9 -30.77% NU (TechAdmin Support) 1 1...

  15. Hydrogen Bonded Arrays: The Power of Multiple Hydrogen Bonds...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bonded Arrays: The Power of Multiple Hydrogen Bonds. Hydrogen Bonded Arrays: The Power of Multiple Hydrogen Bonds. Abstract: Hydrogen bond interactions in small covalent model...

  16. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S. 2008 A794826 YEAR

  17. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S. 200874 YEAR 2014

  18. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S. 200874 YEAR 201434

  19. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S. 200874 YEAR

  20. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S. 200874 YEAR4

  1. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S. 200874 YEAR43

  2. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S. 200874 YEAR434

  3. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S. 200874 YEAR43417

  4. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S. 200874 YEAR434170

  5. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S. 20087486 YEAR 2012

  6. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S. 20087486 YEAR

  7. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S. 20087486 YEAR42

  8. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S. 20087486 YEAR424

  9. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S. 20087486 YEAR4247

  10. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S. 20087486 YEAR42478

  11. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S. 200874861 YEAR

  12. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S. 200874861 YEAR40

  13. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S. 200874861 YEAR4096

  14. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S. 20087486111 YEAR

  15. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S. 20087486111 YEAR17

  16. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S. 2008748611196 YEAR

  17. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S.3 YEAR 2014 Males

  18. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S.3 YEAR 2014 Males16

  19. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S.3 YEAR 2014

  20. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S.3 YEAR 20144

  1. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S.3 YEAR 20144707

  2. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S.3 YEAR 201447072540

  3. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S.3 YEAR

  4. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S.3 YEAR8

  5. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S.3 YEAR8557 563

  6. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S.3 YEAR8557 56378

  7. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S.3 YEAR8557 5637831

  8. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S.3 YEAR8557 56378318

  9. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S.3 YEAR8557

  10. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S.3 YEAR855733 28

  11. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S.3 YEAR855733 280

  12. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S.3 YEAR855733 2801

  13. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S.3 YEAR855733 280192

  14. YEAR

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch SNLMaythe Interior U.S.3 YEAR855733

  15. Year

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001)gasoline prices4 Oil demand Motor444 U.S.Working and.

  16. Preliminary Evaluation of the Section 1603 Treasury Grant Program for Renewable Power Projects in the United States

    E-Print Network [OSTI]

    Bolinger, Mark

    2012-01-01T23:59:59.000Z

    Trends in Tax Equity for Renewable Energy. ” Project Financefirms/ _________. 2010b. “Renewable Energy Money Still GoingTreasury Grant Program on Renewable Energy Deployment in

  17. Investing in Bonds

    E-Print Network [OSTI]

    Johnson, Jason; Polk, Wade

    2002-08-12T23:59:59.000Z

    Bonds, which are issued by governments and corporations, can be an important part of one's investment portfolio. U.S. government bonds, municipal bonds, zero-coupon bonds and other types are described. Also learn strategies for coping with inflation...

  18. Form W-7(Rev. January 2012) Department of the Treasury

    E-Print Network [OSTI]

    , a U.S. social security number (SSN). · Getting an ITIN does not change your immigration status or your (EIN)? No/Do not know. Skip line 6f. Yes. Complete line 6f. If more than one, list on a sheet-appointed guardian Power of Attorney Acceptance Agent's Use ONLY Signature Date (month / day / year) / / Phone Fax

  19. Energy, Treasury Now Accepting Applications for Funding For Renewable

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011AT&T,OfficeEnd of Year 2010 SNFEnergySession 3 |DepartmentDepartment of Energy

  20. Pauling bond strength, bond length and electron density distribution...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pauling bond strength, bond length and electron density distribution. Pauling bond strength, bond length and electron density distribution. Abstract: A power law regression...

  1. Surety Bond Program (Maryland)

    Broader source: Energy.gov [DOE]

    The Surety Bond Program, a program of the Maryland Small Business Development Financing Authority, assists eligible small businesses in obtaining bid, performance or payment bonds necessary to...

  2. Using Qualified Energy Conservation Bonds for Public

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of the Treasury (Treasury). The city leveraged 6.25 million of its QECB allocation to finance half of a 12.6 million initiative to upgrade the energy efficiency of City...

  3. Ideally Glassy Hydrogen Bonded Networks

    E-Print Network [OSTI]

    J. C. Phillips

    2005-08-05T23:59:59.000Z

    The axiomatic theory of ideally glassy networks, which has proved effective in describing phase diagrams and properties of chalcogenide and oxide glasses and their foreign interfaces, is broadened here to include intermolecular interactions in hydrogen-bonded polyalcohols such as glycerol, monosaccharides (glucose), and the optimal bioprotective hydrogen-bonded disaccharide networks formed from trehalose. The methods of Lagrangian mechanics and Maxwellian scaffolds are useful at the molecular level when bonding hierarchies are characterized by constraint counting similar to the chemical methods used by Huckel and Pauling. Whereas Newtonian molecular dynamical methods are useful for simulating large-scale interactions for times of order 10 ps, constraint counting describes network properties on glassy (almost equilibrated) time scales, which may be of cosmological order for oxide glasses, or years for trehalose. The ideally glassy network of trehalose may consist of extensible tandem sandwich arrays.

  4. Bond Financing (New Jersey)

    Broader source: Energy.gov [DOE]

    Bond financing is available to eligible businesses through the New Jersey Economic Development Authority, in the amount of $500,000 to $10 million. The bonds can be used to finance capital...

  5. Essays on corporate bonds

    E-Print Network [OSTI]

    Bao, Jack (Jack C.)

    2009-01-01T23:59:59.000Z

    This thesis consists of three empirical essays on corporate bonds, examining the role of both credit risk and liquidity. In the first chapter, I test the ability of structural models of default to price corporate bonds in ...

  6. Local Government Revenue Bonds (Montana)

    Broader source: Energy.gov [DOE]

    Limited obligation local government bonds ("special revenue bonds") may be issued for qualified electric energy generation facilities, including those powered by renewables. These bonds generally...

  7. Bonding thermoplastic polymers

    DOE Patents [OSTI]

    Wallow, Thomas I. (Fremont, CA); Hunter, Marion C. (Livermore, CA); Krafcik, Karen Lee (Livermore, CA); Morales, Alfredo M. (Livermore, CA); Simmons, Blake A. (San Francisco, CA); Domeier, Linda A. (Danville, CA)

    2008-06-24T23:59:59.000Z

    We demonstrate a new method for joining patterned thermoplastic parts into layered structures. The method takes advantage of case-II permeant diffusion to generate dimensionally controlled, activated bonding layers at the surfaces being joined. It is capable of producing bonds characterized by cohesive failure while preserving the fidelity of patterned features in the bonding surfaces. This approach is uniquely suited to production of microfluidic multilayer structures, as it allows the bond-forming interface between plastic parts to be precisely manipulated at micrometer length scales. The bond enhancing procedure is easily integrated in standard process flows and requires no specialized equipment.

  8. Private Activity Revenue Bonds (Maryland)

    Broader source: Energy.gov [DOE]

    Private Activity Revenue Bonds are available in the form of both taxable bonds and tax-exempt bonds. Both types of bonds provide access to long-term capital markets for fixed asset financing....

  9. THE ACS NEARBY GALAXY SURVEY TREASURY. III. CEPHEIDS IN THE OUTER DISK OF M81

    SciTech Connect (OSTI)

    McCommas, Les P.; Williams, Benjamin F.; Dalcanton, Julianne J.; Davis, Matthew R. [Astronomy Department, University of Washington, Box 351580, Seattle, WA 98195 (United States); Yoachim, Peter [Department of Astronomy and McDonald Observatory, University of Texas, Austin, TX 78712 (United States); Dolphin, Andrew E. [Raytheon Corporation, 870 Winter Street Waltham, MA 02451 (United States)], E-mail: lmccomma@astro.washington.edu, E-mail: jd@astro.washington.edu, E-mail: ben@astro.washington.edu, E-mail: mrdavis@astro.washington.edu, E-mail: yoachim@astro.as.utexas.edu, E-mail: adolphin@ratheon.com

    2009-06-15T23:59:59.000Z

    The ACS Nearby Galaxy Survey Treasury (ANGST) has acquired deep ACS imaging of a field in the outer disk of the large spiral galaxy M81. These data were obtained over a total of 20 Hubble Space Telescope orbits, providing a baseline long enough to reliably identify Cepheid variable stars in the field. Fundamental mode and first overtone types have been distinguished through comparative fits with corresponding Cepheid light curve templates derived from principal component analysis of confirmed Cepheids in the Large Magellanic Cloud (LMC), Small Magellanic Cloud, and Milky Way. A distance modulus of 27.78 {+-} 0.05 {sub r} {+-} 0.14 {sub s} with a corresponding distance of 3.60 {+-} 0.23 Mpc has been calculated from a sample of 11 fundamental mode and two first overtone Cepheids (assuming an LMC distance modulus of {mu}{sub LMC} = 18.41 {+-} 0.10 {sub r} {+-} 0.13 {sub s})

  10. Bonded semiconductor substrate

    DOE Patents [OSTI]

    Atwater, Jr.; Harry A. (South Pasadena, CA), Zahler; James M. (Pasadena, CA)

    2010-07-13T23:59:59.000Z

    Ge/Si and other nonsilicon film heterostructures are formed by hydrogen-induced exfoliation of the Ge film which is wafer bonded to a cheaper substrate, such as Si. A thin, single-crystal layer of Ge is transferred to Si substrate. The bond at the interface of the Ge/Si heterostructures is covalent to ensure good thermal contact, mechanical strength, and to enable the formation of an ohmic contact between the Si substrate and Ge layers. To accomplish this type of bond, hydrophobic wafer bonding is used, because as the invention demonstrates the hydrogen-surface-terminating species that facilitate van der Waals bonding evolves at temperatures above 600.degree. C. into covalent bonding in hydrophobically bound Ge/Si layer transferred systems.

  11. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing...

  12. Preliminary Evaluation of the Impact of the Section 1603 Treasury Grant Program on Renewable Energy Deployment in 2009

    SciTech Connect (OSTI)

    Bolinger, Mark; Wiser, Ryan; Darghouth, Naim

    2010-03-31T23:59:59.000Z

    Federal support for renewable energy deployment in the United States has traditionally been delivered primarily through tax benefits, including the production tax credit ('PTC') in Section 45 of the U.S. tax code, investment tax credits ('ITC') in Sections 25D and 48, and accelerated tax depreciation in Section 168. Many renewable power project developers are unable to use the majority of these tax benefits directly or immediately, however, and have therefore often relied on third-party 'tax equity' investors for the necessary investment capital in order to monetize the available tax benefits. As has been well-publicized, most of these tax equity investors were hit hard by the global financial crisis that unfolded in the last months of 2008 and, as a result, most either withdrew from the renewable power market at that time or reduced their available investment capital. This left a significant financing gap beginning in late 2008, and placed at some risk the continued near-term growth of renewable energy supply in the U.S. In recognition of these developments, the U.S. Congress passed two stimulus bills - The Energy Improvement and Extension Act ('the Extension Act') in October 2008 and The American Recovery and Reinvestment Act ('the Recovery Act') in February 2009 - parts of which were intended to address the growing shortage of finance for renewable power projects. Most notably, Section 1603 of the Recovery Act enables qualifying commercial renewable energy projects to choose between the Section 45 PTC, the Section 48 ITC, or a cash grant of equal value to the Section 48 ITC (i.e., 30% of the project's eligible basis in most cases). By giving developers the option to receive a 30% cash grant (administered by the U.S. Department of the Treasury) in lieu of either the ITC or the PTC, Congress hoped to 'temporarily fill the gap created by the diminished investor demand for tax credits,' and thereby achieve 'the near term goal of creating and retaining jobs - as well as the long-term benefit of expanding the use of clean and renewable energy and decreasing our dependency on non-renewable energy sources' (U.S. Department of the Treasury 2009). More than a year has now passed since the Recovery Act became law. Although the Section 1603 program has been operational for only part of that time - roughly eight months - the program faces a looming milestone in just another nine months. Specifically, in order to qualify for the Section 1603 grant, eligible projects must have commenced construction by the end of 2010. With this deadline approaching, the Committee on Ways and Means of the U.S. House of Representatives requested that Lawrence Berkeley National Laboratory evaluate the effectiveness of the Section 1603 grant program to date (see Attachment 1), focusing on specific elements of the program that were subsequently agreed upon by Committee staff, the U.S. Department of Energy, and Berkeley Lab. This report responds to the Committee's request. The evaluation focuses primarily on the commercial wind power sector, for two reasons: (1) commercial wind power projects had received nearly 86% of all grant money awarded as of March 1, 2010; and (2) there is substantially more market-related information available for the commercial wind power sector than there is for other renewable power sectors, thereby facilitating analysis. Despite the focus on wind power, this initial analysis does endeavor to provide relevant information on other technologies, and in particular geothermal (the second-largest recipient of grant money), where possible.

  13. Economic Research Southern Africa (ERSA) is a research programme funded by the National Treasury of South Africa.

    E-Print Network [OSTI]

    Maranas, Costas

    of South Africa. The views expressed are those of the author(s) and do not necessarily represent those Europe, and the less likely it will be in Central and South Asia or Sub-Saharan Africa. Finally, weEconomic Research Southern Africa (ERSA) is a research programme funded by the National Treasury

  14. Section 1603 Treasury Grant Expiration: Industry Insight on Financing and Market Implications

    SciTech Connect (OSTI)

    Mendelsohn, M.; Harper, J.

    2012-06-01T23:59:59.000Z

    In the wake of the 2008-2009 financial crises, tax equity investors largely withdrew from the market, resulting in stagnation of project development. In response, Congress established the Treasury grant program pursuant to Section 1603 of the American Recovery and Reinvestment Act (..Section..1603 Program) to offer a cash payment in lieu of a production and investment tax credit. This study addresses the likely project financing and market impacts from the expiration of the ..Section..1603 Program. The authors assembled an array of insights offered by financial executives active in the renewable energy (RE) market during conference panel discussions and in presentations, direct interviews, and email correspondences. This analysis found that the ..Section..1603 Program alleviated the need to monetize the tax credit incentives through specialized investors, helped lower the transaction and financing costs associated with renewable electricity projects, and generally supported an extensive build-out of renewable power generation capacity. With the expiration of the ..Section..1603 Program, smaller or less-established renewable power developers will have more difficulty attracting needed financial capital and completing their projects, development of projects relying on newer or 'innovative' technologies will likely slow as traditional tax equity investors are known to be highly averse to technology risk in the projects they fund, and, finally, projects relying on tax equity may be more expensive to develop due to higher transaction costs and potentially higher yields required to attract tax equity.

  15. HUBBLE TARANTULA TREASURY PROJECT: UNRAVELING TARANTULA'S WEB. I. OBSERVATIONAL OVERVIEW AND FIRST RESULTS

    SciTech Connect (OSTI)

    Sabbi, E.; Anderson, J.; Van der Marel, R. P.; Aloisi, A.; De Mink, S. E.; Gordon, K.; Koekemoer, A. M.; Panagia, N. [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Lennon, D. J. [ESA-European Space Astronomy Center, Apdo. de Correo 78, E-28691 Villanueva de la Canada, Madrid (Spain); Boyer, M. L. [Observational Cosmology Lab, Code 665, NASA, Goddard Space Flight Center, Greenbelt, MD 20771 (United States); Cignoni, M. [Dipartimento di Astronomia, Universita degli Studi di Bologna, via Ranzani, I-40127 Bologna (Italy); De Marchi, G. [Space Science Department, European Space Agency, Keplerlaan 1, 2200-AG Noordwijk (Netherlands); Evans, C. J. [UK Astronomy Technology Center, Royal Observatory Edinburgh, Blackford Hill, Edinburgh EH9 3HJ (United Kingdom); Gallagher, J. S. III; Ryon, J. E. [Department of Astronomy, University of Wisconsin, 475 North Charter Street, Madison, WI 53706 (United States); Gouliermis, D. A. [Zentrum fuer Astronomie, Institut fuer Theoretische Astrophysik, Universitaet Heidelberg, Albert-Ueberle-Str. 2, D-69120 Heidelberg (Germany); Grebel, E. K. [Zentrum fuer Astronomie, Astronomisches Rechen-Institut, Universitaet Heidelberg, Moenchhofstr. 12-14, D-69120 Heidelberg (Germany); Larsen, S. S. [Department of Astrophysics/IMAPP, Radboud University Nijmegen, P.O. Box 9010, 6500-GL Nijmegen (Netherlands); Smith, L. J. [ESA/STScI, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Tosi, M., E-mail: sabbi@stsci.edu [Istituto Nazionale di Astrofisica, Osservatorio Astronomico di Bologna, Via Ranzani 1, I-40127 Bologna (Italy); and others

    2013-09-15T23:59:59.000Z

    The Hubble Tarantula Treasury Project (HTTP) is an ongoing panchromatic imaging survey of stellar populations in the Tarantula Nebula in the Large Magellanic Cloud that reaches into the sub-solar mass regime (<0.5 M{sub Sun }). HTTP utilizes the capability of the Hubble Space Telescope to operate the Advanced Camera for Surveys and the Wide Field Camera 3 in parallel to study this remarkable region in the near-ultraviolet, optical, and near-infrared spectral regions, including narrow-band H{alpha} images. The combination of all these bands provides a unique multi-band view. The resulting maps of the stellar content of the Tarantula Nebula within its main body provide the basis for investigations of star formation in an environment resembling the extreme conditions found in starburst galaxies and in the early universe. Access to detailed properties of individual stars allows us to begin to reconstruct the temporal and spatial evolution of the stellar skeleton of the Tarantula Nebula over space and time on a sub-parsec scale. In this first paper we describe the observing strategy, the photometric techniques, and the upcoming data products from this survey and present preliminary results obtained from the analysis of the initial set of near-infrared observations.

  16. Bond Financing Program (New Hampshire)

    Broader source: Energy.gov [DOE]

    BFA’s Bond Financing Program offers tax-exempt and taxable bonds for fixed-asset expansion projects. Industrial development revenue bonds can be used by manufacturers for the acquisition,...

  17. Low Temperature Material Bonding Technique

    DOE Patents [OSTI]

    Ramsey, J. Michael (Knoxville, TN); Foote, Robert S. (Oak Ridge, TN)

    2000-10-10T23:59:59.000Z

    A method of performing a lower temperature bonding technique to bond together two mating pieces of glass includes applying a sodium silicate aqueous solution between the two pieces.

  18. Low temperature material bonding technique

    DOE Patents [OSTI]

    Ramsey, J. Michael (Knoxville, TN); Foote, Robert S. (Oak Ridge, TN)

    2002-02-12T23:59:59.000Z

    A method of performing a lower temperature bonding technique to bond together two mating pieces of glass includes applying a sodium silicate aqueous solution between the two pieces.

  19. Bonding aerogels with polyurethanes

    SciTech Connect (OSTI)

    Matthews, F.M.; Hoffman, D.M.

    1989-11-01T23:59:59.000Z

    Aerogels, porous silica glasses with ultra-fine cell size (30nm), are made by a solution gelation (sol-gel) process. The resulting gel is critical point dried to densities from 0.15--0.60 g/cc. This material is machinable, homogeneous, transparent, coatable and bondable. To bond aerogel an adhesive should have long cure time, no attack on the aerogel structure, and high strength. Several epoxies and urethanes were examined to determine if they satisfied these conditions. Bond strengths above 13 psi were found with double bubble and DP-110 epoxies and XI-208/ODA-1000 and Castall U-2630 urethanes. Hardman Kalex Tough Stuff'' A-85 hardness urethane gave 18 psi bond strength. Hardman A-85, Tuff-Stuff'' was selected for further evaluation because it produced bond strengths comparable to the adherend cohesive strength. 5 refs., 2 figs.

  20. The New Chemical Bond

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    off when the first convincing experimental evidence of the phi bond showed up for the thorium sandwich complex, as revealed by its elaborate, never-before-seen symmetry. The...

  1. Characterization of anodic bonding

    E-Print Network [OSTI]

    Tudryn, Carissa Debra, 1978-

    2004-01-01T23:59:59.000Z

    Anodic bonding is a common process used in MicroElectroMechanical Systems (MEMS) device fabrication and packaging. Polycrystalline chemical vapor deposited (CVD) silicon carbide (SiC) is emerging as a new MEMS device and ...

  2. Empirical study on the Korean treasury auction focusing on the revenue comparison in multiple versus single price auction

    E-Print Network [OSTI]

    Kang, Boo-Sung

    2006-04-12T23:59:59.000Z

    EMPIRICAL STUDY ON THE KOREAN TREASURY AUCTION FOCUSING ON THE REVENUE COMPARISON IN MULTIPLE VERSUS SINGLE PRICE AUCTION A Dissertation by BOO-SUNG KANG Submitted to the Office of Graduate Studies of Texas A&M... IN MULTIPLE VERSUS SINGLE PRICE AUCTION A Dissertation by BOO-SUNG KANG Submitted to Texas A&M University in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY Approved as to style and content by...

  3. Water's Hydrogen Bond Strength

    E-Print Network [OSTI]

    Martin Chaplin

    2007-06-10T23:59:59.000Z

    Water is necessary both for the evolution of life and its continuance. It possesses particular properties that cannot be found in other materials and that are required for life-giving processes. These properties are brought about by the hydrogen bonded environment particularly evident in liquid water. Each liquid water molecule is involved in about four hydrogen bonds with strengths considerably less than covalent bonds but considerably greater than the natural thermal energy. These hydrogen bonds are roughly tetrahedrally arranged such that when strongly formed the local clustering expands, decreasing the density. Such low density structuring naturally occurs at low and supercooled temperatures and gives rise to many physical and chemical properties that evidence the particular uniqueness of liquid water. If aqueous hydrogen bonds were actually somewhat stronger then water would behave similar to a glass, whereas if they were weaker then water would be a gas and only exist as a liquid at sub-zero temperatures. The overall conclusion of this investigation is that water's hydrogen bond strength is poised centrally within a narrow window of its suitability for life.

  4. THE PANCHROMATIC HUBBLE ANDROMEDA TREASURY. I. BRIGHT UV STARS IN THE BULGE OF M31

    SciTech Connect (OSTI)

    Rosenfield, Philip; Johnson, L. Clifton; Dalcanton, Julianne J.; Williams, Benjamin F.; Gilbert, Karoline M. [Department of Astronomy, University of Washington, Box 351580, Seattle, WA 98195 (United States); Girardi, Leo [Osservatorio Astronomico di Padova-INAF, Vicolo dell'Osservatorio 5, I-35122 Padova (Italy); Bressan, Alessandro [SISSA, Via Bonomea 265, 34136 Trieste (Italy); Lang, Dustin [Department of Astrophysical Sciences, Princeton University, Princeton, NJ 08544 (United States); Guhathakurta, Puragra; Dorman, Claire E. [UCO/Lick Observatory and Department of Astronomy and Astrophysics, University of California, Santa Cruz, CA 95064 (United States); Howley, Kirsten M. [Lawrence Livermore National Laboratory, 7000 East Avenue, Livermore, CA 94550 (United States); Lauer, Tod R.; Olsen, Knut A. G. [National Optical Astronomy Observatory, 950 North Cherry Avenue, Tucson, AZ 85719 (United States); Bell, Eric F. [Department of Astronomy, University of Michigan, 500 Church St., Ann Arbor, MI 48109 (United States); Bianchi, Luciana [Department of Physics and Astronomy, Johns Hopkins University, Baltimore, MD 21218 (United States); Caldwell, Nelson [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street Cambridge, MA 02138 (United States); Dolphin, Andrew [Raytheon Company, 1151 East Hermans Road, Tucson, AZ 85756 (United States); Kalirai, Jason [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Larsen, Soren S. [Astronomical Institute, University of Utrecht, Princetonplein 5, 3584 CC Utrecht (Netherlands); Rix, Hans-Walter [Max Planck Institute for Astronomy, Koenigstuhl 17, D-69117 Heidelberg (Germany); and others

    2012-08-20T23:59:59.000Z

    As part of the Panchromatic Hubble Andromeda Treasury multi-cycle program, we observed a 12' Multiplication-Sign 6.'5 area of the bulge of M31 with the WFC3/UVIS filters F275W and F336W. From these data we have assembled a sample of {approx}4000 UV-bright, old stars, vastly larger than previously available. We use updated Padova stellar evolutionary tracks to classify these hot stars into three classes: Post-AGB stars (P-AGB), Post-Early AGB (PE-AGB) stars, and AGB-manque stars. P-AGB stars are the end result of the asymptotic giant branch (AGB) phase and are expected in a wide range of stellar populations, whereas PE-AGB and AGB-manque (together referred to as the hot post-horizontal branch; HP-HB) stars are the result of insufficient envelope masses to allow a full AGB phase, and are expected to be particularly prominent at high helium or {alpha} abundances when the mass loss on the red giant branch is high. Our data support previous claims that most UV-bright sources in the bulge are likely hot (extreme) horizontal branch (EHB) stars and their progeny. We construct the first radial profiles of these stellar populations and show that they are highly centrally concentrated, even more so than the integrated UV or optical light. However, we find that this UV-bright population does not dominate the total UV luminosity at any radius, as we are detecting only the progeny of the EHB stars that are the likely source of the UV excess. We calculate that only a few percent of main-sequence stars in the central bulge can have gone through the HP-HB phase and that this percentage decreases strongly with distance from the center. We also find that the surface density of hot UV-bright stars has the same radial variation as that of low-mass X-ray binaries. We discuss age, metallicity, and abundance variations as possible explanations for the observed radial variation in the UV-bright population.

  5. Preliminary Analysis of the Jobs and Economic Impacts of Renewable Energy Projects Supported by the ..Section..1603 Treasury Grant Program

    SciTech Connect (OSTI)

    Steinberg, D.; Porro, G.; Goldberg, M.

    2012-04-01T23:59:59.000Z

    This analysis responds to a request from the Department of Energy Office of Energy Efficiency and Renewable Energy to the National Renewable Energy Laboratory (NREL) to estimate the direct and indirect jobs and economic impacts of projects supported by the Section 1603 Treasury grant program. The analysis employs the Jobs and Economic Development Impacts (JEDI) models to estimate the gross jobs, earnings, and economic output supported by the construction and operation of the large wind (greater than 1 MW) and solar photovoltaic (PV) projects funded by the Section 1603 grant program.

  6. Economic Development Bond Program (Iowa)

    Broader source: Energy.gov [DOE]

    Through its Economic Development Bond Program, the Iowa Finance Authority (IFA) issues tax-exempt bonds on behalf of private entities or organizations for eligible purposes. The responsibility for...

  7. Private Activity Bond Allocation (Missouri)

    Broader source: Energy.gov [DOE]

    The Private Activity Bond Allocation Program provides low-interest financing through tax-exempt bonds for certain types of projects, including electric and gas utility projects. Eligible applicants...

  8. Pauling bond strength, bond length and electron density distribution

    SciTech Connect (OSTI)

    Gibbs, Gerald V.; Ross, Nancy L.; Cox, David F.; Rosso, Kevin M.; Iversen, Bo B.; Spackman, M. A.

    2014-01-18T23:59:59.000Z

    A power law regression equation, = 1.46(/r)-0.19, connecting the average experimental bond lengths, , with the average accumulation of the electron density at the bond critical point, , between bonded metal M and oxygen atoms, determined at ambient conditions for oxide crystals, where r is the row number of the M atom, is similar to the regression equation R(M-O) = 1.39(?(rc)/r)-0.21 determined for three perovskite crystals for pressures as high as 80 GPa. The two equations are also comparable with those, = 1.43(/r)-0.21, determined for a large number of oxide crystals at ambient conditions and = 1.39(/r)-0.22, determined for geometry optimized hydroxyacid molecules, that connect the bond lengths to the average Pauling electrostatic bond strength, , for the M-O bonded interactions. On the basis of the correspondence between the two sets of equations connecting ?(rc) and the Pauling bond strength s with bond length, it appears that Pauling’s simple definition of bond strength closely mimics the accumulation of the electron density between bonded pairs of atoms. The similarity of the expressions for the crystals and molecules is compelling evidence that the M-O bonded interactions for the crystals and molecules 2 containing the same bonded interactions are comparable. Similar expressions, connecting bond lengths and bond strength, have also been found to hold for fluoride, nitride and sulfide molecules and crystals. The Brown-Shannon bond valence, ?, power law expression ? = [R1/(R(M-O)]N that has found wide use in crystal chemistry, is shown to be connected to a more universal expression determined for oxides and the perovskites, = r[(1.41)/]4.76, demonstrating that the bond valence for a bonded interaction is likewise closely connected to the accumulation of the electron density between the bonded atoms. Unlike the Brown-Shannon expression, it is universal in that it holds for the M-O bonded interactions for a relatively wide range of M atoms of the periodic table. The power law equation determined for the oxide crystals at ambient conditions is similar to the power law expression = r[1.46/]5.26 determined for the perovskites at pressures as high as 80 GPa, indicating that the intrinsic connection between R(M-O) and ?(rc) that holds at ambient conditions also holds, to a first approximation, at high pressures.

  9. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengthening a solidSynthesisAppliancesTrending: Metal Oxo Bonds Print Metal

  10. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengthening a solidSynthesisAppliancesTrending: Metal Oxo Bonds Print

  11. Solder extrusion pressure bonding process and bonded products produced thereby

    DOE Patents [OSTI]

    Beavis, Leonard C. (Albuquerque, NM); Karnowsky, Maurice M. (Albuquerque, NM); Yost, Frederick G. (Ceder Crest, NM)

    1992-01-01T23:59:59.000Z

    Production of soldered joints which are highly reliable and capable of surviving 10,000 thermal cycles between about -40.degree. C. and 110.degree. C. Process involves interposing a thin layer of a metal solder composition between the metal surfaces of members to be bonded and applying heat and up to about 1000 psi compression pressure to the superposed members, in the presence of a reducing atmosphere, to extrude the major amount of the solder composition, contaminants including fluxing gases and air, from between the members being bonded, to form a very thin, strong intermetallic bonding layer having a thermal expansion tolerant with that of the bonded members.

  12. Solder extrusion pressure bonding process and bonded products produced thereby

    DOE Patents [OSTI]

    Beavis, L.C.; Karnowsky, M.M.; Yost, F.G.

    1992-06-16T23:59:59.000Z

    Disclosed is a process for production of soldered joints which are highly reliable and capable of surviving 10,000 thermal cycles between about [minus]40 C and 110 C. Process involves interposing a thin layer of a metal solder composition between the metal surfaces of members to be bonded and applying heat and up to about 1000 psi compression pressure to the superposed members, in the presence of a reducing atmosphere, to extrude the major amount of the solder composition, contaminants including fluxing gases and air, from between the members being bonded, to form a very thin, strong intermetallic bonding layer having a thermal expansion tolerant with that of the bonded members.

  13. Investigation of bonding strength and sealing behavior of aluminum/stainless steel bonded at room temperature

    E-Print Network [OSTI]

    Howlader, Matiar R

    ], spark welding [3], explosive bonding [4], and diffusion bonding [5,6]. However, the processing such as diffusion bonding [5,6], friction welding [7e11], vacuum roll bonding [12] and hot roll bonding [13Investigation of bonding strength and sealing behavior of aluminum/stainless steel bonded at room

  14. Qualified Energy Conservation Bonds (Ohio)

    Broader source: Energy.gov [DOE]

    The Ohio Air Quality Development Authority (OAQDA) administers the Qualified Energy Conservation Bonds (QECB) program in Ohio. QECBs have been used by local governments and public universities to...

  15. Energy Secretary and Secretary of the Treasury Announce the Award of $1

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011AT&T,OfficeEnd of Year 2010 SNFEnergy PolicyEnvironmental-- As Prepared

  16. Quantum Confinement in Hydrogen Bond

    E-Print Network [OSTI]

    Santos, Carlos da Silva dos; Ricotta, Regina Maria

    2015-01-01T23:59:59.000Z

    In this work, the quantum confinement effect is proposed as the cause of the displacement of the vibrational spectrum of molecular groups that involve hydrogen bonds. In this approach the hydrogen bond imposes a space barrier to hydrogen and constrains its oscillatory motion. We studied the vibrational transitions through the Morse potential, for the NH and OH molecular groups inside macromolecules in situation of confinement (when hydrogen bonding is formed) and non-confinement (when there is no hydrogen bonding). The energies were obtained through the variational method with the trial wave functions obtained from Supersymmetric Quantum Mechanics (SQM) formalism. The results indicate that it is possible to distinguish the emission peaks related to the existence of the hydrogen bonds. These analytical results were satisfactorily compared with experimental results obtained from infrared spectroscopy.

  17. Method for vacuum fusion bonding

    DOE Patents [OSTI]

    Ackler, Harold D. (Sunnyvale, CA); Swierkowski, Stefan P. (Livermore, CA); Tarte, Lisa A. (Livermore, CA); Hicks, Randall K. (Stockton, CA)

    2001-01-01T23:59:59.000Z

    An improved vacuum fusion bonding structure and process for aligned bonding of large area glass plates, patterned with microchannels and access holes and slots, for elevated glass fusion temperatures. Vacuum pumpout of all components is through the bottom platform which yields an untouched, defect free top surface which greatly improves optical access through this smooth surface. Also, a completely non-adherent interlayer, such as graphite, with alignment and location features is located between the main steel platform and the glass plate pair, which makes large improvements in quality, yield, and ease of use, and enables aligned bonding of very large glass structures.

  18. Fusion bonding and alignment fixture

    DOE Patents [OSTI]

    Ackler, Harold D. (Sunnyvale, CA); Swierkowski, Stefan P. (Livermore, CA); Tarte, Lisa A. (Livermore, CA); Hicks, Randall K. (Stockton, CA)

    2000-01-01T23:59:59.000Z

    An improved vacuum fusion bonding structure and process for aligned bonding of large area glass plates, patterned with microchannels and access holes and slots, for elevated glass fusion temperatures. Vacuum pumpout of all the components is through the bottom platform which yields an untouched, defect free top surface which greatly improves optical access through this smooth surface. Also, a completely non-adherent interlayer, such as graphite, with alignment and location features is located between the main steel platform and the glass plate pair, which makes large improvements in quality, yield, and ease of use, and enables aligned bonding of very large glass structures.

  19. The Panchromatic Hubble Andromeda Treasury XI: The Spatially-Resolved Recent Star Formation History of M31

    E-Print Network [OSTI]

    Lewis, Alexia R; Dalcanton, Julianne J; Weisz, Daniel R; Williams, Benjamin F; Bell, Eric F; Seth, Anil C; Simones, Jacob E; Skillman, Evan D; Choi, Yumi; Fouesneau, Morgan; Guhathakurta, Puragra; Johnson, Lent C; Kalirai, Jason S; Leroy, Adam K; Monachesi, Antonela; Rix, Hans-Walter; Schruba, Andreas

    2015-01-01T23:59:59.000Z

    We measure the recent star formation history (SFH) across M31 using optical images taken with the \\texit{Hubble Space Telescope} as part of the Panchromatic Hubble Andromeda Treasury (PHAT). We fit the color-magnitude diagrams in ~9000 regions that are ~100 pc $\\times$ 100 pc in projected size, covering a 0.5 square degree area (~380 kpc$^2$, deprojected) in the NE quadrant of M31. We show that the SFHs vary significantly on these small spatial scales but that there are also coherent galaxy-wide fluctuations in the SFH back to ~500 Myr, most notably in M31's 10-kpc star-forming ring. We find that the 10-kpc ring is at least 400 Myr old, showing ongoing star formation over the past ~500 Myr. This indicates the presence of molecular gas in the ring over at least 2 dynamical times at this radius. We also find that the ring's position is constant throughout this time, and is stationary at the level of 1 km/s, although there is evidence for broadening of the ring due to diffusion of stars into the disk. Based on e...

  20. Method of bonding

    DOE Patents [OSTI]

    Saller, deceased, Henry A. (late of Columbus, OH); Hodge, Edwin S. (Columbus, OH); Paprocki, Stanley J. (Columbus, OH); Dayton, Russell W. (Columbus, OH)

    1987-12-01T23:59:59.000Z

    1. A method of making a fuel-containing structure for nuclear reactors, comprising providing an assembly comprising a plurality of fuel units; each fuel unit consisting of a core plate containing thermal-neutron-fissionable material, sheets of cladding metal on its bottom and top surfaces, said cladding sheets being of greater width and length than said core plates whereby recesses are formed at the ends and sides of said core plate, and end pieces and first side pieces of cladding metal of the same thickness as the core plate positioned in said recesses, the assembly further comprising a plurality of second side pieces of cladding metal engaging the cladding sheets so as to space the fuel units from one another, and a plurality of filler plates of an acid-dissolvable nonresilient material whose melting point is above 2000.degree. F., each filler plate being arranged between a pair of said second side pieces and the cladding plates of two adjacent fuel units, the filler plates having the same thickness as the second side pieces; the method further comprising enclosing the entire assembly in an envelope; evacuating the interior of the entire assembly through said envelope; applying inert gas under a pressure of about 10,000 psi to the outside of said envelope while at the same time heating the assembly to a temperature above the flow point of the cladding metal but below the melting point of any material of the assembly, whereby the envelope is pressed against the assembly and integral bonds are formed between plates, sheets, first side pieces, and end pieces and between the sheets and the second side pieces; slowly cooling the assembly to room temperature; removing the envelope; and dissolving the filler plates without attacking the cladding metal.

  1. Low Temperature Material Bonding Techniq Ue

    DOE Patents [OSTI]

    Ramsey, J. Michael (Knoxville, TN); Foote, Robert S. (Oak Ridge, TN)

    2002-08-06T23:59:59.000Z

    A method of performing a lower temperature bonding technique to bond together two mating pieces of glass includes applying a sodium silicate aqueous solution between the two pieces.

  2. Local Option- Industrial Facilities and Development Bonds

    Broader source: Energy.gov [DOE]

    Under the Utah Industrial Facilities and Development Act, counties, municipalities, and state universities in Utah may issue Industrial Revenue Bonds (IRBs) or Industrial Development Bonds (IDBs)...

  3. Pooled Bond Program (South Dakota)

    Broader source: Energy.gov [DOE]

    The Pooled Bond Program offered by the Economic Development Finance Authority is designed for capital intensive projects, providing small businesses access to larger capital markets for tax-exempt...

  4. Qualified Energy Conservation Bonds (QECBs)

    Broader source: Energy.gov [DOE]

    The ''Energy Improvement and Extension Act of 2008'', enacted in October 2008, authorized the issuance of Qualified Energy Conservation Bonds (QECBs) that may be used by state, local and tribal...

  5. THE ACS NEARBY GALAXY SURVEY TREASURY. IX. CONSTRAINING ASYMPTOTIC GIANT BRANCH EVOLUTION WITH OLD METAL-POOR GALAXIES

    SciTech Connect (OSTI)

    Girardi, Leo [Osservatorio Astronomico di Padova-INAF, Vicolo dell'Osservatorio 5, I-35122 Padova (Italy); Williams, Benjamin F.; Gilbert, Karoline M.; Rosenfield, Philip; Dalcanton, Julianne J. [Department of Astronomy, University of Washington, Box 351580, Seattle, WA 98195 (United States); Marigo, Paola [Dipartimento di Astronomia, Universita di Padova, Vicolo dell'Osservatorio 2, I-35122 Padova (Italy); Boyer, Martha L. [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Dolphin, Andrew [Raytheon Company, 1151 East Hermans Road, Tucson, AZ 85756 (United States); Weisz, Daniel R.; Skillman, Evan [Department of Astronomy, University of Minnesota, 116 Church Street SE, Minneapolis, MN 55455 (United States); Melbourne, Jason [Caltech Optical Observatories, Division of Physics, Mathematics and Astronomy, Mail Stop 301-17, California Institute of Technology, Pasadena, CA 91125 (United States); Olsen, Knut A. G. [National Optical Astronomy Observatory, 950 North Cherry Avenue, Tucson, AZ 85719 (United States); Seth, Anil C. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States)

    2010-12-01T23:59:59.000Z

    In an attempt to constrain evolutionary models of the asymptotic giant branch (AGB) phase at the limit of low masses and low metallicities, we have examined the luminosity functions and number ratios between AGB and red giant branch (RGB) stars from a sample of resolved galaxies from the ACS Nearby Galaxy Survey Treasury. This database provides Hubble Space Telescope optical photometry together with maps of completeness, photometric errors, and star formation histories for dozens of galaxies within 4 Mpc. We select 12 galaxies characterized by predominantly metal-poor populations as indicated by a very steep and blue RGB, and which do not present any indication of recent star formation in their color-magnitude diagrams. Thousands of AGB stars brighter than the tip of the RGB (TRGB) are present in the sample (between 60 and 400 per galaxy), hence, the Poisson noise has little impact in our measurements of the AGB/RGB ratio. We model the photometric data with a few sets of thermally pulsing AGB (TP-AGB) evolutionary models with different prescriptions for the mass loss. This technique allows us to set stringent constraints on the TP-AGB models of low-mass, metal-poor stars (with M < 1.5 M{sub sun}, [Fe/H]{approx}< -1.0). Indeed, those which satisfactorily reproduce the observed AGB/RGB ratios have TP-AGB lifetimes between 1.2 and 1.8 Myr, and finish their nuclear burning lives with masses between 0.51 and 0.55 M{sub sun}. This is also in good agreement with recent observations of white dwarf masses in the M4 old globular cluster. These constraints can be added to those already derived from Magellanic Cloud star clusters as important mileposts in the arduous process of calibrating AGB evolutionary models.

  6. THE ADVANCED CAMERA FOR SURVEYS NEARBY GALAXY SURVEY TREASURY. V. RADIAL STAR FORMATION HISTORY OF NGC 300

    SciTech Connect (OSTI)

    Gogarten, Stephanie M.; Dalcanton, Julianne J.; Williams, Benjamin F.; Roskar, Rok; Gilbert, Karoline M.; Quinn, Thomas R. [Department of Astronomy, University of Washington, Box 351580, Seattle, WA 98195 (United States); Holtzman, Jon [Department of Astronomy, New Mexico State University, Box 30001, 1320 Frenger Street, Las Cruces, NM 88003 (United States); Seth, Anil C. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Dolphin, Andrew [Raytheon Company, 1151 East Hermans Road, Tucson, AZ 85756 (United States); Weisz, Daniel; Skillman, Evan [Department of Astronomy, University of Minnesota, 116 Church Street SE, Minneapolis, MN 55455 (United States); Cole, Andrew [School of Mathematics and Physics, University of Tasmania, Hobart, Tasmania (Australia); Debattista, Victor P. [Jeremiah Horrocks Institute, University of Central Lancashire, Preston PR1 2HE (United Kingdom); Olsen, Knut [National Optical Astronomy Observatory, 950 North Cherry Avenue, Tucson, AZ 85719 (United States); De Jong, Roelof S. [Astrophysikalisches Institut Potsdam (AIP), An der Sternwarte 16, 14482 Potsdam (Germany); Karachentsev, Igor D., E-mail: stephanie@astro.washington.ed [Special Astrophysical Observatory, Nizhnij Arkhyz, KChR (Russian Federation)

    2010-04-01T23:59:59.000Z

    We present new Hubble Space Telescope (HST) observations of NGC 300 taken as part of the Advanced Camera for Surveys Nearby Galaxy Survey Treasury (ANGST). Individual stars are resolved in these images down to an absolute magnitude of M{sub F814W} = 1.0 (below the red clump). We determine the star formation history of the galaxy in six radial bins by comparing our observed color-magnitude diagrams (CMDs) with synthetic CMDs based on theoretical isochrones. We find that the stellar disk out to 5.4 kpc is primarily old, in contrast with the outwardly similar galaxy M33. We determine the scale length as a function of age and find evidence for inside-out growth of the stellar disk: the scale length has increased from 1.1 +- 0.1 kpc 10 Gyr ago to 1.3 +- 0.1 kpc at present, indicating a buildup in the fraction of young stars at larger radii. As the scale length of M33 has recently been shown to have increased much more dramatically with time, our results demonstrate that two galaxies with similar sizes and morphologies can have very different histories. With an N-body simulation of a galaxy designed to be similar to NGC 300, we determine that the effects of radial migration should be minimal. We trace the metallicity gradient as a function of time and find a present-day metallicity gradient consistent with that seen in previous studies. Consistent results are obtained from archival images covering the same radial extent but differing in placement and filter combination.

  7. THE ADVANCED CAMERA FOR SURVEYS NEARBY GALAXY SURVEY TREASURY. IV. THE STAR FORMATION HISTORY OF NGC 2976

    SciTech Connect (OSTI)

    Williams, Benjamin F.; Dalcanton, Julianne J.; Stilp, Adrienne; Gilbert, Karoline M.; Roskar, Rok; Gogarten, Stephanie M. [Department of Astronomy, Box 351580, University of Washington, Seattle, WA 98195 (United States); Seth, Anil C. [CfA Fellow, Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Weisz, Daniel; Skillman, Evan [Department of Astronomy, University of Minnesota, 116 Church St. SE, Minneapolis, MN 55455 (United States); Dolphin, Andrew [Raytheon, 1151 E. Hermans Road, Tucson, AZ 85706 (United States); Holtzman, Jon, E-mail: ben@astro.washington.ed, E-mail: jd@astro.washington.ed, E-mail: roskar@astro.washington.ed, E-mail: stephanie@astro.washington.ed, E-mail: aseth@cfa.harvard.ed, E-mail: dweisz@astro.umn.ed, E-mail: skillman@astro.umn.ed, E-mail: dolphin@raytheon.co, E-mail: holtz@nmsu.ed [Department of Astronomy, New Mexico State University, Box 30001, 1320 Frenger St., Las Cruces, NM 88003 (United States)

    2010-01-20T23:59:59.000Z

    We present resolved stellar photometry of NGC 2976 obtained with the Advanced Camera for Surveys (ACS) as part of the ACS Nearby Galaxy Survey Treasury (ANGST) program. The data cover the radial extent of the major axis of the disk out to 6 kpc, or approx6 scale lengths. The outer disk was imaged to a depth of M{sub F606W} approx 1, and an inner field was imaged to the crowding limit at a depth of M{sub F606W} approx -1. Through detailed analysis and modeling of the resulting color-magnitude diagrams, we have reconstructed the star formation history (SFH) of the stellar populations currently residing in these portions of the galaxy, finding similar ancient populations at all radii but significantly different young populations at increasing radii. In particular, outside of the well-measured break in the disk surface brightness profile, the age of the youngest population increases with distance from the galaxy center, suggesting that star formation is shutting down from the outside-in. We use our measured SFH, along with H I surface density measurements, to reconstruct the surface density profile of the disk during previous epochs. Comparisons between the recovered star formation rates and reconstructed gas densities at previous epochs are consistent with star formation following the Schmidt law during the past 0.5 Gyr, but with a drop in star formation efficiency at low gas densities, as seen in local galaxies at the present day. The current rate and gas density suggest that rapid star formation in NGC 2976 is currently in the process of ceasing from the outside-in due to gas depletion. This process of outer disk gas depletion and inner disk star formation was likely triggered by an interaction with the core of the M81 group approx>1 Gyr ago that stripped the gas from the galaxy halo and/or triggered gas inflow from the outer disk toward the galaxy center.

  8. CONVERTIBLE BONDS IN A DEFAULTABLE DIFFUSION MODEL

    E-Print Network [OSTI]

    Jeanblanc, Monique

    CONVERTIBLE BONDS IN A DEFAULTABLE DIFFUSION MODEL Tomasz R. Bielecki Department of Applied Research Grant PS12918. #12;2 Convertible Bonds in a Defaultable Diffusion Model 1 Introduction In [4), such as Convertible Bonds (CB), and we provided a rigorous decomposition of a CB into a bond component and a (game

  9. Transient liquid phase ceramic bonding

    DOE Patents [OSTI]

    Glaeser, Andreas M. (Berkeley, CA)

    1994-01-01T23:59:59.000Z

    Ceramics are joined to themselves or to metals using a transient liquid phase method employing three layers, one of which is a refractory metal, ceramic or alloy. The refractory layer is placed between two metal layers, each of which has a lower melting point than the refractory layer. The three layers are pressed between the two articles to be bonded to form an assembly. The assembly is heated to a bonding temperature at which the refractory layer remains solid, but the two metal layers melt to form a liquid. The refractory layer reacts with the surrounding liquid and a single solid bonding layer is eventually formed. The layers may be designed to react completely with each other and form refractory intermetallic bonding layers. Impurities incorporated into the refractory metal may react with the metal layers to form refractory compounds. Another method for joining ceramic articles employs a ceramic interlayer sandwiched between two metal layers. In alternative embodiments, the metal layers may include sublayers. A method is also provided for joining two ceramic articles using a single interlayer. An alternate bonding method provides a refractory-metal oxide interlayer placed adjacent to a strong oxide former. Aluminum or aluminum alloys are joined together using metal interlayers.

  10. Bond Programs | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:EzfeedflagBiomass ConversionsSouthby 2022 |BleckleyMotionBocaBond County, Illinois:Bond

  11. Opening Pandora's Box - Sovereign Bonds in International Arbitration

    E-Print Network [OSTI]

    Waibel, Michael

    OPENING PANDORA’S BOX: SOVEREIGN BONDS IN INTERNATIONAL ARBITRATION By Michael Waibel* In recent years, sovereign debt crises have received much attention from the perspective of international public policy, but an effective legal solution... . In 1995, Mexico was unable to meet its external debt obligations. Three years later, a severe financial crisis hit East Asia. Russia defaulted in 1998. Argentina’s 2001 default on more than U.S.$100 billion in private debt was the largest in history.7...

  12. Bonded polyimide fuel cell package

    DOE Patents [OSTI]

    Morse, Jeffrey D.; Jankowski, Alan; Graff, Robert T.; Bettencourt, Kerry

    2010-06-08T23:59:59.000Z

    Described herein are processes for fabricating microfluidic fuel cell systems with embedded components in which micron-scale features are formed by bonding layers of DuPont Kapton.TM. polyimide laminate. A microfluidic fuel cell system fabricated using this process is also described.

  13. Non-bonded ultrasonic transducer

    DOE Patents [OSTI]

    Eoff, J.M.

    1984-07-06T23:59:59.000Z

    A mechanically assembled non-bonded ultrasonic transducer includes a substrate, a piezoelectric film, a wetting agent, a thin metal electrode, and a lens held in intimate contact by a mechanical clamp. No epoxy or glue is used in the assembly of this device.

  14. Major Business Expansion Bond Program (Maine)

    Broader source: Energy.gov [DOE]

    The Major Business Expansion Bond Program provides long-term, credit-enhanced financing up to $25,000,000 at taxable bond rates for businesses creating or retaining at least 50 jobs; up to $10,000...

  15. Industrial Revenue Bond Issuance Cost Assistance (Wisconsin)

    Broader source: Energy.gov [DOE]

    Industrial Revenue Bonds (IRB) are tax-exempt bonds that can be used to stimulate capital investment and job creation by providing private borrowers with access to financing at interest rates that...

  16. Secondary Market Taxable Bond Program (Maine)

    Broader source: Energy.gov [DOE]

    The Secondary Market Taxable Bond Program provides tax-exempt interest rate bond financing for real estate and machinery and equipment acquisitions. Up to 90% of the project debt may be financed,...

  17. The Market for Borrowing Corporate Bonds

    E-Print Network [OSTI]

    Asquith, Paul

    This paper describes the market for borrowing corporate bonds using a comprehensive data set from a major lender. The cost of borrowing corporate bonds is comparable to the cost of borrowing stock, between 10 and 20 basis ...

  18. Results from FAA program to validate bonded composite doublers for commercial aviation use

    SciTech Connect (OSTI)

    Roach, D.P.

    1997-09-01T23:59:59.000Z

    The number of commercial airframes exceeding twenty years of service continues to grow. In addition, Service Life Extension Programs are attempting to extend the {open_quotes}economic{close_quotes} service life of commercial airframes to thirty years. The use of bonded composites may offer the airframe manufacturers and aircraft maintenance facilities a cost effective method to extend the lives of their aircraft. The Federal Aviation Administration Assurance NDI Validation Center (AANC) to validate the use of bonded composite doublers on commercial aircraft.

  19. Bonded, walk-off compensated optical elements

    DOE Patents [OSTI]

    Ebbers, Christopher A. (Livermore, CA)

    2003-04-08T23:59:59.000Z

    A bonded, walk-off compensated crystal, for use with optical equipment, and methods of making optical components including same.

  20. Clean Energy and Bond Finance Initiative

    Broader source: Energy.gov [DOE]

    Provides information on Clean Energy and Bond Finance Initiative (CE+BFI). CE+BFI brings together public infrastructure finance agencies, clean energy public fund managers and institutional investors across the country to explore how to raise capital at scale for clean energy development through bond financing. Author: Clean Energy and Bond Finance Initiative

  1. Monetary Policy, Capital Inflows, and the Housing Boom

    E-Print Network [OSTI]

    Sá, Filipa; Wieladek, Tomasz

    2011-02-28T23:59:59.000Z

    government bonds over the course of a year, long rates would be almost 100 basis points higher. Focusing on the spread between the yields on long maturity corporate bonds and Treasury bonds, Krishnamurthy and Vissing-Jorgensen (2007) ?nd that, if governmental... holders (foreign central banks, US Federal Reserve banks, state and local governments) were to sell their holdings of US Treasuries and exit the market, the yield on US Treasuries would rise by the same amount as the yield on corporate bonds. Caballero...

  2. Bonding, antibonding and tunable optical forces in asymmetric membranes

    E-Print Network [OSTI]

    Hui, Pui-Chuen

    We demonstrate that tunable attractive (bonding) and repulsive (anti-bonding) forces can arise in highly asymmetric structures coupled to external radiation, a consequence of the bonding/anti-bonding level repulsion of ...

  3. Bond Program | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:EzfeedflagBiomass ConversionsSouthby 2022 |BleckleyMotionBocaBond County, Illinois:

  4. Revealing the Hidden Value that the Federal Investment Tax Credit and Treasury Cash Grant Provide To Community Wind Projects

    E-Print Network [OSTI]

    Bolinger, Mark A.

    2011-01-01T23:59:59.000Z

    in terms of 20-year levelized LCOE) for both the StrategicITC Loss Loss Results: Strategic Flip LCOE Delta ($/MWh) ($/Results: Cooperative LLC LCOE Delta ($/MWh) ($/MWh) Total

  5. Qualified Energy Conservation Bonds | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    description of qualified energy conservation bonds, including process and mechanics, case studies, utilization trends, barriers, and regulatory and legal issues. Author:...

  6. Tax-Exempt Bond Financing (Delaware)

    Broader source: Energy.gov [DOE]

    The Delaware Economic Development Authority provides tax-exempt bond financing for financial assistance to new or expanding businesses, governmental units and certain organizations that are exempt...

  7. Hydrogen Adsorption Induces Interlayer Carbon Bond Formation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Adsorption Induces Interlayer Carbon Bond Formation in Supported Few-Layer Graphene Friday, February 28, 2014 Among the allotropes of carbon, diamond has some of the most...

  8. Tax-Exempt Industrial Revenue Bonds (Kansas)

    Broader source: Energy.gov [DOE]

    Tax-Exempt Industrial Revenue Bonds are issued by cities and counties for the purchase, construction, improvement or remodeling of a facility for agricultural, commercial, hospital, industrial,...

  9. Nuclear reactor multiphysics via bond graph formalism

    E-Print Network [OSTI]

    Sosnovsky, Eugeny

    2014-01-01T23:59:59.000Z

    This work proposes a simple and effective approach to modeling nuclear reactor multiphysics problems using bond graphs. Conventional multiphysics simulation paradigms normally use operator splitting, which treats the ...

  10. How Hydrogen Bond Redundancy Affects Protein Flexibility

    E-Print Network [OSTI]

    Naomi Fox; Filip Jagodzinski; Jeanne Hardy; Ileana Streinu

    Modeling a Protein as a BodyBarHinge and Associated Graph Main Question: Stability in proteins is the resistance to denaturation, or unfolding. A protein that is highly stable has a high tolerance to bonds breaking before unfolding; an unstable protein has less tolerance. In this study, we focus on the question, how many hydrogen bonds

  11. Dragon Year

    E-Print Network [OSTI]

    Hacker, Randi

    2012-01-11T23:59:59.000Z

    Broadcast Transcript: Can you believe it? It's New Year again. It seems like only yesterday we were celebrating the advent of the year of the Rabbit and now, here it is, the year of the Dragon. January 22nd is New Year's ...

  12. Modeling Low-Barrier Hydrogen Bonds and Solution Effects

    E-Print Network [OSTI]

    Theel, Kelly

    2013-01-01T23:59:59.000Z

    Modeling low-barrier hydrogen bonds . . . . . 1.3 ModelingTypical hydrogen-bond 1-D potential energy surface . LBHB 1-representation of a Low Barrier Hydrogen Bond . . . . . . .

  13. sp2 Carbon-Hydrogen Bond (C-H) Functionalization

    E-Print Network [OSTI]

    Yotphan, Sirilata

    2010-01-01T23:59:59.000Z

    C-C) bonds from carbon-hydrogen (C-H) bonds in organicof them is unusually short. Hydrogen atoms were included insp 2 Carbon-Hydrogen Bond (C-H) Functionalization By

  14. Low Barrier Hydrogen Bonds in Acyclic Tertiary Diamines

    E-Print Network [OSTI]

    Khodagholian, Sevana

    2010-01-01T23:59:59.000Z

    In Search of a Low Barrier Hydrogen Bond in Proton Bridgedand J.A. Gerlt, “The Low Barrier Hydrogen Bond in EnzymaticShow That Low-Barrier Hydrogen Bonds do not Offer a

  15. Process Of Bonding Copper And Tungsten

    DOE Patents [OSTI]

    Slattery, Kevin T. (St. Charles, MO); Driemeyer, Daniel E. (Manchester, MO); Davis, John W. (Ballwin, MO)

    2000-07-18T23:59:59.000Z

    Process for bonding a copper substrate to a tungsten substrate by providing a thin metallic adhesion promoting film bonded to a tungsten substrate and a functionally graded material (FGM) interlayer bonding the thin metallic adhesion promoting film to the copper substrate. The FGM interlayer is formed by sintering a stack of individual copper and tungsten powder blend layers having progressively higher copper content/tungsten content, by volume, ratio values in successive powder blend layers in a lineal direction extending from the tungsten substrate towards the copper substrate. The resulting copper to tungsten joint well accommodates the difference in the coefficient of thermal expansion of the materials.

  16. Qualified Energy Conservation Bonds (QECBs) & New Clean Renewable...

    Broader source: Energy.gov (indexed) [DOE]

    presentation overview of qualified energy conservation bond and new clean renewable energy bonds, including characteristics, mechanics, allocated volume, and other information....

  17. Hydrogen-bond acidic functionalized carbon nanotubes (CNTs) with...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen-bond acidic functionalized carbon nanotubes (CNTs) with covalently-bound hexafluoroisopropanol groups. Hydrogen-bond acidic functionalized carbon nanotubes (CNTs) with...

  18. Three Hydrogen Bond Donor Catalysts: Oxyanion Hole Mimics and...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Bond Donor Catalysts: Oxyanion Hole Mimics and Transition State Analogues. Three Hydrogen Bond Donor Catalysts: Oxyanion Hole Mimics and Transition State Analogues....

  19. A Preorganized Hydrogen Bond Network and Its Effect on Anion...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Preorganized Hydrogen Bond Network and Its Effect on Anion Stability. A Preorganized Hydrogen Bond Network and Its Effect on Anion Stability. Abstract: Rigid tricyclic locked in...

  20. Hydrogen-Bond Acidic Polymers for Chemical Vapor Sensing. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acidic Polymers for Chemical Vapor Sensing. Hydrogen-Bond Acidic Polymers for Chemical Vapor Sensing. Abstract: A review with 171 references. Hydrogen-bond acidic polymers for...

  1. Local Option- Industrial Facilities and Development Bonds (Utah)

    Broader source: Energy.gov [DOE]

    Under the Utah Industrial Facilities and Development Act, counties, municipalities, and state universities in Utah may issue Industrial Revenue Bonds (IRBs) or Industrial Development Bonds (IDBs)...

  2. Qualified Energy Conservation Bonds (ŤQECBs?) & New Clean Renewable...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Qualified Energy Conservation Bonds ("QECBs") & New Clean Renewable Energy Bonds ("New CREBs") Slide 1 DISCLAIMER: The information in this presentation is for informational...

  3. Investigations into the Nature of Halogen Bonding Including Symmetry...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    into the Nature of Halogen Bonding Including Symmetry Adapted Perturbation Theory Analyses. Investigations into the Nature of Halogen Bonding Including Symmetry Adapted...

  4. Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Multiple Bonds Evaluated Using Oxygen K-edge Spectroscopy and Electronic Structure Theory . Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen K-edge Spectroscopy...

  5. Hubble Tarantula Treasury Project: Unraveling Tarantula's Web. II. Optical and Near Infrared Star Formation History of the Starburst Cluster NGC 2070 in 30 Doradus

    E-Print Network [OSTI]

    Cignoni, M; van der Marel, R P; Tosi, M; Zaritsky, D; Anderson, J; Lennon, D J; Aloisi, A; de Marchi, G; Gouliermis, D A; Grebel, E K; Smith, L J; Zeidler, P

    2015-01-01T23:59:59.000Z

    We present a study of the recent star formation of 30 Doradus in the Large Magellanic Cloud (LMC) using the panchromatic imaging survey Hubble Tarantula Treasury Project (HTTP). In this paper we focus on the stars within 20 pc of the center of the massive ionizing cluster of 30 Doradus, NGC 2070. We recovered the star formation history by comparing deep optical and NIR color-magnitude diagrams (CMDs) with state-of-the-art synthetic CMDs generated with the latest PARSEC models, which include all stellar phases from pre-main sequence to post- main sequence. For the first time in this region we are able to measure the star formation using intermediate and low mass stars simultaneously. Our results suggest that NGC2070 experienced a prolonged activity. In particular, we find that the star formation in the region: i) exceeded the average LMC rate ~ 20 Myr ago; ii) accelerated dramatically ~ 7 Myr ago; and iii) reached a peak value 1-3 Myr ago. We did not find significant deviations from a Kroupa initial mass funct...

  6. The Ohio Enterprise Bond Fund (Ohio)

    Broader source: Energy.gov [DOE]

    The Ohio Enterprise Bond Fund (OEBF) was created in 1988 to promote economic development, create and retain quality jobs and assist governmental operations. The program enables non-profit and for...

  7. Industrial Revenue Bond Program (District of Columbia)

    Broader source: Energy.gov [DOE]

    The District provides below market bond financing to lower the costs of borrowing for qualified capital construction and renovation projects. The program is available to non-profits, institutions,...

  8. Corporate bond repurchases and earnings management

    E-Print Network [OSTI]

    Lemayian, Zawadi Rehema

    2013-01-01T23:59:59.000Z

    This paper investigates whether earnings management incentives are associated with gains/losses recognized when firms repurchase bonds. The research question is motivated by the inclusion of these gains/losses in firms' ...

  9. Method of bonding metals to ceramics

    DOE Patents [OSTI]

    Maroni, V.A.

    1991-04-23T23:59:59.000Z

    A ceramic or glass having a thin layer of silver, gold or alloys thereof at the surface thereof is disclosed. A first metal is bonded to the thin layer and a second metal is bonded to the first metal. The first metal is selected from the class consisting of In, Ga, Sn, Bi, Zn, Cd, Pb, Tl and alloys thereof, and the second metal is selected from the class consisting of Cu, Al, Pb, Au and alloys thereof. 3 figures.

  10. July 18, 2012 Using Qualified Energy Conservation Bonds for Public

    E-Print Network [OSTI]

    July 18, 2012 Using Qualified Energy Conservation Bonds for Public Building Upgrades: Reducing Energy Bills in the City of Philadelphia Qualified Energy Conservation Bonds (QECBs) are federally Energy Conservation Bond (QECB) is a bond that enables qualified state, tribal and local government

  11. Qualified Energy Conservation Bond State-by-State Summary Tables

    Broader source: Energy.gov [DOE]

    Provides a list of qualified energy conservation bond state summary tables. Author: Energy Programs Consortium

  12. The Ties That Bond: Re-Examining the Relationship between Facebook Use and Bonding Social Capital

    E-Print Network [OSTI]

    Michigan, University of

    The Ties That Bond: Re-Examining the Relationship between Facebook Use and Bonding Social Capital established a positive relationship between measures of Facebook use and perceptions of social capital. Like other social network sites, Facebook is especially well-positioned to enhance users' bridging social

  13. Hydrogen Bond Networks: Structure and Evolution after Hydrogen Bond Breaking John B. Asbury, Tobias Steinel, and M. D. Fayer*

    E-Print Network [OSTI]

    Fayer, Michael D.

    Hydrogen Bond Networks: Structure and Evolution after Hydrogen Bond Breaking John B. Asbury, TobiasVed: September 1, 2003; In Final Form: December 18, 2003 The nature of hydrogen bonding networks following hydrogen bond breaking is investigated using vibrational echo correlation spectroscopy of the hydroxyl

  14. Shirzadi et al. Surface and Interface Analysis 2001; 31:609-618 Interface evolution and bond strength when diffusion bonding

    E-Print Network [OSTI]

    Cambridge, University of

    strength when diffusion bonding materials with stable oxide films A.A. Shirzadi* , H. Assadi and E morphologies and strengths of aluminium diffusion bonds are reviewed. Previous approaches, proposed to overcome for both solid-state diffusion bonding and conventional transient liquid phase (TLP) diffusion bonding. Non

  15. Bond Strength Measurements from an Australian Standard Bond Wrench in Comparison to the Unbalanced ASTM C 1072 Bond Wrench to the Balanced and Unbalanced Wrenches

    E-Print Network [OSTI]

    Suresh, Sri Vishnu Chaitanya Guptha

    2014-08-14T23:59:59.000Z

    Bond wrenches. The Australian wrench values were significantly higher than the American bond wrenches for similar types of samples. Hence it was recommended that the tests be carried out by replacing the cement with Portland cement. This experimental...

  16. Bonded ultrasonic transducer and method for making

    DOE Patents [OSTI]

    Dixon, Raymond D. (Los Alamos, NM); Roe, Lawrence H. (Los Alamos, NM); Migliori, Albert (Santa Fe, NM)

    1995-01-01T23:59:59.000Z

    An ultrasonic transducer is formed as a diffusion bonded assembly of piezoelectric crystal, backing material, and, optionally, a ceramic wear surface. The mating surfaces of each component are silver films that are diffusion bonded together under the application of pressure and heat. Each mating surface may also be coated with a reactive metal, such as hafnium, to increase the adhesion of the silver films to the component surfaces. Only thin silver films are deposited, e.g., a thickness of about 0.00635 mm, to form a substantially non-compliant bond between surfaces. The resulting transducer assembly is substantially free of self-resonances over normal operating ranges for taking resonant ultrasound measurements.

  17. Process Of Bonding Copper And Tungsten

    DOE Patents [OSTI]

    Slattery, Kevin T. (St. Charles, MO); Driemeyer, Daniel E. (Manchester, MO)

    1999-11-23T23:59:59.000Z

    Process for bonding a copper substrate to a tungsten substrate by providing a thin metallic adhesion promoting film bonded to a tungsten substrate and a functionally graded material (FGM) interlayer bonding the thin metallic adhesion promoting film to the copper substrate. The FGM interlayer is formed by thermal plasma spraying mixtures of copper powder and tungsten powder in a varied blending ratio such that the blending ratio of the copper powder and the tungsten powder that is fed to a plasma torch is intermittently adjusted to provide progressively higher copper content/tungsten content, by volume, ratio values in the interlayer in a lineal direction extending from the tungsten substrate towards the copper substrate. The resulting copper to tungsten joint well accommodates the difference in the coefficient of thermal expansion of the materials.

  18. Alkyl Chlorides as Hydrogen Bond Acceptors

    SciTech Connect (OSTI)

    Nadas, Janos I [ORNL; Vukovic, Sinisa [ORNL; Hay, Benjamin [ORNL

    2012-01-01T23:59:59.000Z

    To gain an understanding of the role of an alkyl chloride as a hydrogen bond acceptor, geometries and interaction energies were calculated at the MP2/aug-cc-pVDZ level of theory for complexes between ethyl chloride and representative hydrogen donor groups. The results establish that these donors, which include hydrogen cyanide, methanol, nitrobenzene, pyrrole, acetamide, and N-methylurea, form X-H {hor_ellipsis} Cl hydrogen bonds (X = C, N, O) of weak to moderate strength, with {Delta}E values ranging from -2.8 to -5.3 kcal/mol.

  19. Phosphate-bonded calcium aluminate cements

    DOE Patents [OSTI]

    Sugama, Toshifumi (Mastic Beach, NY)

    1993-01-01T23:59:59.000Z

    A method is described for making a rapid-setting phosphate-bonded cementitious material. A powdered aluminous cement is mixed with an aqueous solution of ammonium phosphate. The mixture is allowed to set to form an amorphous cementitious material which also may be hydrothermally treated at a temperature of from about 120.degree. C. to about 300.degree. C. to form a crystal-containing phosphate-bonded material. Also described are the cementitious products of this method and the cement composition which includes aluminous cement and ammonium polyphosphate.

  20. Phosphate-bonded calcium aluminate cements

    DOE Patents [OSTI]

    Sugama, T.

    1993-09-21T23:59:59.000Z

    A method is described for making a rapid-setting phosphate-bonded cementitious material. A powdered aluminous cement is mixed with an aqueous solution of ammonium phosphate. The mixture is allowed to set to form an amorphous cementitious material which also may be hydrothermally treated at a temperature of from about 120 C to about 300 C to form a crystal-containing phosphate-bonded material. Also described are the cementitious products of this method and the cement composition which includes aluminous cement and ammonium polyphosphate. 10 figures.

  1. Adhesive bonding using variable frequency microwave energy

    DOE Patents [OSTI]

    Lauf, Robert J. (Oak Ridge, TN); McMillan, April D. (Knoxville, TN); Paulauskas, Felix L. (Oak Ridge, TN); Fathi, Zakaryae (Cary, NC); Wei, Jianghua (Raleigh, NC)

    1998-01-01T23:59:59.000Z

    Methods of facilitating the adhesive bonding of various components with variable frequency microwave energy are disclosed. The time required to cure a polymeric adhesive is decreased by placing components to be bonded via the adhesive in a microwave heating apparatus having a multimode cavity and irradiated with microwaves of varying frequencies. Methods of uniformly heating various articles having conductive fibers disposed therein are provided. Microwave energy may be selectively oriented to enter an edge portion of an article having conductive fibers therein. An edge portion of an article having conductive fibers therein may be selectively shielded from microwave energy.

  2. Adhesive bonding using variable frequency microwave energy

    DOE Patents [OSTI]

    Lauf, R.J.; McMillan, A.D.; Paulauskas, F.L.; Fathi, Z.; Wei, J.

    1998-09-08T23:59:59.000Z

    Methods of facilitating the adhesive bonding of various components with variable frequency microwave energy are disclosed. The time required to cure a polymeric adhesive is decreased by placing components to be bonded via the adhesive in a microwave heating apparatus having a multimode cavity and irradiated with microwaves of varying frequencies. Methods of uniformly heating various articles having conductive fibers disposed therein are provided. Microwave energy may be selectively oriented to enter an edge portion of an article having conductive fibers therein. An edge portion of an article having conductive fibers therein may be selectively shielded from microwave energy. 26 figs.

  3. Adhesive bonding using variable frequency microwave energy

    DOE Patents [OSTI]

    Lauf, R.J.; McMillan, A.D.; Paulauskas, F.L.; Fathi, Z.; Wei, J.

    1998-08-25T23:59:59.000Z

    Methods of facilitating the adhesive bonding of various components with variable frequency microwave energy are disclosed. The time required to cure a polymeric adhesive is decreased by placing components to be bonded via the adhesive in a microwave heating apparatus having a multimode cavity and irradiated with microwaves of varying frequencies. Methods of uniformly heating various articles having conductive fibers disposed therein are provided. Microwave energy may be selectively oriented to enter an edge portion of an article having conductive fibers therein. An edge portion of an article having conductive fibers therein may be selectively shielded from microwave energy. 26 figs.

  4. Nitride-bonded silicon carbide composite filter

    SciTech Connect (OSTI)

    Thomson, B.N.; DiPietro, S.G.

    1995-12-01T23:59:59.000Z

    The objective of this program is to develop and demonstrate an advanced hot gas filter, using ceramic component technology, with enhanced durability to provide increased resistance to thermal fatigue and crack propagation. The material is silicon carbide fiber reinforced nitride bonded silicon carbide.

  5. Fluorinated diamond bonded in fluorocarbon resin

    DOE Patents [OSTI]

    Taylor, Gene W. (Los Alamos, NM)

    1982-01-01T23:59:59.000Z

    By fluorinating diamond grit, the grit may be readily bonded into a fluorocarbon resin matrix. The matrix is formed by simple hot pressing techniques. Diamond grinding wheels may advantageously be manufactured using such a matrix. Teflon fluorocarbon resins are particularly well suited for using in forming the matrix.

  6. Air America: Upholding the Airmen's Bond

    E-Print Network [OSTI]

    Kilgard, Michael P.

    Air America: Upholding the Airmen's Bond April 18, 2009 The University of Texas at Dallas Conference Center Auditorium A Symposium to Acknowledge and Commemorate Air America Rescue Efforts during with Air America Senior Operations Officer, CIA, Retired 2 p.m. Laos Rescues: Lima Site 85 Dr. Tim Castle

  7. THE ACS NEARBY GALAXY SURVEY TREASURY. VII. THE NGC 4214 STARBURST AND THE EFFECTS OF STAR FORMATION HISTORY ON DWARF MORPHOLOGY

    SciTech Connect (OSTI)

    Williams, Benjamin F.; Dalcanton, Julianne J.; Gilbert, Karoline M.; Weisz, Daniel R. [Department of Astronomy, Box 351580, University of Washington, Seattle, WA 98195 (United States); Seth, Anil C. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Skillman, Evan D. [Department of Astronomy, University of Minnesota, 116 Church Street SE, Minneapolis, MN 55455 (United States); Dolphin, Andrew E., E-mail: ben@astro.washington.edu, E-mail: jd@astro.washington.edu, E-mail: kgilbert@astro.washington.edu, E-mail: dweisz@astro.washington.edu, E-mail: aseth@cfa.harvard.edu, E-mail: skillman@astro.umn.edu, E-mail: adolphin@raytheon.com [Raytheon, 1151 E. Hermans Road, Tucson, AZ 85756 (United States)

    2011-07-01T23:59:59.000Z

    We present deep Hubble Space Telescope WFPC2 optical observations obtained as part of the ACS Nearby Galaxy Survey Treasury as well as early release Wide Field Camera 3 ultraviolet and infrared observations of the nearby dwarf starbursting galaxy NGC 4214. Our data provide a detailed example of how covering such a broad range in wavelength provides a powerful tool for constraining the physical properties of stellar populations. The deepest data reach the ancient red clump at M{sub F814W} {approx} - 0.2. All of the optical data reach the main-sequence turnoff for stars younger than {approx}300 Myr and the blue He-burning sequence for stars younger than 500 Myr. The full color-magnitude diagram (CMD) fitting analysis shows that all three fields in our data set are consistent with {approx}75% of the stellar mass being older than 8 Gyr, in spite of showing a wide range in star formation rates at present. Thus, our results suggest that the scale length of NGC 4214 has remained relatively constant for many gigayears. As previously noted by others, we also find the galaxy has recently ramped up production consistent with its bright UV luminosity and its population of UV-bright massive stars. In the central field we find UV point sources with F336W magnitudes as bright as -9.9. These are as bright as stars with masses of at least 52-56 M{sub sun} and ages near 4 Myr in stellar evolution models. Assuming a standard initial mass function, our CMD is well fitted by an increase in star formation rate beginning 100 Myr ago. The stellar populations of this late-type dwarf are compared with those of NGC 404, an early-type dwarf that is also the most massive galaxy in its local environment. The late-type dwarf appears to have a similar high fraction of ancient stars, suggesting that these dominant galaxies may form at early epochs even if they have low total mass and very different present-day morphologies.

  8. Bayesian field theoretic reconstruction of bond potential and bond mobility in single molecule force spectroscopy

    E-Print Network [OSTI]

    Chang, Joshua C; Chou, Tom

    2015-01-01T23:59:59.000Z

    Quantifying the forces between and within macromolecules is a necessary first step in understanding the mechanics of molecular structure, protein folding, and enzyme function and performance. In such macromolecular settings, dynamic single-molecule force spectroscopy (DFS) has been used to distort bonds. The resulting responses, in the form of rupture forces, work applied, and trajectories of displacements, have been used to reconstruct bond potentials. Such approaches often rely on simple parameterizations of one-dimensional bond potentials, assumptions on equilibrium starting states, and/or large amounts of trajectory data. Parametric approaches typically fail at inferring complex-shaped bond potentials with multiple minima, while piecewise estimation may not guarantee smooth results with the appropriate behavior at large distances. Existing techniques, particularly those based on work theorems, also do not address spatial variations in the diffusivity that may arise from spatially inhomogeneous coupling to...

  9. C-O Bond Activation and C-C Bond Formation Paths in Catalytic CO Hydrogenation

    E-Print Network [OSTI]

    Loveless, Brett

    2012-01-01T23:59:59.000Z

    Anderson, The Fischer-Tropsch and Related Synthesis, Wiley,Anderson, The Fischer-Tropsch and Related Synthesis, Wiley,C-C bond formation paths in Fischer-Tropsch synthesis are

  10. Various Carbon to Carbon Bond Lengths Inter-related via the Golden Ratio, and their Linear Dependence on Bond Energies

    E-Print Network [OSTI]

    Raji Heyrovska

    2008-09-11T23:59:59.000Z

    This work presents the relations between the carbon to carbon bond lengths in the single, double and triple bonds and in graphite, butadiene and benzene. The Golden ratio, which was shown to divide the Bohr radius into two parts pertaining to the charged particles, the electron and proton, and to divide inter-atomic distances into their cationic and anionic radii, also plays a role in the carbon-carbon bonds and in the ionic/polar character of those in graphite, butadiene and benzene. Further, the bond energies of the various CC bonds are shown to vary linearly with the bond lengths.

  11. Experimental bond critical point and local energy density properties...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mn-O, Fe-O and Co-O bonded interactions for Abstract: Bond critical point, bcp, and local energy density properties for the electron density, ED, distributions, calculated with...

  12. Pre-plated reactive diffusion-bonded battery electrode plaques

    DOE Patents [OSTI]

    Maskalick, Nicholas J. (Pittsburgh, PA)

    1984-01-01T23:59:59.000Z

    A high strength, metallic fiber battery plaque is made using reactive diffusion bonding techniques, where a substantial amount of the fibers are bonded together by an iron-nickel alloy.

  13. Single-Issue Industrial Revenue Bond Program (Missouri)

    Broader source: Energy.gov [DOE]

    The Missouri Development Finance Board administers a Single-Issue Tax-Exempt Industrial Revenue Bond Program as well as a Taxable Industrial Revenue Bond Program. The Tax-Exempt Program finances (i...

  14. Imaging Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies on TiO2(110). Imaging Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies on TiO2(110). Abstract: Since oxygen atom...

  15. ORNL: Low-Cost Direct Bonded Aluminum (DBA) Substrates (Agreement...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ORNL: Low-Cost Direct Bonded Aluminum (DBA) Substrates (Agreement ID:23278) ORNL: Low-Cost Direct Bonded Aluminum (DBA) Substrates (Agreement ID:23278) 2013 DOE Hydrogen and Fuel...

  16. Ultrafast conversions between hydrogen bonded structures in liquid water observed by femtosecond x-ray spectroscopy

    E-Print Network [OSTI]

    Wen, Haidan

    2010-01-01T23:59:59.000Z

    manifesting in fewer/weaker hydrogen bonds and structuralstructures with weaker hydrogen-bonding is recorded viais characteristic of the hydrogen bond network in water. The

  17. Partial-Transient-Liquid-Phase Bonding of Advanced Ceramics Using Surface-Modified Interlayers

    E-Print Network [OSTI]

    Reynolds, Thomas Bither

    2012-01-01T23:59:59.000Z

    Theoretical-Model for Diffusion Bonding." Metal Science 16,Derby, B. & Wallach, E. "Diffusion Bonding - Development ofInterfacial Contact during Diffusion Bonding." Metallurgical

  18. Hydrogen Bonding DOI: 10.1002/anie.200501349

    E-Print Network [OSTI]

    Simons, Jack

    systems[5­13] and crystal engineering.[14­18] Most C�H···O hydrogen bonds have been observed for the soHydrogen Bonding DOI: 10.1002/anie.200501349 Observation of Weak C�H···O Hydrogen Bonding to Unactivated Alkanes** Xue-Bin Wang, Hin-Koon Woo, Boggavarapu Kiran, and Lai-Sheng Wang* The hydrogen bond

  19. Measuring Interfacial Stiffness of Adhesively-Bonded Wood

    E-Print Network [OSTI]

    Nairn, John A.

    , the interfaces will fail, the elements will cease to share load, and the composite will have poor properties property. Nearly all methods for characterizing wood adhesive bonds consider only strength of the bonds. Typically a bond line is loaded until failure and the final load at failure is recorded. Some common

  20. Hydrogen Bonding Penalty upon Ligand Binding Hongtao Zhao, Danzhi Huang*

    E-Print Network [OSTI]

    Caflisch, Amedeo

    Hydrogen Bonding Penalty upon Ligand Binding Hongtao Zhao, Danzhi Huang* Department of Biochemistry, University of Zurich, Zurich, Switzerland Abstract Ligand binding involves breakage of hydrogen bonds with water molecules and formation of new hydrogen bonds between protein and ligand. In this work, the change

  1. Flip chip electrical interconnection by selective electroplating and bonding

    E-Print Network [OSTI]

    Lin, Liwei

    the interconnection and device substrates to en- hance the ion diffusion during the final electroplating and bondingFlip chip electrical interconnection by selective electroplating and bonding L.-W. Pan, P. Yuen, L of flip-chip, selective elec- troplating and bonding. The electrical interconnection lines are built

  2. Oil prices and government bond risk premiums Herv Alexandre*

    E-Print Network [OSTI]

    Boyer, Edmond

    Oil prices and government bond risk premiums By Hervé Alexandre*ş Antonin de Benoist * Abstract : This article analyses the impact of oil price on bond risk premiums issued by emerging economies. No empirical study has yet focussed on the effects of the oil price on government bond risk premiums. We develop

  3. Energetics of hydrogen bonds in peptides Sheh-Yi Sheu*

    E-Print Network [OSTI]

    Sheu, Sheh-Yi

    for water. We find that the activation energy for the rupture of the hydrogen bond in a -sheet under calculation can be useful for the prediction of hydrogen bond strengths in various environments of interest extensively to calculate free energy changes caused by hydrogen bond rupture. Here the water environment

  4. Analysis of C H...O hydrogen bonds

    E-Print Network [OSTI]

    Babu, M. Madan

    1 Analysis of C H...O hydrogen bonds in high resolution protein crystal structures from the PDB 1.4 Identification of C-H...O hydrogen bonds............................................. 1.4.1 The definition of a C-H...O hydrogen bond.................................... 1.4.2 Fixing the hydrogen and measuring the parameters

  5. Article coated with flash bonded superhydrophobic particles

    DOE Patents [OSTI]

    Simpson, John T (Clinton, TN) [Clinton, TN; Blue, Craig A (Knoxville, TN) [Knoxville, TN; Kiggans, Jr., James O [Oak Ridge, TN

    2010-07-13T23:59:59.000Z

    A method of making article having a superhydrophobic surface includes: providing a solid body defining at least one surface; applying to the surface a plurality of diatomaceous earth particles and/or particles characterized by particle sizes ranging from at least 100 nm to about 10 .mu.m, the particles being further characterized by a plurality of nanopores, wherein at least some of the nanopores provide flow through porosity, the particles being further characterized by a plurality of spaced apart nanostructured features that include a contiguous, protrusive material; flash bonding the particles to the surface so that the particles are adherently bonded to the surface; and applying a hydrophobic coating layer to the surface and the particles so that the hydrophobic coating layer conforms to the nanostructured features.

  6. Anesthesia cutoff phenomenon: Interfacial hydrogen bonding

    SciTech Connect (OSTI)

    Chiou, J.S.; Ma, S.M.; Kamaya, H.; Ueda, I. (Univ. of Utah School of Medicine, Salt Lake City (USA))

    1990-05-04T23:59:59.000Z

    Anesthesia cutoff refers to the phenomenon of loss of anesthetic potency in a homologous series of alkanes and their derivatives when their sizes become too large. In this study, hydrogen bonding of 1-alkanol series (ethanol to eicosanol) to dipalmitoyl-L-alpha-phosphatidylcholine (DPPC) was studied by Fourier transform infrared spectroscopy (FTIR) in DPPC-D2O-in-CCl4 reversed micelles. The alkanols formed hydrogen bonds with the phosphate moiety of DPPC and released the DPPC-bound deuterated water, evidenced by increases in the bound O-H stretching signal of the alkanol-DPPC complex and also in the free O-D stretching band of unbound D2O. These effects increased according to the elongation of the carbon chain of 1-alkanols from ethanol (C2) to 1-decanol (C10), but suddenly almost disappeared at 1-tetradecanol (C14). Anesthetic potencies of these alkanols, estimated by the activity of brine shrimps, were linearly related to hydrogen bond-breaking activities below C10 and agreed with the FTIR data in the cutoff at C10.

  7. Microchannel cooling of face down bonded chips

    DOE Patents [OSTI]

    Bernhardt, Anthony F. (Berkeley, CA)

    1993-01-01T23:59:59.000Z

    Microchannel cooling is applied to flip-chip bonded integrated circuits, in a manner which maintains the advantages of flip-chip bonds, while overcoming the difficulties encountered in cooling the chips. The technique is suited to either multichip integrated circuit boards in a plane, or to stacks of circuit boards in a three dimensional interconnect structure. Integrated circuit chips are mounted on a circuit board using flip-chip or control collapse bonds. A microchannel structure is essentially permanently coupled with the back of the chip. A coolant delivery manifold delivers coolant to the microchannel structure, and a seal consisting of a compressible elastomer is provided between the coolant delivery manifold and the microchannel structure. The integrated circuit chip and microchannel structure are connected together to form a replaceable integrated circuit module which can be easily decoupled from the coolant delivery manifold and the circuit board. The coolant supply manifolds may be disposed between the circuit boards in a stack and coupled to supplies of coolant through a side of the stack.

  8. Microchannel cooling of face down bonded chips

    DOE Patents [OSTI]

    Bernhardt, A.F.

    1993-06-08T23:59:59.000Z

    Microchannel cooling is applied to flip-chip bonded integrated circuits, in a manner which maintains the advantages of flip-chip bonds, while overcoming the difficulties encountered in cooling the chips. The technique is suited to either multi chip integrated circuit boards in a plane, or to stacks of circuit boards in a three dimensional interconnect structure. Integrated circuit chips are mounted on a circuit board using flip-chip or control collapse bonds. A microchannel structure is essentially permanently coupled with the back of the chip. A coolant delivery manifold delivers coolant to the microchannel structure, and a seal consisting of a compressible elastomer is provided between the coolant delivery manifold and the microchannel structure. The integrated circuit chip and microchannel structure are connected together to form a replaceable integrated circuit module which can be easily decoupled from the coolant delivery manifold and the circuit board. The coolant supply manifolds may be disposed between the circuit boards in a stack and coupled to supplies of coolant through a side of the stack.

  9. Thermal Modeling of A Friction Bonding Process

    SciTech Connect (OSTI)

    John Dixon; Douglas Burkes; Pavel Medvedev

    2007-10-01T23:59:59.000Z

    A COMSOL model capable of predicting temperature evolution during nuclear fuel fabrication is being developed at the Idaho National Laboratory (INL). Fuel plates are fabricated by friction bonding (FB) uranium-molybdenum (U-Mo) alloy foils positioned between two aluminum plates. The ability to predict temperature distribution during fabrication is imperative to ensure good quality bonding without inducing an undesirable chemical reaction between U-Mo and aluminum. A three-dimensional heat transfer model of the FB process implementing shallow pin penetration for cladding monolithic nuclear fuel foils is presented. Temperature distribution during the FB process as a function of fabrication parameters such as weld speed, tool load, and tool rotational frequency are predicted. Model assumptions, settings, and equations are described in relation to standard friction stir welding. Current experimental design for validation and calibration of the model is also demonstrated. Resulting experimental data reveal the accuracy in describing asymmetrical temperature distributions about the tool face. Temperature of the bonded plate drops beneath the pin and is higher on the advancing side than the retreating side of the tool.

  10. Vacuum fusion bonding of glass plates

    DOE Patents [OSTI]

    Swierkowski, Steve P. (Livermore, CA); Davidson, James C. (Livermore, CA); Balch, Joseph W. (Livermore, CA)

    2001-01-01T23:59:59.000Z

    An improved apparatus and method for vacuum fusion bonding of large, patterned glass plates. One or both glass plates are patterned with etched features such as microstructure capillaries and a vacuum pumpout moat, with one plate having at least one hole therethrough for communication with a vacuum pumpout fixture. High accuracy alignment of the plates is accomplished by a temporary clamping fixture until the start of the fusion bonding heat cycle. A complete, void-free fusion bond of seamless, full-strength quality is obtained through the plates; because the glass is heated well into its softening point and because of a large, distributed force that is developed that presses the two plates together from the difference in pressure between the furnace ambient (high pressure) and the channeling and microstructures in the plates (low pressure) due to the vacuum drawn. The apparatus and method may be used to fabricate microcapillary arrays for chemical electrophoresis; for example, any apparatus using a network of microfluidic channels embedded between plates of glass or similar moderate melting point substrates with a gradual softening point curve, or for assembly of glass-based substrates onto larger substrates, such as in flat panel display systems.

  11. Vacuum fusion bonding of glass plates

    DOE Patents [OSTI]

    Swierkowski, Steve P. (Livermore, CA); Davidson, James C. (Livermore, CA); Balch, Joseph W. (Livermore, CA)

    2000-01-01T23:59:59.000Z

    An improved apparatus and method for vacuum fusion bonding of large, patterned glass plates. One or both glass plates are patterned with etched features such as microstructure capillaries and a vacuum pumpout moat, with one plate having at least one hole therethrough for communication with a vacuum pumpout fixture. High accuracy alignment of the plates is accomplished by a temporary clamping fixture until the start of the fusion bonding heat cycle. A complete, void-free fusion bond of seamless, full-strength quality is obtained through the plates; because the glass is heated well into its softening point and because of a large, distributed force that is developed that presses the two plates together from the difference in pressure between the furnace ambient (high pressure) and the channeling and microstructures in the plates (low pressure) due to the vacuum drawn. The apparatus and method may be used to fabricate microcapillary arrays for chemical electrophoresis; for example, any apparatus using a network of microfluidic channels embedded between plates of glass or similar moderate melting point substrates with a gradual softening point curve, or for assembly of glass-based substrates onto larger substrates, such as in flat panel display systems.

  12. Hydrogen Bond Breaking and Reformation in Alcohol Oligomers Following Vibrational Relaxation of a Non-Hydrogen-Bond Donating Hydroxyl Stretch

    E-Print Network [OSTI]

    Fayer, Michael D.

    Hydrogen Bond Breaking and Reformation in Alcohol Oligomers Following Vibrational Relaxation of a Non-Hydrogen-Bond Donating Hydroxyl Stretch K. J. Gaffney, I. R. Piletic, and M. D. Fayer* Department measured with ultrafast infrared pump-probe experiments. Non-hydrogen-bond donating OD stretches (2690 cm-1

  13. Method for bonding a transmission line to a downhole tool

    DOE Patents [OSTI]

    Hall, David R. (Provo, UT); Fox, Joe (Spanish Fork, UT)

    2007-11-06T23:59:59.000Z

    An apparatus for bonding a transmission line to the central bore of a downhole tool includes a pre-formed interface for bonding a transmission line to the inside diameter of a downhole tool. The pre-formed interface includes a first surface that substantially conforms to the outside contour of a transmission line and a second surface that substantially conforms to the inside diameter of a downhole tool. In another aspect of the invention, a method for bonding a transmission line to the inside diameter of a downhole tool includes positioning a transmission line near the inside wall of a downhole tool and placing a mold near the transmission line and the inside wall. The method further includes injecting a bonding material into the mold and curing the bonding material such that the bonding material bonds the transmission line to the inside wall.

  14. Partial-Transient-Liquid-Phase Bonding of Advanced Ceramics Using Surface-Modified Interlayers

    E-Print Network [OSTI]

    Reynolds, Thomas Bither

    2012-01-01T23:59:59.000Z

    Alumina Diffusion Bonding and Titanium Active Brazing."O 3 -Titanium Adhesion in the View of the Diffusion Bonding

  15. Bond selective chemistry beyond the adiabatic approximation

    SciTech Connect (OSTI)

    Butler, L.J. [Univ. of Chicago, IL (United States)

    1993-12-01T23:59:59.000Z

    One of the most important challenges in chemistry is to develop predictive ability for the branching between energetically allowed chemical reaction pathways. Such predictive capability, coupled with a fundamental understanding of the important molecular interactions, is essential to the development and utilization of new fuels and the design of efficient combustion processes. Existing transition state and exact quantum theories successfully predict the branching between available product channels for systems in which each reaction coordinate can be adequately described by different paths along a single adiabatic potential energy surface. In particular, unimolecular dissociation following thermal, infrared multiphoton, or overtone excitation in the ground state yields a branching between energetically allowed product channels which can be successfully predicted by the application of statistical theories, i.e. the weakest bond breaks. (The predictions are particularly good for competing reactions in which when there is no saddle point along the reaction coordinates, as in simple bond fission reactions.) The predicted lack of bond selectivity results from the assumption of rapid internal vibrational energy redistribution and the implicit use of a single adiabatic Born-Oppenheimer potential energy surface for the reaction. However, the adiabatic approximation is not valid for the reaction of a wide variety of energetic materials and organic fuels; coupling between the electronic states of the reacting species play a a key role in determining the selectivity of the chemical reactions induced. The work described below investigated the central role played by coupling between electronic states in polyatomic molecules in determining the selective branching between energetically allowed fragmentation pathways in two key systems.

  16. Repairable chip bonding/interconnect process

    DOE Patents [OSTI]

    Bernhardt, Anthony F. (Berkeley, CA); Contolini, Robert J. (Livermore, CA); Malba, Vincent (Livermore, CA); Riddle, Robert A. (Tracy, CA)

    1997-01-01T23:59:59.000Z

    A repairable, chip-to-board interconnect process which addresses cost and testability issues in the multi-chip modules. This process can be carried out using a chip-on-sacrificial-substrate technique, involving laser processing. This process avoids the curing/solvent evolution problems encountered in prior approaches, as well is resolving prior plating problems and the requirements for fillets. For repairable high speed chip-to-board connection, transmission lines can be formed on the sides of the chip from chip bond pads, ending in a gull wing at the bottom of the chip for subsequent solder.

  17. Repairable chip bonding/interconnect process

    DOE Patents [OSTI]

    Bernhardt, A.F.; Contolini, R.J.; Malba, V.; Riddle, R.A.

    1997-08-05T23:59:59.000Z

    A repairable, chip-to-board interconnect process which addresses cost and testability issues in the multi-chip modules is disclosed. This process can be carried out using a chip-on-sacrificial-substrate technique, involving laser processing. This process avoids the curing/solvent evolution problems encountered in prior approaches, as well is resolving prior plating problems and the requirements for fillets. For repairable high speed chip-to-board connection, transmission lines can be formed on the sides of the chip from chip bond pads, ending in a gull wing at the bottom of the chip for subsequent solder. 10 figs.

  18. Covalent Bonding in Actinide Sandwich Molecules

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power Administration would likeConstitution AndControllingCoolCorrectiveCostsXCovalent Bonding in

  19. Covalent Bonding in Actinide Sandwich Molecules

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power Administration would likeConstitution AndControllingCoolCorrectiveCostsXCovalent Bonding

  20. Qualified Energy Conservation Bond (QECB) Update: New

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOrigin of ContaminationHubs+18, 2012 Qualified Energy Conservation Bond (QECB) Update: New

  1. Chemically bonded phospho-silicate ceramics

    DOE Patents [OSTI]

    Wagh, Arun S. (Orland Park, IL); Jeong, Seung Y. (Westmont, IL); Lohan, Dirk (Chicago, IL); Elizabeth, Anne (Chicago, IL)

    2003-01-01T23:59:59.000Z

    A chemically bonded phospho-silicate ceramic formed by chemically reacting a monovalent alkali metal phosphate (or ammonium hydrogen phosphate) and a sparsely soluble oxide, with a sparsely soluble silicate in an aqueous solution. The monovalent alkali metal phosphate (or ammonium hydrogen phosphate) and sparsely soluble oxide are both in powder form and combined in a stochiometric molar ratio range of (0.5-1.5):1 to form a binder powder. Similarly, the sparsely soluble silicate is also in powder form and mixed with the binder powder to form a mixture. Water is added to the mixture to form a slurry. The water comprises 50% by weight of the powder mixture in said slurry. The slurry is allowed to harden. The resulting chemically bonded phospho-silicate ceramic exhibits high flexural strength, high compression strength, low porosity and permeability to water, has a definable and bio-compatible chemical composition, and is readily and easily colored to almost any desired shade or hue.

  2. Using Qualified Energy Conservation Bonds for Public Building...

    Broader source: Energy.gov (indexed) [DOE]

    Summarizes how the City of Philadelphia leveraged 6.25 million in qualified energy conservation bonds to upgrade the energy efficiency of city buildings. Author: Lawrence Berkeley...

  3. Qualified Energy Conservation Bonds (QECBs) APPENDIX A: QECB...

    Broader source: Energy.gov (indexed) [DOE]

    Qualified energy conservation bonds appendices. Author: U. S. Department of Energy Appendix A: QECB Counsel, Underwriters, Banks and Trustees More Documents & Publications...

  4. Qualified Energy Conservation Bond Webinars | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    listing of past qualified energy conservation bond webinars and associated files. Author: U.S. Department of Energy Qualified Energy Conservation Webinars Website More Documents &...

  5. Energetics of Hydrogen Bond Network Rearrangements in Liquid...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly...

  6. Competition between Covalent and Noncovalent Bond Cleavages in...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    localized and mainly affected by the identity of the phosphorylated side chain. The hydrogen bonding in the peptide and ligand properties play a minor role in determining the...

  7. Surface Modification by Atmospheric Pressure Plasma for Improved Bonding

    E-Print Network [OSTI]

    Williams, Thomas Scott

    2013-01-01T23:59:59.000Z

    steel type 410, and aluminum alloy 2024. Helium and oxygensteel type 410, and aluminum alloy 2024 was demonstratedAdhesive Bonding of Aluminum Alloys, Metal Finishing, 13.

  8. Atomistic modeling of amorphous silicon carbide using a bond...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    there is partial recovery of shortrange order. Citation: Devanathan R, F Gao, and WJ Weber.2007."Atomistic modeling of amorphous silicon carbide using a bond-order...

  9. Clean Renewable Energy Bonds (CREBs) | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    different rules than prior CREB allocations authorized under 26 USC 54. ''''' Clean renewable energy bonds (CREBs) may be used by certain entities -- primarily in the public...

  10. Municipal Bond - Power Purchase Agreement Model Continues to...

    Broader source: Energy.gov (indexed) [DOE]

    for power purchase agreement model to provide low-cost solar energy. Author: National Renewable Energy Laboratory Municipal Bond - Power Purchase Agreement Model Continues to...

  11. Hydrogen-Bond Networks: Strengths of Different Types of Hydrogen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    energetic driving force for enzyme catalysis and conformational changes such as in protein folding due to multiple hydrogen bonds in a HBN. Citation: Shokri A, Y Wang, GA...

  12. Effects of atmospheres on bonding characteristics of silver and...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    temperature. To investigate the effects of atmospheres on the bonding characteristics of ceramic joints brazed with Ag-CuO braze filler metals, alumina joints prepared using a...

  13. Torsion Testing of Diffusion Bonded LIGA Formed Nickel

    SciTech Connect (OSTI)

    Buchheit, T.E.; Christenson, T.R.; Schmale, D.T.

    1999-01-27T23:59:59.000Z

    A test technique has been devised which is suitable for the testing of the bond strength of batch diffusion bonded LIGA or DXRL defined structures. The method uses a torsion tester constructed with the aid of LIGA fabrication and distributed torsion specimens which also make use of the high aspect ratio nature of DXRL based processing. Measurements reveal achieved bond strengths of 130MPa between electroplated nickel with a bond temperature of 450 C at 7 ksi pressure which is a sufficiently low temperature to avoid mechanical strength degradation.

  14. FITCH RATES ENERGY NORTHWEST (WA) ELECTRIC REV REF BONDS 'AA...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SECURITY Energy Northwest (ENW) bonds are secured by payments from the Bonneville Power Administration (Bonneville). Bonneville's payment to ENW is made as an operating...

  15. adhesively bonded shell: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    various conditions, including the type of surface preparation, pH of the environmental media, (more) Xu, Dingying 2004-01-01 2 Bond Characteristics and Qualifications of...

  16. Evidence on Financial Globalization and Crisis: Geographic/Bilateral External Balance Sheets

    E-Print Network [OSTI]

    Sá, Filipa

    2010-08-03T23:59:59.000Z

    maturity of more than one year). They are collected by country and record purchases by foreigners from US residents and sales by foreigners to US residents of US assets (equity, US Treasury debt, US government agency debt and US corporate bonds) and foreign... term debt and short term debt. Long term and short term debt are disaggregated further into Treasury, agency and corporate debt. Information goes back to 1974, but until 2001 only data on long term securities were collected. The Bundesbank external...

  17. Method of bonding single crystal quartz by field-assisted bonding

    DOE Patents [OSTI]

    Curlee, R.M.; Tuthill, C.D.; Watkins, R.D.

    1991-04-23T23:59:59.000Z

    The method of producing a hermetic stable structural bond between quartz crystals includes providing first and second quartz crystals and depositing thin films of borosilicate glass and silicon on portions of the first and second crystals, respectively. The portions of the first and second crystals are then juxtaposed in a surface contact relationship and heated to a temperature for a period sufficient to cause the glass and silicon films to become electrically conductive. An electrical potential is then applied across the first and second crystals for creating an electrostatic field between the adjoining surfaces and causing the juxtaposed portions to be attracted into an intimate contact and form a bond for joining the adjoining surfaces of the crystals. 2 figures.

  18. Method of bonding single crystal quartz by field-assisted bonding

    DOE Patents [OSTI]

    Curlee, Richard M. (Tijeras, NM); Tuthill, Clinton D. (Edgewood, NM); Watkins, Randall D. (Albuquerque, NM)

    1991-01-01T23:59:59.000Z

    The method of producing a hermetic stable structural bond between quartz crystals includes providing first and second quartz crystals and depositing thin films of borosilicate glass and silicon on portions of the first and second crystals, respectively. The portions of the first and second crystals are then juxtaposed in a surface contact relationship and heated to a temperature for a period sufficient to cause the glass and silicon films to become electrically conductive. An electrical potential is then applied across the first and second crystals for creating an electrostatic field between the adjoining surfaces and causing the juxtaposed portions to be attracted into an intimate contact and form a bond for joining the adjoining surfaces of the crystals.

  19. Quantum Finance Hamiltonian for Coupon Bond European and Barrier Options

    E-Print Network [OSTI]

    Chaudhuri, Sanjay

    Quantum Finance Hamiltonian for Coupon Bond European and Barrier Options Belal E. Baaquie RMI are financial derivatives that can be analyzed in the Hamiltonian formulation of quantum finance. Forward-2963 Fax: (65) 6777-6126 Email: phybeb@nus.edu.sg #12;Quantum Finance Hamiltonian for Coupon Bond European

  20. BOND PROPERTIES OF CFCC PRESTRESSING STRANDS IN PRETENSIONED CONCRETE BEAMS

    E-Print Network [OSTI]

    BOND PROPERTIES OF CFCC PRESTRESSING STRANDS IN PRETENSIONED CONCRETE BEAMS by Nolan G. Domenico plastic prestressing strands (CFCC) in pretensioned concrete beams. The bond characteristics are examined for 15.2 mm diameter and 12.5 mm diameter seven-wire CFCC strands. Ten prestressed concrete beams

  1. Time- and temperature-dependent failures of a bonded joint

    SciTech Connect (OSTI)

    Sihn, Sangwook; Miyano, Yasushi; Tsai, S.W. [Stanford Univ., Palo Alto, CA (United States)

    1997-07-01T23:59:59.000Z

    Time and temperature dependent properties of a tubular lap bonded joint are reported. The joint bonds a cast iron rod and a composite pipe together with an epoxy type of an adhesive material containing chopped glass fiber. A new fabrication method is proposed.

  2. Proton Transfer and Hydrogen Bonding in Chemical and Biological

    E-Print Network [OSTI]

    Amrhein, Valentin

    Proton Transfer and Hydrogen Bonding in Chemical and Biological Systems: A Force Field Approach and support. i #12;ii #12;Abstract Proton transfer and hydrogen bonds are fundamental for the function be regarded as incipient proton transfer reactions, so theoretically they can be de- scribed in unitary way

  3. Diffusion Bonding Aluminium Alloys and Composites: New Approaches and Modelling

    E-Print Network [OSTI]

    Cambridge, University of

    Diffusion Bonding Aluminium Alloys and Composites: New Approaches and Modelling Amir A. Shirzadi for advanced aluminium alloys and composites will enable them to be more widely used. The aim of this Ph of the research, two new methods for TLP diffusion bonding of aluminium-based composites (aluminium alloys

  4. Electrically conductive resinous bond and method of manufacture

    DOE Patents [OSTI]

    Snowden, Jr., Thomas M. (P.O. Box 4231, Clearwater, FL 33518); Wells, Barbara J. (865 N. Village Dr., Apt. 101B, St. Petersburg, FL 33702)

    1987-01-01T23:59:59.000Z

    A method of bonding elements together with a bond of high strength and good electrical conductivity which comprises: applying an unfilled polyimide resin between surfaces of the elements to be bonded, heat treating said unfilled polyimide resin in stages between a temperature range of about 40.degree. to 365.degree. C. to form a strong adhesive bond between said elements, applying a metal-filled polyimide resin overcoat between said elements so as to provide electrical connection therebetween, and heat treating said metal-filled polyimide resin with substantially the same temperature profile as the unfilled polyimide resin. The present invention is also concerned with an adhesive, resilient, substantially void free bonding combination for providing a high strength, electrically conductive adhesive attachment between electrically conductive elements which comprises a major amount of an unfilled polyimide resin and a minor amount of a metal-filled polyimide resin.

  5. Electrically conductive resinous bond and method of manufacture

    DOE Patents [OSTI]

    Snowden, T.M. Jr.; Wells, B.J.

    1985-01-01T23:59:59.000Z

    A method of bonding elements together with a bond of high strength and good electrical conductivity which comprises: applying an unfilled polyimide resin between surfaces of the elements to be bonded, heat treating said unfilled polyimide resin in stages between a temperature range of about 40 to 365/sup 0/C to form a strong adhesive bond between said elements, applying a metal-filled polyimide resin overcoat between said elements so as to provide electrical connection therebetween, and heat treating said metal-filled polyimide resin with substantially the same temperature profile as the unfilled polyimide resin. The present invention is also concerned with an adhesive, resilient, substantially void free bonding combination for providing a high strength, electrically conductive adhesive attachment between electrically conductive elements which comprises a major amount of an unfilled polyimide resin and a minor amount of a metal-filled polyimide resin.

  6. Clean renewable energy bonds (CREBs) present a low-cost opportunity for public entities to issue bonds to finance

    E-Print Network [OSTI]

    Clean renewable energy bonds (CREBs) present a low-cost opportunity for public entities to issue bonds to finance renewable energy projects. The federal government lowers the cost of debt by providing created under the Energy Tax Incentives Act of 2005 (and detailed in Internal Revenue Code Section 54

  7. Theoretical Electron Density Distributions for Fe-and Cu-Sulfide Earth Materials: A Connection between Bond Length, Bond Critical Point Properties, Local Energy Densities,

    E-Print Network [OSTI]

    Downs, Robert T.

    , Biomolecular and Chemical Sciences, UniVersity of Western Australia, Australia ReceiVed: August 7, 2006 between Bond Length, Bond Critical Point Properties, Local Energy Densities, and Bonded Interactions G. V; In Final Form: December 6, 2006 Bond critical point and local energy density properties together with net

  8. Transient-Liquid-Phase (TLP) Bonding of Al2O3 Using Nb-based Multilayer Interlayers

    E-Print Network [OSTI]

    Hong, Sung Moo

    2009-01-01T23:59:59.000Z

    Alumina Diffusion Bonding and Titanium Active Brazing.Requirements for Diffusion Bonding Titanium. In: Jaffee RI,O 3 -Titanium Adhesion in the View of the Diffusion Bonding

  9. Transient-Liquid-Phase (TLP) Bonding of Al2O3 Using Nb-based Multilayer Interlayers

    E-Print Network [OSTI]

    Hong, Sung Moo

    2009-01-01T23:59:59.000Z

    p. 539-44. Derby B. Diffusion Bonding. In: Nicholas M (ed).Requirements for Diffusion Bonding Titanium. In: Jaffee RI,Contact During Diffusion Bonding. Metallurgical Transactions

  10. Hydrogen Bond Dynamics Probed with Ultrafast Infrared Heterodyne-Detected Multidimensional Vibrational Stimulated Echoes

    E-Print Network [OSTI]

    Fayer, Michael D.

    Hydrogen Bond Dynamics Probed with Ultrafast Infrared Heterodyne-Detected Multidimensional, USA (Received 24 February 2003; published 3 December 2003) Hydrogen bond dynamics are explicated hydrogen bonded network are measured with ultrashort (

  11. Metal-and hydrogen-bonding competition during water absorption on Pd(111) and Ru(0001)

    E-Print Network [OSTI]

    Tatarkhanov, Mouslim

    2010-01-01T23:59:59.000Z

    Metal- and hydrogen-bonding competition during waterwith the greater degree of hydrogen-bonded network formationH and OH to maximize both hydrogen bonding and oxygen-metal

  12. An Investigation of Bonding Mechanism in Metal Cladding by Warm Rolling

    E-Print Network [OSTI]

    Yang, Wei

    2012-02-14T23:59:59.000Z

    , this research presents a bonding mechanism for the roll cladding process of dissimilar metals. The roll bonding model can help optimize rolling parameters for varying bonding strength depending on the demands of the application. It can also provide insights...

  13. Hydrogen-Bond Networks: Strengths of Different Types of Hydrogen Bonds and An Alternative to the Low Barrier Hydrogen-Bond Proposal

    SciTech Connect (OSTI)

    Shokri, Alireza; Wang, Yanping; O'Doherty, George A.; Wang, Xue B.; Kass, Steven R.

    2013-11-27T23:59:59.000Z

    We report quantifying the strengths of different types of hydrogen bonds in hydrogen bond networks (HBNs) via measurement of the adiabatic electron detachment energy of the conjugate base of a small covalent polyol model compound (i.e., (HOCH2CH2CH(OH)CH2)2CHOH) in the gas phase and the pKa of the corresponding acid in DMSO. The latter result reveals that the hydrogen bonds to the charged center and those that are one solvation shell further away (i.e., primary and secondary) provide 5.3 and 2.5 pKa units of stabilization per hydrogen bond in DMSO. Computations indicate that these energies increase to 8.4 and 3.9 pKa units in benzene and that the total stabilizations are 16 (DMSO) and 25 (benzene) pKa units. Calculations on a larger linear heptaol (i.e., (HOCH2CH2CH(OH)CH2CH(OH)CH2)2CHOH) reveal that the terminal hydroxyl groups each contribute 0.6 pKa units of stabilization in DMSO and 1.1 pKa units in benzene. All of these results taken together indicate that the presence of a charged center can provide a powerful energetic driving force for enzyme catalysis and conformational changes such as in protein folding due to multiple hydrogen bonds in a HBN.

  14. E-Print Network 3.0 - amide bonds stabilize Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Amide-Amide and Amide-Water Hydrogen Bonds Summary: Bonds: Implicationsfor Protein Folding and Stability Eric S.Eberhardt and Ronald T. Rained Department... folds, many of...

  15. The Role of Non-Bonded Interactions in the Conformational Dynamics...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Non-Bonded Interactions in the Conformational Dynamics of Organophosphorous Hydrolase Adsorbed onto Functionalized The Role of Non-Bonded Interactions in the Conformational...

  16. Influence of chain topology and bond potential on the glass transition of polymer chains simulated with the bond fluctuation model

    E-Print Network [OSTI]

    Juan J. Freire

    2006-12-20T23:59:59.000Z

    The bond fluctuation model with a bond potential has been applied to investigation of the glass transition of linear chains and chains with a regular disposition of small branches. Cooling and subsequent heating curves are obtained for the chain energies and also for the mean acceptance probability of a bead jump. In order to mimic different trends to vitrification, a factor B gauging the strength of the bond potential with respect to the long-range potential (i.e. the intramolecular or intermolecular potential between indirectly bonded beads) has been introduced. (A higher value of B leads to a preference for the highest bond lengths and a higher total energy, implying a greater tendency to vitrify.) Different cases have been considered for linear chains: no long-range potential, no bond potential and several choices for B. Furthermore, we have considered two distinct values of B for alternate bonds in linear chains. In the case of the branched chains, molecules with different values of B for bonds in the main chain and in the branches have also been investigated. The possible presence of crystallization has been characterized by calculating the collective light scattering function of the different samples after annealing at a convenient temperature below the onset of crystallization. It is concluded that crystallization is inherited more efficiently in the systems with branched chains and also for higher values of B. The branched molecules with the highest B values in the main chain bonds exhibit two distinct transitions in the heating curves which may be associated with two glass transitions. This behavior has been detected experimentally for chains with relatively long flexible branches.

  17. Semi-flexible hydrogen-bonded and non-hydrogen bonded lattice polymers

    E-Print Network [OSTI]

    J Krawczyk; AL Owczarek; T Prellberg

    2008-07-06T23:59:59.000Z

    We investigate the addition of stiffness to the lattice model of hydrogen-bonded polymers in two and three dimensions. We find that, in contrast to polymers that interact via a homogeneous short-range interaction, the collapse transition is unchanged by any amount of stiffness: this supports the physical argument that hydrogen bonding already introduces an effective stiffness. Contrary to possible physical arguments, favouring bends in the polymer does not return the model's behaviour to that comparable to the semi-flexible homogeneous interaction model, where the canonical $\\theta$-point occurs for a range of parameter values. In fact, for sufficiently large bending energies the crystal phase disappears altogether, and no phase transition of any type occurs. We also compare the order-disorder transition from the globule phase to crystalline phase in the semi-flexible homogeneous interaction model to that for the fully-flexible hybrid model with both hydrogen and non-hydrogen like interactions. We show that these phase transitions are of the same type and are a novel polymer critical phenomena in two dimensions. That is, it is confirmed that in two dimensions this transition is second-order, unlike in three dimensions where it is known to be first order. We also estimate the crossover exponent and show that there is a divergent specific heat, finding $\\phi=0.7(1)$ or equivalently $\\alpha=0.6(2)$. This is therefore different from the $\\theta$ transition, for which $\\alpha=-1/3$.

  18. FITCH RATES PORT OF MORROW (OR) TRANSMISSION FACILITIES REV BONDS...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    FITCH RATES PORT OF MORROW (OR) TRANSMISSION FACILITIES REV BONDS 'AA'; OUTLOOK STABLE Fitch Ratings-Austin-24 November 2014: Fitch Ratings assigns 'AA' ratings to the Port of...

  19. Mpemba paradox: Hydrogen bond memory and water-skin supersolidity

    E-Print Network [OSTI]

    Chang Q Sun

    2015-01-05T23:59:59.000Z

    Numerical reproduction of measurements, experimental evidence for skin super-solidity and hydrogen-bond memory clarified that Mpemba paradox integrates the heat emission-conduction-dissipation dynamics in the source-path-drain cycle system.

  20. Wafer bonding : mechanics-based models and experiments

    E-Print Network [OSTI]

    Turner, Kevin Thomas, 1977-

    2004-01-01T23:59:59.000Z

    Direct wafer bonding has emerged as an important technology in the manufacture of silicon-on-insulator substrates (SOI), microelectromechanical systems (MEMS), and three-dimensional integrated circuits (3D IC's). While the ...

  1. aliphatic ch bonds: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2015-01-01 39 H-atom high-n Rydberg time-of-flight spectroscopy of CH bond fission in acrolein dissociated at 193 nm Chemistry Websites Summary: H-atom high-n Rydberg...

  2. Bond Angle Torsion http://www.nobelprize.org/

    E-Print Network [OSTI]

    Fukai, Tomoki

    MARBLE-K 20141024 1 #12;2 MARBLE MARBLE #12;MD Bond Angle Torsion http) MARBLE-K PME CHARMM Force Field AMBER Force Field NMRSAXS molx XNMR #12;MARBLE

  3. Mechanistic Examination of C?-C? Bond Cleavages of Tryptophan...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (X C, S, L, F, Y, Q) species. The C?–C? bond cleavage of a C-terminal decarboxylated tryptophan residue (M - CO2•+) can generate M - CO2 - 116+,...

  4. Creep effects in diffusion bonding of oxygen-free copper

    E-Print Network [OSTI]

    Moilanen, Antti

    Diffusion is the transport of atoms or particles through the surrounding material. Various microstructural changes in metals are based on the diffusion phenomena. In solid metals the diffusion is closely related to crystallographic defects. In single-component metals the dominant mechanism of diffusion is the vacancy mechanism. Diffusion bonding is a direct technological application of diffusion. It is an advanced solidstate joining process in which the surfaces of two components are brought to contact with each other and heated under a pressing load in a controlled environment. During the process, the contact surfaces are bonded by atomic diffusion across the interface and as a result, one solid piece is formed. The condition of high temperature and low applied stress combined with relatively long process duration enables the creep effects to take place in bonded metals. Furthermore, creep causes unwanted permanent deformations in the bonded components. Some authors suggest that there could be a threshold fo...

  5. Spectroscopic investigations of hydrogen bond dynamics in liquid water

    E-Print Network [OSTI]

    Fecko, Christopher J., 1975-

    2004-01-01T23:59:59.000Z

    Many of the remarkable physical and chemical properties of liquid water are due to the strong influence hydrogen bonds have on its microscopic dynamics. However, because of the fast timescales involved, there are relatively ...

  6. Resummed thermodynamic perturbation theory for bond cooperativity in associating fluids

    SciTech Connect (OSTI)

    Marshall, Bennett D., E-mail: bennettd1980@gmail.com; Chapman, Walter G. [Department of Chemical and Biomolecular Engineering, Rice University, 6100 S. Main, Houston, Texas 77005 (United States)] [Department of Chemical and Biomolecular Engineering, Rice University, 6100 S. Main, Houston, Texas 77005 (United States)

    2013-12-07T23:59:59.000Z

    We develop a resummed thermodynamic perturbation theory for bond cooperativity in associating fluids by extension of Wertheim's multi-density formalism. We specifically consider the case of an associating hard sphere with two association sites and both pairwise and triplet contributions to the energy, such that the first bond in an associated cluster receives an energy ??{sup (1)} and each subsequent bond in the cluster receives an energy ??{sup (2)}. To test the theory we perform new Monte Carlo simulations for potentials of this type. Theory and simulation are found to be in excellent agreement. We show that decreasing the energetic benefit of hydrogen bonding can actually result in a decrease in internal energy in the fluid. We also predict that when ?{sup (1)} = 0 and ?{sup (2)} is nonzero there is a transition temperature where the system transitions from a fluid of monomers to a mixture of monomers and very long chains.

  7. Ultrafast structural fluctuations and rearrangements of water's hydrogen bonded network

    E-Print Network [OSTI]

    Loparo, Joseph J. (Joseph John)

    2007-01-01T23:59:59.000Z

    Aqueous chemistry is strongly influenced by water's ability to form an extended network of hydrogen bonds. It is the fluctuations and rearrangements of this network that stabilize reaction products and drive the transport ...

  8. Stress and Fracture Analysis of a Class of Bonded Joints in Wind Turbine Blades 

    E-Print Network [OSTI]

    Chen, Chang

    2013-05-08T23:59:59.000Z

    SERR,G strain energy release rate E Young?s modulus of adherend Ea Young?s modulus of adhesive D exural rigidity of adherend Ga shear modulus of adhesive J J-integral K spring sti ness W strain energy density a coordinate of left side of void..., and will deteriorate the structural sti ness and strength, even cause catastrophic failure [23][25] (Fig. 1.12). Figure 1.12: Catastrophic eld failure of wind turbine During a typical-20-year service life, adhesively bonded joints in wind turbine blades...

  9. Microbial cleavage of organic C-S bonds

    DOE Patents [OSTI]

    Kilbane, J.J. II.

    1994-10-25T23:59:59.000Z

    A microbial process is described for selective cleavage of organic C-S bonds which may be used for reducing the sulfur content of sulfur-containing organic carbonaceous materials. Microorganisms of Rhodococcus rhodochrous and Bacillus sphaericus have been found which have the ability of selective cleavage of organic C-S bonds. Particularly preferred microorganisms are Rhodococcus rhodochrous strain ATCC 53968 and Bacillus sphaericus strain ATCC 53969 and their derivatives.

  10. Storing Renewable Energy in Chemical Bonds

    ScienceCinema (OSTI)

    Helm, Monte; Bullock, Morris

    2014-06-13T23:59:59.000Z

    With nearly 7 billion people, the world's population is demanding more electricity every year. Improved technologies are bringing wind and solar power to our electrical grid. However, wind turbines and solar panels only work when the wind blows or the sun shines. PNNL scientists discuss catalysis approaches for storing and releasing energy on demand.

  11. Storing Renewable Energy in Chemical Bonds

    SciTech Connect (OSTI)

    Helm, Monte; Bullock, Morris

    2013-03-27T23:59:59.000Z

    With nearly 7 billion people, the world's population is demanding more electricity every year. Improved technologies are bringing wind and solar power to our electrical grid. However, wind turbines and solar panels only work when the wind blows or the sun shines. PNNL scientists discuss catalysis approaches for storing and releasing energy on demand.

  12. Bonded Bracket Assmebly for Frameless Solar Panels

    SciTech Connect (OSTI)

    Murray, Todd

    2013-01-30T23:59:59.000Z

    In February 2011 the US Department of Energy announced their new Sunshot Initiative. The Sunshot goal is to reduce the total cost of solar energy systems by about 75 percent before the end of the decade. The DOE estimated that a total installed cost of $1 per watt for photovoltaic systems would be equivalent to 6���¢/kilowatt hour (kWh) for energy available from the grid. The DOE also estimated that to meet the $1 per watt goal, PV module costs would need to be reduced to $.50 per watt, balance of systems costs would need to be reduced to $.40 per watt, and power electronic costs would need to reach $.10 per watt. To address the BOS balance of systems cost component of the $1 per watt goal, the DOE announced a funding opportunity called (BOS-X) Extreme Balance of System Hardware Cost Reductions. The DOE identified eight areas within the total BOS costs: 1) installation labor, 2) installation materials, 3) installation overhead and profit, 4) tracker, 5) permitting and commissioning, 6) site preparation, 7) land acquisition, 8) sales tax. The BOS-X funding announcement requested applications in four specific topics: Topic 1: Transformational Building Integrated Photovoltaic (BIPV) Modules Topic 2: Roof and Ground Mount Innovations Topic 3: Transformational Photovoltaic System Designs Topic 4: Development of New Wind Load Codes for PV Systems The application submitted by ARaymond Tinnerman reflected the requirements listed in Topic #2, Roof and Ground Mount Innovations. The goal of topic #2 was to develop technologies that would result in the extreme reduction of material and labor costs associated with applications that require physical connections and attachments to roof and ground mount structures. The topics researched in this project included component cost reduction, labor reduction, weight reduction, wiring innovations, and alternative material utilization. The project objectives included: 1) The development of an innovative quick snap bracket assembly that would be bonded to frameless PV modules for commercial rooftop installations. 2) The development of a composite pultruded rail to replace traditional racking materials. 3) In partnership with a roofing company, pilot the certification of a commercial roof to be solar panel compliant, eliminating the need for structural analysis and government oversight resulting in significantly decreased permitting costs. 4) Reduce the sum of all cost impacts in topic #2 from a baseline total of $2.05/watt to $.34/watt.

  13. Mercury stabilization in chemically bonded phosphate ceramics

    SciTech Connect (OSTI)

    Wagh, A. S.; Singh, D.; Jeong, S. Y.

    2000-04-04T23:59:59.000Z

    Mercury stabilization and solidification is a significant challenge for conventional stabilization technologies. This is because of the stringent regulatory limits on leaching of its stabilized products. In a conventional cement stabilization process, Hg is converted at high pH to its hydroxide, which is not a very insoluble compound; hence the preferred route for Hg sulfidation to convert it into insoluble cinnabar (HgS). Unfortunately, efficient formation of this compound is pH-dependent. At a high pH, one obtains a more soluble Hg sulfate, in a very low pH range, insufficient immobilization occurs because of the escape of hydrogen sulfide, while efficient formation of HgS occurs only in a moderately acidic region. Thus, the pH range of 4 to 8 is where stabilization with Chemically Bonded Phosphate Ceramics (CBPC) is carried out. This paper discusses the authors experience on bench-scale stabilization of various US Department of Energy (DOE) waste streams containing Hg in the CBPC process. This process was developed to treat DOE's mixed waste streams. It is a room-temperature-setting process based on an acid-base reaction between magnesium oxide and monopotassium phosphate solution that forms a dense ceramic within hours. For Hg stabilization, addition of a small amount (< 1 wt.%) of Na{sub 2}S or K{sub 2}S is sufficient in the binder composition. Here the Toxicity Characteristic Leaching Procedure (TCLP) results on CBPC waste forms of surrogate waste streams representing secondary Hg containing wastes such as combustion residues and Delphi DETOX{trademark} residues are presented. The results show that although the current limit on leaching of Hg is 0.2 mg/L, the results from the CBPC waste forms are at least one order lower than this stringent limit. Encouraged by these results on surrogate wastes, they treated actual low-level Hg-containing mixed waste from their facility at Idaho. TCLP results on this waste are presented here. The efficient stabilization in all these cases is attributed to chemical immobilization as both a sulfide (cinnabar) and a phosphate, followed by its physical encapsulation in a dense matrix of the ceramic.

  14. Hydrogen Bond Migration between Molecular Sites Observed with Ultrafast 2D IR Chemical Exchange Spectroscopy

    E-Print Network [OSTI]

    Fayer, Michael D.

    Hydrogen Bond Migration between Molecular Sites Observed with Ultrafast 2D IR Chemical ExchangeVed: January 12, 2010 Hydrogen-bonded complexes between phenol and phenylacetylene are studied using ultrafast hydrogen bonding acceptor sites (phenyl or acetylene) that compete for hydrogen bond donors in solution

  15. Thermal Performance and Reliability of Bonded Interfaces for Power Electronics Packaging Applications (Presentation)

    SciTech Connect (OSTI)

    Devoto, D.

    2013-07-01T23:59:59.000Z

    This presentation discusses the thermal performance and reliability of bonded interfaces for power electronics packaging applications.

  16. The C OH O hydrogen bond: A determinant of stability and specificity

    E-Print Network [OSTI]

    Senes, Alessandro

    recovered by hydro- gen bond formation, so hydrogen bonds provide a small or even unfavorable net energy hydro- gen bond has been unclear and its interaction energy has been believed to be small. Recently that apparent carbon hydro- gen bonds cluster frequently at glycine-, serine-, and threonine-rich packing

  17. Mechanical Study of Copper Bonded at Low Temperature using Spark Plasma Sintering Process

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    is approximatively 6.47 MPa [7]. J. W. Elmer & al [8] have presented a diffusion bonding of high purity copper using a conventional furnace. A series of diffusion bonds was done to determine the relationship between bond strengthMechanical Study of Copper Bonded at Low Temperature using Spark Plasma Sintering Process Bassem

  18. Highly Efficient Vertical Outgassing Channels for Robust, Void-Free, Low-Temperature Direct Wafer Bonding

    E-Print Network [OSTI]

    Bowers, John

    molecules diffusion at bonding interface to VOCs. Conventional anneal time of 12-18 hours required to bond Bonding Di Liang1 , Erik A. Lucero2 , John E. Bowers1 1 Department of Electrical and Computer Engineering wafer bonding is favored for dissimilar materials integration, particularly in III-V compound

  19. A new hydrogen-bonding potential for the design of proteinRNA interactions predicts specific

    E-Print Network [OSTI]

    Baker, David

    A new hydrogen-bonding potential for the design of protein­RNA interactions predicts specific-dependent hydrogen-bonding potential based on the statistical analysis of hydrogen-bonding geometries of hydrogen-bonding atom pairs at protein­ nucleic acid interfaces. A scoring function based on the hydrogen

  20. Einstein's Miraculous Year

    E-Print Network [OSTI]

    Vasant Natarajan; V Balakrishnan; N Mukunda

    2013-07-12T23:59:59.000Z

    With each passing year, the young Albert Einstein's achievements in physics in the year 1905 seem to be ever more miraculous. We describe why the centenary of this remarkable year is worthy of celebration.

  1. Effect of quantum nuclear motion on hydrogen bonding

    SciTech Connect (OSTI)

    McKenzie, Ross H., E-mail: r.mckenzie@uq.edu.au; Bekker, Christiaan [School of Mathematics and Physics, University of Queensland, Brisbane 4072 (Australia)] [School of Mathematics and Physics, University of Queensland, Brisbane 4072 (Australia); Athokpam, Bijyalaxmi; Ramesh, Sai G. [Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560 012 (India)] [Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560 012 (India)

    2014-05-07T23:59:59.000Z

    This work considers how the properties of hydrogen bonded complexes, X–H?Y, are modified by the quantum motion of the shared proton. Using a simple two-diabatic state model Hamiltonian, the analysis of the symmetric case, where the donor (X) and acceptor (Y) have the same proton affinity, is carried out. For quantitative comparisons, a parametrization specific to the O–H?O complexes is used. The vibrational energy levels of the one-dimensional ground state adiabatic potential of the model are used to make quantitative comparisons with a vast body of condensed phase data, spanning a donor-acceptor separation (R) range of about 2.4 ? 3.0 Ĺ, i.e., from strong to weak hydrogen bonds. The position of the proton (which determines the X–H bond length) and its longitudinal vibrational frequency, along with the isotope effects in both are described quantitatively. An analysis of the secondary geometric isotope effect, using a simple extension of the two-state model, yields an improved agreement of the predicted variation with R of frequency isotope effects. The role of bending modes is also considered: their quantum effects compete with those of the stretching mode for weak to moderate H-bond strengths. In spite of the economy in the parametrization of the model used, it offers key insights into the defining features of H-bonds, and semi-quantitatively captures several trends.

  2. Year of last Year of last

    E-Print Network [OSTI]

    Herring 2003 2002 Transboundary Resource Assessment Committee Monkfish Northern Monkfish 2003 2003FMP Stock Year of last assessment Year of last data used in last stock assessment Source document for stock assessment Atlantic Sea Scallop Atlantic Sea Scallop 2000 2000 Stock Assessment Workshop (SAW

  3. 1,2-CF bond activation of perfluoroarenes and alkylidene isomers of titanium. DFT analysis of the CeF bond activation pathway and rotation of the titanium

    E-Print Network [OSTI]

    Baik, Mu-Hyun

    1,2-CF bond activation of perfluoroarenes and alkylidene isomers of titanium. DFT analysis of the CeF bond activation pathway and rotation of the titanium alkylidene moiety José G. Andino, Hongjun Received in revised form 26 July 2011 Accepted 27 July 2011 Keywords: Alkylidene Titanium CeF bond

  4. Intramolecular Hydrogen Bonding in Disubstituted Ethanes. A Comparison of NH,,,O-and OH,,,O-Hydrogen Bonding through Conformational Analysis of 4-Amino-4-oxobutanoate

    E-Print Network [OSTI]

    Goddard III, William A.

    Intramolecular Hydrogen Bonding in Disubstituted Ethanes. A Comparison of NH,,,O- and OH,,,O- Hydrogen Bonding through Conformational Analysis of 4-Amino-4-oxobutanoate (succinamate) and Monohydrogen 1 of amide NH,,,O- and carboxyl OH,,,O- hydrogen bonds were investigated via conformational analysis

  5. The diffusion bonding of silicon carbide and boron carbide using refractory metals

    SciTech Connect (OSTI)

    Cockeram, B.V.

    1999-10-01T23:59:59.000Z

    Joining is an enabling technology for the application of structural ceramics at high temperatures. Metal foil diffusion bonding is a simple process for joining silicon carbide or boron carbide by solid-state, diffusive conversion of the metal foil into carbide and silicide compounds that produce bonding. Metal diffusion bonding trials were performed using thin foils (5 {micro}m to 100 {micro}m) of refractory metals (niobium, titanium, tungsten, and molybdenum) with plates of silicon carbide (both {alpha}-SiC and {beta}-SiC) or boron carbide that were lapped flat prior to bonding. The influence of bonding temperature, bonding pressure, and foil thickness on bond quality was determined from metallographic inspection of the bonds. The microstructure and phases in the joint region of the diffusion bonds were evaluated using SEM, microprobe, and AES analysis. The use of molybdenum foil appeared to result in the highest quality bond of the metal foils evaluated for the diffusion bonding of silicon carbide and boron carbide. Bonding pressure appeared to have little influence on bond quality. The use of a thinner metal foil improved the bond quality. The microstructure of the bond region produced with either the {alpha}-SiC and {beta}-SiC polytypes were similar.

  6. Rhodium-Catalyzed C-C Bond Formation via Heteroatom-Directed C-H Bond Activation

    SciTech Connect (OSTI)

    Colby, Denise; Bergman, Robert; Ellman, Jonathan

    2010-05-13T23:59:59.000Z

    Once considered the 'holy grail' of organometallic chemistry, synthetically useful reactions employing C-H bond activation have increasingly been developed and applied to natural product and drug synthesis over the past decade. The ubiquity and relative low cost of hydrocarbons makes C-H bond functionalization an attractive alternative to classical C-C bond forming reactions such as cross-coupling, which require organohalides and organometallic reagents. In addition to providing an atom economical alternative to standard cross - coupling strategies, C-H bond functionalization also reduces the production of toxic by-products, thereby contributing to the growing field of reactions with decreased environmental impact. In the area of C-C bond forming reactions that proceed via a C-H activation mechanism, rhodium catalysts stand out for their functional group tolerance and wide range of synthetic utility. Over the course of the last decade, many Rh-catalyzed methods for heteroatom-directed C-H bond functionalization have been reported and will be the focus of this review. Material appearing in the literature prior to 2001 has been reviewed previously and will only be introduced as background when necessary. The synthesis of complex molecules from relatively simple precursors has long been a goal for many organic chemists. The ability to selectively functionalize a molecule with minimal pre-activation can streamline syntheses and expand the opportunities to explore the utility of complex molecules in areas ranging from the pharmaceutical industry to materials science. Indeed, the issue of selectivity is paramount in the development of all C-H bond functionalization methods. Several groups have developed elegant approaches towards achieving selectivity in molecules that possess many sterically and electronically similar C-H bonds. Many of these approaches are discussed in detail in the accompanying articles in this special issue of Chemical Reviews. One approach that has seen widespread success involves the use of a proximal heteroatom that serves as a directing group for the selective functionalization of a specific C-H bond. In a survey of examples of heteroatom-directed Rh catalysis, two mechanistically distinct reaction pathways are revealed. In one case, the heteroatom acts as a chelator to bind the Rh catalyst, facilitating reactivity at a proximal site. In this case, the formation of a five-membered metallacycle provides a favorable driving force in inducing reactivity at the desired location. In the other case, the heteroatom initially coordinates the Rh catalyst and then acts to stabilize the formation of a metal-carbon bond at a proximal site. A true test of the utility of a synthetic method is in its application to the synthesis of natural products or complex molecules. Several groups have demonstrated the applicability of C-H bond functionalization reactions towards complex molecule synthesis. Target-oriented synthesis provides a platform to test the effectiveness of a method in unique chemical and steric environments. In this respect, Rh-catalyzed methods for C-H bond functionalization stand out, with several syntheses being described in the literature that utilize C-H bond functionalization in a key step. These syntheses are highlighted following the discussion of the method they employ.

  7. Metal-bonded, carbon fiber-reinforced composites

    DOE Patents [OSTI]

    Sastri, Suri A. (Lexington, MA); Pemsler, J. Paul (Lexington, MA); Cooke, Richard A. (Framingham, MA); Litchfield, John K. (Bedford, MA); Smith, Mark B. (Ipswich, MA)

    1996-01-01T23:59:59.000Z

    Metal bonded carbon fiber-reinforced composites are disclosed in which the metal and the composite are strongly bound by (1) providing a matrix-depleted zone in the composite of sufficient depth to provide a binding site for the metal to be bonded and then (2) infiltrating the metal into the matrix-free zone to fill a substantial portion of the zone and also provide a surface layer of metal, thereby forming a strong bond between the composite and the metal. The invention also includes the metal-bound composite itself, as well as the provision of a coating over the metal for high-temperature performance or for joining to other such composites or to other substrates.

  8. Metal-bonded, carbon fiber-reinforced composites

    DOE Patents [OSTI]

    Sastri, S.A.; Pemsler, J.P.; Cooke, R.A.; Litchfield, J.K.; Smith, M.B.

    1996-03-05T23:59:59.000Z

    Metal bonded carbon fiber-reinforced composites are disclosed in which the metal and the composite are strongly bound by (1) providing a matrix-depleted zone in the composite of sufficient depth to provide a binding site for the metal to be bonded and then (2) infiltrating the metal into the matrix-free zone to fill a substantial portion of the zone and also provide a surface layer of metal, thereby forming a strong bond between the composite and the metal. The invention also includes the metal-bound composite itself, as well as the provision of a coating over the metal for high-temperature performance or for joining to other such composites or to other substrates. 2 figs.

  9. Chemical strategies for die/wafer submicron alignment and bonding.

    SciTech Connect (OSTI)

    Martin, James Ellis; Baca, Alicia I.; Chu, Dahwey; Rohwer, Lauren Elizabeth Shea

    2010-09-01T23:59:59.000Z

    This late-start LDRD explores chemical strategies that will enable sub-micron alignment accuracy of dies and wafers by exploiting the interfacial energies of chemical ligands. We have micropatterned commensurate features, such as 2-d arrays of micron-sized gold lines on the die to be bonded. Each gold line is functionalized with alkanethiol ligands before the die are brought into contact. The ligand interfacial energy is minimized when the lines on the die are brought into registration, due to favorable interactions between the complementary ligand tails. After registration is achieved, standard bonding techniques are used to create precision permanent bonds. We have computed the alignment forces and torque between two surfaces patterned with arrays of lines or square pads to illustrate how best to maximize the tendency to align. We also discuss complex, aperiodic patterns such as rectilinear pad assemblies, concentric circles, and spirals that point the way towards extremely precise alignment.

  10. Strategic Petroleum Reserve annual report for calendar year 1998

    SciTech Connect (OSTI)

    NONE

    1998-12-31T23:59:59.000Z

    The Strategic Petroleum Reserve was established in 1975 as an emergency response to the 1973 Arab oil embargo. It is authorized by the Energy Policy and Conservation Act (EPCA), and by the comprehensive energy plans of all Administrations since 1975, in recognition of the long-term dependence of the US on imported crude oil and petroleum products. Section 165 of EPCA requires the Secretary of Energy to submit an Annual Report to the President and the Congress. On May 13, 1998, the Department published a Statement of Administration Policy which reaffirmed its commitment to maintain a Government-owned and controlled, centrally located Strategic Petroleum Reserve of crude oil. The Reserve is to be used solely for responding to the types of severe oil supply interruptions presently contemplated in EPCA. Over the past twenty years, the Reserve has grown as large as 592 million barrels--a peak reached in 1994. From 1994 to 1996, nearly 28 million barrels were sold to raise revenues for the U S Treasury. As of December 31, 1998, the crude oil inventory was 561,108,127 barrels which equated to 60 days of net oil imports during 1998. The US now relies on a combination of both the Reserve and private stocks to meet its oil storage obligations to the International Energy Agency.

  11. COMPARISON OF AIR AND DEUTERIUM ON PINCH WELD BOND APPEARANCE

    SciTech Connect (OSTI)

    Korinko, P

    2005-10-11T23:59:59.000Z

    The effect that air and deuterium internal atmospheres have on the pinch weld bond quality was evaluated by conducting a scoping study using type 304L stainless steel LF-7 test stems that were fabricated for an associated study. Welds were made under cool, yet nominal conditions to exacerbate the influence of the atmosphere. The bond quality of the welds was directly related to the internal atmosphere with the air atmosphere welds being of lower quality than the deuterium atmosphere welds for nominally identical welding conditions.

  12. The reduction of carbon-carbon multiple bond systems

    E-Print Network [OSTI]

    Ferguson, Donald Roy

    1965-01-01T23:59:59.000Z

    and Uses, " Reinhold Publishing Corporations New York, N. Y. & 1956, p. 309 the dicarbanion with carbon dioxide yields the di-sodium salt of 1, 1, 2, 4 2-tetraphenylsuccinic acid. If two atoms of an alkali metal add to the multiple bond of an al- kyne... acid. One mole of carbon dioxide reacts with III to form the indone. It was proposed on the basis of the foregoing evidence that alkali metals could be caused to add across an acetylenic bond of a molecule to form a vinylic dicarbanion. It was hoped...

  13. Draft Financial Operating Procedure Treasury Management

    E-Print Network [OSTI]

    Brierley, Andrew

    Management in the Public Services: Code of Practice (the Code), as described in Section 4 of that Code part of the annual review of the financial governance framework) to PARC on the adequacy

  14. SBA 504 Program (South Dakota)

    Broader source: Energy.gov [DOE]

    The SBA 504 Program offers long-tem, fixed rate financing (10-20 years) at reasonable rates comparable to long-term U.S. Treasury bonds. Typically the 504 loan has a 50-40-10 structure where fifty...

  15. Method of preparation of bonded polyimide fuel cell package

    DOE Patents [OSTI]

    Morse, Jeffrey D. (Martinez, CA); Jankowski, Alan (Livermore, CA); Graff, Robert T. (Modesto, CA); Bettencourt, Kerry (Dublin, CA)

    2011-04-26T23:59:59.000Z

    Described herein are processes for fabricating microfluidic fuel cell systems with embedded components in which micron-scale features are formed by bonding layers of DuPont Kapton.TM. polyimide laminate. A microfluidic fuel cell system fabricated using this process is also described.

  16. Advance Refundings of Municipal Bonds Columbia Business School

    E-Print Network [OSTI]

    Sadeh, Norman M.

    Advance Refundings of Municipal Bonds Andrew Ang Columbia Business School and NBER Richard C. Green of Vineer Bhansali, Trevor Harris, Tal Heppenstall, Andrew Kalotay, Kemp Lewis, Paul Luhmann, Matt of colleagues, especially Jennifer Carpenter, Dan Li, Norman Sch¨urhoff, and Chester Spatt, along with seminar

  17. Hydrogen Bonding Increases Packing Density in the Protein Interior

    E-Print Network [OSTI]

    Hydrogen Bonding Increases Packing Density in the Protein Interior David Schell,1,2 Jerry Tsai,1 J System Health Science Center, College Station, Texas 77843-1114 ABSTRACT The contribution of hydrogen to the stability, but experimental studies show that bury- ing polar groups, especially those that are hydrogen

  18. Water inertial reorientation: Hydrogen bond strength and the angular potential

    E-Print Network [OSTI]

    Fayer, Michael D.

    Water inertial reorientation: Hydrogen bond strength and the angular potential David E. Moilanen) The short-time orientational relaxation of water is studied by ultrafast infrared pump-probe spectroscopy with recent molecular dynamics simulations employing the simple point charge-extended water model at room

  19. Channel Bonding in Cognitive Radio Wireless Sensor Networks

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Channel Bonding in Cognitive Radio Wireless Sensor Networks Mubashir Husain Rehmani, St-mail: rehmani@univ-mlv.fr, lohier@univ-mlv.fr, rachedi@univ-mlv.fr Abstract--Recently, wireless sensor networks, Wireless Multimedia Sensor Networks (WMSNs) have lot of new potential applications in different domains

  20. Chemical bonding of hydrogen molecules to transition metal complexes

    SciTech Connect (OSTI)

    Kubas, G.J.

    1990-01-01T23:59:59.000Z

    The complex W(CO){sub 3}(PR{sub 3}){sub 2}(H{sub 2}) (CO = carbonyl; PR{sub 3} = organophosphine) was prepared and was found to be a stable crystalline solid under ambient conditions from which the hydrogen can be reversibly removed in vacuum or under an inert atmosphere. The weakly bonded H{sub 2} exchanges easily with D{sub 2}. This complex represents the first stable compound containing intermolecular interaction of a sigma-bond (H-H) with a metal. The primary interaction is reported to be donation of electron density from the H{sub 2} bonding electron pair to a vacant metal d-orbital. A series of complexes of molybdenum of the type Mo(CO)(H{sub 2})(R{sub 2}PCH{sub 2}CH{sub 2}PR{sub 2}){sub 2} were prepared by varying the organophosphine substitutent to demonstrate that it is possible to bond either dihydrogen or dihydride by adjusting the electron-donating properties of the co-ligands. Results of infrared and NMR spectroscopic studies are reported. 20 refs., 5 fig.

  1. Enantioselective nickel catalysis : exploiting activated C-H bonds

    E-Print Network [OSTI]

    Bencivenga, Nicholas Ernest

    2012-01-01T23:59:59.000Z

    A method for the nickel-catalyzed cross-coupling between benzoxazole and secondary halides was explored. This method was to make use of the activated C-H bond found in benzoxazole at the 2-position to generate the nucleophilic ...

  2. Bonded polyimide fuel cell package and method thereof

    DOE Patents [OSTI]

    Morse, Jeffrey D.; Jankowski, Alan; Graff, Robert T.; Bettencourt, Kerry

    2005-11-01T23:59:59.000Z

    Described herein are processes for fabricating microfluidic fuel cell systems with embedded components in which micron-scale features are formed by bonding layers of DuPont Kapton.TM. polyimide laminate. A microfluidic fuel cell system fabricated using this process is also described.

  3. Diffusion limited cluster aggregation with irreversible flexible bonds

    E-Print Network [OSTI]

    Sujin Babu; Jean-Christophe Gimel; Taco Nicolai

    2008-01-29T23:59:59.000Z

    Irreversible diffusion limited cluster aggregation (DLCA) of hard spheres was simulated using Brownian cluster dynamics. Bound spheres were allowed to move freely within a specified range, but no bond breaking was allowed. The structure and size distribution of the clusters was investigated before gelation. The pair correlation function and the static structure factor of the gels were determined as a function of the volume fraction and time. Bond flexibility led to local densification of the clusters and the gels, with a certain degree of order. At low volume fractions densification of the clusters occurred during their growth, but at higher volume fractions it occurred mainly after gelation. At very low volume fractions, the large scale structure (fractal dimension), size distribution and growth kinetics of the clusters was found to be close to that known for DLCA with rigid bonds. Restructuring of the gels continued for long times, indicating that aging processes in systems with strong attraction do not necessarily involve bond breaking. The mean square displacement of particles in the gels was determined. It is shown to be highly heterogeneous and to increase with decreasing volume fraction.

  4. WHAT'S GRAPHENE? Mono or few layers of sp2 bonded

    E-Print Network [OSTI]

    Mellor-Crummey, John

    WHAT'S GRAPHENE? · Mono or few layers of sp2 bonded carbon atoms in a honeycomb lattice 105cm2/Vs at RT. 1 Due to its unique transport properties, graphene is suitable for implementation sampling (EOS) timeresolved spectroscopy to optically pump and THz probe exfoliated graphene ribbons (GR

  5. A Single Disulfide Bond Differentiates Aggregation Pathways of 2-Microglobulin

    E-Print Network [OSTI]

    Dokholyan, Nikolay V.

    simulation; aggregation; domain swapping*Corresponding author Introduction Amyloid fibrils are insolubleA Single Disulfide Bond Differentiates Aggregation Pathways of ß2-Microglobulin Yiwen Chen1 at Chapel Hill Chapel Hill, NC 27599, USA Deposition of wild-type ß2-microglobulin (ß2m) into amyloid

  6. Bonded labour The Dalits of Nepal are a marginalised

    E-Print Network [OSTI]

    Richner, Heinz

    Bonded labour The Dalits of Nepal are a marginalised group of people who have suffered systematic that, while illegal, is still widespread in remote rural areas of Nepal. To meet their basic needs in their neighbour- hood. Referred to in Nepal as Haliya/ Haruwa and Charuwa, they have to plough the landlords' land

  7. alteredintramolecular hydrogen-bonding pattern: Topics by E-print...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alteredintramolecular hydrogen-bonding pattern First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1...

  8. Comparing systemic risk in European government bonds and national indices

    E-Print Network [OSTI]

    Jurczyk, Jan; Morgenstern, Ingo

    2015-01-01T23:59:59.000Z

    It has been shown, that the systemic risk contained in financial markets can be indicated by the change of cross-correlation between different indices and stocks. This change is tracked by using principle component analysis (PCA). We use this technique to investigate the systemic risk contained in European economy by comparing government long term bonds and indices.

  9. Secretary Moniz's First Year

    Broader source: Energy.gov [DOE]

    We're looking back at some of the biggest moments from Energy Secretary Ernest Moniz's first year in office.

  10. Cu-Cu direct bonding achieved by surface method at room temperature

    SciTech Connect (OSTI)

    Utsumi, Jun [Advanced Technology Research Center, Mitsubishi Heavy Industries, Ltd., 1-8-1 Sachiura, Kanazawa-ku, Yokohama 236-8515 (Japan); Ichiyanagi, Yuko, E-mail: yuko@ynu.ac.jp [Department of Physics, Graduate School of Engineering, Yokohama National University, Tokiwadai, Hodogaya, Yokohama 240-8501 (Japan)

    2014-02-20T23:59:59.000Z

    The metal bonding is a key technology in the processes for the microelectromechanical systems (MEMS) devices and the semiconductor devices to improve functionality and higher density integration. Strong adhesion between surfaces at the atomic level is crucial; however, it is difficult to achieve close bonding in such a system. Cu films were deposited on Si substrates by vacuum deposition, and then, two Cu films were bonded directly by means of surface activated bonding (SAB) at room temperature. The two Cu films, with the surface roughness Ra about 1.3nm, were bonded by using SAB at room temperature, however, the bonding strength was very weak in this method. In order to improve the bonding strength between the Cu films, samples were annealed at low temperatures, between 323 and 473 K, in air. As the result, the Cu-Cu bonding strength was 10 times higher than that of the original samples without annealing.

  11. Hydrogen Bonding, H-D Exchange, and Molecular Mobility in Thin...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bonding, H-D Exchange, and Molecular Mobility in Thin Water Films on TiO2(110). Hydrogen Bonding, H-D Exchange, and Molecular Mobility in Thin Water Films on TiO2(110). Abstract:...

  12. Imaging Adsorbate O-H Bond Cleavage: Methanol on TiO2(110). ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    O-H Bond Cleavage: Methanol on TiO2(110). Abstract: We investigated methanol adsorption and dissociation on bridge-bonded oxygen vacancies of TiO2(110) (1×1) surface...

  13. Chemical Bonding In Amorphous Si Coated-carbon Nanotube As Anodes...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bonding In Amorphous Si Coated-carbon Nanotube As Anodes For Li ion Batteries: A XANES Study. Chemical Bonding In Amorphous Si Coated-carbon Nanotube As Anodes For Li ion...

  14. Dynamical bond cooperativity enables very fast and strong binding between sliding surfaces

    E-Print Network [OSTI]

    Trřmborg, Jřrgen Kjoshagen

    2015-01-01T23:59:59.000Z

    Cooperative binding affects many processes in biology, but it is commonly addressed only in equilibrium. In this work we explore dynamical cooperativity in driven systems, where the cooperation occurs because some of the bonds change the dynamical response of the system to a regime where the other bonds become active. To investigate such cooperativity we study the frictional binding between two flow driven surfaces that interact through a large population of activated bonds. In particular, we study systems where each bond can have two different modes: one mode corresponds to a fast forming yet weak bond, and the other is a strong yet slow forming bond. We find considerable cooperativity between both types of bonds. Under some conditions the system behaves as if there were only one binding mode, corresponding to a strong and fast forming bond. Our results may have important implications on the friction and adhesion between sliding surfaces containing complementary binding motifs, such as in the case of cells b...

  15. The contribution of tyrosine water=hydrogen bonds to protein stability

    E-Print Network [OSTI]

    Bechert, Charles John

    2013-02-22T23:59:59.000Z

    studied: RNase Sa (Tyr 30, 49, 55, 81 ? v Phc). Studying the RNasc Sa mutanls will allow us to compare the importance of intramolccular hydrogen bonds involving other groups within I. he protein versus intermolecular hydrogen bonds involving buried HTO...

  16. New method to diffusion bond superalloys A. A. Shirzadi and E. R. Wallach

    E-Print Network [OSTI]

    Cambridge, University of

    carried out in this eld. Despite recent developments in the fusion welding of superalloys using laser, such as brazing and transient liquid phase (TLP) diffusion bonding, normally require long bonding times and

  17. Facile Thermal W-W Bond Homolysis in the N-Heterocyclic Carbene...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thermal W-W Bond Homolysis in the N-Heterocyclic Carbene-Containing Tungsten Dimer CpW(CO)2(IMe)2. Facile Thermal W-W Bond Homolysis in the N-Heterocyclic Carbene-Containing...

  18. 2-Propanol Dehydration on TiO2(110): The Effect of Bridge-Bonded...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2-Propanol Dehydration on TiO2(110): The Effect of Bridge-Bonded Oxygen Vacancy Blocking. 2-Propanol Dehydration on TiO2(110): The Effect of Bridge-Bonded Oxygen Vacancy Blocking....

  19. Role of interatomic bonding in the mechanical anisotropy and interlayer cohesion of CSH crystals

    SciTech Connect (OSTI)

    Dharmawardhana, C.C. [Department of Physics and Astronomy, University of Missouri—Kansas City, Kansas City, MO 64110 (United States)] [Department of Physics and Astronomy, University of Missouri—Kansas City, Kansas City, MO 64110 (United States); Misra, A. [Department of Civil, Environmental, and Architectural Engineering, University of Kansas, Lawrence, KS 66045 (United States)] [Department of Civil, Environmental, and Architectural Engineering, University of Kansas, Lawrence, KS 66045 (United States); Aryal, S.; Rulis, P. [Department of Physics and Astronomy, University of Missouri—Kansas City, Kansas City, MO 64110 (United States)] [Department of Physics and Astronomy, University of Missouri—Kansas City, Kansas City, MO 64110 (United States); Ching, W.Y., E-mail: ccdxz8@mail.umkc.edu [Department of Physics and Astronomy, University of Missouri—Kansas City, Kansas City, MO 64110 (United States)

    2013-10-15T23:59:59.000Z

    Atomic scale properties of calcium silicate hydrate (CSH), the main binding phase of hardened Portland cement, are not well understood. Over a century of intense research has identified almost 50 different crystalline CSH minerals which are mainly categorized by their Ca/Si ratio. The electronic structure and interatomic bonding in four major CSH crystalline phases with structures close to those found in hardened cement are investigated via ab initio methods. Our result reveals the critical role of hydrogen bonding and importance of specifying precise locations for water molecules. Quantitative analysis of contributions from different bond types to the overall cohesion shows that while the Si-O covalent bonds dominate, the hydrogen bonding and Ca-O bonding are also very significant. Calculated results reveal the correlation between bond topology and interlayer cohesion. The overall bond order density (BOD) is found to be a more critical measure than the Ca/Si ratio in classifying different CSH crystals.

  20. Performance and Reliability of Bonded Interfaces for High-Temperature Packaging (Presentation)

    SciTech Connect (OSTI)

    Devoto, D.

    2014-06-01T23:59:59.000Z

    This presentation reviews the status of the performance and reliability of bonded interfaces for high-temperature packaging.

  1. Ceramic-Metal Bonding Research in Japan japanese metals laboratories are becoming materials

    E-Print Network [OSTI]

    Eagar, Thomas W.

    bonding (Fig. 1), plasma spraying, brazing, or laser processing. In the Department of Weld1ng Engineering

  2. Mixed valency and electronic structure in self-assembled monolayers, self-exchange, and hydrogen bonded assemblies

    E-Print Network [OSTI]

    Goeltz, John Christopher

    2011-01-01T23:59:59.000Z

    P. ”Mixed valency across hydrogen bonds” J. Am. Chem. Soc.6 Mixed valency across hydrogen bonds: a more completeMixed valency across hydrogen bonds,” by John C. Goeltz and

  3. Annual Report Fiscal Year 2013

    E-Print Network [OSTI]

    Year in Review.............................................................. 8 Academic Accomplishments

  4. Hydrogen Bond Dissociation and Reformation in Methanol Oligomers Following Hydroxyl Stretch Relaxation

    E-Print Network [OSTI]

    Fayer, Michael D.

    Hydrogen Bond Dissociation and Reformation in Methanol Oligomers Following Hydroxyl Stretch, 2002 Vibrational relaxation and hydrogen bond dynamics in methanol-d dissolved in CCl4 have been-d molecules both accepting and donating hydrogen bonds at 2500 cm-1 . Following vibrational relaxation

  5. Hydrogen bond dynamics in the active site of photoactive yellow protein

    E-Print Network [OSTI]

    Herschlag, Dan

    Hydrogen bond dynamics in the active site of photoactive yellow protein Paul A. Sigala, Mark A for review February 5, 2009) Hydrogen bonds play major roles in biological structure and function. Nonetheless, hydrogen-bonded protons are not typically observed by X-ray crystallography, and most structural

  6. Hydrogen bond breaking probed with multidimensional stimulated vibrational echo correlation spectroscopy

    E-Print Network [OSTI]

    Fayer, Michael D.

    Hydrogen bond breaking probed with multidimensional stimulated vibrational echo correlation September 2003 Hydrogen bond population dynamics are extricated with exceptional detail using ultrafast ( 50 of methanol­OD oligomers in CCl4 . Hydrogen bond breaking makes it possible to acquire data for times much

  7. The Hydrogen Bonding of Cytosinewith Guanine:Calorimetric and`H-NMR Analysis

    E-Print Network [OSTI]

    Williams, Loren

    The Hydrogen Bonding of Cytosinewith Guanine:Calorimetric and`H-NMR Analysis of the Molecular of hydrogen-bondformation between guanine (G) and cytusine (C) in o-dichloro- benzene and in chloroformat 25°C forming hydrogen bonds. Consequently, hydrogen-bond formation in our system is primarily between the bases

  8. Hydrogen bond dynamics in membrane protein function Ana-Nicoleta Bondar a,

    E-Print Network [OSTI]

    White, Stephen

    Review Hydrogen bond dynamics in membrane protein function Ana-Nicoleta Bondar a, , Stephen H 30 November 2011 Available online 8 December 2011 Keywords: Membrane protein structure Hydrogen bond Membrane protein dynamics Lipid­protein interactions Changes in inter-helical hydrogen bonding

  9. Low Temperature Transient Liquid Phase Bonding of Ti6AI4V

    E-Print Network [OSTI]

    Eagar, Thomas W.

    bonds by intermetallic formation and subsequent diffusion annealing, but are limited to temperatures above 87s·c. Solid state activated diffusion bonding using sputtered copper intcrlayers will form joints temperature [1,2]. 1LP bonding of titanium has been used to produce aerospace components as descnoed by Norris

  10. Bonding is carried out by building up Quartz Wax on the sample holder to

    E-Print Network [OSTI]

    Smith, Tanya M.

    Bonding is carried out by building up Quartz Wax on the sample holder to support and bond the tooth that the Quartz Wax should cover as much of the sample face as possible to ensure a strong bond. Application Note Tooth Wax layer Figure 1 Sample holder Tooth Thin Section #12;B. Cutting - SIngle Selection Figure 2

  11. Correlation Analysis of Chemical Bonds (CACB) II: Quantum Mechanical Operators for Classical Chemical Concepts

    E-Print Network [OSTI]

    Goddard III, William A.

    crossing in reactions still lags far behind. Theoretical approaches to extracting the underlying chemicalCorrelation Analysis of Chemical Bonds (CACB) II: Quantum Mechanical Operators for Classical of the statistical covariance of the previous operator. Here the bonds correlation relates to bond exchange processes

  12. Information-Based Trading in the Junk Bond Market Department of Applied Economics and Management

    E-Print Network [OSTI]

    Kearns, Michael

    Information-Based Trading in the Junk Bond Market Xing Zhou Department of Applied Economics-based trading takes place in the high-yield corporate bond market, and how firm-specific information flow across that current corporate bond returns have explanatory power for future stock price changes. This implies

  13. TRANSIENT UQUID PHASE BONDING PROCESSES W. D. MacDonald and T.W. Eagar

    E-Print Network [OSTI]

    Eagar, Thomas W.

    . In this article, the term TLP \\viii apply to those bonding processes which rely on solid state diffusion to drive) ) ) .. ' TRANSIENT UQUID PHASE BONDING PROCESSES W. D. MacDonald and T.W. Eagar Department Transient liquid phase (TLP) bonding is an ancient process that has received increased attention in recent

  14. Silver diffusion bonding and layer transfer of lithium niobate to silicon Kenneth Diest,a

    E-Print Network [OSTI]

    Atwater, Harry

    Silver diffusion bonding and layer transfer of lithium niobate to silicon Kenneth Diest,a Melissa J July 2008; accepted 8 August 2008; published online 5 September 2008 A diffusion bonding method has, and upon heating, a diffusion bond was formed. Transmission electron microscopy confirms the interface

  15. Influence of silicon dangling bonds on germanium thermal diffusion within R. S. Cai,2

    E-Print Network [OSTI]

    Influence of silicon dangling bonds on germanium thermal diffusion within SiO2 glass D. Barba,1 R online 17 March 2014) We study the influence of silicon dangling bonds on germanium thermal diffusion of several orders of magnitudes.12,16­18 This may suggest that Si dangling bonds can affect the diffusion

  16. Particle/substrate interaction in the cold-spray bonding process

    E-Print Network [OSTI]

    Grujicic, Mica

    , atomic inter-diffusion is not expected to play a significant role in particle/substrate bonding. This canC2 148 9 Particle/substrate interaction in the cold-spray bonding process M. GRUJICIC, Clemson in this chapter to the problem of particle/substrate interactions and bonding during cold spray. The actual

  17. Electric charge trapping, residual stresses and properties of ceramics after metal/ceramics bonding

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    and diffusion of metallic species in the ceramics, during the bonding process. Keywords: Joining; ToughnessElectric charge trapping, residual stresses and properties of ceramics after metal/ceramics bonding applications is rapidly increasing. Most of these applications require the use of ceramics bonded with metal

  18. Low Temperature Transient Liquid Phase (LTTLP) Bonding for Au/Cu

    E-Print Network [OSTI]

    Eagar, Thomas W.

    of Technology, Cambridge, MA 02139 TheLow Temperature TransientLiquidPhase Diffusion Bonding (LTTLP) process has) ) M. M. Hou Low Temperature Transient Liquid Phase (LTTLP) Bonding for Au/Cu and Cu been bonded to copper heatsink.s at temperatures less than 160"C, using /n-Sn eutectic solders. After

  19. Simultaneous Bayesian reconstruction of diffusivity and bond potentials using path integrals

    E-Print Network [OSTI]

    Levine, Alex J.

    Simultaneous Bayesian reconstruction of diffusivity and bond potentials using path integrals Joshua requires fewer data and allows simultaneous inference of both complex bond potentials and diffusivity spectroscopy (DFS) has been used to distort bonds. The resulting responses, in the form of rupture forces, work

  20. The time reversed elastic nonlinearity diagnostic applied to evaluation of diffusion bonds

    E-Print Network [OSTI]

    The time reversed elastic nonlinearity diagnostic applied to evaluation of diffusion bonds T. J based nondestructive evaluation techniques has begun. Here, diffusion bonded metal disks containing and impulse responses to perform TR experiments in thin h 5 mm, d 5 cm diffusion bonded disks, in order

  1. Ionwater hydrogen-bond switching observed with 2D IR vibrational echo chemical

    E-Print Network [OSTI]

    Fayer, Michael D.

    Ion­water hydrogen-bond switching observed with 2D IR vibrational echo chemical exchange for review November 8, 2008) The exchange of water hydroxyl hydrogen bonds between anions and water oxygens of anion­ water hydroxyl hydrogen bond switching under thermal equilib- rium conditions as Taw 7 1 ps. Pump

  2. Extent of Hydrogen-Bond Protection in Folded Proteins: A Constraint on Packing Architectures

    E-Print Network [OSTI]

    Berry, R. Stephen

    Extent of Hydrogen-Bond Protection in Folded Proteins: A Constraint on Packing Architectures Ariel structuring and ultimately exclusion of water by hydrophobes surrounding backbone hydrogen bonds turn hydrophobes yields an optimal hydrogen-bond stabilization. This motif is shown to be nearly ubiquitous

  3. Ligand Binding to the Pregnane X Receptor by Geometric Matching of Hydrogen Bonds

    E-Print Network [OSTI]

    North Carolina at Chapel Hill, University of

    space. Hydrogen bonds have been used in FlexX [3] as part of a more complete energy function. Our conformations to PXR based on hydrogen bond geometry and use them as a starting point for ranking ligands aspect of the energy function, the hydrogen bonds, in order to identify the discriminating factor

  4. Native Hydrogen Bonds in a Molten Globule: The Apoflavodoxin Thermal Intermediate

    E-Print Network [OSTI]

    Sancho, Javier

    Native Hydrogen Bonds in a Molten Globule: The Apoflavodoxin Thermal Intermediate MarőÂa P. IruÂn1 in surface- exposed hydrogen bonds connecting secondary-structure elements in the native protein. All hydrogen bonds analysed are formed in the molten globule intermediate, either with native strength

  5. A CH O Hydrogen Bond Stabilized Polypeptide Chain Reversal Motif at the C Terminus of Helices

    E-Print Network [OSTI]

    Babu, M. Madan

    A C­H· · ·O Hydrogen Bond Stabilized Polypeptide Chain Reversal Motif at the C Terminus of Helices of Science Bangalore 560012, India The serendipitous observation of a C­H· · ·O hydrogen bond mediated­N hydrogen bond involving the side- chain of residue T 2 4 and the N­H group of residue T ţ 3. In as many

  6. Bonding topologies in diamondlike amorphous-carbon films

    SciTech Connect (OSTI)

    SIEGAL,MICHAEL P.; PROVENCIO,PAULA P.; TALLANT,DAVID R.; SIMPSON,REGINA L.; KLEINSORGE,B.; MILNE,W.I.

    2000-01-27T23:59:59.000Z

    The carbon ion energy used during filtered cathodic vacuum arc deposition determines the bonding topologies of amorphous-carbon (a-C) films. Regions of relatively low density occur near the substrate/film and film/surface interfaces and their thicknesses increase with increasing deposition energy. The ion subplantation growth results in mass density gradients in the bulk portion of a-C in the growth direction; density decreases with distance from the substrate for films grown using ion energies < 60 eV and increases for films grown using ion energies > 160 eV. Films grown between these energies are the most diamondlike with relatively uniform bulk density and the highest optical transparencies. Bonding topologies evolve with increasing growth energy consistent with the propagation of subplanted carbon ions inducing a partial transformation of 4-fold to 3-fold coordinated carbon atoms.

  7. Wafer bonded virtual substrate and method for forming the same

    DOE Patents [OSTI]

    Atwater, Jr., Harry A. (So. Pasadena, CA); Zahler, James M. (Pasadena, CA); Morral, Anna Fontcuberta i (Paris, FR)

    2007-07-03T23:59:59.000Z

    A method of forming a virtual substrate comprised of an optoelectronic device substrate and handle substrate comprises the steps of initiating bonding of the device substrate to the handle substrate, improving or increasing the mechanical strength of the device and handle substrates, and thinning the device substrate to leave a single-crystal film on the virtual substrate such as by exfoliation of a device film from the device substrate. The handle substrate is typically Si or other inexpensive common substrate material, while the optoelectronic device substrate is formed of more expensive and specialized electro-optic material. Using the methodology of the invention a wide variety of thin film electro-optic materials of high quality can be bonded to inexpensive substrates which serve as the mechanical support for an optoelectronic device layer fabricated in the thin film electro-optic material.

  8. Characterization of Fuel-Cladding Bond Strength Using Laser Shock

    SciTech Connect (OSTI)

    James A. Smith; David L. Cottle; Barry H. Rabin

    2014-04-01T23:59:59.000Z

    This paper describes new laser-based capabilities for characterization of fuel-cladding bond strength in nuclear fuels, and presents preliminary results obtained from studies on as-fabricated monolithic fuel consisting of uranium-10 wt.% molybdenum alloys clad in 6061 aluminum by hot isostatic pressing. Two complementary experimental methods are employed, laser-shock testing and laser-ultrasonic imaging. Measurements are spatially localized, non-contacting and require minimum specimen preparation, and are therefore ideally suited for applications involving radioactive materials, including irradiated materials. The theoretical principles and experimental approaches employed in characterization of nuclear fuel plates are described. The ability to measure layer thicknesses, elastic properties of the constituents, and the location and nature of laser-shock induced debonds is demonstrated, and preliminary bond strength measurement results are discussed.

  9. Integrated optical MEMS using through-wafer vias and bump-bonding.

    SciTech Connect (OSTI)

    McCormick, Frederick Bossert; Frederick, Scott K.

    2008-01-01T23:59:59.000Z

    This LDRD began as a three year program to integrate through-wafer vias, micro-mirrors and control electronics with high-voltage capability to yield a 64 by 64 array of individually controllable micro-mirrors on 125 or 250 micron pitch with piston, tip and tilt movement. The effort was a mix of R&D and application. Care was taken to create SUMMiT{trademark} (Sandia's ultraplanar, multilevel MEMS technology) compatible via and mirror processes, and the ultimate goal was to mate this MEMS fabrication product to a complementary metal-oxide semiconductor (CMOS) electronics substrate. Significant progress was made on the via and mirror fabrication and design, the attach process development as well as the electronics high voltage (30 volt) and control designs. After approximately 22 months, the program was ready to proceed with fabrication and integration of the electronics, final mirror array, and through wafer vias to create a high resolution OMEMS array with individual mirror electronic control. At this point, however, mission alignment and budget constraints reduced the last year program funding and redirected the program to help support the through-silicon via work in the Hyper-Temporal Sensors (HTS) Grand Challenge (GC) LDRD. Several months of investigation and discussion with the HTS team resulted in a revised plan for the remaining 10 months of the program. We planned to build a capability in finer-pitched via fabrication on thinned substrates along with metallization schemes and bonding techniques for very large arrays of high density interconnects (up to 2000 x 2000 vias). Through this program, Sandia was able to build capability in several different conductive through wafer via processes using internal and external resources, MEMS mirror design and fabrication, various bonding techniques for arrayed substrates, and arrayed electronics control design with high voltage capability.

  10. Fluorinated diamond particles bonded in a filled fluorocarbon resin matrix

    DOE Patents [OSTI]

    Taylor, G.W.; Roybal, H.E.

    1983-11-14T23:59:59.000Z

    A method of producing fluorinated diamond particles bonded in a filled fluorocarbon resin matrix. Simple hot pressing techniques permit the formation of such matrices from which diamond impregnated grinding tools and other articles of manufacture can be produced. Teflon fluorocarbon resins filled with Al/sub 2/O/sub 3/ yield grinding tools with substantially improved work-to-wear ratios over grinding wheels known in the art.

  11. Understanding mechanisms for C-H bond activation

    E-Print Network [OSTI]

    Vastine, Benjamin Alan

    2009-05-15T23:59:59.000Z

    is unclear as electrophilic and oxidative addition / reductive elimination (OA/RE) pathways have been proposed, and the research into this problem and other related aspects of this chemistry have been extensively considered in several books 18 and reviews... been proposed that lie between the two classic mechanisms that were discussed above; Lin has recently reviewed the current work in this field. 41 Webster and coworkers proposed metal-assisted ?-bond metathesis (MA?BM), 42 Lin and coworkers...

  12. Oxford Area Community School District (Michigan) Bonds Case Study

    Broader source: Energy.gov [DOE]

    Michigan’s Oxford Area Community School District entered into an energy savings performance contract and issued limited tax general obligation bonds to fund the up-front costs of almost $3 million of energy-related improvements. Case study is excerpted from Financing Energy Upgrades for K-12 School Districts: A Guide to Tapping into Funding for Energy Efficiency and Renewable Energy Improvements. Author: Merrian Borgeson and Mark Zimring

  13. Compacting Plastic-Bonded Explosive Molding Powders to Dense Solids

    SciTech Connect (OSTI)

    B. Olinger

    2005-04-15T23:59:59.000Z

    Dense solid high explosives are made by compacting plastic-bonded explosive molding powders with high pressures and temperatures for extended periods of time. The density is influenced by manufacturing processes of the powders, compaction temperature, the magnitude of compaction pressure, pressure duration, and number of repeated applications of pressure. The internal density variation of compacted explosives depends on method of compaction and the material being compacted.

  14. Fluorinated diamond particles bonded in a filled fluorocarbon resin matrix

    DOE Patents [OSTI]

    Taylor, Gene W. (Los Alamos, NM); Roybal, Herman E. (Santa Fe, NM)

    1985-01-01T23:59:59.000Z

    A method of producing fluorinated diamond particles bonded in a filled fluorocarbon resin matrix. Simple hot pressing techniques permit the formation of such matrices from which diamond impregnated grinding tools and other articles of manufacture can be produced. Teflon fluorocarbon resins filled with Al.sub.2 O.sub.3 yield grinding tools with substantially improved work-to-wear ratios over grinding wheels known in the art.

  15. Molecular dynamics of gas phase hydrogen-bonded complexes

    E-Print Network [OSTI]

    Wofford, Billy Alan

    1987-01-01T23:59:59.000Z

    . These analyses have permitted the calculation of an approximate stretching harmonic force field for the hydrogen-bound heterodimer HCN---HF. In addition, a new technique is developed to determine both the ground state and equilibrium dissociation energies... OF FIGURES. CHAPTER I. INTRODUCTION. CHAPTER II. MOLECULAR DYNAMICS IN HYDROGEN-BONDED INTERACTIONS: A PRELIMINARY EXPERIMENTALLY DETERMINED HARMONIC STRETCHING FORCE FIELD FOR HCN---HF. Introduction. Experimental Calculations. 10 Discussion. 19...

  16. Cold bond agglomeration of waste oxides for recycling

    SciTech Connect (OSTI)

    D`Alessio, G.; Lu, W.K. [McMaster Univ., Hamilton, Ontario (Canada). Dept. of Materials Science and Engineering

    1996-12-31T23:59:59.000Z

    Recycling of waste oxides has been an on-going challenge for integrated steel plants. The majority of these waste oxides are collected from the cleaning systems of ironmaking and steelmaking processes, and are usually in the form of fine particulates and slurries. In most cases, these waste materials are contaminated by oils and heavy metals and often require treatment at a considerable expense prior to landfill disposal. This contamination also limits the re-use or recycling potential of these oxides as secondary resources of reliable quality. However, recycling of some selected wastes in blast furnaces or steelmaking vessels is possible, but first requires agglomeration of the fine particulate by such methods as cold bond briquetting. Cold bond briquetting technology provides both mechanical compacting and bonding (with appropriate binders) of the particulates. This method of recycling has the potential to be economically viable and environmentally sustainable. The nature of the present study is cold bond briquetting of iron ore pellet fines with a molasses-cement-H{sub 2}O binder for recycling in a blast furnace. The inclusion of molasses is for its contribution to the green strength of briquettes. During the curing stage, significant gains in strength may be credited to molasses in the presence of cement. The interactions of cement (and its substitutes), water and molasses and their effects on the properties of the agglomerates during and after various curing conditions were investigated. Tensile strengths of briquettes made in the laboratory and subjected to experimental conditions which simulated the top part of a blast furnace shaft were also examined.

  17. Algorithm for anisotropic diffusion in hydrogen-bonded networks

    E-Print Network [OSTI]

    Edoardo Milotti

    2007-04-04T23:59:59.000Z

    In this paper I describe a specialized algorithm for anisotropic diffusion determined by a field of transition rates. The algorithm can be used to describe some interesting forms of diffusion that occur in the study of proton motion in a network of hydrogen bonds. The algorithm produces data that require a nonstandard method of spectral analysis which is also developed here. Finally, I apply the algorithm to a simple specific example.

  18. Quantum Confinement in Hydrogen Bond of DNA and RNA

    E-Print Network [OSTI]

    da Silva dos Santos; Elso Drigo Filho; Regina Maria Ricotta

    2015-02-09T23:59:59.000Z

    The hydrogen bond is a fundamental ingredient to stabilize the DNA and RNA macromolecules. The main contribution of this work is to describe quantitatively this interaction as a consequence of the quantum confinement of the hydrogen. The results for the free and confined system are compared with experimental data. The formalism to compute the energy gap of the vibration motion used to identify the spectrum lines is the Variational Method allied to Supersymmetric Quantum Mechanics.

  19. Quantum Confinement in Hydrogen Bond of DNA and RNA

    E-Print Network [OSTI]

    Santos, da Silva dos; Ricotta, Regina Maria

    2015-01-01T23:59:59.000Z

    The hydrogen bond is a fundamental ingredient to stabilize the DNA and RNA macromolecules. The main contribution of this work is to describe quantitatively this interaction as a consequence of the quantum confinement of the hydrogen. The results for the free and confined system are compared with experimental data. The formalism to compute the energy gap of the vibration motion used to identify the spectrum lines is the Variational Method allied to Supersymmetric Quantum Mechanics.

  20. Calendar Year 1999

    Broader source: Energy.gov (indexed) [DOE]

    > Year1999NEFINA1.pdf" class"">Inspection Report: INS-O-00-02

  1. HPSS Yearly Network Traffic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    growth in network traffic to storage over the years. Network Traffic Growth Network Distribution 2010 Network Distribution 2010 Network Distribution 2009 Network Distribution...

  2. Vacuum fusion bonded glass plates having microstructures thereon

    DOE Patents [OSTI]

    Swierkowski, Steve P. (Livermore, CA); Davidson, James C. (Livermore, CA); Balch, Joseph W. (Livermore, CA)

    2001-01-01T23:59:59.000Z

    An improved apparatus and method for vacuum fusion bonding of large, patterned glass plates. One or both glass plates are patterned with etched features such as microstructure capillaries and a vacuum pumpout moat, with one plate having at least one hole therethrough for communication with a vacuum pumpout fixture. High accuracy alignment of the plates is accomplished by a temporary clamping fixture until the start of the fusion bonding heat cycle. A complete, void-free fusion bond of seamless, full-strength quality is obtained through the plates; because the glass is heated well into its softening point and because of a large, distributed force that is developed that presses the two plates together from the difference in pressure between the furnace ambient (high pressure) and the channeling and microstructures in the plates (low pressure) due to the vacuum drawn. The apparatus and method may be used to fabricate microcapillary arrays for chemical electrophoresis; for example, any apparatus using a network of microfluidic channels embedded between plates of glass or similar moderate melting point substrates with a gradual softening point curve, or for assembly of glass-based substrates onto larger substrates, such as in flat panel display systems.

  3. Structural behavior of silicone bonded glass block panels

    SciTech Connect (OSTI)

    Chang, K.F. [Structural Engineering Associates, Inc., San Antonio, TX (United States); Sandberg, L.B. [Michigan Technological Univ. Houghton, MI (United States)

    1996-12-31T23:59:59.000Z

    Silicone sealant was submitted for mortar in bonding glass blocks. The sealant`s tensile and shear strengths and stiffnesses were determined. Joints bonding two glass blocks were tested for stiffness and strength in tension, bending, out-of-plane shear, and in-plane shear. Bending tests were done on specimens one block wide and four blocks long to evaluate one-way bending behavior. A six block by six block panel, supported on all four sides, was built and tested under simulated wind load. An analytical model with material nonlinearity in the joints was developed for the one-way bending case. It gave good comparisons with the experimental data to load levels approaching failure. A more complex analytical model was developed for the two-way panel. It was only valid for lower load levels, in the range of potential allowable design loads, but compared well with test results. Silicone bonded glass block panels have potential for meeting the wind load requirements necessary for exterior use.

  4. Intermetallic compound formation at Cu-Al wire bond interface

    SciTech Connect (OSTI)

    Bae, In-Tae; Young Jung, Dae [Small Scale Systems Integration and Packaging Center, State University of New York at Binghamton, Binghamton, New York 13902 (United States); Chen, William T.; Du Yong [Advanced Semiconductor Engineering Inc., 1255 E Arques Ave, Sunnyvale, California 94085 (United States)

    2012-12-15T23:59:59.000Z

    Intermetallic compound (IMC) formation and evolution at Cu-Al wire bond interface were studied using focused ion beam /scanning electron microscopy, transmission electron microscopy (TEM)/energy dispersive x-ray spectroscopy (EDS), nano beam electron diffraction (NBED) and structure factor (SF) calculation. It was found that discrete IMC patches were formed at the Cu/Al interface in as-packaged state and they grew toward Al pad after high temperature storage (HTS) environment at 150 Degree-Sign C. TEM/EDS and NBED results combined with SF calculation revealed the evidence of metastable {theta} Prime -CuAl{sub 2} IMC phase (tetragonal, space group: I4m2, a = 0.404 nm, c= 0.580 nm) formed at Cu/Al interfaces in both of the as-packaged and the post-HTS samples. Two feasible mechanisms for the formation of the metastable {theta} Prime -CuAl{sub 2} phase are discussed based on (1) non-equilibrium cooling of wire bond that is attributed to highly short bonding process time and (2) the epitaxial relationships between Cu and {theta} Prime -CuAl{sub 2}, which can minimize lattice mismatch for {theta} Prime -CuAl{sub 2} to grow on Cu.

  5. Effect of hydrogen bond cooperativity on the behavior of water

    E-Print Network [OSTI]

    Kevin Stokely; Marco G. Mazza; H. Eugene Stanley; Giancarlo Franzese

    2009-08-27T23:59:59.000Z

    Four scenarios have been proposed for the low--temperature phase behavior of liquid water, each predicting different thermodynamics. The physical mechanism which leads to each is debated. Moreover, it is still unclear which of the scenarios best describes water, as there is no definitive experimental test. Here we address both open issues within the framework of a microscopic cell model by performing a study combining mean field calculations and Monte Carlo simulations. We show that a common physical mechanism underlies each of the four scenarios, and that two key physical quantities determine which of the four scenarios describes water: (i) the strength of the directional component of the hydrogen bond and (ii) the strength of the cooperative component of the hydrogen bond. The four scenarios may be mapped in the space of these two quantities. We argue that our conclusions are model-independent. Using estimates from experimental data for H bond properties the model predicts that the low-temperature phase diagram of water exhibits a liquid--liquid critical point at positive pressure.

  6. Resummed thermodynamic perturbation theory for bond cooperativity in associating fluids with small bond angles: Effects of steric hindrance and ring formation

    SciTech Connect (OSTI)

    Marshall, Bennett D., E-mail: bennettd1980@gmail.com; Haghmoradi, Amin; Chapman, Walter G. [Department of Chemical and Biomolecular Engineering, Rice University, 6100 S. Main, Houston, Texas 77005 (United States)] [Department of Chemical and Biomolecular Engineering, Rice University, 6100 S. Main, Houston, Texas 77005 (United States)

    2014-04-28T23:59:59.000Z

    In this paper we develop a thermodynamic perturbation theory for two site associating fluids which exhibit bond cooperativity (system energy is non-pairwise additive). We include both steric hindrance and ring formation such that the equation of state is bond angle dependent. Here, the bond angle is the angle separating the centers of the two association sites. As a test, new Monte Carlo simulations are performed, and the theory is found to accurately predict the internal energy as well as the distribution of associated clusters as a function of bond angle.

  7. The Breathing Orbital Valence Bond Method in Diffusion Monte Carlo: C-H Bond Dissociation ofAcetylene

    SciTech Connect (OSTI)

    Domin, D.; Braida, Benoit; Lester Jr., William A.

    2008-05-30T23:59:59.000Z

    This study explores the use of breathing orbital valence bond (BOVB) trial wave functions for diffusion Monte Carlo (DMC). The approach is applied to the computation of the carbon-hydrogen (C-H) bond dissociation energy (BDE) of acetylene. DMC with BOVB trial wave functions yields a C-H BDE of 132.4 {+-} 0.9 kcal/mol, which is in excellent accord with the recommended experimental value of 132.8 {+-} 0.7 kcal/mol. These values are to be compared with DMC results obtained with single determinant trial wave functions, using Hartree-Fock orbitals (137.5 {+-} 0.5 kcal/mol) and local spin density (LDA) Kohn-Sham orbitals (135.6 {+-} 0.5 kcal/mol).

  8. Final Year Project Report

    SciTech Connect (OSTI)

    Hubsch, Tristan [Howard University

    2013-06-20T23:59:59.000Z

    In the last years of this eighteen-year grant project, the research efforts have focused mostly on the study of off-shell representations of supersymmetry, both on the worldline and on the world- sheet, i.e., both in supersymmetric quantum mechanics and in supersymmetric field theory in 1+1-dimensional spacetime.

  9. Single versus double bond breakage in a Morse chain under tension: higher index saddles and bond healing

    E-Print Network [OSTI]

    F. A. L. Mauguiere; P. Collins; G. S. Ezra; S. Wiggins

    2012-12-11T23:59:59.000Z

    We investigate the fragmentation dynamics of an atomic chain under tensile stress. We have classified the location, stability type (indices) and energy of all equilibria for the general $n$-particle chain, and have highlighted the importance of saddle points with index $> 1$. We show that for an $n=2$-particle chain under tensile stress the index 2 saddle plays a central role in organizing the dynamics. We apply normal form theory to analyze phase space structure and dynamics in a neighborhood of the index 2 saddle. We define a phase dividing surface (DS) that enables us to classify trajectories passing through a neighborhood of the saddle point using the values of the integrals associated with the normal form. We also generalize our definition of the dividing surface and define an \\emph{extended dividing surface} (EDS), which is used to sample and classify all trajectories that pass through a phase space neighborhood of the index 2 saddle at total energies less than that of the saddle. Classical trajectory simulations are used to study single versus double bond breakage for the $n=2$ chain under tension. Initial conditions for trajectories are obtained by sampling the EDS at constant energy. We sample trajectories at fixed energies both above and below the energy of the saddle. The fate of trajectories (single versus double bond breakage) is explored as a function of the location of the initial condition on the EDS, and a connection made to the work of Chesnavich on collision-induced dissociation. A significant finding is that we can readily identify trajectories that exhibit bond \\emph{healing}. Such trajectories pass outside the nominal (index 1) transition state for single bond dissociation, but return to the potential well region, possibly several times, before ultimately dissociating.

  10. Implementation of Section 1072 of the National Defense Authorization Act for Fiscal Year 2008

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2009-08-12T23:59:59.000Z

    This Notice provides guidance for implementing the mandates of Section 1072 of the National Defense Authorization Act for Fiscal Year 2008, commonly referred to as the Bond Amendment. Extended until 9-28-11 by DOE N 251.90 dated 9-28-10. Canceled by DOE O 472.2. Does not cancel other directives.

  11. PHAT STELLAR CLUSTER SURVEY. I. YEAR 1 CATALOG AND INTEGRATED PHOTOMETRY

    SciTech Connect (OSTI)

    Johnson, L. Clifton; Dalcanton, Julianne J.; Fouesneau, Morgan; Hodge, Paul W.; Weisz, Daniel R.; Williams, Benjamin F.; Beerman, Lori C. [Department of Astronomy, University of Washington, Box 351580, Seattle, WA 98195 (United States); Seth, Anil C. [Department of Physics and Astronomy, University of Utah, Salt Lake City, UT 84112 (United States); Caldwell, Nelson [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Gouliermis, Dimitrios A. [Institut fuer Theoretische Astrophysik, Zentrum fuer Astronomie der Universitaet Heidelberg, Albert-Ueberle-Strasse 2, D-69120 Heidelberg (Germany); Larsen, Soren S. [Department of Astrophysics, IMAPP, Radboud University Nijmegen, P.O. Box 9010, 6500 GL Nijmegen (Netherlands); Olsen, Knut A. G. [National Optical Astronomy Observatory, 950 North Cherry Avenue, Tucson, AZ 85719 (United States); San Roman, Izaskun; Sarajedini, Ata [Department of Astronomy, University of Florida, 211 Bryant Space Science Center, Gainesville, FL 32611-2055 (United States); Bianchi, Luciana [Department of Physics and Astronomy, Johns Hopkins University, 3400 North Charles Street, Baltimore, MD 21218 (United States); Dolphin, Andrew E. [Raytheon Company, 1151 East Hermans Road, Tucson, AZ 85756 (United States); Girardi, Leo [Osservatorio Astronomico di Padova-INAF, Vicolo dell'Osservatorio 5, I-35122 Padova (Italy); Guhathakurta, Puragra [Department of Astronomy and Astrophysics, University of California Observatories/Lick Observatory, University of California, 1156 High Street, Santa Cruz, CA 95064 (United States); Kalirai, Jason [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Lang, Dustin, E-mail: lcjohnso@astro.washington.edu [Department of Astrophysical Sciences, Princeton University, Princeton, NJ 08544 (United States); and others

    2012-06-20T23:59:59.000Z

    The Panchromatic Hubble Andromeda Treasury (PHAT) survey is an ongoing Hubble Space Telescope (HST) multi-cycle program to obtain high spatial resolution imaging of one-third of the M31 disk at ultraviolet through near-infrared wavelengths. In this paper, we present the first installment of the PHAT stellar cluster catalog. When completed, the PHAT cluster catalog will be among the largest and most comprehensive surveys of resolved star clusters in any galaxy. The exquisite spatial resolution achieved with HST has allowed us to identify hundreds of new clusters that were previously inaccessible with existing ground-based surveys. We identify 601 clusters in the Year 1 sample, representing more than a factor of four increase over previous catalogs within the current survey area (390 arcmin{sup 2}). This work presents results derived from the first {approx}25% of the survey data; we estimate that the final sample will include {approx}2500 clusters. For the Year 1 objects, we present a catalog with positions, radii, and six-band integrated photometry. Along with a general characterization of the cluster luminosities and colors, we discuss the cluster luminosity function, the cluster size distributions, and highlight a number of individually interesting clusters found in the Year 1 search.

  12. Development and validation of bonded composite doubler repairs for commercial aircraft.

    SciTech Connect (OSTI)

    Roach, Dennis Patrick; Rackow, Kirk A.

    2007-07-01T23:59:59.000Z

    A typical aircraft can experience over 2,000 fatigue cycles (cabin pressurizations) and even greater flight hours in a single year. An unavoidable by-product of aircraft use is that crack, impact, and corrosion flaws develop throughout the aircraft's skin and substructure elements. Economic barriers to the purchase of new aircraft have placed even greater demands on efficient and safe repair methods. The use of bonded composite doublers offers the airframe manufacturers and aircraft maintenance facilities a cost effective method to safely extend the lives of their aircraft. Instead of riveting multiple steel or aluminum plates to facilitate an aircraft repair, it is now possible to bond a single Boron-Epoxy composite doubler to the damaged structure. The FAA's Airworthiness Assurance Center at Sandia National Labs (AANC), Boeing, and Federal Express completed a pilot program to validate and introduce composite doubler repair technology to the U.S. commercial aircraft industry. This project focused on repair of DC-10 fuselage structure and its primary goal was to demonstrate routine use of this repair technology using niche applications that streamline the design-to-installation process. As composite doubler repairs gradually appear in the commercial aircraft arena, successful flight operation data is being accumulated. These commercial aircraft repairs are not only demonstrating the engineering and economic advantages of composite doubler technology but they are also establishing the ability of commercial maintenance depots to safely adopt this repair technique. This report presents the array of engineering activities that were completed in order to make this technology available for widespread commercial aircraft use. Focused laboratory testing was conducted to compliment the field data and to address specific issues regarding damage tolerance and flaw growth in composite doubler repairs. Fatigue and strength tests were performed on a simulated wing repair using a substandard design and a flawed installation. In addition, the new Sol-Gel surface preparation technique was evaluated. Fatigue coupon tests produced Sol-Gel results that could be compared with a large performance database from conventional, riveted repairs. It was demonstrated that not only can composite doublers perform well in severe off-design conditions (low doubler stiffness and presence of defects in doubler installation) but that the Sol-Gel surface preparation technique is easier and quicker to carry out while still producing optimum bonding properties. Nondestructive inspection (NDI) methods were developed so that the potential for disbond and delamination growth could be monitored and crack growth mitigation could be quantified. The NDI methods were validated using full-scale test articles and the FedEx aircraft installations. It was demonstrated that specialized NDI techniques can detect flaws in composite doubler installations before they reach critical size. Probability of Detection studies were integrated into the FedEx training in order to quantify the ability of aircraft maintenance depots to properly monitor these repairs. In addition, Boeing Structural Repair and Nondestructive Testing Manuals were modified to include composite doubler repair and inspection procedures. This report presents the results from the FedEx Pilot Program that involved installation and surveillance of numerous repairs on operating aircraft. Results from critical NDI evaluations are reported in light of damage tolerance assessments for bonded composite doublers. This work has produced significant interest from airlines and aircraft manufacturers. The successful Pilot Program produced flight performance history to establish the durability of bonded composite patches as a permanent repair on commercial aircraft structures. This report discusses both the laboratory data and Pilot Program results from repair installations on operating aircraft to introduce composite doubler repairs into mainstream commercial aircraft use.

  13. Bond strength of cementitious borehole plugs in welded tuff

    SciTech Connect (OSTI)

    Akgun, H.; Daemen, J.J.K. [Arizona Univ., Tucson, AZ (USA). Dept. of Mining and Geological Engineering

    1991-02-01T23:59:59.000Z

    Axial loads on plugs or seals in an underground repository due to gas, water pressures and temperature changes induced subsequent to waste and plug emplacement lead to shear stresses at the plug/rock contact. Therefore, the bond between the plug and rock is a critical element for the design and effectiveness of plugs in boreholes, shafts or tunnels. This study includes a systematic investigation of the bond strength of cementitious borehole plugs in welded tuff. Analytical and numerical analysis of borehole plug-rock stress transfer mechanics is performed. The interface strength and deformation are studied as a function of Young`s modulus ratio of plug and rock, plug length and rock cylinder outside-to-inside radius ratio. The tensile stresses in and near an axially loaded plug are analyzed. The frictional interface strength of an axially loaded borehole plug, the effect of axial stress and lateral external stress, and thermal effects are also analyzed. Implications for plug design are discussed. The main conclusion is a strong recommendation to design friction plugs in shafts, drifts, tunnels or boreholes with a minimum length to diameter ratio of four. Such a geometrical design will reduce tensile stresses in the plug and in the host rock to a level which should minimize the risk of long-term deterioration caused by excessive tensile stresses. Push-out tests have been used to determine the bond strength by applying an axial load to cement plugs emplaced in boreholes in welded tuff cylinders. A total of 130 push-out tests have been performed as a function of borehole size, plug length, temperature, and degree of saturation of the host tuff. The use of four different borehole radii enables evaluation of size effects. 119 refs., 42 figs., 20 tabs.

  14. Fuel cell system with separating structure bonded to electrolyte

    DOE Patents [OSTI]

    Bourgeois, Richard Scott (Albany, NY); Gudlavalleti, Sauri (Albany, NY); Quek, Shu Ching (Clifton Park, NY); Hasz, Wayne Charles (Pownal, VT); Powers, James Daniel (Santa Monica, CA)

    2010-09-28T23:59:59.000Z

    A fuel cell assembly comprises a separating structure configured for separating a first reactant and a second reactant wherein the separating structure has an opening therein. The fuel cell assembly further comprises a fuel cell comprising a first electrode, a second electrode, and an electrolyte interposed between the first and second electrodes, and a passage configured to introduce the second reactant to the second electrode. The electrolyte is bonded to the separating structure with the first electrode being situated within the opening, and the second electrode being situated within the passage.

  15. Chemical bond and entanglement of electrons in the hydrogen molecule

    E-Print Network [OSTI]

    Nikos Iliopoulos; Andreas F. Terzis

    2014-08-01T23:59:59.000Z

    We theoretically investigate the quantum correlations (in terms of concurrence of indistinguishable electrons) in a prototype molecular system (hydrogen molecule). With the assistance of the standard approximations of the linear combination of atomic orbitals and the con?guration interaction methods we describe the electronic wavefunction of the ground state of the H2 molecule. Moreover, we managed to ?find a rather simple analytic expression for the concurrence (the most used measure of quantum entanglement) of the two electrons when the molecule is in its lowest energy. We have found that concurrence does not really show any relation to the construction of the chemical bond.

  16. Time-Resolved Study of Bonding in Liquid Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in2, 2003 (NextTime-Resolved Study of Bonding in Liquid

  17. Time-Resolved Study of Bonding in Liquid Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in2, 2003 (NextTime-Resolved Study of Bonding in

  18. Time-Resolved Study of Bonding in Liquid Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in2, 2003 (NextTime-Resolved Study of Bonding

  19. Title 43 CFR 3104 Bonds | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro Industries PvtStratosolarTharaldson EthanolTillson,OpenOpen|Amendment JumpBonds Jump to:

  20. Bond County, Illinois: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:EzfeedflagBiomass ConversionsSouthby 2022 |BleckleyMotionBocaBond County, Illinois: Energy

  1. Nitrogen-tuned bonding mechanism of Li and Ti adatom embedded graphene

    SciTech Connect (OSTI)

    Lee, Sangho; Chung, Yong-Chae, E-mail: yongchae@hanyang.ac.kr

    2013-09-15T23:59:59.000Z

    The effects of nitrogen defects on the bonding mechanism and resultant binding energy between the metal and graphene layer were investigated using density functional theory (DFT) calculations. For the graphitic N-doped graphene, Li adatom exhibited ionic bonding character, while Ti adatom showed features of covalent bonding similar to that of pristine graphene. However, in the cases of pyridinic and pyrrolic structures, partially covalent bonding characteristic occurred around N atoms in the process of binding with metals, and this particular bond formation enhanced the bond strength of metal on the graphene layer as much as it exceeded the cohesive energy of the metal bulk. Thus, Li and Ti metals are expected to be dispersed with atomic accuracy on the pyridinic and pyrrolic N-doped graphene layers. These results demonstrate that the bonding mechanism of metal–graphene complex can change according to the type of N defect, and this also affects the binding results. - Graphical abstract: Display Omitted - Highlights: • Nitrogen defects changed the bonding mechanism between metal and graphene. • Bonding character and binding results were investigated using DFT calculations. • Covalent bonding character occurred around pyridinic and pyrrolic N-doped graphene. • Pyridinic and pyrrolic N atoms are effective for metal dispersion on the graphene.

  2. IEEE TRANSACTIONS ON ADVANCED PACKAGING, VOL. 32, NO. 2, MAY 2009 461 Ultrasonic Bonding for MEMS Sealing and Packaging

    E-Print Network [OSTI]

    Lin, Liwei

    utilizing the solid phase vibration and welding process to bond two elements rapidly at low temperature. Two purely mechanical vibration energy to enable low temperature bonding between similar or dissimilar bonding process used tens of Watts at room temperature environment and the bonds were accomplished within

  3. A theory for calculating the surface-adsorbate bond dissociation energy from collision-induced desorption threshold measurements

    E-Print Network [OSTI]

    Levis, Robert J.

    to determine surface-adsorbate bond energies.3 Here we present a new model for determin- ing the bondA theory for calculating the surface-adsorbate bond dissociation energy from collision is presented for determining the bond dissociation energy, Do, of a surface-adsorbate complex from collision

  4. JOURNAL OF MICROELECTROMECHANICAL SYSTEMS, VOL. 21, NO. 2, APRIL 2012 497 Rapid Silicon-to-Steel Bonding by Induction

    E-Print Network [OSTI]

    Lin, Liwei

    , thermocompressive diffusion bonding has been demonstrated for the bonding of sil- icon nitride to steel [1], [2-to-Steel Bonding by Induction Heating for MEMS Strain Sensors Brian D. Sosnowchik, Robert G. Azevedo, Member, IEEE and manufacturable technique to bond sil- icon to steel for microelectromechanical system (MEMS) sensor applications

  5. IMPACT OF CAPILLARY AND BOND NUMBERS ON RELATIVE PERMEABILITY

    SciTech Connect (OSTI)

    Kishore K. Mohanty

    2002-09-30T23:59:59.000Z

    Recovery and recovery rate of oil, gas and condensates depend crucially on their relative permeability. Relative permeability in turn depends on the pore structure, wettability and flooding conditions, which can be represented by a set of dimensionless groups including capillary and bond numbers. The effect of flooding conditions on drainage relative permeabilities is not well understood and is the overall goal of this project. This project has three specific objectives: to improve the centrifuge relative permeability method, to measure capillary and bond number effects experimentally, and to develop a pore network model for multiphase flows. A centrifuge has been built that can accommodate high pressure core holders and x-ray saturation monitoring. The centrifuge core holders can operate at a pore pressure of 6.9 MPa (1000 psi) and an overburden pressure of 17 MPa (2500 psi). The effect of capillary number on residual saturation and relative permeability in drainage flow has been measured. A pore network model has been developed to study the effect of capillary numbers and viscosity ratio on drainage relative permeability. Capillary and Reynolds number dependence of gas-condensate flow has been studied during well testing. A method has been developed to estimate relative permeability parameters from gas-condensate well test data.

  6. Naval Petroleum and Oil Shale Reserves. Annual report of operations, Fiscal year 1993

    SciTech Connect (OSTI)

    Not Available

    1993-12-31T23:59:59.000Z

    During fiscal year 1993, the reserves generated $440 million in revenues, a $33 million decrease from the fiscal year 1992 revenues, primarily due to significant decreases in oil and natural gas prices. Total costs were $207 million, resulting in net cash flow of $233 million, compared with $273 million in fiscal year 1992. From 1976 through fiscal year 1993, the Naval Petroleum and Oil Shale Reserves generated $15.7 billion in revenues for the US Treasury, with expenses of $2.9 billion. The net revenues of $12.8 billion represent a return on costs of 441 percent. See figures 2, 3, and 4. In fiscal year 1993, production at the Naval Petroleum and Oil Shale Reserves at maximum efficient rates yielded 25 million barrels of crude oil, 123 billion cubic feet of natural gas, and 158 million gallons of natural gas liquids. The Naval Petroleum and Oil Shale Reserves has embarked on an effort to identify additional hydrocarbon resources on the reserves for future production. In 1993, in cooperation with the US Geological Survey, the Department initiated a project to assess the oil and gas potential of the program`s oil shale reserves, which remain largely unexplored. These reserves, which total a land area of more than 145,000 acres and are located in Colorado and Utah, are favorably situated in oil and gas producing regions and are likely to contain significant hydrocarbon deposits. Alternatively the producing assets may be sold or leased if that will produce the most value. This task will continue through the first quarter of fiscal year 1994.

  7. Studies of IBL wire bonds operation in a ATLAS-like magnetic field.

    E-Print Network [OSTI]

    Alvarez Feito, D; Mandelli, B

    2015-01-01T23:59:59.000Z

    At the Large Hadron Collider (LHC) experiments, most of silicon detectors use wire bonds to connect front-end chips and sensors to circuit boards for the data and service trans- missions. These wire bonds are operated in strong magnetic field environments and if time varying currents pass through them with frequencies close to their mechanical resonance frequency, strong resonant oscillations may occur. Under certain conditions, this effect can lead to fatigue stress and eventually breakage of wire bonds. During the first LHC Long Shutdown, the ATLAS Pixel Detector has been upgraded with the addition of a fourth innermost layer, the Insertable B-Layer (IBL), which has more than 50000 wire bonds operated in the ATLAS 2 T magnetic field. The results of systematic studies of operating wire bonds under IBL-like conditions are presented. Two different solutions have been investigated to minimize the oscillation amplitude of wire bonds.

  8. Influence of the bonding front propagation on the wafer stack curvature

    SciTech Connect (OSTI)

    Navarro, E. [SOITEC—Parc Technologique des Fontaines, 38190 Bernin (France); SIMaP—Grenoble-INP, 1340 rue de la Piscine, 38402 St. Martin d'Hčres (France); Bréchet, Y. [SIMaP—Grenoble-INP, 1340 rue de la Piscine, 38402 St. Martin d'Hčres (France); Barthelemy, A.; Radu, I. [SOITEC—Parc Technologique des Fontaines, 38190 Bernin (France); Pardoen, T. [Institute of Mechanics, Materials and Civil Engineering (iMMC), Université catholique de Louvain, B-1348 Louvain-la-Neuve (Belgium); Raskin, J.-P. [Institute of Information and Communication Technologies, Electronics and Applied Mathematics (ICTEAM), Université catholique de Louvain, B-1348 Louvain-la-Neuve (Belgium)

    2014-08-11T23:59:59.000Z

    The influence of the dynamics of the direct wafer bonding process on the curvature of the final wafer stack is investigated. An analytical model for the final curvature of the bonded wafers is developed, as a function of the different load components acting during the bonding front propagation, using thin plate theory and considering a strain discontinuity locked at the bonding interface. Experimental profiles are measured for different bonding conditions and wafer thicknesses. A very good agreement with the model prediction is obtained and the influence of the thin air layer trapped in-between the two wafers is demonstrated. The proposed model contributes to further improvement of the bonding process, in particular, for the stacking of layers of electronic devices, which requires a high accuracy of wafer-to-wafer alignment and a very low distortion level.

  9. Project Year Project Title

    E-Print Network [OSTI]

    Gray, Jeffrey J.

    Project Year 2011-2012 Project Title Using M-Health and GIS Technology in the Field to Improve-specialized, but practically useless skill. Solution One goal of this summer's Applied Geographic Information Systems in Public lessons about observational epidemiology. Technologies Used Geographic Info System (GIS), Blackboard

  10. Three Hydrogen Bond Donor Catalysts: Oxyanion Hole Mimics and Transition State Analogues

    SciTech Connect (OSTI)

    Beletskiy, Evgeny V.; Schmidt, Jacob C.; Wang, Xue B.; Kass, Steven R.

    2012-11-14T23:59:59.000Z

    Enzymes and their mimics use hydrogen bonds to catalyze chemical transformations. Small molecule transition state analogs of oxyanion holes are characterized by gas phase IR and photoelectron spectroscopy and their binding constants in acetonitrile. As a result, a new class of hydrogen bond catalysts is proposed (OH donors that can contribute three hydrogen bonds to a single functional group) and demonstrated in a Friedel-Crafts reaction.

  11. Atomic Structures of Graphene, Benzene and Methane with Bond Lengths as Sums of the Single, Double and Resonance Bond Radii of Carbon

    E-Print Network [OSTI]

    Raji Heyrovska

    2008-04-25T23:59:59.000Z

    Two dimensional layers of graphene are currently drawing a great attention in fundamental and applied nanoscience. Graphene consists of interconnected hexagons of carbon atoms as in graphite. This article presents for the first time the structures of graphene at the atomic level and shows how it differs from that of benzene, due to the difference in the double bond and resonance bond based radii of carbon. The carbon atom of an aliphatic compound such as methane has a longer covalent single bond radius as in diamond. All the atomic structures presented here have been drawn to scale.

  12. Thermal barrier and overlay coating systems comprising composite metal/metal oxide bond coating layers

    DOE Patents [OSTI]

    Goedjen, John G. (Oviedo, FL); Sabol, Stephen M. (Orlando, FL); Sloan, Kelly M. (Longwood, FL); Vance, Steven J. (Orlando, FL)

    2001-01-01T23:59:59.000Z

    The present invention generally describes multilayer coating systems comprising a composite metal/metal oxide bond coat layer. The coating systems may be used in gas turbines.

  13. NonDestructive Inspection of Adhesive Bonds in Metal-Metal Joints

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    good bonding Immersion tank Ultrasonic phased array Pulsed thermography Laser ultrasonics (steel sample shown) 2008 DOE Merit Review - ALM Accomplishments - Body in...

  14. EIS-0306: Treatment and Management of Sodium-Bonded Spent Nuclear Fuel

    Broader source: Energy.gov [DOE]

    DOE prepared a EIS that evaluated the potential environmental impacts of treatment and management of DOE-owned sodium bonded spent nuclear fuel.

  15. Innovative use of adhesive interface characteristics to nondestructively quantify the strength of bonded joints.

    SciTech Connect (OSTI)

    Roach, Dennis Patrick; Duvall, Randy L.; Rackow, Kirk A.

    2010-05-01T23:59:59.000Z

    Advances in structural adhesives have permitted engineers to contemplate the use of bonded joints in areas that have long been dominated by mechanical fasteners and welds. Although strength, modulus, and toughness have been improved in modern adhesives, the typical concerns with using these polymers still exist. These include concerns over long-term durability and an inability to quantify bond strength (i.e., identify weak bonds) in adhesive joints. Bond deterioration in aging structures and bond strength in original construction are now critical issues that require more than simple flaw detection. Whether the structure involves metallic or composite materials, it is necessary to extend inspections beyond the detection of disbond flaws to include an assessment of the strength of the bond. Use of advanced nondestructive inspection (NDI) methods to measure the mechanical properties of a bonded joint and associated correlations with post-inspection failure tests have provided some clues regarding the key parameters involved in assessing bond strength. Recent advances in ultrasonic- and thermographic-based inspection methods have shown promise for measuring such properties. Specialized noise reduction and signal enhancement schemes have allowed thermographic interrogations to image the subtle differences between bond lines of various strengths. Similarly, specialized ultrasonic (UT) inspection techniques, including laser UT, guided waves, UT spectroscopy, and resonance methods, can be coupled with unique signal analysis algorithms to accurately characterize the properties of weak interfacial bonds. The generation of sufficient energy input levels to derive bond strength variations, the production of sufficient technique sensitivity to measure such minor response variations, and the difficulty in manufacturing repeatable weak bond specimens are all issues that exacerbate these investigations. The key to evaluating the bond strength lies in the ability to exploit the critical characteristics of weak bonds such as nonlinear responses, poor transmission of shear waves, and changes in response to stiffness-based interrogations. This paper will present several ongoing efforts that have identified promising methods for quantifying bond strength and discuss some completed studies that provide a foundation for further evolution in weak bond assessments.

  16. Liquid Metal Bond for Improved Heat Transfer in LWR Fuel Rods

    SciTech Connect (OSTI)

    Donald Olander

    2005-08-24T23:59:59.000Z

    A liquid metal (LM) consisting of 1/3 weight fraction each of Pb, Sn, and Bi has been proposed as the bonding substance in the pellet-cladding gap in place of He. The LM bond eliminates the large AT over the pre-closure gap which is characteristic of helium-bonded fuel elements. Because the LM does not wet either UO2 or Zircaloy, simply loading fuel pellets into a cladding tube containing LM at atmospheric pressure leaves unfilled regions (voids) in the bond. The HEATING 7.3 heat transfer code indicates that these void spaces lead to local fuel hot spots.

  17. Tuning by pruning: exploiting disorder for global response and the principle of bond-level independence

    E-Print Network [OSTI]

    Carl P. Goodrich; Andrea J. Liu; Sidney R. Nagel

    2015-02-13T23:59:59.000Z

    We exploit the intrinsic difference between disordered and crystalline solids to create systems with unusual and exquisitely tuned mechanical properties. To demonstrate the power of this approach, we design materials that are either virtually incompressible or completely auxetic. Disordered networks can be efficiently driven to these extreme limits by removing a very small fraction of bonds via a selected-bond removal procedure that is both simple and experimentally relevant. The procedure relies on the nearly complete absence of any correlation between the contributions of an individual bond to different elastic moduli. A new principle unique to disordered solids underlies this lack of correlation: independence of bond-level response.

  18. Bimetallic cleavage of aromatic C-H bonds by rare-earth-metal complexes

    E-Print Network [OSTI]

    Huang, W; Huang, W; Dulong, F; Khan, SI; Cantat, T; Diaconescu, PL

    2014-01-01T23:59:59.000Z

    of Aromatic C-H Bonds by Rare Earth Metal Complexes Wenliangone week prior to use. Rare earth metal oxides (scandium,

  19. A Batch Wafer Scale LIGA Assembly and Packaging Technique vai Diffusion Bonding

    SciTech Connect (OSTI)

    Christenson, T.R.; Schmale, D.T.

    1999-01-27T23:59:59.000Z

    A technique using diffusion bonding (or solid-state welding) has been used to achieve batch fabrication of two- level nickel LIGA structures. Interlayer alignment accuracy of less than 1 micron is achieved using press-fit gauge pins. A mini-scale torsion tester was built to measure the diffusion bond strength of LIGA formed specimens that has shown successful bonding at temperatures of 450"C at 7 ksi pressure with bond strength greater than 100 Mpa. Extensions to this basic process to allow for additional layers and thereby more complex assemblies as well as commensurate packaging are discussed.

  20. Covalent features in the hydrogen bond of a water dimer: molecular orbital analysis

    E-Print Network [OSTI]

    Wang, Bo; Dai, Xing; Gao, Yang; Wang, Zhigang; Zhang, Rui-Qin

    2015-01-01T23:59:59.000Z

    The covalent-like characteristics of hydrogen bonds offer a new perspective on intermolecular interactions. Here, using density functional theory and post-Hartree-Fock methods, we reveal that there are two bonding molecular orbitals (MOs) crossing the O and H atoms of the hydrogen-bond in water dimer. Energy decomposition analysis also shows a non-negligible contribution of the induction term. These results illustrate the covalent-like character of the hydrogen bond between water molecules, which contributes to the essential understanding of ice, liquid water, related materials, and life sciences.

  1. alkane c-h bond: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    activation of functionalized hydrocarbons. II. CH and CCN bond activation of acetonitrile and benzonitrile. Open Access Theses and Dissertations Summary: ??Several...

  2. aliphatic c-h bond: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    activation of functionalized hydrocarbons. II. CH and CCN bond activation of acetonitrile and benzonitrile. Open Access Theses and Dissertations Summary: ??Several...

  3. arene c-h bonds: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    activation of functionalized hydrocarbons. II. CH and CCN bond activation of acetonitrile and benzonitrile. Open Access Theses and Dissertations Summary: ??Several...

  4. adhesive bonding high-alumina: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    various conditions, including the type of surface preparation, pH of the environmental media, (more) Xu, Dingying 2004-01-01 2 Bond Characteristics and Qualifications of...

  5. Making it Easier to Complete Clean Energy Projects with Qualified Energy Conservation Bonds (QECBs)

    Broader source: Energy.gov [DOE]

    This presentation, given through the DOE's Technical Assitance Program (TAP), provides information on How to to Complete Clean Energy Projects with Qualified Energy Conservation Bonds (QECBs)

  6. Budget estimates. Fiscal year 1998

    SciTech Connect (OSTI)

    NONE

    1997-02-01T23:59:59.000Z

    The U.S. Congress has determined that the safe use of nuclear materials for peaceful purposes is a legitimate and important national goal. It has entrusted the Nuclear Regulatory Commission (NRC) with the primary Federal responsibility for achieving that goal. The NRC`s mission, therefore, is to regulate the Nation`s civilian use of byproduct, source, and special nuclear materials to ensure adequate protection of public health and safety, to promote the common defense and security, and to protect the environment. The NRC`s FY 1998 budget requests new budget authority of $481,300,000 to be funded by two appropriations - one is the NRC`s Salaraies and Expenses appropriation for $476,500,000, and the other is NRC`s Office of Inspector General appropriation for $4,800,000. Of the funds appropriated to the NRC`s Salaries and Expenses, $17,000,000, shall be derived from the Nuclear Waste Fund and $2,000,000 shall be derived from general funds. The proposed FY 1998 appropriation legislation would also exempt the $2,000,000 for regulatory reviews and other assistance provided to the Department of Energy from the requirement that the NRC collect 100 percent of its budget from fees. The sums appropriated to the NRC`s Salaries and Expenses and NRC`s Office of Inspector General shall be reduced by the amount of revenues received during FY 1998 from licensing fees, inspection services, and other services and collections, so as to result in a final FY 1998 appropriation for the NRC of an estimated $19,000,000 - the amount appropriated from the Nuclear Waste Fund and from general funds. Revenues derived from enforcement actions shall be deposited to miscellaneous receipts of the Treasury.

  7. Measurement-Based Quantum Computing with Valence-Bond-Solids

    E-Print Network [OSTI]

    Leong Chuan Kwek; Zhaohui Wei; Bei Zeng

    2011-11-22T23:59:59.000Z

    Measurement-based quantum computing (MBQC) is a model of quantum computing that proceeds by sequential measurements of individual spins in an entangled resource state. However, it remains a challenge to produce efficiently such resource states. Would it be possible to generate these states by simply cooling a quantum many-body system to its ground state? Cluster states, the canonical resource states for MBQC, do not occur naturally as unique ground states of physical systems. This inherent hurdle has led to a significant effort to identify alternative resource states that appear as ground states in spin lattices. Recently, some interesting candidates have been identified with various valence-bond-solid (VBS) states. In this review, we provide a pedagogical introduction to recent progress regarding MBQC with VBS states as possible resource states. This study has led to an interesting interdisciplinary research area at the interface of quantum information science and condensed matter physics.

  8. Measurement-Based Quantum Computing with Valence-Bond-Solids

    E-Print Network [OSTI]

    Kwek, Leong Chuan; Zeng, Bei

    2011-01-01T23:59:59.000Z

    Measurement-based quantum computing (MBQC) is a model of quantum computing that proceeds by sequential measurements of individual spins in an entangled resource state. However, it remains a challenge to produce efficiently such resource states. Would it be possible to generate these states by simply cooling a quantum many-body system to its ground state? Cluster states, the canonical resource states for MBQC, do not occur naturally as unique ground states of physical systems. This inherent hurdle has led to a significant effort to identify alternative resource states that appear as ground states in spin lattices. Recently, some interesting candidates have been identified with various valence-bond-solid (VBS) states. In this review, we provide a pedagogical introduction to recent progress regarding MBQC with VBS states as possible resource states. This study has led to an interesting interdisciplinary research area at the interface of quantum information science and condensed matter physics.

  9. An investigation of the interfacial bond strength of polymeric laminates

    SciTech Connect (OSTI)

    Eby, R.K. (Akron Univ., OH (United States))

    1991-08-01T23:59:59.000Z

    This report summarizes the results of an investigation of the bond strength of paper - polypropylene - paper (PPP) laminates. The strength has been measured with a peel test for the as--received laminates of different manufacturers, after thermal aging in air and nitrogen, after static thermal age in oil at room temperature and 90{degrees}C as well as after cyclic thermal aging in oil. Differential swelling of the paper and polypropylene at 90{degrees}C leads to a strong decrease in peel strength. Differential thermal expansion at 90{degrees}C is not as important. Cyclic thermal aging in oil leads to the greatest decrease in peel strength. The results further our knowledge of information that should be considered in preparing a PPP specification. 19 refs., 7 figs., 12 tabs.

  10. A parametric pressing study using a plastic-bonded explosive

    SciTech Connect (OSTI)

    Hayden, D. J. (David J.); Maez, L. R. (Leland R.); Olinger, B. W. (Barton W.); Powell, S. J. (Sandra J.)

    2002-01-01T23:59:59.000Z

    Pressed plastic-bonded explosives, PBXs, are commonly used by defense and private industry. PBX 9501 is composed of HMX crystals held together with a plastic binder 'softened' with plasticizers. The detonation behavior of any explosive is very dependent upon its density, with the desire to have a uniform, high density throughout the explosive component. A parametric study has been performed pressing PBX 9501 hydrostatically and uniaxially. The effects of several pressing parameters on the bulk density and density profile, as well as mechanical properties, have been measured. The parameters investigated include pressure, temperature, number of cycles, dwell time, rest time, sack thickness, and particle distribution and size. Density distributions within the pressed explosives were also compared.

  11. Method of making bonded or sintered permanent magnets

    DOE Patents [OSTI]

    McCallum, R.W.; Dennis, K.W.; Lograsso, B.K.; Anderson, I.E.

    1995-11-28T23:59:59.000Z

    An isotropic permanent magnet is made by mixing a thermally responsive, low viscosity binder and atomized rare earth-transition metal (e.g., iron) alloy powder having a carbon-bearing (e.g., graphite) layer thereon that facilitates wetting and bonding of the powder particles by the binder. Prior to mixing with the binder, the atomized alloy powder may be sized or classified to provide a particular particle size fraction having a grain size within a given relatively narrow range. A selected particle size fraction is mixed with the binder and the mixture is molded to a desired complex magnet shape. A molded isotropic permanent magnet is thereby formed. A sintered isotropic permanent magnet can be formed by removing the binder from the molded mixture and thereafter sintering to full density. 14 figs.

  12. Method of making bonded or sintered permanent magnets

    DOE Patents [OSTI]

    McCallum, R.W.; Dennis, K.W.; Lograsso, B.K.; Anderson, I.E.

    1993-08-31T23:59:59.000Z

    An isotropic permanent magnet is made by mixing a thermally responsive, low viscosity binder and atomized rare earth-transition metal (e.g., iron) alloy powder having a carbon-bearing (e.g., graphite) layer thereon that facilitates wetting and bonding of the powder particles by the binder. Prior to mixing with the binder, the atomized alloy powder may be sized or classified to provide a particular particle size fraction having a grain size within a given relatively narrow range. A selected particle size fraction is mixed with the binder and the mixture is molded to a desired complex magnet shape. A molded isotropic permanent magnet is thereby formed. A sintered isotropic permanent magnet can be formed by removing the binder from the molded mixture and thereafter sintering to full density.

  13. Method of making bonded or sintered permanent magnets

    DOE Patents [OSTI]

    McCallum, R. William (Ames, IA); Dennis, Kevin W. (Ames, IA); Lograsso, Barbara K. (Ames, IA); Anderson, Iver E. (Ames, IA)

    1995-11-28T23:59:59.000Z

    An isotropic permanent magnet is made by mixing a thermally responsive, low viscosity binder and atomized rare earth-transition metal (e.g., iron) alloy powder having a carbon-bearing (e.g., graphite) layer thereon that facilitates wetting and bonding of the powder particles by the binder. Prior to mixing with the binder, the atomized alloy powder may be sized or classified to provide a particular particle size fraction having a grain size within a given relatively narrow range. A selected particle size fraction is mixed with the binder and the mixture is molded to a desired complex magnet shape. A molded isotropic permanent magnet is thereby formed. A sintered isotropic permanent magnet can be formed by removing the binder from the molded mixture and thereafter sintering to full density.

  14. Interstellar Isomers: The Importance of Bonding Energy Differences

    E-Print Network [OSTI]

    Anthony J. Remijan; J. M. Hollis; F. J. Lovas; D. F. Plusquellic; P. R. Jewell

    2005-06-21T23:59:59.000Z

    We present strong detections of methyl cyanide, vinyl cyanide, ethyl cyanide and cyanodiacetylene molecules with the Green Bank Telescope (GBT) toward the Sgr B2(N) molecular cloud. Attempts to detect the corresponding isocyanide isomers were only successful in the case of methyl isocyanide for its J(K)=1(0)-0(0) transition, which is the first interstellar report of this line. To determine the spatial distribution of methyl isocyanide, we used archival Berkeley-Illinois-Maryland Association (BIMA) array data for the J(K)=4(K)-3(K) (K=0-3) transitions but no emission was detected. From ab initio calculations, the bonding energy difference between the cyanide and isocyanide molecules is >8500 cm^-1 (>12,000 K). That we detect methyl isocyanide emission with a single antenna (Gaussian beamsize(Omega_B)=1723 arcsec^2) but not with an interferometer (Omega_B=192 arcsec^2), strongly suggests that methyl isocyanide has a widespread spatial distribution toward the Sgr B2(N) region. Thus, large-scale, non-thermal processes in the surrounding medium may account for the conversion of methyl cyanide to methyl isocyanide while the LMH hot core, which is dominated by thermal processes, does not produce a significant amount of methyl isocyanide. Ice analog experiments by other investigators have shown that radiation bombardment of methyl cyanide can produce methyl isocyanide, thus supporting our observations. We conclude that isomers separated by such large bonding energy differences are distributed in different interstellar environments, making the evaluation of column density ratios between such isomers irrelevant unless it can be independently shown that these species are co-spatial.

  15. 2008 Year in Review 1 2008 Year in Review

    E-Print Network [OSTI]

    Hickman, Mark

    2008 Year in Review 1 2008 Year in Review The Science of Communication Disorders Departmental Research Committee. #12;2 2008 Year in Review Billinghurst, M., Moran, C., Gostomski, P., Basu, A

  16. Plasticity of hydrogen bond networks regulates mechanochemistry of cell adhesion complexes

    E-Print Network [OSTI]

    Shaon Chakrabarti; Michael Hinczewski; D. Thirumalai

    2014-06-12T23:59:59.000Z

    Mechanical forces acting on cell adhesion receptor proteins regulate a range of cellular functions by formation and rupture of non-covalent interactions with ligands. Typically, force decreases the lifetimes of intact complexes (slip-bonds), making the discovery that these lifetimes can also be prolonged ("catch-bonds"), a surprise. We created a microscopic analytic theory by incorporating the structures of selectin and integrin receptors into a conceptual framework based on the theory of stochastic equations, which quantitatively explains a wide range of experimental data (including catch-bonds at low forces and slip-bonds at high forces). Catch-bonds arise due to force-induced remodeling of hydrogen bond networks, a finding that also accounts for unbinding in structurally unrelated integrin-fibronectin and actomyosin complexes. For the selectin family, remodeling of hydrogen bond networks drives an allosteric transition resulting in the formation of maximum number of hydrogen bonds determined only by the structure of the receptor and is independent of the ligand. A similar transition allows us to predict the increase in number of hydrogen bonds in a particular allosteric state of $\\alpha_5 \\beta_1$ integrin-fibronectin complex, a conformation which is yet to be crystallized. We also make a testable prediction that a single point mutation (Tyr51Phe) in the ligand associated with selectin should dramatically alter the nature of the catch-bond compared to the wild type. Our work suggests that nature utilizes a ductile network of hydrogen bonds to engineer function over a broad range of forces.

  17. Ecologic: Nanotechnology, Environmental Assurance Bonding, and Symmetric Humility

    E-Print Network [OSTI]

    Kysar, Douglas A.

    2010-01-01T23:59:59.000Z

    Price Biodivers- ity? Economic Incentives and Biodiversityeducation, and economic incentives. Years of experience haveJ. Webber, Promoting Economic Incentives for Environmental

  18. 70 Years of Innovations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem NotEnergy, science,SpeedingWu,IntelligenceYou are70 Years of Innovations

  19. 50 Years of Space

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch >InternshipDepartment ofAugustDecember8th MeetingAllocation50 Years of

  20. Allocation Year Rollover

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWP RelatedCellulase C. bescii CelA,Portal Allocation Year

  1. HPSS Yearly Network Traffic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC) EnvironmentalGyroSolé(tm) Harmonic EngineHIV and evolution studiedHPSSHPSS Yearly

  2. Structure and function of circadian clock proteins and deuterium isotope effects in nucleic acid hydrogen bonds

    E-Print Network [OSTI]

    Vakonakis, Ioannis

    2005-08-29T23:59:59.000Z

    -terminal domain. Hydrogen bonds are of paramount importance in nucleic acid structure and function. Here we show that changes in the width and anharmonicity of vibrational potential energy wells of hydrogen bonded groups can be measured in nucleic acids and can...

  3. Hydrogen incorporation in stishovite at high pressure and symmetric hydrogen bonding in N-AlOOH

    E-Print Network [OSTI]

    Stixrude, Lars

    Hydrogen incorporation in stishovite at high pressure and symmetric hydrogen bonding in N significant amounts of hydrogen in stishovite under lower-mantle conditions. The enthalpy of solution pressure and temperature. We predict asymmetric hydrogen bonding in the stishovite^N-AlOOH solid solution

  4. Bonded carbon or ceramic fiber composite filter vent for radioactive waste

    DOE Patents [OSTI]

    Brassell, Gilbert W. (13237 W. 8th Ave., Golden, CO 80401); Brugger, Ronald P. (Lafayette, CO)

    1985-02-19T23:59:59.000Z

    Carbon bonded carbon fiber composites as well as ceramic or carbon bonded ceramic fiber composites are very useful as filters which can separate particulate matter from gas streams entraining the same. These filters have particular application to the filtering of radioactive particles, e.g., they can act as vents for containers of radioactive waste material.

  5. Rhodium-Catalyzed Activation and Functionalization of the C-C Bond of Biphenylene

    E-Print Network [OSTI]

    Jones, William D.

    temperature, displacing the chelating phosphine. A new five-coordinate complex, (PPh3)2Rh(2,2-biphenyl)Cl (3 that block double-bond migration yield the cleanest product ratios. Introduction The activation of C-C bonds of these projects is to understand factors that govern this transformation and use this knowledge to selectively

  6. Instability of two-dimensional graphene: Breaking sp2 bonds with soft x rays

    E-Print Network [OSTI]

    Zettl, Alex

    Instability of two-dimensional graphene: Breaking sp2 bonds with soft x rays S. Y. Zhou,1,2 Ç. Ö the stability of various kinds of graphene samples under soft x-ray irradiation. Our results show that in single-layer exfoliated graphene a closer analog to two-dimensional material , the in-plane carbon- carbon bonds

  7. EVALUATION OF THE INFLUENCE OF TACK COAT CONSTRUCTION FACTORS ON THE BOND STRENGTH BETWEEN PAVEMENT LAYERS

    E-Print Network [OSTI]

    EVALUATION OF THE INFLUENCE OF TACK COAT CONSTRUCTION FACTORS ON THE BOND STRENGTH BETWEEN PAVEMENT Evaluation of the Influence of Tack Coat Construction Factors on the Bond Strength between Pavement Layers 7 provided by the tack coat at the interface between pavement layers. These factors included the surface

  8. Direct-bonded GaAs/InGaAs tandem solar cell Katsuaki Tanabe,a

    E-Print Network [OSTI]

    Atwater, Harry

    , Pasadena, California 91125 Daniel J. Aiken Emcore Photovoltaics, Albuquerque, New Mexico 87123 Mark W. The direct-bonded interconnect between subcells of this two-junction cell enables monolithic interconnection- proach is to employ direct-bonded interconnects between subcells of a multijunction cell, which enables

  9. Investigation of the suitability of silicate bonding for facet termination in active

    E-Print Network [OSTI]

    Byer, Robert L.

    Investigation of the suitability of silicate bonding for facet termination in active fiber devices Memorial Drive, Rochester, NY 14623, USA supriyo@stanford.edu Abstract: We demonstrate that silicate / OPTICS EXPRESS 13003 #12;11. K. Mackenzie, I. Brown, P. Ranchod, and R. Meinhold, "Silicate bonding

  10. DOI: 10.1002/adma.200602099 Competitive Hydrogen Bonding in p-Stacked Oligomers**

    E-Print Network [OSTI]

    Rochefort, Alain

    DOI: 10.1002/adma.200602099 Competitive Hydrogen Bonding in p-Stacked Oligomers** By Alain, such as light-emitting diodes, field- effect transistors, and photovoltaic cells.[1] Although such mate- rials by multiple amide functional groups with the ability to form hydrogen bonds.[5] Thus, one can sig- nificantly

  11. Reversible Cleavage of Carbon-Carbon Bonds in Benzonitrile Using Nickel(0)

    E-Print Network [OSTI]

    Jones, William D.

    Reversible Cleavage of Carbon-Carbon Bonds in Benzonitrile Using Nickel(0) Juventino J. Garcia 3, 2000 Summary: The nickel(0) fragment [(dippe)Ni] has been found to -coordinate to the CN bond efficient and reversible. The nickel dimer [(dippe)NiH]2 has been reported to be capable of cleaving the C

  12. Mathematical Modeling and Experimental Investigations of Isothermal Solidification during Transient Liquid Phase Bonding of Nickel

    E-Print Network [OSTI]

    Medraj, Mamoun

    Liquid Phase Bonding of Nickel Superalloys M. A. Arafin1, a , M. Medraj1, b , D. P. Turner2, c and P Liquid Phase Bonding, Nickel Superalloys. Abstract. Mathematical model, based on Fick's second law with nickel based brazing filler alloy BNi-2. Experimental investigations were carried out in the range

  13. The Valuation of Convertible Bonds With Credit Risk P. A. Forsyth K. R. Vetzal

    E-Print Network [OSTI]

    Forsyth, Peter A.

    The Valuation of Convertible Bonds With Credit Risk E. Ayache P. A. Forsyth K. R. Vetzal April 22 upon the history of its stock price. This paper explores the valuation of convertible bonds subject implicit method to decou- ple the system of linear complementarity problems at each timestep. Numerical

  14. An Investigation of Bonding Mechanism in Metal Cladding by Warm Rolling 

    E-Print Network [OSTI]

    Yang, Wei

    2012-02-14T23:59:59.000Z

    the knowledge of the roll cladding process. To accomplish the objectives, aluminum 1100 sheet (Al 1100) and stainless steel 304 sheet (SST 304) are bonded by warm rolling under controlled conditions. The 180 degrees peel test is used to determine the bonding...

  15. Bonding PMMA with Titanium for Dental Implants By Zhong Yuan Luo1

    E-Print Network [OSTI]

    Barthelat, Francois

    ` Bonding PMMA with Titanium for Dental Implants By Zhong Yuan Luo1 1Department of Mining(methyl methacrylate) (PMMA) from Titanium (Ti) metal in dental implants. Project Overview ·Bonding is enhanced by modifying the titanium surface ·Modification is achieved using diazonium chemistry ·Different procedures

  16. High-Temperature Thermoelectric Characterization of IIIV Semiconductor Thin Films by Oxide Bonding

    E-Print Network [OSTI]

    High-Temperature Thermoelectric Characterization of III­V Semiconductor Thin Films by Oxide Bonding and measurement method utilizing a SiO2­SiO2 covalent bonding technique is presented for high-temperature surface passivation, and metallization with a Ti-W-N diffusion barrier. A thermoelectric material, thin

  17. High temperature thermoelectric characterization of III-V semiconductor thin films by oxide bonding

    E-Print Network [OSTI]

    Bowers, John

    bonding Je-Hyeong Bahka) , Gehong Zenga) , Joshua M. O. Zide b) , Hong Luc) , Rajeev Singhd) , Di Lianga bonding technique is developed for high temperature thermoelectric characterization of the thin film III-W-N diffusion barrier. A thermoelectric material, thin film ErAs:InGaAlAs metal/semiconductor nanocomposite

  18. FINITE VOLUME APPROXIMATION OF THE EFFECTIVE DIFFUSION MATRIX: THE CASE OF INDEPENDENT BOND

    E-Print Network [OSTI]

    FINITE VOLUME APPROXIMATION OF THE EFFECTIVE DIFFUSION MATRIX: THE CASE OF INDEPENDENT BOND with independent jump rates across nearest neighbour bonds of the lattice. We show that the infinite volume effective diffusion matrix can be almost surely recovered as the limit of finite volume periodized effective

  19. Bonding of thermoplastic polymer microfluidics Chia-Wen Tsao Don L. DeVoe

    E-Print Network [OSTI]

    Rubloff, Gary W.

    REVIEW Bonding of thermoplastic polymer microfluidics Chia-Wen Tsao Ć Don L. DeVoe Received: 20 Abstract Thermoplastics are highly attractive substrate materials for microfluidic systems, with important microchannels and other microfluidic elements, and thus bonding remains a critical step in any thermo- plastic

  20. Chapter 5. Bonds. Manual for SOA Exam FM/CAS Exam 2.

    E-Print Network [OSTI]

    Arcones, Miguel A.

    , limt1- Frt = Fr. The flat price of a bond is the money that actually changes hands at the date of sale that Bf k+t = Bm k+t + Frt. The flat price (also known as the dirty price) is the book value of a bond

  1. Strained Si, SiGe, and Ge on-insulator: review of wafer bonding fabrication techniques

    E-Print Network [OSTI]

    Strained Si, SiGe, and Ge on-insulator: review of wafer bonding fabrication techniques Gianni was arranged by Prof. C.K. Maiti Abstract Techniques for fabricating strained Si, SiGe, and Ge on is presented, with a detailed discussion of wafer bonding approaches for strained Si, SiGe, and Ge on

  2. Low-Energy (0.1 eV) Electron Attachment SS Bond Cleavage

    E-Print Network [OSTI]

    Simons, Jack

    Low-Energy (0.1 eV) Electron Attachment S­S Bond Cleavage Assisted by Coulomb Stabilization Department of Chemistry, University of Gdansk, Gdansk, Poland Received 12 September 2004; accepted 13 October], very low-energy elec- trons are attached to the gaseous sample, after which specific bonds break

  3. MOLECULAR PHYSICS, 1999, VOL. 97, NO. 7, 897 905 Dynamics and hydrogen bonding in liquid ethanol

    E-Print Network [OSTI]

    Saiz, Leonor

    MOLECULAR PHYSICS, 1999, VOL. 97, NO. 7, 897± 905 Dynamics and hydrogen bonding in liquid ethanol L of liquid ethanol at three temperatures have been carried out. The hydrogen bonding states of ethanol measurements of the frequency-dependent dielectric permittivity of liquid ethanol. 1. Introduction A detailed

  4. Transition metal-catalyzed process for addition of amines to carbon-carbon double bonds

    DOE Patents [OSTI]

    Hartwig, John F. (Durham, CT); Kawatsura, Motoi (Chatham, NJ); Loeber, Oliver (New Haven, CT)

    2002-01-01T23:59:59.000Z

    The present invention is directed to a process for addition of amines to carbon-carbon double bonds in a substrate, comprising: reacting an amine with a compound containing at least one carbon-carbon double bond in the presence a transition metal catalyst under reaction conditions effective to form a product having a covalent bond between the amine and a carbon atom of the former carbon-carbon double bond. The transition metal catalyst comprises a Group 8 metal and a ligand containing one or more 2-electron donor atoms. The present invention is also directed to enantioselective reactions of amine compounds with compounds containing carbon-carbon double bonds, and a calorimetric assay to evaluate potential catalysts in these reactions.

  5. Lateral diffusion of receptor-ligand bonds in membrane adhesion zones: Effect of thermal membrane roughness

    E-Print Network [OSTI]

    H. Krobath; G. J. Schuetz; R. Lipowsky; T. R. Weikl

    2007-03-19T23:59:59.000Z

    The adhesion of cells is mediated by membrane receptors that bind to complementary ligands in apposing cell membranes. It is generally assumed that the lateral diffusion of mobile receptor-ligand bonds in membrane-membrane adhesion zones is slower than the diffusion of unbound receptors and ligands. We find that this slowing down is not only caused by the larger size of the bound receptor-ligand complexes, but also by thermal fluctuations of the membrane shape. We model two adhering membranes as elastic sheets pinned together by receptor-ligand bonds and study the diffusion of the bonds using Monte Carlo simulations. In our model, the fluctuations reduce the bond diffusion constant in planar membranes by a factor close to 2 in the biologically relevant regime of small bond concentrations.

  6. Ultrafast conversions between hydrogen bonded structures in liquid water observed by femtosecond x-ray spectroscopy

    SciTech Connect (OSTI)

    Wen, Haidan; Huse, Nils; Schoenlein, Robert W.; Lindenberg, Aaron M.

    2010-05-01T23:59:59.000Z

    We present the first femtosecond soft x-ray spectroscopy in liquids, enabling the observation of changes in hydrogen bond structures in water via core-hole excitation. The oxygen K-edge of vibrationally excited water is probed with femtosecond soft x-ray pulses, exploiting the relation between different water structures and distinct x-ray spectral features. After excitation of the intramolecular OH stretching vibration, characteristic x-ray absorption changes monitor the conversion of strongly hydrogen-bonded water structures to more disordered structures with weaker hydrogen-bonding described by a single subpicosecond time constant. The latter describes the thermalization time of vibrational excitations and defines the characteristic maximum rate with which nonequilibrium populations of more strongly hydrogen-bonded water structures convert to less-bonded ones. On short time scales, the relaxation of vibrational excitations leads to a transient high-pressure state and a transient absorption spectrum different from that of statically heated water.

  7. Diffusion bonding of a superplastic Inconel 718SPF superalloy by electroless nickel plating

    SciTech Connect (OSTI)

    Yeh, M.S.; Chang, C.B.; Chuang, T.H.

    2000-02-01T23:59:59.000Z

    Although intimate contact can be obtained for diffusion bonding of a superplastic Inconel 718SPF superalloy under a low pressure of 7 MPa, the precipitates formed at the interface retarded achievement of a sound joint. The shear strength was only 41.5 MPa for an overlap length of 12 T (T = 1.3 mm, sheet thickness). The diffusion bondability of t his Inconel 718SPF superalloy was enhanced by electroless nickel plating. In this situation, the bonding shear strength increased to 70.4 MPa for the same overlap length of 12 T under the same bonding condition, regardless of the roughness of the surface to be bonded. Upon decreasing the overlap length from 12 to 6T, the bonding strength remained constant.

  8. Manganese Porphyrins Catalyze Selective C-H Bond Halogenations

    SciTech Connect (OSTI)

    Liu, Wei; Groves, John T

    2010-01-01T23:59:59.000Z

    We report a manganese porphyrin mediated aliphatic C?H bond chlorination using sodium hypochlorite as the chlorine source. In the presence of catalytic amounts of phase transfer catalyst and manganese porphyrin Mn(TPP)Cl 1, reaction of sodium hypochlorite with different unactivated alkanes afforded alkyl chlorides as the major products with only trace amounts of oxygenation products. Substrates with strong C?H bonds, such as neopentane (BDE =?100 kcal/mol) can be also chlorinated with moderate yield. Chlorination of a diagnostic substrate, norcarane, afforded rearranged products indicating a long-lived carbon radical intermediate. Moreover, regioselective chlorination was achieved by using a hindered catalyst, Mn(TMP)Cl, 2. Chlorination of trans-decalin with 2 provided 95% selectivity for methylene-chlorinated products as well as a preference for the C2 position. This novel chlorination system was also applied to complex substrates. With 5?-cholestane as the substrate, we observed chlorination only at the C2 and C3 positions in a net 55% yield, corresponding to the least sterically hindered methylene positions in the A-ring. Similarly, chlorination of sclareolide afforded the equatorial C2 chloride in a 42% isolated yield. Regarding the mechanism, reaction of sodium hypochlorite with the Mn{sup III} porphyrin is expected to afford a reactive Mn{sup V}?O complex that abstracts a hydrogen atom from the substrate, resulting in a free alkyl radical and a Mn{sup IV}—OH complex. We suggest that this carbon radical then reacts with a Mn{sup IV}—OCl species, providing the alkyl chloride and regenerating the reactive Mn{sup V}?O complex. The regioselectivity and the preference for CH{sub 2} groups can be attributed to nonbonded interactions between the alkyl groups on the substrates and the aryl groups of the manganese porphyrin. The results are indicative of a bent [Mn{sup v}?O---H---C] geometry due to the C—H approach to the Mn{sup v}?O (d??p?)* frontier orbital.

  9. NUCLEAR ENGINEERING Four Year Plan

    E-Print Network [OSTI]

    Tullos, Desiree

    ;Nuclear Engineering Four Year Plan Starting Fall 2009 FALL Year 1 Credits WINTER Year 1 Credits SPRINGNUCLEAR ENGINEERING Four Year Plan Fall 2009 Nuclear Engineering (67 hrs) CH Grade Perspectives (15 I NE 452 3 Neutronic Analysis II NE 457 2 Nuclear Reactor Lab Western Culture (3): NE 467 4 Nucl

  10. ADSORPTION AND BONDING OF BUTANE AND PENTANE ON THE Pt(111) CRYSTAL SURFACES. EFFECTS OF OXYGEN TREATMENTS AND DEUTERIUM PREADSORPTION

    E-Print Network [OSTI]

    Salmeron, M.

    2012-01-01T23:59:59.000Z

    which may be due to its adsorption on D-covered regions.of Physical Chemistry ADSORPTION AND BONDING OF BUTANE ANDof California. LBL 12617 ADSORPTION AND BONDING OF BUTANE

  11. A Single Phosphine Ligand Allows Palladium-Catalyzed Intermolecular C-O Bond Formation with Secondary and Primary Alcohols

    E-Print Network [OSTI]

    Wu, Xiaoxing

    Forging a bond: An efficient, general palladium catalyst for C-O bond-forming reactions of secondary and primary alcohols with a range of aryl halides has been developed using the ligand 1. Heteroaryl halides, and for the ...

  12. Polyorganosilazane preceramic binder development for reaction bonded silicon nitride composites

    SciTech Connect (OSTI)

    Mohr, D.L.; Starr, T.L. [Georgia Tech Research Inst., Atlanta, GA (United States)

    1992-11-01T23:59:59.000Z

    This study has examined the use of two commercially available polyorganosilazanes for application as preceramic binders in a composite composed of silicon carbide fibers in a reaction bonded silicon nitride (RBSN) matrix. Ceramic monolithic and composite samples were produced. Density of monolithic and whisker reinforced RBSN samples containing the polysilazane binder was increased. Mercury intrusion porosimetry revealed a significant decrease in the pore sizes of samples containing a polyorganosilazane binder. Electron micrographs of samples containing the preceramic binder looked similar to control samples containing no precursor. Overall, incorporation of the polysilazane into monolithic and whisker reinforced samples resulted in significantly increased density and decreased porosity. Nitriding of the RBSN was slightly retarded by addition of the polysilazane binder. Samples with the preceramic binders contained increased contents of {alpha} versus {beta}-silicon nitride which may be due to interaction of hydrogen evolved from polysilazane pyrolysis with the nitriding process. Initial efforts to produce continuous fiber reinforced composites via this method have not realized the same improvements in density and porosity which have been observed for monolithic and whisker reinforced samples. Further, the addition of perceramic binder resulted in a more brittle fracture morphology as compared to similar composites made without the binder.

  13. Polyorganosilazane preceramic binder development for reaction bonded silicon nitride composites

    SciTech Connect (OSTI)

    Mohr, D.L.; Starr, T.L. (Georgia Tech Research Inst., Atlanta, GA (United States))

    1992-11-01T23:59:59.000Z

    This study has examined the use of two commercially available polyorganosilazanes for application as preceramic binders in a composite composed of silicon carbide fibers in a reaction bonded silicon nitride (RBSN) matrix. Ceramic monolithic and composite samples were produced. Density of monolithic and whisker reinforced RBSN samples containing the polysilazane binder was increased. Mercury intrusion porosimetry revealed a significant decrease in the pore sizes of samples containing a polyorganosilazane binder. Electron micrographs of samples containing the preceramic binder looked similar to control samples containing no precursor. Overall, incorporation of the polysilazane into monolithic and whisker reinforced samples resulted in significantly increased density and decreased porosity. Nitriding of the RBSN was slightly retarded by addition of the polysilazane binder. Samples with the preceramic binders contained increased contents of [alpha] versus [beta]-silicon nitride which may be due to interaction of hydrogen evolved from polysilazane pyrolysis with the nitriding process. Initial efforts to produce continuous fiber reinforced composites via this method have not realized the same improvements in density and porosity which have been observed for monolithic and whisker reinforced samples. Further, the addition of perceramic binder resulted in a more brittle fracture morphology as compared to similar composites made without the binder.

  14. Method for bonding thin film thermocouples to ceramics

    DOE Patents [OSTI]

    Kreider, Kenneth G. (Potomac, MD)

    1993-01-01T23:59:59.000Z

    A method is provided for adhering a thin film metal thermocouple to a ceramic substrate used in an environment up to 700 degrees Centigrade, such as at a cylinder of an internal combustion engine. The method includes the steps of: depositing a thin layer of a reactive metal on a clean ceramic substrate; and depositing thin layers of platinum and a platinum-10% rhodium alloy forming the respective legs of the thermocouple on the reactive metal layer. The reactive metal layer serves as a bond coat between the thin noble metal thermocouple layers and the ceramic substrate. The thin layers of noble metal are in the range of 1-4 micrometers thick. Preferably, the ceramic substrate is selected from the group consisting of alumina and partially stabilized zirconia. Preferably, the thin layer of reactive metal is in the range of 0.015-0.030 micrometers (15-30 nanometers) thick. The preferred reactive metal is chromium. Other reactive metals may be titanium or zirconium. The thin layer of reactive metal may be deposited by sputtering in ultra high purity argon in a vacuum of approximately 2 milliTorr (0.3 Pascals).

  15. Nondestructive inspection of bonded composite doublers for aircraft

    SciTech Connect (OSTI)

    Roach, D.; Moore, D.; Walkington, P.

    1996-12-31T23:59:59.000Z

    One major thrust in FAA`s National Aging Aircraft Research Program is to foster new technologies in civil aircraft maintenance. Recent DOD and other government developments in using bonded composite doublers on metal structures support the need for validation of such doubler applications on US certificated airplanes. In this study, a specific composite application was chosen on an L-1011 aircraft. Primary inspection requirements for these doublers include identifying disbonds between composite laminate and aluminum parent material, and delaminations in the composite laminate. Surveillance of cracks or corrosion in the parent aluminum material beneath the double is also a concern. No single NDI method can inspect for every flaw type, therefore we need to know NDI capabilities and limitations. This paper reports on a series of NDI tests conducted on laboratory test structures and on a fuselage section from a retired L-1011. Application of ultrasonics, x-ray, and eddy current to composite doublers and results from test specimens loaded to provide a changing flaw profile, are presented in this paper. Development of appropriate inspection calibration standards are also discussed.

  16. Method of waste stabilization with dewatered chemically bonded phosphate ceramics

    DOE Patents [OSTI]

    Wagh, Arun; Maloney, Martin D.

    2010-06-29T23:59:59.000Z

    A method of stabilizing a waste in a chemically bonded phosphate ceramic (CBPC). The method consists of preparing a slurry including the waste, water, an oxide binder, and a phosphate binder. The slurry is then allowed to cure to a solid, hydrated CBPC matrix. Next, bound water within the solid, hydrated CBPC matrix is removed. Typically, the bound water is removed by applying heat to the cured CBPC matrix. Preferably, the quantity of heat applied to the cured CBPC matrix is sufficient to drive off water bound within the hydrated CBPC matrix, but not to volatalize other non-water components of the matrix, such as metals and radioactive components. Typically, a temperature range of between 100.degree. C.-200.degree. C. will be sufficient. In another embodiment of the invention wherein the waste and water have been mixed prior to the preparation of the slurry, a select amount of water may be evaporated from the waste and water mixture prior to preparation of the slurry. Another aspect of the invention is a direct anyhydrous CBPC fabrication method wherein water is removed from the slurry by heating and mixing the slurry while allowing the slurry to cure. Additional aspects of the invention are ceramic matrix waste forms prepared by the methods disclosed above.

  17. Specificity, flexibility and valence of DNA bonds guide emulsion architecture

    E-Print Network [OSTI]

    Lang Feng; Lea-Laetitia Pontani; Remi Dreyfus; Paul Chaikin; Jasna Brujic

    2013-03-25T23:59:59.000Z

    The specificity and thermal reversibility of DNA interactions have enabled the self-assembly of crystal structures, self-replicating materials and colloidal molecules. Grafting DNA onto liquid interfaces of emulsions leads to exciting new architectural possibilities due to the mobility of the DNA ligands and the patches they form between bound droplets. Here we show that the size and number of these adhesion patches (valency) can be controlled. Valence 2 leads to flexible polymers of emulsion droplets, while valence above 4 leads to rigid droplet networks. A simple thermodynamic model quantitatively describes the increase in the patch size with droplet radii, DNA concentration and the stiffness of the tether to the sticky-end. The patches are formed between droplets with complementary DNA strands or alternatively with complementary colloidal nanoparticles to mediate DNA binding between droplets. This emulsion system opens the route to directed self-assembly of more complex structures through distinct DNA bonds with varying strengths and controlled valence and flexibility.

  18. C-H..O Hydrogen Bonds in Minor Groove of A-tracts in DNA Double Helices

    E-Print Network [OSTI]

    Bansal, Manju

    C-H..O Hydrogen Bonds in Minor Groove of A-tracts in DNA Double Helices Anirban Ghosh and Manju-pair as well as cross-strand C-H..O hydrogen bonds in the minor groove. The C2-H2..O2 hydrogen bonds within leads to a narrow minor groove in these regions. # 1999 Academic Press Keywords: C-H..O hydrogen bonds

  19. Projects of the year

    SciTech Connect (OSTI)

    Hansen, T.

    2007-01-15T23:59:59.000Z

    The Peabody Hotel, Orlando, Florida was the site of Power Engineering magazine's 2006 Projects of the Year Awards Banquet, which kicked-off the Power-Gen International conference and exhibition. The Best Coal-fired Project was awarded to Tri-State Generation and Transmission Association Inc., owner of Springenville Unit 3. This is a 400 MW pulverized coal plant in Springeville, AZ, sited with two existing coal-fired units. Designed to fire Powder River Basin coal, it has low NOx burners and selective catalytic reduction for NOx control, dry flue gas desulfurization for SO{sub 2} control and a pulse jet baghouse for particulate control. It has a seven-stage feedwater heater and condensers to ensure maximum performance. Progress Energy-Carolinas' Asheville Power Station FGD and SCR Project was awarded the 2006 coal-fired Project Honorable Mention. This plant in Skyland, NC was required to significantly reduce NOx emissions. When completed, the improvements will reduce NOx by 93% compared to 1996 levels and SO{sub 2} by 93% compared to 2001 levels. Awards for best gas-fired, nuclear, and renewable/sustainable energy projects are recorded. The Sasyadko Coal-Mine Methane Cogeneration Plant near Donezk, Ukraine, was given the 2006 Honorable Mention for Best Renewable/Sustainable Energy Project. In November 2004, Ukraine was among 14 nations to launch the Methane to Markets partnership. The award-winning plant is fuelled by methane released during coal extraction. It generates 42 MW of power. 4 photos.

  20. Correlation among electronegativity, cation polarizability, optical basicity and single bond strength of simple oxides

    SciTech Connect (OSTI)

    Dimitrov, Vesselin, E-mail: vesselin@uctm.edu [Department of Silicate Technology, University of Chemical Technology and Metallurgy, 8, Kl. Ohridski Blvd., Sofia 1756 (Bulgaria)] [Department of Silicate Technology, University of Chemical Technology and Metallurgy, 8, Kl. Ohridski Blvd., Sofia 1756 (Bulgaria); Komatsu, Takayuki, E-mail: komatsu@mst.nagaokaut.ac.jp [Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka 940-2188 (Japan)] [Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka 940-2188 (Japan)

    2012-12-15T23:59:59.000Z

    A suitable relationship between free-cation polarizability and electronegativity of elements in different valence states and with the most common coordination numbers has been searched on the basis of the similarity in physical nature of both quantities. In general, the cation polarizability increases with decreasing element electronegativity. A systematic periodic change in the polarizability against the electronegativity has been observed in the isoelectronic series. It has been found that generally the optical basicity increases and the single bond strength of simple oxides decreases with decreasing the electronegativity. The observed trends have been discussed on the basis of electron donation ability of the oxide ions and type of chemical bonding in simple oxides. - Graphical abstract: This figure shows the single bond strength of simple oxides as a function of element electronegativity. A remarkable correlation exists between these independently obtained quantities. High values of electronegativity correspond to high values of single bond strength and vice versa. It is obvious that the observed trend in this figure is closely related to the type of chemical bonding in corresponding oxide. Highlights: Black-Right-Pointing-Pointer A suitable relationship between free-cation polarizability and electronegativity of elements was searched. Black-Right-Pointing-Pointer The cation polarizability increases with decreasing element electronegativity. Black-Right-Pointing-Pointer The single bond strength of simple oxides decreases with decreasing the electronegativity. Black-Right-Pointing-Pointer The observed trends were discussed on the basis of type of chemical bonding in simple oxides.

  1. Subangstrom Crystallography Reveals that Short Ionic Hydrogen Bonds, and Not a His-Asp Low-Barrier Hydrogen

    E-Print Network [OSTI]

    Agard, David

    Subangstrom Crystallography Reveals that Short Ionic Hydrogen Bonds, and Not a His-Asp Low-Barrier Hydrogen Bond, Stabilize the Transition State in Serine Protease Catalysis Cynthia N. Fuhrmann, Matthew D that destabilizes the His57-Ser195 hydrogen bond, preventing the back-reaction. In both structures the His57-Asp102

  2. Hydrogen Bond Lifetimes and Energetics for Solute/Solvent Complexes Studied with 2D-IR Vibrational Echo Spectroscopy

    E-Print Network [OSTI]

    Fayer, Michael D.

    Hydrogen Bond Lifetimes and Energetics for Solute/Solvent Complexes Studied with 2D-IR Vibrational@stanford.edu Abstract: Weak hydrogen-bonded solute/solvent complexes are studied with ultrafast two the dissociation and formation rates of the hydrogen-bonded complexes. The dissociation rates of the weak hydrogen

  3. Hydrogen-Bonding Interaction in Molecular Complexes and Clusters of Aerosol Nucleation Alexei Khalizov, and Renyi Zhang*

    E-Print Network [OSTI]

    Hydrogen-Bonding Interaction in Molecular Complexes and Clusters of Aerosol Nucleation Precursors, water, and ammonia. A central feature of the complexes is the presence of two hydrogen bonds. Organic acid-sulfuric acid complexes show one strong and one medium-strength hydrogen bond whereas

  4. Hydrogen Bonds Involved in Binding the Qi-site Semiquinone in the bc1 Complex, Identified through Deuterium Exchange

    E-Print Network [OSTI]

    Crofts, Antony R.

    Hydrogen Bonds Involved in Binding the Qi-site Semiquinone in the bc1 Complex, Identified through them. The strength of interactions indicates that the protons are involved in hydrogen bonds with SQ. The hyperfine cou- plings differ from values typical for in-plane hydrogen bonds previously observed in model

  5. Hydrogen Bond Switching among Flavin and Amino Acid Side Chains in the BLUF Photoreceptor Observed by Ultrafast Infrared Spectroscopy

    E-Print Network [OSTI]

    van Stokkum, Ivo

    Hydrogen Bond Switching among Flavin and Amino Acid Side Chains in the BLUF Photoreceptor Observed hydrogen-bond network with nearby amino acid side chains, including a highly conserved tyrosine and glutamine. The participation of particular amino acid side chains in the ultrafast hydrogen-bond switching

  6. Hydrogen Bond Switching among Flavin and Amino Acids Determines the Nature of Proton-Coupled Electron Transfer in BLUF

    E-Print Network [OSTI]

    van Stokkum, Ivo

    Hydrogen Bond Switching among Flavin and Amino Acids Determines the Nature of Proton results from a hydrogen bond switch between the flavin and its surrounding amino acids that preconfigures a rearrangement of the hydrogen bond network around the flavin takes place leading to a 10-15 nm red shift

  7. Hydrogen bonding preference of equatorial versus axial hydroxyl groups in pyran and cyclohexane rings in organic crystals

    E-Print Network [OSTI]

    de Gispert, Adriŕ

    Paper Hydrogen bonding preference of equatorial versus axial hydroxyl groups in pyran of the hydrogen bonding counts in crystalline pyranose monosaccharides, we noticed that equatorial hydroxyls formed more hydrogen bonds, on average, than axial groups. A survey of the Cambridge Structural Database

  8. Plasma-activated direct bonding of diamond-on-insulator wafers to thermal oxide grown silicon wafers

    E-Print Network [OSTI]

    Akin, Tayfun

    microscopy, profilometer and wafer bow measurements. Plasma-activated direct bonding of DOI wafers to thermalPlasma-activated direct bonding of diamond-on-insulator wafers to thermal oxide grown silicon (CMP) on the diamond surface makes a poor bonding to silicon wafers with thermal oxide. Our results

  9. Bond Graph Modeling of Current Diffusion in Magnetic Cores Herv Morel, Bruno Allard, Sabrine M'Rad, Cyril Buttay

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Bond Graph Modeling of Current Diffusion in Magnetic Cores Hervé Morel, Bruno Allard, Sabrine M, F-69621 Villeurbanne Cedex, France KEYBOARD: Bond Graphs, Variational approximation, Diffusive with the diffusion representation. Both approaches yield a same bond graph representation. 2. MODELING CURRENT

  10. Chemistry of Materials 1989, 1,83-101 How C-C Bonds Are Formed and How They Influence

    E-Print Network [OSTI]

    Li, Jing

    Chemistry of Materials 1989, 1,83-101 How C-C Bonds Are Formed and How They Influence Structural Choices in Some Binary and Ternary Metal Carbides 83 Jing Li and Roald Hoffmann* Department of Chemistry properties. In the UC2structure, both uranium-carbon bonding and carbon-carbon bonding are enhanced upon

  11. Hydrogen-bond equilibria and life times in a supercooled monohydroxy alcohol

    E-Print Network [OSTI]

    C. Gainaru; S. Kastner; F. Mayr; P. Lunkenheimer; S. Schildmann; H. J. Weber; W. Hiller; A. Loidl; R. Böhmer

    2011-06-29T23:59:59.000Z

    Dielectric loss spectra covering 13 decades in frequency were collected for 2-ethyl-1-hexanol, a monohydroxy alcohol that exhibits a prominent Debye-like relaxation, typical for several classes of hydrogen-bonded liquids. The thermal variation of the dielectric absorption amplitude agrees well with that of the hydrogen-bond equilibrium population, experimentally mapped out using near infrared (NIR) and nuclear magnetic resonance (NMR) measurements. Despite this agreement, temperature-jump NIR spectroscopy reveals that the hydrogen-bond switching rate does not define the frequency position of the prominent absorption peak. This contrasts with widespread notions and models based thereon, but is consistent with a recent approach.

  12. Bond Energy Sums in Benzene, Cyclohexatriene and Cyclohexane Prove Resonance Unnecessary

    E-Print Network [OSTI]

    Raji Heyrovska

    2008-07-27T23:59:59.000Z

    The recent new structure of benzene shows that it consists of three C atoms of radii as in graphite alternating with three C atoms with double bond radii. This is different from the hypothetical cyclohexatriene (Kekule structure) involving alternate double and single bonds. It was shown that the difference in the bond energy sum of the atomic structure of benzene from that of the Kekule structure is the energy (erroneously) assumed to be due to resonance. Here it is shown that the present structure of benzene also explains the energy of hydrogenation into cyclohexane and its difference from that of cyclohexatriene.

  13. Endowment Performance, Fiscal Years 1982-2012 Fiscal Year

    E-Print Network [OSTI]

    Management Company, based on reinvestment of all earnings on a monthly basis. (3) Values have been recastEndowment Performance, Fiscal Years 1982-2012 Fiscal Year Year-end market value (in 000's) Return Market Value of Endowment Funds as of June 30, 2012 Endowment Market Value Market Value % of Total Arts

  14. Endowment Performance, Fiscal Years 1981-2011 Fiscal Year

    E-Print Network [OSTI]

    by the Harvard Management Company, based on reinvestment of all earnings on a monthly basis. (3) Values have beenEndowment Performance, Fiscal Years 1981-2011 Fiscal Year Year-end market value (in 000's) Return REPORTS Market Value of Endowment Funds as of June 30, 2011 Endowment Market Value Market Value % of Total

  15. Nepal Migration Year Book 2011 Migration Year Book

    E-Print Network [OSTI]

    Richner, Heinz

    Nepal Migration Year Book 2011 1 #12;Nepal Migration Year Book 2011 NIDS NCCR North-South #12;Book Nepal Migration Year Book 2011 Publishers Nepal Institute of Development Studies (NIDS) G.P.O. Box: 7647, Kathmandu, Nepal Email: nids@mail.com.np Web: www.nids.org.np National Centre of Competence in Research

  16. Developing A Laser Shockwave Model For Characterizing Diffusion Bonded Interfaces

    SciTech Connect (OSTI)

    James A. Smith; Jeffrey M. Lacy; Barry H. Rabin

    2014-07-01T23:59:59.000Z

    12. Other advances in QNDE and related topics: Preferred Session Laser-ultrasonics Developing A Laser Shockwave Model For Characterizing Diffusion Bonded Interfaces 41st Annual Review of Progress in Quantitative Nondestructive Evaluation Conference QNDE Conference July 20-25, 2014 Boise Centre 850 West Front Street Boise, Idaho 83702 James A. Smith, Jeffrey M. Lacy, Barry H. Rabin, Idaho National Laboratory, Idaho Falls, ID ABSTRACT: The US National Nuclear Security Agency has a Global Threat Reduction Initiative (GTRI) which is assigned with reducing the worldwide use of high-enriched uranium (HEU). A salient component of that initiative is the conversion of research reactors from HEU to low enriched uranium (LEU) fuels. An innovative fuel is being developed to replace HEU. The new LEU fuel is based on a monolithic fuel made from a U-Mo alloy foil encapsulated in Al-6061 cladding. In order to complete the fuel qualification process, the laser shock technique is being developed to characterize the clad-clad and fuel-clad interface strengths in fresh and irradiated fuel plates. The Laser Shockwave Technique (LST) is being investigated to characterize interface strength in fuel plates. LST is a non-contact method that uses lasers for the generation and detection of large amplitude acoustic waves to characterize interfaces in nuclear fuel plates. However the deposition of laser energy into the containment layer on specimen’s surface is intractably complex. The shock wave energy is inferred from the velocity on the backside and the depth of the impression left on the surface from the high pressure plasma pulse created by the shock laser. To help quantify the stresses and strengths at the interface, a finite element model is being developed and validated by comparing numerical and experimental results for back face velocities and front face depressions with experimental results. This paper will report on initial efforts to develop a finite element model for laser shock.

  17. Using Qualified Energy Conservation Bonds (QECBs) to Fund a Residential Energy Efficiency Loan Program: Case Study on Saint Louis County, MO

    E-Print Network [OSTI]

    Zimring, Mark

    2012-01-01T23:59:59.000Z

    2011 Using Qualified Energy Conservation Bonds (QECBs) toCounty, MO Qualified Energy Conservation Bonds (QECBs) arerange of qualified energy conservation projects. QECBs offer

  18. Year in Review Annual Report

    E-Print Network [OSTI]

    Machery, Edouard

    Year in Review 2005-06 Annual Report Center for Latin American Studies University Center for International Studies University of Pittsburgh #12;2005-06 Year in Review 2 Message from the Acting Director

  19. Year in Review Annual Report

    E-Print Network [OSTI]

    Machery, Edouard

    Year in Review 2004-05 Annual Report Center for Latin American Studies University Center for International Studies University of Pittsburgh #12;2004-05 Year in Review 2 Message from the Director This has

  20. Year in Review Annual Report

    E-Print Network [OSTI]

    Machery, Edouard

    Year in Review 2006-07 Annual Report Center for Latin American Studies University Center for International Studies University of Pittsburgh #12;2006-07 Year in Review 2 Message from the Director Academic

  1. YEAR 2 BIOMASS UTILIZATION

    SciTech Connect (OSTI)

    Christopher J. Zygarlicke

    2004-11-01T23:59:59.000Z

    This Energy & Environmental Research Center (EERC) Year 2 Biomass Utilization Final Technical Report summarizes multiple projects in biopower or bioenergy, transportation biofuels, and bioproducts. A prototype of a novel advanced power system, termed the high-temperature air furnace (HITAF), was tested for performance while converting biomass and coal blends to energy. Three biomass fuels--wood residue or hog fuel, corn stover, and switchgrass--and Wyoming subbituminous coal were acquired for combustion tests in the 3-million-Btu/hr system. Blend levels were 20% biomass--80% coal on a heat basis. Hog fuel was prepared for the upcoming combustion test by air-drying and processing through a hammer mill and screen. A K-Tron biomass feeder capable of operating in both gravimetric and volumetric modes was selected as the HITAF feed system. Two oxide dispersion-strengthened (ODS) alloys that would be used in the HITAF high-temperature heat exchanger were tested for slag corrosion rates. An alumina layer formed on one particular alloy, which was more corrosion-resistant than a chromia layer that formed on the other alloy. Research activities were completed in the development of an atmospheric pressure, fluidized-bed pyrolysis-type system called the controlled spontaneous reactor (CSR), which is used to process and condition biomass. Tree trimmings were physically and chemically altered by the CSR process, resulting in a fuel that was very suitable for feeding into a coal combustion or gasification system with little or no feed system modifications required. Experimental procedures were successful for producing hydrogen from biomass using the bacteria Thermotoga, a deep-ocean thermal vent organism. Analytical procedures for hydrogen were evaluated, a gas chromatography (GC) method was derived for measuring hydrogen yields, and adaptation culturing and protocols for mutagenesis were initiated to better develop strains that can use biomass cellulose. Fly ash derived from cofiring coal with waste paper, sunflower hulls, and wood waste showed a broad spectrum of chemical and physical characteristics, according to American Society for Testing and Materials (ASTM) C618 procedures. Higher-than-normal levels of magnesium, sodium, and potassium oxide were observed for the biomass-coal fly ash, which may impact utilization in cement replacement in concrete under ASTM requirements. Other niche markets for biomass-derived fly ash were explored. Research was conducted to develop/optimize a catalytic partial oxidation-based concept for a simple, low-cost fuel processor (reformer). Work progressed to evaluate the effects of temperature and denaturant on ethanol catalytic partial oxidation. A catalyst was isolated that had a yield of 24 mole percent, with catalyst coking limited to less than 15% over a period of 2 hours. In biodiesel research, conversion of vegetable oils to biodiesel using an alternative alkaline catalyst was demonstrated without the need for subsequent water washing. In work related to biorefinery technologies, a continuous-flow reactor was used to react ethanol with lactic acid prepared from an ammonium lactate concentrate produced in fermentations conducted at the EERC. Good yields of ester were obtained even though the concentration of lactic acid in the feed was low with respect to the amount of water present. Esterification gave lower yields of ester, owing to the lowered lactic acid content of the feed. All lactic acid fermentation from amylose hydrolysate test trials was completed. Management activities included a decision to extend several projects to December 31, 2003, because of delays in receiving biomass feedstocks for testing and acquisition of commercial matching funds. In strategic studies, methods for producing acetate esters for high-value fibers, fuel additives, solvents, and chemical intermediates were discussed with several commercial entities. Commercial industries have an interest in efficient biomass gasification designs but are waiting for economic incentives. Utility, biorefinery, pulp and paper, or o

  2. ATNI Mid-year Convention

    Broader source: Energy.gov [DOE]

    The Affiliated Tribes of Northwest Indians Mid-year Convention will be hosted by the Chehalis Tribe.

  3. Mourning 2.0: Continuing Bonds between the Living and the Dead on Facebook

    E-Print Network [OSTI]

    Irwin, Melissa D.

    2012-05-31T23:59:59.000Z

    This study examines the burgeoning phenomenon of Facebook memorial pages and how this research about dynamic, online social networking environments can contribute to the existing literature related to Klass et al's (1996) continuing bonds thesis...

  4. Eutectic bonding of a Ti sputter coated, carbon aerogel wafer to a Ni foil

    SciTech Connect (OSTI)

    Jankowski, A.F.; Hayes, J.P.; Kanna, R.L.

    1994-06-01T23:59:59.000Z

    The formation of high energy density, storage devices is achievable using composite material systems. Alternate layering of carbon aerogel wafers and Ni foils with rnicroporous separators is a prospective composite for capacitor applications. An inherent problem exists to form a physical bond between Ni and the porous carbon wafer. The bonding process must be limited to temperatures less than 1000{degrees}C, at which point the aerogel begins to degrade. The advantage of a low temperature eutectic in the Ni-Ti alloy system solves this problem. Ti, a carbide former, is readily adherent as a sputter deposited thin film onto the carbon wafer. A vacuum bonding process is then used to join the Ni foil and Ti coating through eutectic phase formation. The parameters required for successfld bonding are described along with a structural characterization of the Ni foil-carbon aerogel wafer interface.

  5. Hydrogen Bond Rearrangements in Water Probed with Temperature-Dependent 2D IR

    E-Print Network [OSTI]

    Nicodemus, Rebecca A.

    We use temperature-dependent two-dimensional infrared spectroscopy (2D IR) of dilute HOD in H2O to investigate hydrogen bond rearrangements in water. The OD stretching frequency is sensitive to its environment, and loss ...

  6. Water dynamics: Relation between hydrogen bond bifurcations, molecular jumps, local density & hydrophobicity

    E-Print Network [OSTI]

    John Tatini Titantah; Mikko Karttunen

    2013-03-29T23:59:59.000Z

    Structure and dynamics of water remain a challenge. Resolving the properties of hydrogen bonding lies at the heart of this puzzle. Here we employ ab initio Molecular Dynamics (AIMD) simulations over a wide temperature range. The total simulation time was approx 2 ns. Both bulk water and water in the presence of a small hydrophobic molecule were simulated. We show that large-angle jumps and bond bifurcations are fundamental properties of water dynamics and that they are intimately coupled to both local density and hydrogen bond stretch oscillations in scales from about 60 to a few hundred femtoseconds: Local density differences are the driving force for bond bifurcations and the consequent large-angle jumps. The jumps are intimately connected to the recently predicted energy asymmetry. Our analysis also appears to confirm the existence of the so-called negativity track provided by the lone pairs of electrons on the oxygen atom to enable water rotation.

  7. Company Name: Tighe & Bond, Inc. Web Site: www.tighebond.com

    E-Print Network [OSTI]

    New Hampshire, University of

    Company Name: Tighe & Bond, Inc. Web Site: www.tighebond.com Industry: Engineering Brief Company Business. Majors they typically recruit: Civil Engineering, Earth Sciences Do they offer internships: Yes in civil, geotechnical and environmental engineering, environmental science, hydrogeology and geographic

  8. Steel bonded dense silicon nitride compositions and method for their fabrication

    DOE Patents [OSTI]

    Landingham, R.L.; Shell, T.E.

    1985-05-20T23:59:59.000Z

    A two-stage bonding technique for bonding high density silicon nitride and other ceramic materials to stainless steel and other hard metals, and multilayered ceramic-metal composites prepared by the technique are disclosed. The technique involves initially slurry coating a surface of the ceramic material at about 1500/sup 0/C in a vacuum with a refractory material and the stainless steel is then pressure bonded to the metallic coated surface by brazing it with nickel-copper-silver or nickel-copper-manganese alloys at a temperature in the range of about 850/sup 0/ to 950/sup 0/C in a vacuum. The two-stage bonding technique minimizes the temperature-expansion mismatch between the dissimilar materials.

  9. Understanding visual preferences for landscapes: an examination of the relationship between aesthetics and emotional bonding 

    E-Print Network [OSTI]

    Cheng, Chia-Kuen

    2009-05-15T23:59:59.000Z

    The relationship between humans and the quality of the environment have been examined primarily through two conceptual constructs: landscape aesthetics and place attachment or emotional place bonding. The former focuses on the physical environment...

  10. THROUGH-BOND ENERGY TRANSFER CASSETTES FOR MULTIPLEXING & DEVELOPMENT OF METHODS FOR PROTEIN MONO-LABELING

    E-Print Network [OSTI]

    Ueno, Yuichiro

    2010-07-14T23:59:59.000Z

    the potential to increase both the resolution and fluorescence intensities obtained from several probes excited by a laser source operating at a single wavelength. n hv donr aceptor hv' through-bond enrgy transfer ! elctron conjugated linkage Figure 1...

  11. Hydrogen bond reorganization and vibrational relaxation in water studied with ultrafast infrared spectroscopy

    E-Print Network [OSTI]

    Nicodemus, Rebecca Anne

    2011-01-01T23:59:59.000Z

    Water consists of an extended hydrogen bond network that is constantly evolving. More than just a description of the time averaged structure is necessary to understand any process that occurs in water. In this thesis we ...

  12. Environmental durability of FRP bond to concrete subjected to freeze-thaw action

    E-Print Network [OSTI]

    Dohnálek, Pavel

    2006-01-01T23:59:59.000Z

    An experimental study was performed to determine the environmental durability of the adhesive bond between fiber-reinforced plastic (FRP) and concrete. The study specifically focused on freeze-thaw cycling exposure of such ...

  13. Large Angular Jump Mechanism Observed for Hydrogen Bond Exchange in Aqueous Perchlorate Solution

    SciTech Connect (OSTI)

    Ji, Minbiao; /SLAC, PULSE /Stanford U., Phys. Dept.; Odelius3, Michael; /Stockholm U.; Gaffney1, K.J.; /aff SLAC, PULSE

    2010-06-11T23:59:59.000Z

    The mechanism for hydrogen bond (H-bond) switching in solution has remained subject to debate despite extensive experimental and theoretical studies. We have applied polarization-selective multidimensional vibrational spectroscopy to investigate the H-bond exchange mechanism in aqueous NaClO{sub 4} solution. The results show that a water molecule shifts its donated H-bonds between water and perchlorate acceptors by means of large, prompt angular rotation. Using a jump-exchange kinetic model, we extract an average jump angle of 49 {+-} 4{sup o}, in qualitative agreement with the jump angle observed in molecular dynamics simulations of the same aqueous NaClO{sub 4} solution.

  14. Long-term performance of epoxy-bonded rebar-couplers

    E-Print Network [OSTI]

    Brungraber, Griffin Rupp

    2009-01-01T23:59:59.000Z

    Water transport in epoxy resins." Prog. Polymer Science.Hygrothermal effects of epoxy resin. Part I: the nature ofStandard Specification for Epoxy-Resin-Base Bonding Systems

  15. The Development of Werner-type Cobalt Complexes in Enantioselective Hydrogen Bond Mediated Catalysis

    E-Print Network [OSTI]

    Lewis, Kyle

    2013-12-03T23:59:59.000Z

    _(f)^(-) and ?-[Co((S,S)-dpen)_(3)]^(3+) 2X^(–) Bar^( –)(X = Cl^(–), BF_(4)^(–), PF_(6)^(–)). These Werner complexes were then applied as hydrogen bond mediating catalysts for enantioselective Michael additions of dialkyl malonates to nitroolefins...

  16. Stress and Fracture Analysis of a Class of Bonded Joints in Wind Turbine Blades

    E-Print Network [OSTI]

    Chen, Chang

    2013-05-08T23:59:59.000Z

    A simplified model is proposed to investigate the stress fields and the strain energy release rate (SERR) associated with cracks in bonded joints in wind turbine blades. The proposed two-dimensional model consists of nonparallel upper and lower...

  17. Hybrid Two-Dimensional Electronic Systems and Other Applications of sp-2 Bonded Light Elements

    E-Print Network [OSTI]

    Kessler, Brian Maxwell

    2010-01-01T23:59:59.000Z

    A.4 A.5 vii List of Tables DOE Hydrogen Storage Targets forsp-2 Bonded Materials 5 Hydrogen Storage 5.1 Motivation andJeffrey R. Long. Hydrogen storage in a microporous metal-

  18. Evaluation of the Role of Water in the H2 Bond Formation by Ni...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    . Abstract: We investigate the role of water in the H-H bond formation by a family of nickel molecular catalysts that exhibit high rates for H2 production in acetonitrile solvent....

  19. Observation of Weak C-H...O Hydrogen Bonding by Unactivated Alkanes...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    structures at low temperatures due to weak C-H…O hydrogen bonding between the terminal CH3 and CO2- groups for n?5. Temperature-dependent studies showed that the folding...

  20. A Hidden Markov Chain Model for the Term Structure of Bond Credit Risk Spreads 

    E-Print Network [OSTI]

    Thomas, L; Allen, David E; Morkel-Kingsbury, N

    1998-01-01T23:59:59.000Z

    This paper provides a Markov chain model for the term structure and credit risk spreads of bond processes. It allows dependency between the stochastic process modeling the interest rate and the Markov chain process describing ...